KR20230162303A - Composition for deodorant blind, chip for deodorant blind and deodorant blind using the same - Google Patents
Composition for deodorant blind, chip for deodorant blind and deodorant blind using the same Download PDFInfo
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- KR20230162303A KR20230162303A KR1020220062007A KR20220062007A KR20230162303A KR 20230162303 A KR20230162303 A KR 20230162303A KR 1020220062007 A KR1020220062007 A KR 1020220062007A KR 20220062007 A KR20220062007 A KR 20220062007A KR 20230162303 A KR20230162303 A KR 20230162303A
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- deodorizing
- weight
- blinds
- blind
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- 239000000203 mixture Substances 0.000 title claims abstract description 38
- 239000002781 deodorant agent Substances 0.000 title description 5
- 230000001877 deodorizing effect Effects 0.000 claims abstract description 131
- 229920005989 resin Polymers 0.000 claims description 44
- 239000011347 resin Substances 0.000 claims description 44
- 239000004014 plasticizer Substances 0.000 claims description 30
- 239000000463 material Substances 0.000 claims description 19
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 16
- 239000003063 flame retardant Substances 0.000 claims description 16
- 238000006116 polymerization reaction Methods 0.000 claims description 12
- 239000003963 antioxidant agent Substances 0.000 claims description 11
- 239000012760 heat stabilizer Substances 0.000 claims description 11
- OEIWPNWSDYFMIL-UHFFFAOYSA-N dioctyl benzene-1,4-dicarboxylate Chemical compound CCCCCCCCOC(=O)C1=CC=C(C(=O)OCCCCCCCC)C=C1 OEIWPNWSDYFMIL-UHFFFAOYSA-N 0.000 claims description 10
- 230000003078 antioxidant effect Effects 0.000 claims description 9
- 239000012963 UV stabilizer Substances 0.000 claims description 8
- 239000000314 lubricant Substances 0.000 claims description 8
- 239000004743 Polypropylene Substances 0.000 claims description 6
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 6
- -1 polypropylene Polymers 0.000 claims description 6
- 229920001155 polypropylene Polymers 0.000 claims description 6
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 6
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 5
- 239000001110 calcium chloride Substances 0.000 claims description 5
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 5
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 claims description 5
- 239000000155 melt Substances 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- 239000004800 polyvinyl chloride Substances 0.000 claims description 5
- 239000002952 polymeric resin Substances 0.000 claims description 4
- 229920003002 synthetic resin Polymers 0.000 claims description 4
- 239000004814 polyurethane Substances 0.000 claims description 3
- 150000002505 iron Chemical class 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 30
- 230000001747 exhibiting effect Effects 0.000 abstract description 4
- 230000000052 comparative effect Effects 0.000 description 14
- 235000019645 odor Nutrition 0.000 description 11
- 239000012964 benzotriazole Substances 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- 239000000835 fiber Substances 0.000 description 6
- 238000001125 extrusion Methods 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 239000003017 thermal stabilizer Substances 0.000 description 5
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- 159000000014 iron salts Chemical class 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- 230000000704 physical effect Effects 0.000 description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 238000004332 deodorization Methods 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- 238000009413 insulation Methods 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000001179 sorption measurement Methods 0.000 description 3
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 3
- HJIAMFHSAAEUKR-UHFFFAOYSA-N (2-hydroxyphenyl)-phenylmethanone Chemical compound OC1=CC=CC=C1C(=O)C1=CC=CC=C1 HJIAMFHSAAEUKR-UHFFFAOYSA-N 0.000 description 2
- 238000003763 carbonization Methods 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000002845 discoloration Methods 0.000 description 2
- 238000001879 gelation Methods 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000009987 spinning Methods 0.000 description 2
- WVLBCYQITXONBZ-UHFFFAOYSA-N trimethyl phosphate Chemical compound COP(=O)(OC)OC WVLBCYQITXONBZ-UHFFFAOYSA-N 0.000 description 2
- AZSKHRTUXHLAHS-UHFFFAOYSA-N tris(2,4-di-tert-butylphenyl) phosphate Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(=O)(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C AZSKHRTUXHLAHS-UHFFFAOYSA-N 0.000 description 2
- 238000004383 yellowing Methods 0.000 description 2
- XCPFSALHURPPJE-UHFFFAOYSA-N (3,5-ditert-butyl-4-hydroxyphenyl) propanoate Chemical compound CCC(=O)OC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 XCPFSALHURPPJE-UHFFFAOYSA-N 0.000 description 1
- GBZVNKQWXLVYNG-UHFFFAOYSA-N (3-phosphonooxyphenyl) dihydrogen phosphate Chemical compound OP(O)(=O)OC1=CC=CC(OP(O)(O)=O)=C1 GBZVNKQWXLVYNG-UHFFFAOYSA-N 0.000 description 1
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 description 1
- ROHFBIREHKPELA-UHFFFAOYSA-N 2-[(3,5-ditert-butyl-4-hydroxyphenyl)methyl]prop-2-enoic acid;methane Chemical compound C.CC(C)(C)C1=CC(CC(=C)C(O)=O)=CC(C(C)(C)C)=C1O.CC(C)(C)C1=CC(CC(=C)C(O)=O)=CC(C(C)(C)C)=C1O.CC(C)(C)C1=CC(CC(=C)C(O)=O)=CC(C(C)(C)C)=C1O.CC(C)(C)C1=CC(CC(=C)C(O)=O)=CC(C(C)(C)C)=C1O ROHFBIREHKPELA-UHFFFAOYSA-N 0.000 description 1
- ANHAEBWRQNIPEV-UHFFFAOYSA-N 2-chloroethyl dihydrogen phosphate Chemical compound OP(O)(=O)OCCCl ANHAEBWRQNIPEV-UHFFFAOYSA-N 0.000 description 1
- JVYZLBBNUCRSNR-UHFFFAOYSA-N 2-phenyl-1,3-benzothiazol-4-ol Chemical compound N=1C=2C(O)=CC=CC=2SC=1C1=CC=CC=C1 JVYZLBBNUCRSNR-UHFFFAOYSA-N 0.000 description 1
- WPMYUUITDBHVQZ-UHFFFAOYSA-M 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=CC(CCC([O-])=O)=CC(C(C)(C)C)=C1O WPMYUUITDBHVQZ-UHFFFAOYSA-M 0.000 description 1
- VKJLYEDTHCTCOH-UHFFFAOYSA-N 3-(3-octadecoxy-3-oxopropyl)sulfanylpropanoic acid Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCSCCC(O)=O VKJLYEDTHCTCOH-UHFFFAOYSA-N 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-M 4-hydroxybenzoate Chemical compound OC1=CC=C(C([O-])=O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-M 0.000 description 1
- 239000004114 Ammonium polyphosphate Substances 0.000 description 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- GHKOFFNLGXMVNJ-UHFFFAOYSA-N Didodecyl thiobispropanoate Chemical compound CCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCC GHKOFFNLGXMVNJ-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 1
- 229920000388 Polyphosphate Polymers 0.000 description 1
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 1
- WOURXYYHORRGQO-UHFFFAOYSA-N Tri(3-chloropropyl) phosphate Chemical compound ClCCCOP(=O)(OCCCCl)OCCCCl WOURXYYHORRGQO-UHFFFAOYSA-N 0.000 description 1
