KR20200127569A - Process Of Producing Fabrics For Camouflage Patterned Combat Uniform Having Excellent Infrared Blocking Property - Google Patents

Process Of Producing Fabrics For Camouflage Patterned Combat Uniform Having Excellent Infrared Blocking Property Download PDF

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KR20200127569A
KR20200127569A KR1020190051964A KR20190051964A KR20200127569A KR 20200127569 A KR20200127569 A KR 20200127569A KR 1020190051964 A KR1020190051964 A KR 1020190051964A KR 20190051964 A KR20190051964 A KR 20190051964A KR 20200127569 A KR20200127569 A KR 20200127569A
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fabric
flame
manufacturing
fiber
camouflage pattern
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KR102179413B1 (en
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노현호
노현석
오상엽
신동우
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삼일방 (주)
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/22—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using vat dyestuffs including indigo
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B3/00—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
    • D06B3/10—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B7/00—Mercerising, e.g. lustring by mercerising
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06C—FINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
    • D06C3/00—Stretching, tentering or spreading textile fabrics; Producing elasticity in textile fabrics
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06C—FINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
    • D06C7/00—Heating or cooling textile fabrics
    • D06C7/02—Setting
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/13—Fugitive dyeing or stripping dyes
    • D06P5/138—Fugitive dyeing or stripping dyes fugitive dyeing
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/20—Physical treatments affecting dyeing, e.g. ultrasonic or electric
    • D06P5/2066—Thermic treatments of textile materials
    • D06P5/2077—Thermic treatments of textile materials after dyeing
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F41—WEAPONS
    • F41H—ARMOUR; ARMOURED TURRETS; ARMOURED OR ARMED VEHICLES; MEANS OF ATTACK OR DEFENCE, e.g. CAMOUFLAGE, IN GENERAL
    • F41H3/00—Camouflage, i.e. means or methods for concealment or disguise
    • F41H3/02—Flexible, e.g. fabric covers, e.g. screens, nets characterised by their material or structure
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00—Physical properties
    • D10B2401/22—Physical properties protective against sunlight or UV radiation
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2501/00—Wearing apparel
    • D10B2501/04—Outerwear; Protective garments
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2507/00—Sport; Military

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  • Textile Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Woven Fabrics (AREA)
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Abstract

The present invention relates to a military camouflage pattern combat clothing fabric. According to the present invention, provided is the military camouflage pattern combat clothing fabric having permanent flame retardancy and infrared shielding functionality, and formed with printed camouflage patterns.

Description

적외선 차단 기능이 우수한 난연 위장무늬전투복용 직물의 제조방법{Process Of Producing Fabrics For Camouflage Patterned Combat Uniform Having Excellent Infrared Blocking Property}Process Of Producing Fabrics For Camouflage Patterned Combat Uniform Having Excellent Infrared Blocking Property}

본 발명은 군용 위장무늬 전투복용 직물에 관한 것으로서 영구적인 난연성과 날염 위장무늬, 적외선 차폐 기능성이 있는 원단의 제조 방법에 관한 것이다.The present invention relates to a fabric for military camouflage pattern combat clothing, and relates to a method of manufacturing a fabric having permanent flame retardancy, printed camouflage pattern, and infrared shielding function.

일반적으로 영구적인 난연성을 부여하기 위해선 FR 섬유소재인 meta-Aramid, para-Aramid, FR-Rayon을 사용하지만 Aramid 섬유는 인장강도 및 인열강도는 높지만 날염 염색가공과 적외선차폐가공이 어려운 문제가 있다. FR-Rayon은 상대적으로 날염 염색이 용이하나, Rayon 자체로서는 강도가 낮아 군용 피복류로서는 부적합하다.In general, to impart permanent flame retardancy, FR fiber materials such as meta-Aramid, para-Aramid, and FR-Rayon are used, but aramid fiber has high tensile and tear strength, but printing dyeing and infrared shielding are difficult. . FR-Rayon is relatively easy to print and dye, but Rayon itself has low strength, making it unsuitable for military clothing.

따라서 대표적인 미군 난연 위장 전투복도 FR-Rayon을 기본적으로 두고, para-Aramid, Nylon 복합소재로 피복소재로 구성하여 위장 날염 기능과 군용 피복으로서의 강도는 부여하고 있으나, para-Aramid 소재로 인한 적외선 차폐 기능을 떨어지는 문제가 있다. Therefore, the representative U.S. military flame-retardant camouflage combat corridor is composed of a para-Aramid and nylon composite material as a cover material, giving the camouflage printing function and strength as military clothing, but the infrared shielding function due to the para-Aramid material. There is a problem with falling.

