KR930006067A - 지방족 용매에서의 분산코폴리머 - Google Patents

지방족 용매에서의 분산코폴리머 Download PDF

Info

Publication number
KR930006067A
KR930006067A KR1019920016192A KR920016192A KR930006067A KR 930006067 A KR930006067 A KR 930006067A KR 1019920016192 A KR1019920016192 A KR 1019920016192A KR 920016192 A KR920016192 A KR 920016192A KR 930006067 A KR930006067 A KR 930006067A
Authority
KR
South Korea
Prior art keywords
block
weight
dispersant
polymer
copolymer
Prior art date
Application number
KR1019920016192A
Other languages
English (en)
Other versions
KR100237193B1 (ko
Inventor
이. 홀 제임스
Original Assignee
데이비드 에이 토마스
브리지스톤 코포레이션
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 데이비드 에이 토마스, 브리지스톤 코포레이션 filed Critical 데이비드 에이 토마스
Publication of KR930006067A publication Critical patent/KR930006067A/ko
Application granted granted Critical
Publication of KR100237193B1 publication Critical patent/KR100237193B1/ko

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/10—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated with vinyl-aromatic monomers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Graft Or Block Polymers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

본 발명은 최소한 하나의 폴리머 블록이 분산배지에 용해되고, 최소한 하나의 또다른 폴리머 블록이 분산배지에 비용해 되며, 분산제는 비닐치환 방향족 화합물 및 분산제의 존재하에서 형성된 콘쥬게이트된 디엔의 랜덤 코폴리머를 분산하도록 작용하고, 액체 지방족 선형 탄화수소 분산배지, 비이온성 촉매계 및 최소한 두개의 폴리머 블록을 함유하는 블록 코폴리머 분산제를 포함하는 반응혼합물에서 공중합을 수행하는 것을 포함하는 35-70중량%의 비닐치환 방향족 모노머와 30-60중량%의 콘쥬게이트된 디엔 모노머를 분산 공중합하는 방법에 관한 것이다.

Description

지방족 용매에서의 분산코폴리머
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (13)

  1. 최소한 하나의 폴리머 블록이 분산배지에 용해되고, 최소한 하나의 또다른 폴리머 블록이 분산배지에 비용해 되며, 분산제는 비닐치환 방향족 화합물 및 분산제의 존재하에서 형성된 콘쥬게이트된 디엔의 랜덤 코폴리머를 분산하도록 작용하고, 액체 지방족 선형 탄화수소 분산배지, 비이온성 촉매계 및 최소한 두개의 폴리머 블록을 함유하는 블록 코폴리머 분산제를 포함하는 반응혼합물에서 공중합을 수행하는 것을 포함하는 35-70중량%의 비닐치환 방향족 모노머와 30-65중량%의 콘쥬게이트된 디엔 모노머를 분산 공중합하는 방법.
  2. 제1항에 있어서, 분산배지가 최소한 60중량%의 n-헥산을 포함하는 방법.
  3. 제1항에 있어서, 블록 코폴리머 분산제가 콘쥬게이트된 디엔 모노머와 비닐치환 방향족 모노머의 공중합에 의해 형성된 용해성 블록의 폴리디엔 또는 코폴리머 및 콘쥬게이트된 디엔 모노머와 비닐치환 방향족 모노머의 공중합에 의해 형성된 비용해성 블록의 폴리비닐 방향족 폴리머 또는 코폴리머를 포함하는 방법.
  4. 제3항에 있어서, 용해성 블록은 70-10중량부의 콘쥬게이트된 디엔 모노머 기여 단위체와 0-30중량부의 비닐치환 방향족 모노머 기여 단위체로부터 형성된 폴리머 또는 코폴리머이고 비용해성 블록은 0-65중량부의 콘쥬게이트된 디엔 기여 단위체와 35-100중량부의 비닐치환 방향족 모노머 기여 단위체인 방법.
  5. 제1항에 있어서, 블록 코폴리머 분산제가 폴리부타디엔 한 블록과 0-65중량%의 부타디엔 및 35-100중량%의 스티렌의 랜덤 공중합에 의해 형성된 한 블록을 함유하는 두 블록의 폴리머인 방법.
  6. 제1항에 있어서, 블록 코폴리머 분산제가 70-100중량%의 부타디엔과 0-30중량%의 스티렌의 랜덤 공중합에 의해 형성된 제1블록 및 0-65중량%의 부타디엔과 35-100중량%의 스티렌의 랜덤 공중합에 의해 형성된 제2블록을 함유하는 두 블록의 폴리머인 방법.
  7. 제1항에 있어서, 촉매는 리튬기초 비이온성 개시제인 방법.
  8. 제1항에 있어서, 분산이 이루어졌을 때 10-50중량% 폴리머 고형물을 함유하는 방법.
  9. 제1항에 있어서, 분산제가 약 1.0-20.0중량%의 모노머를 포함하는 방법.
  10. 제1항에 있어서, 콘쥬게이트된 디엔 모노머가 1,3-부타디엔 또는 이소프렌인 방법.
  11. 제1항에 있어서, 비닐치환 방향족 모노머가 스티렌인 방법.
  12. 제1항에 있어서, 비용해성 폴리머 블록에 대한 분산제의 용해성 폴리머 블록의 중량비가 9.0/1.0-약 1.0/9.0인 방법.
  13. 제1항에 있어서, 랜덤 코폴리머가 분산배지의 용해도 파라메터보다 최소한 1.9 더 큰 용해도 파라메터를 가지는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019920016192A 1991-09-03 1992-09-03 지방족 용매에서의 분산코폴리머 KR100237193B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US75449291A 1991-09-03 1991-09-03
US754,492 1991-09-03

