KR830006371A - 비초벌 플라스틱 기질에 사용하는 실리콘 피복조성물 및 피복된 제품 - Google Patents

비초벌 플라스틱 기질에 사용하는 실리콘 피복조성물 및 피복된 제품 Download PDF

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KR830006371A
KR830006371A KR1019810001910A KR810001910A KR830006371A KR 830006371 A KR830006371 A KR 830006371A KR 1019810001910 A KR1019810001910 A KR 1019810001910A KR 810001910 A KR810001910 A KR 810001910A KR 830006371 A KR830006371 A KR 830006371A
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mole
alkyl
halogen
hydrogen
weight
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KR1019810001910A
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KR840001744B1 (ko
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타-엔칭
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아더 엠 킹
제네랄 일렉트릭 캄파니
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04—Polysiloxanes

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Paints Or Removers (AREA)
  • Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
  • Laminated Bodies (AREA)
  • Silicon Polymers (AREA)

Abstract

내용 없음

Description

비초벌된 플라스틱 기질에 사용하는 실리콘 피복조성물 및 피복된 제품
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (3)

  1. (a) 구조식RSi(OH)3실란올의 유기용매 수용액중의 클로이드성 실리카 분산액(여기서 실란올의 50% 이상이 CH3Si(OH)3이고 유기용매는 지방족 알코올이며 (a)성분에는 10 내지 70중량%의 클로이드성 실리카와 30 내지 90중량%의 부분적 축합물로 이루어진 고체 10 내지 40%이 함유된다)과
    (b) 다음 구조식을 갖는 알콕시실란-작용화 지방족 자외선 흡수 화합물 안정화량으로 이루어진 혼합물을 10℃이상, pH 6.6 내지 7.8 또는 내지 3.8에서 2시간 이상 혼성 가수분해시켜, 초벌제없이 플라스틱 기질에 접착시키는데 유용한 수성 혼성 가수분해물을 제조하는 방법.
    상기 구조식에서
    R은 C1-3알킬 또는 C1-13아릴이고
    R1은 수소, C1-C8알킬 또는 할로겐이고
    R2는 C1-C8알킬이고
    R3및 R4는 수소, C1-C8알콕시, 카복시, 할로겐, 하이드록스, 아미노, 카브에톡시 또는 -Q-(CH2)3Si(OR2)3(여기서 Q는 -NH-또는 -0-임)이고
    a는 1 내지 3의 정수이다.
  2. (C) 55 내지 90중량%의 용매(주로 물과 C1-8알칸올로 구성됨)와
    (d) 40 내지 75몰%의 RSiO1.5단위 및 0 내지 10몰%(R)2(SiO) 단위 및 0.5 내지 5몰%의 (Z)d 단위와 화학적으로 결합된 25 내지 50몰%의 SiO2로 구성된 오르가노폴리 실록산(여기서 화학적으로 결합된 총단위는 100몰%임)으로 이루어진 혼성 가수분해물 10 내지 45중량%로 구성되며, 초벌제 사용없이 열가소성 기질에 사용하였을때 적어도 하나의 내마모성 UV안정성을 갖는 피복 표면을 갖는합성물이 형성됨을 특징으로 하는 비초벌 열가소성 기질의 최외각 피복물로 사용되는 피복조성물.
    상기식에서
    d는 1 내지 3의 정수이고
    z는 다음 구조식의 그룹이다.
    (여기서 R1은 수소, C1-C8알킬 또는 할로겐이고
    R3및 R4는 수소, C1-C8알콕시, 카복시, 할로겐, 하이드록스, 아미노, 카브에톡시 또는 -Q-(CH2)3Si(OR2)3이고
    R2는 C1-C8알킬이고
    Q는 -NH- 또는 -0-이다).
  3. (C) 55 내지 90중량%의 용매(주로 물과 C1-8알칸올로 구성됨)와
    (d) 40 내지 75몰%의 RSiO1.5단위 및 0 내지 10몰%(R)2(SiO) 단위 및 0.5 내지 5몰%의 (Z)d 단위와 화학적으로 결합된 25 내지 50몰%의 SiO2로 구성된 오르가노폴리 실록산(여기서 화학적으로 결합된 총단위는 100몰%임)으로 이루어진 혼성 가수분해물 10 내지 45중량%로 구성된 수성의 피복조성물을 비초벌기질상에 피복시켜 내마모성 피막을 형성시키는 방법.
    상기식에서
    d는 1 내지 3의 정수이고
    z는 다음 구조식의 그룹이다.
    (여기서 R1은 수소, C1-C8알킬 또는 할로겐이고
    R3및 R4는 수소, C1-C8알콕시, 카복시, 할로겐, 하이드록스, 아미노, 카브에톡시 또는 -Q-(CH2)3Si(OR2)3이고
    R2는 C1-C8알킬이고
    Q는 -NH- 또는 -0-이다).
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019810001910A 1980-05-30 1981-05-29 실리콘 피복조성물의 제조방법 KR840001744B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US154624 1980-05-30
US06/154,624 US4373061A (en) 1980-05-30 1980-05-30 Silicone coating for unprimed plastic substrate and coated articles
US154,624 1980-05-30

Publications (2)

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KR830006371A true KR830006371A (ko) 1983-09-24
KR840001744B1 KR840001744B1 (ko) 1984-10-18

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US (1) US4373061A (ko)
JP (1) JPS5721432A (ko)
KR (1) KR840001744B1 (ko)
AU (1) AU7119181A (ko)
BR (1) BR8103496A (ko)
DE (1) DE3120853A1 (ko)
ES (1) ES8207568A1 (ko)
FR (1) FR2483436A1 (ko)
GB (1) GB2078242B (ko)

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Also Published As

Publication number Publication date
ES502636A0 (es) 1982-10-01
JPH0345095B2 (ko) 1991-07-10
AU7119181A (en) 1981-12-03
BR8103496A (pt) 1982-02-24
FR2483436B1 (ko) 1984-12-21
KR840001744B1 (ko) 1984-10-18
JPS5721432A (en) 1982-02-04
US4373061A (en) 1983-02-08
DE3120853A1 (de) 1982-02-18
ES8207568A1 (es) 1982-10-01
FR2483436A1 (fr) 1981-12-04
GB2078242A (en) 1982-01-06
GB2078242B (en) 1984-12-12

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