KR927003772A - Liquid hard surface detergent composition containing zwitterionic cleaning surfactant and monoethanolamine and / or β-aminoalkanol - Google Patents

Liquid hard surface detergent composition containing zwitterionic cleaning surfactant and monoethanolamine and / or β-aminoalkanol Download PDF

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KR927003772A
KR927003772A KR1019920701779A KR920701779A KR927003772A KR 927003772 A KR927003772 A KR 927003772A KR 1019920701779 A KR1019920701779 A KR 1019920701779A KR 920701779 A KR920701779 A KR 920701779A KR 927003772 A KR927003772 A KR 927003772A
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group
hydrogen
carbon atoms
composition
hydroxy
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KR1019920701779A
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Korean (ko)
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웨인 마이클 다니엘
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리차드 찰스 위테
더 프록터 앤드 갬블 컴퍼니
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Priority claimed from US07/628,064 external-priority patent/US5108660A/en
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Publication of KR927003772A publication Critical patent/KR927003772A/en

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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/92—Sulfobetaines ; Sulfitobetaines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/90—Betaines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0043—For use with aerosol devices
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/30—Amines; Substituted amines ; Quaternized amines

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

내용 없음No content

Description

쯔비터이온성 세정 계면활성제 및 모노에탄올아민 및/또는 β-아미노알칸올을 함유하는 액체 경질 표면 세제 조성물Liquid hard surface detergent composition containing zwitterionic cleaning surfactant and monoethanolamine and / or β-aminoalkanol

[도면의 간단한 설명][Brief Description of Drawings]

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (10)