현재 대한민국 국군 난연 항공 피복 원단도 meta-Aramid와 FR-Rayon 복합소재로 구성되어, 이도 위장 날염 기능만 부여되고 적외선 차폐 기능은 부여할 수 없어 야간 위장에 큰 문제를 가지고 있다.Currently, the Korean Armed Forces' flame-retardant aviation cloth fabric is also composed of meta-Aramid and FR-Rayon composite material, and it has a big problem in camouflage at night because only the camouflage printing function is given to the ear canal and the infrared shield function cannot be provided.

대한민국특허등록제10-1616270호(2017년10월10일 공고)Korean Patent Registration No. 10-1616270 (announced on October 10, 2017)

그러므로 본 발명에서는 FR-Rayon, 고강도 폴리비닐알콜섬유로 복합방적사를 제조하고 이를 제직한 원단으로 이루어진 위장무늬 날염, 적외선 차폐작용을 부여하여 영구적인 난연성과 고강도 및 적외선 차폐 기능을 가진 난연 전투복용 직물을 제공하는 것을 기술적 과제로 한다.Therefore, in the present invention, a flame-retardant combat suit fabric with permanent flame retardancy, high strength, and infrared shielding function by providing a camouflage pattern printing and infrared shielding function made of a fabric made of FR-Rayon, high-strength polyvinyl alcohol fiber, and woven fabric. It is a technical task to provide

그러므로 본 발명에 의하면, FR-Rayon 섬유와 폴리비닐알콜섬유를 사용하여 혼합방적사를 만드는 단계;Therefore, according to the present invention, the steps of making a blended yarn using FR-Rayon fibers and polyvinyl alcohol fibers;

상기 혼합방적사로 직물을 제조하는 단계; 상기 직물로 전처리단계; 날염가공단계 및 열고정 단계를 행하는 것을 특징으로 하는 적외선 차단 기능이 우수한 난연 위장무늬전투복용 직물의 제조방법이 제공된다.Manufacturing a fabric with the blended yarn; Pretreatment step with the fabric; There is provided a method of manufacturing a flame-retardant camouflage pattern combat clothing fabric having excellent infrared blocking function, characterized in that the printing process step and the heat setting step are performed.

본 발명의 적외선 차단 기능이 우수한 난연 위장무늬전투복용 직물의 제조방법은 혼합방적사 제조단계; 직물제조단계; 전처리단계; 날염가공단계 및 열고정 단계로 크게 이루어진다.The manufacturing method of the flame-retardant camouflage pattern combat suit fabric having excellent infrared blocking function of the present invention comprises: a blended yarn manufacturing step; Fabric manufacturing step; Pretreatment step; It is largely composed of a printing process step and a heat setting step.

먼저, 혼합방적사 제조단계에서 원료섬유로는 FR-Rayon 섬유와 폴리비닐알콜섬유를 혼합하여 사용하는데, FR-Rayon섬유는 인계 무기질을 함유하는 FR 소재로서 Lenzing FR, 다이와보 FR-Rayon 등의 제조사에서 제조된 섬유를 사용할 수 있다. FR Rayon은 나무, 천연에서 온 재생 셀룰로오스 섬유로서 비 할로겐 방염제를 사용한 친환경 난연 섬유 소재로서 영구적인 방염성과 편안한 착용감 및 통기성, 수분조절기능외 타 방염소재와 혼방성이 뛰어난 장점이 있지만 강도가 낮고 내구성이 떨어지는 단점이 있어 주로 아라미드 섬유와 혼방하여 사용한다. First, in the mixed spun yarn manufacturing step, FR-Rayon fibers and polyvinyl alcohol fibers are mixed and used as raw fibers, and FR-Rayon fibers are FR materials containing phosphorus-based inorganic substances and are manufactured by manufacturers such as Lenzing FR and Daiwabo FR-Rayon. The prepared fibers can be used. FR Rayon is an eco-friendly flame-retardant fiber material that uses a non-halogen flame retardant as a regenerated cellulose fiber from wood and nature. It has the advantages of permanent flame retardant, comfortable fit, breathability, moisture control, and excellent blendability with other flame retardant materials, but low strength and durability. Due to this drop, it is mainly used by blending with aramid fibers.

폴리비닐알콜섬유는 고강력, 저신도, 고탄성율을 가지고, 알칼리에 대한 우수한 내성을 가지는 섬유인 쿠라레社의 "Kuralon K-Ⅱ"를 사용하는 것이 바람직하다. 특히, 상기 섬유는 난연성은 없으나, 날염이 용이하고 고강도 섬유로서 군용 피복으로서의 강도를 보완하여 준다.It is preferable to use "Kuralon K-II" manufactured by Kuraray, which is a fiber having high strength, low elongation, and high modulus of elasticity and excellent resistance to alkali. In particular, the fiber is not flame retardant, but it is easy to print and is a high-strength fiber that complements the strength as a military coating.

