KR940009798B1 - Method for squeeze casting powdery mold releasing agent - Google Patents

Method for squeeze casting powdery mold releasing agent Download PDF

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Publication number
KR940009798B1
KR940009798B1 KR1019910008263A KR910008263A KR940009798B1 KR 940009798 B1 KR940009798 B1 KR 940009798B1 KR 1019910008263 A KR1019910008263 A KR 1019910008263A KR 910008263 A KR910008263 A KR 910008263A KR 940009798 B1 KR940009798 B1 KR 940009798B1
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KR
South Korea
Prior art keywords
squeeze casting
compound
mold
releasing agent
mold release
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KR1019910008263A
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Korean (ko)
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KR920017741A (en
Inventor
다까시 하나노
Original Assignee
하나노 쇼오지 가부시기가이샤
하나노 히로시
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Publication of KR920017741A publication Critical patent/KR920017741A/en
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    • C10M111/02—Lubrication compositions characterised by the base-material being a mixture of two or more compounds covered by more than one of the main groups C10M101/00 - C10M109/00, each of these compounds being essential at least one of them being a non-macromolecular organic compound
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22C—FOUNDRY MOULDING
    • B22C1/00—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22C—FOUNDRY MOULDING
    • B22C3/00—Selection of compositions for coating the surfaces of moulds, cores, or patterns
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    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04—Siloxanes with specific structure
    • C10M2229/05—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon
    • C10M2229/054—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon containing phosphorus
    • C10M2229/0545—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon containing phosphorus used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/02—Groups 1 or 11
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/04—Groups 2 or 12
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working

Abstract

내용 없음.No content.

Description

스퀴이즈 캐스팅용 분말상 주형 탈형제Powder mold release agent for squeeze casting

본 발명은 단조(鍛造)작업을 비롯한 스퀴이즈 캐스팅(squeeze casting) 작업시에 주형(molding die)의 내면에다 분무하여 사용하는 주형 탈형제(mold releasing agent)에 관한 것이다.BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to mold releasing agents for use by spraying onto the inner surface of a molding die during squeeze casting operations, including forging operations.

단조를 비롯한 스퀴이즈 캐스팅법은 고정밀도의 주조부품을 이 방법에 의하여 연속적으로 다량 제조할 수 있기 때문에 자동차 및 전기 설비용 각종 부품 제조시에 널리 활용되고 있다.The squeeze casting method including forging has been widely used in manufacturing various parts for automobiles and electrical equipment because a large amount of high precision cast parts can be continuously produced by this method.

또한 이러한 스퀴이즈 캐스팅법에 있어서 주형 탈형제를 사용하여 주형이 용융금속과 직접 접촉하지 못하게 함으로써 소부현상(seizure)을 방지함과 아울러 제품을 주형으로 부터 보다 쉽게 탈형할 수 있도록 한다.In addition, in the squeeze casting method, the mold release agent is used to prevent the mold from directly contacting the molten metal, thereby preventing seizure and making it easier to demould the product from the mold.

스퀴이즈 캐스팅용 주형 탈형제는 수용성(水溶性) 주형 탈형제와 수불용성(水不溶性) 주형 탈형제의 두 가지로 주로 구분되고 있는 것이 일반적이다. 이들 탈형제 중에서 수불용성 주형 탈형제는 매연과 인화성으로 인한 위험이 크기 때문에 안전성의 관점에서 여러 가지 문제를 내포하고 있으므로 수용성 주형 탈형제가 빈번히 사용되고 있다.Mold releasing agents for squeeze casting are generally classified into two types: water soluble mold releasing agents and water insoluble mold releasing agents. Among these mold release agents, water-insoluble mold release agents have a high risk due to soot and flammability, and thus have various problems in terms of safety. Therefore, water-soluble mold release agents are frequently used.

수용성 주형 탈형제는 일반적으로 물, 광유 등과 같은 주형 탈형 기재에 계면활성제 또는 극압(extreme pressure) 부여제 등의 용도로 실리콘 오일, 합성 또는 천연 왁스, 유지, 지방산 에스테르 등을 첨가해서 된 것이다.Water-soluble mold release agents are generally obtained by adding silicone oil, synthetic or natural waxes, fats and oils, fatty acid esters and the like to mold release substrates such as water and mineral oils for use as surfactants or extreme pressure imparting agents.

