KR940008741A - 선형 폴리아민을 제조하기 위한 촉매 및 방법 - Google Patents

선형 폴리아민을 제조하기 위한 촉매 및 방법 Download PDF

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KR940008741A
KR940008741A KR1019930020705A KR930020705A KR940008741A KR 940008741 A KR940008741 A KR 940008741A KR 1019930020705 A KR1019930020705 A KR 1019930020705A KR 930020705 A KR930020705 A KR 930020705A KR 940008741 A KR940008741 A KR 940008741A
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catalyst composition
oxide
group
groups
mixture
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KR1019930020705A
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KR100196257B1 (ko
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로이 듀막스 2세 아투어
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카렌 엘. 존슨
유니온 카바이드 케미칼즈 앤드 플라스틱스 테크날러지 코포레이션
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
    • B01J27/18—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr with metals other than Al or Zr
    • B01J27/1802—Salts or mixtures of anhydrides with compounds of other metals than V, Nb, Ta, Cr, Mo, W, Mn, Tc, Re, e.g. phosphates, thiophosphates
    • B01J27/1806—Salts or mixtures of anhydrides with compounds of other metals than V, Nb, Ta, Cr, Mo, W, Mn, Tc, Re, e.g. phosphates, thiophosphates with alkaline or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
    • B01J27/18—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr with metals other than Al or Zr
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/04—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups
    • C07C209/14—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups
    • C07C209/16—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups with formation of amino groups bound to acyclic carbon atoms or to carbon atoms of rings other than six-membered aromatic rings

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)

Abstract

본 발명은 (a)주기율표에서 3,4,5,6,8,12,13,14 및 15족으로 이루어진 그룹중에서 선택된 금속의, 표면적이 넓은, 산화물 또는 산화물 전구체, 또는 이들의 혼합물, (b)인-함유 성분 및 (c)주기율표에서 1,2및 3족으로 이루어진 그룹중에서 선택된 금속의 산화물 또는 산화물 전구체, 또는 이들의 혼합물의 반응 생성물을 포함하는, 아크릴성 폴리아민대 기타 반응생성물의 비율을 개선시키는, 알콜과 아민을 축합반응시키기 위한 촉매 조성물에 관한 것이다.
또한, 본 발명은 주로 선형이 폴리아민을 제조하기 위한 촉매의 제조방법 및 이의 사용방법에 관한 것이다.

Description

선형 폴리아민을 제조하기 위한 촉매 및 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 본 발명의 바람직한 촉매 조성물을 이의 활성성분들의 몰%로 도시한 3성분 도표이다.

Claims (10)

  1. (a)주기율표에서 3,4,5,6,8,12,13,14 및 15족으로 이루어진 그룹중에서 선택된 금속의, 표면적이 넓은, 산화물 또는 산화물 전구체, 또는 이들의 혼합물, (b)인-함유 성분 및 (c)주기율표에서 1,2및 3족으로이루어진 그룹중에서 선택된 금속의 산화물 또는 산화물 전구체, 또는 이들의 혼합물의 반응 생성물을 포함하는, 아크릴성폴리아민대 기타 반응생성물의 비율을 개선시키는, 알콜과 아민을 축합반응시키기 위한 촉매 조성물.
  2. 제1항에 있어서, P2O5로서 계산된 인-함유 화합물 약 10내지 약 50몰%, 산화물(들) 약 5내지 약 40몰%및 잔여량의 4,5,6,8,12,13,14 또는 15족 금속(들)의 산화물을 포함하는 촉매 조성물.
  3. 제2항에 있어서, P2O5로서 계산된 인-함유 화합물 약 15내지 약 40몰%, 산화물(들)로서 계산된 1족 금속(들)약 20내지 약 30몰% 및 잔여량의 TiO2, ZrO2또는 이들의 혼합물을 포함하는 촉매 조성물.
  4. 제2항에 있어서, 1족 금속이 Na인 촉매 조성물.
  5. 제1항에 있어서, 당해 촉매 조성물이 제1도의3원 도표에서 A-B-C-A의 지점을 잇는 지정된 조성물 영역내에 포함되는 촉매 조성물.
  6. 제5항에 있어서, 당해 촉매 조성물이 제1도의 3원 도표에서 D-E-F-K-G-H-D의 지점을 잇는 지정된 조성물 영역내의 포함되는 촉매 조성물.
  7. 제6항에 있어서, 당해 촉매 조성물이 제1도의 3원 도표에서 I-J-K-L-M-N-I의 지점을 잇는 지정된 조성물 영역내에 포함되는 촉매 조성물.
  8. 제1항에 있어서, 약 350℃이상의 온도에서 하나 이상의 촉매적으로 활성인 포스페이트 종을 생성시키기에 충분한 시간 동안 처리한 촉매 조성물.
  9. 제5항에 있어서, 약 350℃이상의 온도에서 하나 이상의 촉매적으로 활성이 포스페이트 종을 생성시키기에 충분한 시간 동안 촉매 조성물.
  10. (a)주기율표에서 3,4,5,6,8,12,13,14 및 15족으로 이루어진 그룹중에서 선택된 금속의, 표면적이 넓은, 산화물 또는 산화물 전구체, 또는 이들의 혼합물, 및 (b)주기율표에서 1,2 및 3족으로 이루어진 그룹중에서 선택된 금속의 산화물 또는 산화물 전구체, 또는 이들의 혼합물과 인-함유 성분의 반응 생성물의 반응 생성물을 포함하는 제1항의 촉매.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019930020705A 1992-10-08 1993-10-07 선형 폴리아민 제조용 촉매 조성물 및 이의 제조방법 KR100196257B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US07/957,901 1992-10-08
US07/957,901 US5362700A (en) 1992-10-08 1992-10-08 Catalysts and process of making same for the production of linear polyamines
US7/957,901 1992-10-08

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KR940008741A true KR940008741A (ko) 1994-05-16
KR100196257B1 KR100196257B1 (ko) 1999-06-15

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US (1) US5362700A (ko)
EP (1) EP0592052B1 (ko)
JP (1) JP3218378B2 (ko)
KR (1) KR100196257B1 (ko)
CA (1) CA2107968C (ko)
DE (1) DE69329266T2 (ko)
MX (1) MX9306256A (ko)

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EP2340240B1 (en) * 2008-10-06 2014-07-23 Union Carbide Chemicals & Plastics Technology LLC Transalkoxylation of nucleophilic compounds
EP2797902B1 (en) 2011-12-29 2017-04-26 Dow Global Technologies LLC Compositions containing cyclic amine compounds, and polyurethane foams made therefrom
BR112014015972B1 (pt) * 2011-12-29 2020-12-29 Dow Global Technologies Llc composição, poliéter poliol de amina, espuma de poliuretano, método para preparar um poliéter poliol de amina e método para preparar uma espuma de poliuretano
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Also Published As

Publication number Publication date
KR100196257B1 (ko) 1999-06-15
DE69329266D1 (de) 2000-09-28
CA2107968C (en) 1998-06-30
DE69329266T2 (de) 2001-02-22
MX9306256A (es) 1994-06-30
EP0592052B1 (en) 2000-08-23
US5362700A (en) 1994-11-08
JPH06279585A (ja) 1994-10-04
EP0592052A1 (en) 1994-04-13
CA2107968A1 (en) 1994-04-09
JP3218378B2 (ja) 2001-10-15

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