상기 혼합방적사는 FR-Rayon 섬유가 섬유장 36~55㎜, 섬도 1.4 ∼2.2 데니어이며, 폴리비닐알콜섬유가 섬유장이 36~55㎜, 섬도 1.4 ∼2.2 데니어이며, FR-Rayon섬유는 80∼95중량%, 폴리비닐알콜섬유는 5∼20중량%로 혼합된 것이 난연성 및 강도 부여에 바람직하다. 폴리비닐알콜섬유의 구성비 20중량%초과시에는 난연성이 저하되고, 적외선 차폐작용의 부여가 어려우며, 5%미만시에는 적외선 차폐작용 부여는 유리하나 원단의 강도가 떨어지는 단점이 있다.The mixed-spun yarn FR-Rayon fiber has a fiber length of 36 to 55 mm and a fineness of 1.4 to 2.2 denier, polyvinyl alcohol fiber has a fiber length of 36 to 55 mm and a fineness of 1.4 to 2.2 denier, and FR-Rayon fiber is 80 to 95 It is preferable to impart flame retardancy and strength to a mixture of 5 to 20% by weight of polyvinyl alcohol fiber by weight. When the composition ratio of the polyvinyl alcohol fiber exceeds 20% by weight, the flame retardancy decreases, and it is difficult to impart an infrared shielding function, and when it is less than 5%, it is advantageous to impart an infrared shielding effect, but the strength of the fabric is lowered.

상기 혼합방적사는 일반적인 Ring Spun Spinning, Air jet Spun Spinning, Rotor Spinning으로 제조가능하며, 단사는 Nec 10∼30수의 굵기가, 합연사로 사용시에는 Nec 20/2∼40/2의 섬도를 가지는 것이 바람직하다.The mixed spun yarn can be manufactured by general Ring Spun Spinning, Air Jet Spun Spinning, and Rotor Spinning, and the single yarn has a thickness of 10 to 30 Nec, and a fineness of Nec 20/2 to 40/2 when used as a ply yarn. desirable.

이후 상기 혼합방적사로 직물을 제조하는 단계를 행하는데, 직물의 조직은 평직, 변화평직(Rib Stop), 능직, 변화능직(Twill Rib)등으로 제조할 수 있다. 직물의 평량은 150∼280g/㎡이 바람직하다. 150g/㎡미만일 경우 원단의 파단강도가 크게 떨어지고 280g/㎡초과일 경우 날염시 염료의 침투가 불균일할 수 있다. 하계용으로는 180g/㎡ 평량, 동계용으로는 230g/㎡, 점퍼류는 260g/㎡가 바람직하다.Thereafter, a step of manufacturing a fabric with the blended spun yarn is performed, and the fabric of the fabric may be made of plain weave, change plain weave (Rib Stop), twill weave, change twill weave (Twill Rib). The basis weight of the fabric is preferably 150 to 280 g/m2. If it is less than 150g/m2, the breaking strength of the fabric is greatly reduced, and if it exceeds 280g/m2, the penetration of dye may be uneven during printing. The basis weight of 180g/m2 for summer, 230g/m2 for winter, and 260g/m2 for jumpers is preferable.

이후, 상기 직물로 전처리단계, 날염가공단계 및 열고정 단계를 행한다. 상기 전처리단계는 모소, 정련표백, 머서화로 이루어진다. 모소공정은 Speed 80m/min, 호발제 5g/L, Pick-up율 80%로 진행하며, 충분히 탈호를 시켜야 그라운드 염색시 불균염이 없다. 모소공정이 완료된 후 정련표백공정을 거치게 되는데 NaOH(50°Be') 0.9cc/L, 금속안정제 1g/L, H2O2 5g/L를 사용하여 원단에 손상이 적고 충분한 불순물을 제거한다. 머서화 공정은 원단에 장력을 주면서 견과 같은 광택과 염착성 향상, 치수안정화, 흡습성 증가, 강도의 향상을 도모할수 있으나, 높은 알카리 처리시 오히려 원단을 손상시킬 수 있으므로 NaOH 7°Be'를 권장한다. 날염가공단계는 텐타폭출, 날염, 고착화의 순서로 진행한다. 텐터폭출은 폴리비닐알콜섬유의 연화를 방지하기 위해 100∼150℃의 건열 온도를 추천한다. 150℃ 초과시의 Tenter 폭출시에는 피복 원단의 강도가 현저히 떨어지며, 연화 수축이 일어나므로 주의가 필요하다.Thereafter, the fabric is subjected to a pretreatment step, a printing process step, and a heat setting step. The pretreatment step consists of moso, scouring, bleaching, and mercerization. The microprocessing is carried out at a speed of 80m/min, desizing agent 5g/L, and a pick-up rate of 80%, and desorption must be done so that there is no unevenness during ground dyeing. After the microprocess is completed, it goes through the refining and bleaching process. NaOH (50°Be') 0.9cc/L, metal stabilizer 1g/L, H 2 O 2 Using 5g/L, the fabric is less damaged and sufficient impurities are removed. The mercerization process can improve the gloss and dyeability, dimensional stability, hygroscopicity, and strength of the fabric while giving tension to the fabric.However, NaOH 7°Be' is recommended because high alkali treatment may damage the fabric. The printing process step proceeds in the order of tenter exploding, printing, and fixing. For tenter exploding, a dry heat temperature of 100~150℃ is recommended to prevent softening of polyvinyl alcohol fibers. When the tenter is exploded above 150℃, the strength of the coated fabric decreases significantly and softening and shrinkage occurs, so care is required.

텐타폭출후 날염을 행하는데, Rotary 방식으로 하는 것이 바람직하다. FR-Rayon 소재 자체로는 일반 반응성 염료로도 충분히 견뢰도를 낼 수 있지만, 폴리비닐알콜섬유는 반드시 Vat 염료를 사용하여 날염하여야만 고견뢰도를 발현할 수 있다. 대한민국 국군의 위장 무늬는 5도 칼라로서 단순하지만 위장 무늬의 선이 뚜렷하므로 Over Lap Flat Screen 방식 보다 양호한 Rotary 방식이 바람직하다.Printing is performed after tenter exploding, preferably in a rotary method. The FR-Rayon material itself can achieve sufficient fastness even with a general reactive dye, but polyvinyl alcohol fibers must be printed using Vat dye to achieve high fastness. The camouflage pattern of the ROK Armed Forces is a 5 degree color and is simple, but since the line of the camouflage pattern is clear, the Rotary method is preferable to the Over Lap Flat Screen method.

군복용 원단은 적외선 차폐기능이 필요함에 따라 NIR 영역(380nm~1300nm)에서 특정 반사율을 가지는 Cibanone계 VAT염료와 Indanthrene계 VAT염료를 조합한 Vat 염료로 날염하며, 대한민국 국군 5도계(목탄, 초콜릿, 다크 그린, 그린, 베이지 그레이)색상의 적외선 반사율 파장대를 발현한다. Military fabrics are printed with Vat dyes that combine Cibanone-based VAT dyes and Indanthrene-based VAT dyes having a specific reflectance in the NIR region (380nm~1300nm) as infrared shielding function is required. Dark green, green, beige gray) color infrared reflectance wavelength band.

고착화는 염료와 섬유간의 고착화를 위해 고온 증열기에서 행하는데, FR-Rayon의 경우 인계 화합물 재생섬유이며, 폴리비닐알콜섬유는 고강도이나 연화점이 낮아 고온에서 일정시간 방치시 황변 및 강도저하, 난연성 저하를 발생하므로 고착화시 사용하는 발색제와 발색 시간이 중요하다. 발색제로는 NaOH(50°Be）와 Hydrosulfite를 각각 80∼150g/L를 사용하며 100∼150℃ 온도에서 20∼40sec간 고온증열기에서 처리한다.The fixation is performed in a high-temperature vaporizer to fix the dye and the fiber. FR-Rayon is a phosphorus compound recycled fiber, and polyvinyl alcohol fiber has low strength and softening point, so yellowing, strength reduction, and low flame retardancy when left at high temperature for a certain period of time As it occurs, the color developing agent and the color development time used for fixation are important. 80~150g/L of NaOH (50°Be) and Hydrosulfite are used as coloring agents, respectively, and treated in a high-temperature evaporator at 100~150℃ for 20~40sec.

열고정단계에서는 텐타에서 Silicon계 유연제 20∼30g/L, Hydrophilic 유연제 20∼30g/L, 유연제로 인한 난연성 저하를 막기 위한 질소계 인산 난연제 20~30g/L 및 잔부로서 물을 함유한 처리액에 침지한 후, 건열 온도 120~150℃에서 건조하여 적외선 차단 기능이 우수한 난연 위장무늬전투복용 직물의 제조를 완료한다.In the heat setting step, use a silicon-based softener 20-30g/L, a hydrophilic softener 20-30g/L, a nitrogen-based phosphoric acid flame retardant 20-30g/L to prevent the deterioration of flame retardancy due to the softener, and a treatment liquid containing water as the balance. After immersion, it is dried at a dry heat temperature of 120 to 150°C to complete the manufacture of a flame-retardant camouflage pattern combat suit fabric with excellent infrared blocking function.

이와 같이 제조된 난연 위장 전투복용 피복은 항공 조종복, 육군 전투복, 괘도차량 승무원복 및 조종 점퍼류로 사용이 가능하다. The flame-retardant camouflage combat suit fabric manufactured as described above can be used as an aviation control suit, an army combat suit, a tracked vehicle crew uniform, and a control jumper.

따라서 본 발명에 의하면, 영구적인 난연성과 날염 위장무늬, 적외선 차폐 기능성이 있는 군용 난연 위장 무늬 전투복용 직물을 제공할 수 있다.Therefore, according to the present invention, it is possible to provide a military flame-retardant camouflage pattern combat suit fabric having permanent flame retardancy and printing camouflage pattern and infrared shielding function.

도 1은 본 발명인 난연 위장무늬전투복용 직물의 사진이다.1 is a photograph of the present inventor's flame retardant camouflage pattern combat suit fabric.

이하 다음의 실시 예에서는 본 발명의 적외선 차단 기능이 우수한 난연 위장무늬전투복용 직물의 제조방법에 대한 비한정적인 예시를 하고 있다.Hereinafter, in the following examples, a non-limiting example of a method of manufacturing a flame-retardant camouflage pattern combat suit fabric having excellent infrared blocking function of the present invention is given.

[실시예 1][Example 1]

FR-Rayon 88%, 폴리비닐알콜섬유 12% 중량으로 이루어지며, FR-Rayon은 1.5데니어 섬유장 51㎜를 사용하고, 폴리비닐알콜섬유(쿠라레社의 "Kuralon K-Ⅱ")는 1.5데니어 섬유장 51㎜를 사용하여 Ring Spinning 방식으로 방적하여 TPM 800의 혼방사 Nec 33/2수를 제조하였다. 상기 원사를 이용하여 1/2 능직 원단을 제직하여 It consists of 88% of FR-Rayon and 12% of polyvinyl alcohol fiber, and FR-Rayon uses a 1.5 denier fiber length of 51 mm, and polyvinyl alcohol fiber ("Kuralon K-II" of Kuraray) is 1.5 denier. Using a fiber length of 51 mm, it was spun in a ring spinning method to prepare a blended yarn Nec 33/2 of TPM 800. Weaving 1/2 twill fabric using the above yarn

Speed 80m/min, 호발제 5g/L, Pick-up율 80%로 모소호발을 거친후, NaOH(50°Be') 0.9cc/L, 금속안정제 1g/L, H2O2 5g/L를 사용하여 정련 표백하고, 머서화 공정을 한 후, 100∼150℃의 건열 온도에서 텐터폭출후, NIR 영역(380nm~1300nm)에서 특정 반사율을 가지는 Cibanone계 VAT염료와 Indanthrene계 VAT염료를 조합한 Vat 염료로 Rotary Print로 130℃ 20m/min로 날염후, 발색제로는 NaOH(50°Be）와 Hydrosulfite를 각각 150g/L를 사용하며 130℃ 온도에서 20∼40sec간 고온증열기에서 염료와 섬유간의 고착화를 행한 후, 텐타에서 Silicon계 유연제 30g/L, Hydrophilic 유연제 30g/L, 질소계 인산 난연제 30g/L를 함유한 처리액에 침지한 후, 건열 온도 130℃에서 건조하여 난연 위장무늬전투복용 직물의 제조를 완료하였다. Speed 80m/min, desorption agent 5g/L, pick-up rate 80% after desorption, NaOH(50°Be') 0.9cc/L, metal stabilizer 1g/L, H 2 O 2 After refining and bleaching using 5g/L, mercerization, and tenter exploding at a dry heat temperature of 100-150℃, Cibanone-based VAT dye and Indanthrene-based VAT dye having a specific reflectance in the NIR region (380nm-1300nm) After printing at 130℃ 20m/min with Rotary Print, NaOH (50°Be) and 150g/L of Hydrosulfite each are used as color developing agents. Dye in a high-temperature evaporator at 130℃ for 20~40sec. After fixing between the fiber and the fiber, it is immersed in a treatment solution containing 30g/L of silicon softener, 30g/L of hydrophilic softener, and 30g/L of nitrogen-based phosphoric acid flame retardant, and then dried at a dry heat temperature of 130℃ in a tenter to flame retardant camouflage pattern. The fabrication of combat clothing was completed.