부수적으로 근년에 와서 스퀴이즈 캐스팅 기술의 발전과 더불어 작업성이 보다 양호하고 고품질의 제품을 제조할 수 있는 주형 탈형제에 대한 수요가 점차 커지고 있다. 그러나 수용성 주형 탈형제를 사용하여 이러한 요구를 충족시킨다는 것은 불가능해지고 있다. 즉 수용성 주형 탈형제는 그 수용성으로 인해 주형의 온도 조절이 어렵고 잔존 수분으로 인해 제품내부에 결함이 발생할 가능성이 크다는 등 여러 가지 문제점을 내포하고 있다. 더욱이 수질오염을 방지하기 위해 폐수 처리를 해야 하므로 공장 시설 투자에 필요한 각종 경비의 증가 요인이 되고 있다는 문제점도 가지고 있다. 따라서 새로운 유형의 주형 탈형제에 대한 요청이 강하게 대두되고 있다.Incidentally, in recent years, with the development of squeeze casting technology, there is a growing demand for mold release agents capable of producing better workability and high quality products. However, it is becoming impossible to meet these needs with water soluble mold release agents. That is, the water-soluble mold release agent has various problems, such as difficult to control the temperature of the mold due to its water solubility, and the possibility of defects in the product due to the residual moisture. In addition, wastewater treatment is required to prevent water pollution, which is a factor in increasing various expenses required for plant facility investment. Thus, there is a strong demand for new types of mold release agents.

본 발명은 위에 나온 상황을 고려하여 구체적인 연구와 체계적인 실험에 입각하여 완성된 것이다.The present invention has been completed based on specific studies and systematic experiments in consideration of the above situation.

본 발명의 목적은 작업성이 보다 양호하고 주변 환경을 악화시킴이 없이 고품질의 주조제품을 제조할 수 있는 스퀴이즈용 주형 탈형제를 제공함에 있다. 즉 더 구체적으로는 제품의 소부현상과 내부결함 발생을 확실하게 방지하여 제품을 주형으로 부터 탈형할 수 있는 능력을 향상시키고 사용 후에 주형 내부와 제품 표면으로 부터 쉽사리 제거되며, 주조 도중 가스 발생과 주조 후의 수질오염을 전혀 일으키지 않는 주형 탈형제를 제공함에 있다.It is an object of the present invention to provide a mold release agent for squeeze which can produce high quality cast products without better workability and without deteriorating the surrounding environment. More specifically, it prevents the quenching of the product and the occurrence of internal defects, thereby improving the ability to demold the product from the mold, and is easily removed from the inside of the mold and the surface of the product after use. It is to provide a mold release agent that does not cause any subsequent water pollution.

본 발명은 단조작업을 비롯한 스퀴이즈 캐스팅 작업시에 주형의 내면에다 분무하여 사용하는 스퀴이즈 캐스팅용 주형 탈형제에 있어서 고체형태로 윤활제로 사용되는 분말상 또는 과립상 무기화합물과 주형 탈형기재(基材)에 접착성을 부여하는 분말상 또는 과립상 유기화합물로 구성되며 유기화합물로 코우팅된 분말상 또는 과립상 주형 탈형 기재로 된 혼합물을 함유하는 스퀴이즈 캐스팅용 분말상 주형 탈형제에 관한 것이다.The present invention relates to a powder or granular inorganic compound and a mold demolding substrate used as a lubricant in a solid form in a mold releasing agent for squeeze casting used by spraying the inner surface of a mold during a squeeze casting operation including a forging operation. The present invention relates to a powder mold release agent for squeeze casting comprising a mixture of powdered or granular organic compounds imparting adhesiveness to a) and containing a mixture of powdered or granular mold release substrates coated with organic compounds.

본 발명의 가장 현저한 특징은 주형 탈형 기재가 분말상 또는 과립상이라는 것이다.The most striking feature of the present invention is that the mold demolding substrate is in powder or granular form.

