KR20230113460A - A light conversion ink composition, a light converting laminating unit, a light converting pixel and an image display apparatus unit manufactured by using thereof - Google Patents
A light conversion ink composition, a light converting laminating unit, a light converting pixel and an image display apparatus unit manufactured by using thereof Download PDFInfo
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- KR20230113460A KR20230113460A KR1020220009449A KR20220009449A KR20230113460A KR 20230113460 A KR20230113460 A KR 20230113460A KR 1020220009449 A KR1020220009449 A KR 1020220009449A KR 20220009449 A KR20220009449 A KR 20220009449A KR 20230113460 A KR20230113460 A KR 20230113460A
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- South Korea
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- formula
- ink composition
- light conversion
- light
- carbon atoms
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- 238000006243 chemical reaction Methods 0.000 title claims abstract description 95
- 239000000203 mixture Substances 0.000 title claims abstract description 79
- 238000010030 laminating Methods 0.000 title 1
- 239000000654 additive Substances 0.000 claims abstract description 56
- 230000000996 additive effect Effects 0.000 claims abstract description 51
- 150000001875 compounds Chemical class 0.000 claims abstract description 51
- 239000002245 particle Substances 0.000 claims abstract description 51
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- 150000001412 amines Chemical class 0.000 claims abstract description 11
- 125000004432 carbon atom Chemical group C* 0.000 claims description 36
- 238000000034 method Methods 0.000 claims description 21
- 239000002904 solvent Substances 0.000 claims description 18
- -1 R 13 Chemical compound 0.000 claims description 16
- 125000002947 alkylene group Chemical group 0.000 claims description 15
- 239000003999 initiator Substances 0.000 claims description 15
- 125000000217 alkyl group Chemical group 0.000 claims description 13
- 229910052739 hydrogen Inorganic materials 0.000 claims description 13
- 239000001257 hydrogen Substances 0.000 claims description 13
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- 239000007787 solid Substances 0.000 claims description 7
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- VWDXBRMLFUFNSX-UHFFFAOYSA-N (2-hydroxy-5-methyl-4-oxohex-5-enyl) prop-2-enoate Chemical compound CC(=C)C(=O)CC(O)COC(=O)C=C VWDXBRMLFUFNSX-UHFFFAOYSA-N 0.000 claims description 2
- ZDQNWDNMNKSMHI-UHFFFAOYSA-N 1-[2-(2-prop-2-enoyloxypropoxy)propoxy]propan-2-yl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COCC(C)OC(=O)C=C ZDQNWDNMNKSMHI-UHFFFAOYSA-N 0.000 claims description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 2
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- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 14
- 230000000052 comparative effect Effects 0.000 description 11
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- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 5
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- 238000007704 wet chemistry method Methods 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
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- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
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- SVONRAPFKPVNKG-UHFFFAOYSA-N 2-ethoxyethyl acetate Chemical compound CCOCCOC(C)=O SVONRAPFKPVNKG-UHFFFAOYSA-N 0.000 description 2
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- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
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- VFHVQBAGLAREND-UHFFFAOYSA-N diphenylphosphoryl-(2,4,6-trimethylphenyl)methanone Chemical compound CC1=CC(C)=CC(C)=C1C(=O)P(=O)(C=1C=CC=CC=1)C1=CC=CC=C1 VFHVQBAGLAREND-UHFFFAOYSA-N 0.000 description 2
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- 125000001827 mesitylenyl group Chemical group [H]C1=C(C(*)=C(C([H])=C1C([H])([H])[H])C([H])([H])[H])C([H])([H])[H] 0.000 description 1
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- QMXSDTGNCZVWTB-UHFFFAOYSA-N n',n'-bis(3-aminopropyl)propane-1,3-diamine Chemical compound NCCCN(CCCN)CCCN QMXSDTGNCZVWTB-UHFFFAOYSA-N 0.000 description 1
- VMGSQCIDWAUGLQ-UHFFFAOYSA-N n',n'-bis[2-(dimethylamino)ethyl]-n,n-dimethylethane-1,2-diamine Chemical compound CN(C)CCN(CCN(C)C)CCN(C)C VMGSQCIDWAUGLQ-UHFFFAOYSA-N 0.000 description 1
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- ODZZIKZQNODXFS-UHFFFAOYSA-N n,n'-dimethyl-n'-[2-(methylamino)ethyl]ethane-1,2-diamine Chemical compound CNCCN(C)CCNC ODZZIKZQNODXFS-UHFFFAOYSA-N 0.000 description 1
- DVVORTHDQVBZOO-UHFFFAOYSA-N n-[2-[di(propan-2-yl)amino]ethyl]-n',n'-di(propan-2-yl)ethane-1,2-diamine Chemical compound CC(C)N(C(C)C)CCNCCN(C(C)C)C(C)C DVVORTHDQVBZOO-UHFFFAOYSA-N 0.000 description 1
- BXYVQNNEFZOBOZ-UHFFFAOYSA-N n-[3-(dimethylamino)propyl]-n',n'-dimethylpropane-1,3-diamine Chemical compound CN(C)CCCNCCCN(C)C BXYVQNNEFZOBOZ-UHFFFAOYSA-N 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
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- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
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- UKODFQOELJFMII-UHFFFAOYSA-N pentamethyldiethylenetriamine Chemical compound CN(C)CCN(C)CCN(C)C UKODFQOELJFMII-UHFFFAOYSA-N 0.000 description 1
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- 238000006116 polymerization reaction Methods 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
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- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 229910052701 rubidium Inorganic materials 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 229910052706 scandium Inorganic materials 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 229940045105 silver iodide Drugs 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- SNOOUWRIMMFWNE-UHFFFAOYSA-M sodium;6-[(3,4,5-trimethoxybenzoyl)amino]hexanoate Chemical compound [Na+].COC1=CC(C(=O)NCCCCCC([O-])=O)=CC(OC)=C1OC SNOOUWRIMMFWNE-UHFFFAOYSA-M 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
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- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 1
- 229910052716 thallium Inorganic materials 0.000 description 1
- 238000001029 thermal curing Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 125000003396 thiol group Chemical group [H]S* 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- MBYLVOKEDDQJDY-UHFFFAOYSA-N tris(2-aminoethyl)amine Chemical compound NCCN(CCN)CCN MBYLVOKEDDQJDY-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 238000001771 vacuum deposition Methods 0.000 description 1
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- 238000007740 vapor deposition Methods 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/50—Sympathetic, colour changing or similar inks
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/48—Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor body packages
- H01L33/50—Wavelength conversion elements
- H01L33/501—Wavelength conversion elements characterised by the materials, e.g. binder
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
- C08F222/10—Esters
- C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
- C08F222/102—Esters of polyhydric alcohols or polyhydric phenols of dialcohols, e.g. ethylene glycol di(meth)acrylate or 1,4-butanediol dimethacrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
- C08F222/10—Esters
- C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
- C08F222/106—Esters of polycondensation macromers
- C08F222/1063—Esters of polycondensation macromers of alcohol terminated polyethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/38—Inkjet printing inks characterised by non-macromolecular additives other than solvents, pigments or dyes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/02—Use of particular materials as binders, particle coatings or suspension media therefor
- C09K11/025—Use of particular materials as binders, particle coatings or suspension media therefor non-luminescent particle coatings or suspension media
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/20—Filters
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/48—Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor body packages
- H01L33/50—Wavelength conversion elements
- H01L33/501—Wavelength conversion elements characterised by the materials, e.g. binder
- H01L33/502—Wavelength conversion materials
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K50/00—Organic light-emitting devices
- H10K50/10—OLEDs or polymer light-emitting diodes [PLED]
- H10K50/11—OLEDs or polymer light-emitting diodes [PLED] characterised by the electroluminescent [EL] layers
- H10K50/115—OLEDs or polymer light-emitting diodes [PLED] characterised by the electroluminescent [EL] layers comprising active inorganic nanostructures, e.g. luminescent quantum dots
Abstract
본 발명은 발광입자, 중합성 모노머 및 아민계 첨가제를 포함하며, 상기 아민계 첨가제는 화학식 I로 나타나는 화합물을 포함하는, 광변환 잉크 조성물에 대한 것으로, 광변환 효율이 향상되고, 상온에서 보관하는 경우에도 청색광(Blue)에 대한 흡광도 및 드롭 사이즈(Drop size)의 변화가 적은 광변환 잉크 조성물, 이를 이용하여 제조된 광변환 적층기판, 광변환 화소기판 및 화상표시장치에 관한 것이다.The present invention relates to a light conversion ink composition comprising light emitting particles, a polymerizable monomer, and an amine-based additive, wherein the amine-based additive includes a compound represented by Formula (I), which has improved light conversion efficiency and is stored at room temperature. The present invention relates to a photoconversion ink composition having little change in absorbance and drop size for blue light, a photoconversion laminated substrate manufactured using the same, a photoconversion pixel substrate, and an image display device.
Description
본 발명은 광변환 잉크 조성물, 이를 이용하여 제조된 광변환 적층기판, 광변환 화소기판 및 화상표시장치에 관한 것이다.The present invention relates to a photoconversion ink composition, a photoconversion laminated substrate manufactured using the same, a photoconversion pixel substrate, and an image display device.
정보화 사회가 발전함에 따라 화상을 표시하기 위한 표시장치에 대한 요구가 다양한 형태로 증가하고 있으며, 근래에는 액정표시장치(LCD: Liquid Crystal Display), 플라즈마표시장치(PDP: Plasma Display Panel), 유기전계발광표시장치(OLED: Organic Light Emitting Diode Display Device)와 같은 여러 가지 표시장치가 활용되고 있다.As the information society develops, the demand for display devices for displaying images is increasing in various forms. Recently, liquid crystal displays (LCDs), plasma displays (PDPs), organic electric fields Various display devices such as an organic light emitting diode display device (OLED) are being used.
색재현율은 표시장치에서 가장 중요한 요소 중 하나이다. 최근에는 표시장치의 색 재현율을 높이기 위한 방안의 일 예로, 통상의 백색 LED를 대체하여 청색 LED를 이용하고, 별도의 광 변환수단인 양자점(quantum dot)을 포함하는 광변환 적층기판을 구비한 표시장치가 사용되고 있다. 예를 들면, 청색의 LED칩을 사용한 백라이트 또는 화소를 포함하는 컬러필터에 양자점이 분산된 광변환층을 포함하는 광변환 적층기판 또는 광변환 화소기판을 적용하여 광변환 효율을 높임으로써 표시장치의 색재현성을 향상하고자 한다.Color gamut is one of the most important factors in a display device. Recently, as an example of a plan to increase the color gamut of a display device, a blue LED is used instead of a normal white LED, and a display having a light conversion laminated board including quantum dots, which are separate light conversion means, is used. Device is in use. For example, by applying a light-conversion multilayer substrate or a light-conversion pixel substrate including a light-conversion layer in which quantum dots are dispersed to a backlight using a blue LED chip or a color filter including pixels to increase the light-conversion efficiency of a display device. It is intended to improve color reproducibility.
한편, 광변환 화소가 적용된 컬러필터를 제조하기 위하여, 양자점과 같은 발광입자를 포함하는 조성물을 이용한 포토리소그래피 방법을 사용할 수 있다. 그러나, 이러한 방법은 컬러 필터의 정교성과 재현성 측면에서는 우수하지만, 화소를 형성하기 위하여 각각의 색에 대하여 코팅, 노광, 현상 및 경화하는 과정이 각각 요구되어 제조 공정, 시간 및 비용이 늘어나고 공정간 제어 인자가 많아져 수율 관리에 어려움이 있다.Meanwhile, in order to manufacture a color filter to which a light conversion pixel is applied, a photolithography method using a composition including light emitting particles such as quantum dots may be used. However, although this method is excellent in terms of sophistication and reproducibility of color filters, processes of coating, exposing, developing, and curing are required for each color to form pixels, which increases the manufacturing process, time and cost, and controls between processes. Yield management is difficult due to the large number of factors.
