KR880000066B1 - Apparatus for manufacturing substituting oil of heavy oil - Google Patents

Apparatus for manufacturing substituting oil of heavy oil Download PDF

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KR880000066B1
KR880000066B1 KR1019850003229A KR850003229A KR880000066B1 KR 880000066 B1 KR880000066 B1 KR 880000066B1 KR 1019850003229 A KR1019850003229 A KR 1019850003229A KR 850003229 A KR850003229 A KR 850003229A KR 880000066 B1 KR880000066 B1 KR 880000066B1
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oil
catalyst
substitute
impeller
present
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KR1019850003229A
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KR860009102A (en
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김재훈
박위만
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주식회사 삼아상역
정남훈 · 김재훈
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G31/00Refining of hydrocarbon oils, in the absence of hydrogen, by methods not otherwise provided for
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/32Liquid carbonaceous fuels consisting of coal-oil suspensions or aqueous emulsions or oil emulsions

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)

Abstract

In an apparatus for chemically combining natural water with heavy oils such as bunker (A), (B) or (C) oil to produce a substitute oil, there are provided with a steam coil (3), a screw impeller (8) with perforations (8-1) of 1/10 open area of the total impeller surface area, a round aluminum tube spray unit (9) with perforations (9-1) and with as many weight balls (9-2) within the tube, a heat- dissolving unit for catalyst with recrystalizing unit, basic oil supplies (B) and (C), and a purifier (D) for separating the produced oil by means of differential liquid pressures.

Description

중질유계 대체유의 제조 장치Manufacturing apparatus of heavy oil substitute oil

제1도는, 본 발명의 전제장치를 결합한 사시도.1 is a perspective view of the combination of the premise device of the present invention.

제2도는, 본 발명의 촉매제를 가온함과 동시 용해하는 장치(A기)의 일부 절개 정면도.FIG. 2 is a partially cutaway front view of the apparatus (Group A) which simultaneously melts and heats the catalyst of the present invention.

제2a도는, (A), (B), (C)기에 내장된 임페라의 확대 사시도.Fig. 2A is an enlarged perspective view of the impeller built in the (A), (B) and (C) groups.

제3도는, 기초유 조성기(B)의 일부 절개 정면도.3 is a partially cutaway front view of the base oil composition group (B).

제3a도는, 수용시킨 촉매제의 살포 장치(C)의 확대 사시도.FIG. 3A is an enlarged perspective view of the spreading device C of the contained catalyst.

제3b도는, 제3a도의 a-a선 단면 내부도.FIG. 3B is a cross-sectional internal view of the a-a line in FIG. 3A.

제4도는, 대체유 조성기(C)의 일부 절개 정면도.4 is a partially cutaway front view of the replacement oil forming machine (C).

제5도는 순화기(D)의 단면도.5 is a cross-sectional view of the purifier (D).

제5a도는 제5도의 원판임페라의 측면도이다.FIG. 5A is a side view of the disc impeller of FIG.

본 발명은 유전지질층의 구조중 필수적으로 구성된 단수층에 부존하는 단수의 주성분을 인공적으로 조성 농축한 것을 촉매제로 하여 중질유, 특히 방카 A, B, C유 등에 자연수를 화합적으로 결수시켜 대체유를 제조하는 방법(특허출원 제85-3227호)에 사용되는 장치에 관한 것이다.The present invention uses artificially concentrated concentration of a single main component existing in a single layer consisting essentially of the structure of the dielectric geological layer as a catalyst to replace the natural oils in the heavy oil, especially banca A, B, C oil, etc. It relates to an apparatus used in the manufacturing method (Patent Application No. 85-3227).

