KR20200078726A - Silicone capsules with liquid composition for curing - Google Patents
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Abstract
Description
본 발명은 실리콘캡슐에 관한 것으로써, 사용과 목적 및 효과에 따라 함유량을 달리하여 경화되는 시간을 조절할 수 있고, 경화력을 상승시킨 액상의 조성물이 내부에 구비된 실리콘캡슐에 관한 것이다. The present invention relates to a silicone capsule, it is possible to control the time for curing by varying the content according to the use and purpose and effect, and relates to a silicone capsule having a liquid composition having an increased curing power therein.
우선, 종래기술을 살펴보면, First, looking at the prior art,
일반적으로, 하이드로실릴화 경화성 오가노폴리실록산 조성물은 접착 특성이 불량한 문제점이 있다. In general, the hydrosilylation curable organopolysiloxane composition has a problem of poor adhesion properties.
이러한 문제점을 해결하기 위해, 에폭시 화합물 및 유기 알루미늄 화합물을 조성물에 가하는 방법 또는 조성물을 규소 결합 불포화 그룹 및 알콕시 그룹을 갖는 유기 규소 화합물 및 알루미늄 또는 지르코늄 화합물과 배합하는 방법이 제안되었다. To solve this problem, a method of adding an epoxy compound and an organoaluminum compound to the composition or a method of combining the composition with an organosilicon compound having a silicon-bonded unsaturated group and an alkoxy group and an aluminum or zirconium compound has been proposed.
또 다른 방법은 조성물을 지르코늄 화합물 및 비스(트리알콕시실릴)알칸, 규소 결합 알콕시 그룹을 갖는 디실란, 및 에폭시 그룹을 갖는 실록산 또는 알콕시실란으로 이루어진 그룹으로부터 선택된 규소 화합물과 배합하는 것으로 이루어진다. Another method consists in blending the composition with a zirconium compound and a silicon compound selected from the group consisting of bis(trialkoxysilyl)alkanes, disilanes having silicon-bonded alkoxy groups, and siloxanes or alkoxysilanes with epoxy groups.
상기 경화성 오가노폴리실록산 조성물의 단점은 조성물의 저장 동안 시간 경과시 발생하는, 유기 금속 화합물의 존재하에 규소 결합 수소 원자 및 물 또는 실란올 그룹 사이의 축합 반응 또는 기타 반응하에, 상기 조성물로부터 형성된 경화 생성물이 허용되는 수치 이하로 경도가 손실되는 것으로 이루어진다. The disadvantage of the curable organopolysiloxane composition is that the cured product formed from the composition under condensation reaction or other reaction between silicon-bonded hydrogen atoms and water or silanol groups in the presence of an organometallic compound, which occurs over time during storage of the composition. It consists in losing hardness below the permissible value.
한편, 축합 경화성 오가노폴리실록산 조성물에 대한 축합 반응 촉매가 유기 수지에 캡슐화된 유기 금속 화합물로 이루어진 마이크로캡슐의 형태로 제조될 수 있는 것으로 공지되어 있다. On the other hand, it is known that the condensation reaction catalyst for the condensation-curable organopolysiloxane composition can be prepared in the form of microcapsules made of an organometallic compound encapsulated in an organic resin.
그러나, 이러한 축합반응 촉매가 하이드로실릴화 경화성 오가노폴리실록산 조성물에 첨가되는 경우, 시간이 지남에 따라 경화체에서 경도 손실을 억제할 수 있다는 것은 공지되어 있지 않다. However, it is not known that when such a condensation reaction catalyst is added to a hydrosilylation curable organopolysiloxane composition, it is possible to suppress hardness loss in the cured body over time.
이에 종래에는 등록번호 제10-1187594호의 '경화성 오가노폴리실록산 조성물'와, 등록번호 제10-1623220호의 '접착성 캡슐화 조성물 및 그로 제조된 전자 소자' 및 등록번호 제10-1740185호의 '접착제 조성물'이 개시되어 있지만, 상기한 문제점에 대해서는 여전히 개선되고 있지 않은 실정이다. Accordingly, in the related art,'curable organopolysiloxane composition' of registration number 10-1187594,'adhesive encapsulation composition and electronic device manufactured therein' of registration number 10-1623220 and'adhesive composition' of registration number 10-1740185 Although this is disclosed, the situation has not been improved for the above-mentioned problems.
본 발명은 상기한 종래기술의 문제점을 해결하기 위해 안출해낸 것으로써, 실리콘캡슐 내부의 조성물을 이용하여 경화시키는 위치 및 제품에 맞게 상기 조성물 중에서 일부분의 성분량을 조절하여 경화되는 시간을 조절할 수 있고, 경화력을 극대화하기 위해 추가적인 조성물을 혼합하였으며, 사용자가 실리콘캡슐의 파열을 손쉽게 하거나 또는 별도의 제품을 통해 실리콘캡슐의 파열이 손쉽게 되도록 실리콘캡슐에 대한 형상, 구조 및 재질에 대해서도 한정한 경화용 액상 조성물이 구비된 실리콘캡슐을 제공함에 주안점을 두고 기술적 과제로서 완성해낸 것이다. The present invention has been devised to solve the above-described problems of the prior art, it is possible to control the curing time by adjusting the amount of components in a portion of the composition according to the position and product to cure using the composition inside the silicone capsule, In order to maximize the curing power, additional compositions are mixed, and the curing liquid is limited to the shape, structure, and material of the silicone capsules so that the user can easily break the silicone capsule or easily break the silicone capsule through a separate product. It was completed as a technical task with the emphasis on providing a silicone capsule with a composition.
이에 본 발명은 외부의 힘으로 피막이 파열되어 내부에 있는 액상이 외부로 흘러내려 상기 액상이 시간의 흐름에 따라 경화되는 액상용 실리콘캡슐에 있어서, 상기 실리콘캡슐의 내부에는 다수개의 성분이 혼합된 액상의 조성물이 구비되되 상기 조성물에는, 폴리디메틸실록산 45 ~ 65wt%, 디오가노 폴리실록산(액상) 20 ~ 35wt%, 촉매제 0.01 ~ 0.3wt% 가 혼합된 조성물로 이루어지는 것을 특징으로 하는 경화용 액상 조성물이 구비된 실리콘캡슐을 그 기술적 특징으로 한다. Accordingly, the present invention is a silicone capsule for a liquid in which the coating is ruptured by external force and the liquid in the interior flows to the outside, so that the liquid is cured over time. A liquid in which a plurality of components are mixed in the silicone capsule. The composition is provided, the composition, polydimethylsiloxane 45 ~ 65wt%, diorgano polysiloxane (liquid phase) 20 ~ 35wt%, the catalyst is a liquid composition for curing, characterized in that consisting of a mixture of 0.01 ~ 0.3wt% The silicone capsule is characterized by its technical characteristics.
본 발명인 경화용 액상 조성물이 구비된 실리콘캡슐에 따르면, 실리콘캡슐의 형상을 한정하여 사용자가 직접 파열하거나 또는 별도의 제품을 통해 파열 시, 손쉽게 파열될 수 있도록 하였고, 실리콘캡슐의 파열을 더욱 손쉽게 하기 위해 돌출부 또는 홈부를 형성하였으며, 사용자의 외력 또는 별도 제품의 외력을 제외하고는 손쉽게 파열되지 않도록 재질을 한정하였고, 실리콘캡슐 내부의 액상 조성물에 대한 성분 중에서 경화되는 시간을 조절할 수 있도록 하였으며, 경화 시 경화력을 상승시킬 수 있는 성분에 대해서도 조절할 수 있도록 하는 등 효과가 큰 발명이다. According to the silicone capsules provided with the liquid composition for curing according to the present inventors, the shape of the silicone capsules is limited to allow the user to rupture or rupture easily through a separate product, and to more easily rupture the silicone capsule. In order to form the protrusions or grooves, the material was limited so as not to be easily ruptured except for the external force of the user or the external force of a separate product, and it was possible to control the curing time among the ingredients for the liquid composition inside the silicone capsule. It is an invention having a great effect such that it is possible to adjust even a component capable of increasing the curing power.
도 1은 본 발명인 실리콘캡슐을 나타내는 평면도
도 2는 본 발명인 실리콘캡슐에 대한 다양한 형상을 나타내는 측면도
도 3은 본 발명인 실리콘캡슐에 이중피막이 형성된 것을 나타내는 평면도
도 4는 본 발명인 실리콘캡슐에 돌출부 또는 홈부가 형성된 것을 나타내는 단면도
도 5는 도 3의 이중피막에 대한 다른 실시 예를 나타내는 단면도1 is a plan view showing a silicone capsule of the present invention
Figure 2 is a side view showing a variety of shapes for the present invention silicone capsules
Figure 3 is a plan view showing that the double coating is formed on the silicone capsule of the present invention
Figure 4 is a cross-sectional view showing a protrusion or groove formed in the silicone capsule of the present invention
Figure 5 is a cross-sectional view showing another embodiment of the double film of Figure 3
이하, 첨부되는 도면과 관련하여 상기 목적을 달성하기 위한 본 발명의 바람직한 구성 및 작용에 대해 도 1 내지 도 5를 참고로 설명하면 다음과 같다. Hereinafter, with reference to Figures 1 to 5 for the preferred configuration and operation of the present invention for achieving the above object with reference to the accompanying drawings as follows.
우선, 본 발명인 실리콘캡슐은 외부의 힘으로 피막이 파열되어 내부에 있는 액상이 외부로 흘러내려 상기 액상이 시간의 흐름에 따라 경화되는 액상용 실리콘캡슐에 있어서, 상기 실리콘캡슐의 내부에는 다수개의 성분이 혼합된 액상의 조성물이 구비되되 상기 조성물에는, 폴리디메틸실록산 45 ~ 65wt%, 디오가노 폴리실록산(액상) 20 ~ 35wt%, 촉매제 0.01 ~ 0.3wt% 가 혼합된 조성물로 이루어진다. First, the silicone capsule of the present invention is a silicone capsule for liquids in which the film is ruptured by external force and the liquid inside is cured over time, and the liquid is cured over time. A mixed liquid composition is provided, wherein the composition is composed of 45 to 65 wt% of polydimethylsiloxane, 20 to 35 wt% of diorgano polysiloxane (liquid phase), and 0.01 to 0.3 wt% of catalyst.
상기 혼합물에 폴리 아크릴산 나트륨 1 ~ 1.2wt%, 실리콘오일 8 ~ 20wt%, 메틸옥시미노실란(methyl oximino silane : MOS) 1.5 ~ 8wt%, 비닐옥시미노실란(vinyl oximino silane : VOS) 0.2 ~ 3wt%, 연무질 실리카 2 ~ 15wt%, 아미노실란 0.2 ~ 3wt% 가 혼합된 제 1조성물이 포함된다. Sodium polyacrylate 1 to 1.2 wt%, silicone oil 8 to 20 wt%, methyl oximino silane (MOS) 1.5 to 8 wt%, vinyl oximino silane (VOS) 0.2 to 3 wt% , Aerosol silica 2 ~ 15wt%, aminosilane 0.2 ~ 3wt% of the first composition is included.
상기 실리콘캡슐의 피막은 다수개의 성분이 혼합된 혼합물로 제조되되 나일론 50 ~ 70% 중량부와, MWNT(Multi-Walled Nano Tube. 이하 '다층나노튜브'라함.) 2 ~ 4%(0.1g/㎖) 중량부와, 산화방지제 0.2% 중량부 및 분산제 1 ~ 5% 중량부가 혼합된 혼합물을 가공, 압출하여 제조된다. The coating of the silicone capsule is made of a mixture of a plurality of components, but 50 to 70% by weight of nylon and MWNT (Multi-Walled Nano Tube. hereinafter referred to as'multilayer nanotube') 2 to 4% (0.1 g/ ㎖) It is prepared by processing and extruding a mixture of parts by weight, 0.2% by weight of antioxidant and 1 to 5% by weight of dispersant.
상기 혼합물에는 불포화 카르복실산 화합물의 공중합체로 이루어진 스티렌계수지 8 ~ 20% 중량부와, 폴리에테르에스테르 수지 10 ~ 15% 중량부와, 폴리에틸렌글리콜-디아크릴레이트를 친수성 단량체로 하는 화합물 3 ~ 7% 중량부 및 플루오르 화합물 0.3 ~ 0.5%중량부가 혼합된 제 1혼합물이 포함된다. The mixture contains 8 to 20% by weight of a styrene-based resin composed of a copolymer of an unsaturated carboxylic acid compound, 10 to 15% by weight of a polyether ester resin, and 3 to 3 of polyethylene glycol-diacrylate as a hydrophilic monomer. A first mixture containing 7% by weight and 0.3 to 0.5% by weight of fluorine compound is included.
상기 실리콘캡슐은 원형 또는 다각형 또는 하나 이상의 중공부가 형성된 원형 또는 하나 이상의 중공부가 형성된 다각형으로 형성된다. The silicone capsule is formed of a circular or polygonal shape or a circular shape in which one or more hollow portions are formed or a polygonal shape in which one or more hollow portions are formed.
상기 실리콘캡슐의 상부 또는 하부 또는 측면부 또는 중공부가 형성된 부분에는 하나 이상의 돌출부 또는 홈부가 형성되어 있다. One or more protrusions or grooves are formed in the upper or lower portion or the side portion or the hollow portion of the silicone capsule.
상기한 본 발명에 대해 도 1 내지 도 5를 참고로 보다 상세히 설명하면, If the present invention described above in more detail with reference to Figures 1 to 5,
본 발명인 실리콘캡슐은 외부의 힘으로 피막이 파열되어 내부에 있는 액상이 외부로 흘러내려 상기 액상이 시간의 흐름에 따라 경화되도록 하는 실리콘캡슐로써, 내부에는 다수개의 성분이 혼합된 액상의 조성물이 구비되고, 피막은 다수개의 성분이 혼합된 합성수지재질로 제조된다. The silicone capsule according to the present invention is a silicone capsule that ruptures a film due to external force so that the liquid in the interior flows to the outside, so that the liquid is cured over time, and a liquid composition in which a plurality of components are mixed is provided therein. , The coating is made of a synthetic resin material in which a plurality of components are mixed.
우선, 내부에 구비되는 다수개의 조성물은, First, a plurality of compositions provided inside,
상기 실리콘캡슐의 내부에 구비되되 폴리디메틸실록산 45 ~ 65wt%, 디오가노 폴리실록산(액상) 20 ~ 35wt%, 촉매제 0.01 ~ 0.3wt% 가 혼합된 조성물로 이루어진다. It is provided inside the silicone capsule, but is composed of a composition in which 45 to 65 wt% of polydimethylsiloxane, 20 to 35 wt% of diorgano polysiloxane (liquid phase), and 0.01 to 0.3 wt% of catalyst are mixed.
상기 조성물에는 실리콘캡슐의 사용용도 및 경화되는 시간에 따라 촉매제의 양을 조절할 수 있으며, 그에 따라 폴리디메틸실록산과 디오가노 폴리실록산에 대한 양도 조절될 수 있다. In the composition, the amount of the catalyst can be adjusted depending on the use of the silicone capsule and the curing time, and accordingly, the amount of the polydimethylsiloxane and the diorgano polysiloxane can also be adjusted.
또한, 상기 혼합된 조성물에는 조성물의 목적 및 효과에 따라 혼합된 제 1조성물이 포함된다. In addition, the mixed composition includes the first composition mixed according to the purpose and effect of the composition.
상기 제 1조성물에는 폴리 아크릴산 나트륨 1 ~ 1.2wt%, 실리콘오일 8 ~ 20wt%, 메틸옥시미노실란(methyl oximino silane : MOS) 1.5 ~ 8wt%, 비닐옥시미노실란(vinyl oximino silane : VOS) 0.2 ~ 3wt%, 연무질 실리카 2 ~ 15wt%, 아미노실란 0.2 ~ 3wt% 가 혼합된다. In the first composition, sodium polyacrylate 1 to 1.2 wt%, silicone oil 8 to 20 wt%, methyl oximino silane (MOS) 1.5 to 8 wt%, vinyl oxymino silane (VOS) 0.2 to 3 wt%, aerosol silica 2-15 wt%, aminosilane 0.2-3 wt% are mixed.
상기 기본조성물(폴리디메틸실록산, 디오가노 폴리실록산, 촉매제가 혼합된 조성물)은 제 1조성물과 동시에 혼합한 후, 일정 온도로 가열단계를 거쳐 완성된다. The basic composition (polydimethylsiloxane, diorgano polysiloxane, a composition in which a catalyst is mixed) is mixed with the first composition at the same time, and then completed through a heating step at a constant temperature.
또한, 상기 제 1조성물의 경우, 상기와 같이 기본조성물에 동시에 혼합하거나 또는 상기 제 1조성물의 성분을 별도로 혼합한 후, 일정온도로 가열하고 건조기를 이용하여 1차 건조하고, 완전 건조된 제 1조성물에 대해 일정온도로 가열하고 자연건조를 이용하여 2차 건조한 후, 완전 건조된 제 1조성물에 대해 상기 기본조성물과 혼합하여 일정 온도로 가열단계를 거쳐 최종적으로 완성하게 되도록 하였다. In addition, in the case of the first composition, the mixture is simultaneously mixed with the basic composition as described above or the components of the first composition are separately mixed, heated to a constant temperature, primary dried using a dryer, and completely dried. The composition was heated to a constant temperature and secondary dried using natural drying, and then mixed with the basic composition for a completely dried first composition to be finally completed through a heating step at a constant temperature.
상기 1차 건조 후 또는 1차 건조와 2차 건조 후에는 각각 촉매제가 일정량 추가될 수도 있다. A certain amount of the catalyst may be added after the first drying or after the first drying and second drying.
상기 실리콘캡슐의 피막은 다수개의 성분이 혼합된 혼합물로 제조되되 나일론 50 ~ 70% 중량부와, MWNT(Multi-Walled Nano Tube. 이하 '다층나노튜브'라함.) 2 ~ 4%(0.1g/㎖) 중량부와, 산화방지제 0.2% 중량부 및 분산제 1 ~ 5% 중량부가 혼합된 혼합물을 가열, 가공 및 압출하여 제조된다. The coating of the silicone capsule is made of a mixture of a plurality of components, but 50 to 70% by weight of nylon and MWNT (Multi-Walled Nano Tube. hereinafter referred to as'multilayer nanotube') 2 to 4% (0.1 g/ ㎖) It is prepared by heating, processing and extruding a mixture of parts by weight, 0.2% by weight of antioxidant and 1 to 5% by weight of dispersant.
상기 혼합물은 가열, 가공 및 압출을 순차적으로 진행할 수도 있지만, The mixture may be sequentially heated, processed and extruded,
혼합물의 내구성을 위해 1차 가공 후, 건조기를 통한 1차 건조와, 1차 건조 완료된 혼합물을 2차 가공하여 자연건조를 통한 2차 건조 및 2차 건조 완료된 혼합물을 3차 가공하여 건조기를 통한 3차 건조까지 완료된 혼합물을 압출하여 피막을 제조할 수 있다. For the durability of the mixture, after primary processing, primary drying through a dryer, secondary processing of the primary drying completed mixture, secondary drying through natural drying, and secondary processing of the secondary drying completed mixture are further processed, followed by drying through a dryer. The film can be prepared by extruding the mixture that has been dried up to the tea.
또한, 상기 혼합물에는 불포화 카르복실산 화합물의 공중합체로 이루어진 스티렌계수지 8 ~ 20% 중량부와, 폴리에테르에스테르 수지 10 ~ 15% 중량부와, 폴리에틸렌글리콜-디아크릴레이트를 친수성 단량체로 하는 화합물 3 ~ 7% 중량부 및 플루오르 화합물 0.3 ~ 0.5%중량부가 혼합된 제 1혼합물이 포함된다. In addition, the mixture is a compound containing 8 to 20% by weight of a styrene-based resin composed of a copolymer of an unsaturated carboxylic acid compound, 10 to 15% by weight of a polyether ester resin, and polyethylene glycol-diacrylate as a hydrophilic monomer. The first mixture includes 3 to 7% by weight of the fluorine compound and 0.3 to 0.5% by weight of the fluorine compound.
상기 혼합물과 제 1혼합물의 혼합은, Mixing the mixture and the first mixture,
단순 혼합으로 통해 피막을 제조할 수도 있지만, The film can be prepared by simple mixing,
상기 제 1혼합물을 혼합물과 혼합하기 전, 전처리과정을 거친 후, 혼합하여 사용할 수도 있다. The first mixture may be mixed with the mixture before, after the pre-treatment process, and mixed.
상기 제 1혼합물에 대한 전처리과정은, The pre-treatment process for the first mixture,
상기 제 1혼합물을 혼합하여 1차 가공 후, 건조기를 통한 1차 건조와, 1차 건조 완료된 혼합물을 2차 가공하여 자연건조를 통한 2차 건조까지 완료된 제 1혼합물을 상기한 혼합물과 혼합하여 최종적으로 건조기를 통해 건조한 후, 압출하여 피막을 제조할 수 있다. After the primary processing by mixing the first mixture, primary drying through a dryer, secondary processing of the primary drying-completed mixture and secondary drying through natural drying to complete drying to the first mixture completed with the above-mentioned mixture are final. After drying through a dryer, the film can be prepared by extrusion.
상기 실리콘캡슐은 원형 또는 다각형 또는 하나 이상의 중공부가 형성된 원형 또는 하나 이상의 중공부가 형성된 다각형으로 형성된다. The silicone capsule is formed of a circular or polygonal shape or a circular shape in which one or more hollow portions are formed or a polygonal shape in which one or more hollow portions are formed.
상기 실리콘캡슐의 상부 또는 하부 또는 측면부 또는 중공부가 형성된 부분에는 하나 이상의 돌출부 또는 홈부가 형성되어 있다. One or more protrusions or grooves are formed in the upper or lower portion or the side portion or the hollow portion of the silicone capsule.
상기 실리콘캡슐이 사용자로 하여금 외력이 닿는 부분 또는 실리콘캡슐이 파열되도록 외력을 가진 별도의 제품이 닿는 부분인 실리콘캡슐의 상부 또는 하부 또는 측면도 또는 중공부가 형성된 내측부분에는 2중피막이 하나 이상 형성된다. At least one double layer is formed on the inner portion of the upper or lower portion or the side view or the hollow portion of the silicone capsule, which is the portion where the silicone capsule allows the user to contact the external force or the portion of the silicone capsule that separates the product with external force so as to rupture.
상기 2중피막은 내부에 공기층이 형성되며, 상기한 2중피막을 제외한 부분의 피막보다 2중피막의 두께가 얇게 형성된다. An air layer is formed inside the double coat, and the thickness of the double coat is thinner than that of the portion except for the above-described double coat.
상기 얇게 형성되는 2중피막은 한겹으로 형성된 피막과 대비하여 단일의 피막 두께를 나타낸다. The thinly formed double film exhibits a single film thickness as compared to a single layer film.
상기 2중피막의 경우, 외피와 내피로 각각 구분되지만, 외피의 내측에는 상기한 돌출부 또는 홈부가 하나 이상 형성될 수도 있다. In the case of the double-coated film, they are respectively divided into an outer skin and an inner skin, but one or more of the above-described protrusions or grooves may be formed inside the outer skin.
또한, 상기 2중피막의 내부에는 공기층이 형성되거나 또는 촉매제가 일정량 위치될 수도 있다. In addition, an air layer may be formed inside the double coat or a certain amount of catalyst may be positioned.
상기 2중피막에 위치되는 촉매제는 실리콘캡슐의 파열 시, 액상 조성물에 대한 경화 시간을 조절하기 위함이다. The catalyst located in the double coat is to control the curing time for the liquid composition when the silicone capsule is ruptured.
상기와 같은 본 발명에 따르면, 실리콘캡슐의 형상을 한정하여 사용자가 직접 파열하거나 또는 별도의 제품을 통해 파열 시, 손쉽게 파열될 수 있도록 하였고, 실리콘캡슐의 파열을 더욱 손쉽게 하기 위해 돌출부 또는 홈부를 형성하였으며, 사용자의 외력 또는 별도 제품의 외력을 제외하고는 손쉽게 파열되지 않도록 재질을 한정하였고, 실리콘캡슐 내부의 액상 조성물에 대한 성분 중에서 경화되는 시간을 조절할 수 있도록 하였으며, 경화 시 경화력을 상승시킬 수 있는 성분에 대해서도 조절할 수 있도록 한다. According to the present invention as described above, by limiting the shape of the silicone capsule to allow the user to rupture or rupture easily through a separate product, to form a protrusion or groove to more easily rupture the silicone capsule. In addition, the material was limited so that it does not rupture easily except the external force of the user or the external force of a separate product, and it was possible to adjust the curing time among the ingredients for the liquid composition inside the silicone capsule, and the curing power may be increased during curing. It is also possible to adjust the ingredients.
Claims (7)
상기 실리콘캡슐의 내부에는 다수개의 성분이 혼합된 액상의 조성물이 구비되되
상기 조성물에는,
폴리디메틸실록산 45 ~ 65wt%, 디오가노 폴리실록산(액상) 20 ~ 35wt%, 촉매제 0.01 ~ 0.3wt% 가 혼합된 조성물로 이루어지는 것을 특징으로 하는 경화용 액상 조성물이 구비된 실리콘캡슐.
In the silicone capsule for a liquid that the film is ruptured by an external force and the liquid in the interior flows to the outside and the liquid is cured over time,
A liquid composition in which a plurality of components are mixed is provided inside the silicone capsule.
In the composition,
Polydimethylsiloxane 45 ~ 65wt%, diorgano polysiloxane (liquid phase) 20 ~ 35wt%, a silicone capsule with a liquid composition for curing, characterized in that consisting of a composition containing a catalyst 0.01 ~ 0.3wt%.
상기 조성물에 폴리 아크릴산 나트륨 1 ~ 1.2wt%, 실리콘오일 8 ~ 20wt%, 메틸옥시미노실란(methyl oximino silane : MOS) 1.5 ~ 8wt%, 비닐옥시미노실란(vinyl oximino silane : VOS) 0.2 ~ 3wt%, 연무질 실리카 2 ~ 15wt%, 아미노실란 0.2 ~ 3wt% 가 혼합된 제 1조성물이 포함되는 것을 특징으로 하는 경화용 액상 조성물이 구비된 실리콘캡슐.
According to claim 1,
Sodium polyacrylate 1 to 1.2 wt%, silicone oil 8 to 20 wt%, methyl oximino silane (MOS) 1.5 to 8 wt%, vinyl oximino silane (VOS) 0.2 to 3 wt% in the composition , Silicone capsule with a liquid composition for curing, characterized in that the first composition containing aerosol silica 2 ~ 15wt%, aminosilane 0.2 ~ 3wt% mixed.
상기 실리콘캡슐(10)의 피막(100)은 다수개의 성분이 혼합된 혼합물로 제조되되
나일론 50 ~ 70% 중량부와, MWNT(Multi-Walled Nano Tube. 이하 '다층나노튜브'라함.) 2 ~ 4%(0.1g/㎖) 중량부와, 산화방지제 0.2% 중량부 및 분산제 1 ~ 5% 중량부가 혼합된 혼합물을 가공, 압출하여 제조되는 것을 특징으로 하는 경화용 액상 조성물이 구비된 실리콘캡슐.
According to claim 1,
The film 100 of the silicone capsule 10 is made of a mixture of a plurality of components
50 to 70% by weight of nylon, MWNT (Multi-Walled Nano Tube. Hereinafter referred to as'multilayer nanotube') 2 to 4% (0.1 g/ml) by weight, antioxidant 0.2% by weight and dispersant 1 to A silicone capsule with a liquid composition for curing, which is prepared by processing and extruding a mixture of 5% parts by weight.
상기 혼합물에는 불포화 카르복실산 화합물의 공중합체로 이루어진 스티렌계수지 8 ~ 20% 중량부와, 폴리에테르에스테르 수지 10 ~ 15% 중량부와, 폴리에틸렌글리콜-디아크릴레이트를 친수성 단량체로 하는 화합물 3 ~ 7% 중량부 및 플루오르 화합물 0.3 ~ 0.5%중량부가 혼합된 제 1혼합물이 포함되는 것을 특징으로 하는 경화용 액상 조성물이 구비된 실리콘캡슐.
According to claim 3,
The mixture contains 8 to 20% by weight of a styrene-based resin composed of a copolymer of an unsaturated carboxylic acid compound, 10 to 15% by weight of a polyether ester resin, and 3 to 3 of polyethylene glycol-diacrylate as a hydrophilic monomer. A silicone capsule with a liquid composition for curing, comprising a first mixture in which 7% by weight and 0.3 to 0.5% by weight of fluorine compound are mixed.
상기 실리콘캡슐(10)은 원형 또는 다각형 또는 하나 이상의 중공부가 형성된 원형 또는 하나 이상의 중공부가 형성된 다각형으로 형성되는 것을 특징으로 하는 경화용 액상 조성물이 구비된 실리콘캡슐.
According to claim 1,
The silicone capsule 10 is a silicone capsule with a liquid composition for curing, characterized in that it is formed of a circular or polygonal or a circular or polygonal formed with one or more hollows.
상기 실리콘캡슐(10)의 상부 또는 하부 또는 측면부 또는 중공부가 형성된 부분에는 하나 이상의 돌출부 또는 홈부(110)가 형성되어 있는 것을 특징으로 하는 경화용 액상 조성물이 구비된 실리콘캡슐.
The method of claim 5,
The silicone capsule with a liquid composition for curing, characterized in that one or more protrusions or grooves 110 are formed in the upper or lower portion or the side portion or the hollow portion of the silicone capsule 10.
상기 실리콘캡슐(10)의 상부 또는 하부 또는 측면부 또는 중공부가 형성된 내측부분에는 2중 피막(120)으로 형성되는 것을 특징으로 하는 경화용 액상 조성물이 구비된 실리콘캡슐.
The method of claim 5,
A silicone capsule with a liquid composition for curing, characterized in that it is formed of a double coating 120 on the inner portion of the upper or lower portion or the side portion or the hollow portion of the silicone capsule 10.
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| KR20230011452A (en) * | 2021-02-10 | 2023-01-20 | 남병수 | Anchor assembly that increases the fixing force of anchor pipes using threaded threads |
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| KR20240003665A (en) | 2022-07-01 | 2024-01-09 | 이기호 | Silicone insole using the action of non-polar rubber and non-polar material |
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