- JBTXGEJRJCNRLU-UHFFFAOYSA-N [2-(dihydroxyphosphanyloxymethyl)-3-hydroxy-2-(hydroxymethyl)propyl] dihydrogen phosphite Chemical compound OP(O)OCC(CO)(CO)COP(O)O JBTXGEJRJCNRLU-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 229920005822 acrylic binder Polymers 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 235000019826 ammonium polyphosphate Nutrition 0.000 description 1
- 229920001276 ammonium polyphosphate Polymers 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000012217 deletion Methods 0.000 description 1
- 230000037430 deletion Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- MCPKSFINULVDNX-UHFFFAOYSA-N drometrizole Chemical compound CC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 MCPKSFINULVDNX-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 239000010794 food waste Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- FTWUXYZHDFCGSV-UHFFFAOYSA-N n,n'-diphenyloxamide Chemical compound C=1C=CC=CC=1NC(=O)C(=O)NC1=CC=CC=C1 FTWUXYZHDFCGSV-UHFFFAOYSA-N 0.000 description 1
- 150000002816 nickel compounds Chemical class 0.000 description 1
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- 238000006303 photolysis reaction Methods 0.000 description 1
- DOIRQSBPFJWKBE-UHFFFAOYSA-N phthalic acid di-n-butyl ester Natural products CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- GDESWOTWNNGOMW-UHFFFAOYSA-N resorcinol monobenzoate Chemical compound OC1=CC=CC(OC(=O)C=2C=CC=CC=2)=C1 GDESWOTWNNGOMW-UHFFFAOYSA-N 0.000 description 1
- YGSDEFSMJLZEOE-UHFFFAOYSA-M salicylate Chemical compound OC1=CC=CC=C1C([O-])=O YGSDEFSMJLZEOE-UHFFFAOYSA-M 0.000 description 1
- 229960001860 salicylate Drugs 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- LVEOKSIILWWVEO-UHFFFAOYSA-N tetradecyl 3-(3-oxo-3-tetradecoxypropyl)sulfanylpropanoate Chemical compound CCCCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCCCC LVEOKSIILWWVEO-UHFFFAOYSA-N 0.000 description 1
- WBYWAXJHAXSJNI-VOTSOKGWSA-M trans-cinnamate Chemical class [O-]C(=O)\C=C\C1=CC=CC=C1 WBYWAXJHAXSJNI-VOTSOKGWSA-M 0.000 description 1
- KOWVWXQNQNCRRS-UHFFFAOYSA-N tris(2,4-dimethylphenyl) phosphate Chemical compound CC1=CC(C)=CC=C1OP(=O)(OC=1C(=CC(C)=CC=1)C)OC1=CC=C(C)C=C1C KOWVWXQNQNCRRS-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/16—Halogen-containing compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B11/00—Making preforms
- B29B11/06—Making preforms by moulding the material
- B29B11/10—Extrusion moulding
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0025—Crosslinking or vulcanising agents; including accelerators
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
-
- E—FIXED CONSTRUCTIONS
- E06—DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
- E06B—FIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
- E06B9/00—Screening or protective devices for wall or similar openings, with or without operating or securing mechanisms; Closures of similar construction
- E06B9/24—Screens or other constructions affording protection against light, especially against sunshine; Similar screens for privacy or appearance; Slat blinds
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Structural Engineering (AREA)
- Mechanical Engineering (AREA)
- Architecture (AREA)
- Civil Engineering (AREA)
- Curtains And Furnishings For Windows Or Doors (AREA)
Abstract
본 발명은 소취 블라인드용 조성물에 관한 것으로, 더욱 상세하게는 소취성능, 난연성 및 형태복원력이 우수한 동시에, 블라인드 제조 시 작업성이 우수한 효과를 발현하는 소취 블라인드용 조성물, 소취 블라인드용 칩 및 이를 통해 형성된 소취 블라인드에 관한 것이다.The present invention relates to a composition for deodorizing blinds, and more specifically, to a composition for deodorizing blinds that exhibits excellent deodorizing performance, flame retardancy, and shape restoration ability while also exhibiting excellent workability during blind manufacturing, chips for deodorizing blinds, and a product formed thereby. It's about deodorizing blinds.
Description
본 발명은 소취 블라인드용 조성물에 관한 것으로, 더욱 상세하게는 소취성능, 난연성 및 형태복원력이 우수한 동시에, 블라인드 제조 시 작업성이 우수한 효과를 발현하는 소취 블라인드용 조성물, 소취 블라인드용 칩 및 이를 통해 형성된 소취 블라인드에 관한 것이다.The present invention relates to a composition for deodorizing blinds, and more specifically, to a composition for deodorizing blinds that exhibits excellent deodorizing performance, flame retardancy, and shape restoration ability while also exhibiting excellent workability during blind manufacturing, chips for deodorizing blinds, and a product formed thereby. It's about deodorizing blinds.
최근, 일상 생활에 있어서의 취기(臭氣) 에 대한 관심이 높아지고 있고, 불쾌취 또는 악취를 저감시키기 위해, 실내 비치형이나 스프레이 타입의 소취 제품, 소취 벽지, 소취 의류 등의 다양한 소취 가공 제품이 제안되어 있다. 불쾌취 또는 악취로는, 음식물 쓰레기 등의 부패취, 인간 또는 동물의 배설취, 한취, 가령취, 가구나 가전으로부터 발생하는 알데히드, 담배의 연기 등을 들 수 있다.Recently, interest in odor in daily life has been increasing, and in order to reduce unpleasant odors or bad odors, various deodorizing products such as indoor beach or spray type deodorizing products, deodorizing wallpaper, and deodorizing clothing have been developed. It is proposed. Unpleasant odors or bad odors include rotting odors such as food waste, human or animal excrement odors, cold odors, old age odors, aldehydes generated from furniture and home appliances, cigarette smoke, etc.
종래에는 소취제로서 활성탄이 다수 제품에 적용되어 왔으나, 활성탄은 물리 적 흡착물질임에 따라, 다양한 용도에 대한 범용적 소취제로서의 사용은 곤란하다. 물리 흡착물질의 단점은 가스 성분은 무엇이든 흡착시키기 때문에, 개방 공간에서는 악취 이외의 가스를 계속 흡착함으로써, 흡착능이 빠르게 포화되어 버리는 것이다. 또한, 흡착량이 포화되거나 또는 온도가 높아지면 기흡착된 가스를 다시 방출할 수 있기 때문에, 새로운 악취원이 되는 문제가 있다. 따라서, 활성탄은 교체형 제품으로만 사용할 수 있었다.Conventionally, activated carbon has been applied to many products as a deodorant, but since activated carbon is a physically adsorbent material, it is difficult to use it as a general-purpose deodorant for various purposes. The disadvantage of physical adsorption materials is that since they adsorb any gas component, their adsorption capacity is quickly saturated as they continue to adsorb gases other than odors in open spaces. In addition, when the adsorption amount is saturated or the temperature increases, the previously adsorbed gas can be released again, so there is a problem of becoming a new source of odor. Therefore, activated carbon could only be used as a replacement product.
한편, 창문에 설치되는 블라인드는 차양과 같은 기본적인 기능이나 효과를 탈피하여 에너지 절감을 위한 보온성과 소취성 등이 향상된 기능성 블라인드의 제품이 점차적으로 개발되고 있다.Meanwhile, blinds installed on windows are gradually being developed as functional blinds with improved thermal insulation and deodorization properties for energy saving by breaking away from basic functions and effects such as sunshades.
이와 같이 실내 소취 및 보온성 향상을 위한 제품의 개발을 위해서는, 기본적으로 보온성이 우수한 섬유소재를 사용하여 두껍게 제작함으로써 일차적인 목적 달성이 가능하지만, 소재의 선택에 따른 비용의 문제를 무시할 수 없을 뿐만 아니라, 목적하는 수준의 소취 성능을 발현할 수 없는 문제가 있었다.In this way, in order to develop products to improve indoor deodorization and thermal insulation, the primary purpose can be achieved by manufacturing thickly using fiber materials with excellent thermal insulation, but the problem of cost depending on the choice of material cannot be ignored. , there was a problem that the deodorizing performance could not be achieved at the desired level.
따라서, 소취성능, 난연성 및 형태복원력이 우수한 동시에, 블라인드 제조 시 작업성이 우수한 효과를 발현하는 소취 블라인드용 조성물에 대한 연구가 시급한 실정이다.Therefore, there is an urgent need to research a composition for deodorizing blinds that has excellent deodorizing performance, flame retardancy, and shape restoration ability, while also exhibiting excellent workability when manufacturing blinds.