이러한 문제점들을 해결하기 위하여, 잉크젯(inkjet) 방법이 제시되었다. 잉크젯 방법은 잉크젯 헤드(inkjet head)를 사용하여 구획되어 있는 소정 위치에 액체 잉크를 분사하여 각각의 잉크가 착색된 이미지를 구현하는 기술로, 적색, 녹색 및 청색을 포함한 복수의 색을 한번에 착색할 수 있어서 제조 공정, 시간 및 비용이 크게 절감될 수 있다. In order to solve these problems, an inkjet method has been proposed. The inkjet method is a technology that uses an inkjet head to jet liquid ink to a defined location to create an image in which each ink is colored, and a plurality of colors including red, green, and blue can be colored at once. Thus, the manufacturing process, time and cost can be greatly reduced.
관련하여, 대한민국 등록특허공보 제10-1475520호에서 잉크젯 프린트용 양자점 잉크 조성물에 관한 기술을, 대한민국 등록특허공보 제10-1628065호 에서 발광 복합체를 포함하는 조성물에 관한 기술을 개시하고 있으나, 광변환 효율이 충분하지 않으며, 특히 청색광(Blue)에 대한 흡광도 및 드롭 사이즈가 시간이 지남에 따라 크게 변화되는 문제가 있다.In relation to this, Korean Patent Registration No. 10-1475520 discloses a technique for a quantum dot ink composition for inkjet printing, and Korean Patent Registration No. 10-1628065 discloses a technique for a composition including a light emitting composite, but light conversion The efficiency is not sufficient, and in particular, there is a problem in that the absorbance for blue light and the drop size change greatly over time.
따라서, 광변환 효율이 우수한 광변환 적층기판 및 광변환 화소기판을 형성할 수 있으며, 시간이 지남에 따라 청색광(Blue)에 대한 흡광도 및 드롭 사이즈(Drop size)의 변화가 적은 광변환 잉크 조성물의 개발이 요구되고 있다.Therefore, it is possible to form a photoconversion laminated substrate and a photoconversion pixel substrate having excellent photoconversion efficiency, and a photoconversion ink composition having little change in absorbance and drop size for blue light over time. development is required.
본 발명은 광변환 효율이 향상되고, 상온에서 방치하는 경우에도 청색광(Blue)에 대한 흡광도 및 드롭 사이즈(Drop size)가 적은 광변환 잉크 조성물을 제공하는 것을 일 목적으로 한다.An object of the present invention is to provide a light conversion ink composition having improved light conversion efficiency and low absorbance and drop size for blue light even when left at room temperature.
또한, 본 발명은 상기 광변환 잉크 조성물을 이용하여 제조된 광변환 적층기판, 광변환 화소기판 및 화상표시장치를 제공하는 것을 일 목적으로 한다.In addition, an object of the present invention is to provide a photoconversion laminated substrate, a photoconversion pixel substrate, and an image display device manufactured using the photoconversion ink composition.
상기 과제를 해결하기 위하여, 본 발명은 발광입자, 중합성 모노머 및 아민계 첨가제를 포함하며, 상기 아민계 첨가제는 화학식 I로 나타내는 화합물을 포함하는, 광변환 잉크 조성물을 제공한다.In order to solve the above problems, the present invention provides a light conversion ink composition comprising light-emitting particles, a polymerizable monomer and an amine-based additive, wherein the amine-based additive includes a compound represented by Formula I.
또한, 본 발명은 상기 광변환 잉크 조성물을 이용하여 제조된 광변환 적층기판, 광변환 화소기판 및 화상표시장치를 제공한다.In addition, the present invention provides a photoconversion laminated substrate, a photoconversion pixel substrate, and an image display device manufactured using the photoconversion ink composition.
본 발명에 따른 광변환 잉크 조성물을 이용하면 광변환 효율이 향상되고, 상온에서 보관하는 경우에도 청색광(Blue)에 대한 흡광도 및 드롭 사이즈(Drop size)가 적은 광변환 도막을 제공할 수 있다.When the light conversion ink composition according to the present invention is used, the light conversion efficiency is improved, and even when stored at room temperature, a light conversion coating film having low absorbance and drop size for blue light can be provided.
본 발명은, 상기 광변환 잉크 조성물을 이용하여 백라이트 유닛 또는 광변환 화소기판 및 화상표시장치에 유용하게 응용될 수 있다.In the present invention, the photoconversion ink composition can be usefully applied to a backlight unit or a photoconversion pixel substrate and an image display device.
본 발명은 발광입자 및 중합성 모노머를 포함하며, 상기 발광입자로 특정한 금속 원소들을 포함하는 코어 및 쉘을 포함하며, 화학식 1로 나타내는 화합물을 포함함으로써, 광변환 효율이 향상되고, 청색광(Blue)에 대한 흡광도 및 드롭 사이즈(Drop size)의 변화가 적은 광변환 잉크 조성물 및 이를 이용하여 제조된 광변환 적층기판, 광변환 화소기판 및 화상표시장치을 제공한다.The present invention includes a light-emitting particle and a polymerizable monomer, and includes a core and a shell containing specific metal elements as the light-emitting particle, and by including the compound represented by Formula 1, light conversion efficiency is improved, and blue light (Blue) Provided is a light conversion ink composition having little change in absorbance and drop size for a light conversion layered substrate, a light conversion pixel substrate, and an image display device manufactured using the same.
구체적으로, 본 발명은, Ag, In, Ga 및 S를 포함하는 코어; 및 In, Ga 및 S 중 적어도 2종의 원소를 포함하는 쉘을 포함하는 발광입자를 포함하며, 화학식 I을 포함하는 아민계 첨가제를 더 포함함에 따라, 청색광원에 대한 흡수가 향상되는 특성이 있어서, 광변환 효율이 향상되며, 내광성, 내열성, 고온고습 안정성 및 점도 안정성이 향상된 것을 특징으로 한다. Specifically, the present invention is a core containing Ag, In, Ga and S; and light-emitting particles including a shell containing at least two elements of In, Ga, and S, and further comprising an amine-based additive containing Formula I, thereby improving absorption of a blue light source. , Light conversion efficiency is improved, and light resistance, heat resistance, high temperature and high humidity stability, and viscosity stability are improved.
이하, 본 발명을 상세히 설명한다.Hereinafter, the present invention will be described in detail.
<광변환 잉크 조성물><Light conversion ink composition>
본 발명의 광변환 잉크 조성물은 발광입자 및 중합성 모노머를 포함하며, 화학식 I 로 나타내는 화합물을 포함하고, 산란입자, 광중합 개시제, 첨가제 및 용제 중 1종 이상을 더 포함할 수 있다. The light conversion ink composition of the present invention includes light-emitting particles and a polymerizable monomer, and includes a compound represented by Formula I, and may further include at least one of scattering particles, a photopolymerization initiator, an additive, and a solvent.
발광 입자luminous particles
발광 입자는, 예를 들면, 소정의 파장의 광을 흡수함으로써, 흡수한 파장과는 다른 파장의 광을 발할 수 있다. 발광성 나노 결정 입자는, 605∼665㎚의 범위에 발광 피크 파장을 갖는 광(적색광)을 발하는 적색 발광입자 일 수 있고, 500∼600㎚의 범위에 발광 피크 파장을 갖는 광(녹색광)을 발하는 녹색 발광 입자 일 수 있으며, 420∼480㎚의 범위에 발광 피크 파장을 갖는 광(청색광)을 발하는 청색 발광 입자일 수 있다. 본 발명의 광변환 잉크 조성물은, 상기 발광 입자 중 적어도 1종을 포함하는 것이 바람직하다.The light-emitting particles can emit light of a wavelength different from the absorbed wavelength by, for example, absorbing light of a predetermined wavelength. The luminescent nanocrystal particles may be red light emitting particles emitting light (red light) having a peak emission wavelength in the range of 605 to 665 nm, and green light emitting light (green light) having a peak emission wavelength in the range of 500 to 600 nm. It may be a light-emitting particle, and may be a blue light-emitting particle that emits light (blue light) having a peak emission wavelength in the range of 420 to 480 nm. The light conversion ink composition of the present invention preferably contains at least one of the light-emitting particles.
본 발명에서, 상기 발광 입자는 반도체 재료를 포함하는 것으로, 예컨데, 양자점 등을 들 수 있다.In the present invention, the light-emitting particles include semiconductor materials, such as quantum dots.
본 발명의 일 실시예에 따르면, 상기 발광 입자는 표면 상에 리간드층을 가지는 것 일 수 있다.According to one embodiment of the present invention, the light emitting particle may have a ligand layer on the surface.
본 발명의 일 실시예에 있어서, 상기 양자점은 코어 및 상기 코어의 적어도 일부를 덮은 쉘을 포함하는 코어-쉘 구조를 가진다.In one embodiment of the present invention, the quantum dot has a core-shell structure including a core and a shell covering at least a portion of the core.
본 발명에서, 상기 코어-쉘 구조는, 코어와 제1 쉘로 이루어지는 구조, 예컨데 코어/쉘 구조일 수 있고, 코어와 제1 쉘 및 제2 쉘로 이루어지는 구조, 즉 코어/쉘/쉘 구조일 수 있다.In the present invention, the core-shell structure may be a structure composed of a core and a first shell, such as a core/shell structure, and may be a structure composed of a core, a first shell, and a second shell, that is, a core/shell/shell structure. .
상기 코어는 은(Ag), 인듐(In), 갈륨(Ga) 및 황(S)의 사원소 화합물을 포함한다. 예컨데, 상기 코어는 AgInGaS이다. 이러한 코어는 단파장의 광원을 보다 효율적으로 흡수하고, 발광영역의 광흡수율은 최소화 할 수 있는 이점이 있어서, 적은 함량에서도 우수한 광변환 효율을 기대할 수 있다. The core includes a quaternary compound of silver (Ag), indium (In), gallium (Ga), and sulfur (S). For example, the core is AgInGaS. Such a core has an advantage of more efficiently absorbing a short-wavelength light source and minimizing the light absorption rate of the light emitting region, so that excellent light conversion efficiency can be expected even with a small content.
상기 쉘은 In, Ga 및 S 중 적어도 2종의 원소를 포함하며, 예컨데, GaS 등을 포함할 수 있다. 이때, 쉘은 본 발명에서 상기 쉘은 코어의 트랩에미션을 억제하여 발광파장의 반치폭을 좁게 유지할 수 있어서 색순도가 향상되는 기능을 한다. The shell includes at least two elements of In, Ga, and S, and may include, for example, GaS. At this time, in the present invention, the shell functions to improve color purity by suppressing the trap emission of the core and maintaining a narrow half width of the emission wavelength.
예시적인 실시예 따르면, 코어-쉘 구조의 양자점은 AgInGaS/GaS 등을 들 수 있으며, 이에 제한되는 것은 아니다.According to an exemplary embodiment, the quantum dot of the core-shell structure may include AgInGaS/GaS, etc., but is not limited thereto.
일부 실시예에 있어서, 본 발명은 필요에 따라 상술한 코어-쉘 구조 외에 다른 구조의 양자점을 더 포함할 수 있다. 예를 들면, InP/ZnSe/ZnS, InP/ZnS, InGaP/ZnS, InGaP/ZnSe/ZnS등의 코어-쉘 구조의 양자점을 더 포함할 수 있으나, 이에 제한되는 것은 아니다.In some embodiments, the present invention may further include a quantum dot having a structure other than the core-shell structure described above, if necessary. For example, core-shell quantum dots such as InP/ZnSe/ZnS, InP/ZnS, InGaP/ZnS, and InGaP/ZnSe/ZnS may be further included, but are not limited thereto.
상기 양자점은 습식 화학 공정(wet chemical process), 유기금속 화학증착 공정(MOCVD, metal organic chemical vapor deposition) 또는 분자선 에피텍시 공정(MBE, molecular beam epitaxy)에 의해 합성될 수 있으나 이에 한정되는 것은 아니나, 바람직하게는 습식 화학 공정(wet chemical process)에 의해 합성하는 것이 더욱 광특성이 우수한 양자점을 수득할 수 있다.The quantum dots may be synthesized by a wet chemical process, a metal organic chemical vapor deposition (MOCVD) process, or a molecular beam epitaxy (MBE) process, but are not limited thereto. , Preferably, it is possible to obtain quantum dots having excellent optical properties when synthesized by a wet chemical process.
상기 습식 화학 공정이란 유기용제에 전구체 물질을 넣어 입자를 성장시키는 방법이다. 결정이 성장될 때 유기용제가 자연스럽게 양자점 결정의 표면에 배위되어 분산제 역할을 하여 결정의 성장을 조절하게 되므로, 유기금속 화학증착 공정이나 분자선 에피텍시와 같은 기상증착법보다 더 쉽고 저렴한 공정을 통하여 나노 입자의 성장을 제어할 수 있으므로, 상기 습식 화학 공정을 사용하여 상기 양자점을 제조하는 것이 바람직하다.The wet chemical process is a method of growing particles by putting a precursor material in an organic solvent. When the crystal grows, the organic solvent is naturally coordinated on the surface of the quantum dot crystal and acts as a dispersant to control the growth of the crystal, so it is easier and cheaper than vapor deposition methods such as organometallic chemical vapor deposition or molecular beam epitaxy to produce nano Since the growth of the particles can be controlled, it is preferred to prepare the quantum dots using the wet chemical process.
본 발명에 있어서, 상기 발광 입자는 상기 광변환 잉크 조성물 내 고형분 100중량%에 대하여 3 내지 50 중량%, 바람직하게는 5 내지 45 중량%, 더욱 바람직하게는 8 내지 40 중량%로 포함될 수 있다. 발광 입자가 상기 범위 내로 포함되는 경우 광변환 효율이 향상될 수 있다. In the present invention, the light-emitting particles may be included in an amount of 3 to 50% by weight, preferably 5 to 45% by weight, and more preferably 8 to 40% by weight based on 100% by weight of the solid content in the light conversion ink composition. When the light emitting particles are included within the above range, light conversion efficiency may be improved.
상기 발광 입자가 상기 함량범위 미만으로 포함될 경우 광변환 효율이 저하되어 고품위의 표시장치의 구현이 어려울 수 있다. 또한 상기 함량범위를 초과할 경우 경화를 구현하는 성분들이 부족하여 도막의 경화도 부족에 의해 디스플레이 제조 후공정의 생산성 및 제품의 신뢰성을 저하시킬 수 있다.When the content of the light emitting particles is less than the above range, light conversion efficiency is lowered, making it difficult to implement a high-quality display device. In addition, if the content exceeds the above range, the productivity of the post-production process of the display and the reliability of the product may be reduced due to insufficient curing of the coating film due to lack of components that implement curing.
중합성 모노머polymerizable monomer
본 발명의 일 실시형태에서, 광변환 잉크 조성물은 중합성 모너머를 포함한다.In one embodiment of the present invention, the light conversion ink composition includes a polymerizable monomer.
상기 중합성 모노머는 하기 화학식 5로 표시되는 화합물을 포함할 수 있다.The polymerizable monomer may include a compound represented by Formula 5 below.
[화학식 5][Formula 5]
상기 화학식 2에서, In Formula 2,
R28는 탄소 수 1 내지 20의 알킬렌기, 페닐렌기 또는 탄소 수 3 내지 10의 의 사이클로알킬렌기이며, R 28 is an alkylene group having 1 to 20 carbon atoms, a phenylene group, or a cycloalkylene group having 3 to 10 carbon atoms;
R29는, 각각 독립적으로, 수소 또는 탄소 수 1 내지 20의 알킬기이며, 바람직하게는 수소 또는 메틸기이고, R 29 is each independently hydrogen or an alkyl group having 1 to 20 carbon atoms, preferably hydrogen or a methyl group;
m은 1 내지 15의 정수이다.m is an integer from 1 to 15;
본 명세서에서 사용되는 탄소 수 1 내지 20의 알킬렌기는 탄소수 1 내지 20개로 구성된 직쇄형 또는 분지형의 2가 탄화수소를 의미하며, 예를 들어 메틸렌, 에틸렌, n-프로필렌, 이소프로필렌, n-부틸렌, 이소부틸렌, n-펜틸렌, n-헥실렌, n-헵틸렌, n-옥틸렌, n-노닐렌 등이 포함되나 이에 한정되는 것은 아니다.An alkylene group having 1 to 20 carbon atoms as used herein means a straight-chain or branched divalent hydrocarbon having 1 to 20 carbon atoms, for example, methylene, ethylene, n-propylene, isopropylene, n-butyl include, but are not limited to, ene, isobutylene, n-pentylene, n-hexylene, n-heptylene, n-octylene, n-nonylene, and the like.
본 명세서에서 사용되는 탄소 수 3 내지 10의 사이클로알킬렌기는 탄소수 3 내지 10개로 구성된 단순 또는 융합 고리형 2가 탄화수소를 의미하며, 예를 들어 사이클로프로필렌, 사이클로부틸렌, 사이클로펜틸렌, 사이클로헥실렌 등이 포함되나 이에 한정되는 것은 아니다.The cycloalkylene group having 3 to 10 carbon atoms as used herein refers to a simple or fused cyclic divalent hydrocarbon having 3 to 10 carbon atoms, for example, cyclopropylene, cyclobutylene, cyclopentylene, and cyclohexylene. Including, but not limited to.
상기 탄소 수 1 내지 20의 알킬렌기, 페닐렌기 및 탄소 수 3 내지 10의 사이클로알킬렌기는 한 개 또는 그 이상의 수소가 C1-C6의 알킬기, C2-C6의 알케닐기, C2-C6의 알키닐기, C3-C10의 사이클로알킬기, C3-C10의 헤테로사이클로알킬기, C3-C10의 헤테로사이클로알킬옥시기, C1-C6의 할로알킬기, C1-C6의 알콕시기, C1-C6의 티오알콕시기, 아릴기, 아실기, 히드록시, 티오(thio), 할로겐, 아미노, 알콕시카르보닐, 카르복시, 카바모일, 시아노, 니트로 등으로 치환될 수 있다.The alkylene group having 1 to 20 carbon atoms, the phenylene group and the cycloalkylene group having 3 to 10 carbon atoms have one or more hydrogens in a C 1 -C 6 alkyl group, a C 2 -C 6 alkenyl group, a C 2 - C 6 alkynyl group, C 3 -C 10 cycloalkyl group, C 3 -C 10 heterocycloalkyl group, C 3 -C 10 heterocycloalkyloxy group, C 1 -C 6 haloalkyl group, C 1 -C Substituted with a 6- membered alkoxy group, C 1 -C 6 thioalkoxy group, aryl group, acyl group, hydroxy, thio, halogen, amino, alkoxycarbonyl, carboxy, carbamoyl, cyano, nitro, etc. can
본 발명의 일 실시형태에서, R28은 C1-C20의 알킬렌기일 수 있으며, 바람직하게는 C2 - C16의 알킬렌기 일 수 있다. R28이 C1-C20의 알킬렌기인 경우, 본 발명의 광변환 잉크 조성물은 용제 없이도 발광입자의 분산성이 우수하여 제팅성이 개선되고, 도막 경도 및 두께 균일도가 향상될 수 있다.In one embodiment of the present invention, R 28 may be a C 1 -C 20 alkylene group, preferably a C 2 -C 16 alkylene group. When R 28 is a C 1 -C 20 alkylene group, the light conversion ink composition of the present invention has excellent dispersibility of light emitting particles even without a solvent, so that jetting property can be improved, and coating film hardness and thickness uniformity can be improved.
본 발명의 일 실시예에 따르면, 상기 m은 상술한 바와 같이 1 내지 15의 정수일 수 있고, 바람직하게는 1 내지 5의 정수일 수 있다. 상기 범위를 초과하는 경우, 점도가 높아서 분산성이 떨어질 수 있다. According to one embodiment of the present invention, m may be an integer of 1 to 15, preferably an integer of 1 to 5, as described above. If it exceeds the above range, the viscosity may be high and dispersibility may be deteriorated.
상기 화학식 5로 표시되는 화합물의 구체예로는 1,6-헥산디올 디아크릴레이트, 폴리에틸렌글리콜디아크릴레이트, 2-하이드록시-3-메타크릴프로필아크릴레이트, 1,9-비스아크릴로일옥시노난, 트리프로필렌글리콜디아크릴레이트 등을 들 수 있으며, 이에 제한되는 것은 아니다.Specific examples of the compound represented by Formula 5 include 1,6-hexanediol diacrylate, polyethylene glycol diacrylate, 2-hydroxy-3-methacrylpropyl acrylate, 1,9-bisacryloyloxyno eggs, tripropylene glycol diacrylate, and the like, but are not limited thereto.
상기 화학식 5로 표시되는 화합물은 발광입자의 분산성을 향상시킴으로써 용제 없이도 80cP이하의 저점도 광변환 잉크 조성물의 구현을 가능하게 한다. 이에 따라, 본 발명에 따른 광변환 잉크 조성물은 잉크젯 인쇄 방식으로 광변환 적층기판를 제조하는데 효과적으로 사용될 수 있다.The compound represented by Chemical Formula 5 enables the implementation of a low-viscosity light conversion ink composition of 80 cP or less without a solvent by improving the dispersibility of light-emitting particles. Accordingly, the light-conversion ink composition according to the present invention can be effectively used to manufacture a light-conversion laminated substrate using an inkjet printing method.
본 발명의 광변환 잉크 조성물은 상기 화학식 5로 표시되는 중합성 모노머 외에도 본 발명의 목적을 벗어나지 않는 한도 내에서 당 분야에서 통상적으로 사용되는 중합성 화합물를 더 포함할 수 있다. 예를 들면 단관능 단량체, 2관능 단량체, 그 밖의 다관능 단량체 등을 들 수 있으며, 이들 중에서 2관능 단량체가 바람직하게 사용된다.In addition to the polymerizable monomer represented by Chemical Formula 5, the light conversion ink composition of the present invention may further include a polymerizable compound commonly used in the art within the scope of not departing from the object of the present invention. Examples thereof include monofunctional monomers, bifunctional monomers, and other polyfunctional monomers, and among these, bifunctional monomers are preferably used.
상기 단관능 단량체의 종류는 특별히 한정되지 않으며, 예를 들면 노닐페닐카르비톨아크릴레이트, 2-히드록시-3-페녹시프로필아크릴레이트, 2-에틸헥실카르비톨아크릴레이트, 2-히드록시에틸아크릴레이트, N-비닐피롤리돈 등을 들 수 있다.The type of the monofunctional monomer is not particularly limited, and examples thereof include nonylphenylcarbitol acrylate, 2-hydroxy-3-phenoxypropyl acrylate, 2-ethylhexylcarbitol acrylate, and 2-hydroxyethyl acrylate. rate, N-vinylpyrrolidone, and the like.
상기 2관능 단량체의 종류는 특별히 한정되지 않으며, 예를 들면 비스페놀 A의 비스(아크릴로일옥시에틸)에테르 등을 들 수 있다.The type of the bifunctional monomer is not particularly limited, and examples thereof include bis(acryloyloxyethyl) ether of bisphenol A and the like.