Publications (2)

Publication Number Publication Date
KR930006067A true KR930006067A (ko) 1993-04-20
KR100237193B1 KR100237193B1 (ko) 2000-01-15

Family

ID=25035045

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019920016192A KR100237193B1 (ko) 1991-09-03 1992-09-03 지방족 용매에서의 분산코폴리머

Country Status (10)

Country Link
US (1) US5395902A (ko)
EP (1) EP0530796B1 (ko)
JP (1) JPH07108930B2 (ko)
KR (1) KR100237193B1 (ko)
BR (1) BR9203445A (ko)
CA (1) CA2077370C (ko)
DE (1) DE69205931T2 (ko)
ES (1) ES2081536T3 (ko)
MX (1) MX9205059A (ko)
ZA (1) ZA926695B (ko)

Families Citing this family (45)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4416478A1 (de) * 1994-05-10 1995-11-16 Basf Ag Plastisole, enthaltend anionische Polymerisate
DE4444016A1 (de) * 1994-12-10 1996-06-13 Basf Ag Verfahren zur Herstellung von Polystyrol durch anionische Polymerisation
DE19507777A1 (de) * 1995-03-06 1996-09-12 Basf Ag Filtrierbare Polystyrol-Dispersionen
DE19509785A1 (de) * 1995-03-17 1996-09-19 Basf Ag Verfahren zur Herstellung von Polymerisaten von vinylaromatischen Verbindungen unter Druck in Gegenwart von leicht flüchtigen Kohlenwasserstoffen
US6008295A (en) * 1997-07-11 1999-12-28 Bridgestone Corporation Diene polymers and copolymers incorporating partial coupling and terminals formed from hydrocarboxysilane compounds
DE19733535A1 (de) * 1997-08-02 1999-02-04 Basf Ag Schaumstoff-Formteile für die Lebensmittelverpackung
US6605680B1 (en) 2000-04-07 2003-08-12 Eastman Chemical Resins, Inc. Low color, aromatic modified C5 hydrocarbon resins
US6881795B2 (en) * 2001-03-28 2005-04-19 Firestone Polymers, Llc CO2 terminated rubber for plastics
US6437050B1 (en) 2001-10-04 2002-08-20 Bridgestone Corporation Nano-particle preparation and applications
US6956084B2 (en) * 2001-10-04 2005-10-18 Bridgestone Corporation Nano-particle preparation and applications
US6706823B2 (en) 2001-12-31 2004-03-16 Bridgestone Corporation Conductive gels
AU2003301053A1 (en) * 2002-12-18 2004-07-22 Bridgestone Corporation Method for clay exfoliation, compositions therefore, and modified rubber contaiing same
US6875818B2 (en) 2003-01-16 2005-04-05 Bridgestone Corporation Polymer nano-strings
US7205370B2 (en) * 2004-01-12 2007-04-17 Bridgestone Corporation Polymeric nano-particles of flower-like structure and applications
US8063142B2 (en) 2004-03-02 2011-11-22 Bridgestone Corporation Method of making nano-particles of selected size distribution
US7718737B2 (en) * 2004-03-02 2010-05-18 Bridgestone Corporation Rubber composition containing functionalized polymer nanoparticles
US7112369B2 (en) * 2004-03-02 2006-09-26 Bridgestone Corporation Nano-sized polymer-metal composites
US20050215693A1 (en) * 2004-03-29 2005-09-29 Xiaorong Wang Clay modified rubber composition and a method for manufacturing same
US20050228074A1 (en) * 2004-04-05 2005-10-13 Bridgestone Corporation Amphiphilic polymer micelles and use thereof
US20050282956A1 (en) * 2004-06-21 2005-12-22 Xiaorong Wang Reversible polymer/metal nano-composites and method for manufacturing same
