KR870011149A - 액체상 트리아릴 티오포스페이트 혼합물 및 그 제조방법 - Google Patents
액체상 트리아릴 티오포스페이트 혼합물 및 그 제조방법 Download PDFInfo
- Publication number
- KR870011149A KR870011149A KR870002884A KR870002884A KR870011149A KR 870011149 A KR870011149 A KR 870011149A KR 870002884 A KR870002884 A KR 870002884A KR 870002884 A KR870002884 A KR 870002884A KR 870011149 A KR870011149 A KR 870011149A
- Authority
- KR
- South Korea
- Prior art keywords
- thiophosphate
- composition
- triaryl
- aliphatic group
- butyl
- Prior art date
Links
- RYYWUUFWQRZTIU-UHFFFAOYSA-K thiophosphate Chemical compound [O-]P([O-])([O-])=S RYYWUUFWQRZTIU-UHFFFAOYSA-K 0.000 title claims 15
- 239000000203 mixture Substances 0.000 title claims 12
- 239000007788 liquid Substances 0.000 title claims 3
- 238000002360 preparation method Methods 0.000 title 1
- 238000000034 method Methods 0.000 claims 11
- 125000001931 aliphatic group Chemical group 0.000 claims 8
- -1 phosphorus halide Chemical class 0.000 claims 5
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 3
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims 2
- 239000007791 liquid phase Substances 0.000 claims 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims 1
- 125000003118 aryl group Chemical group 0.000 claims 1
- 239000003637 basic solution Substances 0.000 claims 1
- 235000010290 biphenyl Nutrition 0.000 claims 1
- 239000004305 biphenyl Substances 0.000 claims 1
- 238000009835 boiling Methods 0.000 claims 1
- 230000015556 catabolic process Effects 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 238000006731 degradation reaction Methods 0.000 claims 1
- 238000001035 drying Methods 0.000 claims 1
- 150000004820 halides Chemical class 0.000 claims 1
- 239000012535 impurity Substances 0.000 claims 1
- 239000003960 organic solvent Substances 0.000 claims 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims 1
- 229910052698 phosphorus Inorganic materials 0.000 claims 1
- 239000011574 phosphorus Substances 0.000 claims 1
- 239000007787 solid Substances 0.000 claims 1
- 239000002904 solvent Substances 0.000 claims 1
- IKXFIBBKEARMLL-UHFFFAOYSA-N triphenoxy(sulfanylidene)-$l^{5}-phosphane Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=S)OC1=CC=CC=C1 IKXFIBBKEARMLL-UHFFFAOYSA-N 0.000 claims 1
- 238000005406 washing Methods 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/16—Esters of thiophosphoric acids or thiophosphorous acids
- C07F9/165—Esters of thiophosphoric acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/08—Esters of oxyacids of phosphorus
- C07F9/141—Esters of phosphorous acids
- C07F9/145—Esters of phosphorous acids with hydroxyaryl compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/16—Esters of thiophosphoric acids or thiophosphorous acids
- C07F9/165—Esters of thiophosphoric acids
- C07F9/18—Esters of thiophosphoric acids with hydroxyaryl compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (16)
- 포스포터스 할라이드 또는 티오포스포릴 할라이드를 하이드록시아릴 화합물 및 그 치환된 유도체와의 혼합물을 반응시켜 이루어지며, 치환된 유도체의 양이 통상 고체의 트리아릴 티오포스파이트를 액체화하는데 충분하도록 하고, 포스포터스 할라이드의 경우 포스파이트를 가황하여 티오포스페이트를 생성하고, 불순물을 제거하도록 염기성 용액으로 티오포스페이트를 세척하고, 티오포스페이트의 상당한 정도의 분해를 피하도록 하는데 충분히 은훈하 상태에서 세척된 티오포스페이트를 온훈 건조하여 이루어지는 액체상 트리아릴 티오포스페이트 혼합물의 제조방법.
- 제1항에 있어서, 상기 하이드록시 아릴화합물이 페놀인 상기 제조방법.
- 제1항에 있어서, 치환된 유도체의 치환분이 C2내지 C8의 지방족기인 상기 제조방법.
- 제3항에 있어서, 지방족기 대 아릴 화합물의 비가 약 0.2 내지 약 0.8의 범위인 상기 제조방법.
- 제4항에 있어서, 상기 비가 약 0.3 내지 약 0.6의 범위인 상기 제조방법.
- 제1항에 있어서, 세척을 용이하게 하는데 충분한 점성도까지 생성물을 희석하도록 충분한 양의 불활성의 물과 혼합되지 않는 유기용매와 혼합되므로써 세척되기 전에 티오포스페이트의 점성도를 낮추는 상기 제조방법.]
- 제6항에 있어서,상기 용매가 약 120℃ 이하의 비등점을 가지는 상기 제조방법.
- 제3항에 있어서, 상기 지방족기가 프로필 또는 부틸인 상기 제조방법.
- 제3항에 있어서, 상기 지방족기가 이소프로필 또는 터트-부틸인 상기 제조방법.
- 적어도 25%의 대칭형 트리아릴 티오포스페이트와, 대칭형 트리아릴 티오포스테이트와 결합하여 액체상 혼합 트리아릴 티오포스페이트 조성물을 생성하는데 충분한 양의 치환된 트리아릴 티오포스페이트의 혼합으로 이루어지는 액체상 혼합 트리아릴 티오포스페이트 조성물.
