KR870002244A - Low phosphate or phosphate-free liquid non-aqueous nonionic laundry detergent composition and washing method using same - Google Patents

Low phosphate or phosphate-free liquid non-aqueous nonionic laundry detergent composition and washing method using same Download PDF

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KR870002244A
KR870002244A KR1019860006828A KR860006828A KR870002244A KR 870002244 A KR870002244 A KR 870002244A KR 1019860006828 A KR1019860006828 A KR 1019860006828A KR 860006828 A KR860006828 A KR 860006828A KR 870002244 A KR870002244 A KR 870002244A
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detergent composition
enhancer
detergent
polymer
salt
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KR1019860006828A
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Korean (ko)
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기브로즈
바스땡 다니엘트
레떵 레오
우아디 트라졸라
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에이치 에스 실베스터
콜게이트-파아므올리브 캄파니
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Priority claimed from US06/767,570 external-priority patent/US4655954A/en
Application filed by 에이치 에스 실베스터, 콜게이트-파아므올리브 캄파니 filed Critical 에이치 에스 실베스터
Publication of KR870002244A publication Critical patent/KR870002244A/en

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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0004—Non aqueous liquid compositions comprising insoluble particles
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3711—Polyacetal carboxylates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

내용 없음No content

Description

저인산염 또는 인산염이 없는 액상의 비수성 이온오계 세탁용 세제 조성물 및 이를 사용한 세탁방법Low phosphate or phosphate-free liquid nonaqueous ion-based laundry detergent composition and washing method using the same

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (16)