무기화합물에 대하여 유기화합물의 함량을 0.1∼45wt.% 범위에서 선택하는 것이 효과적인데, 그 이유는 무기화합물의 금속 주형 내부에 대한 접착효과는 그 함량이 0.1wt.% 이하인 경우에는 충분히 나타나지 않고 또한 그 함량이 45wt.% 이상인 경우에는 축적이 되어 금속 주형 내부로 부터 주형 탈형제를 제거할 때 곤란을 겪게 되는데, 즉 주형 탈형 효율이 감소하거나 제품의 칫수 정확도가 나빠지기 때문인 것이다.It is effective to select an organic compound content in the range of 0.1 to 45 wt.% For the inorganic compound, because the adhesion effect of the inorganic compound to the inside of the metal mold does not appear sufficiently when the content is 0.1 wt.% Or less. If the content is more than 45wt.%, It accumulates and it is difficult to remove the mold release agent from the inside of the metal mold, that is, because the mold release efficiency decreases or the dimensional accuracy of the product is deteriorated.

본 발명에 사용되는 주형 탈형 기재에는 아무런 제한이 없으나 단, 이들은 윤활제용으로 사용되는 고체 무기화합물로 된 것이면 좋은데 일반적으로 질화 붕소, 운모, 금속 산화물, 질화 규소, 황 화합물, 플루오르화물, 활석, 붕소 화합물 및 인 화합물을 사용하는 것이 바람직하다.There are no limitations on the mold demolding substrate used in the present invention, however, these may be made of solid inorganic compounds used for lubricants. Generally, boron nitride, mica, metal oxide, silicon nitride, sulfur compounds, fluorides, talc, and boron compounds And phosphorus compounds.

그러나 종래부터 주형 탈형제로 사용되어온 이황화 몰리브덴, 흑연 등과 같은 기타 공지의 고체 윤활제도 사용할 수 있다. 이들 무기화합물은 분말상 또는 과립상의 것인데 이들 중 한 가지만을 사용하거나 두 가지 이상을 조합하여 사용한다.However, other well-known solid lubricants such as molybdenum disulfide, graphite, and the like, which have conventionally been used as mold release agents, can also be used. These inorganic compounds are in the form of powder or granules, using only one of them or a combination of two or more thereof.

더욱이 본 발명에 사용되는 유기화합물에는 아무런 특별한 제한이 없으나 단, 위에 나온 무기화합물에 대하여 접착성과 결합성을 부여하는 특성을 가진 것이 좋으며, 일반적으로 금속비누 또는 고분자 화합물을 사용하는 것이 바람직하다.Moreover, there is no particular limitation on the organic compound used in the present invention, but it is preferable to have the property of giving adhesion and bonding property to the inorganic compound described above, and it is generally preferable to use a metal soap or a high molecular compound.

금속비누용으로는 나트륨, 칼슘, 바륨, 리튬, 칼륨, 마스네슘 또는 아연과 결합한 카르복실산 구조의 것을 사용하고, 고분자 화합물 용으로는 폴리에틸렌, 폴리프로필렌, 에폭시 수지, 규소 수지, 페놀 수지, 아크릴레이트 수지, 알키드 수지 또는 폴리스티렌을 사용하는 것이 바람직하다.For metal soaps, carboxylic acid structures combined with sodium, calcium, barium, lithium, potassium, magnesium or zinc are used.For polymer compounds, polyethylene, polypropylene, epoxy resins, silicon resins, phenolic resins and acrylics are used. Preference is given to using rate resins, alkyd resins or polystyrenes.

이들 유기화합물을 분말상 또는 과립상 주형 탈형 기재와 혼합하거나 가열용융된 상태로 하여 혼합한다.These organic compounds are mixed with a powdery or granular mold demolding substrate or mixed in a heat-melted state.

따라서 본 발명의 주형 탈형제에 있어서 주형 탈형 기재와 유기화합물을 모두 분말 또는 과립형태로 하던지 분말상 또는 과립상 주형 탈형 기재를 유기화합물로 코우팅한다. 부수적으로 위에 나온 유기화합물 중 한 가지만을 사용하거나 두 가지 이상을 조합해서 사용한다. 금속비누와 고분자 화합물을 조합해서 사용해도 좋다.Therefore, in the mold demolding agent of the present invention, both the mold demolding substrate and the organic compound are in powder or granular form, or the powdery or granular mold demolding substrate is coated with the organic compound. Incidentally, use only one of the above organic compounds or a combination of two or more of them. You may use combining metal soap and a high molecular compound.

