KR910000224A - 메탄올 해리 촉매 - Google Patents
메탄올 해리 촉매 Download PDFInfo
- Publication number
- KR910000224A KR910000224A KR1019900009704A KR900009704A KR910000224A KR 910000224 A KR910000224 A KR 910000224A KR 1019900009704 A KR1019900009704 A KR 1019900009704A KR 900009704 A KR900009704 A KR 900009704A KR 910000224 A KR910000224 A KR 910000224A
- Authority
- KR
- South Korea
- Prior art keywords
- catalyst composition
- methanol
- catalyst
- weight
- weight percent
- Prior art date
Links
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 title claims 24
- 239000003054 catalyst Substances 0.000 title claims 15
- 238000010494 dissociation reaction Methods 0.000 title claims 2
- 230000005593 dissociations Effects 0.000 title claims 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 3
- 229910052804 chromium Inorganic materials 0.000 claims 3
- 239000011651 chromium Substances 0.000 claims 3
- 238000000034 method Methods 0.000 claims 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims 2
- 229910052788 barium Inorganic materials 0.000 claims 2
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims 2
- 229910052802 copper Inorganic materials 0.000 claims 2
- 239000010949 copper Substances 0.000 claims 2
- 229910052751 metal Inorganic materials 0.000 claims 2
- 239000002184 metal Substances 0.000 claims 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 1
- 229910052791 calcium Inorganic materials 0.000 claims 1
- 239000011575 calcium Substances 0.000 claims 1
- 229910052736 halogen Inorganic materials 0.000 claims 1
- 150000002367 halogens Chemical class 0.000 claims 1
- 150000004679 hydroxides Chemical class 0.000 claims 1
- 229910052749 magnesium Inorganic materials 0.000 claims 1
- 239000011777 magnesium Substances 0.000 claims 1
- 229910052748 manganese Inorganic materials 0.000 claims 1
- 239000011572 manganese Substances 0.000 claims 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims 1
- 229910052750 molybdenum Inorganic materials 0.000 claims 1
- 239000011733 molybdenum Substances 0.000 claims 1
- 229910052763 palladium Inorganic materials 0.000 claims 1
- 229910052707 ruthenium Inorganic materials 0.000 claims 1
- 229910052712 strontium Inorganic materials 0.000 claims 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims 1
- 239000011593 sulfur Substances 0.000 claims 1
- 229910052717 sulfur Inorganic materials 0.000 claims 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/885—Molybdenum and copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/72—Copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/86—Chromium
- B01J23/868—Chromium copper and chromium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/889—Manganese, technetium or rhenium
- B01J23/8892—Manganese
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/8926—Copper and noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/613—10-100 m2/g
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/22—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/22—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
- C01B3/24—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons
- C01B3/26—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons using catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/40—Carbon monoxide
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (13)
- 구리 20 내지 99.9중량% 및 무정형 실리카 0.1 내지 20중량%의 비융합 메탄올 해리 촉매를 함유함을 특징으로 하는 촉매 조성물.
- 제1항에 있어서, 추가로 크롬 5 내지 75중량%를 함유하는 촉매 조성물.
- 제1항 또는 제2항에 있어서, 추가로 마그네슘, 칼슘, 바륨, 스트론튬, 망간, 몰리브덴, 루테늄 및 팔라듐, 및 이들의 산화물 및 수산화물 중에서 선택된 하나이상의 금속을 함유하는 촉매 조성물.
- 제3항에 있어서, 무정형 실리카 2 내지 10중량%를 함유하는 촉매 조성물.
- 제4항에 있어서, 크롬 10 내지 45중량%를 함유하는 촉매 조성물.
- 제5항에 있어서, 바륨 1 내지 15중량%를 함유하는 촉매 조성물.
- 제5항에 있어서, 망간 1 내지 5중량%를 함유하는 촉매 조성물.
- 제7항에 있어서, 구리65 내지 75중량%, 크롬 20 내지 30중량%, 및 무정형 실리카 2 내지 4주량%를 함유하는 촉매 조성물.
- 제3항에 있어서, 하나 이상의 금속이 할로겐 또는 황을 함유하지 않는 촉매 조성물.
- 제1항, 2항 또는 3항에 있어서, 최소 표면적이 30㎡/g인 촉매 조성물.
- 메탄올을 해리시키는 방법에 있어서, 메탄올을 약 100 내지 약 400℃범위의 온도에서 제1항 또는 2항의 촉매와 접촉시킴을 특징으로 하는 개선된 방법.
- 메탄올을 해리시키는 방법에 있어서, 메탄올을 약 100 내지 약 400℃범위의 온도에서 제3항의 촉매와 접촉시킴을 특징으로 하는 개선된 방법.
