KR890008112A - 피리미딘 유도체, 그의 제조방법 및 제초조성물 - Google Patents
피리미딘 유도체, 그의 제조방법 및 제초조성물 Download PDFInfo
- Publication number
- KR890008112A KR890008112A KR1019880014516A KR880014516A KR890008112A KR 890008112 A KR890008112 A KR 890008112A KR 1019880014516 A KR1019880014516 A KR 1019880014516A KR 880014516 A KR880014516 A KR 880014516A KR 890008112 A KR890008112 A KR 890008112A
- Authority
- KR
- South Korea
- Prior art keywords
- group
- formula
- alkyl group
- lower alkyl
- pyrimidine derivative
- Prior art date
Links
- 150000003230 pyrimidines Chemical class 0.000 title claims 15
- 230000002363 herbicidal effect Effects 0.000 title claims 4
- 229940083082 pyrimidine derivative acting on arteriolar smooth muscle Drugs 0.000 title claims 2
- 238000002360 preparation method Methods 0.000 title 1
- 125000000217 alkyl group Chemical group 0.000 claims 14
- 150000003839 salts Chemical class 0.000 claims 11
- 150000001875 compounds Chemical class 0.000 claims 7
- 125000005843 halogen group Chemical group 0.000 claims 7
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 7
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 claims 4
- -1 alkaline earth metal salt Chemical class 0.000 claims 3
- 125000004183 alkoxy alkyl group Chemical group 0.000 claims 3
- 125000003545 alkoxy group Chemical group 0.000 claims 3
- 125000006515 benzyloxy alkyl group Chemical group 0.000 claims 3
- 125000005078 alkoxycarbonylalkyl group Chemical group 0.000 claims 2
- 125000004966 cyanoalkyl group Chemical group 0.000 claims 2
- 229910052736 halogen Inorganic materials 0.000 claims 2
- 239000004009 herbicide Substances 0.000 claims 2
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 2
- QEGVVEOAVNHRAA-UHFFFAOYSA-N 2-chloro-6-(4,6-dimethoxypyrimidin-2-yl)sulfanylbenzoic acid Chemical group COC1=CC(OC)=NC(SC=2C(=C(Cl)C=CC=2)C(O)=O)=N1 QEGVVEOAVNHRAA-UHFFFAOYSA-N 0.000 claims 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims 1
- 125000004390 alkyl sulfonyl group Chemical group 0.000 claims 1
- 229910052801 chlorine Inorganic materials 0.000 claims 1
- 125000001309 chloro group Chemical group Cl* 0.000 claims 1
- 239000012954 diazonium Substances 0.000 claims 1
- 150000001989 diazonium salts Chemical class 0.000 claims 1
- 125000001153 fluoro group Chemical group F* 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- 229910052723 transition metal Inorganic materials 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
- C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
- C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
- C07D239/28—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
- C07D239/32—One oxygen, sulfur or nitrogen atom
- C07D239/38—One sulfur atom
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
- C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
- C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
- C07D239/28—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
- C07D239/46—Two or more oxygen, sulphur or nitrogen atoms
- C07D239/60—Three or more oxygen or sulfur atoms
Landscapes
- Organic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Plural Heterocyclic Compounds (AREA)
- Catching Or Destruction (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (12)
- 다음식의 피리미딘 유도체 또는 그의 염.식중, X는 할로겐원자, 저급 알킬기 또는 페녹시기(이중에서 페녹시기는 할로겐, 저급알킬 또는 저급알콕시기에 의하여 치환가능하다)이고 R은 수소원자, 저급알킬기, 알콕시 알킬기, 벤질옥시알킬기, 알콕시카르보닐 알킬기, 시아노 알킬기 또는(이중 R1은 수소원자 또는 저급알킬기이고 R2는 저급알킬기 또는 니트로에 의해 치환가능한 페닐기).
