KR890010273A - 금속표면의인산처리방법 - Google Patents

금속표면의인산처리방법 Download PDF

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Publication number
KR890010273A
KR890010273A KR1019880016866A KR880016866A KR890010273A KR 890010273 A KR890010273 A KR 890010273A KR 1019880016866 A KR1019880016866 A KR 1019880016866A KR 880016866 A KR880016866 A KR 880016866A KR 890010273 A KR890010273 A KR 890010273A
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South Korea
Prior art keywords
ions
solution
zinc
tungsten
phosphate
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KR1019880016866A
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English (en)
Inventor
마사히로 죠오
야쓰다께 미노
다까마사 시미즈
아끼오 도꾸야마
고우에쓰 엔도오
다모쯔 소바다
Original Assignee
사사끼 가즈오
닛뽄 페이트 가부시끼가이샤
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Priority claimed from JP32173787A external-priority patent/JPH01162780A/ja
Priority claimed from JP6527188A external-priority patent/JPH01240671A/ja
Application filed by 사사끼 가즈오, 닛뽄 페이트 가부시끼가이샤 filed Critical 사사끼 가즈오
Publication of KR890010273A publication Critical patent/KR890010273A/ko

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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/07Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/40Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing molybdates, tungstates or vanadates
    • C23C22/42Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing molybdates, tungstates or vanadates containing also phosphates

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  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Chemical Treatment Of Metals (AREA)

Abstract

내용 없음

Description

금속표면의 인산처리방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (16)

  1. 텅스텐으로서 약 0.01 내지 20.0g/1의 가용성 텅스텐화합물로 이루어진 수성의 산 아연-인산처리용액과 금속표면을 접촉시키는 것을 특징으로 하는 금속표면의 아연 인산처리 방법.
  2. 제 1 항에 있어서, 수성의 산용액이 (a) 아연이온 약 0.1 내지 2.0g/1, (b) 인산이온 약 5 내지 40g/1, (c) 텅스텐화합물의 텅스텐으로서 약 0.01 내지 20.0g/1, 및 (d) 전환 피복 촉진제로 이루어진 것을 특징으로 하는 방법.
  3. 제 1 항에 있어서, 가용성 텅스텐 화합물이 다음이 적어도 하나인 것을 특징으로 하는 방법 : (1) 알칼리금속 텅스테이트, (2) 텅스텐산 암모늄, (3) 보로텅스텐산, (4) 실리코팅스텐산, (5) 알칼리금속 실리코팅스테이트, (6) 실리코팅스텐산 암모늄, 및 (7) 알칼리토금속 실리코팅스테이트.
  4. 제 3 항에 있어서, 가용성 텅스텐 화합물이 다음의 적어도 하나인 것을 특징으로 한느 방법 : 실리코팅스텐산, 알칼리금속 실리코팅스테이트, 암모늄 실리코팅스테이트, 및 알칼리토금속 실리코팅스테이트.
  5. 제 2 항에 있어서, (d)중의 전환피복 촉진제가 다음의 적어도 하나로부터 선택되는 것을 특징으로 하는 방법 : (1) 아질산이온 약 0.01 내지 0.5g/1, (2)m-니트로벤젠 술포네이트이온 약 0.05 내지 5g/1, 및 (3) 과산화수소 약 0.5 내지 10g/1.
  6. 제 1 항에 있어서, 상기 용액이 또한 다음의 적어도 하나를 함유하는 것을 특징으로 하는 방법 : (4) 망간이온 약 약 0.1 내지 3g/1, (5) 니켈이온 약 0.1 내지 4g/1, (6) 플루오르화이온 약 0.05 내지 4g/1, 및 (7) 질산이온 약 0.1 내지 15g/1.
  7. 제 1 항 내지 제 6항중의 어느 하나에 있어서, 상기 접촉이 금속표면을 용액중에 침지시킴으로써 시행되는 것을 특징으로 하는 방법.
  8. 제 1 항 내지 제6항중의 어느 하나에 있어서, 상기 접촉이 금속표면에 용액을 스프레이함으로써 시행되는 것을 특징으로 하는 방법.
  9. 제 1 항 내지 제6항중의 어느 하나에 있어서, 상기 접촉이 침지 및 스프레이처리를 병용함으로써 시행되는 것을 특징으로 하는 방법.
  10. 제 7 항 또는 제 9 항에 있어서, 상기 용액이 또한 약 0.05 내지 2g/1의 염소산 이온을 함유하는 것을 특징으로 하는 방법.
  11. 제 8 항 또는 제 9 항에 있어서, 상기 용액이 또한 약 2 내지 5.0g/1의 염소산 이온을 함유하는 것을 특징으로 하는 방법.
  12. 제11항에 있어서, 약 0.4 내지 1.3g/1의 아연이온이 존재하는 것을 특징으로 하는 방법.
  13. 제 1 항에 있어서, 금속표면이 다음의 어느 하나인 것을 특징으로 하는 방법 : 철-기재 표면, 아연-기재표면, 및 이들의 결합.
  14. 수성의 산 아연-인산처리용액의 처방에 사용되는 수성 농축조성물에 있어서, 아연이온, 인산이온 및 가용성 텅스텐화합물 형태의 텅스텐의 중량비가 1:2.5 내지 400:0.005 내지 200으로 이루어진 성분(A)와, 전환피부 촉진제를 함유하는 성분(B)로 구성된 것을 특징으로 하는 상기 농축 조성물.
  15. 제14항에 있어서, 가용성 텅스텐화합물 형태의 텅스텐이 상기 성분(b)에 포함되는 것을 특징으로 하는 수성 농축 조성물.
  16. (a) 아연이온 약 0.1 내지 2.0g/1, (b) 인산이온 약 5 내지 40g/1, (c) 가용성 텅스텐화합물의 텅스텐으로서 약 0.01 내지 20.0g/1, 및 (d) 전환피복 촉진제로 이루어진 수성 산용액으로 금속표면을 처리함으로써 얻어지는 것을 특징으로 하는 인산처리된 금속.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880016866A 1987-12-18 1988-12-17 금속표면의인산처리방법 KR890010273A (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP32173787A JPH01162780A (ja) 1987-12-18 1987-12-18 塗装用金属表面のリン酸亜鉛処理方法
JP62-321737 1987-12-18
JP63-65271 1988-03-17
JP6527188A JPH01240671A (ja) 1988-03-17 1988-03-17 塗装用金属表面のリン酸亜鉛処理方法