- 메탄올을 해리시키는 방법에 있어서, 메탄올을 약 200 내지 약 300℃범위의 온도에서 제8항의 촉매와 접촉시킴을 특징으로 하는 개선된 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US37325389A | 1989-06-29 | 1989-06-29 | |
US373253 | 1989-06-29 | ||
US07/525,829 US5106810A (en) | 1989-06-29 | 1990-05-23 | Methanol dissociation catalysts |
US525829 | 1990-05-23 |
Publications (1)
Publication Number | Publication Date |
---|---|
KR910000224A true KR910000224A (ko) | 1991-01-29 |
Family
ID=27006114
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019900009704A KR910000224A (ko) | 1989-06-29 | 1990-06-29 | 메탄올 해리 촉매 |
Country Status (4)
Country | Link |
---|---|
US (1) | US5106810A (ko) |
EP (1) | EP0405958A1 (ko) |
KR (1) | KR910000224A (ko) |
CA (1) | CA2020176A1 (ko) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4239247A1 (de) * | 1992-11-21 | 1994-05-26 | Huels Chemische Werke Ag | Katalysator für ein Verfahren zur Herstellung von 4-Hydroxy-2.2.6.6-tetramethylpiperidin |
JP4032248B2 (ja) * | 2003-04-25 | 2008-01-16 | 本田技研工業株式会社 | 自動車排ガス浄化用燃焼触媒 |
US8404908B2 (en) * | 2009-10-13 | 2013-03-26 | Uop Llc | Process for lignin conversion to chemicals or fuels with H2 generated from lignin depolymerization products |
CN110577190A (zh) * | 2018-06-11 | 2019-12-17 | 河南车权健新能源科技有限公司 | 一种甲醇裂解制备氢气的工艺 |
CN110327933B (zh) * | 2019-07-25 | 2022-09-20 | 甄崇礼 | 二氧化碳加氢制备甲醇的催化剂及其制备方法和应用 |
Family Cites Families (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1939708A (en) * | 1927-06-28 | 1933-12-19 | Du Pont | Catalysts for the production of methanol and other carbon compounds |
US2010427A (en) * | 1933-01-14 | 1935-08-06 | Carbide & Carbon Chem Corp | Dehydrogenation of methanol |
NL260833A (ko) * | 1960-02-09 | |||
US3213145A (en) * | 1960-03-28 | 1965-10-19 | Standard Oil Co | Catalytic hydrogenation of esters of aromatic monocarboxylic acids to aryl-substituted methanols |
GB1010574A (en) * | 1963-04-23 | 1965-11-17 | British Petroleum Co | Production of hydrogen-containing gases |
FR93716E (fr) * | 1967-02-27 | 1969-05-09 | Melle Bezons | Catalyseurs d'hydrogenation et leur procede de preparation. |
DE1940412A1 (de) * | 1969-08-08 | 1971-04-29 | Degussa | Verfahren zur Herstellung feinteiliger,durch Metalloxid modifizierter Kieselsaeuren |
US3826758A (en) * | 1972-05-25 | 1974-07-30 | Grace W R & Co | Method of preparing exhaust catalyst |
DE2506348C3 (de) * | 1975-02-14 | 1980-07-17 | Bayer Ag, 5090 Leverkusen | Hydrierkatalysator |
IT1065295B (it) * | 1976-12-23 | 1985-02-25 | Snam Progetti | Processo per la produzione di dimetil etere e catalizzatore utilizzabile in detto processo |
GB1577069A (en) * | 1977-07-27 | 1980-10-15 | British Petroleum Co | Process for the production of synthesis gas by the catalysed decomposition of methanol |
CA1130265A (en) * | 1978-10-06 | 1982-08-24 | William J. Ball | Process for the production of amorphous aluminosilicates and their use as catalysts |
US4279781A (en) * | 1979-10-09 | 1981-07-21 | United Catalysts Inc. | Catalyst for the synthesis of methanol |
US4407238A (en) * | 1981-10-26 | 1983-10-04 | Conoco Inc. | Methanol dissociation using a copper-chromium-manganese catalyst |
NL8205027A (nl) * | 1982-12-29 | 1984-07-16 | Unilever Nv | Katalysator voor de methanolbereiding. |
ZA848604B (en) * | 1983-11-04 | 1985-06-26 | Veg Gasinstituut Nv | Process for the production of hydrogen |
BE898679A (fr) * | 1984-01-13 | 1984-05-02 | Grande Paroisse Azote Et Prod | Catalyseurs pour le reformage de l'ethanol, du methanol ou de leurs melanges en presence de vapeur d'eau |
US4826798A (en) * | 1988-03-04 | 1989-05-02 | E. I. Du Pont De Nemours And Company | Carbon dioxide calcination of methanol dissociation catalysts |
-
1990
- 1990-05-23 US US07/525,829 patent/US5106810A/en not_active Expired - Fee Related
- 1990-06-28 EP EP90307059A patent/EP0405958A1/en not_active Withdrawn
- 1990-06-29 CA CA002020176A patent/CA2020176A1/en not_active Abandoned
- 1990-06-29 KR KR1019900009704A patent/KR910000224A/ko not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
CA2020176A1 (en) | 1990-12-30 |
US5106810A (en) | 1992-04-21 |
EP0405958A1 (en) | 1991-01-02 |
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WITN | Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid |