KR940021609A - 불포화 폴리우레탄 및 알키드 수지용 분산제로서 이의 용도 - Google Patents

불포화 폴리우레탄 및 알키드 수지용 분산제로서 이의 용도 Download PDF

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KR940021609A
KR940021609A KR1019940004168A KR19940004168A KR940021609A KR 940021609 A KR940021609 A KR 940021609A KR 1019940004168 A KR1019940004168 A KR 1019940004168A KR 19940004168 A KR19940004168 A KR 19940004168A KR 940021609 A KR940021609 A KR 940021609A
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unsaturated
component
groups
unsaturated polyurethane
group
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안겔마이어 칼-한스
발쯔 게르트
조엘러 요아힘
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칼-헤르만 메이어-둘호이어, 베른하르트 엠. 벡크
훽스트 아크티엔게젤샤프트
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Publication of KR940021609A publication Critical patent/KR940021609A/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
    • C08J3/03—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
    • C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/2805—Compounds having only one group containing active hydrogen
    • C08G18/2815—Monohydroxy compounds
    • C08G18/282—Alkanols, cycloalkanols or arylalkanols including terpenealcohols
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/2805—Compounds having only one group containing active hydrogen
    • C08G18/2815—Monohydroxy compounds
    • C08G18/283—Compounds containing ether groups, e.g. oxyalkylated monohydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/2805—Compounds having only one group containing active hydrogen
    • C08G18/2815—Monohydroxy compounds
    • C08G18/284—Compounds containing ester groups, e.g. oxyalkylated monocarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/2805—Compounds having only one group containing active hydrogen
    • C08G18/285—Nitrogen containing compounds
    • C08G18/2865—Compounds having only one primary or secondary amino group; Ammonia
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4833—Polyethers containing oxyethylene units
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67—Unsaturated compounds having active hydrogen
    • C08G18/671—Unsaturated compounds having only one group containing active hydrogen
    • C08G18/672—Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C08J2367/08—Polyesters modified with higher fatty oils or their acids, or with resins or resin acids
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • Y10T428/31645—Next to addition polymer from unsaturated monomers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • Y10T428/31645—Next to addition polymer from unsaturated monomers
    • Y10T428/31649—Ester, halide or nitrile of addition polymer

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Dispersion Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

본 발명은 a) 하나 이상의 유기 폴리이소시아네이트, b) 불포화 지방 알콜 또는 이의 폴리알킬렌 글리콜에테르, 불포화 지방아민 또는 불포화 지방산 및 모노 에폭사이드의 반응 생성물, c) 이소시아네이트 그룹과 반응하는 그룹 2개 뿐만 아니라, 이온성인 그룹 하나 이상을 포함하는 화합물, d) 분자량 750 내지 10,000의 폴리알킬렌 글리콜 및 필요한 경우, e) 3 내지 6개의 하이드록실 그룹 또는 아미노 그룹을 함유하는 화합물을 성분(a)중의 이소시아네이트 그룹/나머지 성분중의 하이드록실 그룹 및 아미노 그룹의 비를 0.7 : 1 내지 1.2 : 1로 반응시켜 제조할 수 있으며 폴리에틸렌 글리콜 단위를 20 내지 80중량% 포함하는 불포화 폴리우레탄에 관한것이다.
불포화 폴리우레탄은 알키드 수지용 분산액으로서 사용된다.

Description

불포화 폴리우레탄 및 알키드 수지용 분산제로서 이의 용도
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (7)