상기 다관능 단량체의 종류는 특별히 한정되지 않으며, 예를 들면, 트리메틸올프로판트리(메타)아크릴레이트, 에톡실레이티드트리메틸올프로판트리(메타)아크릴레이트, 프로폭실레이티드트리메틸올프로판트리(메타)아크릴레이트, 펜타에리스리톨트리(메타)아크릴레이트, 펜타에리스리톨테트라(메타)아크릴레이트, 디펜타에리스리톨트리(메타)아크릴레이트, 디펜타에리스리톨펜타(메타)아크릴레이트, 에톡실레이티드디펜타에리스리톨헥사(메타)아크릴레이트, 프로폭실레이티드디펜타에리스리톨헥사(메타)아크릴레이트, 디펜타에리스리톨헥사(메타)아크릴레이트 등을 들 수 있다.The type of the multifunctional monomer is not particularly limited, and examples thereof include trimethylolpropane tri(meth)acrylate, ethoxylated trimethylolpropane tri(meth)acrylate, and propoxylated trimethylolpropane tri(meth)acrylate. )Acrylate, pentaerythritol tri(meth)acrylate, pentaerythritol tetra(meth)acrylate, dipentaerythritol tri(meth)acrylate, dipentaerythritol penta(meth)acrylate, ethoxylated dipentaerythritol hexa (meth)acrylate, propoxylated dipentaerythritol hexa(meth)acrylate, dipentaerythritol hexa(meth)acrylate, etc. are mentioned.
이때 3관능 이상, 다관능 경화성 모노머를 더 포함하는 경우 잉크조성물의 점도를 80cP이내로 제어하는 경우 잉크젯 특성을 얻을 수 있다.In this case, when a trifunctional or more functional curable monomer is further included, inkjet characteristics can be obtained when the viscosity of the ink composition is controlled within 80 cP.
상기 중합성 모노머는 광변환 잉크 조성물 고형분 전체 100중량%에 대하여 30 내지 95 중량%, 바람직하게는 40 내지 90 중량%로 포함될 수 있다. 상기 중합성 모노머가 상기 범위 내로 포함될 경우 화소부의 강도나 평활성 측면에서 바람직한 이점이 있다. 상기 중합성 모노머가 상기 범위 미만으로 포함되는 경우 잉크 제팅을 위한 유동성 확보가 어려워 지며, 상기 범위를 초과하여 포함되는 경우 발광입자의 함량이 부족하여 광효율이 떨어지는 문제를 야기 할 수 있으므로 상기 범위 내로 포함되는 것이 바람직하다.The polymerizable monomer may be included in an amount of 30 to 95% by weight, preferably 40 to 90% by weight, based on 100% by weight of the total solid content of the light conversion ink composition. When the polymerizable monomer is included within the above range, there is a preferable advantage in terms of strength or smoothness of the pixel unit. When the polymerizable monomer is included in less than the above range, it becomes difficult to secure fluidity for ink jetting, and when it is included in more than the above range, the content of light emitting particles is insufficient, which may cause a problem of low light efficiency, so included within the above range it is desirable to be
화학식 I로 나타내는 아민계 첨가제Amine-based additive represented by Formula I
본 발명은 하기 화학식 I로 나타내는 화합물을 포함하는 것을 특징으로 하며, 잉크 조성물 내에 양자점이 안정적으로 분산될 수 있도록 하여, 잉크 젯팅 공정 간에서도 노즐이 막히지 않도록 돕는 효과를 갖는다. The present invention is characterized in that it includes a compound represented by Formula I, and has an effect of helping to prevent nozzles from being clogged even between ink jetting processes by stably dispersing quantum dots in an ink composition.
[화학식 I][Formula I]
상기 화학식 I에서,In the above formula I,
Ra, Rb 및 Rc는, 각각 독립적으로, 수소, 치환 또는 비치환된 탄소 수 1 내지 5의 알킬기, 또는 하나 이상의 질소원자, 바람직하게는 2개 이상의 질소원자를 포함하는 탄소 수 2 내지 50의 탄화수소기이다.R a , R b and R c are each independently hydrogen, a substituted or unsubstituted alkyl group having 1 to 5 carbon atoms, or one or more nitrogen atoms, preferably 2 to 10 carbon atoms including 2 or more nitrogen atoms. It is a hydrocarbon group of 50.
본 발명에서, 상기 “치환”된의 치환기는, 수산화기, 아미노기, 탄소 수 1 내지 10의 알킬기, 탄소 수 1 내지 10의 알케닐기, 탄소 수 1 내지 10의 알키닐기, 탄소 수 1 내지 10의 아민기, 탄소 수 1 내지 10의 에톡시기, 및/또는 할로겐기를 포함하며, 상기 알킬기, 알케닐기, 알키닐기, 아민기 및 에톡시기는, 직쇄, 분쇄, 선형 및 환형을 모두 포함하며, 하나 이상의 수산화기, 할로겐기, 아미노기 등으로 치환되거나 치환되지 않은 것을 포함한다. In the present invention, the “substituted” substituent is a hydroxyl group, an amino group, an alkyl group having 1 to 10 carbon atoms, an alkenyl group having 1 to 10 carbon atoms, an alkynyl group having 1 to 10 carbon atoms, an amine having 1 to 10 carbon atoms group, an ethoxy group having 1 to 10 carbon atoms, and/or a halogen group, wherein the alkyl group, alkenyl group, alkynyl group, amine group, and ethoxy group include all of straight-chain, branched, linear, and cyclic groups, and at least one hydroxyl group , including those unsubstituted or substituted with a halogen group, an amino group, and the like.
구체적으로, 본 발명의 화학식 I로 나타내는 화합물은, 다음의 화학식 1 내지 4의 구조를 갖는 것 중 하나이상을 포함할 수 있다. Specifically, the compound represented by Formula I of the present invention may include one or more of those having structures of Formulas 1 to 4 below.
[화학식 1][Formula 1]
상기 화학식 1에서,In Formula 1,
R1, R2, R4, R6 및 R7은 각각 독립적으로, 수소 또는 치환 또는 비치환된 탄소 수 1 내지 5의 알킬기이며,R 1 , R 2 , R 4 , R 6 and R 7 are each independently hydrogen or a substituted or unsubstituted alkyl group having 1 to 5 carbon atoms;
R3 및 R5는 각각 독립적으로, 치환 또는 비치환된 탄소 수 1 내지 5의 알킬렌기이다.R 3 and R 5 are each independently a substituted or unsubstituted alkylene group having 1 to 5 carbon atoms.
[화학식 2][Formula 2]
상기 화학식 2에서,In Formula 2,
R8, R9, R11, R13, R15 및 R16은 각각 독립적으로, 수소 또는 치환 또는 비치환된 탄소 수 1 내지 5의 알킬기이며,R 8 , R 9 , R 11 , R 13 , R 15 and R 16 are each independently hydrogen or a substituted or unsubstituted alkyl group having 1 to 5 carbon atoms;
R10, R12 및 R14는 각각 독립적으로, 치환 또는 비치환된 탄소 수 1 내지 5의 알킬렌기이다.R 10 , R 12 and R 14 are each independently a substituted or unsubstituted alkylene group having 1 to 5 carbon atoms.
[화학식 3][Formula 3]
상기 화학식 3에서,In Formula 3,
R17, R18, R21, R22, R24 및 R25는 각각 독립적으로, 수소 또는 치환 또는 비치환된 탄소 수 1 내지 5의 알킬기이며,R 17 , R 18 , R 21 , R 22 , R 24 and R 25 are each independently hydrogen or a substituted or unsubstituted alkyl group having 1 to 5 carbon atoms;
R19, R20 및 R23은 각각 독립적으로, 치환 또는 비치환된 탄소 수 1 내지 5의 알킬렌기이다.R 19 , R 20 and R 23 are each independently a substituted or unsubstituted alkylene group having 1 to 5 carbon atoms.
[화학식 4][Formula 4]
상기 화학식 4에서,In Formula 4,
R17, R18, R20, R22, R24, R26 및 R27은 각각 독립적으로, 수소 또는 치환 또는 비치환된 탄소 수 1 내지 5의 알킬기이며,R 17 , R 18 , R 20 , R 22 , R 24 , R 26 and R 27 are each independently hydrogen or a substituted or unsubstituted alkyl group having 1 to 5 carbon atoms;
R19, R21, R23 및 R25는 각각 독립적으로, 치환 또는 비치환된 탄소 수 1 내지 5의 알킬렌기이다.R 19 , R 21 , R 23 and R 25 are each independently a substituted or unsubstituted alkylene group having 1 to 5 carbon atoms.
바람직하게, 본 발명의 화학식 I로 나타내는 화합물은, 다음의 구조를 갖는 것 중 하나이상을 포함할 수 있으나, 이에 한정되지 않는다. Preferably, the compound represented by Formula I of the present invention may include, but is not limited to, one or more of those having the following structures.
[화학식 1-1][Formula 1-1]
Diethylenetriamine, TCI사Diethylenetriamine, TCI company
[화학식 1-2][Formula 1-2]
2,2'-Diamino-N-methyldiethylamine, TCI사2,2'-Diamino-N-methyldiethylamine, TCI company
[화학식 1-3][Formula 1-3]
N,N',N''-Trimethyldiethylenetriamine, TCI사N,N',N''-Trimethyldiethylenetriamine, TCI company
[화학식 1-4][Formula 1-4]
N,N,N',N'',N''-Pentamethyldiethylenetriamine, TCI사N,N,N',N'',N''-Pentamethyldiethylenetriamine, TCI
[화학식 1-5][Formula 1-5]
3,3'-Diaminodipropylamine, TCI사3,3'-Diaminodipropylamine, TCI company
[화학식 1-6][Formula 1-6]
3,3'-Iminobis(N,N-dimethylpropylamine), TCI사3,3'-Iminobis (N,N-dimethylpropylamine), TCI company
[화학식 1-7][Formula 1-7]
2,6,10-Trimethyl-2,6,10-triazaundecane, TCI사2,6,10-Trimethyl-2,6,10-triazaundecane, TCI company
[화학식 1-8][Formula 1-8]
N,N,N'',N''-Tetrabutyldiethylenetriamine, TCI사N,N,N'',N''-Tetrabutyldiethylenetriamine, TCI
[화학식 1-9][Formula 1-9]
N,N,N'',N''-Tetraisopropyldiethylenetriamine, TCI사N,N,N'',N''-Tetraisopropyldiethylenetriamine, TCI company
[화학식 1-10][Formula 1-10]
N,N,N',N'',N''-Pentakis(2-hydroxypropyl)diethylenetriamine, TCI사N,N,N',N'',N''-Pentakis(2-hydroxypropyl)diethylenetriamine, TCI company
[화학식 2-1] [Formula 2-1]
Triethylenetetramine, TCI사Triethylenetetramine, TCI company
[화학식 2-2][Formula 2-2]
1,1,4,7,10,10-Hexamethyltriethylenetetramine, TCI사1,1,4,7,10,10-Hexamethyltriethylenetetramine, TCI
[화학식 2-3][Formula 2-3]
N,N'-Bis(3-aminopropyl)ethylenediamine, TCI사N,N'-Bis(3-aminopropyl)ethylenediamine, TCI company
[화학식3-1] [Formula 3-1]
Tris(2-aminoethyl)amine, TCI사Tris(2-aminoethyl)amine, TCI company
[화학식3-2][Formula 3-2]
Tris[2-(dimethylamino)ethyl]amine, TCI사Tris[2-(dimethylamino)ethyl]amine, TCI company
[화학식3-3][Formula 3-3]
Tris(3-aminopropyl)amine, TCI사Tris(3-aminopropyl)amine, TCI company
[화학식 4-1] [Formula 4-1]
Tetraethylene pentaamine, 시그마알드리치사Tetraethylene pentaamine, Sigma Aldrich
상기 화학식 I로 나타내는 화합물은, 광변환 잉크 조성물 고형분 전체 100중량%에 대하여 0.1 중량% 초과 및 15 중량% 미만으로 포함될 수 있으며, 바람직하게는 0.01 내지 10 중량%의 범위로 포함될 수 있다. 상기 화학식 I로 나타내는 화합물이 상기 범위 내로 포함될 경우 광변환 효율이 향상되고, 청색광(Blue)에 대한 흡광도 및 드롭 사이즈(Drop size)의 변화 측면에서 유리하므로, 상기 범위 내로 포함되는 것이 바람직하다.The compound represented by Formula I may be included in an amount greater than 0.1% by weight and less than 15% by weight, preferably in the range of 0.01 to 10% by weight, based on 100% by weight of the total solid content of the light conversion ink composition. When the compound represented by Formula I is included within the above range, the light conversion efficiency is improved, and it is advantageous in terms of change in absorbance and drop size for blue light, so it is preferably included within the above range.
산란입자scattering particles
본 발명에 따른 광변환 잉크 조성물은 산란입자를 더 포함할 수 있다.The light conversion ink composition according to the present invention may further include scattering particles.
상기 산란입자는 통상의 무기 재료를 사용할 수 있으며, 바람직하게는 평균입경이 50 내지 1000nm인 금속산화물을 포함할 수 있다.The scattering particles may use a conventional inorganic material, and preferably may include a metal oxide having an average particle diameter of 50 to 1000 nm.
상기 금속산화물은 Li, Be, B, Na, Mg, Al, Si, K, Ca, Sc, V, Cr, Mn, Fe, Ni, Cu, Zn, Ga, Ge, Rb, Sr, Y, Mo, Cs, Ba, La, Hf, W, Tl, Pb, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Ti, Sb, Sn, Zr, Nb,Ce, Ta, In 및 이들의 조합으로 이루어진 군에서 선택된 1종의 금속을 포함하는 산화물일 수 있으나, 이에 한정되지는 않는다.The metal oxides include Li, Be, B, Na, Mg, Al, Si, K, Ca, Sc, V, Cr, Mn, Fe, Ni, Cu, Zn, Ga, Ge, Rb, Sr, Y, Mo, Cs, Ba, La, Hf, W, Tl, Pb, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Ti, Sb, Sn, Zr, Nb, It may be an oxide containing one type of metal selected from the group consisting of Ce, Ta, In, and combinations thereof, but is not limited thereto.
구체적으로 Al2O3, SiO2, ZnO, ZrO2, BaTiO3, TiO2, Ta2O5, Ti3O5, ITO, IZO, ATO, ZnO-Al, Nb2O3, SnO, MgO, BaSO4 및 이들의 조합으로 이루어진 군에서 선택된 1종이 가능하다. 필요한 경우 아크릴레이트 등의 불포화 결합을 갖는 화합물로 표면 처리된 재질도 사용 가능하다.Specifically, Al 2 O 3 , SiO 2 , ZnO, ZrO 2 , BaTiO 3 , TiO 2 , Ta 2 O 5 , Ti 3 O 5 , ITO, IZO, ATO, ZnO-Al, Nb 2 O 3 , SnO, MgO, BaSO 4 and one selected from the group consisting of combinations thereof is possible. If necessary, a material surface-treated with a compound having an unsaturated bond such as acrylate may also be used.
본 발명에 따른 광변환 잉크 조성물이 산란입자를 포함할 경우, 상기 산란입자를 통해 발광입자에서 방출된 광의 경로를 증가시켜 광변환 코팅층에서의 전체적인 광효율을 높일 수 있어 바람직하다. 이러한 측면에서, 본 발명의 광변환 잉크 조성물은 산란입자로 TiO2, SiO2, ZnO, BaSO4 중에서 선택된 1종 이상을 포함하는 것이 바람직하다.When the light conversion ink composition according to the present invention includes scattering particles, it is preferable to increase the overall light efficiency in the light conversion coating layer by increasing the path of light emitted from the light emitting particles through the scattering particles. In this aspect, the light conversion ink composition of the present invention preferably includes at least one selected from among TiO 2 , SiO 2 , ZnO, and BaSO 4 as scattering particles.
상기 산란입자는 50 내지 1000nm의 평균입경을 가질 수 있으며, 바람직하기로 100 내지 500nm 범위인 것을 사용한다. 이때 입자 크기가 너무 작으면 양자점으로부터 방출된 빛의 충분한 산란 효과를 기대할 수 없고, 이와 반대로 너무 큰 경우에는 조성물 내에 가라 앉거나 균일한 품질의 자발광층 표면을 얻을 수 없으므로, 상기 범위내에서 적절히 조절하여 사용한다.The scattering particles may have an average particle diameter of 50 to 1000 nm, preferably used in the range of 100 to 500 nm. At this time, if the particle size is too small, sufficient scattering effect of the light emitted from the quantum dots cannot be expected, and on the other hand, if it is too large, it sinks in the composition or the surface of the self-luminous layer of uniform quality cannot be obtained. and use it
상기 산란입자는 상기 광변환 잉크 조성물 고형분 전체 100중량%에 대하여 0.5 내지 20중량%, 바람직하게는 1 내지 15 중량%, 보다 바람직하게는 2 내지 10중량%로 포함될 수 있다. 상기 산란입자가 상기 범위 내로 포함될 경우 발광 세기 증가 효과가 극대화될 수 있어 바람직하다. 상기 산란입자가 상기 범위 미만으로 포함될 경우 얻고자 하는 발광 세기의 확보가 다소 어려울 수 있고, 상기 범위를 초과할 경우 청색 조사광의 투과도가 현저히 저하되어 발광입자의 광변환이 작용하지 않는 문제가 있으므로, 상기 범위 내에서 적절하게 사용하는 것이 바람직하다.The scattering particles may be included in an amount of 0.5 to 20% by weight, preferably 1 to 15% by weight, and more preferably 2 to 10% by weight, based on 100% by weight of the total solid content of the light conversion ink composition. When the scattering particles are included within the above range, it is preferable that the effect of increasing the luminous intensity can be maximized. If the scattering particles are contained within the above range, it may be difficult to obtain the desired luminous intensity, and if the scattering particles exceed the above range, the transmittance of blue irradiation light is significantly reduced, so that the light conversion of the light emitting particles does not work. It is preferable to use it suitably within the said range.
광중합 개시제photopolymerization initiator
본 발명의 일 실시예에 따른 광변환 잉크 조성물은 광중합 개시제를 추가로 포함할 수 있다.The light conversion ink composition according to an embodiment of the present invention may further include a photopolymerization initiator.
본 발명의 일 실시예에서, 상기 광중합 개시제는 상기 중합성 모노머를 중합시킬 수 있는 것이라면 그 종류를 특별히 제한하지 않고 사용할 수 있다. 예를 들면, 상기 광중합 개시제는 중합특성, 개시효율, 흡수파장, 입수성, 가격 등의 관점에서 아세토페논계 화합물, 벤조페논계 화합물, 트리아진계 화합물, 비이미다졸계 화합물, 옥심계 화합물, 티오크산톤계 화합물, 및 포스핀 옥사이드 화합물로 이루어지는 군으로부터 선택되는 1종 이상의 화합물을 사용하는 것이 바람직하다.In one embodiment of the present invention, as long as the photopolymerization initiator can polymerize the polymerizable monomer, its kind may be used without particular limitation. For example, the photopolymerization initiator is an acetophenone-based compound, a benzophenone-based compound, a triazine-based compound, a biimidazole-based compound, an oxime-based compound, a tea in terms of polymerization characteristics, initiation efficiency, absorption wavelength, availability, price, etc. It is preferable to use at least one compound selected from the group consisting of oxanthone-based compounds and phosphine oxide compounds.
예를 들면, 5㎛이상의 후막경화를 위해서는 옥심계 화합물 또는 포스핀옥사이드 화합물을 사용하는 것이 경화막의 경화밀도 및 표면조도에 더욱 우수한 물성을 확보 할 수 있다.For example, for curing a thick film of 5 μm or more, using an oxime-based compound or a phosphine oxide compound can secure better physical properties in terms of cured density and surface roughness of a cured film.
상기 옥심계 화합물의 구체적인 예로는 o-에톡시카르보닐-α-옥시이미노-1-페닐프로판-1-온등을 들 수 있으며, 시판품으로 바스프사의 Irgacure OXE 01, OXE 02가 대표적이다.Specific examples of the oxime-based compound include o-ethoxycarbonyl-α-oxyimino-1-phenylpropan-1-one, and Irgacure OXE 01 and OXE 02 commercially available from BASF are representative.
상기 포스핀 옥사이드화합물로의 구체적인 예로는 트리메틸벤조일페닐포스핀옥사이드인 바스프사 Darocur TPO, Lucirin TPO가 대표적이다.Specific examples of the phosphine oxide compound include Darocur TPO and Lucirin TPO from BASF, which are trimethylbenzoylphenylphosphine oxide.
상기 광중합 개시제는 상기 광변환 잉크 조성물 고형분 전체 100 중량%에 대하여 0.1 내지 10 중량%, 바람직하게는 0.5 내지 8 중량%로 포함될 수 있다. 상기 광중합 개시제가 상기 범위 내로 포함되는 경우 상기 광변환 잉크 조성물이 고감도화되어 노광 시간이 단축되므로 생산성이 향상할 수 있기 때문에 바람직하다. 광중합 개시제가 상기 범위 미만으로 포함될 경우 광에의한 경화가 부족하여 충분한 경도를 얻을 수 없으며, 상기 범위를 초과하여 포함 될 경우 광중합 개시제에 의한 발광입자의 광변환 효율저하가 급격히 증가하여 얻고자 하는 발광세기를 얻을 수 없는 문제가 있으므로, 상기 범위 내에서 사용하는 것이 화소부의 강도와 상기 화소부의 표면에서의 평활성이 양호해지는 이점이 있다.The photopolymerization initiator may be included in an amount of 0.1 to 10% by weight, preferably 0.5 to 8% by weight, based on 100% by weight of the total solid content of the light conversion ink composition. When the photopolymerization initiator is included within the above range, the photoconversion ink composition is highly sensitive and the exposure time is shortened, which is preferable because productivity can be improved. When the photopolymerization initiator is included within the above range, sufficient hardness cannot be obtained due to insufficient curing by light, and when the photopolymerization initiator is included in the above range, the decrease in light conversion efficiency of the light emitting particles due to the photopolymerization initiator increases rapidly. Since there is a problem of not being able to obtain the luminous intensity, there is an advantage in that the strength of the pixel portion and the smoothness of the surface of the pixel portion are improved when used within the above range.
상기 광중합 개시제는 본 발명에 따른 광변환 잉크 조성물의 감도를 향상시키기 위해서, 광중합 개시 보조제를 더 포함할 수 있다. 상기 광중합 개시 보조제가 포함되는 경우 감도가 더욱 높아져 생산성이 향상되는 이점이 있다.The photopolymerization initiator may further include a photopolymerization initiator to improve the sensitivity of the light conversion ink composition according to the present invention. When the photopolymerization initiation aid is included, there is an advantage in that the sensitivity is further increased and the productivity is improved.
상기 광중합 개시 보조제는 예컨대, 아민 화합물, 카르복시산 화합물, 티올기를 가지는 유기 황화합물로 이루어진 군으로부터 선택되는 1종 이상의 화합물이 바람직하게 사용될 수 있으나 이에 한정되지 않는다. The photopolymerization initiation aid may be, for example, one or more compounds selected from the group consisting of amine compounds, carboxylic acid compounds, and organic sulfur compounds having a thiol group, but is not limited thereto.
상기 광중합 개시 보조제는 본 발명의 효과를 해치지 않는 범위에서 적절히 추가하여 사용할 수 있다.The photopolymerization initiation auxiliary agent may be appropriately added and used within a range that does not impair the effects of the present invention.
첨가제additive
본 발명의 일 실시형태에 따른 광변환 잉크 조성물은 상기한 성분들 이외에, 도막 평탄성 또는 밀착성을 증진시키기 위해서 계면활성제, 밀착촉진제와 같은 첨가제를 추가로 포함할 수 있다.In addition to the above components, the light conversion ink composition according to an embodiment of the present invention may further include additives such as a surfactant and an adhesion promoter in order to improve flatness or adhesion of a coating film.
본 발명에 따른 광변환 잉크 조성물이 상기 계면활성제를 포함하는 경우 도막 평탄성이 향상될 수 있는 이점이 있다. 예컨대 상기 계면활성제는 BM-1000, BM-1100(BM Chemie사), 프로라이드 FC-135/FC-170C/FC-430(스미토모 쓰리엠㈜), SH-28PA/-190/-8400/SZ-6032(도레 시리콘㈜) 등의 불소계 계면 활성제를 사용할 수 있으나, 이에 한정되지는 않는다. When the light conversion ink composition according to the present invention includes the surfactant, there is an advantage in that coating film flatness can be improved. For example, the surfactant is BM-1000, BM-1100 (BM Chemie), Proride FC-135/FC-170C/FC-430 (Sumitomo 3M Co.), SH-28PA/-190/-8400/SZ-6032 (Tore Silicon Co., Ltd.), but it is possible to use a fluorine-based surfactant, but is not limited thereto.