본 발명은 상술한 문제점을 해결하기 위해 안출된 것으로, 소취성능, 난연성 및 형태복원력이 우수한 동시에, 블라인드 제조 시 작업성이 우수한 효과를 발현하는 소취 블라인드용 조성물, 소취 블라인드용 칩 및 이를 통해 형성된 소취 블라인드를 제공하는데 목적이 있다.The present invention was developed to solve the above-mentioned problems, and is a composition for deodorizing blinds that has excellent deodorizing performance, flame retardancy, and shape recovery ability while also exhibiting excellent workability when manufacturing blinds, a chip for deodorizing blinds, and the deodorizing smell formed thereby. The purpose is to provide blinds.
상술한 과제를 해결하기 위해 본 발명은, 주제수지; 가소제; 및 상기 주제수지 100 중량부에 대하여 1 ~ 15 중량부로 포함되는 소취 물질;을 포함하는 소취 블라인드용 조성물을 제공한다.In order to solve the above-mentioned problem, the present invention, the subject resin; plasticizer; and a deodorizing material included in an amount of 1 to 15 parts by weight based on 100 parts by weight of the main resin.
본 발명의 일 실시예에 의하면, 상기 주제수지는 중합도(degree of polymerization)가 800 ~ 1200 인 고분자 수지일 수 있다.According to one embodiment of the present invention, the main resin may be a polymer resin with a degree of polymerization of 800 to 1200.
또한, 상기 주제수지 100 중량부에 대하여 상기 가소제를 20 ~ 50 중량부 포함할 수 있다.Additionally, 20 to 50 parts by weight of the plasticizer may be included based on 100 parts by weight of the main resin.
또한, 상기 주제수지는 폴리비닐클로라이드(PVC), 폴리우레탄(PU), 폴리프로필렌(PP) 및 폴리비닐알콜(PVA)로 이루어진 군에서 선택된 1종 이상을 포함할 수 있다.Additionally, the main resin may include one or more selected from the group consisting of polyvinyl chloride (PVC), polyurethane (PU), polypropylene (PP), and polyvinyl alcohol (PVA).
또한, 상기 가소제는 디옥틸 테레프탈레이트(DOTP)계 가소제 및 디프로필헵실 프탈레이트(DPHP)계 가소제 중 어느 하나 이상을 포함할 수 있다.Additionally, the plasticizer may include one or more of a dioctyl terephthalate (DOTP)-based plasticizer and a dipropylhexyl phthalate (DPHP)-based plasticizer.
또한, 상기 소취 물질은 염화칼슘, 염화구리 및 철염으로 이루어진 군에서 선택된 1종 이상을 포함할 수 있다.Additionally, the deodorizing substance may include one or more selected from the group consisting of calcium chloride, copper chloride, and iron salts.
또한, 상기 주제수지 100 중량부에 대하여 난연제를 1 ~ 7 중량부로 더 포함할 수 있다.In addition, 1 to 7 parts by weight of a flame retardant may be further included based on 100 parts by weight of the main resin.
또한, 상기 주제수지 100 중량부에 대하여 열 안정제를 0.1 ~ 1 중량부 및 UV 안정제를 0.1 ~ 1 중량부 더 포함할 수 있다.In addition, 0.1 to 1 part by weight of a heat stabilizer and 0.1 to 1 part by weight of a UV stabilizer may be further included based on 100 parts by weight of the main resin.
또한, 상기 주제수지 100 중량부에 대하여 활제를 0.05 ~ 0.5 중량부 및 산화방지제 0.1 ~ 1 중량부 더 포함할 수 있다.In addition, it may further include 0.05 to 0.5 parts by weight of a lubricant and 0.1 to 1 part by weight of an antioxidant based on 100 parts by weight of the main resin.
또한, 본 발명은 상술한 소취 블라인드용 조성물;을 통해 형성된 소취 블라인드용 칩을 제공한다.In addition, the present invention provides a chip for deodorizing blinds formed using the composition for deodorizing blinds described above.
본 발명의 일 실시예에 의하면, 상기 소취 블라인드용 칩은, 상기 소취 블라인드용 조성물을 130 ~ 190℃의 온도에서 압출시켜서 형성될 수 있다.According to one embodiment of the present invention, the chip for deodorizing blinds may be formed by extruding the composition for deodorizing blinds at a temperature of 130 to 190°C.
또한, 상기 소취 블라인드용 칩은, 쇼어 A(shore A) 경도가 80 ~ 115이고, 온도 200℃ 및 하중 2.16 kg의 조건에서 측정한 용융지수(melt index)가 4 ~ 7 g/min일 수 있다.In addition, the chip for deodorizing blinds may have a Shore A hardness of 80 to 115 and a melt index of 4 to 7 g/min measured under the conditions of a temperature of 200°C and a load of 2.16 kg. .
또한, 본 발명은 상술한 소취 블라인드용 칩;을 통해 형성된 소취 블라인드를 제공한다.In addition, the present invention provides a deodorizing blind formed through the above-described deodorizing blind chip.
본 발명의 소취 블라인드용 조성물, 소취 블라인드용 칩 및 이를 통해 형성된 소취 블라인드는 소취성능, 난연성 및 형태복원력이 우수한 동시에, 블라인드 제조 시 작업성이 우수한 효과가 있다.The composition for deodorizing blinds of the present invention, the chips for deodorizing blinds, and the deodorizing blinds formed using the same have excellent deodorizing performance, flame retardancy, and shape restoration ability, and have excellent workability when manufacturing blinds.
이하 본 발명의 실시예에 대하여 본 발명이 속하는 기술분야에서 통상의 지식을 가진 자가 용이하게 실시할 수 있도록 상세히 설명한다. 본 발명은 여러 가지 상이한 형태로 구현될 수 있으며 여기에서 설명하는 실시예에 한정되지 않는다.Hereinafter, embodiments of the present invention will be described in detail so that those skilled in the art can easily implement the present invention. The present invention may be implemented in many different forms and is not limited to the embodiments described herein.
본 발명의 일 실시예에 따른 소취 블라인드용 조성물은, 주제수지; 가소제; 및 소취 물질;을 포함하여 구현된다.A composition for deodorizing blinds according to an embodiment of the present invention includes a main resin; plasticizer; and a deodorizing material.
먼저, 상기 주제수지에 대하여 설명한다.First, the subject balance will be explained.
상기 주제수지는 칩을 형성하여 블라인드를 제조할 수 있는 것으로 당업계에 공지된 성분의 경우 제한 없이 사용될 수 있다. 다만, 소취성능, 난연성, 형태복원력이 우수하고 블라인드 제조 시 작업성이 우수한 측면에서, 상기 주제수지는 폴리비닐클로라이드(PVC), 폴리우레탄(PU), 폴리프로필렌(PP) 및 폴리비닐알콜(PVA)로 이루어진 군에서 선택된 1종 이상을 포함할 수 있고, 바람직하게는 폴리비닐클로라이드(PVC)를 사용할 수 있다.The main resin can be used without limitation if it is a component known in the art that can manufacture blinds by forming chips. However, in terms of excellent deodorizing performance, flame retardancy, shape restoration, and workability when manufacturing blinds, the main resins include polyvinyl chloride (PVC), polyurethane (PU), polypropylene (PP), and polyvinyl alcohol (PVA). ), and preferably polyvinyl chloride (PVC).
한편, 상기 주제수지는 중합도(degree of polymerization)가 800 ~ 1200인, 바람직하게는 중합도가 900 ~ 1100인 고분자 수지일 수 있다. 만일 상기 주제수지의 중합도가 800 미만이면 제조되는 소취 블라인드의 난연성이 저하될 수 있고, 블라인드 제조 시 작업성이 저하될 수 있다. 또한, 만일 상기 주제수지의 중합도가 1200을 초과하면 제조되는 소취 블라인드의 형태복원력이 저하될 수 있고, 블라인드 롤업이 용이하지 않음에 따라 블라인드 제조 시 작업성이 저하될 수 있다.Meanwhile, the main resin may be a polymer resin with a degree of polymerization of 800 to 1200, preferably a polymer resin with a degree of polymerization of 900 to 1100. If the degree of polymerization of the main resin is less than 800, the flame retardancy of the deodorizing blind manufactured may be reduced, and workability may be reduced when manufacturing the blind. In addition, if the degree of polymerization of the main resin exceeds 1200, the shape restoration power of the deodorizing blind manufactured may be reduced, and workability when manufacturing the blind may be reduced as it is not easy to roll up the blind.
