KR870005691A - 알카놀 아민의 증기상 분자내 탈수반응용 촉매 - Google Patents

알카놀 아민의 증기상 분자내 탈수반응용 촉매 Download PDF

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Publication number
KR870005691A
KR870005691A KR860011138A KR860011138A KR870005691A KR 870005691 A KR870005691 A KR 870005691A KR 860011138 A KR860011138 A KR 860011138A KR 860011138 A KR860011138 A KR 860011138A KR 870005691 A KR870005691 A KR 870005691A
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catalyst
general formula
following general
vapor phase
represented
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KR860011138A
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English (en)
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KR910005188B1 (ko
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유이찌 히노
유지 시마사끼
미시오 우에지마
Original Assignee
나까지마 미쓰라
닛뽕쇼꾸 바이가가꾸고오교 가부시끼가이샤
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Priority claimed from JP60287924A external-priority patent/JPS62149337A/ja
Priority claimed from JP60292540A external-priority patent/JPS62152539A/ja
Application filed by 나까지마 미쓰라, 닛뽕쇼꾸 바이가가꾸고오교 가부시끼가이샤 filed Critical 나까지마 미쓰라
Publication of KR870005691A publication Critical patent/KR870005691A/ko
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/02—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms containing only hydrogen and carbon atoms in addition to the ring hetero elements
    • C07D295/023—Preparation; Separation; Stabilisation; Use of additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
    • B01J23/04—Alkali metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of rare earths
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/14—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of germanium, tin or lead
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D203/00—Heterocyclic compounds containing three-membered rings with one nitrogen atom as the only ring hetero atom
    • C07D203/02—Preparation by ring-closure

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

내용 없음

Description

알카놀 아민의 증기상 분자내 탈수반응용 촉매
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (4)

  1. 하기 일반식(I)로 표시되는 화합물을 하기 일반식(Ⅱ)로 표시되는 환상아민으로 전화시키는, 알카놀 아민의 증기상 분자내 탈수반응용 촉매.
    식중 R 및 R'는 각각 수소원자, 메틸기 및 에틸기 중에서 선택된 것이고 n은 2내지 5의 정수임)
    [식중 R,R' 및 n은 상기 정의와 동일하고, 언급된 촉매는 하기 일반식으로 표시되는 옥사이드 조성물임.
    (식중 Si는 실리콘이고, X는 알카리금속, 알카리토류 금속으로부터 선택된 최소한 하나의 원소이고, Y는 B,Al,Ti,Zr,Sn,Zn 및 Ce으로부터 선택된 최소한 하나의 원소이며, O는 산소임; 접미어 a,x,y방b는 원소 Si,X,Y 및 O의 원자수비를 각각 표시하며, a=1, x=0.005-1 및 y=0-1 일때 b는 a,x및 y에 의하여 정하여지는 수치임)]
  2. 제1항에 있어서, 옥사이드 조성물중에서 a=1 이면, X=0.01-0.6이고 y는 = 0.005-0.2인 촉매,
  3. 제1항에 있어서, 옥사이드 조성물이 하기 일반식으로 표시되는 촉매
    (식중 Si,X,O 및 접미어 a,b 및 x는 상기 정의와 같고, a=1, x=0.01-0.6 일때 b 는 a 및 x에 의하여 정해지는 수치임)
  4. 제1항에 있어서, 일반식(I)인 알카놀아민 중에서 n이 2인 촉매.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019860011138A 1985-12-23 1986-12-23 알칸올 아민의 증기상 분자내 탈수반응용 촉매 KR910005188B1 (ko)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
JP287924 1985-12-23
JP287924/85 1985-12-23
JP60287924A JPS62149337A (ja) 1985-12-23 1985-12-23 アルカノ−ルアミン類の気相分子内脱水反応用触媒
JP292540/85 1985-12-27
JP292540 1985-12-27
JP60292540A JPS62152539A (ja) 1985-12-27 1985-12-27 アルカノ−ルアミン類の気相分子内脱水反応用触媒

Publications (2)

Publication Number Publication Date
KR870005691A true KR870005691A (ko) 1987-07-06
KR910005188B1 KR910005188B1 (ko) 1991-07-23

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KR1019860011138A KR910005188B1 (ko) 1985-12-23 1986-12-23 알칸올 아민의 증기상 분자내 탈수반응용 촉매

Country Status (7)

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US (1) US4841060A (ko)
EP (1) EP0227461B1 (ko)
KR (1) KR910005188B1 (ko)
CN (1) CN1014059B (ko)
AU (1) AU591208B2 (ko)
CA (1) CA1276617C (ko)
DE (1) DE3675751D1 (ko)

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Also Published As

Publication number Publication date
CA1276617C (en) 1990-11-20
CN86108813A (zh) 1987-07-08
AU591208B2 (en) 1989-11-30
CN1014059B (zh) 1991-09-25
EP0227461B1 (en) 1990-11-22
EP0227461A3 (en) 1988-07-27
US4841060A (en) 1989-06-20
KR910005188B1 (ko) 1991-07-23
EP0227461A2 (en) 1987-07-01
AU6666486A (en) 1987-06-25
DE3675751D1 (de) 1991-01-03

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