- 제 1 항에 있어서, X은 6위치에 치환된 것을 특징으로하는 피리미딘 유도체.
- 제 1 항에 있어서, R은 수소원자, 저급알킬기, 알콕시알킬기 또는 벤질옥시알킬기 인것을 특징으로하는 피리미딘 유도체.
- 제 1 항에 있어서, 피리미딘 유도체가 다음 식 또는 그의염인 것을 특징으로하는 피리미딘 유도체.식중, R은 청구범위 1에서와 같이 정의되며 X는 할로겐 원자 또는 저급 알킬기.
- 제 1 항에 있어서, 염이 알킬리 금속염, 알칼리토류금속염, 전이금속염 또는 유기암모늄염인것을 특징으로하는 피리미딘 유도체.
- 제 1 항에 있어서, 피리미딘 유도체가 다음 식 또는 그의 염인 것을 특징으로하는 리미딘 유도체.식중, R은 청구범위 1에서와 같이 정의되며 Y는 수소원자, 할로겐원자, 저급알킬기 또는 저급알콕시기.
- 제 1 항에 있어서, R이 수소원자인 것을 특징으로하는 피리미딘 유도체.
- 제 1 항에 있어서, 피리미딘 유도체가 2-클로로-6-[(4,6-디메톡시피리미딘-2-일)티오]벤조산 또는 그의 염인것을 특징으로하는 피리미딘 유도체.
- 제 1 항에 있어서, X는 6-위치에서 염소원자, 메틸기 또는 플루오로 원자인 것을 특징으로하는 피리미딘 유도체.
- 식(Ⅰ)인 피리미딘 유도체 또는 그의 염의 제초제로서의 유효량과 농업적 보조제로 이루어진 제초조성물.
- 제 1 항에서 정의된 식(Ⅰ)인 피리미딘 유도체 또는 그의 염의 제초제로서의 유효량을 보호될 장소에 적용하는 것으로 이루어진 제조방법.
- 다음식인 피리미딘 유도체 또는 그의 염의 제조방법으로서 ;(식중 X는 할로겐원자, 저급 알킬기 또는 페녹시기(그중에서 상기 페녹시기는 할로겐, 저급알킬 또는 저급알콕시에 의하여 치환가능)이고 R은 수소원자, 저급알킬기, 알콕시알킬기, 벤질옥시알킬기, 알콕시카르보닐 알킬기, 시아노알킬기 또는기(식중 R1은 수소원자 또는 저급알킬기이고 R2는 저급알킬기 또는 니트로기에 의해 치환가능한 페닐기)X 및 R이 이와같이 정의되는 식(Ⅱ)인 화합물을,Y1가 할로겐 원자, 알킬술포닐기, 치환 또는 비치환된 벤질 술포닐기인 식(Ⅲ)과 반응시켜서 식(Ⅰ)인 화합물을 수득하거나 ;또는 X와 R이 위와같이 정의되는 식(Ⅳ)인 화합물을,X와 R이 위와같이 정의되는 식(Ⅴ)인 디아조늄염으로 전환시킨 다음식(Ⅳ)인 화합물과 반응시켜서식(Ⅰ)인 화합물을 수득하고 ; 선택적으로는 식(Ⅰ)인 화합물을 염기와 반응시켜서 식(Ⅰ)인 화합물의 염을 수득하는 것으로 이루어진 제조방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP27889487 | 1987-11-04 | ||
JP62-278894 | 1987-11-04 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR890008112A true KR890008112A (ko) | 1989-07-08 |
KR960012178B1 KR960012178B1 (ko) | 1996-09-16 |
Family
ID=17603582
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019880014516A KR960012178B1 (ko) | 1987-11-04 | 1988-11-04 | 피리미딘 유도체, 그의 제조방법, 제초방법 및 제초조성물 |
Country Status (11)
Country | Link |
---|---|
US (2) | US4923501A (ko) |
EP (1) | EP0315889B1 (ko) |
KR (1) | KR960012178B1 (ko) |
CN (1) | CN1025981C (ko) |
AU (1) | AU611219B2 (ko) |
BR (1) | BR8805749A (ko) |
DE (1) | DE3855427T2 (ko) |
GR (1) | GR3021341T3 (ko) |
RU (2) | RU2024227C1 (ko) |
TR (1) | TR28607A (ko) |
UA (1) | UA21892A (ko) |
Families Citing this family (41)
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ES2063075T3 (es) * | 1988-06-16 | 1995-01-01 | Basf Ag | Derivados del acido salicilico y sus analogos azufrados. |
US6107248A (en) * | 1988-12-29 | 2000-08-22 | Anderson; Richard J. | Potentiating herbicidal compositions of auxin transport inhibitors and growth regulators |
US5665673A (en) * | 1988-12-29 | 1997-09-09 | Anderson; Richard J. | Potentiating herbicidal compositions |
WO1991005781A1 (de) * | 1989-10-12 | 1991-05-02 | Dr. R. Maag Ag | Pyrimidin- und triazin-derivate mit herbizider und pflanzenwachstumsregulierender wirkung |
