KR920701341A - 폴리염화비닐용 중합가소제 - Google Patents

폴리염화비닐용 중합가소제

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Publication number
KR920701341A
KR920701341A KR1019910701515A KR910701515A KR920701341A KR 920701341 A KR920701341 A KR 920701341A KR 1019910701515 A KR1019910701515 A KR 1019910701515A KR 910701515 A KR910701515 A KR 910701515A KR 920701341 A KR920701341 A KR 920701341A
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KR
South Korea
Prior art keywords
terpolymer
weight
prepared
composition
ethylene
Prior art date
Application number
KR1019910701515A
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English (en)
Inventor
버튼 케이스 로버트
죠셉 스타쯔 로버트
Original Assignee
미리엄 디이 데코너헤이
이이 아이 듀우판 디 네모아 앤드 캄파니
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by 미리엄 디이 데코너헤이, 이이 아이 듀우판 디 네모아 앤드 캄파니 filed Critical 미리엄 디이 데코너헤이
Publication of KR920701341A publication Critical patent/KR920701341A/ko

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L73/00—Compositions of macromolecular compounds obtained by reactions forming a linkage containing oxygen or oxygen and carbon in the main chain, not provided for in groups C08L59/00 - C08L71/00; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L81/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen or carbon only; Compositions of polysulfones; Compositions of derivatives of such polymers
    • C08L81/06—Polysulfones; Polyethersulfones

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polymerisation Methods In General (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

내용 없음

Description

폴리염화비닐용 중합가소제
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (11)

  1. 일반식 E/X/Y(이때 E는 에틸렌이고, Y는 CO 또는 SO2이고, X는 C1-C10n-알킬 아크릴레이트임)을 갖는 삼원공중합체와 폴리염화비닐과의 낮은 요(腰)강도 블렌드로 필수적으로 구성되는 조성물로서, 상기 삼원공중합체는 중합조건하에서 주어진 X 고단량체에 관해 최대의 획득 중합율 이하로 그의 E,X 및 Y공단량체의 자유라디칼로 개시되는 연속 공중합에 의해 제조되며 약 2.14의 최대 다이 팽윤비를 가지며; 에틸렌 외의 이들 공단량체의 각각의 중량비는 5-60/3-20%이고, 에틸렌은 나머지, 100%-X-Y를 구성하고; 상기 블렌드는 폴리염화비닐 100 중량부당 E/X/Y 삼원공중합체 약 20-400중량부를 포함하는 조성물.
  2. 제1항에 있어서, 삼원 공중합체 E/X/Y는 약 80-150℃, 바람직하게는 100-120℃의 공급 온도와 삼원공중합체 배출온도간의 온도차이에서 제조되는 조성물.
  3. 제2항에 있어서, 삼원 공중합체 E/X/Y는 특정한 삼원공중합체 조성을 위해 최대 획득 중합율의 약 80%이하의 중합율로 제조되는 조성물.
  4. 제3항에 있어서, Y는 CO이고 삼원공중합체는 약 11.5±1%의 중합율로 제조되는 조성물.
  5. 제2항에 있어서, 반응기 온도는 약 140-195℃, 바람직하게는 160-170℃인 조성물.
  6. 제1항에 있어서, X는 메틸 아크릴레이트, 에틸 아크릴레이트, 또는 부틸 아크릴레이트이고 Y는 CO인 조성물.
  7. 일반식 E/X/Y는 (이때 E는 에틸렌이고, Y는 CO 또는 SO2이고, X는 C1-C10n-알킬 아크릴레이트임)을 갖는 삼원공중합체와 폴리염화비닐과의 낮은 요강도 블렌드로부터 제조되는 캘린더된 시이트로서, 상기 삼원 공중합체는 중합 조건하에서 주어진 X는 공단량체에 관한 최대 획득 중합율로 그의 E,X 및 Y 공단량체의 자유 라디칼로 개시되는 연속 공중합에 의해 제조되고, 약 2.14의 최대 다이 팽윤비를 가지며; 에틸렌외의 공단량체 각각의 중량 비율은 5-60/3-20%이고, 에틸렌은 나머지, 100%-X-Y를 구성하고; 상기 블렌드는 폴리염화비닐 100 중량부 당 E/X/Y 상원공중합체 약 20-400 중량부를 포함하는 캘린더된 시이트.
  8. 제7항에 있어서, E/X/Y 삼원 공중합체는 최대 약80-150℃, 바람직하게는 100-120℃의 공급 유입온도와 중합체 배출온도간의 온도 차이로 제조되는 캘린더된 시이트.
  9. 제8항에 있어서, E/X/Y 삼원공중합체에서 Y는 CO 이고 삼원공중합체는 주어진시간 간격동안 반응기로 투입된 단량체의 중량에 관한, 제조된 삼원공중합체의 중량으로 부터 결정된 약 11.5±1%이하의 중합율로 제조되는 캘린더된 시이트.
  10. 제7항에 있어서, E/X/Y 삼원공중합체는 약 140-195℃바람직하게는 160-170℃의 반응기 온도에서 제조되는 캘린더된 시이트.
  11. 제7항에 잇어서, E/X/Y 삼원 공중합체에서 공단량체 X는 메틸아크릴레이트, 에틸 아크릴레이트, 또는 n-부틸 아크릴레이트이고, Y는 CO인 캘린더된 시이트.
    ※참고사항 : 최초출원 내용에 의하여 공개되는 것임.
KR1019910701515A 1989-05-04 1990-04-30 폴리염화비닐용 중합가소제 KR920701341A (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US34705389A 1989-05-04 1989-05-04
PCT/US1990/002249 WO1990013600A1 (en) 1989-05-04 1990-04-30 Polymeric plasticizers for polyvinyl chloride
US347053 1994-11-30

Publications (1)

Publication Number Publication Date
KR920701341A true KR920701341A (ko) 1992-08-11

Family

ID=23362129

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019910701515A KR920701341A (ko) 1989-05-04 1990-04-30 폴리염화비닐용 중합가소제

Country Status (16)

Country Link
US (1) US5278236A (ko)
EP (1) EP0471016A4 (ko)
JP (1) JPH04502644A (ko)
KR (1) KR920701341A (ko)
CN (1) CN1046918A (ko)
AR (1) AR244278A1 (ko)
AU (1) AU5645090A (ko)
BR (1) BR9007349A (ko)
CA (1) CA2015928A1 (ko)
FI (1) FI915160A0 (ko)
HU (1) HU209937B (ko)
IL (1) IL94276A0 (ko)
MX (1) MX171851B (ko)
NZ (1) NZ233541A (ko)
WO (1) WO1990013600A1 (ko)
ZA (1) ZA903407B (ko)

Families Citing this family (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5219665A (en) * 1991-01-30 1993-06-15 E. I. Du Pont De Nemours And Company Fabricated articles with improved resistance to hydrohalocarbons
US5209983A (en) * 1992-06-26 1993-05-11 E. I. Du Pont De Nemours And Company Adhesives for laminating vinyl to various substrates
US5843581A (en) * 1993-06-03 1998-12-01 Cryovac, Inc. Barrier blend and food packaging film containing the blend
EP0627465B1 (en) * 1993-06-03 1998-11-25 W.R. Grace & Co.-Conn. Barrier blend and food packaging film containing the blend
GB9403701D0 (en) * 1994-02-25 1994-04-13 Bp Chem Int Ltd Polymer composition
USH1437H (en) * 1994-03-04 1995-05-02 Spelthann Heinz H Grafted copolymers
US6060136A (en) * 1995-10-13 2000-05-09 Cryovac, Inc. High modulus oxygen-permeable multilayer film
US5464903A (en) * 1994-10-31 1995-11-07 E. I. Du Pont De Nemours And Company Process for preparing ethylene copolymer plasticized PVC
DE19548681C2 (de) * 1995-12-23 1998-01-22 Pegulan Tarkett Ag Verfahren zur Herstellung von geschäumten Schichten aus Polyolefin auf Kalandern
JPH10194979A (ja) * 1997-01-07 1998-07-28 Teika Corp イムノグロブリンｅ抗体産生抑制剤
US6977277B2 (en) 2000-07-18 2005-12-20 Exxonmobil Research And Engineering Company Polyvinyl chloride resins
US20020042475A1 (en) * 2000-07-18 2002-04-11 Patil Abhimanyu Onkar Novel polyvinyl chloride resins
EP1356925A1 (en) 2002-04-25 2003-10-29 Amcor Flexibles Transpac Peelable packaging system and method for making same
US6777514B2 (en) 2002-08-27 2004-08-17 Exxonmobil Research And Engineering Company Geminally disubstituted olefin-carbon monoxide-ethylene polymer useful as a polyvinyl chloride plasticizer and a method of making same
US7566495B2 (en) 2003-10-24 2009-07-28 Avery Dennison Corporation Antimicrobial composites, films, labelstocks, and labels
CA2543496C (en) 2003-10-24 2013-07-16 Avery International Corporation Antimicrobial composites, films, labelstocks and labels
CN100393793C (zh) * 2005-09-30 2008-06-11 赵东日 聚氯乙烯加工塑化改性剂、制备方法及其应用
CN101418058B (zh) * 2007-10-23 2010-12-08 山东瑞丰高分子材料股份有限公司 应用于中小型仪器设备注塑外壳的硬质pvc树脂助剂
CN102007176A (zh) 2008-02-15 2011-04-06 联合碳化化学及塑料技术有限责任公司 用于邻苯二甲酸酯增塑制剂的替代增塑剂体系
DE102009006470B4 (de) 2008-12-23 2012-04-12 Alkor Folien Gmbh Peelbare Folie für faserige Substrate, Verbund aus der Folie und einem Substrat und Verwendung desselben
US8552098B2 (en) 2009-09-30 2013-10-08 Dow Global Technologies Llc Purified acetylated derivatives of castor oil and compositions including same
EP2470598B1 (en) 2009-09-30 2013-07-17 Dow Global Technologies LLC Acetylated glyceride of 12-hydroxystearic acid and blends with epoxidized fatty acid esters
JP5841946B2 (ja) 2009-09-30 2016-01-13 ダウ グローバル テクノロジーズ エルエルシー ヒマシ油のアセチル化誘導体およびそのエポキシ化脂肪酸エステルとのブレンド
JP5757952B2 (ja) 2009-09-30 2015-08-05 ダウ グローバル テクノロジーズ エルエルシー エポキシ化脂肪酸エステル可塑剤を有する熱安定化ポリマー組成物
BR112012028732B1 (pt) 2010-05-10 2020-04-07 Dow Global Technologies Llc composição e fio ou cabo
TW201209168A (en) 2010-07-28 2012-03-01 Dow Global Technologies Llc Plasticizers made from oil extracted from microorganisms and polar polymeric compositions comprising the same
BR112014018121B1 (pt) 2012-02-08 2021-02-02 Dow Global Technologies Llc método para produzir um plastificante tratado
KR102088075B1 (ko) 2012-06-22 2020-03-11 다우 글로벌 테크놀로지스 엘엘씨 아세틸화 폴리올 히드록시스테아레이트 가소제 및 가소화된 중합체 조성물
CN104583292B (zh) 2012-06-26 2017-10-27 陶氏环球技术有限责任公司 增塑剂和增塑的聚合物组合物
BR112015008187B1 (pt) 2012-10-18 2020-10-06 Dow Global Technologies Llc. Processo para fazer um plastificante, composição polimérica e artigo de manufatura
JP6192733B2 (ja) 2012-11-12 2017-09-06 ダウ グローバル テクノロジーズ エルエルシー エポキシ化脂肪酸アルキルエステル可塑剤およびエポキシ化脂肪酸アルキルエステル可塑剤を作製するための方法
CA2891062C (en) 2012-11-12 2020-03-24 Dow Global Technologies Llc Methods for making epoxidized fatty acid alkyl esters
CN103881273B (zh) * 2014-04-11 2016-08-24 厦门港光塑胶工业有限公司 一种耐油耐寒pvc透明粒料及其制备方法

