KR830009030A - 페녹시 피리딜 메틸 에스테르의 제조방법 - Google Patents

페녹시 피리딜 메틸 에스테르의 제조방법 Download PDF

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KR830009030A
KR830009030A KR1019820001288A KR820001288A KR830009030A KR 830009030 A KR830009030 A KR 830009030A KR 1019820001288 A KR1019820001288 A KR 1019820001288A KR 820001288 A KR820001288 A KR 820001288A KR 830009030 A KR830009030 A KR 830009030A
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South Korea
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general formula
diluent
halogen
reaction
carboxylic acid
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KR1019820001288A
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KR880001864B1 (ko
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푸크스 라이너
함만 잉게보르그
호메이어 베른하르트
스텐델 빌헬름
Original Assignee
게르하르트 뷔네만, 에리히 데브리쯔
바이엘 아크티엔 게젤샤프트
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Publication of KR830009030A publication Critical patent/KR830009030A/ko
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/62—Oxygen or sulfur atoms
    • C07D213/63—One oxygen atom
    • C07D213/64—One oxygen atom attached in position 2 or 6
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/62—Oxygen or sulfur atoms
    • C07D213/63—One oxygen atom
    • C07D213/64—One oxygen atom attached in position 2 or 6
    • C07D213/643—2-Phenoxypyridines; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/62—Oxygen or sulfur atoms
    • C07D213/63—One oxygen atom
    • C07D213/64—One oxygen atom attached in position 2 or 6
    • C07D213/647—One oxygen atom attached in position 2 or 6 and having in the molecule an acyl radical containing a saturated three-membered ring, e.g. chrysanthemumic acid esters

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Pyridine Compounds (AREA)

Abstract

내용 없음

Description

페녹시 피리딜 메틸 에스테르의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (12)

  1. 다음 일반식(II)의 카복실산 또는 이의 반응성 유도체를 다음 일반식(III)의 페녹시피리딜 알콜 또는 이의 반응성 유도체와 반응시킴을 특징으로하는 다음 일반식(I)의 페녹시피리딜메틸 에스테르의 제조방법.
    상기 일반식에서
    R은 다음 일반식의 래디칼
    (여기에서 R4는 수소, 염소 또는 브롬원자, 시아노기 또는 임의로 할로겐으로 치환된 알킬기이고 R5는 수소 또는 할로겐원자 또는 임의로 할로겐으로 치환된 알킬 또는 알콕시기임)또는 R은 다음 일반식의 래다칼
    (여기에서 R6는 이소프로필 또는 시클로프로필기이고 R7은 소수, 불소원자 또는 트리플루오로메틸 또는 클로로-(디)플루오로메틸기임)이고
    R1은 수소원자 또는 시아노, 탄소수 4이하의 알킬 알케닐 또는 알키닐기로서 할로겐에 의해 임의로 치환되며,
    R2및 R3는 같거나 서로 다르며 수소 또는 할로겐원자이다.
  2. 제1항에 있어서, 반응을 산수용체 존재하에 수행하는 방법.
  3. 제1항 또는 제2항에 있어서, 반응을 촉매존재하에 수행하는 방법.
  4. 제1항 또는 제3항에 있어서, 반응을 희석제 존재하에 수행하는 방법.
  5. 제4항에 있어서, 희석제가 불활성 유기용매인 방법.
  6. 제1항에 있어서, 일반식 R-CO-C(IIa)의 카복실산 클로라이드를 일반식(III)의 페녹시피리딜 알콜과 산수용체 및 희석제존재하에 반응시키는 방법.
    상기 일반식에서, R은 제1항에서 정의된 바와 같다.
  7. 제1항에 있어서, 일반식 R-CO-C(IIa)의 카복실산 클로라이드를 다음 일반식(IV)의 페녹시 카브알데히드 및 등몰량이상의 나트륨 시아나이드 또는 칼륨 시아나이드와 물 및 수-불혼화성 유기용매 존재하에, 필요시에는 촉매 존재하에 반응시킴을 특징으로 하는, R1이 시아노기인 제1항의 화합물을 제조하는 방법.
    상기 일반식에서
    R2및 R3는 제1항에 정의된 바와같다.
  8. 제1항 내지 제7항에 있어서, 반응을 0내지 100℃의 온도에서 수행하는 방법.
  9. 제1항 내지 제7항에 있어서, 반응물이 상기에서 언급된 반응물 모두가 해당되는 방법.
  10. 제1항에 있어서, 실제적으로 실시예 1내지 10중의 어느 하나에 기술된 방법.
  11. 활성성분으로 제1항의 화합물을 고체 또는 액화가스 희석제 또는 담체와의 혼합물로 또는 액체희석제 또는 계면활성제가 함유된 담체와의 혼합물로 함유시킨 농약조성물.
  12. 제11항에 있어서, 유효성분 0.1 내지 95중량%가 함유된 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR8201288A 1981-03-25 1982-03-25 페녹시피리딜메틸 에스테르의 제조방법 KR880001864B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DEP3111644.2 1981-03-25
DE19813111644 DE3111644A1 (de) 1981-03-25 1981-03-25 Phenoxypyridylmethylester, verfahren zu ihrer herstellung und ihre verwendung in schaedlingsbekaempfungsmitteln

Publications (2)

Publication Number Publication Date
KR830009030A true KR830009030A (ko) 1983-12-17
KR880001864B1 KR880001864B1 (ko) 1988-09-23

Family

ID=6128193

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KR8201288A KR880001864B1 (ko) 1981-03-25 1982-03-25 페녹시피리딜메틸 에스테르의 제조방법

Country Status (15)

Country Link
US (1) US4491585A (ko)
EP (1) EP0061114B1 (ko)
JP (1) JPS57169461A (ko)
KR (1) KR880001864B1 (ko)
AU (1) AU548247B2 (ko)
BR (1) BR8201665A (ko)
CA (1) CA1162925A (ko)
DE (2) DE3111644A1 (ko)
DK (1) DK133982A (ko)
ES (1) ES8303344A1 (ko)
HU (1) HU188313B (ko)
IL (1) IL65311A (ko)
NZ (1) NZ200086A (ko)
OA (1) OA07046A (ko)
ZA (1) ZA821983B (ko)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0150678B1 (de) * 1984-01-12 1989-03-01 Ciba-Geigy Ag Cyclopropancarbonsäure-alpha-methyl-(6-phenoxy)-2-picolylester
US4694013A (en) * 1985-11-08 1987-09-15 E. I. Du Pont De Nemours And Company Insecticidal and acaricidal phenoxypyrdinyl esters and intermediates
FR2629452B1 (fr) * 1988-03-31 1990-11-09 Roussel Uclaf Nouveau procede de preparation de derives trifluoromethylvinyliques a partir de derives halogenovinyliques correspondants

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4183942A (en) * 1976-08-27 1980-01-15 Fmc Corporation Insecticidal (β-phenyl-β-substituted-vinyl)cyclopropanecarboxylates
US4163787A (en) * 1977-03-14 1979-08-07 The Dow Chemical Company Substituted pyridine methyl esters of cyclopropane carboxylic acids and their use as insecticides
JPS56147770A (en) * 1980-04-15 1981-11-16 Sumitomo Chem Co Ltd Novel carboxylic ester, its preparation and insecticide and acaricide containing the same as active constituent
FR2486078A1 (fr) * 1980-07-04 1982-01-08 Roussel Uclaf Nouveaux esters de l'acide cyclopropane carboxylique, leur procede de preparation et leur application a la lutte contre les parasites
US4285954A (en) * 1980-11-19 1981-08-25 Zoecon Corporation Pesticidal S-pyridyl thioesters of phenylbutanoic acids and derivatives thereof

Also Published As

Publication number Publication date
ES510752A0 (es) 1983-02-01
DE3261501D1 (en) 1985-01-24
EP0061114B1 (de) 1984-12-12
AU548247B2 (en) 1985-12-05
CA1162925A (en) 1984-02-28
DE3111644A1 (de) 1982-10-07
NZ200086A (en) 1984-11-09
AU8185282A (en) 1982-09-30
KR880001864B1 (ko) 1988-09-23
EP0061114A1 (de) 1982-09-29
ES8303344A1 (es) 1983-02-01
US4491585A (en) 1985-01-01
DK133982A (da) 1982-09-26
BR8201665A (pt) 1983-02-16
ZA821983B (en) 1983-02-23
IL65311A (en) 1985-12-31
IL65311A0 (en) 1982-05-31
HU188313B (en) 1986-04-28
JPS57169461A (en) 1982-10-19
OA07046A (fr) 1983-12-31

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