KR930010076A - 중합반응 생성물 - Google Patents

중합반응 생성물 Download PDF

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KR930010076A
KR930010076A KR1019920022028A KR920022028A KR930010076A KR 930010076 A KR930010076 A KR 930010076A KR 1019920022028 A KR1019920022028 A KR 1019920022028A KR 920022028 A KR920022028 A KR 920022028A KR 930010076 A KR930010076 A KR 930010076A
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polymerization product
average
component
primary
compound
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KR1019920022028A
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KR100243786B1 (ko
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파울 디터
호프만 게르하르트
후엠케 클라우스
하이만 울리히
에이.길버트 죤
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빈터, 트리에슈만
바스프 락케+파르벤 악티엔게젤샤프트
트리에슈만
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/44—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/44—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
    • C09D5/4488—Cathodic paints
    • C09D5/4492—Cathodic paints containing special additives, e.g. grinding agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/80—Masked polyisocyanates
    • C08G18/8003—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen
    • C08G18/8006—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/32
    • C08G18/8009—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/32 with compounds of C08G18/3203
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G81/00—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers
    • C08G81/02—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers at least one of the polymers being obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C08G81/024—Block or graft polymers containing sequences of polymers of C08C or C08F and of polymers of C08G
    • C08G81/025—Block or graft polymers containing sequences of polymers of C08C or C08F and of polymers of C08G containing polyether sequences
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
    • C08J3/246—Intercrosslinking of at least two polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • C08L71/02—Polyalkylene oxides
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/44—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
    • C09D5/4488—Cathodic paints
    • C09D5/4496—Cathodic paints characterised by the nature of the curing agents
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31511—Of epoxy ether
    • Y10T428/31529—Next to metal

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Molecular Biology (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Paints Or Removers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Epoxy Resins (AREA)
  • Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
  • Polyethers (AREA)

Abstract

하기 성분들의 반응에 의해 얻을 수 있는 중합반응 생성물, I) 하기 성분(a1) 및 (b2) 또는 (a2) 또는 (b1)은 서로 반응하여 성분(a2) 또는 (b2)의 에폭사이드 당량당 성분(a1) 또는 (b1)의 1.05 내지 3.0 아미노 당량이 존재하는 A) 분자당 평균 1.5 내지 3.5 a1) 1차 및/또는 2차 아미노기 또는 a2)에폭시기를 함유하고 140 내지 10000 평균분자량을 가지는 폴리옥시 알킬렌 및 B) 분자당 평균 1.5 내지 3.0 b1) 1차 및/또는 2차 아미노기 도는 b2)에폭시기를 함유하고 250 내지 50000의 평균분자량

Description

중합반응 생성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. 하기 성분들의 반응에 의해 얻을 수 있는 중합반응 생성물, I) 하기 성분(a1) 및 (b2) 또는 a2(b1)은 서로 반응하여 성분(a2) 또는 (b2)의 에폭사이드 당량당 성분(a1) 또는 (b1)의 1.05 내지 3.0 아미노 당량이 존재하는 A) 분자당 평균 1.5 내지 3.0 a1) 1차 및/또는 2차 아미노기 또는 a2)에폭시기를 함유하고 140 내지 10000평균분자량을 가지는 폴리옥시 알킬렌 및 B) 분자당 평균 1.5 내지 3.0 b1)1차 및/또는 2차 아미노기 또는 b2)에폭시기를 함유하고 250 내지 50000의 평균분자량을 가지는, 공액디엔을 기초로 하는 중합체로부터 얻을 수 있는 예비중합체 및 II) 유리 라디칼을 형성하는 하나 이상의 화합물.
  2. 제1항에 있어서, 예비중합체(I)을 예비중합체(I)의 고체함량을 기준으로 0.1 내지 20중량%의 하나 이상의 화합물(II)와 반응시켜 얻을 수 있는 중합반응 생성물.
  3. 제1항에 있어서, 폴리옥시알킬렌(A)는 폴리옥시부틸렌임을 특징으로 하는 중합반응 생성물.
  4. 제1항에 있어서, 중합체(B)는 5 내지 45중량%의 아클릴로니트릴 함량을 가지는 부타디엔/아크릴로니트릴 공중합체임을 특징으로 하는 중합반응 생성물.
  5. 제1항에 있어서, 성분(II)는 아조비스이소부티로니트릴, 3차-부틸퍼벤조에이트, 3차-부틸 퍼옥테이트, 3차-부틸퍼피발레이트 및 라우릴 퍼옥사이드로 구성된 그룹으로부터 선택됨을 특징으로 하는 중합반응 생성물.
  6. 하기 성분(I)을 하기 성분(II)와 반응시킴을 특징으로 하는 제1항의 중합반응 생성물을 제조하는 방법.
    I) 하기 성분(a1) 및 (b2) 또는 (a2) 또는 (b1)은 서로 반응하여 성분(a2) 또는 (b2)의 에폭사이드 당량당 성분(a1) 또는 (b1)의 1.05 내지 3.0 아미노 당량이 존재하는 A) 분자당 평균 1.5 내지 3.0 a1) 1차 및/또는 2차 아미노기 또는 a2)에폭시기를 함유하고 140 내지 10000 평균분자량을 가지는 폴리옥시 알킬렌 및 B) 분자당 평균 1.5 내지 3.0 b1) 1차 및/또는 2차 아미노기 또는 b2) 에폭시기를 함유하고 250 내지 50000의 평균분다량을 가지는, 공액디엔을 기초로 하는 중합체로부터 얻을 수 있는 예비중합체.
    II) 유리 라디칼을 형성하는 하나 이상의 화합물.
  7. 예비중합체(I)은 부분적으로 또는 완전히 산과 중화된 후, 화합물(II)와 함께 분산되고 40 내지 100℃에서 반응됨을 특징으로 하는 제1항의 중합반응 생성물을 제조하는 방법.
  8. 전기피복조에 첨가제로서의 제1항의 중합반응 생성물의 용도.
  9. 전기피복조의 전체 중합체 함량을 기준으로, 1 내지 40중량%의 제1항의 중합반응 생성물을 함유하는 전기피복조.
  10. 제9항의 전기피복조를 사용하여 양극 전기피복에 의해 피복되는 제품.
    ※ 참고사항 : 최초출원 내용에 의하여 공개되는 것임.
KR1019920022028A 1991-11-23 1992-11-23 중합반응 생성물 KR100243786B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DEP4138586.1 1991-11-23
DE4138586A DE4138586A1 (de) 1991-11-23 1991-11-23 Polymere umsetzungsprodukte

