KR930013079A - Cleaning composition and bleaching method of stain - Google Patents

Cleaning composition and bleaching method of stain Download PDF

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Publication number
KR930013079A
KR930013079A KR1019920024784A KR920024784A KR930013079A KR 930013079 A KR930013079 A KR 930013079A KR 1019920024784 A KR1019920024784 A KR 1019920024784A KR 920024784 A KR920024784 A KR 920024784A KR 930013079 A KR930013079 A KR 930013079A
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KR
South Korea
Prior art keywords
integer
manganese
ligand
aryl
substituted alkyl
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KR1019920024784A
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Korean (ko)
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KR960002630B1 (en
Inventor
헤이그 로날드
에릭 이버그 잔
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원본미기재
유니레버 엔브이
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Publication of KR930013079A publication Critical patent/KR930013079A/en
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Publication of KR960002630B1 publication Critical patent/KR960002630B1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3902—Organic or inorganic per-compounds combined with specific additives
    • C11D3/3905—Bleach activators or bleach catalysts
    • C11D3/3932—Inorganic compounds or complexes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/28—Heterocyclic compounds containing nitrogen in the ring

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Catalysts (AREA)

Abstract

본 발명은 표면활성물질 및 거대환상 유리리간드를 함유하는 세척조성물에 관한 것이다.The present invention relates to a cleaning composition containing the surface active material and the macrocyclic free ligand.

본 조성물은 임의로 철 및/또는 망간이온류를 포함할수 있으며, 퍼옥시화합물을 포함하는 경우에는 유효한 표백조성물이다.The composition may optionally contain iron and / or manganese ions and is an effective bleaching composition when containing peroxy compounds.

Description

세척조성물 및 이를 이용한 얼룩기질의 표백방법Cleaning composition and bleaching method of stain

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음As this is a public information case, the full text was not included.

Claims (12)

