KR920701106A - α, β-불포화케톤의 합성방법 - Google Patents

α, β-불포화케톤의 합성방법

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Publication number
KR920701106A
KR920701106A KR1019910700748A KR910700748A KR920701106A KR 920701106 A KR920701106 A KR 920701106A KR 1019910700748 A KR1019910700748 A KR 1019910700748A KR 910700748 A KR910700748 A KR 910700748A KR 920701106 A KR920701106 A KR 920701106A
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KR
South Korea
Prior art keywords
group
substituted
general formula
alicyclic
phenyl
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KR1019910700748A
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English (en)
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KR950003331B1 (ko
Inventor
게이이찌 쓰까시마
마사시 나까지마
마사요시 후지마루
겐지 스즈끼
Original Assignee
오리따 미찌오
닛뽕소다 가부시까가이샤
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Publication of KR920701106A publication Critical patent/KR920701106A/ko
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Publication of KR950003331B1 publication Critical patent/KR950003331B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/20—Unsaturated compounds containing keto groups bound to acyclic carbon atoms
    • C07C49/203—Unsaturated compounds containing keto groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C403/00—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone
    • C07C403/14—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone having side-chains substituted by doubly-bound oxygen atoms
    • C07C403/16—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone having side-chains substituted by doubly-bound oxygen atoms not being part of —CHO groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
    • C07C319/14—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides
    • C07C319/20—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides by reactions not involving the formation of sulfide groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C45/72—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/04—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
    • C07D307/10—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/12—Radicals substituted by oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D309/00—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings
    • C07D309/02—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
    • C07D309/04—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • C07D309/06—Radicals substituted by oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D335/00—Heterocyclic compounds containing six-membered rings having one sulfur atom as the only ring hetero atom
    • C07D335/02—Heterocyclic compounds containing six-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Heterocyclic Compounds Containing Sulfur Atoms (AREA)
  • Furan Compounds (AREA)
  • Pyrane Compounds (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Crystals, And After-Treatments Of Crystals (AREA)

Abstract

내용 없음

Description

α,β-불포화케톤의 합성방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (1)

  1. 일반식에 의해 표현되는 α,β-불포화케톤의 합성방법에서
    (식중, R1은 1위치에 측쇄를 갖는 지방족기, 지환족기, 치환된 치환족기, 헤테로고리기, 치환된 헤토로고리기, 페닐기 또는 치환된 페닐기이다), 일반식에 의해 표현되는 알데히드
    R1CHO
    (식중, R1은 상기에서 정의된 바와 같다)를 일반식에 의해 표현되는 아세토아세트 산의 알칼리 금속염.
    (상기식중, M는 알칼라 금속이온)과 촉매로서 3-아자비시클로〔3,2,2,〕노난, 일반식(1)에 의해 표현되는 시클릭 2차 아민
    (식중, n는 3이상 5에 이르며, m은 1이상 10에 이르고, R2는 1내지 10의 탄소원자를 갖는 직쇄의 또는 측쇄를 갖는 알킬기, 지환기 또는 페닐기로 치환된 알킬기, 저알킬기로 치환될 수 있는 지환기, 또는 저 알킬기로 치환될 수 있는 페닐기이며 R2의 치환위치는 N에 인접한 두개의 탄소가 아닌 다른 탄소이다), 일반식(2)에 의해 표현되는 시클릭 2차 아민
    (식중, ℓ은 1이상 6에 이르며, N을 포함하는 고리는 6-원, 7-원, 또는 8-원 고리이고, N의 두측은 메틸렌이고, R3은 저 알킬기이며, 그의 치환위치는 N에 인접한 탄소가 아닌 다른 탄소원자이고은 비지환족기 또는 페닐기이다), 또는 일반식(3)에 의해 표현되는 2차 아민
    CH3NHCH2R4(3)
    (식중, R4는 측쇄 또는 5내지 17개의 탄소원자를 갖는 직쇄를 갖는 지방족기이고, 저 알칼기로 치환될 수 있는 지환족기, 저알킬기로 치환될 수 있는 페닐기, 또는 페닐기로 치환된 알킬기이다)이 존재하는, 물 및 비수용성 유기용매의 혼합 용매내에서, pH를 산으로 일정하게 유지시키는 동안 물의 양을 조절함으로써 반응시키는 것을 특징으로 하는 α,β-불포화케톤의 합성방법이다.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019910700748A 1989-11-17 1990-11-15 α,β-불포화 케톤의 합성방법 KR950003331B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP297387/89 1989-11-17
JP1297387A JP2830210B2 (ja) 1989-11-17 1989-11-17 α，β―不飽和ケトン類の合成法
PCT/JP1990/001487 WO1991007370A1 (en) 1989-11-17 1990-11-15 A METHOD FOR THE SYNTHESIS OF α, β-UNSATURATED KETONES

Publications (2)

Publication Number Publication Date
KR920701106A true KR920701106A (ko) 1992-08-11
KR950003331B1 KR950003331B1 (ko) 1995-04-10

Family

ID=17845832

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019910700748A KR950003331B1 (ko) 1989-11-17 1990-11-15 α,β-불포화 케톤의 합성방법

Country Status (9)

Country Link
EP (1) EP0454867B1 (ko)
JP (1) JP2830210B2 (ko)
KR (1) KR950003331B1 (ko)
AT (1) ATE117977T1 (ko)
AU (1) AU638769B2 (ko)
BR (1) BR9007030A (ko)
CA (1) CA2044618A1 (ko)
DE (1) DE69016647T2 (ko)
WO (1) WO1991007370A1 (ko)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH03161454A (ja) * 1989-11-17 1991-07-11 Nippon Soda Co Ltd β―ヒドロキシケトン類の製造方法
JP2789735B2 (ja) * 1989-11-17 1998-08-20 日本曹達株式会社 α，β―不飽和ケトン類の製法
SE0302827D0 (sv) * 2003-10-23 2003-10-23 Amersham Biosciences Ab Method for synthesis of acrylamide derivatives
JP4973210B2 (ja) * 2006-11-14 2012-07-11 東亞合成株式会社 新規合成方法
TW201437211A (zh) * 2013-03-01 2014-10-01 Bayer Pharma AG 經取代咪唑并嗒□

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS574930A (en) * 1980-05-02 1982-01-11 Nippon Soda Co Ltd Synthesis of alpha,beta-unsaturated ketone
EP0195053B1 (en) * 1984-09-27 1992-02-12 Chevron Research And Technology Company Process for preparing 1,3-cyclohexanedione derivatives and intermediates therefor
AU609560B2 (en) * 1988-01-07 1991-05-02 Sumitomo Chemical Company, Limited Beta-hydroxyketone and its production
JPH03161454A (ja) * 1989-11-17 1991-07-11 Nippon Soda Co Ltd β―ヒドロキシケトン類の製造方法

Also Published As

Publication number Publication date
KR950003331B1 (ko) 1995-04-10
ATE117977T1 (de) 1995-02-15
DE69016647D1 (de) 1995-03-16
BR9007030A (pt) 1991-12-24
JP2830210B2 (ja) 1998-12-02
JPH03161456A (ja) 1991-07-11
EP0454867A1 (en) 1991-11-06
AU6642590A (en) 1991-06-13
EP0454867B1 (en) 1995-02-01
AU638769B2 (en) 1993-07-08
CA2044618A1 (en) 1991-05-18
WO1991007370A1 (en) 1991-05-30
DE69016647T2 (de) 1995-05-24

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