Publications (2)

Publication Number Publication Date
KR930010076A true KR930010076A (ko) 1993-06-22
KR100243786B1 KR100243786B1 (ko) 2000-02-01

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ID=6445454

Family Applications (2)

Application Number Title Priority Date Filing Date
KR1019920703093A KR960014106B1 (ko) 1990-06-06 1991-05-31 전기 전도성 기판의 코팅방법, 물-기저 코팅 및 차단된 nco기 함유 교차결합제
KR1019920022028A KR100243786B1 (ko) 1991-11-23 1992-11-23 중합반응 생성물

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KR1019920703093A KR960014106B1 (ko) 1990-06-06 1991-05-31 전기 전도성 기판의 코팅방법, 물-기저 코팅 및 차단된 nco기 함유 교차결합제

Country Status (12)

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US (2) US5336722A (ko)
EP (1) EP0544182B1 (ko)
JP (1) JP3335392B2 (ko)
KR (2) KR960014106B1 (ko)
CN (2) CN1036403C (ko)
AT (1) ATE152749T1 (ko)
BR (1) BR9204507A (ko)
CA (1) CA2083466A1 (ko)
DE (2) DE4138586A1 (ko)
DK (1) DK0544182T3 (ko)
ES (1) ES2103868T3 (ko)
ZA (1) ZA928976B (ko)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4421623A1 (de) * 1994-06-21 1996-01-04 Thera Ges Fuer Patente Mehrkomponentige, kationisch härtende Epoxidmassen und deren Verwendung sowie Verfahren zur Herstellung gehärteter Massen
DE19753456B4 (de) * 1997-12-02 2007-01-11 3M Espe Ag Zweikomponente, kationisch aushärtende Zubereitungen auf der Basis von Aziridinopolyethern und deren Verwendung
FR2802542A1 (fr) 1999-12-20 2001-06-22 Michelin Soc Tech Composition de caoutchouc vulcanisable pour la fabrication d'un pneumatique et pneumatique dont la bande de roulement comprend une telle composition
DE60109224T2 (de) * 2000-02-24 2006-01-19 Société de Technologie Michelin Vulkanisierbare Kautschukmischung zur Herstellung eines Luftreifens und Luft- reifens und Luftreifen, der eine solche Zusammensetzung enthält.
US20040204551A1 (en) * 2003-03-04 2004-10-14 L&L Products, Inc. Epoxy/elastomer adduct, method of forming same and materials and articles formed therewith
JP5682594B2 (ja) 2012-05-24 2015-03-11 横浜ゴム株式会社 変性ジエン系ポリマー

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4432850A (en) * 1981-07-20 1984-02-21 Ppg Industries, Inc. Ungelled polyepoxide-polyoxyalkylenepolyamine resins, aqueous dispersions thereof, and their use in cationic electrodeposition
US4532299A (en) * 1982-01-12 1985-07-30 Ameron, Inc. Flexibilized chemically resistant epoxy resin
US4804581A (en) * 1987-05-14 1989-02-14 Ppg Industries, Inc. Chip resistant coatings
JP2686635B2 (ja) * 1989-02-03 1997-12-08 神東塗料株式会社 カチオン電着塗料組成物
DE3906144A1 (de) * 1989-02-28 1990-09-06 Basf Lacke & Farben Durch protonieren mit saeure wasserverduennbare polymere umsetzungsprodukte
EP0432923A1 (en) * 1989-11-30 1991-06-19 Lord Corporation Epoxy-rubber alloy compositions
DE4029199A1 (de) * 1990-09-14 1992-03-19 Basf Lacke & Farben Polymere umsetzungsprodukte

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Publication number Publication date
KR960014106B1 (ko) 1996-10-14
KR930701554A (ko) 1993-06-12
JPH05262883A (ja) 1993-10-12
BR9204507A (pt) 1993-06-01
EP0544182A1 (de) 1993-06-02
ATE152749T1 (de) 1997-05-15
CN1168909A (zh) 1997-12-31
DE4138586A1 (de) 1993-05-27
CA2083466A1 (en) 1993-05-24
KR100243786B1 (ko) 2000-02-01
US5336722A (en) 1994-08-09
ES2103868T3 (es) 1997-10-01
ZA928976B (en) 1994-05-20
DE59208451D1 (de) 1997-06-12
CN1073693A (zh) 1993-06-30
EP0544182B1 (de) 1997-05-07
US5385977A (en) 1995-01-31
CN1036403C (zh) 1997-11-12
DK0544182T3 (da) 1997-11-03
JP3335392B2 (ja) 2002-10-15

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