본 발명의 장치에 있어서 특징적이라 함은, 자연계의 유전지층의 각 기질구조층(가스층, 유층, 단수층)에서 석유를 조성케 하는 각기의 화학적, 물리적 작용에 기준한 역활과 효과를 유기적으로 발생시켜 달성하도록 결합시킨 것으로, 이하 첨부된 도면을 통하여 구체적으로 설명한다.Characteristic in the device of the present invention is that organically generated roles and effects based on the chemical and physical actions of the petroleum formation in each substrate structure layer (gas layer, oil layer, singular layer) of the natural dielectric layer. It is combined to achieve by the following, will be described in detail with reference to the accompanying drawings.

제 1도는 본 발명의 일체장치를 결합시킨 전체 장치의 사시도로써 각 단위별로 구별하여 기술한다.1 is a perspective view of the whole device incorporating the integrated device of the present invention, and is described separately for each unit.

(A)기는 상기한 단수층의 주된 역활 즉, 상기한 특허출원에 의한 본 발명의 촉매제에 함유된 여러 성분을 단시간 내에 균질되게 수용(水榕)작용에 적격 구조되고, 또 상기 발명에 의해 주장된 온도(45℃∼50℃)으롤 상승 내지 유지시키는 장치이며, 해당량(H2O(700ℓ)+촉매제(7ℓ)의 조성물질을 규격된 도관(P-5)과 자동개폐 장치(C-1), 전동로타리 펌퍼(M-1)등이 (B)기와 연통되게 장착하였고, (A)기 원통 상단부엔 견대(1) 그 내부에 T자 앵글과 전동기 및 감속기(2), 온도 조절용 및 유체 외부 유출 방지용 뚜껑(1-1)등으로 구조 하였다.The group (A) is structured and qualified by the above-described main role of the single layer, that is, the homogenous water-retaining function of the various components contained in the catalyst of the present invention according to the above-described patent application within a short time, and claimed by the present invention. the temperature (45 ℃ ~50 ℃) a device for holding eurol rise to, the quantity (H 2 O (700ℓ) + catalyst (7ℓ) of a standard composite material pipe (P-5) and the automatic opening and closing device (the C- 1), Rotary Rotary Pump (M-1) is installed in communication with (B). It was constructed with a lid (1-1) for preventing the outflow of the fluid.

(B)기는, 상기한 유층에서 탄화수소의 조성작용 및 반응에 기여하는 특허출원 제85-3227호에 의한 본 발명의 기초유(B.C유(30%)

Figure kpo00001
H2O (70%)+촉매제(1%)를 조성하는 장치로서, 유층의 온도(70℃)를 가온 내지 유지 및 A기에서 성숙된 촉매액을 B.C유 표면에 살포 화합케 하는 살포기(제3a도)가 장착되고 있고, (C)기와는 도관(P-6), 자동개폐기(C-2), 전기구동 자동식 로타리 펌프(M-2)와 연통되고 전동 감속기, 견대, 뚜껑 등은 (A)기와 동일하게 장착되어 있는 것이다.Group (B) is the base oil of the present invention (BC oil (30%) according to Patent Application No. 85-3227, which contributes to the compositional reaction and reaction of hydrocarbons in the oil layer described above).
Figure kpo00001
A device for forming H 2 O (70%) + catalyst (1%), the sparger for heating and maintaining the temperature of the oil layer (70 ° C.) and spraying and combining the catalyst liquid matured in group A on the surface of BC oil. 3a), and (C) is connected to the conduit (P-6), automatic switch (C-2), electric drive automatic rotary pump (M-2), and the electric reducer, strap, lid, etc. It is installed in the same way as A).