상기 밀착촉진제는 기판과의 밀착성을 높이기 위하여 첨가될 수 있는 것으로서 카르복실기, 메타크릴로일기, 이 소시아네이트기, 에폭시기 및 이들의 조합으로 이루어진 군에서 선택되는 반응성 치환기를 갖는 실란 커플링제를 포함할 수 있으나 이에 한정되는 것은 아니다.The adhesion promoter may be added to increase adhesion with a substrate, and may include a silane coupling agent having a reactive substituent selected from the group consisting of a carboxyl group, a methacryloyl group, an isocyanate group, an epoxy group, and combinations thereof. However, it is not limited thereto.
이 외에도 본 발명에 따른 광변환 잉크 조성물은 본 발명의 효과를 저해하지 않는 범위에서 산화 방지제, 자외선 흡수제, 응집 방지제와 같은 첨가제를 더 포함할 수도 있으며, 상기 첨가제는 역시 본 발명의 효과를 저해하지 않는 범위에서 당업자가 적절히 추가하여 사용이 가능하다.In addition, the light conversion ink composition according to the present invention may further include additives such as antioxidants, ultraviolet absorbers, and anti-agglomeration agents within a range that does not impair the effects of the present invention, and the additives also do not impair the effects of the present invention. It is possible for those skilled in the art to appropriately add and use it within the range.
상기산화방지제는 페놀계 화합물, 인계 화합물 및 황계 화합물을 포함하는 산화 방지제 중 적어도 1종 이상을 포함할 수 있다. The antioxidant may include at least one of antioxidants including a phenol-based compound, a phosphorus-based compound, and a sulfur-based compound.
용제solvent
본 발명의 일 실시예에 따른 광 변환 잉크 조성물은 용제를 더 포함할 수 있으며, 용제를 포함하지 않는 무용제 형일 수 있다. 본 발명의 광변환 잉크 조성물이 용제를 포함하는 경우, 예를 들면, 광변환 잉크 조성물 전체 100 중량%에 대하여 20 중량% 이하의 양으로 용제를 더 포함할 수 있다.The light conversion ink composition according to an embodiment of the present invention may further include a solvent, and may be a solvent-free type that does not contain a solvent. When the light conversion ink composition of the present invention includes a solvent, for example, the solvent may be further included in an amount of 20% by weight or less based on 100% by weight of the entire light conversion ink composition.
바람직하게는, 본 발명의 일 실시예에 따른 광변환 잉크 조성물은 연속 공정성 면에서 용제를 포함하지 않는 무용제형일 수 있다. Preferably, the light conversion ink composition according to an embodiment of the present invention may be a solvent-free type that does not contain a solvent in terms of continuous processability.
본 발명의 광변환 조성물은 용제를 포함하지 않는 무용제형인 경우라도, 상술한 중합성 모노머를 포함함에 따라 발광입자의 광특성 및 분산성이 우수하고, 저점도 구현이 가능하여 잉크의 노즐 젯팅 특성이 우수하다.Even if the light conversion composition of the present invention is a non-solvent type that does not contain a solvent, as it contains the above-described polymerizable monomer, the light characteristics and dispersibility of the light emitting particles are excellent, and it is possible to implement low viscosity, so that the nozzle jetting property of the ink is improved. great.
상기 용제로는 에테르 또는 에스테르계 용제, 지방족 포화 탄화수소계 용제, 할로겐화 탄화수소계 용제, 방향족 탄화수소계 용제 등을 사용할 수 있으며, 예컨대 프로필렌글리콜메틸에테르아세테이트(PGMEA), 에틸렌 글리콜모노에틸 에테르 아세테이트, 에틸렌글리콜모노메틸에테르, 에틸렌글리콜모노에틸에테르, 에틸렌글리콜모노프로필에테르, 에틸렌글리콜모노부틸에테르 등의 에틸렌글리콜모노알킬에테르류, 디에틸렌글리콜디메틸에테르, 디에틸렌글리콜디에틸에테르, 디에틸렌글리콜디프로필에테르, 디에틸렌글리콜디부틸에테르 등의 디에틸렌글리콜디알킬에테르류, 메틸셀로솔브아세테이트, 에틸셀로솔브아세테이트 등의 에틸렌글리콜알킬에테르아세테이트류, 프로필렌글리콜모노프로필에테르아세테이트, 메톡시부틸아세테이트, 메톡시펜틸아세테이트 등의 알킬렌글리콜알킬에테르아세테이트류, 벤젠, 톨루엔, 크실렌, 메시틸렌 등의 방향족 탄화수소류, 메틸에틸케톤, 아세톤, 메틸아밀케톤, 메틸이소부틸케톤, 시클로헥사논 등의 케톤류, 에탄올, 프로판올, 부탄올, 헥산올, 시클로헥산올, 에틸렌글리콜, 글리세린 등의 알코올류, 3-에톡시프로피온산에틸, 3-메톡시프로피온산메틸 등의 에스테르류, γ-부티로락톤 등의 환상 에스테르류 등을 사용할 수 있다.As the solvent, ether or ester-based solvents, aliphatic saturated hydrocarbon-based solvents, halogenated hydrocarbon-based solvents, aromatic hydrocarbon-based solvents, etc. may be used, for example, propylene glycol methyl ether acetate (PGMEA), ethylene glycol monoethyl ether acetate, ethylene glycol ethylene glycol monoalkyl ethers such as monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol monopropyl ether, and ethylene glycol monobutyl ether, diethylene glycol dimethyl ether, diethylene glycol diethyl ether, diethylene glycol dipropyl ether, Diethylene glycol dialkyl ethers such as diethylene glycol dibutyl ether, ethylene glycol alkyl ether acetates such as methyl cellosolve acetate and ethyl cellosolve acetate, propylene glycol monopropyl ether acetate, methoxybutyl acetate, methoxy Alkylene glycol alkyl ether acetates such as pentyl acetate, aromatic hydrocarbons such as benzene, toluene, xylene and mesitylene, ketones such as methyl ethyl ketone, acetone, methyl amyl ketone, methyl isobutyl ketone and cyclohexanone, ethanol, alcohols such as propanol, butanol, hexanol, cyclohexanol, ethylene glycol, and glycerin; esters such as 3-ethoxyethylpropionate and 3-methoxymethylpropionate; and cyclic esters such as γ-butyrolactone. can be used
< 광변환 적층기판, 백라이트 유닛 및 화상표시장치><Light conversion laminated board, backlight unit and image display device>
본 발명의 일 실시형태는 발광 소자가 방출하는 광을 흡수하여 청색 또는 녹색 또는 적색으로 변환하여 방출하는 광변환 적층기판으로서, 상기 광변환 적층기판은 상술한 광변환 잉크 조성물을 이용하여 형성된다.One embodiment of the present invention is a light conversion laminated board that absorbs light emitted from a light emitting device and converts it to blue, green, or red light, and emits the light, wherein the light conversion laminated board is formed using the above-described photoconversion ink composition.
또한, 본 발명은 상술한 광변환 잉크 조성물을 이용하여 제조된, 레드(RED), 그린(GREEN) 및 블루(BLUE)의 컬러필터 기능을 하는 광변환 화소기판을 제공할 수 있다.In addition, the present invention may provide a photoconversion pixel substrate manufactured using the above-described photoconversion ink composition and functioning as a color filter of RED, GREEN, and BLUE.
상기 광변환 적층기판 및/또는 광변환 화소기판은 상술한 광변환 잉크 조성물을 잉크젯 방식으로 소정영역에 도포하고, 상기 도포된 광변환 잉크 조성물을 경화시켜 형성될 수 있다.The photo-conversion laminated substrate and/or the photo-conversion pixel substrate may be formed by applying the above-described photo-conversion ink composition to a predetermined area using an inkjet method and curing the applied photo-conversion ink composition.
상기 기재로는 유리 기판, 실리콘 기판, 폴리카보네이트 기판, 폴리에스테르 기판, 방향족 폴리아미드 기판, 폴리아미드이미드 기판, 폴리이미드 기판, Al 기판, GaAs 기판 등의 표면이 평탄한 기판을 들 수 있으나, 이에 제한되는 것은 아니다. 이들 기판은 실란 커플링제 등의 약품에 의한 약품 처리, 플라스마 처리, 이온 플레이팅 처리, 스퍼터링 처리, 기상반응 처리, 진공증착 처리 등의 전처리를 실시할 수 있다. 기판으로서 실리콘 기판 등을 사용하는 경우, 실리콘 기판 등의 표면에는 전하 결합소자(CCD), 박막 트랜지스터(TFT) 등이 형성될 수 있다. 또한, 격벽 매트릭스가 형성되어 있을 수도 있다. 상기 경화는 열경화 조건으로 수행할 수 있다.The substrate may include a substrate with a flat surface such as a glass substrate, a silicon substrate, a polycarbonate substrate, a polyester substrate, an aromatic polyamide substrate, a polyamideimide substrate, a polyimide substrate, an Al substrate, and a GaAs substrate, but is limited thereto. it is not going to be These substrates can be subjected to pretreatment such as chemical treatment with a chemical such as a silane coupling agent, plasma treatment, ion plating treatment, sputtering treatment, vapor phase reaction treatment, and vacuum deposition treatment. When a silicon substrate or the like is used as the substrate, a charge coupled device (CCD), a thin film transistor (TFT), or the like may be formed on a surface of the silicon substrate or the like. Also, a barrier rib matrix may be formed. The curing may be performed under thermal curing conditions.
예컨대, 상기 경화는 100 내지 250℃, 바람직하게는 150 내지 230℃에서, 5분 내지 30분, 바람직하게는 10분 동안 수행할 수 있다.For example, the curing may be performed at 100 to 250°C, preferably 150 to 230°C, for 5 to 30 minutes, preferably 10 minutes.
잉크젯 분사기의 일례인 피에조 잉크젯 헤드에서 분사되어 기판 위에서 적절한 상(phase)을 형성하기 위하여, 점도, 유동성, 양자점 입자 등의 특성이 잉크젯 헤드와 균형 있게 맞춰져야 한다. 본 발명에서 사용된 피에조 잉크젯 헤드는 제한되지 않으나, 약 3 내지 100pL, 바람직하게는 약 5 내지 40pL의 액적 크기를 가지는 잉크를 분사한다.In order to be ejected from a piezo inkjet head, which is an example of an inkjet injector, to form an appropriate phase on a substrate, properties such as viscosity, fluidity, and quantum dot particles must be balanced with the inkjet head. The piezo inkjet head used in the present invention is not limited, but ejects ink having a droplet size of about 3 to 100 pL, preferably about 5 to 40 pL.
본 발명의 광변환 잉크 조성물의 점도는 약 3 내지 50cP가 적당하며, 보다 바람직하게는 7 내지 40cP의 범위에서 조절된다.The viscosity of the light conversion ink composition of the present invention is suitably about 3 to 50 cP, more preferably adjusted in the range of 7 to 40 cP.
본 발명에 따른 광변환 적층기판은 청색 광원에 적용되는 경우 뛰어난 광출력을 나타낼 수 있다.The light conversion laminated substrate according to the present invention can exhibit excellent light output when applied to a blue light source.
본 발명의 일 실시예는, 녹색 광을 발광시키는 녹색 발광 소자로서, 구체적으로 500∼600㎚ 파장의 녹색 광을 방출하는 것일 수 있으나, 이에 제한되는 것은 아니다.An embodiment of the present invention is a green light emitting device that emits green light, and may specifically emit green light having a wavelength of 500 to 600 nm, but is not limited thereto.
