KR940014489A - 폴리이소시아네이트 혼합물, 그의 제조 방법 및 폴리우레탄 제조를 위한 용도 - Google Patents
폴리이소시아네이트 혼합물, 그의 제조 방법 및 폴리우레탄 제조를 위한 용도 Download PDFInfo
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- KR940014489A KR940014489A KR1019930025754A KR930025754A KR940014489A KR 940014489 A KR940014489 A KR 940014489A KR 1019930025754 A KR1019930025754 A KR 1019930025754A KR 930025754 A KR930025754 A KR 930025754A KR 940014489 A KR940014489 A KR 940014489A
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- C07C265/00—Derivatives of isocyanic acid
- C07C265/02—Derivatives of isocyanic acid having isocyanate groups bound to acyclic carbon atoms
- C07C265/04—Derivatives of isocyanic acid having isocyanate groups bound to acyclic carbon atoms of a saturated carbon skeleton
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C265/00—Derivatives of isocyanic acid
- C07C265/10—Derivatives of isocyanic acid having isocyanate groups bound to carbon atoms of rings other than six-membered aromatic rings
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- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C271/00—Derivatives of carbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
- C07C271/06—Esters of carbamic acids
- C07C271/08—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms
- C07C271/10—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atoms of the carbamate groups bound to hydrogen atoms or to acyclic carbon atoms
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- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C271/00—Derivatives of carbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
- C07C271/06—Esters of carbamic acids
- C07C271/08—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms
- C07C271/24—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atom of at least one of the carbamate groups bound to a carbon atom of a ring other than a six-membered aromatic ring
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
- C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
- C07D251/12—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
- C07D251/26—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with only hetero atoms directly attached to ring carbon atoms
- C07D251/30—Only oxygen atoms
- C07D251/34—Cyanuric or isocyanuric esters
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
- C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
- C08G18/792—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/03—Powdery paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/04—Thixotropic paints
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- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Polyurethanes Or Polyureas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Paints Or Removers (AREA)
Abstract
본 발명은 a) 평균 이소시아네이트 관능도 2.1이상, b) 3차 (시클로)지방족 탄소 원자에 결합된 유리 이소시아네이트기 함량 5 내지 22중량%(NCO로서 계산 ; 분자량42), c) 우레탄기 함량 2 내지 30중량%(-NH-CO-O로서 계산 ; 분자량 59), d) 이소시아네이트기 함량 0 내지 30중량%(C3N3O3로서 계산 ; 분자량 126), e) 카르복실산 에스테르기 함량 0 내지 25중량%(-CO-O로서 계산 ; 분자량 44) 및(또는), f) 카르보네이트기 함량 0 내지 34중량%(-O-CO-O로서 계산 ; 분자량 60)이고, 여기서 에스테르기 e) 및 카르보네이트기 f)의 총량은 적어도 2중량%이며 40℃ 이하에서는 고체이고 125℃ 이상에서는 액체인 폴리이소시아네이트 혼합물에 관한 것이다.
본 발명은 또한 상기 폴리이소시아네이트 혼합물의 제조방법 및 폴리우레탄 제조를 위한 용도, 특히 내열성 재료의 코팅을 위한 열경화성의 이성분 폴리우레탄 분말 도료 중의 가교 성분으로서의 용도에 관한 것이다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (6)
- a) 평균 이소시아네이트 관능도 2.1이상, b) 3차 (시클로)지방족 탄소 원자에 결합된 유리 이소시아네이트기 함량 5 내지 22중량%(NCO로서 계산 ; 분자량 42), c) 우레탄기 함량 2 내지 30중량%(-NH-CO-O로서 계산 ; 분자량 59), d) 이소시아네이트기 함량 0 내지 30중량%(C3N3O3로서 계산 ; 분자량 126), e) 카르복실산 에스테르기 함량 0 내지 25중량%(-CO-O로서 계산 ; 분자량 44) 및(또는), f)카르보네이트기 함량 0 내지 34중량%(-O-CO-O로서 계산 ; 분자량 60)를 가지고, 여기서 에스테르기 e)및 카르보네이트기 f)의 총량은 적어도 2중량%이며, 40℃ 이하에서는 고체이고 125℃이상에서는 액체인 폴리이소시아네이트 혼합물.