US7998554B2 (en) * 2004-07-06 2011-08-16 Bridgestone Corporation Hydrophobic surfaces with nanoparticles
US7572855B2 (en) 2005-01-28 2009-08-11 Bridgestone Corporation Nano-composite and compositions manufactured thereof
US7579398B2 (en) * 2005-02-02 2009-08-25 Bridgestone Corporation Nano-composite and compositions therefrom
US7659342B2 (en) * 2005-02-03 2010-02-09 Bridgestone Corporation Polymer nano-particle with polar core and method for manufacturing same
US7538159B2 (en) 2005-12-16 2009-05-26 Bridgestone Corporation Nanoparticles with controlled architecture and method thereof
US9061900B2 (en) * 2005-12-16 2015-06-23 Bridgestone Corporation Combined use of liquid polymer and polymeric nanoparticles for rubber applications
US8288473B2 (en) * 2005-12-19 2012-10-16 Bridgestone Corporation Disk-like nanoparticles
US7884160B2 (en) 2005-12-19 2011-02-08 Bridgestone Corporation Non-spherical nanoparticles made from living triblock polymer chains
US8697775B2 (en) * 2005-12-20 2014-04-15 Bridgestone Corporation Vulcanizable nanoparticles having a core with a high glass transition temperature
US7560510B2 (en) 2005-12-20 2009-07-14 Bridgestone Corporation Nano-sized inorganic metal particles, preparation thereof, and application thereof in improving rubber properties
US8877250B2 (en) * 2005-12-20 2014-11-04 Bridgestone Corporation Hollow nano-particles and method thereof
US7601772B2 (en) * 2005-12-20 2009-10-13 Bridgestone Corporation Nano-composite and method thereof
US7935184B2 (en) 2006-06-19 2011-05-03 Bridgestone Corporation Method of preparing imidazolium surfactants
EP2046575A4 (en) 2006-07-28 2010-01-13 Bridgestone Corp POLYMERS CORE SHELL NANOPARTICLES WITH AN INTERPHASE AREA
US7597959B2 (en) * 2006-12-19 2009-10-06 Bridgestone Corporation Core-shell fluorescent nanoparticles
US7649049B2 (en) * 2006-12-20 2010-01-19 Bridgestone Corporation Rubber composition containing a polymer nanoparticle
US8716409B2 (en) * 2006-12-29 2014-05-06 Firestone Polymers, Llc Carboxylate terminated polymers and their use in impact-modified plastics
US7829624B2 (en) * 2007-06-29 2010-11-09 Bridgestone Corporation One-pot synthesis of nanoparticles and liquid polymer for rubber applications
RU2501816C2 (ru) * 2008-04-30 2013-12-20 Стирон Юроп Гмбх Стирол-бутадиеновые полимеры со стирольным градиентом и способы изготовления таковых
ES2527600T3 (es) 2008-12-31 2015-01-27 Bridgestone Corporation Procedimiento de formación de nanopartículas formando primero el núcleo, nanopartícula y composición
US9062144B2 (en) * 2009-04-03 2015-06-23 Bridgestone Corporation Hairy polymeric nanoparticles with first and second shell block polymer arms
KR101762461B1 (ko) 2009-10-14 2017-07-27 가부시키가이샤 브리지스톤 환식 비환식 디엔 공중합체의 제조 방법 및 고무 조성물
US20110172364A1 (en) * 2009-12-29 2011-07-14 Chen Yaohong Charged Nanoparticles And Method Of Controlling Charge
US9115222B2 (en) * 2009-12-29 2015-08-25 Bridgestone Corporation Well defined, highly crosslinked nanoparticles and method for making same
US9428604B1 (en) 2011-12-30 2016-08-30 Bridgestone Corporation Nanoparticle fillers and methods of mixing into elastomers

