KR870009992A - 살균제 - Google Patents

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KR870009992A
KR870009992A KR870003676A KR870003676A KR870009992A KR 870009992 A KR870009992 A KR 870009992A KR 870003676 A KR870003676 A KR 870003676A KR 870003676 A KR870003676 A KR 870003676A KR 870009992 A KR870009992 A KR 870009992A
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마가렛트 안토니 비비엔
마틴 클라우 존
디프레인 폴
리차드 엘리스 고프레이 크리스토퍼
조제프 태폴크제이 데이비드
유젠 위진스 토마스
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알란 브라이안 벡
임페리알 케미칼 인더스트리스 피엘씨
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Publication of KR870009992A publication Critical patent/KR870009992A/ko

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    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/54—Radicals substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
    • A01N43/08—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings with oxygen as the ring hetero atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/50—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton
    • C07C323/51—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton
    • C07C323/56—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton containing six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/50—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton
    • C07C323/51—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton
    • C07C323/57—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton being further substituted by nitrogen atoms, not being part of nitro or nitroso groups
    • C07C323/58—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton being further substituted by nitrogen atoms, not being part of nitro or nitroso groups with amino groups bound to the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/50—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton
    • C07C323/62—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atom of at least one of the thio groups bound to a carbon atom of a six-membered aromatic ring of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/64—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and sulfur atoms, not being part of thio groups, bound to the same carbon skeleton
    • C07C323/65—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and sulfur atoms, not being part of thio groups, bound to the same carbon skeleton containing sulfur atoms of sulfone or sulfoxide groups bound to the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2603/00—Systems containing at least three condensed rings
    • C07C2603/02—Ortho- or ortho- and peri-condensed systems
    • C07C2603/04—Ortho- or ortho- and peri-condensed systems containing three rings
    • C07C2603/22—Ortho- or ortho- and peri-condensed systems containing three rings containing only six-membered rings
    • C07C2603/26—Phenanthrenes; Hydrogenated phenanthrenes

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  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
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  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
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  • Heterocyclic Compounds Containing Sulfur Atoms (AREA)
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Abstract

내용 없음

Description

살균제
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (13)

  1. 구조식(1)의 화합물 및 그것의 입체 이성체.
    [식중, R1및 R2는 같거나 다르고, 임의 치환 일킬(특히 에틸),
    W,X,Y 및 Z는 같거나 다르고, 수소, 할로겐, 하이드록시, 임의 치환 알킬, 임의치환 사이클로알킬, 임의 치환 사이클로알킬알킬, 임의 치환 아랄킬, 임의 치환 아릴옥시알킬, 임의 치환 알케닐, 임의 치환 아릴, 임의 치환 알키닐, 임의 치환아미노, 임의 치환 아릴아조, 임의 치환 헤테로아릴아킬, 임의 치환 헤테로아릴옥시알킬, 임의 치환 아실아미노, 니트로, 시아노, -OR3, -SR3, -CO2R4, -CONR5R6, -COR7, -CR8=NR9, -N=CR10R11, -SOR12또는 -SO2R|13, 또는
    W,X,Y 및 Z 중 둘은 페닐 한의 근접 위치에서 임의로 결합하여 하나 이상의 헤테로원자를 임의로 포함하는 방향족 또는 지방족의 하나인 임의 치환 축합 환을 형성.
    R3는 임의치환 알킬 또는 사이클로알킬 환내에 헤테로 원자를 임의로 포함하는 사이클로알킬, 임의 치환 알케닐, 임의 치환 아릴, 임의 치환 아랄킬, 임의 치환 아실, 또는 임의 치환 헤테로아릴,
    R4,R5,R6,R7,R8,R10및 R11은 같거나 다르고, 수소 또는 임의 치환 알킬, 임의 치환 사이클로알킬, 임의 치환 사이클로알킬알킬, 임의 치환 알케닐, 임의 치환 알키닐, 임의 치환 아릴, 임의 치환 헤테로아릴, 임의 치환 아란킬 또는 사이클로알킬알킬,
    R9,R12및 R13은 임의 치환 아릴 또는 임의 치환 헤테로아릴]
  2. 구조식(1a)의 화합물 및 그것의 입체 이성체.
    [식중, W,X,Y 및 Z는 같거나 다르고, 수소 할로겐, 하이드록시 또는 C1-4알콕시카보닐로 임의 치환된 C1-4알킬, 트리플루오로메틸, 페닐(C1-4)알킬, 페녹시(C1-4알킬, 예를들면 임의 치환되거나 알케닐 그룹의 말단 탄소 원자가 5- 또는 6-원의 사이클로알킬 그룹의 부분을 형성하는, 방향족 또는 헤테로방향족 그룹으로 임의 치환된 C2-4알키닐, 임의 치환 C2-4알키닐, 임의 치환 아릴, 아릴 또는 C1-4알킬로 치환된 아미노, 임의 치환된 아릴 아조, 임의 치환 아실 아조, 니트로, R3가 임의 치환 알킬, 임의 치환 아릴, 임의 치환 헤테로아릴, 임의 치환 아랄킬 또는 아실인 -OR3또는 -SR3,R12및 R13이 아릴인 -SOR12또는 -SO2R13,R14가 임의 치환 알킬, 아릴, C3-6사이클로알킬, C3-6사이클로알킬(C1-4) 알킬 또는 아릴(C1-4)알킬로 임의 치환된 -CO2R4,
    R7가 임의 치환 알킬 또는 임의 치환 아릴인 -COR7이고, 또는 페닐 환의 근접 위치에 있는 W,X,Y 및 Z 중 두개는 결합하여 축합 환을 형성]
  3. 구조식 (1b)의 화합물.
    [식중, R은 수소, C1-4알킬티오, 페닐 티오 또는 페닐로 임의 치환된 C1-4알킬, C3-6사이클로알킬, 테트라하이드로피라닐, C2-4알케닐, 하나 이상의 할로겐, 하이드록시, C1-4알킬,C1-4알콕시, 트리플루오로메톡시, 페녹시, 니트로, 아미노, 아릴(C1-4) 알킨, 페닐, 카복시, 카복실산 에스테르, 시아노, C1-4알킬가보닐아미노 또는 메틸렌디옥시로 임의 치환된 페닐, 나프틸, 피리디닐 및 피리미디닐 부분이 할로겐, 트리플루오로메틸, 니트로, C1-4알킬, C1-4알콕시, 트리플루오로메톡시 또는 아미노로 임의 치환된 피리디닐 또는 피리미디닐,
    Y및 Z는 같거나 다르고, 수소, 할로겐, C1-4알킬, C1-4알콕시, C1-4알킬티오, 트리플루오로메틸, 니트로, N,N-디(C1-4)알킬아미노이거나 Y 및 Z는 함께 메틸렌디옥시 그룹을 형성]
  4. 구조식(1c)의 화합물.
    [식중, R, Y 및 Z는 R이 티에닐, 푸릴, 또는 피롤일인 경우를 제외하고 제3항에 기재된 바와 같음.]
  5. 구조식(1d)의 화합물.
    [식중, R, Y 및 Z는 제4항에 기재된 바와 같음.]
  6. (1) 구조식(2)의 알파-케토에스테르를
    구조 Ph3P+--CHSR2의 포스포란 또는 구조 Me3SiCH(Li)SR|2의 라티오 종으로 처리하거나, 또는
    (2) 구조식(3)의 엔올을 산성 조건하에
    티올 R2SH로 처리하거나, 또는
    (3) 구조식(4)의 베타-알콕시아크릴레이트를
    산성조건 하에 티올 R2SH 또는 티올레이트 R2SM 으로 처리하거나, 또는
    (4) 구조식(5)의 베타-클로로아크릴레이트를
    티올레이트R2SM으로 처리하거나, 또는
    (5) 구조식(6)의 베타-설포닐옥시아크릴레이트를
    티올레이트 R2SM으로 처리하거나, 또는
    (6) 구조식(7)의 티티오-아세탈로 부터
    [식중, W,X,Y,Z,R1및 R2는 제1항의 정의와 같고,
    Ph는 페닐,
    Me는 에틸,
    R14는 알킬,
    R15는 알킬 도는 임의 치환 아릴,
    M은 금속이온]
    산성 또는 염기성 조건하에 티올 R2SH 원소를 제거하는 것으로 구성되는, 제1항의 구조식(1) 화합물을 제조하는 방법.
  7. 제6항 구조식(2)-(7)의 중간 화합물.
  8. 활성 성분으로서 상균 효과량인 제1항의 화합물 및 살균적으로 허용 가능한 담체 또는 희석제로 구성되는 살균 조성물.
  9. 제1항의 화합물 또는 제8항의 조성물을 식물 또는 씨 또는 그것의 소재지에 사용하는 것으로 구성되는, 균류를 퇴치하는 방법.
  10. 활성성분으로서 효과량의 제1항 화합물 및 허용가능한 담체 또는 희석제로 구성되는 살충 또는 식물 생장 조절 조성물.
  11. 제1항 구조식(1)의 살충/살선충 화합물의 유효량을 해충 또는 그것의 소재지에 투약하는 것으로 구성되는, 곤출 및 선충을 박멸 또는 조절하는 방법.
  12. 제11항에 있어서, 구조식(1)의 화합물은 W,X,Y 또는 Z가 치화 알케닐인 것인 방법.
  13. 제1항 구조식(1)의 식물 생장 조절 화합물 효과량을 식물에 사용하는 것으로 구성되는, 식물 생장을 조절하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR870003676A 1986-04-17 1987-04-17 살균제 KR870009992A (ko)

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GB868609455A GB8609455D0 (en) 1986-04-17 1986-04-17 Fungicides

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GB8619236D0 (en) * 1986-08-06 1986-09-17 Ici Plc Fungicides
GB8620251D0 (en) * 1986-08-20 1986-10-01 Ici Plc Fungicides
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CN87102877A (zh) 1988-02-10
DE3771558D1 (de) 1991-08-29
GB2189484B (en) 1990-05-23
GB2189484A (en) 1987-10-28
ZA872096B (en) 1987-12-30
AU7077487A (en) 1987-10-22
NZ219750A (en) 1990-04-26
HU204031B (en) 1991-11-28
DK196987A (da) 1987-10-18
HUT43231A (en) 1987-10-28
GB8706402D0 (en) 1987-04-23
GR3002357T3 (en) 1992-12-30
ATE65499T1 (de) 1991-08-15
DK196987D0 (da) 1987-04-15
GB8609455D0 (en) 1986-05-21
ES2038657T3 (es) 1993-08-01
JPS62255469A (ja) 1987-11-07
JPH07116130B2 (ja) 1995-12-13
AU601721B2 (en) 1990-09-20
EP0244077A1 (en) 1987-11-04
US5145954A (en) 1992-09-08
EP0244077B1 (en) 1991-07-24
CA1287047C (en) 1991-07-30

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