KR900701891A - 자외선을 흡수하는 메틴 잔기가 함유되어 있는 축합 중합체 및 이것으로 제조된 성형 제품 - Google Patents

자외선을 흡수하는 메틴 잔기가 함유되어 있는 축합 중합체 및 이것으로 제조된 성형 제품

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Publication number
KR900701891A
KR900701891A KR1019900700800A KR900700800A KR900701891A KR 900701891 A KR900701891 A KR 900701891A KR 1019900700800 A KR1019900700800 A KR 1019900700800A KR 900700800 A KR900700800 A KR 900700800A KR 900701891 A KR900701891 A KR 900701891A
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KR
South Korea
Prior art keywords
composition
polyester
mol
unsubstituted
acid
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KR1019900700800A
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English (en)
Inventor
막스 알렌 위버
웨인 페이턴 프루엣
클레이렌스 앨빈 2세 코우티스
사무엘 데이비드 힐버트
Original Assignee
존 디. 후써
이스트만 코닥 컴퍼니
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by 존 디. 후써, 이스트만 코닥 컴퍼니 filed Critical 존 디. 후써
Publication of KR900701891A publication Critical patent/KR900701891A/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
    • C08G64/04—Aromatic polycarbonates
    • C08G64/045—Aromatic polycarbonates containing aliphatic unsaturation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
    • C08G63/688—Polyesters containing atoms other than carbon, hydrogen and oxygen containing sulfur
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
    • C08G63/688—Polyesters containing atoms other than carbon, hydrogen and oxygen containing sulfur
    • C08G63/6884—Polyesters containing atoms other than carbon, hydrogen and oxygen containing sulfur derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/6888—Polycarboxylic acids and polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

내용 없음

Description

자외선을 흡수하는 메틴 잔기가 함유되어 있는 축합 중합체 및 이것으로 제조된 성형 제품
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (14)