- i) 이론적으로 계산된 NCO 함량에 도달할 때까지 NCO/OH 당량비 1.2;1 내지 40;1로, A) 3차 (시클로)지방족 탄소 원자에 결합된 적어도 하나의 이소시아네이트기를 갖는 디이소시아네이트 1종 이상 및 B) 임의로 1차 및(또는) 2차 (시클로)지방족 탄소 원자에 독점적으로 결함된 이소시아네이트기를 갖는 디이소시아네이트를 1종 이상을 C) 에스테르 및(또는) 카르보네이트기를 함유하고 평균 분자량이 134 내지 1,200인 폴리히드록실 화합물 및 D) 임의로 에스테르 및 카르보네이트기를 함유하지 않는 분자량 60 내지 400의 폴리히드록실 화합물과 반응시키고, ii) 임의로 잔류 이소시아네이트기의 일부를 접촉 삼량체화 반응시킴으로써 반응 생성물을 개질시키고, iii) 임의로 박막 증류에 의해 과량의 미반응 디이소시아네이트를 분리하는 것으로 이루어진, a) 평균 이소시아네이트 관능도 2.1 이상, b) 3차 (시클로)지방족 탄소 원자에 결합된 유리 이소시아네이트기 함량 5 내지 22중량%(NCO로서 계산 ; 분자량 42), c) 우레탄기 함량 2 내지 30중량%(-NH-CO-O로서 계산 ; 분자량 59), d) 이소시아네이트기 함량 0 내지 30중량%(C3N3O3로서 계산 ; 분자량 126), e) 카르복실산 에스테르기 함량 0 내지 25중량%(-CO-O로서 계산 ; 분자량 44) 및 (또는), f) 카르보네이트기 함량 0 내지 34중량%(-O-CO-O로서 계산 ; 분자량 60)이고, 여기서 에스테르기 e) 및 카르보네이트기 f)의 총량은 적어도 2중량%이며, 40℃ 이하에서는 고체이고 125℃ 이상에서는 액체인 폴리이소시아네이트 혼합물의 제조방법.
- 제2항에 있어서, 성분 A)가 A1) NCO 함량이 24 내지 50중량%이고 1차 지방족 탄소 원자에 결합된 입체적으로 가리워지지 않은 이소시아네이트기와 3차 지방족 탄소 원자에 결합된 입체적으로 가리워진 이소시아네이트기를 갖는 지방족 디이소시아네이트, A2) NCO 함량이 20 내지 50중량%이고, 1차 지방족 탄소 원자에 결합된 입체적으로 가리워지지 않은 이소시아네이트기와 시클로지방족 고리의 일부인 3차 탄소 원자에 결합된 입체적으로 가리워진 이소시아네이트기를 갖는 지방족-시클로지방족 디이소시아네이트 및 A3)이소시아나토알킬 치환제를 갖고, NCO 함량이 20 내지 35중량%이며, 두 이소시아네이트기가 3차 지방족 탄소 원자에 결합된 방향족 화합물로 이루어진 군으로부터 선택된 것인 방법.
- 제2항에 있어서, A0 가 1-이소시아나토-1메틸-4(3)-이소시아나토메틸-시클로헥산으로 이루어진 방법.
- 제1항의 폴리이소시아네이트 혼합물로부터 제조된 폴리우레탄.
- 제1항의 폴리이소시아네이트 혼합물 및 이소시아네이트-방향성 성분을 함유한 분말 도료 조성물.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEP4240330.8 | 1992-12-01 | ||
DE4240330A DE4240330A1 (de) | 1992-12-01 | 1992-12-01 | Polyisocyanatgemische, ein Verfahren zu ihrer Herstellung und ihre Verwendung |
Publications (1)
Publication Number | Publication Date |
---|---|
KR940014489A true KR940014489A (ko) | 1994-07-18 |
Family
ID=6474076
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019930025754A KR940014489A (ko) | 1992-12-01 | 1993-11-30 | 폴리이소시아네이트 혼합물, 그의 제조 방법 및 폴리우레탄 제조를 위한 용도 |
Country Status (8)
Country | Link |
---|---|
US (1) | US5464921A (ko) |
EP (1) | EP0600310B1 (ko) |
JP (1) | JPH06228076A (ko) |
KR (1) | KR940014489A (ko) |
AT (1) | ATE137495T1 (ko) |
CA (1) | CA2110236A1 (ko) |
DE (2) | DE4240330A1 (ko) |
ES (1) | ES2087636T3 (ko) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6630537B1 (en) | 1997-07-22 | 2003-10-07 | Basf Coatings Ag | Coating agent and method for producing same |
US6441087B1 (en) * | 1999-10-19 | 2002-08-27 | Shell Oil Company | High gloss acrylic coatings with improved impact resistance |
DE10205608A1 (de) * | 2002-02-11 | 2003-08-21 | Degussa | Bei niedriger Temperatur härtbare feste uretdiongruppenhaltige Polyurethan-Pulverlackzusammensetzungen |
US6870000B2 (en) * | 2002-04-09 | 2005-03-22 | Laxmi C. Gupta | Water curable polyurethane compositions and uses thereof |
DE10320266A1 (de) * | 2003-05-03 | 2004-11-18 | Degussa Ag | Feste Uretdiongruppenhaltige Polyurethan-Pulverlackzusammensetzungen bei niedriger Temperatur härtbar |
US7148287B2 (en) * | 2003-05-15 | 2006-12-12 | Gupta Laxmi C | Water curable polyurethane compositions with improved viscosity characteristics |
US20060160978A1 (en) * | 2005-01-20 | 2006-07-20 | Gupta Laxmi C | Flame retardant systems, and related methods and uses |
US20070083003A1 (en) * | 2005-10-11 | 2007-04-12 | Gupta Laxmi C | Water curable polyurethane compositions and uses thereof |
US8932497B2 (en) | 2008-03-13 | 2015-01-13 | Laxmi C. Gupta | Fire retardant coatings and bodies, and methods of use |
US20090292032A1 (en) * | 2008-05-02 | 2009-11-26 | Gupta Laxmi C | Fire retardant foam and methods of use |