  1. (a) 하나 이상의 유기 폴리이소시아네이트, (b) 불포화 지방 알콜 또는 이의 폴리알킬렌 글리콜에테르, 불포화 지방아민 또는 불포화 지방산 및 모노 에폭사이드의 반응 생성물, (c) 이소시아네이트 그룹과 반응하는 그룹 2개 뿐만 아니라, 이온성 그룹 또는 이온성 그룹으로 전환될 수 있는 구조 성분 하나 이상을 함유하는 화합물, (d) 분자량 750 내지 10,000의 폴리알킬렌 글리콜 및 필요한 경우, (e) 3 내지 6개의 하이드록실 그룹 또는 아미노 그룹을 함유하는 화합물을 성분(a)중의 이소시아네이트 그룹/나머지 성분중의 하이드록실 그룹 및 아미노 그룹의 비를 0.7 : 1 내지 1.2 : 1로 반응시켜 제조할 수 있으며 폴리에틸렌 글리콜 단위를 20 내지 80중량% 포함하는 불포화 폴리우레탄.
  2. 제 1 항에 있어서, 성분(b)가 다중불포화된 불포화 폴리우레탄.
  3. 제 1 항에 있어서, 성분(b)가 1 내지 20개의 에틸렌옥사이드 단위를 갖는 에톡실화 C8-20지방 알콜인 불포화 폴리우레탄.
  4. 제 1 항에 있어서, 성분(b)가 불포화 지방산 및 모노 에폭사이드의 반응 생성물인 불포화 폴리우레탄.
  5. 제 1 항에 있어서, 성분(c)가 비스하이드록시알칸 카복실산인 불포화 폴리우레탄.
  6. 소수성 알키드 수지의 수성 분산액을 제조하기 위한 분산제로서 제 1 항에서 청구한 바와 같은 불포화 폴리우레탄을 사용하는 방법.
  7. 제 1 항에서 청구한 바와 같은 불포화 폴리우레탄을 포함하는 소수성 알키드 수지의 수성 분산액.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019940004168A 1993-03-05 1994-03-04 불포화 폴리우레탄 및 알키드 수지용 분산제로서 이의 용도 KR940021609A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE?P4306946.0? 1993-03-05
DE4306946A DE4306946A1 (de) 1993-03-05 1993-03-05 Ungesättigte Polyurethane und deren Verwendung als Dispergiermittel für Alkydharze

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KR940021609A true KR940021609A (ko) 1994-10-19

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US (1) US5466772A (ko)
EP (1) EP0613914A1 (ko)
JP (1) JPH072972A (ko)
KR (1) KR940021609A (ko)
AU (1) AU668272B2 (ko)
BR (1) BR9400831A (ko)
CA (1) CA2115818A1 (ko)
CZ (1) CZ49794A3 (ko)
DE (1) DE4306946A1 (ko)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4416336A1 (de) * 1994-05-09 1995-11-16 Hoechst Ag Hydrophile Polyurethan-Polyharnstoffe und deren Verwendung als Dispergiermittel für Kunstharze
DE19515918A1 (de) * 1995-05-02 1996-11-07 Hoechst Ag Wasserverdünnbare Zweikomponenten-Überzugsmasse auf Basis fremdemulgierter Alkydharze, ein Verfahren zu deren Herstellung und deren Verwendung
US6548588B1 (en) 1998-06-11 2003-04-15 Avecia Inc. Aqueous resin dispersions
WO2000027938A1 (en) * 1998-11-06 2000-05-18 Avecia Inc. Aqueous resin dispersions
EP1471123A1 (de) 2003-04-21 2004-10-27 Surface Specialties Austria GmbH Alkydharz-Emulsion für Decklacke
DE10334753A1 (de) * 2003-07-30 2005-03-10 Constr Res & Tech Gmbh Selbstvernetzende hochmolekulare Polyurethan-Dispersion
WO2005016999A1 (en) * 2003-08-13 2005-02-24 The Valspar Corporation Water-based polyurethane - polyethylene compositions
US7888425B2 (en) * 2004-07-16 2011-02-15 Reichhold, Inc. Low volatile organic compound stable solvent-based polyurethane compositions for coatings
JP5054692B2 (ja) * 2005-08-23 2012-10-24 アクゾ ノーベル コーティングス インターナショナル ビー ヴィ 分散性ポリウレタン樹脂
US8349945B2 (en) * 2008-06-03 2013-01-08 Dow Global Technologies Llc Composite dispersion, method of producing the same, and articles made therefrom
BR112013009600B1 (pt) * 2010-10-22 2020-11-10 Basf Se espessantes de poliuretano
EP2655527A1 (de) 2010-12-20 2013-10-30 ALLNEX AUSTRIA GmbH Verfahren zur härtung von oberflächenbeschichtungsmitteln

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2011636A1 (de) * 1970-03-12 1971-09-23 Henkel & Cie GmbH, 4000 Düsseldorf Feuchtigkeitshärtende Polyurethanlacke
GB1520940A (en) * 1977-06-16 1978-08-09 Ciba Geigy Ag Production of low molecular weight urethane polymer dispersions
US4116902A (en) * 1977-10-05 1978-09-26 International Minerals & Chemical Corp. Polyurethane-modified alkyd resin
US4499233A (en) * 1983-05-03 1985-02-12 Nl Industries, Inc. Water dispersible, modified polyurethane and a thickened aqueous composition containing it

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US5466772A (en) 1995-11-14
CA2115818A1 (en) 1994-09-06
AU5754494A (en) 1994-09-08
JPH072972A (ja) 1995-01-06
AU668272B2 (en) 1996-04-26
DE4306946A1 (de) 1994-09-08
CZ49794A3 (en) 1994-09-14
EP0613914A1 (de) 1994-09-07
BR9400831A (pt) 1994-11-22

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