(C)기는, 본 발명의 대체유 조성기로써, 상기한(B)기에서 조성된 본 발명의 기초유와, 본 특허출원의 방법에서 제시된 비율의 각종 석유류, 동식물, 어류의 유지, 수지와 폐유(Slag, sludge)등과 반응시켜 가용할 수 있는 대체유를 조성하는 장치이며 지정된 온도를 가열 내지 유지하는 장치로서, 유통과정의 제기, (C-3), (M-3)등으로, 본 발명의 순화기(D)와 연통되게 구조하였고, 여타 각 장치 및 구조물은 (B)기의 것과 동일하다. (A), (B), (C)의 각기의 회전율은 60 r.p.m로 조정 장치 하였다.(C) is a substitute oil composition group of the present invention, and the base oil of the present invention formed in the above-mentioned (B) group, oils, resins and waste oils of various petroleum, animals, plants and fish in the ratios proposed by the method of the present patent application (Slag, sludge) and the like to create an alternative oil that can be used to create a device for heating or maintaining a specified temperature, the distribution process, (C-3), (M-3), etc., the present invention It is structured in communication with the purifier (D) of, and each of the other devices and structures are the same as those of the (B) group. The rotation rate of each of (A), (B), and (C) was adjusted to 60 r.p.m.

(D)기는 본 발명의 대체유를 최종적으로 순화(醇化)시키는 장치로서, (C)기에서 0.01%의 미량인 미반응 물질을 (D)기의 물리적 작용에 의해서 결수(結手)케 하는 방사형 다공구조인 원판임페라(제 5a도)등이 내장된 장치이다. 이곳을 경유, 보조 탱크(S.T)로 송유되어 연소장치 내지 수요처로 공급된다.Group (D) is a device for finally purifying the replacement oil of the present invention, and in (C) group, a small amount of unreacted material of 0.01% is collected by the physical action of group (D). It is a device with a built-in radial impeller (Fig. 5a). It is sent to diesel fuel and to an auxiliary tank (S.T) and supplied to the combustor or the customer.

이하 본 발명의 장치에 관한 기계적 특수 구조와 기능 및 효과의 설명에 앞서 일반적인 교반 및 혼합의 개념과 본 발명의 장치의 그것과를 비교하여 본다.Prior to the description of the special mechanical structures, functions and effects of the device of the present invention, the general concept of stirring and mixing is compared with that of the device of the present invention.

혼합내지 화합이 난이한 물질 즉, 물과 기름과 같은 물질을 혼합 내지 화합함에 있어서, 통념적으로, 교반날개의 고속회전, 전자식 내지 초음파식 충격, 진동(Vibration), 전단(剪斷)등이 필수 요건임은 주지의 상식이다.In mixing or compounding materials that are difficult to mix, ie, materials such as water and oil, conventionally, high speed rotation of the stirring blades, electronic to ultrasonic shock, vibration, shear, etc. are essential. This is a common sense.

그러나 본 발명의 방법(특허 출원 85-3227)이나 본 장치에 있어서는 회전율이 60 r.p.m을 이하 내지 초과작용을 하거나 온도한계, 촉매액(45℃∼50℃), 기초유, 대체유 조성시 온도(70℃)이하 내지 과열되면, 교반이던 화합이던간에 반응작용이 절대 일어나지 않는다.However, in the method of the present invention (patent application 85-3227) or the apparatus, the rotation rate is 60 rpm or less or exceeds the temperature limit, the temperature limit, the temperature of the catalyst liquid (45 ° C. to 50 ° C.), the base oil and the replacement oil ( 70 ° C.) or higher, the reaction never occurs, whether stirring or compounding.

위의 요건에 주안된 구조이며 장치임을 선론한다.Declare that it is a structure and device focused on the above requirements.