CN104583258B (zh) | 2012-06-26 | 2019-01-04 | 陶氏环球技术有限责任公司 | 双组分聚氨酯粘合剂 |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1255660A (en) * | 1967-12-19 | 1971-12-01 | Inter Polymer Res Corp | Method for the production of polyurethane foams |
US3857818A (en) * | 1972-09-18 | 1974-12-31 | Cook Paint & Varnish Co | Blocked polyurethane powder coating compositions |
US4159376A (en) * | 1977-07-27 | 1979-06-26 | Ici Americas Inc. | Isocyanurates from unsaturated monohydric alcohols and polyisocyanates |
DE3030588A1 (de) * | 1980-08-13 | 1982-03-18 | Chemische Werke Hüls AG, 4370 Marl | Verfahren zur herstellung von blockierungsmittelfreien polyurethan-pulverlacken mit hoher lagerstabilitaet, die oberhalb 120(grad) c haertbar sind, sowie die danach hergestellten polyurethan-pulverlacke |
DE3030572A1 (de) * | 1980-08-13 | 1982-03-18 | Chemische Werke Hüls AG, 4370 Marl | Verfahren zur herstellung von uretdiongruppenhaltigen polyadditionsprodukten sowie die danach hergestellten produkte |
DE3030539A1 (de) * | 1980-08-13 | 1982-04-01 | Chemische Werke Hüls AG, 4370 Marl | Verfahren zur herstellung von abspaltfreien polyurethan-pulverlacken sowie die danach hergestellten lacke |
US4375539A (en) * | 1981-07-22 | 1983-03-01 | Eastman Kodak Company | Solid blocked crosslinking agents based on 1,4-cyclohexane bis(methylisocyanate) |
DE3507719A1 (de) * | 1985-03-05 | 1986-09-11 | Bayer Ag, 5090 Leverkusen | Isocyanuratgruppen aufweisende polyisocyanate, ein verfahren zu ihrer herstellung und ihre verwendung als isocyanatkomponente in polyurethanlacken |
DE3541859A1 (de) * | 1985-11-27 | 1987-06-04 | Bayer Ag | Verfahren zur herstellung von isocyanuratgruppen aufweisenden polyisocyanaten und ihre verwendung als isocyanatkomponente in polyurethanlacken |
DE3624775A1 (de) * | 1986-07-22 | 1988-01-28 | Bayer Ag | Pulverlack und seine verwendung zur beschichtung von hitzeresistenten substraten |
GB8705801D0 (en) * | 1987-03-11 | 1987-04-15 | Ici Plc | Injection moulding compositions |
FR2663931B1 (fr) * | 1990-07-02 | 1993-05-28 | Norsolor Sa | Precurseurs de polymeres a motifs isocyanurates comportant des fonctions hydroxyles, urethanes, isocyanates ou acryliques et leurs combinaisons, et leurs procedes de fabrication. |
CA2041532C (en) * | 1991-04-30 | 2002-01-01 | Hamdy Khalil | Urethane sealant having improved sag properties |
-
1992
- 1992-12-01 DE DE4240330A patent/DE4240330A1/de not_active Withdrawn
-
1993
- 1993-11-18 DE DE59302442T patent/DE59302442D1/de not_active Expired - Fee Related
- 1993-11-18 AT AT93118555T patent/ATE137495T1/de not_active IP Right Cessation
- 1993-11-18 ES ES93118555T patent/ES2087636T3/es not_active Expired - Lifetime
- 1993-11-18 EP EP93118555A patent/EP0600310B1/de not_active Expired - Lifetime
- 1993-11-22 US US08/156,202 patent/US5464921A/en not_active Expired - Lifetime
- 1993-11-29 CA CA002110236A patent/CA2110236A1/en not_active Abandoned
- 1993-11-30 KR KR1019930025754A patent/KR940014489A/ko not_active Application Discontinuation
- 1993-11-30 JP JP5323345A patent/JPH06228076A/ja active Pending
Also Published As
Publication number | Publication date |
---|---|
JPH06228076A (ja) | 1994-08-16 |
DE59302442D1 (de) | 1996-06-05 |
EP0600310B1 (de) | 1996-05-01 |
DE4240330A1 (de) | 1994-06-09 |
ATE137495T1 (de) | 1996-05-15 |
US5464921A (en) | 1995-11-07 |
EP0600310A1 (de) | 1994-06-08 |
CA2110236A1 (en) | 1994-06-02 |
ES2087636T3 (es) | 1996-07-16 |
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