다음, 상기 가소제에 대하여 설명한다.Next, the plasticizer will be described.
상기 가소제는 블라인드에 탄력성과 유연성을 부여하고, 블라인드 제조 시 작업성을 향상시키는 기능을 수행한다.The plasticizer provides elasticity and flexibility to the blind and improves workability when manufacturing the blind.
상기 가소제는 당업계에서 통상적으로 사용할 수 있는 가소제라면 제한 없이 사용할 수 있으나, 바람직하게는 디옥틸 테레프탈레이트(DOTP)계 가소제 및 디프로필헵실 프탈레이트(DPHP)계 가소제 중 어느 하나 이상을 포함할 수 있고, 보다 바람직하게는 디옥틸 테레프탈레이트(DOTP)계 가소제를 사용하는 것이 탄력성과 유연성을 부여하고, 블라인드 제조 시 작업성을 향상시키는 측면에서 더욱 유리할 수 있다.The plasticizer may be used without limitation as long as it is a plasticizer commonly used in the art, but preferably includes at least one of a dioctyl terephthalate (DOTP)-based plasticizer and a dipropylhexyl phthalate (DPHP)-based plasticizer. , More preferably, using a dioctyl terephthalate (DOTP)-based plasticizer may be more advantageous in terms of providing elasticity and flexibility and improving workability when manufacturing blinds.
한편, 본 발명에 따른 소취 블라인드용 조성물은 상기 주제수지 100 중량부에 대하여 상기 가소제를 20 ~ 50 중량부로, 바람직하게는 상기 가소제를 25 ~ 45 중량부로 포함할 수 있다. 만일 상기 주제수지 100 중량부에 대하여 상기 가소제가 20 중량부 미만이면 제조되는 소취 블라인드의 형태복원력이 저하될 수 있고, 블라인드 제조 시 작업성이 저하될 수 있으며, 상기 가소제가 50 중량부를 초과하면 난연성능이 저하될 수 있고, 블라인드 제조 시 작업성이 저하될 수 있다.Meanwhile, the composition for deodorizing blinds according to the present invention may contain 20 to 50 parts by weight of the plasticizer, preferably 25 to 45 parts by weight, based on 100 parts by weight of the main resin. If the amount of the plasticizer is less than 20 parts by weight based on 100 parts by weight of the main resin, the shape restoration power of the deodorizing blind manufactured may be reduced, workability may be reduced when manufacturing the blind, and if the plasticizer exceeds 50 parts by weight, the flame retardant may be reduced. Performance may deteriorate, and workability may deteriorate when manufacturing blinds.
다음, 상기 소취 물질에 대하여 설명한다.Next, the above deodorizing substances will be described.
상기 소취 물질은 소취 블라인드에서 소취성능을 향상시키는 기능을 수행한다.The deodorizing material functions to improve the deodorizing performance of the deodorizing blind.
상기 소취 물질은 염화칼슘, 염화구리 및 철염으로 이루어진 군에서 선택된 1종 이상을 포함할 수 있고, 바람직하게는 염화칼슘, 염화구리 및 철염으로 이루어진 군에서 선택된 2종 이상을 포함할 수 있으며, 보다 바람직하게는 염화칼슘, 염화구리 및 철염을 모두 포함할 수 있다.The deodorizing substance may include one or more types selected from the group consisting of calcium chloride, copper chloride, and iron salts, and may preferably include two or more types selected from the group consisting of calcium chloride, copper chloride, and iron salts, and more preferably May include all calcium chloride, copper chloride, and iron salts.
한편, 본 발명에 따른 소취 블라인드용 조성물은 상기 주제수지 100 중량부에 대하여 소취 물질을 1 ~ 15 중량부로 포함하고, 바람직하게는 소취 물질을 2 ~ 10 중량부로 포함할 수 있다. 만일 상기 주제수지 100 중량부에 대하여 소취 물질이 1 중량부 미만이면 소취 블라인드의 소취성능이 저하될 수 있고, 소취 물질이 15 중량부를 초과하면 블라인드 제조 시 작업성이 저하될 수 있으며 형태복원력이 저하될 수 있다.Meanwhile, the composition for deodorizing blinds according to the present invention may contain 1 to 15 parts by weight of a deodorizing material, and preferably 2 to 10 parts by weight of a deodorizing material based on 100 parts by weight of the main resin. If the deodorizing material is less than 1 part by weight per 100 parts by weight of the main resin, the deodorizing performance of the deodorizing blind may be reduced, and if the deodorizing material exceeds 15 parts by weight, workability during blind manufacturing may be reduced and the shape restoration ability may be reduced. It can be.
한편, 본 발명에 따른 소취 블라인드용 조성물은 난연제를 더 포함할 수 있다.Meanwhile, the composition for deodorizing blinds according to the present invention may further include a flame retardant.
상기 난연제는 당업계에서 통상적으로 난연성을 발현할 수 있는 물질이라면 제한 없이 사용할 수 있고, 바람직하게는 삼산화 안티몬, 트리페닐 포스페이트, 트리자일레닐 포스페이트, 트리크레실 포스페이트, 트리이소페닐 포스페이트, 트리스-클로로에틸 포스페이트, 트리스-클로로프로필 포스페이트, 레조르시놀 디-포스페이트, 아로마틱 폴리포스페이트, 폴리인산 암모늄, 레드 포스포러스 및 수산화 알루미늄으로 이루어진 군에서 선택된 1종 이상을 포함할 수 있고, 보다 바람직하게는 삼산화 안티몬을 포함할 수 있다.The flame retardant can be used without limitation as long as it is a material that can commonly exhibit flame retardancy in the art, and is preferably antimony trioxide, triphenyl phosphate, trixylenyl phosphate, tricresyl phosphate, triisophenyl phosphate, tris- It may include one or more selected from the group consisting of chloroethyl phosphate, tris-chloropropyl phosphate, resorcinol di-phosphate, aromatic polyphosphate, ammonium polyphosphate, red phosphorus, and aluminum hydroxide, and more preferably trioxide. May contain antimony.
또한, 상기 난연제는 주제수지 100 중량부에 대하여 1 ~ 7 중량부로, 바람직하게는 2 ~ 6 중량부로 더 포함할 수 있다. 만일 상기 주제수지 100 중량부에 대하여 1 중량부 미만이면 목적하는 수준의 난연성을 발현할 수 없고, 7 중량부를 초과하면 소취 블라인드의 형태복원력이 저하되거나, 블라인드 제조 시 작업성이 저하될 수 있다.In addition, the flame retardant may be further included in an amount of 1 to 7 parts by weight, preferably 2 to 6 parts by weight, based on 100 parts by weight of the main resin. If it is less than 1 part by weight based on 100 parts by weight of the main resin, the desired level of flame retardancy cannot be achieved, and if it exceeds 7 parts by weight, the shape restoration power of the deodorizing blind may be reduced, or workability may be reduced when manufacturing the blind.
한편, 본 발명에 따른 소취 블라인드용 조성물은 열 안정제 및 UV안정제를 더 포함할 수 있다.Meanwhile, the composition for deodorizing blinds according to the present invention may further include a heat stabilizer and a UV stabilizer.
상기 열 안정제는 열에 의한 물성 변화를 방지하는 기능을 수행하는 것으로, 당업계에서 통상적으로 사용할 수 있는 열 안정제라면 제한 없이 사용할 수 있으며, 바람직하게는 Ca/Zn계 열 안정제, Na/Zn계 열 안정제, Sn계 열 안정제, Pb계 열 안정제, Cd계 열 안정제 및 Zn계 열 안정제로 이루어진 군에서 선택된 1종 이상을 포함할 수 있고, 보다 바람직하게는 Ca/Zn계 열 안정제를 사용할 수 있다.The heat stabilizer functions to prevent changes in physical properties due to heat, and any heat stabilizer commonly used in the industry can be used without limitation, preferably a Ca/Zn-based heat stabilizer or a Na/Zn-based heat stabilizer. , Sn-based thermal stabilizer, Pb-based thermal stabilizer, Cd-based thermal stabilizer, and Zn-based thermal stabilizer may be included, and more preferably, Ca/Zn-based thermal stabilizer may be used.
한편, 본 발명의 일 실시예에 따른 소취 블라인드용 조성물은 주제수지 100 중량부에 대하여 상기 열 안정제를 0.1 ~ 1 중량부로, 바람직하게는 0.1 ~ 0.5 중량부로 더 포함할 수 있다. 만일 상기 주제수지 100 중량부에 대하여 상기 열 안정제가 0.1 중량부 미만이면 목적하는 수준으로 열에 의한 물성변화를 방지할 수 없음에 따라 형태복원력이 저하되거나 블라인드 제조 시 작업성이 저하될 수 있고, 1 중량부를 초과하면 블라인드 제조 시 작업성이 저하될 수 있다.Meanwhile, the composition for deodorizing blinds according to an embodiment of the present invention may further include 0.1 to 1 part by weight of the heat stabilizer, preferably 0.1 to 0.5 parts by weight, based on 100 parts by weight of the main resin. If the amount of the heat stabilizer is less than 0.1 parts by weight based on 100 parts by weight of the main resin, the change in physical properties due to heat cannot be prevented to the desired level, and thus the shape restoration power may be reduced or workability when manufacturing blinds may be reduced, 1 If the weight part is exceeded, workability may be reduced when manufacturing blinds.
또한, 상기 UV 안정제는 UV에 의한 황변을 방지하기 위한 것으로, 당업계에서 통상적으로 사용할 수 있는 UV 안정제라면 제한 없이 사용할 수 있으며, 바람직하게는 2-(2'-하이드록시-3, 5'-디(1, 1-디메틸벤질-페닐)-벤조트리아졸, 2-(2'-하이드록시- 3', 5'-디-터-부틸페닐)-벤조트리아졸, 2-(2'-하이드록시-3'-터부틸-5'-메틸페닐)-5-클로로-벤조트리아졸, 2-(2-하이드록시-5-터-옥틸페닐)-벤조트리아졸, 2-(5-메틸-2-하이드록시-페닐)-벤조트리아졸, 2,6-디-t-부틸-4-메틸페놀, 테트라키스[메틸렌-3-(3,5-디-t-부틸-4-하이드록시페닐)프로피오네이트]메탄, 옥타데실-3,5-디-t-부틸-4-하이드록시하이드로신나메이트, 2,2-메틸렌비스(4-메틸-6-t-부틸페놀), 트리스(2,4-디-t-부틸페닐)-포스파이트, 비스(2,4-디-t-부틸), 펜타에리스리톨-디-포스파이트 알킬에스터 포스파이트, 디라우릴 티오-디-프로피오네이트, 디-스테아릴 티오-디-프로피오네이트 및 디미리스틸 티오-디-프로피오네이트로 이루어진 군에서 선택된 1종 이상을 포함할 수 있고, 보다 바람직하게는 2-(2'-하이드록시-3, 5'-디(1, 1-디메틸벤질-페닐)-벤조트리아졸, 2-(2'-하이드록시- 3', 5'-디-터-부틸페닐)-벤조트리아졸, 2-(2'-하이드록시-3'-터부틸-5'-메틸페닐)-5-클로로-벤조트리아졸, 2-(2-하이드록시-5-터-옥틸페닐)-벤조트리아졸 및 2-(5-메틸-2-하이드록시-페닐)-벤조트리아졸로 이루어진 군에서 선택된 1종 이상을 포함할 수 있다.In addition, the UV stabilizer is intended to prevent yellowing caused by UV, and any UV stabilizer commonly used in the industry can be used without limitation, preferably 2-(2'-hydroxy-3, 5'- Di(1, 1-dimethylbenzyl-phenyl)-benzotriazole, 2-(2'-hydroxy-3', 5'-di-ter-butylphenyl)-benzotriazole, 2-(2'-hyde Roxy-3'-terbutyl-5'-methylphenyl)-5-chloro-benzotriazole, 2-(2-hydroxy-5-ter-octylphenyl)-benzotriazole, 2-(5-methyl-2 -Hydroxy-phenyl)-benzotriazole, 2,6-di-t-butyl-4-methylphenol, tetrakis[methylene-3-(3,5-di-t-butyl-4-hydroxyphenyl) propionate] methane, octadecyl-3,5-di-t-butyl-4-hydroxyhydrocinnamate, 2,2-methylenebis (4-methyl-6-t-butylphenol), tris (2, 4-di-t-butylphenyl)-phosphite, bis(2,4-di-t-butyl), pentaerythritol-di-phosphite alkyl ester phosphite, dilauryl thio-di-propionate, di- It may include one or more selected from the group consisting of stearyl thio-di-propionate and dimyristyl thio-di-propionate, and more preferably 2-(2'-hydroxy-3, 5). '-di(1, 1-dimethylbenzyl-phenyl)-benzotriazole, 2-(2'-hydroxy-3', 5'-di-ter-butylphenyl)-benzotriazole, 2-(2' -Hydroxy-3'-terbutyl-5'-methylphenyl)-5-chloro-benzotriazole, 2-(2-hydroxy-5-ter-octylphenyl)-benzotriazole and 2-(5-methyl It may include one or more selected from the group consisting of -2-hydroxy-phenyl)-benzotriazole.
한편, 본 발명의 일 실시예에 따른 소취 블라인드용 조성물은 주제수지 100 중량부에 대하여 상기 UV 안정제를 0.1 ~ 1 중량부로, 바람직하게는 0.1 ~ 0.5 중량부로 더 포함할 수 있다. 만일 상기 주제수지 100 중량부에 대하여 상기 UV 안정제가 0.1 중량부 미만이면 목적하는 수준으로 광분해 반응을 저해시킬 수 없고, 1 중량부를 초과하면 제조되는 블라인드의 황변 발생 확률이 증가할 수 있다.Meanwhile, the composition for deodorizing blinds according to an embodiment of the present invention may further include 0.1 to 1 part by weight of the UV stabilizer, preferably 0.1 to 0.5 parts by weight, based on 100 parts by weight of the main resin. If the amount of the UV stabilizer is less than 0.1 parts by weight relative to 100 parts by weight of the main resin, the photodecomposition reaction cannot be inhibited to the desired level, and if it exceeds 1 part by weight, the probability of yellowing of the manufactured blind may increase.
한편, 본 발명에 따른 소취 블라인드용 조성물은 활제 및 산화방지제를 더 포함할 수 있다.Meanwhile, the composition for deodorizing blinds according to the present invention may further include a lubricant and an antioxidant.
상기 활제는 소취 블라인드용 칩 형성 시 가공성 및 생산성을 향상시키는 기능을 수행하는 것으로, 당업계에서 통상적으로 사용할 수 있는 활제라면 제한 없이 사용할 수 있고, 바람직하게는 지방산, 스테라인산, 실리콘 및 파라핀 왁스로 이루어진 군에서 선택된 1종 이상을 포함할 수 있고, 보다 바람직하게는 지방산일 수 있다.The lubricant functions to improve processability and productivity when forming chips for deodorizing blinds, and any lubricant commonly used in the industry can be used without limitation, preferably fatty acids, steric acids, silicone, and paraffin wax. It may include one or more types selected from the group consisting of, and more preferably, it may be a fatty acid.