제 2도와, 제2a도를 참조하며, 설명함에, (A)기의 외형조형은 원통 직경의 길이보다 종면의 길이가 1/3배가 긴 원통형 구조이며, 저면은 솥밑바닥 모양으로 구조되고, 원통의 상단부에는 L형 견대(1)를 둘렀으며, 그 내부의 중심부위에 T자형 앵글(1-2)을 기설하여, 그 위에 전동기와 감속기 (2) (60 r.p.m.)를 설치하고,이것에 감착 연결시킨 축(6)의 하단부에 축지지 베아링(7)을 설치하여, 축의 회전의 원활을 기하였고, 그것의 상부 위에 스크류식 임페라(8)를 장착 시켰고, 또 원통 내부의 온도 조절 및 유체 유출방지용 뚜껑(1-1)이 장착되고, 원통의 저면 상부위에 전자식 온도 감지기(5)를 감삽하여, 스팀 자동 제어밸브(4)와 회로 연결시켜, 지시 온도를 위한 작동을 자동케 하였다.Referring to Figure 2 and Figure 2a, in the description, the outer mold of the group (A) is a cylindrical structure having a longitudinal length 1/3 times longer than the length of the cylinder diameter, the bottom is a bottom of the pot structure, An L-shaped shoulder (1) was enclosed at the upper end, and a T-shaped angle (1-2) was installed on the center of the inner part thereof, and an electric motor and a reducer (2) (60 rpm) were installed thereon, and a squeezed connection was made thereon A shaft support bearing 7 is installed at the lower end of the shaft 6 to facilitate the rotation of the shaft, and a screw impeller 8 is mounted on the upper portion of the shaft 6, and for adjusting the temperature inside the cylinder and preventing fluid leakage. A lid 1-1 was mounted and an electronic temperature sensor 5 was superimposed on the top of the bottom of the cylinder and connected to a steam automatic control valve 4 to automatically operate for the indicated temperature.

원통의 내주면에는 스팀·코일(Steam Coil) (3)을 장착시켜, 수용물을 가온하게 하였다.A steam coil 3 was attached to the inner circumferential surface of the cylinder to warm the contents.

원통 상단 위치에 촉매제 주입구(P-1)와 자연수구 입구(P-2)를 부설하여 도면 기재외의 계량기 미 탱그와 연통되게 하였다.A catalyst inlet (P-1) and a natural water inlet (P-2) were placed at the top of the cylinder to communicate with the meter tank without the description.

또, 원통의 외주면에 종선으로 유체감식기(V-1, V-2)를 부설하여 (A)기 내부를 관찰하게 하고, (V-2)에 의해서는 (P-1)(P-2)와 전자회로를 연관시켜 다음 작동의 자동화를 기하였다.In addition, the fluid indenters (V-1, V-2) are laid on the outer circumferential surface of the cylinder in a vertical line to observe the inside of the (A) machine, and (P-1) (P-2) by (V-2). And electronic circuits were associated to automate the following operations.

제 2a도는 (A), (B), (C)기에 내장된 임페라의 확대 사시도로 도면과 같이 3엽의 교반날개에 날개면적의 1/10에 해당되는 면적의 천공 구조를 실시한 것이 통상의 교반날개와는 다르다.Figure 2a is an enlarged perspective view of the impeller built in the (A), (B), (C) group, as shown in the drawing, the perforated structure of an area corresponding to 1/10 of the wing area to the stirring blades of the three leaves as shown in the conventional stirring It is different from wings.

이와 같은 본 발명의 장치의 특징으로써, 천공(8-1)은 자연수에 촉매제를 용해시키는 과정중 촉매제의 제성분에 부하되는 원심 분리작용(H2O와 각 성분간의 비중차에 의해서 발생하는)을 억제시키는 역활과, 아울러 각 성분간의 결정화를 방지하고, 특히 본 발명인 대체유와 기초유를 조성할시에 촉매제 살포장치 (제 3a도)(9)를 통과한 촉매액(조성량의 70%)을 5분간에 걸쳐 임페라에 의해 와류하는 방카C유(조성량의 30%)의 표면상에서 반응시키는 본 발명의 방법의 실시과정에서, 천공(8-1)구조의 작용원리를 응용하여, 반응 완료된 물질의 표면에로의 재차 부상(浮上)을 억제하고 미반응물질을 부상시켜 균질되게 반응을 달성하는 장치이다. 다시 부연하면, 기존 B.C유(미반응물질)와 반응이 달성된 양 유동체 사이에는 점성도, 지중, 유동성의 차이가 발생한다.As a feature of the apparatus of the present invention as described above, the perforation (8-1) is centrifugal action (generated by the specific gravity difference between H 2 O and each component) loaded on the catalyst component during the process of dissolving the catalyst in natural water. And the catalyst liquid (70% of the composition amount) which passed the catalyst sparging device (FIG. 3a) 9 at the time of forming the substitute oil and the base oil of the present invention, and preventing the crystallization between the components. ) In the course of the process of the present invention in which the reaction is carried out on the surface of the banca C oil (30% of the composition) vortexed by the impeller over 5 minutes. It is a device that suppresses injuries to the surface of the finished material and floats unreacted material to achieve a homogeneous reaction. In other words, there is a difference in viscosity, soil and fluidity between existing BC oil (unreacted material) and both fluids in which the reaction is achieved.