  1. 다음 구조식을 갖는 메턴 화합물 또는 메틸 화합물의 잔기가 공중합되어 있거나 또는 이러한 잔기와 반응하는 성형용 축합 중합체로 구성된 조성물.
    식중, R1은 비치환되었거나 치환된 알킬, 시클로알킬 또는 아릴 라디칼; A는 비치환되었거나 치환된 1,4-페닐렌 라디칼 R2는 수소 또는 비치환되었거나 치환된 알킬, 아케닐, 시클로알킬 또는 아릴 라디칼 및 R3는, 시아노 또는 비치환되었거나 치환된 카바모일, 알카노일, 아로일, 알킬설포닐, 아릴설포닐, 아릴 또는 방향족 복소환식 라디칼임.
  2. 제1항에 있어서, 중합체가 선형폴리에스테르이고 에틴 화합물이 다음 구조식을 갖는 조성물.
    식중, R1및 R2는 제1항에 정의된 바와 같고 R3는 시아노 또는및 R4는 수소 알킬, 알콕시 또는 할로겐임.
  3. 제1항에 있어서, 중합체가 선형 폴리에스테르이고 메틴 화합물이 다음 구조식을 갖는 조성물.
    식중, R1및 R2는 저급 알킬임.
  4. 제2항에 있어서, 폴리에스테르 산 부분이 최소한 약 50mol%의 테레프탈산 잔기로 구성되고 글리콜 부분이 최소한 약 50mol%의 에틸렌 글리콜이나 1,4-사이크로헥산디메탄을 잔기로 구성되는 조성물.
  5. 제3항에 있어서, 폴리에스테르가 약 75-100 mol%의 테레프탈산 잔기 및 약 75-100mol%의 에틸렌 달리콜 잔기로 구성되는 조성물.
  6. 재1항에 있어서, 중합체가 푸마르산이나 말레인산 또는 이것의 혼합물 및 약 60mol%까지의 O-프탈산, 이소프탈산, 또는 테레프탈산 또는 이것의 혼합물로 구성된 산 부분과 프로필렌 글리콜, 네오펜틸 글리콜, 2,2,4-트리메틸-1,3-펜탄디올, 에틸렌 글리콜 또는 디에틸렌 글리콜 또는 이것의 혼합물로 구성된 글리콜 부분을 갖는 불포화 폴리에스테르인 조성물.
  7. 제6항에 있어서, 산 부분이 약 1/2 내지 약 2/1mole비율인 약 75-100mol%의 O-프탈산과 말레인산으로 구성되고 글리콜 부분이 약 75-100mol%의 프로필렌 글리콜로 구성되는 조성물.
  8. 섬유 중량에 기초하여 약 0.01-5.0중량%의 분산 염료로 염색된 제2항의 조성물로 만들어진 섬유.
  9. 제2항의 조성물로 만들어진 성형 제품.
  10. 제4항의 조성물로 만들어진 성형 제품.
  11. 제5항의 조성물로 제조된 용기.
  12. 최소한 하나의 디카복실산, 또는 이것의 에스테르 형성 물질과 최소한 하나의 디올을 200-300℃온도 및 444.7-0.53kPa 압력에서 고유점도가 0.4-1.2인 폴리에스테르가 얻어질때까지 반응시키며 반응이 다음 구조식을 갖는 메틴 화합물 또는 메틴 화합물의 혼합물 내에서 행헤지는 것으로 특징지어지는, 성형용 폴리에스테르를 제조하는 방법.
    식중, R1은 비치환되었거나 치환된 알킬, 시클로알킬 또는 아릴 라니칸: A는 비치환되었거나 치환된 1,4-페닐렌 라디칼 R2는 수소 또는 비치환되었거나 치환된 알킬, 알케닐, 시클로알킬 또는 아릴 라디칼 및 R3는시아노 또는 비치환되었거나 치환된 카바모일, 알카노일, 아로일, 알킬설포닐, 아릴설포닐, 아릴 또는 방향족 복소환식 라디칼임.
  13. 제12항에 있어서, 폴리에스테르는 산 부분이 최소한 50몰%의 테레프탈산 잔기로 구성되고 달리콜 부분이 최소한 50몰%의 에틸렌 글리코 또는 1,4-시클로헥산디메탄을 잔기로 구성되는 선형 폴리에스테르이며 에턴 화합물이 다음 구조식을 갖는 것으로 특징되는 방법.
    식중, R1및 R2는 제12항에 정의된 바와 같고 R3는 시아노 또는및 R4는 수소, 알킬, 알콕시 또는 할로겐임.
  14. 12항에 있어서, 폴리에스테르가 75-100몰%의 테레프탈산 잔기 및 75-100몰%의 에틸렌글리콜 잔기로 구성되며 메틴 화합물이 다음 구조식을 갖는 방법.
    식중, R1및 R2는 제12항에 정의된 바와 같고 R3는 시아노 또는및 R4는 수소, 알킬, 알콕시 또는 할로겐임.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019900700800A 1988-08-19 1989-08-10 자외선을 흡수하는 메틴 잔기가 함유되어 있는 축합 중합체 및 이것으로 제조된 성형 제품 KR900701891A (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US07/233,790 US4845188A (en) 1988-08-19 1988-08-19 Condensation polymers containing methine ultraviolet radiation-absorbing residues and shaped articles produced therefrom
US233,790 1988-08-19
PCT/US1989/003420 WO1990002147A1 (en) 1988-08-19 1989-08-10 Condensation polymers containing methine ultraviolet radiation-absorbing residues and shaped articles produced therefrom

Publications (1)

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KR900701891A true KR900701891A (ko) 1990-12-04

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Country Status (8)

Country Link
US (1) US4845188A (ko)
EP (2) EP0356350A1 (ko)
JP (1) JPH04500228A (ko)
KR (1) KR900701891A (ko)
CN (1) CN1040599A (ko)
AU (1) AU620150B2 (ko)
TR (1) TR24000A (ko)
WO (1) WO1990002147A1 (ko)

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Also Published As

Publication number Publication date
US4845188A (en) 1989-07-04
JPH04500228A (ja) 1992-01-16
WO1990002147A1 (en) 1990-03-08
AU4207689A (en) 1990-03-23
AU620150B2 (en) 1992-02-13
EP0356350A1 (en) 1990-02-28
CN1040599A (zh) 1990-03-21
EP0429540A1 (en) 1991-06-05
TR24000A (tr) 1991-01-15

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