최소한 하나의 액상 비인온 계면활성제 세제, 히드록시 아크릴산 또는 아크릴산 염 중합체 증강제 또는 유기폴리아세탈 카르복시레이트 증강제염, 산 말단의 비이온 계면활성제 겔-억제제 및 알킬렌 글리콜모노알킬 에테르로 구성된 군으로부터 선택된 최소한 나하의 원, 및 침강 방지제로 구성된 비수성의 액상강력 세탁용 세제 조성물.At least one liquid non-ionic surfactant detergent, hydroxy acrylic acid or acrylate salt polymer enhancer or organopolyacetal carboxylate enhancer salt, at least a non-ionic surfactant gel-inhibitor at the acid end and an alkylene glycol monoalkyl ether A non-aqueous liquid strong laundry detergent composition consisting of a Naha circle and a sedimentation inhibitor. 제1항에 있어서, 히드록시 아크릴산 또는 히드록시 아크릴산 염 중합체 세제 증강제 또는 폴리아세틸카르복시레이트 세제 증강제 염 5-50%를 포함하는 세제 조성물.The detergent composition of claim 1 comprising 5-50% of hydroxy acrylic acid or hydroxy acrylic acid salt polymer detergent enhancer or polyacetylcarboxylate detergent enhancer salt. 제1항에 있어서, 히드록시 아크릴산 중합체 세제증강제가 하기 일반식의 단량체 단위를 포함하는 세제조성물.The detergent composition according to claim 1, wherein the hydroxy acrylic polymer detergent builder comprises a monomer unit of the following general formula. 상기식에서, R1및 R2는 같거나 다를 수 있고 수소 및 탄수소 1-3의 알킬로 구성된 군으로 부터 선택하고 M은 수소, 알카리금속, 알카리금속 및 암모늄 양이온으로 구성된 군으로 부터 선택된다.Wherein R 1 and R 2 may be the same or different and are selected from the group consisting of hydrogen and alkyl of hydrocarbon 1-3 and M is selected from the group consisting of hydrogen, alkali metal, alkali metal and ammonium cation. 제1항에 있어서, 최소한 하나의 액상비이온 계면활성제 약 25-50%, 산-말단 비이온 계면활성제 약 2-20%, 알킬렌 글리콜 모노알킬 에테르 약 5-20%, 히드록시 아크릴레이트 중합체 증강제 약10-30%, 및 알칸올 인산에스테르 약 0.1-1.0%로 구성된 세제 조성물.The method of claim 1, wherein at least one liquid nonionic surfactant is about 25-50%, acid-terminated nonionic surfactant is about 2-20%, alkylene glycol monoalkyl ether about 5-20%, hydroxy acrylate polymer A detergent composition consisting of about 10-30% enhancer, and about 0.1-1.0% alkanol phosphate ester. 제4항에 있어서, 히드록시 아크릴산 중합체 세제 증강제가 하기 일반식의 단량체 단위를 포함하는 세제 조성물.The detergent composition according to claim 4, wherein the hydroxy acrylic acid polymer detergent enhancer comprises monomer units of the following general formula. 상기식에서, R1및 R2는 같거나 다를 수 있고 수소, 메틸, 에틸 및 프로필로 구성된 군에서 선택되고, M은 나트륨 및 칼륨으로 구성된 군에서 선택되고 n값은 중합체가 수용성일 수 있게 선택된다.Wherein R 1 and R 2 may be the same or different and are selected from the group consisting of hydrogen, methyl, ethyl and propyl, M is selected from the group consisting of sodium and potassium and the n value is selected such that the polymer is water soluble. . 비이온 계면 활성제 30-55%Nonionic surfactant 30-55% 산-말단 계면활성제 1-10%Acid-Terminal Surfactants 1-10% 알킬렌 글리콜 모노알킬 에테르 3-15%Alkylene glycol monoalkyl ether 3-15% 히드록시 아크릴레이트 중합체 나트륨 염 증강제 7-22%Hydroxy acrylate polymer sodium salt enhancer 7-22% 인산의 C16-C18알칸올 에스테르 0.1-0.9%C 16 -C 18 alkanol ester of phosphoric acid 0.1-0.9% 과붕산 나트륨염 일수화물 표백제 10-22%Sodium Perborate Salt Monohydrate Bleach 10-22% 레트라아세틸에틸렌디아민 표백활성제 4-15%Retraacetylethylenediamine Bleach 4-15% 로 구성된 인산염 세제 증강제가 없는 비수성의 액상 강력 세탁용 세제 조성물.Non-aqueous liquid strong laundry detergent composition without a phosphate detergent enhancer consisting of. 제6항에 있어서, 히드록시 아크릴레이트 중합체가 2000-20,000의 분자량을 갖는 세제 조성물.7. The detergent composition of claim 6, wherein the hydroxy acrylate polymer has a molecular weight of 2000-20,000. 제1항에 있어서, 폴리아세탈 카르복시레이트가 하기 일반식을 갖는 세제 조성물,The detergent composition according to claim 1, wherein the polyacetal carboxylate has the general formula 상기식에서 M은 알카리금속, 암모늄, 탄소수 1-4의 알킬기, 테트라알킬 암모늄기 및 알킬 사슬내의 탄소수가 1-4인 알칸올 아민기로 구성된 군으로부터 선택되고, n은 최소한 4이고, R1및 R2는 알칼리 용액에서 해중합에 대해 중합체를 안정시키는 개개의 안정기로 선택되고 비이온의 액상 세제 조성물의 성분과 양립할 수 있는 것으로 선택된다.Wherein M is selected from the group consisting of alkali metals, ammonium, alkyl groups of 1-4 carbon atoms, tetraalkyl ammonium groups and alkanol amine groups of 1-4 carbon atoms in the alkyl chain, n is at least 4, and R 1 and R 2 Is selected as the individual ballast to stabilize the polymer against depolymerization in alkaline solution and is compatible with the components of the nonionic liquid detergent composition. 제1항에 있어서,The method of claim 1, 최소한 하나의 액상의 비이온 계면활성제 약 25-50%,About 25-50% of at least one liquid nonionic surfactant, 폴리아세탈 카르복시레이트 증강제 약 10-30%Polyacetal carboxylate enhancer about 10-30% 다중인산염 세제 증강제 약 0-20% 및,About 0-20% of a polyphosphate detergent enhancer and, 알칸올 인산 에스테르 약 0.1-1.0%Alkanol Phosphate Esters about 0.1-1.0% 로 구성되고, 다중인산염이 없거나 적은 세탁용 세제 조성물.A laundry detergent composition consisting of, low or no polyphosphate. 제9항에 있어서, 폴리아세탈 카르복시레이트가 하기 일반식을 갖는 세제 조성물,The detergent composition according to claim 9, wherein the polyacetal carboxylate has the general formula 상기식에서 M은 알카리 금속이고, n은 50-200이고, R1및 R2는 알카리 용액에서 해중합에 대해 중합체를 안정시키는 개개의 안정기로 선택되고, 비이온 액상 세제 조성물의 성분과 양립할 수 있는 것으로 선택된다.Wherein M is an alkali metal, n is 50-200, R 1 and R 2 are selected as individual ballasts to stabilize the polymer against depolymerization in alkaline solution and are compatible with the components of the nonionic liquid detergent composition. Is selected. 비이온 계면 활성제 약 30-45%Nonionic surfactant about 30-45% 산-말단 계면활성제 약 2-18%Acid-Terminal Surfactant About 2-18% 폴리아세탈 카르복실산의 나트륨염 약 5-22%Sodium salt of polyacetal carboxylic acid about 5-22% 인산의 C16-C18알칸올 에스테르 약0.1-0.9%C 16 -C 18 alkanol ester of phosphoric acid about 0.1-0.9% 과붕산나트륨염일 수화물 표백제 약 7-22%Sodium perborate salt monohydrate bleach about 7-22% 테트라아세틸에틸렌디아민(TAED) 표백활성제 약 4-12%Tetraacetylethylenediamine (TAED) bleach about 4-12% 로 구성된 인산염 세제 증강제가 없는 비수성의 액상 강력 세탁용 세제 조성물.Non-aqueous liquid strong laundry detergent composition without a phosphate detergent enhancer consisting of. 제11항에 있어서, 폴리아세틸 카르복시레이트가 하기 일반식을 갖고 폴리아세탈 카르복시레이트 단편이 총 폴리아세탈 카르복시레이트 중량의 50-80%를 구성하는 세제 조성물.12. The detergent composition of claim 11, wherein the polyacetyl carboxylate has the following general formula and the polyacetal carboxylate fragment comprises 50-80% of the total polyacetal carboxylate weight. 상기식에서 M은 나트륨 및 칼륨으로 구성된 군으로 부터 선택되고 n은 50-200이고또는 Wherein M is selected from the group consisting of sodium and potassium and n is 50-200 or 제12항에 있어서, 폴리아세탈 카르복시레이트가 니트륨염이고 R1이 인정화 말단기인 세제조성물.13. The detergent composition according to claim 12, wherein the polyacetal carboxylate is a nitrile salt and R 1 is an accepting end group. 제3항 또는 제11항에 있어서, 알카리금속 과붕산염 일수화물 표백제 약 5-30%, 테트라에틸에틸렌디아민 표백활성제 약 5-20%, 및 형광증백제, 효소 및 향료로 구성된 군으로 부터 선택된 임의의 하나 또는 그 이상의 세제 보조제를 포함하는 세제 조성물.12. The compound according to claim 3 or 11, wherein the alkali metal perborate monohydrate bleach is about 5-30%, the tetraethylethylenediamine bleach is about 5-20%, and any selected from the group consisting of fluorescent brighteners, enzymes and flavorings. A detergent composition comprising one or more detergent auxiliaries. 제6항의 세탁용 세제 조성물을 더러워진 직물에 접촉시키는 것으로 구성된 더러워진 직물의 세탁방법.A method of washing a soiled fabric, comprising contacting the laundry detergent composition of claim 6 with the soiled fabric. 제11항의 세탁용 세제 조성물을 더러워진 직물에 접촉시키는 것으로 구성된 더러워진 직물의 세탁방법.A method of washing a soiled fabric, comprising contacting the soil detergent composition of claim 11 with a soiled fabric. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019860006828A 1985-08-20 1986-08-19 Low phosphate or phosphate-free liquid non-aqueous nonionic laundry detergent composition and washing method using same KR870002244A (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US76753585A 1985-08-20 1985-08-20
US06/767,570 US4655954A (en) 1985-08-20 1985-08-20 Low phosphate or phosphate free nonaqueous liquid nonionic laundry detergent composition and method of use
US767570 1985-08-20
US767535 1996-12-16

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GR79172B (en) * 1983-01-28 1984-10-02 Procter & Gamble
NZ211550A (en) * 1984-04-06 1987-06-30 Colgate Palmolive Co Liquid detergent composition containing acidic phosphorus compound and polyphosphate
ZA852201B (en) * 1984-04-09 1986-11-26 Colgate Palmolive Co Liquid bleaching laundry detergent composition
ZA852200B (en) * 1984-04-09 1986-11-26 Colgate Palmolive Co Liquid laundry detergent composition
US4753750A (en) * 1984-12-31 1988-06-28 Delaware Liquid laundry detergent composition and method of use

Also Published As

Publication number Publication date
PT83191B (en) 1987-12-15
GB2179365B (en) 1989-08-02
GR862159B (en) 1986-12-24
IT1196578B (en) 1988-11-16
AT396113B (en) 1993-06-25
DK168397B1 (en) 1994-03-21
HK68892A (en) 1992-09-18
NO863334L (en) 1987-02-23
FR2586424B1 (en) 1993-11-12
DK379486A (en) 1987-02-21
NL8602119A (en) 1987-03-16
SE8603447D0 (en) 1986-08-18
MX168222B (en) 1993-05-13
NZ216987A (en) 1988-09-29
NO863334D0 (en) 1986-08-19
CH671235A5 (en) 1989-08-15
SG72792G (en) 1992-10-02
NO169782C (en) 1992-08-05
BR8603960A (en) 1987-03-31
ATA218486A (en) 1992-10-15
PT83191A (en) 1986-09-01
ZW15486A1 (en) 1987-07-01
ES2001237A6 (en) 1988-05-01
DE3626572A1 (en) 1987-02-26
GB2179365A (en) 1987-03-04
EG18069A (en) 1991-11-30
IL79635A0 (en) 1986-11-30
GB8619793D0 (en) 1986-09-24
DK379486D0 (en) 1986-08-08
NO169782B (en) 1992-04-27
AU590781B2 (en) 1989-11-16
FR2586424A1 (en) 1987-02-27
BE905290A (en) 1987-02-19
LU86558A1 (en) 1987-03-06
AU6081086A (en) 1987-02-26
IT8648379A0 (en) 1986-08-13
SE8603447L (en) 1987-02-21
SE468598B (en) 1993-02-15

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