US5125957A (en) * | 1989-11-01 | 1992-06-30 | Sumitomo Chemical Company, Limited | Pyrimidine derivatives |
BR9006558A (pt) * | 1989-12-26 | 1991-10-01 | Mitsui Toatsu Chemicals | Derivado de piridiloxipirimidina e processo para a sua preparacao,processos para a preparacao de 2-(2-formil-3-piridiloxi)-4,6-dimetoxipirimidina e de 3-(2-pirimidiniloxi)-2-piridinocarboxaldeido acetal,e composicao herbicida |
DE4002365A1 (de) * | 1990-01-25 | 1991-08-01 | Schering Ag | Substituierte (beta)-pyrimidinyloxy(thio)- und (beta)-triazinyloxy(thio)cycloalkylcarbonsaeurederivate, verfahren zu ihrer herstellung und ihre verwendung als mittel mit herbizider, fungizider und pflanzenwachstumsregulierender wirkung |
AU7324291A (en) * | 1990-02-20 | 1991-09-18 | Fmc Corporation | 6-aryl-2-substituted benzoic acid herbicides |
US5232897A (en) * | 1990-05-15 | 1993-08-03 | Sumitomo Chemical Company, Limited | Herbicidal pyrimidine compounds, compositions containing the same and method of use |
US5298632A (en) * | 1990-05-15 | 1994-03-29 | Sumitomo Chemical Company, Limited | Herbicidal pyrimidine compounds, compositions containing the same and method of use |
JPH04235171A (ja) * | 1990-07-26 | 1992-08-24 | Sumitomo Chem Co Ltd | スルホヒドロキサム酸誘導体、その製造法およびそれを有効成分とする除草剤 |
US5506192A (en) * | 1990-06-07 | 1996-04-09 | Sandoz Ltd. | Substituted phthalides and heterocyclic phthalides |
DE4021441A1 (de) * | 1990-07-05 | 1992-01-09 | Bayer Ag | Substituierte acrylophenone |
AU638840B2 (en) * | 1990-07-05 | 1993-07-08 | Sumitomo Chemical Company, Limited | Pyrimidine derivative |
AU642753B2 (en) * | 1990-07-24 | 1993-10-28 | Mitsubishi Petrochemical Company Limited | Halogen-containing compounds, herbicidal composition containing the same as an active ingredient, and intermediary compounds therefor |
CA2053603A1 (en) * | 1990-10-19 | 1992-04-20 | Katsumasa Harada | 3-alkoxyalkanoic acid derivative, process for preparing the same and herbicide using the same |
IL100428A0 (en) * | 1990-12-21 | 1992-09-06 | Ciba Geigy | Pyrimidinyl-and triazinyl-salicylamides,their preparation and their use as herbicides and plant growth regulants |
DE4208254A1 (de) * | 1992-03-14 | 1993-09-16 | Hoechst Ag | Substituierte pyrimidine, verfahren zu ihrer herstellung und ihre verwendung als schaedlingsbekaempfungsmittel und fungizid |
EP0608862A1 (en) * | 1993-01-27 | 1994-08-03 | Lucky Ltd. | Novel 6-chloro-2-(4,6-dimethoxypyrimidin-2-yl) oxybenzoic acid ester derivatives, processes for their production an a method for their application as herbicides |
US5895774A (en) * | 1993-02-18 | 1999-04-20 | Fenderson; John M. | Herbicidal compositions comprising dimethenamid and ethofumesate |
US5877115A (en) * | 1993-02-18 | 1999-03-02 | Sandoz Ltd. | Dicamba and dimethenamid synergistic herbicidal compositions |
US5716901A (en) * | 1993-02-18 | 1998-02-10 | Sandoz Ltd. | Synergistic herbicidal compositions of dimethenamid, sulcotrione, and atrazine |
ES2207637T3 (es) | 1993-02-18 | 2004-06-01 | Basf Aktiengesellschaft | Composiciones herbicidas. |
US5721191A (en) * | 1993-02-18 | 1998-02-24 | Sandoz Ltd. | Synergistic herbicidal compositions of dimethenamid and sulfonylureas |
DE4337321A1 (de) * | 1993-11-02 | 1995-05-04 | Basf Ag | Cyclische Acetale, Verfahren zu deren Herstellung und deren Umsetzung zu Pflanzenschutzmitteln |
US5977024A (en) * | 1997-11-03 | 1999-11-02 | Basf Corporation | Mixtures and methods for suppressing precipitation of chloroacetamides |
TWI220428B (en) | 1999-02-05 | 2004-08-21 | Syngenta Participations Ag | Method of producing thiobarbituric acid derivatives |
US7615575B2 (en) | 2003-02-13 | 2009-11-10 | Wellstat Therapeutics Corporation | Compounds for the treatment of metabolic disorders |
CN100381427C (zh) * | 2005-09-02 | 2008-04-16 | 浙江化工科技集团有限公司 | 苄胺类化合物、制备方法及其用途 |
US7820721B2 (en) | 2006-01-25 | 2010-10-26 | Wellstat Therapeutics Corporation | Compounds for the treatment of metabolic disorders |
CA2637373A1 (en) | 2006-01-25 | 2007-08-02 | Wellstat Therapeutics Corporation | Compounds for the treatment of metabolic disorders |
AU2007212104A1 (en) | 2006-02-02 | 2007-08-16 | Wellstat Therapeutics Corporation | Compounds for the treatment of metabolic disorders |
EP2052608A1 (de) | 2007-10-24 | 2009-04-29 | Bayer CropScience AG | Herbizid-Kombination |
DE102008037631A1 (de) | 2008-08-14 | 2010-02-18 | Bayer Cropscience Ag | Herbizid-Kombination mit Dimethoxytriazinyl-substituierten Difluormethansulfonylaniliden |
PT2627183T (pt) | 2010-10-15 | 2017-12-11 | Bayer Ip Gmbh | Utilização de herbicidas inibidores de als para controlo de vegetação indesejada em plantas beta vulgaris tolerantes a inibidor de als |
CN102037970A (zh) * | 2011-01-25 | 2011-05-04 | 青岛瀚生生物科技股份有限公司 | 一种含有嘧草硫醚的农药剂型 |
UA117447C2 (uk) | 2011-05-04 | 2018-08-10 | Байєр Інтеллектуал Проперті Гмбх | Застосування гербіцидів інгібіторів als для боротьби з небажаною рослинністю на площі вирощування brassica |
LT2931034T (lt) | 2012-12-13 | 2018-10-10 | Bayer Cropscience Ag | Als slopinančių herbicidų panaudojimas nepageidaujamos augmenijos kontrolei augaluose beta vulgaris, kurie tolerantiški als slopinantiems herbicidams |
CN103039454B (zh) * | 2013-01-22 | 2014-12-03 | 南京高正农用化工有限公司 | 一种嘧草硫醚与百草枯除草组合物及其应用 |
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AR127377A1 (es) | 2021-10-15 | 2024-01-17 | Kws Saat Se & Co Kgaa | Mutantes de beta vulgaris tolerantes a herbicidas inhibidores de als |
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NZ188244A (en) * | 1977-09-13 | 1981-04-24 | Ici Australia Ltd | 2-substituted pyrimidines compositions growth regulating processes |
JPH0651684B2 (ja) * | 1985-10-15 | 1994-07-06 | クミアイ化学工業株式会社 | ピリミジン誘導体および除草剤 |
DE3644799A1 (de) * | 1986-06-04 | 1987-12-10 | Hoechst Ag | Neue pyrimidin-derivate, deren herstellung und verwendung |
JPH082883B2 (ja) * | 1986-06-06 | 1996-01-17 | クミアイ化学工業株式会社 | 2−フエノキシピリミジン誘導体および除草剤 |
US4889552A (en) * | 1987-04-14 | 1989-12-26 | Kumiai Chemical Industry Co., Ltd. | 2-Phenoxypyrimidine derivative and herbidical composition |
ES2063075T3 (es) * | 1988-06-16 | 1995-01-01 | Basf Ag | Derivados del acido salicilico y sus analogos azufrados. |
-
1988
- 1988-10-28 US US07/264,015 patent/US4923501A/en not_active Expired - Lifetime
- 1988-11-02 EP EP88118254A patent/EP0315889B1/en not_active Expired - Lifetime
- 1988-11-02 DE DE3855427T patent/DE3855427T2/de not_active Expired - Lifetime
- 1988-11-03 TR TR00785/88A patent/TR28607A/xx unknown
- 1988-11-03 RU SU884356788A patent/RU2024227C1/ru active
- 1988-11-03 UA UA4356788A patent/UA21892A/uk unknown
- 1988-11-04 KR KR1019880014516A patent/KR960012178B1/ko not_active IP Right Cessation
- 1988-11-04 CN CN88107663A patent/CN1025981C/zh not_active Expired - Lifetime
- 1988-11-04 AU AU24717/88A patent/AU611219B2/en not_active Expired
- 1988-11-04 BR BR888805749A patent/BR8805749A/pt not_active IP Right Cessation
-
1989
- 1989-10-02 US US07/415,871 patent/US4932999A/en not_active Expired - Lifetime
-
1992
- 1992-06-30 RU SU925011920A patent/RU2049781C1/ru active
-
1996
- 1996-10-15 GR GR960402714T patent/GR3021341T3/el unknown
Also Published As
Publication number | Publication date |
---|---|
EP0315889A2 (en) | 1989-05-17 |
RU2024227C1 (ru) | 1994-12-15 |
EP0315889A3 (en) | 1990-07-25 |
US4923501A (en) | 1990-05-08 |
DE3855427D1 (de) | 1996-08-22 |
GR3021341T3 (en) | 1997-01-31 |
TR28607A (tr) | 1996-11-15 |
US4932999A (en) | 1990-06-12 |
DE3855427T2 (de) | 1996-12-05 |
AU611219B2 (en) | 1991-06-06 |
RU2049781C1 (ru) | 1995-12-10 |
BR8805749A (pt) | 1989-07-18 |
KR960012178B1 (ko) | 1996-09-16 |
EP0315889B1 (en) | 1996-07-17 |
UA21892A (uk) | 1998-04-30 |
CN1033050A (zh) | 1989-05-24 |
CN1025981C (zh) | 1994-09-28 |
AU2471788A (en) | 1989-05-04 |
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