(a) 약 0.001% 내지 약 15%, 더욱 바람직하게는 약 0.02% 내지 약 10%농도의 쯔비터이온성 세정 계면활성제, 바람직하게는 하기 일반식의 쯔비터이온성 세정 계면활성제, 더욱 바람직하게는 하이드로카빌아미도알킬렌 설포베타인 세정 계면활성제, (b) 탄소수 3 내지 약 6의 모노에탄올아민 및/또는 β-아미노알칸올[여기서, β-아미노알칸올은 바람직하게는 2-아미노, 2-메틸-프로판올, 2-아미노, 1-부탄올, 및 이의 혼합물로 이루어진 그룹중에서 선택된다], 바람직하게는 모노에탄올아민을 포함하고, m이 0인 경우에 반점/막 형성을 감소시키기에 유효한 양으로 존재함, 약 7.7미만의 수소결합 파라미터를 갖는 용매 및 바람직하게는 약 9.5 내지 약 13의 목적하는 pH를 제공하는 완충 시스템을 함유하는, 약 0.05% 내지, 약 10%, 바람직하게는 0.2 내지 약 5%농도의 임의의 용매/완충제 시스템, 및 나머지로서 (c) 수성 용매 시스템 및/또는 소량의 성분을 포함하는 수성 액체 경질 표면 세제 조성물.(a) a zwitterionic cleaning surfactant at a concentration of about 0.001% to about 15%, more preferably about 0.02% to about 10%, preferably a zwitterionic cleaning surfactant of the general formula Carbylamidoalkylene sulfobetaine cleaning surfactant, (b) monoethanolamine having 3 to about 6 carbon atoms and / or β-aminoalkanol, wherein β-aminoalkanol is preferably 2-amino, 2- Selected from the group consisting of methyl-propanol, 2-amino, 1-butanol, and mixtures thereof, preferably monoethanolamine, in an amount effective to reduce spot / membrane formation when m is zero. Present, from about 0.05% to about 10%, preferably from 0.2 to about, containing a solvent having a hydrogen bonding parameter of less than about 7.7 and preferably a buffer system providing a desired pH of about 9.5 to about 13. 5% concentration of any dragon An aqueous liquid hard surface detergent composition comprising a medium / buffer system and, as a remainder, (c) an aqueous solvent system and / or a small amount of components. R3-[C(O)-N(R4)-(CR5 2)n-]mN(R6)2(+)-(CR5 2)p-Y(-)R 3- [C (O) -N (R 4 )-(CR 5 2 ) n- ] m N (R 6 ) 2 (+)-(CR 5 2 ) p -Y (-) 상기 식에서, R3은 각각 탄소수 약 8 내지 약 20, 바람직하게는 약 10 내지 약 18의 알킬 또는 알킬렌 그룹이고, (R4) 및 (R6)은 각각 수소, 메틸, 에틸, 프로필, 하이드록시 치환된 에틸 또는 프로필 및 이의 혼합물로 이루어진 그룹중에서 선택되며, (R5)는 각각 수소 및 하이드록시 그룹으로 이루어진 그룹 중에서 선택되고, 이때 [(CR2)잔기에는 약 1개 이하의 하이드록시 그룹이 존재하며, m은 0 또는 1, 바람직하게는 1이며, n 및 p는 각각 1 내지 약 4의 수이고, Y는 설포네이트 또는 카복실레이트 그룹, 바람직하게는 설포네이트 그룹이다.Wherein R 3 is each an alkyl or alkylene group of about 8 to about 20 carbon atoms, preferably about 10 to about 18 carbon atoms, and (R 4 ) and (R 6 ) are each hydrogen, methyl, ethyl, propyl, hydroxy Is selected from the group consisting of oxy substituted ethyl or propyl and mixtures thereof, wherein (R 5 ) is each selected from the group consisting of hydrogen and hydroxy groups, wherein in the [(CR 2 ) residue there are no more than about 1 hydroxy group Is present, m is 0 or 1, preferably 1, n and p are each a number from 1 to about 4, and Y is a sulfonate or carboxylate group, preferably a sulfonate group. 제1항에 있어서, 쯔비터이온성 세정 계면활성제(a)가 다음 일반식의 하이드로카빌-아미도알킬렌-설포베타인을 포함하는 조성물.The composition of claim 1, wherein the zwitterionic cleaning surfactant (a) comprises hydrocarbyl-amidoalkylene-sulfobetaine of the formula: R3-C(O)-N(R4)-(CR5 2)n-N(R6)2(+)-(CR5 2)p-SO3(-)R 3 -C (O) -N (R 4 )-(CR 5 2 ) n -N (R 6 ) 2 (+)-(CR 5 2 ) p -SO 3 (-) 상기 식에서, R3은 각각 탄소수 약 10 내지 약 18, 바람직하게는 약 12 내지 약 16의 알킬 또는 알킬렌 그룹이고, (R4) 및 (R6)은 각각 수소, 메틸, 에틸, 프로필, 하이드록시 치환된 에틸 또는 프로필 및 이의 혼합물로 이루어진 그룹중에서 선택되며, (R4)는 수소이고 (R6)은 메틸이며, (R5)는 각각 수소 및 하이드록시 그룹으로 이루어진 그룹 중에서 선택되고, 이때 (CR5)2잔기에는 약 1개 이하의 하이드록시 그룹, 바람직하게는 1개의 하이드록시 그룹이 존재하며, n 및 p는 각각 1 내지 약 4의 수이고, 바람직하게는 3이다.Wherein R 3 is each an alkyl or alkylene group of about 10 to about 18 carbon atoms, preferably about 12 to about 16 carbon atoms, and (R 4 ) and (R 6 ) are each hydrogen, methyl, ethyl, propyl, hydroxy Is selected from the group consisting of oxy substituted ethyl or propyl and mixtures thereof, wherein (R 4 ) is hydrogen and (R 6 ) is methyl and (R 5 ) is each selected from the group consisting of hydrogen and hydroxy groups, wherein There are up to about 1 hydroxy group, preferably 1 hydroxy group, at the (CR 5 ) 2 residue, n and p each being a number from 1 to about 4, preferably 3. 제1항에 있어서, 쯔비터이온성 세정 계면활성제(a)가 다음 일반식의 하이드로카빌-아미도알킬베타인 조성물.The composition according to claim 1, wherein the zwitterionic cleaning surfactant (a) is a hydrocarbyl-amidoalkylbeta of the following general formula. R3-C(O)-N(R4)-(CR5 2)n-N(R6)2(+)-(CR5 2)n-COO(-)R 3 -C (O) -N (R 4 )-(CR 5 2 ) n -N (R 6 ) 2 (+)-(CR 5 2 ) n -COO (-) 상기 식에서, R3은 각각 탄소수 약 10 내지 약 18, 바람직하게는 약 12 내지 약 16의 알킬 또는 알킬렌 그룹이고, (R4) 및 (R6)은 각각 수소, 메틸, 에틸, 프로필, 하이드록시 치환된 에틸 또는 프로필 및 이의 혼합물로 이루어진 그룹중에서 선택되며, 바람직하게는 R4는 수소이고 R6은 메틸이며, (R5)는 각각 수소 및 하이드록시 그룹으로 이루어진 그룹 중에서 선택되고, 이때 (CR5)2잔기에는 약 1개 이하의 하이드록시 그룹이 존재하고, n 및 p는 각각 1 내지 약 4의 수이다.Wherein R 3 is each an alkyl or alkylene group of about 10 to about 18 carbon atoms, preferably about 12 to about 16 carbon atoms, and (R 4 ) and (R 6 ) are each hydrogen, methyl, ethyl, propyl, hydroxy Is selected from the group consisting of oxy substituted ethyl or propyl and mixtures thereof, preferably R 4 is hydrogen and R 6 is methyl and (R 5 ) is each selected from the group consisting of hydrogen and hydroxy groups, wherein ( Up to about 1 hydroxy group is present at the CR 5 ) 2 residue, and n and p are each a number from 1 to about 4. 제1항 내지 제3항 중의 어느 한 항에 있어서, 쯔비터이온성 세정 계면활성제가 설포네이트 그룹을 함유하고 이의 (+) 및 (-)전하 중심부 사이의 R5그룹들 중의 하나가 하이드록시 그룹이고 나머지 R5그룹이 수소인 경우, R3그룹의 탄소수가 약 12 내지 약 16이고, R4가 수소이며, 각각의 R6이 메틸이고, n 및 p가 각각 3인 조성물.The method of claim 1, wherein the zwitterionic cleaning surfactant contains a sulfonate group and one of the R 5 groups between its (+) and (−) charge centers is a hydroxy group. Wherein if the remaining R 5 groups are hydrogen, the carbon number of the R 3 groups is from about 12 to about 16, R 4 is hydrogen, each R 6 is methyl, and n and p are each 3; 제1항 내지 제4항 중의 어느 한 항에 있어서, 공계면활성제, 바람직하게는 음이온성 세정 계면활성제, 더욱 바람직하게는 C12-C18알킬 설페이트, C12-C18파라핀 설포네이트, C12-C18아실아미도알킬렌 아미노 알킬렌 설포네이트 및 이의 혼합물로 이루어진 그룹 중에서 선택된, 유효량의 하나 이상의 공계면활성제를 함유하는 조성물.Co-surfactant, preferably an anionic cleaning surfactant, more preferably C 12 -C 18 alkyl sulfate, C 12 -C 18 paraffin sulfonate, C 12 according to claim 1. A composition containing an effective amount of at least one cosurfactant selected from the group consisting of -C 18 acylamidoalkylene amino alkylene sulfonates and mixtures thereof. 제1항 내지 제5항 중의 어느 한 항에 있어서, 바람직하게는 약 9.5 내지 약 13, 더욱 바람직하게는 약 9.7 내지 약 12의 목적하는 pH를 제공하기에 충분한 완충제/알칼리도 공급원, 바람직하게는 암모니아, 알칸올아민, 알칼리 금속 하이드록사이드, 알칼리 금속 실리케이트, 알칼리 금속 보레이트, 알칼리 금속 카보네이트, 알칼리 금속 비카보네이트, 및 이의 혼합물로 이루어진 그룹 중에서 선택된 물질, 보다 바람직하게는 모노에탄올아민 및/또는 β-아미노알칸올아민, 및/또는 알칼리 금속 하이드록사이드(바람직하게는 수산화 나트륨)를 함유하는 조성물.6. A buffer / alkali source, preferably ammonia, as claimed in any one of claims 1 to 5, preferably to provide a desired pH of from about 9.5 to about 13, more preferably from about 9.7 to about 12. , Alkanolamines, alkali metal hydroxides, alkali metal silicates, alkali metal borates, alkali metal carbonates, alkali metal bicarbonates, and mixtures thereof, more preferably monoethanolamine and / or β- A composition containing aminoalkanolamines, and / or alkali metal hydroxides (preferably sodium hydroxide). 제1항 내지 제6항 중의 어느 한 항에 있어서, 용매/완충제 시스템이, 수소결합 파라미터가 약 2 내지 약 7, 바람직하게는 약 3 내지 약 6인 유기용매, 바람직하게는 알킬 및 사이클로알킬 탄화수소 및 할로탄화수소, 알파 올레핀, 벤질, 알콜, 송유, 바람직하게는 일반식 R1O(R2O)mH(여기서, R1은 각각 탄소수 약 3 내지 약 8의 알킬 그룹이고, R2는 각각 에틸렌 또는 프로필렌으로 이루어진 그룹 중에서 선택되며, m은 1 내지 약 3의 수이다)을 갖고, 바람직하게는 모노프로필렌글리콜모노프로필 에테르, 디프로필렌글리콜모노부틸 에테르, 모노프로필렌글리콜모노부틸 에테르, 디에틸렌글리콜모노헥실에테르, 모노에틸렌글리콜모노헥실 에테르 및 이의 혼합물로 이루어진 그룹 중에서 선택된 글리콜 에테르, 탄소수 6 내지 16, 바람직하게는 8 내지 12의 디올, 바람직하게는 2,2,4-트리틸-1,3-펜탄디올, 및 이의 혼합물로 이루어진 그룹 중에서 선택된 유기용매를 약 0.5% 내지 약 20%, 바람직하게는 약 1% 내지 약 15% 포함하는 조성물.The organic solvent, preferably alkyl and cycloalkyl hydrocarbon, according to any one of claims 1 to 6, wherein the solvent / buffer system has a hydrogen bonding parameter of about 2 to about 7, preferably about 3 to about 6. And halohydrocarbons, alpha olefins, benzyl, alcohols, oils, preferably of the general formula R 1 O (R 2 O) mH, wherein R 1 is each an alkyl group having from about 3 to about 8 carbon atoms, and R 2 is each ethylene Or propylene, m is a number from 1 to about 3), preferably monopropylene glycol monopropyl ether, dipropylene glycol monobutyl ether, monopropylene glycol monobutyl ether, diethylene glycol mono A glycol ether selected from the group consisting of hexyl ether, monoethylene glycol monohexyl ether and mixtures thereof, diols having 6 to 16 carbon atoms, preferably 8 to 12 carbon atoms, Preferably from about 0.5% to about 20%, preferably from about 1% to about 15% of an organic solvent selected from the group consisting of 2,2,4-trityl-1,3-pentanediol, and mixtures thereof Composition. 제1항 내지 제7항 중의 어느 한 항에 있어서, 수소결합 파라미터가 약 7.7이상인 비-수성 극성 공용매를 하나 이상 함유하는 조성물.8. The composition of any one of the preceding claims, wherein the composition contains at least one non-aqueous polar cosolvent having a hydrogen bonding parameter of at least about 7.7. 제1항 내지 제8항 중의 어느 한 항에 있어서, 분무 수단을 포함하는 포장물 속에 포장된 조성물.The composition of claim 1 packaged in a package comprising spraying means. 바람직하게는 조성물에서 물 중의 성분(a)의 농도가 약 0.02% 내지 약 1%이고 경질 표면이 유리인 경우, 제9항의 조성물을 경질 표면에 분무시킴을 포함하며, 경질 표면을 세정하는 방법.Preferably, when the concentration of component (a) in water in the composition is from about 0.02% to about 1% and the hard surface is glass, spraying the composition of claim 9 to the hard surface, the method of cleaning the hard surface. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019920701779A 1990-01-29 1991-01-22 Liquid hard surface detergent composition containing zwitterionic cleaning surfactant and monoethanolamine and / or β-aminoalkanol KR927003772A (en)