[비교예 1][Comparative Example 1]

실시예 1과 동일한 Ring Spinning을 이용하여 FR-Rayon 80%, meta-Aramid 20%의 중량으로 이루어지며, 상기 FR-Rayon은 실시예1과 동일한 섬유소재를 사용하고 meta-Aramid는 1.5데니어 51mm 섬유장을 가진 Brawn Color의 Dope Dyed meta Aramid를 사용하여 TPM 800, Nec 33/2합사를 제조한 후 실시예 1과 동일한 편량의 난연 위장 무늬 직물을 제직한 후 염색가공 전처리 단계는 실시예1과 동일한 방법으로 처리한 후, 텐타 폭출 온도 180℃ 적용, 반응성 염료로 날염하는 방법으로 염색하여 위장무늬전투복용 직물을 제조하였다.Using the same ring spinning as in Example 1, the weight of FR-Rayon 80% and meta-Aramid 20% was used, and the FR-Rayon used the same fiber material as Example 1, and the meta-Aramid was 1.5 denier 51 mm fiber After manufacturing TPM 800 and Nec 33/2 ply yarn using Dope Dyed meta Aramid of long Brawn Color, after weaving the same amount of flame-retardant camouflage pattern fabric as in Example 1, the pretreatment step for dyeing was the same as in Example 1. After treatment by the method, a tenta explosive temperature of 180°C was applied and dyed by a method of printing with a reactive dye to prepare a camouflage patterned combat suit fabric.

상기 실시예 1 및 비교예 1의 직물의 물성을 측정하여 표 1에 나타내었으며, 실시예 1의 직물의 적외선반사율(%)을 측정하여 표 2에 나타내었다.The physical properties of the fabrics of Example 1 and Comparative Example 1 were measured and shown in Table 1, and the infrared reflectance (%) of the fabric of Example 1 was measured and shown in Table 2.

구분division 인장강도
(N)The tensile strength
(N) 인열 강도
(N)Tear strength
(N) 방화도Arson degree IR 반사율
(현 육군 전투복 색상IR reflectance
(Current Army Combat Uniform Color 잔진시간(S)Residual time (S) 탄화거리
(cm)Carbonization distance
(cm) 실시예 1Example 1 680680 3131 00 88 IR 차폐발현IR shielding expression 비교예 2Comparative Example 2 410410 2020 00 88 IR 차폐미발현No IR shielding

색상별

파장(nm)By color

Wavelength(nm) 목탄색Charcoal color 초콜릿 색chocolate Dark Olive GreenDark Olive Green Forest GreenForest Green 베이지 그레이Beige gray 600600 3 ~ 183 to 18 4 ~ 184 to 18 4 ~ 184 to 18 6 ~ 186 to 18 18 ~ 3218 to 32 620620 3 ~ 183 to 18 4 ~ 184 to 18 4 ~ 184 to 18 6 ~ 186 to 18 18 ~ 3218 to 32 640640 3 ~ 183 to 18 4 ~ 184 to 18 4 ~ 184 to 18 6 ~ 206 to 20 18 ~ 3218 to 32 660660 3 ~ 223 to 22 6 ~ 186 to 18 4 ~ 184 to 18 8 ~ 228 to 22 20 ~ 4020 to 40 680680 4 ~ 284 to 28 12 ~ 2412 to 24 4 ~ 224 to 22 12 ~ 3012 to 30 28 ~ 4828 to 48 700700 12 ~ 2812 to 28 12 ~ 2412 to 24 8 ~ 228 to 22 14 ~ 3214 to 32 38 ~ 5838 ~ 58 720720 18 ~ 3618 to 36 16 ~ 3616 to 36 10 ~ 2810 to 28 22 ~ 4622 ~ 46 38 ~ 5838 ~ 58 740740 18 ~ 3618 to 36 16 ~ 3616 to 36 16 ~ 2816 to 28 28 ~ 5228 to 52 46 ~ 7246 ~ 72 760760 24 ~ 4024 to 40 24 ~ 4424-44 18 ~ 3418 to 34 28 ~ 5628 ~ 56 46 ~ 7246 ~ 72 780780 24 ~ 4024 to 40 24 ~ 4424-44 22 ~ 4022 to 40 34 ~ 6434 ~ 64 46 ~ 7246 ~ 72 800800 28 ~ 4628 ~ 46 30 ~ 5230 to 52 22 ~ 4622 ~ 46 34 ~ 6434 ~ 64 52 ~ 7652 ~ 76 820820 28 ~ 4628 ~ 46 30 ~ 5230 to 52 24 ~ 5224-52 34 ~ 6434 ~ 64 52 ~ 7652 ~ 76 840840 32 ~ 4832 to 48 34 ~ 5834 ~ 58 24 ~ 5424-54 40 ~ 7040 to 70 52 ~ 7652 ~ 76 860860 32 ~ 4832 to 48 34 ~ 5834 ~ 58 24 ~ 5824-58 40 ~ 7040 to 70 52 ~ 7652 ~ 76 880880 36 ~ 5636 ~ 56 38 ~ 6438 ~ 64 34 ~ 6434 ~ 64 40 ~ 7040 to 70 52 ~ 7652 ~ 76 900900 36 ~ 5636 ~ 56 38 ~ 6438 ~ 64 34 ~ 6434 ~ 64 46 ~ 7246 ~ 72 52 ~ 7652 ~ 76 920920 40 ~ 6640 ~ 66 44 ~ 6644 ~ 66 38 ~ 7238 to 72 46 ~ 7246 ~ 72 52 ~ 7652 ~ 76 940940 40 ~ 6640 ~ 66 44 ~ 6644 ~ 66 40 ~ 7440 ~ 74 48 ~ 7348 to 73 52 ~ 7652 ~ 76 960960 40 ~ 6640 ~ 66 44 ~ 6644 ~ 66 40 ~ 7440 ~ 74 48 ~ 7348 to 73 52 ~ 7652 ~ 76 980980 44 ~ 6844 ~ 68 44 ~ 6844 ~ 68 46 ~ 7646 ~ 76 48 ~ 7348 to 73 52 ~ 7652 ~ 76 10001000 44 ~ 6844 ~ 68 44 ~ 6844 ~ 68 46 ~ 7646 ~ 76 48 ~ 7348 to 73 52 ~ 7652 ~ 76 10201020 46 ~ 6946 ~ 69 44 ~ 6844 ~ 68 48 ~ 7848 to 78 48 ~ 7348 to 73 52 ~ 7652 ~ 76 10401040 46 ~ 6946 ~ 69 44 ~ 6844 ~ 68 48 ~ 7848 to 78 48 ~ 7348 to 73 52 ~ 7652 ~ 76 10601060 46 ~ 6946 ~ 69 44 ~ 6844 ~ 68 48 ~ 7848 to 78 48 ~ 7348 to 73 52 ~ 7652 ~ 76 10801080 46 ~ 6946 ~ 69 44 ~ 6844 ~ 68 48 ~ 7848 to 78 49 ~ 7449 to 74 52 ~ 7652 ~ 76 11001100 46 ~ 6946 ~ 69 44 ~ 6844 ~ 68 48 ~ 7848 to 78 49 ~ 7449 to 74 52 ~ 7652 ~ 76 11201120 46 ~ 6946 ~ 69 44 ~ 6844 ~ 68 48 ~ 7848 to 78 49 ~ 7449 to 74 52 ~ 7652 ~ 76 11401140 46 ~ 6946 ~ 69 44 ~ 6844 ~ 68 48 ~ 7848 to 78 49 ~ 7449 to 74 52 ~ 7652 ~ 76 11601160 46 ~ 6946 ~ 69 44 ~ 6844 ~ 68 48 ~ 7848 to 78 50 ~ 7550 to 75 52 ~ 7652 ~ 76 11801180 46 ~ 6946 ~ 69 45 ~ 6845 ~ 68 50 ~ 8050 to 80 50 ~ 7550 to 75 53 ~ 7653 ~ 76 12001200 47 ~ 6947 to 69 45 ~ 6845 ~ 68 48 ~ 7848 to 78 50 ~ 7650 to 76 53 ~ 7653 ~ 76 12201220 47 ~ 7047 to 70 45 ~ 6845 ~ 68 48 ~ 7848 to 78 50 ~ 7650 to 76 53 ~ 7653 ~ 76 12401240 47 ~ 7047 to 70 45 ~ 6845 ~ 68 49 ~ 7949 ~ 79 50 ~ 7650 to 76 53 ~ 7653 ~ 76 12601260 47 ~ 7047 to 70 45 ~ 6845 ~ 68 49 ~ 7949 ~ 79 50 ~ 7650 to 76 53 ~ 7653 ~ 76

Claims (6)