본 발명에 의한 스퀴이즈 캐스팅용 분말상 주형 탈형제에 있어서 주형 탈형 기재는 최소한 분말상 또는 과립상이기 때문에 주형 탈형제가 부착하는 금속 주형 내면의 일부에 있는 주형 탈형 기재의 분말 또는 과립의 입자직경만큼 적어도 금속 주형 내면과 제품이 확실히 간격을 두고 떨어져 있게 된다.In the powder mold release agent for squeeze casting according to the present invention, since the mold release mold substrate is at least powdery or granular, at least as much as the particle diameter of the powder or granule of the mold release mold substrate on the inner part of the metal mold to which the mold release agent adheres. The inner surface of the mold and the product are clearly spaced apart.

따라서 주형 탈형제는 금속 주형 내면 전체에 균일하게 부착하기 때문에 제품과 금속 주형 내면과 직접 접촉하여 생기는 소부현상을 확실히 피할 수 있다. 더욱이 본 발명에 의한 주형 탈형제는 유기화합물과 무기화합물로 되어 있고 수분을 함유하지 않기 때문에 제품내면에는 잔존 수분으로 인한 결함이 전혀 생기지 않는다. 따라서 제품품질을 형성시킬 수 있다.Therefore, since the mold release agent uniformly adheres to the entire inner surface of the metal mold, it is possible to reliably avoid the burning phenomenon caused by the direct contact with the product and the inner surface of the metal mold. Furthermore, since the mold release agent of the present invention is composed of an organic compound and an inorganic compound and does not contain water, defects due to residual water do not occur on the inner surface of the product. Therefore, product quality can be formed.

또한 본 발명에 의한 주형 탈형제에 있어서 주형 탈형 기재는 최소한 분말 또는 과립형태이고 수분을 함유하지 않기 때문에 금속 주형 내면과 제품 사이에 작용하는 장력은 약하다. 따라서 금속 주형으로 부터 제품을 탈형하기가 용이해지고, 더욱이 주형 탈형제를 금속 주형 내면과 제품 표면으로 부터 쉽사리 제거할 수 있다.Further, in the mold release agent according to the present invention, since the mold release base material is at least in powder or granule form and does not contain water, the tension between the inner surface of the metal mold and the product is weak. Therefore, it is easy to demold the product from the metal mold, and moreover, the mold demolding agent can be easily removed from the metal mold inner surface and the product surface.

또한 본 발명의 주형 탈형제에 있어서 주형 탈형 기재는 최소한 분말 또는 과립형태이므로 기재가 스퀴이즈 캐스팅 도중 열을 받는다 하더라도 반응하기가 어렵고 가스를 거의 발생하지 않는다.In addition, in the mold release agent of the present invention, since the mold release substrate is at least in powder or granule form, even if the substrate receives heat during squeeze casting, it is difficult to react and generates little gas.

그리고 본 발명의 탈형제는 주조후에 수용성 주형 탈형제의 경우에서 나타나는 것과 같은 수질오염을 일으키지 않는다.In addition, the demolding agent of the present invention does not cause water pollution such as that seen in the case of water-soluble mold demolding agent after casting.

따라서 환경오염을 피할 수 있고 폐수 처리 경비가 필요없기 때문에 유지비를 절감할 수 있다.Therefore, environmental pollution can be avoided and maintenance costs can be reduced because no waste water treatment expenses are required.

본 발명에 있어서 무기화합물과 유기화합물로 구성된 주형 탈형 기재의 혼합물을 함유하는 스퀴이즈 캐스팅 주형 탈형제를 최소한 기재가 분말상 또는 과립상인 것을 사용하여 탈형제로 제조한 것이다.In the present invention, a squeeze casting mold releasing agent containing a mixture of a mold releasing base material composed of an inorganic compound and an organic compound is prepared as a releasing agent using at least a base material in powder or granular form.

따라서 스퀴이즈 캐스팅법으로 제조된 알루미늄 합금과 아연 합금 등의 주물에 있어서 소부현상과 내부결함을 확실히 제거할 수 있고, 주물의 품질을 향상시킬 수 있으며, 스퀴이즈 캐스팅법에 의한 주조작업시 그 작업성이 양호하고, 본 발명의 탈형제를 사용하기 전후에 있어서의 환경오염을 완전히 피할 수 있다.Therefore, in the casting of aluminum alloy and zinc alloy manufactured by squeeze casting method, it is possible to surely eliminate the quenching phenomenon and internal defects, improve the quality of the casting, and the work during casting work by squeeze casting method. The properties are good, and environmental pollution before and after using the mold release agent of the present invention can be completely avoided.