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3780140A (en) * 1971-08-06 1973-12-18 Du Pont Ethylene/carbon monoxide polymer compositions
US4137382A (en) * 1977-09-12 1979-01-30 National Distillers And Chemical Corporation Process for copolymerizing ethylene, vinyl acetate and carbon monoxide to provide copolymers of reduced melt flow rate
US4489193A (en) * 1981-01-30 1984-12-18 Stauffer Chemical Company Blend of internally plasticized vinyl chloride copolymer and ethylene/carbon monoxide polymer
US4391922A (en) * 1982-05-06 1983-07-05 E. I. Du Pont De Nemours And Company Blowing agents as curatives for ethylene/carbon monoxide copolymers
US4613533A (en) * 1982-07-01 1986-09-23 E. I. Du Pont De Nemours And Company Thermoplastic elastomeric compositions based on compatible blends of an ethylene copolymer and vinyl or vinylidene halide polymer
US4699857A (en) * 1986-10-15 1987-10-13 W. R. Grace & Co. Battery separator
JP2516996B2 (ja) * 1987-08-11 1996-07-24 三井・デュポンポリケミカル株式会社 塩化ビニル系輸液容器用樹脂組成物
JPH02212536A (ja) * 1989-02-10 1990-08-23 Sekisui Chem Co Ltd 医療器材用樹脂組成物
JPH02212537A (ja) * 1989-02-10 1990-08-23 Sekisui Chem Co Ltd ディスクマット

Also Published As

Publication number Publication date
WO1990013600A1 (en) 1990-11-15
AU5645090A (en) 1990-11-29
CA2015928A1 (en) 1990-11-04
HU904396D0 (en) 1992-01-28
JPH04502644A (ja) 1992-05-14
AR244278A1 (es) 1993-10-29
ZA903407B (en) 1992-01-29
US5278236A (en) 1994-01-11
EP0471016A4 (en) 1993-01-13
EP0471016A1 (en) 1992-02-19
CN1046918A (zh) 1990-11-14
FI915160A0 (fi) 1991-11-01
BR9007349A (pt) 1992-04-28
IL94276A0 (en) 1991-03-10
NZ233541A (en) 1991-08-27
MX171851B (es) 1993-11-19
HUT60310A (en) 1992-08-28
HU209937B (en) 1994-12-28

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