이때에 천공 구조가 실시되지 않은 일반 교반날개라면, 같은 질량의 운동량에 의해서 반응된 유체가 재 부상될 기회가 많아 진다. 그러나 천공(8-1)날개에 의해서는 성질과 질량의 차이에 의한 유동 원리에 준하여 반응액체는 천공(8-1)사이로 빠져 하부로 떨어지는 타성에 의해서 저부 방향으로 부침하고, 신선한 유체가 반대 작용으로 부상하게 하는 원리가 적용된 장치로서 특징될 수 있다.At this time, if it is a general stirring blade which is not provided with a perforation structure, the chance that the reacted fluid will resurface by the momentum of the same mass will increase. However, the perforation (8-1) wing, according to the flow principle due to the difference in properties and mass, the reaction liquid is immersed in the bottom direction by the inertia falling between the perforations (8-1) falling to the bottom, the fresh fluid is the opposite action Can be characterized as an applied device.

제 3도는 기초유 조성기(B)의 일부 절개 정면도로써, 외형을 원추형으로 구조함이 (A)기, (B)기와는 다를 뿐 여타, 즉 L형 견대(1), 스팀코일(3), T자 앵글(1-2) 전동기와 감속기(2), 온도 조절 및 유체 외부 유출 방지용 뚜껑(1-1), 온도 감지기(5), 스팀 자동제어 밸브(4), 축(6), 천공구조 스크류(8)(8-1), 유체 감식기(V-1, V-2), 축지지용 베아링 박스(7)등의 장착위치, 규격, 구조, 목적, 효과 등은 동일하다. 다만, 기초유의 점성이 높기 때문에 천공 구조 스프류(8)(8-1)를 축(6)에 2개조 장착 하였다.3 is a partial cutaway front view of the base oil composition (B), the outer structure of the conical shape is different from the (A), (B) and other, that is, L-shaped shoulder (1), steam coil (3), T-angle (1-2) Electric motor and reducer (2), temperature control and fluid leakage prevention cap (1-1), temperature sensor (5), steam automatic control valve (4), shaft (6), drilling structure The mounting positions, specifications, structures, objects, effects, and the like of the screws 8 and 8-1, the fluid sensitizers V-1 and V-2, and the shaft support bearing box 7 are the same. However, because the viscosity of the base oil is high, two sets of perforated structure soups (8) (8-1) are mounted on the shaft (6).

또한 조성기(B)의 상단 중앙부에 촉매제 살포장치(9)를 부설 하였다.In addition, a catalyst sparging device 9 was placed in the upper center portion of the formulator B.

제 3a도, 제3b도는, 자연수에 수용시킨 촉매제를 살포함에 주관된 장치로서, 상기 특허출원의 실시예에서 주장한 요건에 합당한 효과를 부여하겠끔 구조 내지 조직설치한 살포 장치(9)이다.FIG. 3A and FIG. 3B are apparatuses that are mainly involved in spraying catalysts contained in natural water, and are spraying apparatuses 9 constructed or structured so as to give a reasonable effect to the requirements claimed in the embodiments of the patent application.

살포 장치(9)에 제공되는 재질은 알루미늄제 관이라야 한다. 이에 대한 이유는, 본 발명의 촉매제는 알루미늄과 급속도로 반응하여 수소를 발생함과 동시에 촉매제를 구성하는 제요소 및 성분의 완전 수용을 촉진시키는 작용도 겸하기 때문이다.The material provided to the spreading device 9 should be an aluminum tube. The reason for this is that the catalyst of the present invention reacts rapidly with aluminum to generate hydrogen, and at the same time, also serves to promote the complete reception of the agents and components constituting the catalyst.

(B) 기 내주면 상단 중앙부에 설치된 살포 장치(9)는 도관을 원형으로 조형하고, 도관 반주면의 중앙선을 따라 2열의 천공(9-1)을 실시하고, 도관 내면에 (제 3b도)철제인 구체(9-2)를 천공(9-1)의 숫자만큼 충전한다.(B) The sprinkling apparatus 9 installed at the upper center of the inner peripheral surface of the machine forms a conduit in a circular shape, performs two rows of perforations (9-1) along the center line of the conduit accommodating surface, and the inner surface of the conduit (FIG. The phosphor sphere 9-2 is filled by the number of perforations 9-1.

이와 같이 구조 및 조형하므로서, 압송(M-1에 의해 )된 촉매제의 수압을 줄여 기름 표면에 연유하게 낙하반응토록 하고, 또 구체(9-2)의 유동회전에 의한 볼밀작용을 발생시켜 촉매제와 H2O의 반응 과정중 결정화를 효과적으로 발생케 하는 특징적인 장치이다.In this way, the structure and the molding reduce the water pressure of the pumped catalyst (by M-1) so as to drop the oil onto the oil surface, and generate a ball mill action by the flow rotation of the sphere (9-2). It is a characteristic device that effectively generates crystallization during the reaction of H 2 O.

제 4도는 대체유 조성기(C)의 일부절개 정면도로써, 외형구조는(A)기와 동일한 원통형이며, 용량 크기는 본 발명의 방법의 실시예에 따라서 확대 조형 한다.4 is a partial cutaway front view of the replacement oil composition (C), the outer structure of which is the same cylindrical as (A), the capacity size is enlarged in accordance with an embodiment of the method of the present invention.

내외부, 조직, 구조는 (B)기와 동일함에 설명을 생략하며, (B)기에서 조성된 기초유는 주입관(9-1)을 통하여 조달되며, 대체유 조성 방법에서 주장한 비율에 의해 반응 공정이 실시된다.Internal and external structures, structures, and structures are the same as in group (B), and description thereof is omitted. The base oil formed in group (B) is procured through the injection pipe (9-1), and the reaction process is carried out at the ratio claimed in the alternative oil composition method. This is carried out.

제 5도 및 제 5a도는 본 발명의 순화기(D)의 단면도와. 이곳에 내장된 원판임페라의 측면도이다.5 and 5a are cross-sectional views of the purifier (D) of the present invention. This is a side view of the original impeller built here.

적정구경 및 길이를 갖는 원통형 케이싱(10)이 본 장치(D)의 주체이며, 양단에 헤드카바(head-cover)(11)를 감착시켜 케이싱(10)을 밀폐함과 동시 축을 베아링(13)하는 장치도 겸한다. 축(12)에는 원판형 임페라(14)를 동일 간격으로 수 개 감착시켜, 케이싱(10)의 내경의 벽면에 홈(15)을 설비하여 상기 원판형 임페라(14)가 회전되게 하였다.A cylindrical casing 10 having a proper diameter and length is the main body of the apparatus D. The head cover 11 is attached to both ends to seal the casing 10 and the simultaneous shaft bearing 13 is carried out. Also serves as a device. Several disk-shaped impellers 14 were mounted on the shaft 12 at equal intervals, and grooves 15 were provided on the wall surface of the inner diameter of the casing 10 so that the disk-shaped impellers 14 were rotated.

(D)기의 양단부위에는 주입구(16)와 토출구(17)를 설비하고, 축의 외부 일단부에는 폴리(18)를 장착하여 구동력을 전달받게 구성하였다.The inlet 16 and the outlet 17 were installed at both ends of the machine (D), and a poly 18 was mounted at the outer end of the shaft to receive the driving force.

원판형 임페라(14)는 축(12)과의 감착공(19)을 중심하여, 원판 외주를 향한 방사선상에 점차 공(20)의 규격이 확대되도록 천공이 실시되었다.The disk-shaped impeller 14 was punched so that the standard of the ball 20 gradually expanded on the radiation hole toward the outer circumference of the disk about the sensitizing hole 19 with the shaft 12.

이와 같이 조형된 다공형 원판을 회전하게 함과 동시 압력이 부하된 유동체가 원판임페라에 수평직각 방향으로 대면하면, 각기의 공(20)으로 통과하는 유동체(동일성분)는 유속과 유량의 비율에 격차가 발생한다.When the formed porous disk is rotated in this way and the fluid loaded with the simultaneous pressure faces the disk impeller in a horizontal orthogonal direction, the fluid (same component) passing through the respective balls 20 is in the ratio of the flow rate and the flow rate. A gap occurs.

따라서 원판과 원판사이에서는 유동이 새끼 모양으로 꼬여 진다. 이런 작용이 수차례 반복되게 원판형임페라(14)를 수개 병열장치하여 본 발명의 대체유의 완전 수화를 도모한 장치임에 특징을 두었다.Therefore, the flow is twisted between the disc and the disc. This action was repeated several times and the disk-shaped impeller 14 was arranged in parallel and it was characterized by the apparatus which aimed at the complete hydration of the substitute oil of this invention.

본 발명의 장치에 의한 실시예를 설명함에 편의상 기초유 조성량을 1,000ℓ으로 한다.In describing the embodiment of the apparatus of the present invention, the base oil composition amount is 1,000 liter for convenience.

계량기와 연결된 자연수 주입구(P-2), 촉매제 주입구(P-1)를 통하여 각기 지정된 량의 액체가 (A)기에 주입되는(주입량 H2O=700ℓ, 촉매제 7ℓ) 동시에 (B)기에는 유량계에서 지정된 B.C유 (300ℓ)가 주입된다. 위와 같이 지정 주입량 유입공정이 완료됨과 동시 전자 감지기는 작동되어, (A)(B)기의 교반 전동기를 구동시키고 스팀코일(3)에는 스팀이 주입되어 지시된 온도까지 가열한다.The specified amount of liquid is injected into (A) through the natural water inlet (P-2) and the catalyst inlet (P-1) connected to the meter (injection amount H 2 O = 700ℓ, catalyst 7L). BC oil (300 liters) specified in the above is injected. At the same time as the designated injection amount inflow process is completed as described above, the electronic sensor is operated to drive the stirring motor of (A) and (B) machines, and steam is injected into the steam coil 3 to heat up to the indicated temperature.

(A)기에서의 촉매제 수용액이 완숙되고 온도가 달성되면 감지기의 작동(C-1)으로 (M-1)기가 구동, 촉매액을 B기의 살포장치에서 와류하는 B,C유 표면상에 살포하게 한다.When the aqueous catalyst solution in (A) is mature and the temperature is achieved, the (M-1) machine is driven by the operation of the detector (C-1), and on the surface of oils B and C vortexing the catalyst liquid from the B spreader Let it spray

5분간의 살포가 끝나면 기초유(H2O(70%)+촉매제 7%

Figure kpo00002
CnH2n+2(30%)1,000ℓ가 조성된다.After 5 minutes of spraying, base oil (H 2 O (70%) + catalyst 7%
Figure kpo00002
1,000 liters of C n H 2n + 2 (30%) are formed.