특히 무기화합물에 대한 유기화합물의 함량범위를 0.1∼45wt.%로 함으로써 제조된 주물의 품질을 향상시킬 수 있다.In particular, the content range of the organic compound to the inorganic compound in the range of 0.1 to 45 wt.% Can improve the quality of the produced casting.

더욱이 무기화합물로서는 질화 붕소, 운모, 금속 산화물, 질화 규소, 황 화합물, 플루오르화물, 활석, 붕소 화합물 또는 인 화합물을 사용하고, 유기화합물로서는 나트륨, 칼슘, 바륨, 리튬, 칼륨, 마그네슘 또는 아연이 결합된 카르복실산 화합물로 된 금속비누 또는 폴리에틸렌, 폴리프로필렌, 에폭시 수지, 규소 수지, 페놀 수지, 아크릴레이트 수지, 알키드 수지 또는 폴리스티렌 등과 같은 고분자 화합물을 사용하면 위에 나온 효과를 훨씬 더 많이 향상시킬 수 있다.Furthermore, as inorganic compounds, boron nitride, mica, metal oxides, silicon nitrides, sulfur compounds, fluorides, talc, boron compounds, or phosphorus compounds are used, and as organic compounds, sodium, calcium, barium, lithium, potassium, magnesium or zinc are combined. The use of metal soaps of carboxylic acid compounds or high molecular compounds such as polyethylene, polypropylene, epoxy resins, silicon resins, phenolic resins, acrylate resins, alkyd resins or polystyrene can improve the above effects even more.

각기 해당하는 다이 캐스팅 작업에 가장 적절히 사용할 수 있는 주형 탈형제는 위에 나온 무기화합물과 유기화합물을 각각 두 가지 이상을 조합하여 사용해서 제조할 수 있다.The mold release agent most suitably used for the respective die casting operation can be prepared by combining two or more of the above inorganic and organic compounds.

본 발명을 실시예로 설명하는데 본 발명은 이들 실시예에 한정되는 것은 아니다.Although an Example demonstrates this invention, this invention is not limited to these Examples.

[실시예]EXAMPLE

다음에 나오는 주형 탈형제 (A)∼(F)를 제조한 후 스퀴이즈 캐스팅법에 따라 이들 주형 탈형제를 사용하여 주조시험을 하여 표에 나와 있는 각 시험항목을 비교검토하였다.The following mold release agents (A) to (F) were prepared, and casting tests were carried out using these mold release agents according to the squeeze casting method, and each test item shown in the table was compared.

두 가지 혼합물, 즉 유기화합물과 무기화합물을 분말 또는 과립형태로 하여 혼합한 혼합물과 유기화합물과 무기화합물을 가열용융된 상태로 하여 혼합한 혼합물을 제조하여 본 발명의 실시예(A)∼(C)로 하였다.Two mixtures, i.e., a mixture of organic and inorganic compounds in the form of powder or granules, and a mixture of organic and inorganic compounds in a heat-melted state were prepared to prepare a mixture of Examples (A) to (C). ).

이들 두 가지 혼합물을 검토하여 얻은 결과는 두 가지 혼합물에 있어서 동일하였다. 부수적으로 주형 탈형제 (A)∼(F)에 사용된 화합물은 시판품이다.The results obtained by examining these two mixtures were the same for both mixtures. Incidentally, the compounds used in the mold release agents (A) to (F) are commercially available products.

(A) 실시예 1 : 질화 붕소(평균 입자크기 : 1∼5마이크론) 95부와 스테아르산 칼슘 5부로 된 혼합물(A) Example 1 mixture of 95 parts of boron nitride (average particle size: 1 to 5 microns) and 5 parts of calcium stearate

(B) 실시예 2 : 질화 붕소 20부, 운모 75부 및 폴리에틸렌 5부로 된 혼합물(B) Example 2 mixture of 20 parts boron nitride, 75 parts mica and 5 parts polyethylene

(C) 실시예 3 : 질화 붕소 50부, 질화 규소 45부, 스테아르산 바륨 3부 및 폴리프로필렌 2부로 된 혼합물(C) Example 3 mixture of 50 parts of boron nitride, 45 parts of silicon nitride, 3 parts of barium stearate and 2 parts of polypropylene