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3402160A (en) * 1967-02-16 1968-09-17 Firestone Tire & Rubber Co Styrene resins
US4098980A (en) * 1976-06-24 1978-07-04 The Goodyear Tire & Rubber Company Non-aqueous dispersion polymerization of conjugated diolefins
US4452960A (en) * 1982-09-20 1984-06-05 The Goodyear Tire & Rubber Company Process for nonaqueous dispersion polymerization of butadiene in the presence of polymeric dispersing agents
US5270395A (en) * 1987-05-01 1993-12-14 Basf Corporation Process of dispersion polymerization of butadiene in propane or butane
US4942209A (en) * 1987-12-18 1990-07-17 Mobil Oil Corporation Anionic polymerization in high viscosity dispersing medium to form microparticles with narrow size distribution

Also Published As

Publication number Publication date
DE69205931D1 (de) 1995-12-14
ZA926695B (en) 1993-12-23
KR100237193B1 (ko) 2000-01-15
ES2081536T3 (es) 1996-03-16
US5395902A (en) 1995-03-07
BR9203445A (pt) 1993-04-06
JPH05214005A (ja) 1993-08-24
MX9205059A (es) 1993-03-01
CA2077370A1 (en) 1993-03-04
EP0530796A1 (en) 1993-03-10
JPH07108930B2 (ja) 1995-11-22
DE69205931T2 (de) 1996-04-04
CA2077370C (en) 1998-12-15
EP0530796B1 (en) 1995-11-08

Similar Documents

Publication Publication Date Title
KR930006067A (ko) 지방족 용매에서의 분산코폴리머
KR910020044A (ko) 수소화 공역 디올레핀 중합체의 제조방법
US5276101A (en) Melt metalation of block copolymers
GB1533683A (en) Non-aqueous dispersion polymerization of conjugated diolefins
DE69119440T2 (de) Härtbares flüssiges Copolymer
KR840007091A (ko) 중합체 수소화 방법
AU6933791A (en) Solid block and random elastomeric copolymers
KR930006063A (ko) 연속 테이퍼 중합체 및 공중합체, 및 이들의 제조방법
KR950704405A (ko) 폴리디메틸실록산 블록 공중합체의 제조 방법(process for the preparati0n of polydimethy siloxane block copolymers)
KR930007995A (ko) 비대칭 방사상 중합체의 제조 방법
CA2169610A1 (en) Process for the preparation of vinylaromatic copolymers reinforced with rubber
SE7514515L (sv) Sett for losningspolymerisation eller -sampolymerisation av en eller flera konjugerade diener, eventuellt tillsammans med en eller flera vinylaromatiska foreningar
KR960029358A (ko) 이소프렌 함유 블록 공중합체의 제조 방법
KR960705870A (ko) 수소첨가된 비대칭 방사상 공중합체(hydrogenated asymmetric radial copolymers)
KR850001776A (ko) 이소프로페닐 방향족 단량체와 비닐 방향족 단량체와의 공중합체의 제조방법
JPS56166213A (en) Aftertreatment of liquid conjugate diene polymerization product
KR910020057A (ko) 투명 내충격성 스티렌 수지의 제조방법
GB1414924A (en) Method of preparing thermostable block-copolymers
Hall Dispersion copolymers in aliphatic solvents
KR840004129A (ko) 디엔 스티렌 α-메틸스티렌 블럭 폴리머의 제조방법
GB1409956A (en) Method of preparing a thermostable block-copolymer
RU98112996A (ru) Способ получения термоэластопластов
GB1460453A (en) Butadiene polymer and copolymer adducts
MX9703558A (es) Copolimerizacion anionica de dienos conjugados y vinilarenos en presencia de alquileters de tetrahidropiranilo-metanol.

Legal Events

Date Code Title Description
A201 Request for examination
E902 Notification of reason for refusal
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
FPAY Annual fee payment

Payment date: 20101006

Year of fee payment: 12

LAPS Lapse due to unpaid annual fee