상기 녹색 발광 소자는 녹색 발광 다이오드(LED)일 수 있다.The green light emitting device may be a green light emitting diode (LED).
본 발명의 일 실시형태는 상기 청색 광원에 적용된 광변환 적층기판을 포함하는 것을 특징으로 하는 백라이트 유닛에 관한 것이다. One embodiment of the present invention relates to a backlight unit comprising a light conversion laminated substrate applied to the blue light source.
상기 백라이트 유닛은 도광판, 반사판 등의 통상적으로 포함되는 구성을 추가로 포함할 수 있다.The backlight unit may further include commonly included components such as a light guide plate and a reflector.
본 발명의 일 실시형태는 상기 백라이트 유닛을 포함하는 화상표시장치에 관한 것이다.One embodiment of the present invention relates to an image display device including the backlight unit.
본 발명의 화상표시장치는 통상의 액정 표시 장치뿐만 아니라, 전계 발광 표시 장치, 플라스마 표시 장치, 전계방출 표시 장치 등 각종 화상표시장치를 포함한다.The image display device of the present invention includes not only a conventional liquid crystal display device, but also various image display devices such as an electroluminescence display device, a plasma display device, and a field emission display device.
또한, 본 발명의 일 실시형태는, 상술한 광변환 잉크 조성물의 경화물을 포함하는 광변환 화소에 관한 것이다.In addition, one embodiment of the present invention relates to a photoconversion pixel including a cured product of the photoconversion ink composition described above.
예를 들면, 상술한 광변환 잉크 조성물을 잉크젯 방식으로 소정영역에 도포하는 단계 및 상기 도포된 광변환 잉크 조성물을 경화시키는 단계를 포함하여, 광변환 잉크 조성물의 패턴을 형성함으로써 광변환 화소를 제조할 수 있다.For example, manufacturing a photo-conversion pixel by forming a pattern of the photo-conversion ink composition, including applying the above-described photo-conversion ink composition to a predetermined area by an inkjet method and curing the applied photo-conversion ink composition. can do.
이하, 본 발명의 이해를 돕기 위하여 구체적인 실시예 및 비교예들을 포함하는 실험예를 제시하나, 이는 본 발명을 예시하는 것일 뿐 첨부된 특허청구범위를 제한하는 것이 아니며, 본 발명의 범주 및 기술사상 범위 내에서 실시예에 대한 다양한 변경 및 수정이 가능함은 당업자에게 있어서 명백한 것이며, 이러한 변형 및 수정이 첨부된 특허청구범위에 속하는 것도 당연한 것이다. 또한, 이하에서 함유량을 나타내는 “%” 및 “부”는 특별히 언급하지 않는 한 중량 기준이다.Hereinafter, experimental examples including specific examples and comparative examples are presented to aid understanding of the present invention, but these are only illustrative of the present invention and do not limit the scope of the appended claims, and the scope and technical spirit of the present invention It is obvious to those skilled in the art that various changes and modifications to the embodiments are possible within the scope, and it is natural that these changes and modifications fall within the scope of the appended claims. In addition, "%" and "part" which represent content below are based on weight unless otherwise indicated.
합성예synthesis example
A-1의 제조예: AgInGaS/GaS 코어-쉘 발광입자 합성 및 분산액 제조Preparation Example of A-1: Synthesis of AgInGaS/GaS core-shell light-emitting particles and preparation of dispersion
0.0625mmol의 요오드화 은(AgI, 99.999%), 1.25mmol의 갈륨아세틸아세토네이트(Ga(acac)3, 99.99%) 및 1mmol의 황(99.998%)을 1-도데칸티올(DDT≥98%) 1.5mL 및 올레일아민(OLA, 70%) 5mL와 함께 플라스크(three-neck flask)에 넣어 혼합 용액을 제조하고, 혼합 용액을 120℃로 가열해 디가스한 후 N2 퍼징을 하며 성장 온도인 240℃까지 승온하였다. 이 온도에서 30분간 유지하여 AGS 코어 QD를 성장시켰다. 이 AGS 코어 용액에 0.01mmol의 인듐아세테이트(In(Ac)3, 99.99%)를 추가하였다. 혼합 용액을 120℃로 가열해 디가스한 후 N2 퍼징을 하며 성장 온도인 240℃까지 승온하였다. 이 온도에서 10분간 유지하여 AIGS 코어 QD를 성장시켰다.0.0625 mmol silver iodide (AgI, 99.999%), 1.25 mmol gallium acetylacetonate (Ga(acac)3, 99.99%) and 1 mmol sulfur (99.998%) were mixed with 1-dodecanethiol (DDT≥98%) 1.5 mL and oleylamine (OLA, 70%) in a flask (three-neck flask) to prepare a mixed solution, heat the mixed solution to 120 ° C to degas, and then N2 purging to grow at 240 ° C, the growth temperature. was heated up to It was maintained at this temperature for 30 minutes to grow AGS core QDs. 0.01 mmol of indium acetate (In(Ac) 3 , 99.99%) was added to the AGS core solution. After degassing the mixed solution by heating it to 120 ° C, the temperature was raised to 240 ° C, the growth temperature, while purging with N2. It was maintained at this temperature for 10 minutes to grow AIGS core QDs.
상기 AIGS 코어 QD를 7ml 올레일 아민, 0.1mmol 갈륨 아세틸아세토네이트(Ga(acac)3, 99.99%), 0.1mmol의 1,3-dimethyl-thiourea 와 함께 혼합하고, 빠르게 230℃까지 승온하였다. 그리고 inert 조건에서 1분당 2℃씩 증가시켜 280℃까지 승온하였다. 용액을 다시 상온으로 냉각시키고, 30분간 반응에 참여하지 않은 황 화합물들을 degas하여 제거한다. 양자점은 에탄올에 침전 시켜 원심분리하여 정제한 후 감압건조를 실시하여 AgInGaS/GaS 양자점 파우더를 수득하였다. 수득된 양자점 파우더를 1,6-헥산디올 디아크릴레이트와 1 : 1 비율로 혼합하여 AgInGaS/GaS 분산액을 제조하였다. The AIGS core QD was mixed with 7ml oleylamine, 0.1mmol gallium acetylacetonate (Ga(acac)3, 99.99%), and 0.1mmol 1,3-dimethyl-thiourea, and rapidly heated to 230°C. And the temperature was raised to 280℃ by increasing 2℃ per minute under inert condition. The solution was cooled to room temperature again, and sulfur compounds not participating in the reaction were removed by degas for 30 minutes. Quantum dots were precipitated in ethanol, purified by centrifugation, and dried under reduced pressure to obtain AgInGaS/GaS quantum dot powder. The obtained quantum dot powder was mixed with 1,6-hexanediol diacrylate in a ratio of 1:1 to prepare an AgInGaS/GaS dispersion.
실시예, 비교예 및 참조예: 광변환 잉크 조성물의 제조Examples, Comparative Examples and Reference Examples: Preparation of Light Conversion Ink Compositions
하기 표 1의 조성으로 각각의 성분들을 혼합하여, 실시예, 비교예 및 참조예의 광변환 잉크 조성물을 제조하였다 (단위: 중량%).The light conversion ink compositions of Examples, Comparative Examples, and Reference Examples were prepared by mixing the respective components according to the composition shown in Table 1 below (Unit: % by weight).
모노머 polymeric
monomer
(A-1)QD dispersion
(A-1)
모노머 polymeric
monomer
-A-1: AgInGaS/GaS QD 분산액-A-1: AgInGaS/GaS QD dispersion
-B-1: 1,6-헥산디올 디아크릴레이트(신나카무라가가쿠 사)-B-1: 1,6-hexanediol diacrylate (Shin Nakamura Chemical Co., Ltd.)
-B-2: 폴리에틸렌글리콜디아크릴레이트 (신나카무라가가쿠 사)-B-2: Polyethylene glycol diacrylate (Shin Nakamura Chemical Co., Ltd.)
-C: TiO2 (훈츠만사, TR-88, 입경 220nm)-C: TiO 2 (Huntsman, TR-88, particle size 220 nm)
-D: Diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide (알드리치 사)-D: Diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide (Aldrich)
-E-1: SH8400(다우코닝 도레이 실리콘사) -E-1: SH8400 (Dow Corning Toray Silicon Co.)
-E-2: 화학식 1-1의 화합물-E-2: Compound of formula 1-1
-E-3: 화학식 1-2의 화합물-E-3: Compound of formula 1-2
-E-4: 화학식 1-3의 화합물-E-4: Compound of Formula 1-3
-E-5: 화학식 1-4의 화합물-E-5: a compound of Formula 1-4
-E-6: 화학식 1-5의 화합물-E-6: a compound of formula 1-5
-E-7: 화학식 1-6의 화합물-E-7: a compound of formula 1-6
-E-8: 화학식 1-7의 화합물-E-8: compound of formula 1-7
-E-9: 화학식 1-8의 화합물-E-9: a compound of formula 1-8
-E-10: 화학식 1-9의 화합물-E-10: a compound of formula 1-9
-E-11: 화학식 1-10의 화합물-E-11: a compound of formula 1-10
-E-12: 화학식 2-1의 화합물-E-12: compound of formula 2-1
-E-13: 화학식 2-2의 화합물-E-13: the compound of formula 2-2
-E-14: 화학식 2-3의 화합물-E-14: compound of formula 2-3
-E-15: 화학식 3-1의 화합물-E-15: compound of formula 3-1
-E-16: 화학식 3-2의 화합물-E-16: compound of formula 3-2
-E-17: 화학식 3-3의 화합물-E-17: compound of formula 3-3
-E-18: 화학식 4-1의 화합물-E-18: the compound of formula 4-1
- E-19: 1,8-Diaminooctane(TCI사)- E-19: 1,8-Diaminooctane (TCI)
- E-20: Polyethyleneimine, branched, M.W. 1,800 (Alfa aesar사)- E-20: Polyethyleneimine, branched, M.W. 1,800 (Alfa aesar)
-F-1: Sumilizer-GP (스미토모화학 사)-F-1: Sumilizer-GP (Sumitomo Chemical Co.)
실험예Experimental example
1. 광변환 코팅층의 제조 및 광변환 효율 측정1. Preparation of light conversion coating layer and measurement of light conversion efficiency
실시예 및 비교예에서 제조된 각각의 광변환 잉크 조성물을 잉크젯 방식으로 5cm×5cm 유리 기판 위에 도포한 다음, 질소 조건 하에서 395nm Blue LED등을 사용하여 4000mJ/cm2로 조사 후, 질소 조건 하에서 핫플레이트 위에 180℃, 30분 동안 가열하여 광변환 코팅층을 제조하였다.Each light conversion ink composition prepared in Examples and Comparative Examples was applied on a 5cm×5cm glass substrate by an inkjet method, and then irradiated at 4000mJ/cm 2 using a 395nm Blue LED under nitrogen conditions, followed by hot under nitrogen conditions. A light conversion coating layer was prepared by heating on the plate at 180° C. for 30 minutes.
제조된 광변환 코팅층을 청색(blue) 광원(XLamp XR-E LED, Royal blue 450, Cree 社) 상부에 위치시킨 후 휘도 측정기(CAS140CT Spectrometer, Instrument systems 社)를 이용하여 광변환 효율을 하기의 식을 이용하여 측정하였다. 측정된 결과를 하기 표 3에 기재하였다. After placing the prepared light conversion coating layer on top of a blue light source (XLamp XR-E LED, Royal blue 450, Cree Co.), the light conversion efficiency was calculated using the following equation using a luminance meter (CAS140CT Spectrometer, Instrument Systems Co.) was measured using The measured results are listed in Table 3 below.