(D) 질화 붕소 단독(비교 실시예 1)(D) boron nitride alone (comparative example 1)

(E) 주성분으로서 왁스와 실리콘 오일을 1 : 80의 비율로 함유한 수용성 주형 탈형제(비교 실시예 2)(E) Water-soluble mold release agent containing wax and silicone oil in a ratio of 1:80 as a main component (Comparative Example 2)

(F)왁스, 실리콘 오일 및 흑연으로 된 수용성 주형 탈형제 시판품(비교실시예3)(F) Commercially available water-soluble mold release agent made of wax, silicone oil and graphite (Comparative Example 3)

[표 1]TABLE 1

X : 완전히 없음, - : 측정 불가X: none completely,-: not measurable

* : 작음, ○ : 중간, ◎ : 큼*: Small, ○: Medium, ◎: Large

Claims (6)

단조 작업을 비롯한 스퀴이즈 캐스팅 작업시에 주형의 내면에다 분무하여 사용하는 스퀴이즈 캐스팅용 주형 탈형제에 있어서 고체형태로 윤활제로 사용되는 분말상 또는 과립상 무기화합물과 주형 탈형 기재(基材)에 접착성을 부여하는 분말상 또는 과립상 유기화합물로 구성되며 유기화합물로 코우팅된 분말상 또는 과립상 주형 탈형 기재로 된 혼합물을 함유하는 스퀴이즈 캐스팅용 분말상 주형 탈형제.In the mold release agent for squeeze casting, which is sprayed onto the inner surface of the mold during the squeeze casting operation including forging, it adheres to the powder or granular inorganic compound used as a lubricant in solid form and the mold release substrate. A powdery mold releasing agent for squeeze casting, comprising a mixture of powdered or granular organic compounds coated with organic compounds and impregnated with an organic compound. 제 1 항에 있어서, 무기화합물에 대하여 유기화합물을 0.1∼45wt.%의 함량으로 함유하는 스퀴이즈 캐스팅용 분말상 주형 탈형제.The powdery mold releasing agent for squeeze casting according to claim 1, which contains an organic compound in an amount of 0.1 to 45 wt.% Relative to the inorganic compound. 제 1 항에 있어서, 무기화합물로는 질화 붕소, 질화 규소, 운모, 금속 산화물, 황 화합물, 플루오라이드, 활석, 붕소 화합물 및 인 화합물 중 한 가지 이상을 함유하는 스퀴이즈 캐스팅용 분말상 주형 탈형제.The powdery mold releasing agent for squeeze casting according to claim 1, wherein the inorganic compound contains at least one of boron nitride, silicon nitride, mica, metal oxide, sulfur compound, fluoride, talc, boron compound, and phosphorus compound. 제 1 항에 있어서, 유기화합물로는 금속비누 및/또는 고분자 화합물 중 한 가지 이상을 함유하는 스퀴이즈 캐스팅용 분말상 주형 탈형제.The powdery mold release agent for squeeze casting according to claim 1, wherein the organic compound contains at least one of a metal soap and / or a high molecular compound. 제 4 항에 있어서, 금속비누가 나트륨, 칼슘, 바륨, 리튬, 칼륨, 마그네슘 또는 아연과 결합한 카르복실산 그룹을 함유하는 것인 스퀴이즈 캐스팅용 분말상 주형 탈형제.5. The powdery mold releasing agent for squeeze casting according to claim 4, wherein the metal soap contains a carboxylic acid group bonded with sodium, calcium, barium, lithium, potassium, magnesium or zinc. 제 4 항에 있어서, 고분자 화합물이 폴리에틸렌, 폴리프로필렌, 에폭시 수지, 규소 수지, 페놀 수지, 아크릴레이트 수지, 알키드 수지 또는 폴리스티렌인 스퀴이즈 캐스팅용 분말상 주형 탈형제.The powdery mold releasing agent for squeeze casting according to claim 4, wherein the polymer compound is polyethylene, polypropylene, epoxy resin, silicon resin, phenol resin, acrylate resin, alkyd resin or polystyrene.
KR1019910008263A 1991-03-06 1991-05-22 Method for squeeze casting powdery mold releasing agent KR940009798B1 (en)

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JP3067975A JPH0759345B2 (en) 1991-03-06 1991-03-06 Powder mold release agent for high pressure casting
JP1991-67975 1991-03-06

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