표면 활성물질 및 하기 일반식(I)의 리간드 L을 함유하는 세척 조성물.Washing composition containing surface active material and ligand L of the following general formula (I). 상기식에서,t는 2또는 3의 정수이고, s는 3내지 4의 정수이고, u는 0 또는 1이고, R1,R2및 R3는 각각 독립적으로 수소, 또는 임의치환된 알킬 또는 아릴중에서 선택된다.Wherein t is an integer of 2 or 3, s is an integer of 3 to 4, u is 0 or 1, and R 1 , R 2 and R 3 are each independently hydrogen or optionally substituted alkyl or aryl Is selected. 퍼옥시화합물 및 하기 일반식(I)의 리간드 L을 함유하는 세제조성물.A detergent composition containing a peroxy compound and ligand L of general formula (I) below. 상기식에서, t는 2또는 3의 정수이고, s는 3내지 4의 정수이고,u는 0또는 1이고,R1,R2및 R3는 각각 독립적으로 수소, 또는 임의치환된 알킬 또는 아릴중에서 선택된다.Wherein t is an integer of 2 or 3, s is an integer of 3 to 4, u is 0 or 1, and R 1 , R 2 and R 3 are each independently hydrogen or optionally substituted alkyl or aryl Is selected. 제1항에 있어서, 퍼옥시화합물을 추가로 함유하는 세척조성물.The washing composition according to claim 1, further comprising a peroxy compound. 제1항 또는 3항에 있어서, 철 및/또는 망간이온류를 추가로 함유하는 세척조성물.The cleaning composition according to claim 1 or 3, further comprising iron and / or manganese ions. 제1항 내지 4항중 어느하나에 있어서, 하기 일반식(A)의 일핵 또는 이핵 망간착화합물을 추가로 함유하는 세척 조성물.The washing composition according to any one of claims 1 to 4, further comprising a mononuclear or dinuclear manganese complex compound of the following general formula (A). 상기식에서, n및 m은 독립적으로 1또는 2이고, p는 1내지 3의 정수이고, z는 착화합물의 전하로서, 양의정수, 0 또는 음의 정수이며, Y는 대이온으로서 그의 형태를 착화합물의 전하 z에 따라 다라지며, q는 z/전하 Y이며, Mn은 Ⅱ,Ⅲ 또는 Ⅳ 산화상태에 망간 또는 그의 혼합물이며, X는 배위 또는 브리지하는 부분이며,L은 상기 일반식(B)의 리간드이며, t는 2내지 3의 정수이며, s는 3내지 4의 정수이며, R1,R2및 R3는 각각 독립적으로 수소, 알킬, 아릴 또는 치환된 알킬 또는 아릴이다.Wherein n and m are independently 1 or 2, p is an integer of 1 to 3, z is a charge of a complex, a positive integer, 0 or a negative integer, and Y is a complex ion, complexing its form Depends on the charge z, q is z / charge Y, Mn is manganese or a mixture thereof in the II, III or IV oxidation state, X is the coordinating or bridging moiety and L is the formula (B) Ligand, t is an integer from 2 to 3, s is an integer from 3 to 4, and R 1 , R 2 and R 3 are each independently hydrogen, alkyl, aryl or substituted alkyl or aryl. 제1항 내지 5항의 어느하나에 있어서, 리간드 L에서 t가 2내지 3의 정수이고, s는 3내지 4의 정수이고, u는 0또는 1이며, R1,R2및 R3는 각각 독립적으로 수소 또는 임의 치환된 알킬 또는 아릴인 세척조성물.The ligand L according to any one of claims 1 to 5, wherein in the ligand L, t is an integer of 2 to 3, s is an integer of 3 to 4, u is 0 or 1, and R 1 , R 2 and R 3 are each independently Washing composition which is hydrogen or optionally substituted alkyl or aryl. 제4항에 있어서, 철 및 망간 이온류가 철(Ⅲ) 니트레이트, 망간니트레이트, 망간클로라이드, 망간설페이트, 망간아세테이트, 망간아세틸아세트네이트 및 망간에틸렌디아민테트라아세트산 중에서 선택되는 세척조성물.The cleaning composition according to claim 4, wherein the iron and manganese ions are selected from iron (III) nitrate, manganese nitrate, manganese chloride, manganese sulfate, manganese acetate, manganese acetylacetate and manganese ethylenediaminetetraacetic acid. (i)2내지 30중량%의 퍼옥시화합물, (ⅱ)50중량%까지의 표면활성물질, (ⅲ)하기 일반식(I)의 리간를 함유하는 세제조성물.A detergent composition comprising (i) 2 to 30% by weight of a peroxy compound, (ii) up to 50% by weight of surface active substance, and (i) a ligand of the following general formula (I). 상기식에서, t는 2 또는 3의 정수이고, s는 3내지 4의 정수이고 u는 0또는 1이고, R1, R2및 R3는 각각 독립적으로 수소, 또는 임의치환된 알킬 또는 카본중에서 선택된다.Wherein t is an integer of 2 or 3, s is an integer of 3-4, u is 0 or 1, and R 1 , R 2 and R 3 are each independently selected from hydrogen or optionally substituted alkyl or carbon do. 제8항에 있어서, 철 및/또는 망간이온류를 추가로 함유하는 조성물.The composition of claim 8 further comprising iron and / or manganese ions. 제9항에 있어서, 일반식(I)의 리간드가 0.003내지 300ppm의 농도로 존재하고 철 및/또는 망간이온류가 0.001 내지 100ppm의 농도로 존재하는 조성물.The composition according to claim 9, wherein the ligand of formula (I) is present at a concentration of 0.003 to 300 ppm and iron and / or manganese ions are present at a concentration of 0.001 to 100 ppm. 제8항 내지 10항중 어느하나에 있어서, 5내지 80중량%의 세제보강제를 추가로 함유하는 조성물.The composition according to any one of claims 8 to 10, further comprising 5 to 80% by weight of a detergent adjuvant. 수성매체중의 얼룩기질을 퍼옥시화합물과 하기 일반식(I)의 리간드와 상호반응하여 기질에 세척효과를 제공하기 충분한 양으로 접촉시킴을 특징으로 하는 얼룩기질의 표백방법.A method of bleaching bleaching substrates, comprising contacting the bleaching substrate in an aqueous medium with a peroxy compound and a ligand of the general formula (I) in an amount sufficient to provide a cleaning effect to the substrate. 상기식에서,t는 2또는 3의 정수이고, s는 3내지 4의 정수이고, u는 0또는 1이고, R1,R2및 R3는 각각 독립적으로 수소, 또는 임의치환된 알킬 또는 아릴로 부터 선택된다.Wherein t is an integer of 2 or 3, s is an integer of 3 to 4, u is 0 or 1, and R 1 , R 2 and R 3 are each independently hydrogen or optionally substituted alkyl or aryl Is selected. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR92024784A 1991-12-20 1992-12-19 Bleach activation KR960002630B1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB919127060A GB9127060D0 (en) 1991-12-20 1991-12-20 Bleach activation
GB9127060.3 1991-12-20
GB929204706A GB9204706D0 (en) 1991-12-20 1992-03-04 Bleach activation

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KR930013079A true KR930013079A (en) 1993-07-21
KR960002630B1 KR960002630B1 (en) 1996-02-24

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KR1019920024785A KR930012103A (en) 1991-12-20 1992-12-19 Bleaching catalyst, bleaching composition and bleaching method of stain substrate

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EP (1) EP0549272A1 (en)
JP (1) JPH05263098A (en)
KR (2) KR960002630B1 (en)
CN (1) CN1074237A (en)
AU (1) AU3029792A (en)
BR (1) BR9205100A (en)
CA (1) CA2085720A1 (en)
GB (2) GB9127060D0 (en)
MX (1) MX9207471A (en)
NO (1) NO924895L (en)
TW (1) TW232706B (en)
ZA (2) ZA929850B (en)

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