위의 조성시간내에 본 발명의 방법에서 주장한 배율비에 의한 량의 B.C유 및 기타 대상유가(C)기에 주입이 완료 된다. 동시에 교반 구동기 및 스팀 등이 가동 내지 유입되어, 각기의 공정을 실시한다.Within the above composition time, the injection is completed in the B.C oil and other target oil price (C) in the amount by the magnification ratio claimed in the method of the present invention. At the same time, a stirring driver, steam, and the like are operated or introduced to perform respective processes.

만약, 기초유 5 : B.C유 5의 사전 지시된 조제량이면 (B)기에서 500ℓ의 기초유가 각 송유도관을 경유(C)기에 주입(5분간)되면서 대체유로 합성된다.If base oil 5: B.C oil 5 has a pre-specified amount of preparation, 500 liters of base oil in (B) is injected into the diesel oil (C) into the oil (C) for 5 minutes to be synthesized as a substitute oil.

위에서 합성된 대체유로 본 장치인 순화기(D)를 경유 저장탱크(S.T)내지 연소기로 송유된다.As a substitute oil synthesized above, the purifier (D), which is the device, is fed to the diesel storage tank (S.T) to the combustor.

위와 같은 공정을 계속 반복 실시하므로, 본 발명의 장치에 의해서 단시간내에 막대량의 대체유를 조성할 수 있게 된다.Since the above process is repeatedly carried out, it is possible to form a rod replacement oil in a short time by the apparatus of the present invention.

Claims (1)

유전 지질층의 구조중 필수적으로 구성된 단수층에 부존하는 단수의 주성분을 인공적으로 조성 농축한 것을 촉매제로 하여 중질유 특히 방카 A, B, C유 등에 자연수를 화합적으로 결수시켜 대체유를 제조하는 장치에 있어서, 화합적 조성 반응의 여건 구비 장치인 스팀코일(3), 스크류식 임페라(8)에 단위면적의 1/10에 해당하는 천공(8-1)구조를 하고, 알미늄금속제 도관을 사용하여 원형 완곡 조형한 촉매액 살포장치(9)에 천공(9-1)된 수량에 해당되는 중량구체(9-2)를 도관내에 충전 장치하여, 유수압을 억제하고 촉매제의 재 결정 내지 볼밀작용을 겸하게 하는 장치등을 적절한 위치에 설비한 원통형 촉매제 가온 용해기(A), 기초유 조성기(B), 대체유 조성기(C)와, 다공형 임페라(14)를 수매 내장하여 관통되는 유체압의 차등을 이용한 대체유 최종 순화를 작용케 하는 순화장치(D)등에 특정된 장치를 결합시켜서 된 것을 특징으로 하는 중질유계 대체유의 제조장치It is a device that manufactures substitute oil by chemically condensing natural water in heavy oil, especially banca A, B, C oil. The perforated structure 8-1 corresponding to 1/10 of the unit area is provided in the steam coil 3 and the screw impeller 8, which are equipped with the conditions for the compound composition reaction, and are made of aluminum metal conduits. Filling device in the conduit with a weight sphere (9-2) corresponding to the number of perforations (9-1) in the catalyst liquid spraying device (9) formed in a circumferential shape, to suppress the hydraulic pressure and to act as a recrystallization or ball mill of the catalyst Differential pressure difference between the cylindrical catalyst heating dissolving machine (A), the base oil composition machine (B), the replacement oil composition machine (C), and the porous impeller 14, which are installed at an appropriate position, are provided. Final purification of substitute oil using Purifying device (D) heavy oil-based substitute significant manufacturing apparatus for a specific device, characterized by that the combination or the like to
KR1019850003229A 1985-05-13 1985-05-13 Apparatus for manufacturing substituting oil of heavy oil KR880000066B1 (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100778493B1 (en) * 2006-11-28 2007-11-28 한국엑스오일 주식회사 Alternative emulsification fuel and manufacturing method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100778493B1 (en) * 2006-11-28 2007-11-28 한국엑스오일 주식회사 Alternative emulsification fuel and manufacturing method thereof

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