한편, 본 발명의 일 실시예에 따른 소취 블라인드용 조성물은 주제수지 100 중량부에 대하여 상기 활제를 0.05 ~ 0.5 중량부로, 바람직하게는 0.1 ~ 0.3 중량부로 더 포함할 수 있다. 만일 주제수지 100 중량부에 대하여 상기 활제가 0.05 중량부 미만이면 유동 점도 하락, gel화 속도 하락, 탄화현상 유발 가능성이 높아짐에 따라 칩 형성 시 작업성이 저하될 수 있고, 0.5 중량부를 초과하면 성형 가공성, gel화 속도, 유동 점도가 전부 높아짐에 따라 작업성이 저하될 수 있다.Meanwhile, the composition for deodorizing blinds according to an embodiment of the present invention may further include 0.05 to 0.5 parts by weight, preferably 0.1 to 0.3 parts by weight, of the lubricant based on 100 parts by weight of the main resin. If the amount of the lubricant is less than 0.05 parts by weight per 100 parts by weight of the main resin, the flow viscosity decreases, the gelation speed decreases, and the possibility of carbonization increases, which may reduce workability when forming chips. If it exceeds 0.5 parts by weight, the molding process may decrease. As processability, gelation speed, and flow viscosity all increase, workability may decrease.
그리고, 상기 산화방지제는 블라인드의 변색 방지, 산화에 의한 형태복원력 등의 물성 저하를 방지하는 기능을 수행한다.In addition, the antioxidant performs the function of preventing discoloration of blinds and deterioration of physical properties such as shape restoration ability due to oxidation.
상기 산화방지제는 당업계에서 채용하는 공지된 성분을 사용할 수 있으며, 바람직하게는 인계 산화방지제, 페놀계 산화방지제 및 이들의 혼합물로 이루어진 군에서 선택된 1종 이상을 포함할 수 있다.The antioxidant may be a known component employed in the art, and may preferably include at least one selected from the group consisting of phosphorus-based antioxidants, phenolic-based antioxidants, and mixtures thereof.
구체적으로, 상기 인계 산화방지제는 트리-메틸포스페이트, 트리-페닐포스페이트 및 트리스(2, 4-디-터트-부틸페닐)포스페이트로 이루어진 군에서 선택된 1종 이상을 포함할 수 있고, 상기 페놀계 산화방지제는 트리에틸렌글리콜-비스-3-(3-터트-부틸-4-하이드록시-5-메틸페닐)프로피오네이트, 1, 6-헥세인-디올-3(3, 5-디-터트-부틸-4-하이드록시페닐)프로피오네이트, 펜타에리스리틸-테트라키스(3-(3, 5-디-터트-부틸-4-하이드록시페닐)프로피오네이트, 2-하이드록시벤조페논, 2-하이드록시페닐벤조티아졸, 힌더드 아민, 유기 니켈 화합물, 살리실산염, 신나메이트 유도체, 레조르시놀 모노벤조에이트, 옥사닐리드 및 p-하이드록시벤조에이트로 이루어진 군에서 선택된 1종 이상을 포함할 수 있고, 바람직하게는, 트리-메틸포스페이트, 트리-페닐포스페이트, 트리스(2,4-디-터트-부틸페닐)포스페이트, 트리에틸렌글리콜-비스-3-(3-터트-부틸-4-하이드록시-5-메틸페닐)프로피오네이트, 1,6-헥세인-디올-3(3,5-디-터트-부틸-4-하이드록시페닐)프로피오네이트 및 펜타에리스리틸-테트라키스(3-(3,5-디-터트-부틸-4-하이드록시페닐)프로피오네이트로 이루어진 군에서 선택된 1종 이상을 포함할 수 있다.Specifically, the phosphorus-based antioxidant may include one or more selected from the group consisting of tri-methyl phosphate, tri-phenyl phosphate, and tris (2, 4-di-tert-butylphenyl) phosphate, and the phenol-based oxidation The inhibitor is triethylene glycol-bis-3-(3-tert-butyl-4-hydroxy-5-methylphenyl)propionate, 1, 6-hexane-diol-3(3, 5-di-tert-butyl) -4-hydroxyphenyl)propionate, pentaerythrityl-tetrakis(3-(3, 5-di-tert-butyl-4-hydroxyphenyl)propionate, 2-hydroxybenzophenone, 2- It may contain one or more selected from the group consisting of hydroxyphenylbenzothiazole, hindered amine, organic nickel compound, salicylate, cinnamate derivative, resorcinol monobenzoate, oxanilide, and p-hydroxybenzoate. Can be, preferably tri-methyl phosphate, tri-phenyl phosphate, tris (2,4-di-tert-butylphenyl) phosphate, triethylene glycol-bis-3- (3-tert-butyl-4-hyde Roxy-5-methylphenyl)propionate, 1,6-hexane-diol-3(3,5-di-tert-butyl-4-hydroxyphenyl)propionate and pentaerythrityl-tetrakis(3- It may include one or more selected from the group consisting of (3,5-di-tert-butyl-4-hydroxyphenyl)propionate.
한편, 본 발명의 일 실시예에 따른 소취 블라인드용 조성물은 주제수지 100 중량부에 대하여 상기 산화방지제를 0.1 ~ 1 중량부로, 바람직하게는 0.1 ~ 0.5 중량부로 더 포함할 수 있다. 만일 주제수지 100 중량부에 대하여 상기 산화방지제가 0.1 중량부 미만이면 산화반응에 의해 노화, 변색이 발생하여 형태복원력이 저하될 수 있으며, 산화방지제가 1 중량부를 초과하면 블라인드 제조 시 작업성이 저하될 수 있다.Meanwhile, the composition for deodorizing blinds according to an embodiment of the present invention may further include 0.1 to 1 part by weight, preferably 0.1 to 0.5 parts by weight, of the antioxidant based on 100 parts by weight of the main resin. If the amount of the antioxidant is less than 0.1 part by weight per 100 parts by weight of the main resin, aging and discoloration may occur due to oxidation reactions, which may reduce shape restoration. If the antioxidant exceeds 1 part by weight, workability when manufacturing blinds is reduced. It can be.
한편, 본 발명은 상술한 소취 블라인드용 조성물을 통해 형성된 소취 블라인드용 칩을 제공한다.Meanwhile, the present invention provides a chip for deodorizing blinds formed using the composition for deodorizing blinds described above.
상기 소취 블라인드용 칩은 상술한 소취 블라인드용 조성물을 압출시켜서 형성될 수 있다.The chip for deodorizing blinds may be formed by extruding the composition for deodorizing blinds described above.
이때, 상기 압출은 130 ~ 190℃의 온도에서, 바람직하게는 140 ~ 180℃의 온도에서 수행할 수 있다. 만일 상기 압출 온도가 130℃ 미만이면 수지가 제대로 용융되지 않아 압출이 매우 용이하지 않은 문제가 발생할 수 있고, 190℃를 초과하면 탄화가 발생할 수 있다.At this time, the extrusion can be performed at a temperature of 130 to 190°C, preferably 140 to 180°C. If the extrusion temperature is less than 130°C, the resin may not melt properly and extrusion may not be easy, and if it exceeds 190°C, carbonization may occur.
한편, 상기 소취 블라인드용 칩은 쇼어 A(shore A) 경도가 80 ~ 115일 수 있고, 바람직하게는 쇼어 A(shore A) 경도가 85 ~ 110일 수 있다. 만일 상기 소취 블라인드용 칩의 쇼어 A(shore A) 경도가 80 미만이면 블라인드 제조 시 작업성이 저하될 수 있고, 115을 초과하면 형태복원력 및 블라인드 제조 시 작업성이 저하될 수 있다.Meanwhile, the chip for deodorizing blinds may have a shore A hardness of 80 to 115, and preferably, a shore A hardness of 85 to 110. If the shore A hardness of the deodorizing blind chip is less than 80, workability may be reduced when manufacturing blinds, and if it exceeds 115, shape restoration power and workability when manufacturing blinds may be reduced.
또한, 상기 소취 블라인드용 칩은 온도 200℃ 및 하중 2.16kg의 조건에서 측정한 용융지수(melt index)가 4 ~ 7 g/min일 수 있고, 바람직하게는 4.5 ~ 6.5 g/min일 수 있다. 만일 상기 소취 블라인드용 칩의 온도 200℃ 및 하중 2.16kg의 조건에서 측정한 용융지수가 4 g/min 미만이면 압출 시 고온 및/또는 고압 조건이 요구되며 작업성이 저하될 수 있고, 용융지수가 7 g/min을 초과하면 압출 시 수지가 흘러내릴 수 있음에 따라 작업성이 저하될 수 있다.In addition, the deodorizing blind chip may have a melt index of 4 to 7 g/min, preferably 4.5 to 6.5 g/min, measured at a temperature of 200°C and a load of 2.16 kg. If the melt index of the deodorizing blind chip measured at a temperature of 200°C and a load of 2.16 kg is less than 4 g/min, high temperature and/or high pressure conditions are required during extrusion, workability may be reduced, and the melt index If it exceeds 7 g/min, workability may deteriorate as the resin may flow out during extrusion.
한편, 본 발명은 상술한 소취 블라인드용 칩을 통해 형성된 소취 블라인드를 제공한다.Meanwhile, the present invention provides a deodorizing blind formed through the above-described deodorizing blind chip.
이때 상기 소취 블라인드는, 상기 소취 블라인드용 칩을 통해 복수 개의 섬유를 형성하고 형성한 섬유를 통해 원단을 제조하여 형성시키거나, 상기 소취 블라인드용 칩을 압착함으로써 그 자체를 소취 블라인드로 구현하여 형성시킬 수도 있다. 다만, 제조되는 블라인드의 우수한 형태복원력과, 블라인드 제조 시 우수한 작업성 측면에서 상기 소취 블라인드용 칩을 통해 복수 개의 섬유를 형성하고 형성한 섬유를 통해 원단을 제조하여 소취 블라인드를 구현하는 것이 더욱 유리하다.At this time, the deodorizing blind can be formed by forming a plurality of fibers through the deodorizing blind chip and manufacturing fabric using the formed fibers, or by pressing the deodorizing blind chip to implement itself as a deodorizing blind. It may be possible. However, in terms of the excellent shape recovery of the manufactured blind and excellent workability when manufacturing the blind, it is more advantageous to form a plurality of fibers through the deodorizing blind chip and manufacture the fabric using the formed fiber to implement the deodorizing blind. .
한편, 본 발명의 소취 블라인드용 조성물, 소취 블라인드용 칩 및 이를 통해 형성된 소취 블라인드는 소취성능, 난연성 및 형태복원력이 우수한 동시에, 블라인드 제조 시 작업성이 우수한 효과가 있다.On the other hand, the composition for deodorizing blinds of the present invention, the chips for deodorizing blinds, and the deodorizing blinds formed using the same have excellent deodorizing performance, flame retardancy, and shape restoration ability, and have excellent workability when manufacturing blinds.
하기의 실시예를 통하여 본 발명을 더욱 구체적으로 설명하기로 하지만, 하기 실시예가 본 발명의 범위를 제한하는 것은 아니며, 이는 본 발명의 이해를 돕기 위한 것으로 해석되어야 할 것이다.The present invention will be described in more detail through the following examples, but the following examples do not limit the scope of the present invention, and should be interpreted to aid understanding of the present invention.
<실시예 1><Example 1>
먼저, 주제수지로 중합도(degree of polymerization)가 1000인 폴리비닐클로라이드(PVC) 레진 100 중량부에 대하여, 가소제로 디옥틸 테레프탈레이트(DOTP)계 가소제를 34 중량부를 첨가 및 교반하고, 소취 물질(HEALTHA CLEAN, VENTEX)을 5 중량부, 난연제로 삼산화 안티몬 난연제를 4 중량부, 열 안정제로 Ca/Zn계 열 안정제를 0.3 중량부, UV 안정제를 0.3 중량부, 활제로 지방산을 0.2 중량부 및 산화방지제를 0.3 중량부 첨가 및 교반하여 소취 블라인드용 조성물을 제조하였다. 그리고, 상기 소취 블라인드용 조성물을 160℃의 온도에서 압출시켜서 소취 블라인드용 칩을 제조하였다.First, for 100 parts by weight of polyvinyl chloride (PVC) resin with a degree of polymerization of 1000 as the main resin, 34 parts by weight of dioctyl terephthalate (DOTP)-based plasticizer was added and stirred as a plasticizer, and a deodorizing substance ( 5 parts by weight of HEALTHA CLEAN, VENTEX), 4 parts by weight of antimony trioxide flame retardant as a flame retardant, 0.3 part by weight of Ca/Zn-based heat stabilizer as a heat stabilizer, 0.3 part by weight of UV stabilizer, 0.2 part by weight of fatty acid as a lubricant and oxidation A composition for deodorizing blinds was prepared by adding 0.3 parts by weight of an inhibitor and stirring. Then, the composition for deodorizing blinds was extruded at a temperature of 160°C to manufacture chips for deodorizing blinds.
이후, 상기 제조한 소취 블라인드용 칩을 온도 160℃ 조건에서 방사시켜서 섬유를 형성한 후, 형성한 섬유 각각을 경사 및 위사로 적용하여 원단을 직조함으로써 소취 블라인드를 제조하였다.Thereafter, the above-prepared deodorizing blind chip was spun at a temperature of 160°C to form fibers, and then each of the formed fibers was applied as warp and weft yarns to weave fabric, thereby manufacturing a deodorizing blind.
<실시예 2 ~ 13 및 비교예 1 ~ 4><Examples 2 to 13 and Comparative Examples 1 to 4>
실시예 1과 동일하게 실시하여 제조하되, 소취 물질의 함량, 가소제의 함량, 주제수지의 중합도, 난연제 함량, 가소제 포함여부 및 소취 물질 포함여부 등을 변경하여 표 1 내지 표 3과 같은 소취 블라인드를 제조하였다.Manufactured in the same manner as in Example 1, but changing the content of the deodorizing material, the content of the plasticizer, the degree of polymerization of the main resin, the content of the flame retardant, whether the plasticizer is included, and whether the deodorizing material is included, etc. to produce deodorizing blinds as shown in Tables 1 to 3. Manufactured.
<비교준비예><Example of comparison preparation>
물 100 중량부에 대하여 실시예 1의 소취물질을 0.8 중량부 첨가하고 온도 60℃에서 120분 동안 혼합하여 반응시킨 후, 반응이 완료된 뒤 상온에서 방치하는 냉각단계를 수행하여 코팅 용액을 제조하였다.A coating solution was prepared by adding 0.8 parts by weight of the deodorizing material of Example 1 to 100 parts by weight of water, mixing and reacting at a temperature of 60°C for 120 minutes, and then performing a cooling step of leaving the mixture at room temperature after the reaction was completed.
<비교예 5><Comparative Example 5>
실시예 1과 동일하게 실시하여 제조하되, 소취 물질을 포함하지 않고, 원단을 직조하여 블라인드를 제조한 후, 상기 비교준비예에 따른 코팅 용액과 아크릴계 바인더를 2:8의 중량비로 혼합한 코팅 조성물을 블라인드에 프린팅을 통한 코팅으로 소취코팅층을 형성하여 소취 블라인드를 제조하였다.A coating composition prepared in the same manner as in Example 1, but without containing the deodorizing material, manufacturing a blind by weaving the fabric, and then mixing the coating solution according to the comparative preparation example and an acrylic binder at a weight ratio of 2:8. A deodorizing blind was manufactured by forming a deodorizing coating layer on the blind by coating it through printing.
<실험예> <Experimental example>
실시예 및 비교예에 따른 소취 블라인드에 대하여 하기의 물성을 평가하여 표 1 내지 표 4에 나타내었다.The following physical properties were evaluated for the deodorizing blinds according to Examples and Comparative Examples and are shown in Tables 1 to 4.