2. 청색광(Blue) 흡광도 변화 2. Blue light absorbance change
10ml 메스실린더에 상기 제조된 광변환 잉크 조성물을 5ml 투입하고, 상온에서 하루 방치 후, 중앙부의 잉크 조성물을 채취하여 상기 평가와 같이 광변환 코팅층을 제조한다. 방치하기 전과 방치한 후의 동일 10㎛에서의 광변환 코팅층의 청색광(Blue) 흡광도 변화율을 비교하였다. TiO2의 침강이 많이 진행될수록 청색광(Blue) 흡광도가 감소되고 보관 안정성에 문제가 발생되었다고 판단할 수 있다. 5 ml of the light conversion ink composition prepared above was put into a 10 ml measuring cylinder, left at room temperature for one day, and then the ink composition in the center was collected to prepare a light conversion coating layer as described above. The blue light absorbance change rate of the light conversion coating layer at the same 10 μm before and after leaving was compared. It can be determined that as the precipitation of TiO 2 increases, the absorbance of blue light decreases and a problem occurs in storage stability.
다음 기준으로, 청색광(Blue) 흡광도 변화율을 측정하여 그 결과를 표 3에 나타내었다. Based on the following criteria, the blue light absorbance change rate was measured and the results are shown in Table 3.
< 기준 ><Standard>
○ : 흡광도 0% 이상 3% 미만○: Absorbance 0% or more and less than 3%
△ : 흡광도 변화 3% 이상 5% 미만△: Absorbance change 3% or more and less than 5%
Ｘ : 흡광도 변화 5% 이상X: Absorbance change of 5% or more
3. 잉크젯 Drop size 변화확인3. Check inkjet drop size change
가로 30㎛, 세로 90㎛, 깊이 10㎛의 우물형패턴이 형성된 기재에 유니젯사 잉크젯장비를 이용하여 20pL의 액적을 5분간 적하시킨 후, 1시간 방치 후 다시 액적을 적하시켰을 때의 Drop size 변화 유무를 확인하였다. Drop size의 변화가 발생되면, 패턴안에 잉크가 제대로 채워지지 않거나, 막두께가 변하는 문제가 발생할 수 있다. Change in drop size when a droplet of 20 pL is dropped on a substrate with a well-shaped pattern of 30 μm in width, 90 μm in length, and 10 μm in depth for 5 minutes using Unijet’s inkjet equipment, and then left for 1 hour and then dropped again. The presence or absence was confirmed. If the drop size changes, ink may not be properly filled in the pattern or the film thickness may change.
다음 기준으로, Drop size 변화를 측정하여 그 결과를 표 3에 나타내었다. Based on the following criteria, the drop size change was measured and the results are shown in Table 3.
< 기준 ><Standard>
○ : Drop size 0pL 이상 1pL미만 ○ : Drop size 0pL or more and less than 1pL
△ : Drop size 1pL 이상 2pL미만△: Drop size 1pL or more and less than 2pL
Ｘ : Drop size 2pL 이상X : Drop size 2pL or more
상기 실험결과를 통해, 화학식 I의 구조에 해당하는 아민 첨가제를 포함하는 실시예의 조성물은, 이를 포함하지 않는 비교예에 비해 광변환 효율이 향상되고, 청색광(Blue)에 대한 흡광도 및 드롭 사이즈(Drop size)의 변화가 적은 것을 확인할 수 있었다. Through the above experimental results, the composition of the example containing the amine additive corresponding to the structure of Formula I has improved light conversion efficiency compared to the comparative example without it, and the absorbance and drop size for blue light (Drop size) was found to be small.
또한, 화학식 I의 구조에 해당하는 아민 첨가제를 광변환 잉크 조성물 고형분 전체 100 중량%에 대하여 0.01 내지 10 중량%의 범위로 포함하는, 실시예의 조성물이, 이를 벗어나는 범위로 포함하는 참고예보다 우수한 효과를 나타냄을 확인할 수 있었다. In addition, the composition of the example, which includes the amine additive corresponding to the structure of Formula I in the range of 0.01 to 10% by weight based on 100% by weight of the total solid content of the light conversion ink composition, is superior to the reference example including the outside range. It was confirmed that it represents
Claims (16)
상기 아민계 첨가제는 하기 화학식 I을 포함하는, 광변환 잉크 조성물.
[화학식 I]
(상기 화학식 I에서,
Ra, Rb 및 Rc는, 각각 독립적으로, 수소, 치환 또는 비치환된 탄소 수 1 내지 5의 알킬기, 또는 2개 이상의 질소원자를 포함하는 탄소 수 2 내지 50의 탄화수소기이다.)
Including light emitting particles, polymerizable monomers and amine-based additives,
The amine-based additive comprises the formula (I), the light conversion ink composition.
[Formula I]
(In the above formula I,
R a , R b and R c are each independently hydrogen, a substituted or unsubstituted alkyl group having 1 to 5 carbon atoms, or a hydrocarbon group having 2 to 50 carbon atoms containing two or more nitrogen atoms.)
상기 화학식 I는, 하기 화학식 1 내지 4로 나타내는 화합물 중 적어도 하나 이상의 화합물을 포함하는, 광변환 잉크 조성물.
[화학식 1]
(상기 화학식 1에서,
R1, R2, R4, R6 및 R7은 각각 독립적으로, 수소 또는 치환 또는 비치환된 탄소 수 1 내지 5의 알킬기이며,
R3 및 R5는 각각 독립적으로, 치환 또는 비치환된 탄소 수 1 내지 5의 알킬렌기이다.)
[화학식 2]
(상기 화학식 2에서,
R8, R9, R11, R13, R15 및 R16은 각각 독립적으로, 수소 또는 치환 또는 비치환된 탄소 수 1 내지 5의 알킬기이며,
R10, R12 및 R14는 각각 독립적으로, 치환 또는 비치환된 탄소 수 1 내지 5의 알킬렌기이다.)
[화학식 3]
(상기 화학식 3에서,
R17, R18, R21, R22, R24 및 R25는 각각 독립적으로, 수소 또는 치환 또는 비치환된 탄소 수 1 내지 5의 알킬기이며,
R19, R20 및 R23은 각각 독립적으로, 치환 또는 비치환된 탄소 수 1 내지 5의 알킬렌기이다.)
[화학식 4]
(상기 화학식 4에서,
R17, R18, R20, R22, R24, R26 및 R27은 각각 독립적으로, 수소 또는 치환 또는 비치환된 탄소 수 1 내지 5의 알킬기이며,
R19, R21, R23 및 R25는 각각 독립적으로, 치환 또는 비치환된 탄소 수 1 내지 5의 알킬렌기이다.)
The method of claim 1,
Formula I is a light conversion ink composition comprising at least one compound among the compounds represented by the following Formulas 1 to 4.
[Formula 1]
(In Formula 1 above,
R 1 , R 2 , R 4 , R 6 and R 7 are each independently hydrogen or a substituted or unsubstituted alkyl group having 1 to 5 carbon atoms;
R 3 and R 5 are each independently a substituted or unsubstituted alkylene group having 1 to 5 carbon atoms.)
[Formula 2]
(In Formula 2 above,
R 8 , R 9 , R 11 , R 13 , R 15 and R 16 are each independently hydrogen or a substituted or unsubstituted alkyl group having 1 to 5 carbon atoms;
R 10 , R 12 and R 14 are each independently a substituted or unsubstituted alkylene group having 1 to 5 carbon atoms.)
[Formula 3]
(In Formula 3,
R 17 , R 18 , R 21 , R 22 , R 24 and R 25 are each independently hydrogen or a substituted or unsubstituted alkyl group having 1 to 5 carbon atoms;
R 19 , R 20 and R 23 are each independently a substituted or unsubstituted alkylene group having 1 to 5 carbon atoms.)
[Formula 4]
(In Chemical Formula 4,
R 17 , R 18 , R 20 , R 22 , R 24 , R 26 and R 27 are each independently hydrogen or a substituted or unsubstituted alkyl group having 1 to 5 carbon atoms;
R 19 , R 21 , R 23 and R 25 are each independently a substituted or unsubstituted alkylene group having 1 to 5 carbon atoms.)
상기 화학식 I로 나타내는 화합물은, 광변환 잉크 조성물 고형분 전체 100 중량%에 대하여 0.01 내지 10 중량%으로 포함되는, 광변환 잉크 조성물.
The method of claim 1,
The compound represented by Formula I is included in 0.01 to 10% by weight based on 100% by weight of the total solid content of the light conversion ink composition, the light conversion ink composition.
[화학식 5]
(상기 화학식 5에서,
R28는 탄소 수 1 내지 20의 알킬렌기, 페닐렌기 또는 탄소 수 3 내지 10의 사이클로알킬렌기이며,
R29는, 각각 독립적으로, 수소 또는 메틸기이고,
m은 1 내지 15의 정수이다.)
The light conversion ink composition of claim 1, wherein the polymerizable monomer comprises a compound represented by Formula 5 below.
[Formula 5]
(In Formula 5,
R 28 is an alkylene group having 1 to 20 carbon atoms, a phenylene group, or a cycloalkylene group having 3 to 10 carbon atoms;
R 29 is each independently hydrogen or a methyl group;
m is an integer from 1 to 15.)
The light conversion ink composition of claim 4, wherein the polymerizable monomer further comprises a monofunctional or multifunctional monomer having three or more unsaturated double bonds.
The method according to claim 4, wherein the compound represented by Formula 5 is 1,6-hexanediol diacrylate, polyethylene glycol diacrylate, 2-hydroxy-3-methacrylpropyl acrylate, 1,9-bisacryloyloxy A light conversion ink composition comprising at least one selected from the group consisting of cinonan and tripropylene glycol diacrylate.
The light conversion ink composition according to claim 1, further comprising at least one selected from the group consisting of scattering particles, photopolymerization initiators, additives and solvents.
The method according to claim 7, wherein the scattering particles are Al 2 O 3 , SiO 2 , ZnO, ZrO 2 , BaTiO 3 , TiO 2 , Ta 2 O 5 , Ti 3 O 5 , ITO, IZO, ATO, ZnO-Al, Nb 2 A light conversion ink composition comprising at least one selected from the group consisting of O 3 , SnO and MgO.
The light conversion ink composition of claim 1 , further comprising an antioxidant.
The light conversion ink composition of claim 11, wherein the antioxidant includes at least one of antioxidants including a phenol-based compound, a phosphorus-based compound, and a sulfur-based compound.
The light conversion ink composition according to claim 1, which is a non-solvent type that does not contain a solvent.
A light conversion laminated substrate manufactured using the light conversion ink composition according to any one of claims 1 to 11.
A backlight unit comprising the light conversion laminated board according to claim 12 .
A photoconversion pixel substrate manufactured using the photoconversion ink composition according to any one of claims 1 to 11.
An image display device comprising the backlight unit of claim 13.
An image display device comprising the photo-conversion pixel substrate of claim 14.
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| TW111148360A TW202334334A (en) | 2022-01-21 | 2022-12-16 | A light conversion ink composition, a light converting laminating substrate, a light converting pixel, an image display apparatus unit and a backlight unit manufactured by using thereof |
| CN202310039568.3A CN116478574A (en) | 2022-01-21 | 2023-01-12 | Light-converting ink composition, light-converting laminated substrate produced using same, light-converting pixel substrate, and image display device |
| JP2023006656A JP2023107229A (en) | 2022-01-21 | 2023-01-19 | Photoconversion ink composition and photoconversion laminated substrate, photoconversion pixel substrate and image display device obtained using the same |
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| KR101475520B1 (en) | 2008-01-14 | 2014-12-23 | 삼성전자주식회사 | Quantum dot ink composition for inkjet printing and electronic device using the same |
| KR101628065B1 (en) | 2014-08-07 | 2016-06-08 | 주식회사 엘엠에스 | Luminescence complex, composition including the complex, hardened member of the composition, optical sheet, backlight unit, and display device |
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| KR101475520B1 (en) | 2008-01-14 | 2014-12-23 | 삼성전자주식회사 | Quantum dot ink composition for inkjet printing and electronic device using the same |
| KR101628065B1 (en) | 2014-08-07 | 2016-06-08 | 주식회사 엘엠에스 | Luminescence complex, composition including the complex, hardened member of the composition, optical sheet, backlight unit, and display device |
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