Applications Claiming Priority (15)

Application Number Priority Date Filing Date Title
US47190890A 1990-01-29 1990-01-29
US47190990A 1990-01-29 1990-01-29
US?07/471,909? 1990-01-29
US?07/471,908? 1990-01-29
US49985890A 1990-03-27 1990-03-27
US?07/499,858? 1990-03-27
US62806690A 1990-12-21 1990-12-21
US62806590A 1990-12-21 1990-12-21
US62806790A 1990-12-21 1990-12-21
US?07/628,065? 1990-12-21
US?07/628,066? 1990-12-21
US07/628,064 US5108660A (en) 1990-01-29 1990-12-21 Hard surface liquid detergent compositions containing hydrocarbyl amidoalkylenesulfobetaine
US?07/628,064? 1990-12-21
US?07/628,067? 1990-12-21
PCT/US1991/000337 WO1991011505A1 (en) 1990-01-29 1991-01-22 Liquid hard surface detergent compositions containing zwitterionic detergent surfactant and monoethanolamine and/or beta-aminoalkanol

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KR927003772A true KR927003772A (en) 1992-12-18

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EP (1) EP0513240B1 (en)
JP (1) JPH05503547A (en)
KR (1) KR927003772A (en)
CN (1) CN1036073C (en)
AR (1) AR245202A1 (en)
AU (1) AU659994B2 (en)
BR (1) BR9105962A (en)
CA (1) CA2074823C (en)
DE (1) DE69129981T2 (en)
ES (1) ES2119773T3 (en)
MX (1) MX173001B (en)
MY (1) MY107342A (en)
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MY107342A (en) 1995-11-30
CA2074823C (en) 1998-01-20
AU7342691A (en) 1991-08-21
EP0513240A4 (en) 1993-10-20
CN1036073C (en) 1997-10-08
DE69129981D1 (en) 1998-09-17
ES2119773T3 (en) 1998-10-16
EP0513240B1 (en) 1998-08-12
JPH05503547A (en) 1993-06-10
CN1054265A (en) 1991-09-04
BR9105962A (en) 1992-10-20
WO1991011505A1 (en) 1991-08-08
AU659994B2 (en) 1995-06-08
NZ236922A (en) 1994-06-27
EP0513240A1 (en) 1992-11-19
CA2074823A1 (en) 1991-07-30
AR245202A1 (en) 1993-12-30
DE69129981T2 (en) 1999-04-15
MX173001B (en) 1994-01-27

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