1. 소취성능 평가1. Deodorization performance evaluation
실시예 및 비교예에 따른 각각의 소취 블라인드에 대하여 농도 30ppm으로 아세트산 가스를 주입한 후, 24시간후 농도를 측정하여 아세트산 가스 감소율을 통해 소취성능을 평가하였다.Acetic acid gas was injected at a concentration of 30 ppm into each deodorizing blind according to the examples and comparative examples, and then the concentration was measured 24 hours later to evaluate the deodorizing performance through the acetic acid gas reduction rate.
2. 난연성 평가2. Flame retardancy evaluation
실시예 및 비교예에 따른 각각의 소취 블라인드에 대하여 NFPA 701 규격에 의거하여 난연성을 평가하였다.Flame retardancy was evaluated for each deodorizing blind according to Examples and Comparative Examples according to the NFPA 701 standard.
3. 형태복원력 평가3. Evaluation of shape resilience
실시예 및 비교예에 따른 각각의 소취 블라인드에 대하여 ASTM D1388의 OPTION A-캔틸레버법에 의거하여 형태복원력을 평가하였다.For each deodorizing blind according to Examples and Comparative Examples, the shape restoration ability was evaluated based on the OPTION A-cantilever method of ASTM D1388.
4. 작업성 평가4. Workability evaluation
실시예 및 비교예에 따른 소취 블라인드용 칩을 통해 각각의 소취 블라인드를 제조하는 중 방사온도 160℃ 조건에서 방사품질 상태 확인 및 블라인드 롤업 공정 용이성을 판단하는 방법을 통해 작업성을 평가하였다.While manufacturing each deodorizing blind using the deodorizing blind chip according to the examples and comparative examples, workability was evaluated by checking the spinning quality and judging the ease of the blind roll-up process at a spinning temperature of 160°C.
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상기 표 1 내지 표 3에서 알 수 있듯이, 본 발명에 따른 소취 물질의 함량, 가소제의 함량, 주제수지의 중합도, 난연제 함량, 가소제 포함여부 및 소취 물질 포함여부 등을 모두 만족하는 실시예 1 ~ 3, 5, 6, 9 및 10이, 이 중에서 하나라도 누락된 실시예 4, 7, 8, 11 ~ 13 및 비교예 1 ~ 5에 비하여 소취성능, 난연성 및 형태복원력이 우수한 동시에 블라인드 제조 시 작업성이 우수한 것을 알 수 있었다.As can be seen from Tables 1 to 3, Examples 1 to 3 satisfy all of the content of the deodorizing material, the content of the plasticizer, the degree of polymerization of the main resin, the content of the flame retardant, the inclusion of the plasticizer, and the inclusion of the deodorizing material according to the present invention. , 5, 6, 9, and 10 are superior in deodorizing performance, flame retardancy, and shape restoration compared to Examples 4, 7, 8, 11 to 13 and Comparative Examples 1 to 5 in which any one of them is missing, and at the same time, workability when manufacturing blinds. I could see that this was excellent.
이상에서 본 발명의 일 실시예에 대하여 설명하였으나, 본 발명의 사상은 본 명세서에 제시되는 실시 예에 제한되지 아니하며, 본 발명의 사상을 이해하는 당업자는 동일한 사상의 범위 내에서, 구성요소의 부가, 변경, 삭제, 추가 등에 의해서 다른 실시 예를 용이하게 제안할 수 있을 것이나, 이 또한 본 발명의 사상범위 내에 든다고 할 것이다.Although one embodiment of the present invention has been described above, the spirit of the present invention is not limited to the embodiment presented in the present specification, and those skilled in the art who understand the spirit of the present invention can add components within the scope of the same spirit. , other embodiments can be easily proposed by change, deletion, addition, etc., but this will also be said to be within the scope of the present invention.
Claims (13)
가소제; 및
상기 주제수지 100 중량부에 대하여 1 ~ 15 중량부로 포함되는 소취 물질;을 포함하는 소취 블라인드용 조성물.topic balance;
plasticizer; and
A composition for deodorizing blinds comprising: a deodorizing material contained in an amount of 1 to 15 parts by weight based on 100 parts by weight of the main resin.
상기 주제수지는 중합도(degree of polymerization)가 800 ~ 1200 인 고분자 수지인 소취 블라인드용 조성물.According to paragraph 1,
The main resin is a composition for deodorizing blinds, which is a polymer resin with a degree of polymerization of 800 to 1200.
상기 주제수지 100 중량부에 대하여 상기 가소제를 20 ~ 50 중량부 포함하는 소취 블라인드용 조성물.According to paragraph 1,
A composition for deodorizing blinds containing 20 to 50 parts by weight of the plasticizer based on 100 parts by weight of the main resin.
상기 주제수지는 폴리비닐클로라이드(PVC), 폴리우레탄(PU), 폴리프로필렌(PP) 및 폴리비닐알콜(PVA)로 이루어진 군에서 선택된 1종 이상을 포함하는 소취 블라인드용 조성물.According to paragraph 1,
The main resin is a composition for deodorizing blinds containing at least one selected from the group consisting of polyvinyl chloride (PVC), polyurethane (PU), polypropylene (PP), and polyvinyl alcohol (PVA).
상기 가소제는 디옥틸 테레프탈레이트(DOTP)계 가소제 및 디프로필헵실 프탈레이트(DPHP)계 가소제 중 어느 하나 이상을 포함하는 소취 블라인드용 조성물.According to paragraph 1,
The plasticizer is a composition for deodorizing blinds containing at least one of a dioctyl terephthalate (DOTP)-based plasticizer and a dipropylhexyl phthalate (DPHP)-based plasticizer.
상기 소취 물질은 염화칼슘, 염화구리 및 철염으로 이루어진 군에서 선택된 1종 이상을 포함하는 소취 블라인드용 조성물.According to paragraph 1,
The deodorizing material is a composition for deodorizing blinds comprising at least one selected from the group consisting of calcium chloride, copper chloride, and iron salt.
상기 주제수지 100 중량부에 대하여 난연제를 1 ~ 7 중량부로 더 포함하는 소취 블라인드용 조성물.According to paragraph 1,
A composition for deodorizing blinds further comprising 1 to 7 parts by weight of a flame retardant based on 100 parts by weight of the main resin.
열 안정제를 0.1 ~ 1 중량부 및 UV 안정제를 0.1 ~ 1 중량부 더 포함하는 소취 블라인드용 조성물.According to claim 1, For 100 parts by weight of the main resin,
A composition for deodorizing blinds further comprising 0.1 to 1 part by weight of a heat stabilizer and 0.1 to 1 part by weight of a UV stabilizer.
활제를 0.05 ~ 0.5 중량부 및 산화방지제 0.1 ~ 1 중량부 더 포함하는 소취 블라인드용 조성물.According to claim 1, with respect to 100 parts by weight of the main resin,
A composition for deodorizing blinds further comprising 0.05 to 0.5 parts by weight of a lubricant and 0.1 to 1 part by weight of an antioxidant.
상기 소취 블라인드용 조성물을 130 ~ 190℃의 온도에서 압출시켜서 형성된 소취 블라인드용 칩.The method of claim 10, wherein the deodorizing blind chip is,
A chip for a deodorizing blind formed by extruding the composition for a deodorizing blind at a temperature of 130 to 190°C.
쇼어 A(shore A) 경도가 80 ~ 115이고,
온도 200℃ 및 하중 2.16 kg의 조건에서 측정한 용융지수(melt index)가 4 ~ 7 g/min인 소취 블라인드용 칩.The method of claim 10, wherein the deodorizing blind chip is,
Shore A hardness is 80 to 115,
A chip for deodorizing blinds with a melt index of 4 to 7 g/min measured at a temperature of 200℃ and a load of 2.16 kg.
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| KR (1) | KR20230162303A (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101126064B1 (en) | 2009-11-12 | 2012-03-29 | 주식회사 윈플러스 | Curtain Type Vertical of roll blind |
-
2022
- 2022-05-20 KR KR1020220062007A patent/KR20230162303A/en unknown
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101126064B1 (en) | 2009-11-12 | 2012-03-29 | 주식회사 윈플러스 | Curtain Type Vertical of roll blind |
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