Publications (1)

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KR890010273A true KR890010273A (ko) 1989-08-07

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US (1) US5039363A (ko)
EP (1) EP0321059B1 (ko)
KR (1) KR890010273A (ko)
AU (1) AU610313B2 (ko)
CA (1) CA1333683C (ko)
DE (1) DE3875459T2 (ko)
ES (1) ES2092983T3 (ko)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100597759B1 (ko) * 1998-04-16 2006-07-05 니혼 파커라이징 가부시키가이샤 금속의 표면처리 방법 및 이 표면처리 방법으로 얻어진 표면을 가진 금속부재

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JP3392008B2 (ja) 1996-10-30 2003-03-31 日本表面化学株式会社 金属の保護皮膜形成処理剤と処理方法
JPH0696773B2 (ja) * 1989-06-15 1994-11-30 日本ペイント株式会社 金属表面のリン酸亜鉛皮膜形成方法
US5792283A (en) * 1993-09-06 1998-08-11 Henkel Kommanditgesellschaft Auf Aktien Nickel-free phosphating process
US5653790A (en) * 1994-11-23 1997-08-05 Ppg Industries, Inc. Zinc phosphate tungsten-containing coating compositions using accelerators
DE19500927A1 (de) * 1995-01-16 1996-07-18 Henkel Kgaa Lithiumhaltige Zinkphosphatierlösung
DE19511573A1 (de) * 1995-03-29 1996-10-02 Henkel Kgaa Verfahren zur Phosphatierung mit metallhaltiger Nachspülung
DE19541285C2 (de) * 1995-11-06 2003-04-17 Kluthe Gmbh Chem Werke Verfahren und Mittel zur Phosphatierung von Metalloberflächen
DE19834796A1 (de) 1998-08-01 2000-02-03 Henkel Kgaa Verfahren zur Phosphatierung, Nachspülung und kathodischer Elektrotauchlackierung
US6391384B1 (en) * 2000-07-10 2002-05-21 Carus Corporation Method for providing a corrosion inhibiting solution
US10611986B1 (en) 2018-03-15 2020-04-07 Earthcare Labs, Llc Cleaning composition comprising a cationic/nonionic mixture

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US2502441A (en) * 1946-11-22 1950-04-04 Oakite Prod Inc Phosphate coating of metals
FR1092299A (fr) * 1953-03-27 1955-04-20 Parker Ste Continentale Revêtements noirs pour métaux et leur procédé d'obtention
US2854369A (en) * 1957-10-04 1958-09-30 Oakite Prod Inc Increasing the solubility of metal accelerators in phosphatizing solutions
US3261723A (en) * 1962-11-30 1966-07-19 Lubrizol Corp Method for reducing combustion chamber deposits in internal combustion engines
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CA1133806A (en) * 1978-05-08 1982-10-19 George D. Howell Detergent phosphatizer composition and method of using same
DE2905535A1 (de) * 1979-02-14 1980-09-04 Metallgesellschaft Ag Verfahren zur oberflaechenbehandlung von metallen
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100597759B1 (ko) * 1998-04-16 2006-07-05 니혼 파커라이징 가부시키가이샤 금속의 표면처리 방법 및 이 표면처리 방법으로 얻어진 표면을 가진 금속부재

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Publication number Publication date
DE3875459T2 (de) 1993-03-25
US5039363A (en) 1991-08-13
EP0321059B1 (en) 1992-10-21
AU610313B2 (en) 1991-05-16
AU2702388A (en) 1989-06-22
ES2092983T3 (es) 1996-12-16
CA1333683C (en) 1994-12-27
EP0321059A1 (en) 1989-06-21
DE3875459D1 (de) 1992-11-26

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