FR-Rayon 섬유와 폴리비닐알콜섬유를 사용하여 혼합방적사를 만드는 단계;
상기 혼합방적사로 직물을 제조하는 단계; 및
상기 직물로 전처리단계; 날염가공단계 및 열고정 단계를 행하는 것을 특징으로 하는 적외선 차단 기능이 우수한 난연 위장무늬전투복용 직물의 제조방법.Making a blended yarn using FR-Rayon fiber and polyvinyl alcohol fiber;
Manufacturing a fabric with the blended yarn; And
Pretreatment step with the fabric; A method of manufacturing a flame-retardant camouflage pattern combat clothing fabric with excellent infrared blocking function, characterized in that performing a printing process step and a heat setting step. 제 1항에 있어서,
상기 혼합방적사는 FR-Rayon 섬유가 섬유장 36~55㎜, 섬도 1.4 ∼2.2 데니어이며, 폴리비닐알콜섬유가 섬유장이 36~55㎜, 섬도 1.4 ∼2.2 데니어이며, FR-Rayon섬유는 80∼95중량%, 폴리비닐알콜섬유는 5∼20중량%로 혼합된 것을 특징으로 하는 적외선 차단 기능이 우수한 난연 위장무늬전투복용 직물의 제조방법.The method of claim 1,
The mixed-spun yarn FR-Rayon fiber has a fiber length of 36 to 55 mm and a fineness of 1.4 to 2.2 denier, polyvinyl alcohol fiber has a fiber length of 36 to 55 mm and a fineness of 1.4 to 2.2 denier, and FR-Rayon fiber is 80 to 95 A method of manufacturing a flame-retardant camouflage pattern combat suit fabric with excellent infrared blocking function, characterized in that the weight%, polyvinyl alcohol fiber is mixed in an amount of 5-20% by weight. 제 1항에 있어서,
상기 혼합방적사의 섬도는 Nec 10∼40수인 것이 특징으로 하는 적외선 차단 기능이 우수한 난연 위장무늬전투복용 직물의 제조방법.The method of claim 1,
The fineness of the mixed-spun yarn is Nec 10 ~ 40, characterized in that the method of manufacturing a flame-retardant camouflage pattern combat suit fabric excellent in infrared ray blocking function. 제 1항에 있어서,
상기 직물은 평직, 변화평직(Rib Stop), 능직, 변화능직(Twill Rib) 중 어느 하나인 것을 특징으로 하는 적외선 차단 기능이 우수한 난연 위장무늬전투복용 직물의 제조방법.The method of claim 1,
The fabric is a method of manufacturing a flame-retardant camouflage pattern combat suit fabric having excellent infrared blocking function, characterized in that any one of plain weave, change plain weave (Rib Stop), twill weave, and change twill weave (Twill Rib). 제 1항에 있어서,
상기 직물의 평량은 150∼280g/㎡인 것을 특징으로 하는 적외선 차단 기능이 우수한 난연 위장무늬전투복용 직물의 제조방법.The method of claim 1,
The method of manufacturing a flame-retardant camouflage pattern combat suit fabric with excellent infrared blocking function, characterized in that the basis weight of the fabric is 150 to 280 g/m 2. 제 1항에 있어서,
상기 전처리단계는 모소, 정련표백, 머서화로 이루어지고,
상기 날염가공단계는 100∼150℃ 의 건열 온도에서 텐터폭출후, NIR 영역(380nm~1300nm)에서 특정 반사율을 가지는 Cibanone계 VAT염료와 Indanthrene계 VAT염료를 조합한 Vat 염료로 날염한 후, 발색제로 NaOH(50°Be）와 Hydrosulfite를 각각 80∼150g/L를 사용하여 100∼150℃ 온도에서 20∼40sec간 고온증열기에서 고착화처리하고,
상기 열고정단계에서는 텐타에서 Silicon계 유연제 20∼30g/L, Hydrophilic 유연제 20∼30g/L, 질소계 인산 난연제 20~30g/L 및 잔부로서 물을 함유한 처리액에 침지한 후, 건열 온도 120~150℃에서 건조하는 것을 특징으로 하는 적외선 차단 기능이 우수한 난연 위장무늬전투복용 직물의 제조방법.The method of claim 1,
The pretreatment step consists of moso, scouring, bleaching, mercerization,
The printing process step is after tenter exploding at a dry heat temperature of 100 to 150°C, printing with a Vat dye combining Cibanone-based VAT dye and Indanthrene-based VAT dye having a specific reflectance in the NIR region (380 nm to 1300 nm), NaOH (50°Be) and Hydrosulfite are fixed in a high-temperature evaporator for 20 to 40 sec at 100 to 150°C using 80 to 150 g/L, respectively,
In the heat setting step, after immersing in a treatment solution containing water as the remainder and 20-30 g/L of a silicon-based softener, 20-30 g/L of a hydrophilic softener, and 20-30 g/L of a nitrogen-based phosphoric acid flame retardant in a tenter, dry heat temperature 120 Method of manufacturing a flame-retardant camouflage pattern combat suit fabric with excellent infrared blocking function, characterized in that drying at ~150 ℃.
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KR20160009168A (en) * 2014-07-15 2016-01-26 대한민국(육군참모총장) Aviation Garments with Outstanding Flame Retardant Property Produced by using Infusion Technology of Aramid Fibers and manufacturing method thereby
KR101616270B1 (en) 2014-07-15 2016-06-08 대한민국(육군참모총장) Aviation Garments with Outstanding Flame Retardant Property Produced by using Infusion Technology of Aramid Fibers manufacturing method

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