- 제10항에 있어서, 상기 치환된 트리아릴 티오포스페이트의 치환분이 C2내지 C8의 지방족기인 상기조성물.
- 제11항에 있어서, 상기 지방족기가 프로필 또는 부틸인 상기 조성물.
- 제11항에 있어서, 상기 지방족기가 이소프로필 또는 터트-부틸인 상기 조성물.
- 제13항에 있어서, 상기 지방족기가 터셔리 부틸기인 상기 조성물.
- 제10항에 있어서, 적어도 25%의 디페닐 t-부틸페닐 티오포스페이트와 적어도 40%의 트리페닐 티오페이트로 이루어지며, 상기 두 화합물의 중량비인 상기 조성물.
- 제1항의 방법의 생성물인 액체상 트리아릴 티오포스페이트 혼합물.※ 참고사항 : 최초출원내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US863656 | 1986-05-15 | ||
| US06/863,656 US4724265A (en) | 1986-05-15 | 1986-05-15 | Process for preparing liquid triaryl thiophosphate mixtures |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR870011149A true KR870011149A (ko) | 1987-12-21 |
Family
ID=25341513
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR870002884A KR870011149A (ko) | 1986-05-15 | 1987-03-28 | 액체상 트리아릴 티오포스페이트 혼합물 및 그 제조방법 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US4724265A (ko) |
| EP (1) | EP0245852B1 (ko) |
| JP (1) | JPH07116204B2 (ko) |
| KR (1) | KR870011149A (ko) |
| AU (1) | AU7276287A (ko) |
| BR (1) | BR8702446A (ko) |
| CA (1) | CA1297496C (ko) |
| DE (1) | DE3783941T2 (ko) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4479963A (en) * | 1981-02-17 | 1984-10-30 | Ciba-Geigy Corporation | 1-Carboxyalkanoylindoline-2-carboxylic acids |
| US7888414B2 (en) * | 2006-06-20 | 2011-02-15 | Chemtura Corporation | Liquid phosphite blends as stabilizers |
| CN101472986B (zh) * | 2006-06-20 | 2012-04-11 | 科聚亚公司 | 作为稳定剂的液体亚磷酸酯共混物 |
| US8178005B2 (en) | 2006-06-20 | 2012-05-15 | Chemtura Corporation | Liquid phosphite compositions having different alkyl groups |
| US7947769B2 (en) | 2006-06-20 | 2011-05-24 | Chemtura Corporation | Liquid amylaryl phosphite compositions and alkylate compositions for manufacturing same |
| US8008384B2 (en) | 2006-06-20 | 2011-08-30 | Chemtura Corporation | Liquid butylaryl phosphite compositions |
| US8008383B2 (en) | 2006-06-20 | 2011-08-30 | Chemtura Corporation | Liquid amylaryl phosphite compositions |
| US8183311B2 (en) | 2006-06-20 | 2012-05-22 | Chemtura Corporation | Liquid phosphite composition derived from cresols |
| US8188170B2 (en) | 2006-06-20 | 2012-05-29 | Chemtura Corporation | Polymers with low gel content and enhanced gas-fading |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2250049A (en) * | 1938-12-19 | 1941-07-22 | Dow Chemical Co | Mixed triaryl thiophosphates |
| BE786068A (fr) * | 1971-07-12 | 1973-01-10 | Bayer Ag | Nouveaux esters d'acides organophosphoriques, leur preparation et leur application comme insecticides et nematicides |
| US3829565A (en) * | 1971-09-07 | 1974-08-13 | Bayer Ag | Combating insects,acarids and nematodes using s,s-di(2-alkoxy-ethyl)phosphoro-or phosphonothionothiolates |
-
1986
- 1986-05-15 US US06/863,656 patent/US4724265A/en not_active Expired - Fee Related
-
1987
- 1987-03-23 CA CA000532713A patent/CA1297496C/en not_active Expired - Fee Related
- 1987-03-28 KR KR870002884A patent/KR870011149A/ko not_active Application Discontinuation
- 1987-05-13 JP JP62114883A patent/JPH07116204B2/ja not_active Expired - Lifetime
- 1987-05-13 DE DE8787106950T patent/DE3783941T2/de not_active Expired - Fee Related
- 1987-05-13 EP EP87106950A patent/EP0245852B1/en not_active Expired - Lifetime
- 1987-05-13 BR BR8702446A patent/BR8702446A/pt unknown
- 1987-05-13 AU AU72762/87A patent/AU7276287A/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| EP0245852A3 (en) | 1989-07-26 |
| EP0245852B1 (en) | 1993-02-03 |
| CA1297496C (en) | 1992-03-17 |
| DE3783941D1 (de) | 1993-03-18 |
| AU7276287A (en) | 1987-11-19 |
| BR8702446A (pt) | 1988-02-23 |
| JPS62273987A (ja) | 1987-11-28 |
| EP0245852A2 (en) | 1987-11-19 |
| DE3783941T2 (de) | 1993-06-17 |
| US4724265A (en) | 1988-02-09 |
| JPH07116204B2 (ja) | 1995-12-13 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| WITN | Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid |