KR20190110950A - square shape secondary cell battery - Google Patents
square shape secondary cell battery Download PDFInfo
- Publication number
- KR20190110950A KR20190110950A KR1020190032322A KR20190032322A KR20190110950A KR 20190110950 A KR20190110950 A KR 20190110950A KR 1020190032322 A KR1020190032322 A KR 1020190032322A KR 20190032322 A KR20190032322 A KR 20190032322A KR 20190110950 A KR20190110950 A KR 20190110950A
- Authority
- KR
- South Korea
- Prior art keywords
- secondary battery
- ion
- electrode
- fullerene
- halogen
- Prior art date
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- XMWRBQBLMFGWIX-UHFFFAOYSA-N C60 fullerene Chemical class C12=C3C(C4=C56)=C7C8=C5C5=C9C%10=C6C6=C4C1=C1C4=C6C6=C%10C%10=C9C9=C%11C5=C8C5=C8C7=C3C3=C7C2=C1C1=C2C4=C6C4=C%10C6=C9C9=C%11C5=C5C8=C3C3=C7C1=C1C2=C4C6=C2C9=C5C3=C12 XMWRBQBLMFGWIX-UHFFFAOYSA-N 0.000 claims abstract description 175
- 229910003472 fullerene Inorganic materials 0.000 claims abstract description 168
- 239000003792 electrolyte Substances 0.000 claims abstract description 54
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 149
- 150000002500 ions Chemical class 0.000 claims description 101
- -1 fluoro dimethyl carbonate Chemical compound 0.000 claims description 70
- 229910021393 carbon nanotube Inorganic materials 0.000 claims description 50
- 239000002041 carbon nanotube Substances 0.000 claims description 50
- 229920000642 polymer Polymers 0.000 claims description 37
- 238000000034 method Methods 0.000 claims description 35
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 33
- 229910052736 halogen Inorganic materials 0.000 claims description 32
- 150000002367 halogens Chemical class 0.000 claims description 28
- 239000002608 ionic liquid Substances 0.000 claims description 27
- 239000011356 non-aqueous organic solvent Substances 0.000 claims description 26
- 239000011255 nonaqueous electrolyte Substances 0.000 claims description 26
- 229910021389 graphene Inorganic materials 0.000 claims description 24
- 239000007789 gas Substances 0.000 claims description 23
- 230000010287 polarization Effects 0.000 claims description 20
- 239000000203 mixture Substances 0.000 claims description 15
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 15
- 239000000126 substance Substances 0.000 claims description 14
- 125000005843 halogen group Chemical group 0.000 claims description 11
- 239000011521 glass Substances 0.000 claims description 9
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 8
- 125000000217 alkyl group Chemical group 0.000 claims description 8
- 229920006318 anionic polymer Polymers 0.000 claims description 8
- 150000001450 anions Chemical class 0.000 claims description 8
- 125000003118 aryl group Chemical group 0.000 claims description 8
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 8
- 150000003839 salts Chemical class 0.000 claims description 8
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 7
- 229920006317 cationic polymer Polymers 0.000 claims description 7
- 150000005676 cyclic carbonates Chemical group 0.000 claims description 7
- 230000002687 intercalation Effects 0.000 claims description 7
- 238000009830 intercalation Methods 0.000 claims description 7
- 229910052751 metal Inorganic materials 0.000 claims description 7
- 239000002184 metal Substances 0.000 claims description 7
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 6
- 150000005678 chain carbonates Chemical class 0.000 claims description 6
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 claims description 6
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 claims description 5
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical group COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 claims description 5
- 239000003791 organic solvent mixture Substances 0.000 claims description 5
- 229920003002 synthetic resin Polymers 0.000 claims description 5
- 239000000057 synthetic resin Substances 0.000 claims description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 4
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 4
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 4
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Natural products C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 claims description 4
- 150000001454 anthracenes Chemical class 0.000 claims description 4
- 150000001555 benzenes Chemical class 0.000 claims description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 4
- 229910052744 lithium Inorganic materials 0.000 claims description 4
- UFWIBTONFRDIAS-UHFFFAOYSA-N naphthalene-acid Natural products C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 claims description 4
- 150000002790 naphthalenes Chemical class 0.000 claims description 4
- 239000010453 quartz Substances 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- ZZXUZKXVROWEIF-UHFFFAOYSA-N 1,2-butylene carbonate Chemical compound CCC1COC(=O)O1 ZZXUZKXVROWEIF-UHFFFAOYSA-N 0.000 claims description 3
- VAYTZRYEBVHVLE-UHFFFAOYSA-N 1,3-dioxol-2-one Chemical compound O=C1OC=CO1 VAYTZRYEBVHVLE-UHFFFAOYSA-N 0.000 claims description 3
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 claims description 3
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 claims description 3
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 claims description 3
- 230000009977 dual effect Effects 0.000 claims description 3
- PMWGIVRHUIAIII-UHFFFAOYSA-N 2,2-difluoropropanoic acid Chemical compound CC(F)(F)C(O)=O PMWGIVRHUIAIII-UHFFFAOYSA-N 0.000 claims description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 2
- 229910020366 ClO 4 Inorganic materials 0.000 claims description 2
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 2
- 229910018286 SbF 6 Inorganic materials 0.000 claims description 2
- STSCVKRWJPWALQ-UHFFFAOYSA-N TRIFLUOROACETIC ACID ETHYL ESTER Chemical compound CCOC(=O)C(F)(F)F STSCVKRWJPWALQ-UHFFFAOYSA-N 0.000 claims description 2
- FWBMVXOCTXTBAD-UHFFFAOYSA-N butyl methyl carbonate Chemical compound CCCCOC(=O)OC FWBMVXOCTXTBAD-UHFFFAOYSA-N 0.000 claims description 2
- 229910052792 caesium Inorganic materials 0.000 claims description 2
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 claims description 2
- 239000011575 calcium Substances 0.000 claims description 2
- 229910052791 calcium Inorganic materials 0.000 claims description 2
- VUPKGFBOKBGHFZ-UHFFFAOYSA-N dipropyl carbonate Chemical compound CCCOC(=O)OCCC VUPKGFBOKBGHFZ-UHFFFAOYSA-N 0.000 claims description 2
- GZKHDVAKKLTJPO-UHFFFAOYSA-N ethyl 2,2-difluoroacetate Chemical compound CCOC(=O)C(F)F GZKHDVAKKLTJPO-UHFFFAOYSA-N 0.000 claims description 2
- JBTWLSYIZRCDFO-UHFFFAOYSA-N ethyl methyl carbonate Chemical compound CCOC(=O)OC JBTWLSYIZRCDFO-UHFFFAOYSA-N 0.000 claims description 2
- AEHVMUMGWLAZNV-UHFFFAOYSA-N ethyl propan-2-yl carbonate Chemical compound CCOC(=O)OC(C)C AEHVMUMGWLAZNV-UHFFFAOYSA-N 0.000 claims description 2
- CYEDOLFRAIXARV-UHFFFAOYSA-N ethyl propyl carbonate Chemical compound CCCOC(=O)OCC CYEDOLFRAIXARV-UHFFFAOYSA-N 0.000 claims description 2
- 239000011777 magnesium Substances 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- VMVNZNXAVJHNDJ-UHFFFAOYSA-N methyl 2,2,2-trifluoroacetate Chemical compound COC(=O)C(F)(F)F VMVNZNXAVJHNDJ-UHFFFAOYSA-N 0.000 claims description 2
- RCIJMMSZBQEWKW-UHFFFAOYSA-N methyl propan-2-yl carbonate Chemical compound COC(=O)OC(C)C RCIJMMSZBQEWKW-UHFFFAOYSA-N 0.000 claims description 2
- KKQAVHGECIBFRQ-UHFFFAOYSA-N methyl propyl carbonate Chemical compound CCCOC(=O)OC KKQAVHGECIBFRQ-UHFFFAOYSA-N 0.000 claims description 2
- 125000000896 monocarboxylic acid group Chemical group 0.000 claims description 2
- 229910052700 potassium Inorganic materials 0.000 claims description 2
- 239000011591 potassium Substances 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 229910052712 strontium Inorganic materials 0.000 claims description 2
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims description 2
- QOARFWDBTJVWJG-UHFFFAOYSA-N 2,2-difluoroethyl methyl carbonate Chemical compound COC(=O)OCC(F)F QOARFWDBTJVWJG-UHFFFAOYSA-N 0.000 claims 1
- KSNKQSPJFRQSEI-UHFFFAOYSA-N 3,3,3-trifluoropropanoic acid Chemical compound OC(=O)CC(F)(F)F KSNKQSPJFRQSEI-UHFFFAOYSA-N 0.000 claims 1
- QICGXQFDSUGLMM-UHFFFAOYSA-N FCC(=O)OC.C(CC)(=O)O Chemical compound FCC(=O)OC.C(CC)(=O)O QICGXQFDSUGLMM-UHFFFAOYSA-N 0.000 claims 1
- 229910052783 alkali metal Inorganic materials 0.000 claims 1
- 150000001340 alkali metals Chemical class 0.000 claims 1
- VCYZVXRKYPKDQB-UHFFFAOYSA-N ethyl 2-fluoroacetate Chemical compound CCOC(=O)CF VCYZVXRKYPKDQB-UHFFFAOYSA-N 0.000 claims 1
- 125000005842 heteroatom Chemical group 0.000 claims 1
- 229920000831 ionic polymer Polymers 0.000 claims 1
- GBPVMEKUJUKTBA-UHFFFAOYSA-N methyl 2,2,2-trifluoroethyl carbonate Chemical compound COC(=O)OCC(F)(F)F GBPVMEKUJUKTBA-UHFFFAOYSA-N 0.000 claims 1
- RWBWZPDOQVNCHU-UHFFFAOYSA-N methyl 2,2-difluoropropanoate Chemical compound COC(=O)C(C)(F)F RWBWZPDOQVNCHU-UHFFFAOYSA-N 0.000 claims 1
- MHAIQPNJLRLFLO-UHFFFAOYSA-N methyl 2-fluoropropanoate Chemical compound COC(=O)C(C)F MHAIQPNJLRLFLO-UHFFFAOYSA-N 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- 239000002585 base Substances 0.000 description 19
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 18
- 239000007983 Tris buffer Substances 0.000 description 18
- 239000003990 capacitor Substances 0.000 description 18
- 229910001416 lithium ion Inorganic materials 0.000 description 18
- JFZKOODUSFUFIZ-UHFFFAOYSA-N trifluoro phosphate Chemical compound FOP(=O)(OF)OF JFZKOODUSFUFIZ-UHFFFAOYSA-N 0.000 description 17
- 125000006340 pentafluoro ethyl group Chemical group FC(F)(F)C(F)(F)* 0.000 description 16
- ZXMGHDIOOHOAAE-UHFFFAOYSA-N 1,1,1-trifluoro-n-(trifluoromethylsulfonyl)methanesulfonamide Chemical compound FC(F)(F)S(=O)(=O)NS(=O)(=O)C(F)(F)F ZXMGHDIOOHOAAE-UHFFFAOYSA-N 0.000 description 13
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- DZLFLBLQUQXARW-UHFFFAOYSA-N tetrabutylammonium Chemical compound CCCC[N+](CCCC)(CCCC)CCCC DZLFLBLQUQXARW-UHFFFAOYSA-N 0.000 description 11
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- PXELHGDYRQLRQO-UHFFFAOYSA-N 1-butyl-1-methylpyrrolidin-1-ium Chemical compound CCCC[N+]1(C)CCCC1 PXELHGDYRQLRQO-UHFFFAOYSA-N 0.000 description 6
- IQQRAVYLUAZUGX-UHFFFAOYSA-N 1-butyl-3-methylimidazolium Chemical compound CCCCN1C=C[N+](C)=C1 IQQRAVYLUAZUGX-UHFFFAOYSA-N 0.000 description 6
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Images
Classifications
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- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0561—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of inorganic materials only
- H01M10/0563—Liquid materials, e.g. for Li-SOCl2 cells
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- H—ELECTRICITY
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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- H01M10/058—Construction or manufacture
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- H—ELECTRICITY
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0561—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of inorganic materials only
- H01M10/0562—Solid materials
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- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/133—Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/137—Electrodes based on electro-active polymers
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings, jackets or wrappings of a single cell or a single battery
- H01M50/102—Primary casings, jackets or wrappings of a single cell or a single battery characterised by their shape or physical structure
- H01M50/103—Primary casings, jackets or wrappings of a single cell or a single battery characterised by their shape or physical structure prismatic or rectangular
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/002—Inorganic electrolyte
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0025—Organic electrolyte
- H01M2300/0028—Organic electrolyte characterised by the solvent
- H01M2300/0037—Mixture of solvents
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0025—Organic electrolyte
- H01M2300/0045—Room temperature molten salts comprising at least one organic ion
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Abstract
Description
본 발명은 각형 2차 전지에 관한 것이다. The present invention relates to a square secondary battery.
더 상세하게는, 이온이 내포된 풀러렌(Fullerene)(이하 이온내포풀러렌”이라 한다.)과 비수성 전해액을 이용한 2차 전지에 관한 것으로, 특히 기체에 전극을 설치하고, 이온내포풀러렌을 전해질로 사용하며, 이 이온내포풀러렌에 대해 분극성과 전도성을 갖는 물질로 전극을 구성한 후, 상기 이온내포풀러렌의 환원 전위 이상의 전압에서 충전이 이루어지도록 함으로써 첫째, 상기 전기화학적 메카니즘에 의한 1차 충전과 이온내포풀러렌에 의한 2차 충전 그리고 이온내포풀러렌 자체에 의한 3차 충전이 이루어지는 새로 개념의 각형 2차 전지에 관한 것이다. More specifically, the present invention relates to a secondary battery using fullerene containing ions (hereinafter referred to as ion-containing fullerene) and a non-aqueous electrolytic solution. In particular, an electrode is installed in a gas and ion-containing fullerene is used as an electrolyte. First, the electrode is composed of a material having polarity and conductivity with respect to the ion-containing fullerene, and then the charging is performed at a voltage above the reduction potential of the ion-containing fullerene. The present invention relates to a new concept square secondary battery in which secondary charging with fullerene and tertiary charging with ion-containing fullerene itself are performed.
본 발명은, 내부저항은 낮추고 용해도는 높이며, 화학 반응성이 우수한 비수성 유기용매와, 할로겐치환 방향족 탄화수소, 이온액체폴리머를 필요에 따라 포함함으로써, 첫째 에너지 밀도를 향상시키고, 둘째 인터칼레이션(Intercalation)에 의한 결합을 유도하여 충전의 지속성을 향상시켜 자연방전을 억제하고, 셋째, 용량 유지율 및 용량 회복률을 상승시킴과 아울러 전해액의 안정성을 현저히 상승시킨 각형 2차 전지에 관한 것이다. The present invention includes a non-aqueous organic solvent having low internal resistance, high solubility, and excellent chemical reactivity, a halogen-substituted aromatic hydrocarbon, and an ionic liquid polymer, as necessary, thereby improving first energy density, and second intercalation. The present invention relates to a square secondary battery that induces binding by) to improve the sustainability of charging to suppress natural discharge, and to increase capacity retention rate and capacity recovery rate, and to significantly increase stability of electrolyte solution.
또한 본 발명은, 이온내포풀러렌을 전해질로 사용함으로써, 소형화 및 경량화가 가능하고, 정사각, 직사각 등의 일반적인 전지 형태 이외에 마름모, 평행사변형, 사다리꼴 등 다양한 형태로 선택 제조가 가능하며, 범용성이 뛰어난 각형 2차 전지에 관한 것이다.In addition, the present invention, by using the ion-containing fullerene as an electrolyte, can be reduced in size and weight, and can be manufactured in various forms such as rhombus, parallelogram, trapezoid, etc. in addition to the general battery form such as square, rectangular, etc. It relates to a secondary battery.
주지하다시피 전기에너지를 저장하는 방법은 크게 두 가지로 나눌 수 있다. 첫 번째는 이온의 산화환원 반응을 이용하여 전기에너지를 화학에너지로 저장하는 전해식(Electrolytic) 방법이고, 두 번째는 두 전극 사이의 분극 현상을 이용하여 전기에너지를 전기에너지 자체로 저장하는 정전기식(Electrostatic) 방법이다.As is well known, there are two ways to store electrical energy. The first is an electrolytic method of storing electrical energy as chemical energy by using the redox reaction of ions. The second is an electrostatic method of storing electrical energy as electric energy by using a polarization phenomenon between two electrodes. (Electrostatic) method.
납축전지, 니켈카드뮴 전지, 니켈수소 전지, 리튬이온폴리머 전지 등과 같은 2차 전지는 화학에너지와 전기에너지 사이의 가역적인 상호 변환을 통해 충전과 방전을 반복하여 재사용할 수 있도록 하는 첫 번째 전해식 저장방법의 예이고, 커패시터는 두 극판 사이의 분극현상을 이용하여 충전과 방전을 반복하여 재사용할 수 있도록 하는 두 번째 정전기식 저장방법의 예이다.Secondary batteries such as lead acid batteries, nickel cadmium batteries, nickel hydrogen batteries, and lithium ion polymer batteries are the first electrolytic storage that can be repeatedly reused for charging and discharging through reversible interconversion between chemical and electrical energy. This is an example of a method, and a capacitor is an example of a second electrostatic storage method that allows the charge and discharge to be reused repeatedly by using polarization between two pole plates.
전기에너지와 화학에너지 사이의 가역적인 산화환원 반응을 통해 충전과 방전을 반복하는 전해식 배터리는, 에너지 밀도가 높아 대용량의 에너지를 저장할 수 있다는 장점이 있는 반면, 전기에너지와 화학에너지 사이의 상호 변환 시 에너지 변환 손실이 발생하고, 열이 발생하며, 화재 및 폭발 위험이 있고, 대용량의 에너지를 짧은 시간 안에 충전 및 방전할 수 없어 충전 시간이 길어짐은 물론, 충전이 어렵고, 방전 특성이 저하되며, 수명이 짧고, 공해물질을 배출시킨다는 단점이 있다.Electrolytic batteries that repeat charging and discharging through reversible redox reactions between electrical and chemical energy have the advantage that they can store large amounts of energy due to their high energy density, while converting between electrical and chemical energy. Energy conversion loss occurs, heat is generated, there is a risk of fire and explosion, the large amount of energy can not be charged and discharged in a short time, the charging time is long, charging is difficult, discharge characteristics are deteriorated, It has a short life and has the disadvantage of emitting pollutants.
전기에너지를 전기에너지 그 자체로 저장하여 충전과 방전을 반복하는 커패시터는, 충전과 방전 시 에너지 변환 손실이 없고, 열이 발생하지 않으며, 폭발 위험이 없고, 수명이 무제한에 가깝도록 길며, 순간 충전 및 순간 방전이 가능하고, 공해물질 배출이 없다는 장점이 있는 반면, 에너지 밀도가 낮아 대용량의 에너지를 저장할 수 없다는 단점이 있다. 따라서 화학배터리의 장점과 커패시터의 장점을 모두 가지면서도 단점은 없앤 에너지 저장장치에 대한 연구가 지속적으로 이루어져 왔다.Capacitors that store electrical energy as electrical energy itself and repeat charging and discharging have no energy conversion loss during charging and discharging, no heat generation, no risk of explosion, and have a long service life with almost unlimited lifetime. And instantaneous discharge is possible, and there is an advantage that there is no pollutant discharge, while low energy density has a disadvantage that can not store a large amount of energy. Therefore, research on energy storage devices having both the advantages of chemical batteries and the advantages of capacitors, but without the disadvantages, has been continuously conducted.
기술이 발전함에 따라 커패시터의 에너지 밀도를 현저하게 높인 슈퍼커패시터가 개발되어 화학배터리의 장점과 커패시터의 장점을 모두 갖는 대용량의 충전이 가능하게 되었다.As technology has advanced, supercapacitors have been developed that significantly increase the energy density of capacitors, enabling large-capacity charging with both the advantages of chemical batteries and capacitors.
슈퍼커패시터는 화학반응을 이용하는 전해식 배터리와는 달리, 단위 셀 전극의 양단에 전압을 인가하면 전해액 내의 이온들이 전기장을 따라 이동되고, 이동된 이온이 전극 표면에 흡착되어 전하가 축전되는 전기화학적 메커니즘을 이용하는 것으로, 전해식 또는 정전기식과 구분하여 전기화학식 커패시터(Electrochemacal capacitor)라고도 한다. 이러한 슈퍼커패시터는 전극과 전해질 계면으로의 단순한 이온의 이동이나 표면화학반응에 의한 충전현상을 이용하므로, 급속 충방전이 가능하고, 높은 충방전 효율 및 반영구적인 사이클 수명이 가능하며, 전해식 배터리보다 100배 이상의 고출력이 가능하고 환경친화적이어서 전기자동차, 휴대전화, 카메라 플래시, 드론 등의 차세대 에너지저장장치로 각광받고 있다. 슈퍼커패시터는 사용되는 전극 및 메커니즘에 따라 전기이중층 커패시터(Electric Double Layer Capacitor: ELDC), 유사 커패시터(Pseudo Capacitor), 하이브리드 커패시터(Hybrid capacitor) 등으로 구분된다. Unlike electrolytic batteries that use chemical reactions, supercapacitors are electrochemical mechanisms whereby voltages across the unit cell electrodes move along the electric field, and the transferred ions are adsorbed on the electrode surface to accumulate charge. It is also referred to as an electrochemical capacitor (Electrochemacal capacitor) separately from the electrolytic or electrostatic. These supercapacitors use simple ions to move between the electrode and the electrolyte or charge by surface chemical reactions, so they can be rapidly charged and discharged, have high charge and discharge efficiency, and semi-permanent cycle life. It is capable of more than 100 times higher power and is environmentally friendly, making it the next generation energy storage device for electric vehicles, mobile phones, camera flashes, and drones. Supercapacitors are classified into Electric Double Layer Capacitors (ELDC), Pseudo Capacitors, and Hybrid Capacitors according to the electrodes and mechanisms used.
전기이중층 커패시터는 전극 양단에 전위차가 가해지면 두 전극 각각에 양전하(+)와 음전하(-)가 모이고 이로 인해 전해질 내에서 각각의 전극 주위에 반대되는 전하 이온들이 모여 전기적 이중층을 형성하여 이온의 저장이 일어나는 현상을 이용한 것으로, 다공성 전극(Electrode), 전해질(Electrolyte), 집전체(Current Collector), 분리막(Separator) 및 케이스 등을 기본 구조로 하고 있다. In the electric double layer capacitor, when a potential difference is applied across the electrodes, positive and negative charges are collected at each of the two electrodes, and as a result, charge ions opposite to each electrode in the electrolyte are collected to form an electrical double layer to store ions. This phenomenon is used as a basic structure of a porous electrode (Electrode), an electrolyte (Electrolyte), a current collector (Current Collector), a separator (Separator) and the case.
유사 커패시터는 전극과 전기화학 산화물 반응물의 산화환원 반응을 이용하는 커패시터로, 전기 이중층 커패시터가 전극 표면에 형성된 이중층에만 전하를 저장하는 데 비하여 전극 재료의 표면 근처까지 전하를 저장할 수 있어 높은 에너지 밀도를 갖도록 한 커패시터이다.Pseudocapacitors are capacitors that use redox reactions of electrodes and electrochemical oxide reactants, and they can store charge near the surface of the electrode material as compared to the double layer formed on the electrode surface. One capacitor.
하이브리드 커패시터는 양극과 음극에 작동전압 영역 및 비축전용량이 서로 다른 비대칭전극을 사용함으로써, 한쪽 전극은 고용량 특성의 전극재료를 사용하고, 다른 전극은 고출력 특성의 전극재료를 사용하여 용량 특성을 개선한 것으로, 고출력 특성 손실을 최소화하고, 높은 작동 전압 및 높은 에너지 밀도를 갖도록 한 커패시터이다. Hybrid capacitors use asymmetric electrodes with different operating voltage ranges and specific capacitances for the positive and negative electrodes, so that one electrode uses high-capacity electrode materials and the other uses high-output electrode materials to improve capacitance characteristics. It is a capacitor which minimizes a high output characteristic loss and has high operating voltage and high energy density.
슈퍼커패시터의 용량을 더욱 증가시키고 충방전 특성을 개선시키기 위해 넓은 표면적과 높은 전도성 및 전기화학적 안정성을 갖는 전극물질과 전해질에 대한 연구가 지속적으로 이루어져 왔다.In order to further increase the capacity of supercapacitors and to improve the charge and discharge characteristics, researches on electrode materials and electrolytes having a large surface area, high conductivity, and electrochemical stability have been continuously conducted.
전극의 비표면적을 높이기 위한 전극재질 중 많은 주목을 받는 탄소전극재질로는 활성탄(Active carbon), 활성탄소섬유(Active carbon fiber), 비정질탄소(Glassy carbon), 탄소에어로젤(Carbon aerogel), 그래핀(Graphene), 탄소나노튜브(Carbon nanotube)와 같은 것이 있으며, 이러한 전극의 비표면적을 더욱 높이기 위해 다양한 방법의 가공이 이루어지고 있다. 활성탄의 경우 2~50nm의 세공과 1,000~3,000/g의 표면적을 가지며, 전기전도도가 높고 성형이 용이하여 많이 사용된다.Among the electrode materials to increase the specific surface area of the electrode, the carbon electrode materials attracting much attention include active carbon, active carbon fiber, amorphous carbon, carbon aerogel, and graphene. (Graphene) and carbon nanotubes (Carbon nanotube) and the like, and to increase the specific surface area of these electrodes, various methods of processing are made. Activated carbon has a pore size of 2 to 50 nm and a surface area of 1,000 to 3,000 / g, and is widely used because of its high electrical conductivity and easy molding.
슈퍼커패시터의 전해질은 수용성과 비수용성(유기성)으로 구분되는데, 수용성 전해질의 경우에는 출력특성이 높은 반면 에너지 밀도가 낮다는 특징이 있으며, 유기성 전해질의 경우에는 저항특성이 낮은 반면 에너지밀도가 높다는 특징이 있다. 이러한 전해질은 용매와 용질에 따라 그 특성이 달라지며 용매의 내부저항 특성과, 용해도 특성 및 화학반응 속도를 고려하여 많은 연구가 이루어지고 있다.The supercapacitor electrolytes are classified into water-soluble and non-water-soluble (organic), which is characterized by high output characteristics and low energy density in the case of water-soluble electrolytes, and low energy density and high energy density in organic electrolytes. There is this. The characteristics of the electrolyte vary depending on the solvent and the solute, and many studies have been conducted in consideration of the internal resistance, the solubility, and the chemical reaction rate of the solvent.
기술이 더욱 발전함에 따라 그래핀과 탄소나노튜브를 전극으로 사용할 수 있게 됨으로써 슈퍼커패시터의 용량이 더욱 커지고 특성이 향상되었다. As technology advances, it is possible to use graphene and carbon nanotubes as electrodes, thereby increasing the capacity of supercapacitors and improving their characteristics.
그래핀은 탄소가 육각형의 형태로 서로 연결되어 벌집 모양의 2차원 평면 구조를 이루는 물질이며, 탄소나노튜브는 탄소 6개로 이루어진 육각 모양이 서로 연결되어 관 모양을 이루고 있는 것으로 합성 조건에 따라 관의 지름을 다르게 할 수 있다. 대한민국 특허출원 제10-2015-7006745호 높은 분산성의 그래핀 조성물, 그의 제조방법 및 높은 분산성의 그래핀 조성물을 함유하는 리튬 이온 이차 배터리의 전극, 대한민국 특허등록 제10-1486658호 고성능 슈퍼커패시터 전극을 위한 그래핀 기반 전극재료 및 이를 포함하는 슈퍼커패시터에는 그래핀을 전극으로 사용하는 기술에 대한 일례가 기술되어 있으며, 대한민국 특허출원 제10-2013-7033691호 탄소나노튜브 기반 전극 및 재충전 가능한 배터리, 대한민국 특허등록 제10-1600185호 배터리용 전극 및 그 제조방법에는 탄소나노튜브를 전극으로 사용하는 기술에 대한 일례가 기술되어 있다.Graphene is a material in which two carbons are connected to each other in a hexagonal shape to form a honeycomb two-dimensional planar structure. Carbon nanotubes are formed by connecting six hexagonal shapes consisting of six carbons to each other to form a tubular shape. The diameter can be different. Korea Patent Application No. 10-2015-7006745 No. of the high dispersible graphene composition, its manufacturing method and electrode of a lithium ion secondary battery containing a high dispersible graphene composition, Korean Patent Registration No. 10-1486658 high performance supercapacitor electrode The graphene-based electrode material and a supercapacitor including the same are described as an example of a technique using graphene as an electrode, and Korean Patent Application No. 10-2013-7033691 Carbon Nanotube-Based Electrode and Rechargeable Battery, Korea Patent No. 10-1600185 discloses an example of a technique for using a carbon nanotube as an electrode for a battery electrode and a manufacturing method thereof.
나노 기술의 발전과 탄소 재질에 대한 연구가 심화됨에 따라 탄소의 다른 존재 형태인 풀러렌이 발견되어 슈퍼커패시터에 응용되고 있다.As nanotechnology advances and studies on carbon materials are intensified, fullerenes, which are other forms of carbon, have been discovered and applied to supercapacitors.
풀러렌은 탄소 5개가 모인 5각형과 탄소 6개가 모인 6각형이 공 모양의 구체 형상으로 결합되어 중공(中空)을 형성하고 있는 것으로, 사용된 탄소 수에 따라 다양한 형태의 풀러렌이 있다. C60, C70, C72, C78, C82, C90, C94, C96 등과 같은 풀러렌이 있으며, 이보다 더 큰 탄소 수를 갖는 것도 있다. 이러한 풀러렌은 그 구조적 형태에 있어서, 축구공의 형상을 갖거나, 축구공과 유사한 구체 등의 형상으로서, 중공 상의 구조적 특성을 갖는다.Fullerene is a pentagon of five carbons and a hexagon of six carbons combined in a spherical spherical shape to form a hollow, and there are various forms of fullerenes depending on the number of carbons used. There are fullerenes such as C60, C70, C72, C78, C82, C90, C94, C96 and the like, and some have larger carbon numbers. Such fullerenes have the shape of a soccer ball in the structural form thereof, or have the shape of a sphere similar to a soccer ball, and have hollow structural properties.
풀러렌은 이와 같은 탄소 고리 배열 및 중공 상의 특이한 구조 등으로 인해, 뛰어난 물리적 및 화학적 성질을 갖는다. 구체적으로, 강력한 항산화성, 흡착성, 촉매성(흡착된 물질의 분해성), 전자기파 흡수성, 전기 전도성, 및 경우에 따라서는 다이아몬드보다 높은 강도 등의 여러 가지 유용한 물리적 및 화학적 성질을 가지고 있어 그 응용 가치가 높다. Fullerenes have excellent physical and chemical properties due to such carbon ring arrangement and unique structure of the hollow phase. Specifically, it has many useful physical and chemical properties such as strong antioxidant properties, adsorption properties, catalytic properties (decomposability of adsorbed materials), electromagnetic wave absorption properties, electrical conductivity, and sometimes higher strength than diamond. high.
풀러렌은 카본 블랙이나 흑연을 원료로 하여 아크 방전법이나 연속 연소법 등을 통해 인공적으로 만들거나, 천연 광물로부터 추출하여 만든다. 대한민국 등록특허 10-1515534호 전극 소재용 풀러렌의 제조방법에는 풀러렌 또는 이와 유사한 구조의 유사 풀러렌을 함유하는 규산염과 같은 천연광물로부터 전기화학적 방법이나 극성용매추출 방법 등을 사용하여 풀러렌을 제조하는 방법이 제시되어 있다.Fullerene is made of carbon black or graphite as an raw material, either artificially by the arc discharge method or continuous combustion method, or extracted from natural minerals. The method for producing fullerene for electrode material is a method for producing fullerene using an electrochemical method or a polar solvent extraction method from natural minerals such as silicates containing fullerenes or similar fullerenes of similar structure. Presented.
여러 종류의 풀러렌 중 20개의 6각형과 12개의 5각형으로 이루어진 축구공 모양의 C60은 유클리드 공간에 존재할 수 있는 가장 대칭성이 좋은 분자로 평가받고 있다. 이러한 C60은 그 구조적 특징에 의해 나노 베어링이라고 불릴 정도로 물리적, 화학적으로 안정되어 있으며, 이동이 쉽다는 특징이 있다.Of the various fullerenes, the soccer ball-shaped C60, consisting of 20 hexagons and 12 pentagons, is considered the most symmetrical molecule that can exist in Euclidean space. The C60 is physically and chemically stable and is easy to move because of its structural characteristics, called a nano bearing.
최근에는 이러한 풀러렌의 특징을 슈퍼커패시터에 이용함으로써 슈퍼커패시터의 용량을 증가시키고 특성을 향상시키고자 하는 연구들이 지속되고 있다. 대한민국 특허등록 제10-0773585호 연료전지용 전극의 제조 방법에는 풀러렌을 이용한 연료전지가 제시되어 있고, 대한민국 특허등록 제10-1251635호 풀러렌 기반 이차 전지 전극들은 풀러렌 물질은 n100인 Cn의 카본 성분을 갖는 것으로 배터리용 전극 기술이 제시되어 있다.Recently, studies on increasing the capacity and improving the characteristics of supercapacitors by using the characteristics of fullerenes in supercapacitors have been continued. A fuel cell using a fullerene is proposed in the method of manufacturing a fuel cell electrode of Korea Patent Registration No. 10-0773585, and a Korean Patent Registration No. 10-1251635 fullerene-based secondary cell electrodes have a carbon component of Cn having a fullerene material of n100. Electrode technology for batteries has been proposed.
그러나 상기와 같은 종래 기술들은 전극의 표면적을 넓히기 위해 활성탄이나 그래핀, 또는 탄소나노튜브나 풀러렌의 조성물을 전극물질로 이용하고, 넓어진 전극의 표면적을 이용하여 슈퍼커패시터의 용량 및 특성을 개선시켜 왔으나, 슈퍼커패시터의 특성을 향상시키는 중요한 부분인 전해질에 대한 연구와 다른 구조적 연구는 만족할만한 진전이 이루어지지 않아 슈퍼커패시터의 특성 향상에 한계점으로 작용된다는 문제점 등이 있었다.However, the prior art as described above has been using the composition of activated carbon, graphene, carbon nanotubes or fullerene as the electrode material to increase the surface area of the electrode, and improved the capacity and characteristics of the supercapacitor by using the surface area of the electrode However, studies on electrolytes and other structural studies, which are important parts to improve the characteristics of supercapacitors, have been problematic in that satisfactory progress has been made, which is a limitation in improving the characteristics of supercapacitors.
또한, 종래의 기술들은 파워 밀도가 낮아 에너지 충전 용량이 저하됨은 물론, 충전 지속시간이 짧아 자연방전으로 인한 손실이 크다는 문제점 등이 있었다.In addition, the conventional techniques have a problem that the loss of energy charge capacity is low, as well as the charge duration is short, so that the loss due to natural discharge is large.
본 발명은 이와 같은 종래의 문제점을 감안하여 이루어진 것으로, 그 목적은 이온내포풀러렌을 전해질로 사용하며, 이 이온내포풀러렌에 대해 분극성과 전도성을 갖는 물질로 전극을 구성한 후, 상기 이온내포풀러렌의 환원 전위 이상의 전압에서 충전이 이루어지도록 함으로써 첫째, 상기 전기화학적 메카니즘에 의한 1차 충전과 이온내포풀러렌에 의한 2차 충전 그리고 이온내포풀러렌 자체에 의한 3차 충전이 이루어져 충전 용량이 비약적으로 증가된 각형 2차 전지를 제공하는 데 있다.The present invention has been made in view of such a conventional problem, and an object thereof is to use ion-encapsulated fullerene as an electrolyte, and to form an electrode with a material having polarization and conductivity with respect to the ion-containing fullerene, followed by reduction of the ion-containing fullerene. First, charging is performed at a voltage higher than the potential. First, the first charging by the electrochemical mechanism, the second charging by ion-containing fullerene, and the third charging by the ion-containing fullerene itself are performed. To provide a car battery.
또한 본 발명은 내부저항은 낮추고 용해도는 높이며, 화학 반응성이 우수한 비수성 유기용매와, 할로겐치환 방향족 탄화수소, 이온액체폴리머를 필요에 따라 포함함으로써, 첫째 에너지 밀도를 향상시키고, 둘째 인터칼레이션(Intercalation)에 의한 결합을 유도하여 충전의 지속성을 향상시켜 자연방전을 억제하고, 셋째, 용량 유지율 및 용량 회복률을 상승시킴과 아울러 전해액의 안정성을 현저히 상승시킨 2차 전지를 제공하는데 있다. In addition, the present invention includes a non-aqueous organic solvent having low internal resistance, high solubility, and excellent chemical reactivity, halogen-substituted aromatic hydrocarbons, and ionic liquid polymers as necessary, thereby improving first energy density, and second intercalation. In order to improve the sustainability of the charge by inducing the bond by the) to suppress the natural discharge, and third, to increase the capacity retention rate and capacity recovery rate, and to provide a secondary battery significantly increased the stability of the electrolyte.
또 본 발명은, 이온내포풀러렌을 전해질로 사용함으로써, 소형화 및 경량화가 가능하고, 정사각, 직사각 등의 일반적인 전지 형태 이외에 마름모, 평행사변형, 사다리꼴 등 다양한 형태로 선택 제조가 가능하며, 범용성이 뛰어난 각형 2차 전지를 제공하는데 있다. In addition, the present invention can be miniaturized and reduced in weight by using ion-containing fullerene as an electrolyte, and can be selectively manufactured in various forms such as rhombus, parallelogram, and trapezoid in addition to general battery forms such as square and rectangular, and have excellent versatility. It is to provide a secondary battery.
나아가 본 발명은 자동차는 물론이고 휴대 전화, 노트북, PDA 등과 같은 IT 제품, 조명, 각종 전자 제품 및 기계 기구 장치 등 다양한 용처에 사용될 수 있는 범용성이 뛰어난 각형 2차 전지를 제공하는 데 있다. Furthermore, the present invention provides a rectangular battery having excellent general purpose that can be used in various applications such as automobiles, IT products such as mobile phones, laptops, PDAs, lighting, various electronic products, and mechanical devices.
본 발명은, 각형으로 이루어진 2차 전지로써, 사각의 육면체로 구성되는 기체; 상기 기체의 내부에 구비되는 음극집전체와 양극집전체; 상기 각 집전체에 접합 또는 성장되는 전극; 상기 전극 사이에 충진되는 이온내포풀러렌으로 이루어진 전해질;로 구성된 것을 포함하는 특징이 있다.The present invention is a rectangular secondary battery, a gas consisting of a square hexahedron; A negative electrode current collector and a positive electrode current collector provided inside the gas; Electrodes bonded or grown on the respective current collectors; It is characterized in that it comprises a; consisting of an electrolyte consisting of ion-encapsulated fullerene filled between the electrodes.
또한 본 발명은 각형으로 이루어진 2차 전지로써, 사각의 육면체로 구성되는 기체; 상기 기체의 내부에 구비되는 진공 챔버; 상기 진공 챔버의 내면 또는 외면에 접합되는 양극집전체와 음극집전체로 구성된 집전체; 상기 각 집전체에 접합 또는 성장되는 전극; 상기 전극 사이에 충진되는 이온내포풀러렌으로 이루어진 전해질;로 구성된 것을 포함하는 것이다.In addition, the present invention is a rectangular secondary battery consisting of a gas consisting of a square hexahedron; A vacuum chamber provided inside the gas; A current collector including a positive electrode current collector and a negative electrode current collector bonded to an inner surface or an outer surface of the vacuum chamber; Electrodes bonded or grown on the respective current collectors; It comprises a; consisting of an electrolyte consisting of ion-encapsulated fullerenes filled between the electrodes.
본 발명의 상기 음극집전체와 양극집전체 중 어느 하나에 탄소나노튜브를 성장시켜 전극으로 구성하고, 대향측 집전체에 활성탄 전극이 구비되도록 하되, 상기 탄소나노튜브 전극에 이온내포풀러렌이 주입된 것을 포함하는 특징이 있다. Carbon nanotubes are grown on one of the negative electrode current collector and the positive electrode current collector of the present invention to form an electrode, and an active carbon electrode is provided on the opposite current collector, and the iontophore fullerene is injected into the carbon nanotube electrode. It is characterized by including.
본 발명은 첫째, 전기화학적 메카니즘에 의한 1차 충전과 이온내포풀러렌에 의한 2차 충전 그리고 이온내포풀러렌 자체에 의한 3차 충전이 이루어져 충전 용량을 비약적으로 향상시키며, 충전 특성 및 방전 특성을 향상시킬 수 있는 효과가 있는 발명이다. The present invention is first, the first charge by the electrochemical mechanism, the second charge by the ion-containing fullerene and the third charge by the ion-containing fullerene itself is made to dramatically improve the charging capacity, improve the charging characteristics and discharge characteristics It is an invention that can be effective.
둘째 본 발명은 내부저항은 낮추고 용해도는 높이며, 화학 반응성이 우수한 비수성 유기용매와, 할로겐치환 방향족 탄화수소, 이온액체폴리머를 필요에 따라 포함함으로써, 에너지 밀도를 향상시키고, 인터칼레이션(Intercalation)에 의한 결합을 유도하여 충전의 지속성을 향상시켜 자연방전을 억제하고, 용량 유지율 및 용량 회복률을 상승시키는 효과가 있다. Secondly, the present invention includes a non-aqueous organic solvent having low internal resistance, high solubility, and excellent chemical reactivity, halogen-substituted aromatic hydrocarbons and ionic liquid polymers as necessary, thereby improving energy density and improving intercalation. By inducing binding by improving the durability of the charge to suppress the natural discharge, there is an effect of increasing the capacity retention rate and capacity recovery rate.
셋째 본 발명은 자동차는 물론 휴대 전화, 노트북, PDA 등과 같은 IT 제품, 조명, 각종 전자 제품 및 기계 기구 장치 등에 다양한 용처에 사용될 수 있는 범용성이 뛰어난 각형 2차 전지를 제조하며, 작고 가벼운 각형 2 전지를 제조할 수 있는 발명이다.Thirdly, the present invention manufactures a highly versatile rectangular secondary battery that can be used in various applications such as automobiles, IT products such as mobile phones, laptops, PDAs, lighting, various electronic products, and mechanical devices. It is an invention that can be prepared.
도 1은 본 발명에 따른 2차 전지의 사시도,
도 2는 본 발명에 따른 2차 전지의 일부를 절개한 사시도,
도 3은 본 발명에 따른 2차 전지의 내부를 보인 다른 실시 예의 평면도,
도 4는 본 발명에 따른 2차 전지의 다른 형태를 나타낸 사시도,
도 5는 본 발명에 적용되는 집전체의 다른 실시 예를 나타낸 사시도,
도 6은 본 발명의 다른 실시 예가 적용되는 2차 전지의 분해 사시도,
도 7은 본 발명의 다른 실시 예를 나타낸 사시도,
도 8a는 본 발명에 적용되는 그래핀의 구조를 나타낸 사시도,
도 8b는 본 발명에 적용되는 분극성을 갖는 그래핀 전극 형성을 위한 접합 방향을 나타낸 사시도,
도 8c는 본 발명에 적용되는 전도성을 갖는 그래핀 전극 형성을 위한 접합 방향을 나타낸 사시도,
도 9는 본 발명에 적용되는 탄소나노튜브의 키랄성을 나타낸 사시도,
도 10a는 본 발명에 적용되는 풀러렌의 결합을 나타낸 구조도,
도 10b는 본 발명에 적용되는 풀러렌의 x-y 평면상의 결합을 나타낸 구조도,
도 10c는 본 발명에 적용되는 풀러렌의 x-y 평면상의 다른 결합을 나타낸 구조도,
도 11은 본 발명에 따른 금의 밀러면을 이용한 풀러렌의 흡착 과정을 나타낸 개략도,
도 12는 본 발명에 적용되는 풀러렌의 예를 나타낸 사시도.
도 13은 본 발명에 따른 2차 전지의 확대 단면도,
도 14는 본 발명에 따른 2차 전지에 탄소나노튜브 전극이 적용된 단면도,
도 15 및 도 16은 진공챔버가 구비된 2차 전지의 단면도,
도 17 및 도 18은 본 발명에 적용되는 진공챔버의 일 예를 나타낸 단면도,
도 18은 본 발명에 따른 C60의 CV 곡선을 나타낸 그래프. 1 is a perspective view of a secondary battery according to the present invention;
2 is a perspective view of a part of the rechargeable battery according to the present invention;
3 is a plan view of another embodiment showing the inside of a secondary battery according to the present invention;
4 is a perspective view showing another form of a secondary battery according to the present invention;
5 is a perspective view showing another embodiment of the current collector applied to the present invention,
6 is an exploded perspective view of a secondary battery to which another embodiment of the present invention is applied;
7 is a perspective view showing another embodiment of the present invention;
Figure 8a is a perspective view showing the structure of a graphene applied to the present invention,
8B is a perspective view illustrating a bonding direction for forming a graphene electrode having polarization applied to the present invention;
Figure 8c is a perspective view showing the bonding direction for forming a conductive graphene electrode applied to the present invention,
9 is a perspective view showing the chirality of the carbon nanotubes applied to the present invention,
Figure 10a is a structural diagram showing the bond of fullerenes applied to the present invention,
Figure 10b is a structural diagram showing the bond on the xy plane of the fullerene applied to the present invention,
Figure 10c is a structural diagram showing another bond on the xy plane of the fullerene applied to the present invention,
11 is a schematic diagram showing the adsorption process of fullerene using the Miller surface of gold according to the present invention,
12 is a perspective view showing an example of a fullerene applied to the present invention.
13 is an enlarged cross-sectional view of a secondary battery according to the present invention;
14 is a cross-sectional view of a carbon nanotube electrode applied to a secondary battery according to the present invention;
15 and 16 are cross-sectional views of a secondary battery equipped with a vacuum chamber,
17 and 18 are cross-sectional views showing an example of a vacuum chamber applied to the present invention,
18 is a graph showing the CV curve of C60 according to the present invention.
본 발명을 실시 예들을 설명함에 있어서, 동일부호는 동일한 구성을 의미하고, 중복되거나 발명의 의미를 한정적으로 해석되게 할 수 있는 부가적인 설명은 본 발명의 실시 예들을 설명함에 있어서 생략될 수 있다.In the following description of the embodiments, the same reference numerals refer to the same configuration, and additional descriptions that may be duplicated or limited in meaning of the invention may be omitted in describing the embodiments of the present invention.
구체적인 설명에 앞서, 본 명세서상에 비록 단수적 표현으로 기재되어 있을지라도 국어 사용에 있어서 단수/복수를 명확하게 구분 짓지 않고 사용되는 환경과 당해 분야에서의 통상적인 용어 사용 환경에 비추어, 발명의 개념에 반하지 않고 해석상 모순되거나 명백하게 다르게 뜻하지 않는 이상 복수의 표현을 포함하는 의미로 사용된다. 또한, 본 명세서에 기재되었거나 기재될 수 있는 '포함한다', '갖는다', '구비한다', '포함하여 이루어진다' 등은 하나 또는 그 이상의 다른 특징이나 구성요소 또는 그들 조합의 존재 또는 부가 가능성을 미리 배제하지 않는 것으로 이해되어야 한다.Prior to the detailed description, the concept of the invention, in spite of the singular form of the present disclosure, in light of the circumstances in which the singular / plural is not clearly distinguished in the use of Korean language and the general terminology used in the art. It is used in the sense that it includes plural expressions unless otherwise contradictory or clearly different from each other. In addition, 'includes', 'haves', 'comprises', 'comprises', and the like, as described or described herein, may indicate the presence or addition of one or more other features or components or combinations thereof. It should be understood that it is not excluded in advance.
본 발명을 설명하기에 앞서, 본 발명에 따른 이온내포풀러렌에 대해 분극성을 갖는 전극이라 함은, 활성탄과 같이 분극을 형성하면서도 이온내포풀러렌과 전극이 물리적 결합을 하지 않는 전극을 말한다.Prior to explaining the present invention, the electrode having polarization with respect to the ion-containing fullerene according to the present invention refers to an electrode which forms a polarization like activated carbon but does not physically bond the ion-containing fullerene and the electrode.
또한, 본 발명에 있어서, 이온내포풀러렌에 대해 분극성과 전도성을 갖는 전극이라 함은, 할로젠 원소를 도핑하여 전도성을 갖도록 한 활성탄과 같이, 이온내포풀러렌이 전극과 물리적 결합을 하지 않으면서도 전극을 통해 이온내포풀러렌으로 전자 이동이 가능한 전극을 말한다. 즉, 이온내포풀러렌에 내포된 이온과 전극은 분극을 형성하지만, 이온내포풀러렌 자체에는 전극을 통해 전자의 이동이 있는 가능한 전극을 말한다. In addition, in the present invention, the electrode having polarity and conductivity with respect to the ion-containing fullerene is, like activated carbon doped with a halogen element to have conductivity, the ion-containing fullerene does not have to be physically bonded to the electrode. It refers to an electrode capable of electron transfer to the ion-containing fullerene through. In other words, the ion and the electrode contained in the ionic fullerene form a polarization, but the ion-full fullerene itself refers to an electrode capable of moving electrons through the electrode.
하나의 관점에서 본 발명은 이온내포풀러렌을 포함하는 비수성 전해액과 전극과 집전체 그리고 이들이 수용되는 기체를 포함하는 각형 2차 전진에 관한 것이다 In one aspect, the present invention is directed to a rectangular secondary advance comprising a non-aqueous electrolyte comprising iontophorus fullerene, an electrode, a current collector, and a gas containing them.
다른 관점에서 본 발명의 비수성 전해액은, 비수성 유기 용매와, 할로겐치환방향족탄화수소와 이온액체폴리머와 이온내포풀러렌을 포함하며, 이들은 내부 저항을 조절하고, 충전 방전 특성을 향상시키며, 나아가 에너지 저장 밀도 및 에너지 저장 용량을 비약적으로 향상시키며, 또한 자연방전을 억제시켜 충전의 지속성을 상승시킴으로써 용량 유지율 및 용량 회복률을 상승시키고, 전해액의 안정성을 현저히 향상시키는 효과가 있는 새로운 개념의 2차 전지에 관한 것이다. In another aspect, the non-aqueous electrolyte of the present invention comprises a non-aqueous organic solvent, a halogen-substituted aromatic hydrocarbon, an ionic liquid polymer, and an iontofullerene, which control internal resistance, improve charge discharge characteristics, and further, store energy. A new concept of a secondary battery having an effect of drastically improving density and energy storage capacity, increasing capacity retention and capacity recovery rate by suppressing natural discharge, increasing sustainability of charging, and significantly improving stability of electrolyte solution. will be.
또 다른 관점에서 본 발명은 진공챔버를 구성하고, 이 진공챔버에 집전체와 전극을 구비하며 이온내포풀러렌을 전해질로 사용하는 2차 전지에 관한 것이다. In still another aspect, the present invention relates to a secondary battery that constitutes a vacuum chamber, includes a current collector and an electrode in the vacuum chamber, and uses ion-containing fullerene as an electrolyte.
이러한 본 발명은 휴대 전화, 노트북, PDA 등과 같은 IT 제품, 조명, 각종 전자 제품 및 기계 기구 장치, 자동차 등에 사용될 수 있으며, 여기에 기재되지 않은 여러 제품에 사용될 수 있는 것은 당연한 것이다.The present invention can be used in IT products such as mobile phones, laptops, PDAs, lighting, various electronic products and mechanical devices, automobiles, and the like, and it can be used for various products not described herein.
이하 본 발명의 바람직한 실시 예를 설명한다. Hereinafter, preferred embodiments of the present invention will be described.
먼저 본 발명의 비수성 전해액을 상세히 설명한다. First, the non-aqueous electrolyte solution of the present invention will be described in detail.
비수성 전해액Non-aqueous electrolyte
하나의 관점에서 본 발명의 비수성 전해액은 (A) 이온내포 풀러렌 또는 그 염; (B) 이온액체 폴리머; (C) 비수성 유기용매; 및 (D) 할로겐 치환 방향족 탄화수소를 포함하는 것이다. In one aspect, the non-aqueous electrolyte solution of the present invention comprises (A) ion-containing fullerene or salt thereof; (B) an ionic liquid polymer; (C) a non-aqueous organic solvent; And (D) halogen substituted aromatic hydrocarbons.
다른 관점에서 본 발명은 (A) 이온내포 풀러렌 또는 그 염; (C) 비수성 유기용매; 및 (D) 할로겐 치환 방향족 탄화수소를 포함하는 비수성 전해액에 관한 것이다. In another aspect, the present invention (A) ion-containing fullerenes or salts thereof; (C) a non-aqueous organic solvent; And (D) relates to a non-aqueous electrolyte containing a halogen-substituted aromatic hydrocarbon.
나아가 본 발명의 비수성 전해액은, 하기의 유기 용매와, 이온 액체가 선택적으로 더 추가될 수 있다. Furthermore, in the non-aqueous electrolyte solution of the present invention, an organic solvent and an ionic liquid may be optionally further added.
이하 본 발명에 의한 비수성 전해액의 구성 성분을 상세하게 설명한다.Hereinafter, the component of the non-aqueous electrolyte solution by this invention is demonstrated in detail.
(A) 이온내포 풀러렌(fullerene) 또는 그 염(A) ion-containing fullerenes or salts thereof
본 발명에 있어서, 전해질에 해당하는 이온내포 풀러렌은 할로겐 치환 방향족 탄화수소의 π-π 상호작용에 의해 인터칼레이션(intercalation)함으로써 충전의 지속성을 유지하고 자연 방전을 억제하는 역할을 한다.In the present invention, the ion-containing fullerene corresponding to the electrolyte is intercalated by π-π interaction of halogen-substituted aromatic hydrocarbons, thereby maintaining the sustainability of charging and suppressing natural discharge.
풀러렌은 탄소 5개가 모인 5각형과 탄소 6개가 모인 6각형이 공 모양의 구체 형상으로 결합되어 중공을 형성하고 있는 것으로, 사용된 탄소 수에 따라 다양한 형태의 풀러렌이 있다. 예를 들어, C60, C70, C72, C76, C78, C82, C84, C90, C94, C96 등의 풀러렌이 가능하지만 20개의 6각형과 12개의 5각형으로 이루어진 C60이 가장 좋다. 이러한 C60은 그 구조적 특성에 의해 물리적 화학적으로 지극히 안정적이고, 구형 대칭성으로 이동성이 우수하여 안정성과 충방전 특성 등을 향상시킨다.Fullerene is a pentagon of five carbons and a hexagon of six carbons combined in a spherical spherical shape to form a hollow. There are various types of fullerenes depending on the number of carbons used. For example, fullerenes such as C60, C70, C72, C76, C78, C82, C84, C90, C94, and C96 are possible, but C60 consisting of 20 hexagons and 12 pentagons is best. The C60 is extremely stable physically and chemically by its structural characteristics, and has excellent mobility due to spherical symmetry, thereby improving stability and charge / discharge characteristics.
본 발명에 따른 C60 풀러렌에 내포되는 이온은 금속 이온, 특히 알칼리 금속 이온이 바람직하다. 이러한 이온으로는 리튬, 나트륨, 칼륨, 세슘, 마그네슘, 칼슘, 스트론튬 등이 있으며, 금속 이온이 내포된 풀러렌은, 풀러렌에 내포된 금속 이온에 의해 전하를 갖게 되어 두 전극 사이에 전기장이 가해졌을 경우 이동이 용이하게 된다. 금속이온이 내포된 풀러렌으로 Li+@C60(여기서, @은 내포폴리머를 의미함), Li+@C70, Li+@C76 또는 Li+@C84을 바람직하게 사용할 수 있다.The ions contained in the C60 fullerene according to the present invention are preferably metal ions, especially alkali metal ions. These ions include lithium, sodium, potassium, cesium, magnesium, calcium, strontium, and the like. When fullerenes containing metal ions are charged by metal ions contained in fullerene, an electric field is applied between the two electrodes. It is easy to move. As fullerenes containing metal ions, Li + @ C 60 (where @ means an inclusion polymer), Li + @ C 70, Li + @ C 76 or Li + @ C 84 can be preferably used.
또한, 상기 이온내포 풀러렌 염은 이온내포 풀러렌과 Cl-, Br-, F-, I-, ClO3 -, ClO4 -, BF4 -, A1Cl4-, PF6 -, SbC16 - 또는 SbF6 -으로 구성된 군에서 선택된 1종 이상의 음이온과 결합된 것을 사용할 수 있다. 이러한 음이온은 이온내포 풀러렌 또는 이온내포 풀러렌 염을 적층하였을 경우 형성되는 공극의 크기보다 작은 직경을 갖는 이온이 더욱 바람직하다. 이 때, 할로겐이 바람직하고, 특히 F-가 바람직하다. 대응되는 이온을 교환하기 위해서는 일반적으로 알려진 방법을 사용하여도 무방하다. 예를 들어, Li + @C60] [PF6 -]를 [Li + @C60] [F-]로 교체하려는 경우 다음에 나타내는 일반적으로 알려진 방법을 사용할 수 있다.Further, the ion-containing fullerene salt ion containing-fullerene and Cl -, Br -, F - , I -, ClO 3 -, ClO 4 -, BF 4 -, A1Cl4 -, PF 6 -, SbC 16 - or SbF 6 - Combined with at least one anion selected from the group consisting of. Such anions are more preferably ions having a diameter smaller than the size of the pores formed when the ion-containing fullerene or ion-containing fullerene salt is laminated. In this case, halogen is preferable, and F − is particularly preferable. In order to exchange corresponding ions, a generally known method may be used. For example, Li + @ C60] [PF 6 - a] [Li + @ C60] [ F - If you want to replace it with a] can be used a method generally known as shown in the following.
(Li + @C60] [PF6 -)+KF+18-crown-6(Li + @ C60] [PF 6 -) + KF + 18-crown-6
(Li + @C60] [F-)+(18-crown-6]K+)+PF6 -](Li + @ C60] [F -) + (18-crown-6] K +) + PF 6 -]
또 다른 방법으로는 이온 교환 수지를 이용하는 방법도 있다.Another method is to use an ion exchange resin.
한편 본 발명에 따른 C60 풀러렌의 전자운을 포함한 C60의 크기는 1.002nm이며, 주 골격은 0.704nm로 내부에 지름 0.4nm의 공간이 있다. 따라서 이 공간에 이온을 내포시킬 수 있다.On the other hand, the size of C60 including the electron cloud of C60 fullerene according to the present invention is 1.002nm, the main skeleton is 0.704nm, there is a space of 0.4nm diameter inside. Therefore, ions can be contained in this space.
본 발명에 따른 이온내포풀러렌은 아크방전법을 이용하여 만든다. 또는, 플라즈마 생성 수단을 이용하여 주입하고자 하는 이온에 에너지를 주고, 플라즈마와 자기장의 작용을 이용하여 이온내포풀러렌을 만들 수 있다. Ion-containing fullerenes according to the present invention are made using the arc discharge method. Alternatively, energy may be supplied to ions to be implanted by using plasma generating means, and ion-encapsulated fullerenes may be produced by using the action of plasma and magnetic field.
본 발명에서는 이온내포풀러렌을 사용하여 각형 2차 전지를 만들 수 있음은 물론, 이온내포풀러렌 염을 사용하여 각형 2차 전지를 만들 수도 있다. 이온내포풀러렌 염은 예를 들어, 클러스터 분해, 용해 고형물 제거, 침전, 생성 염류 제거, 공 풀러렌 제거, 원자 내포 풀러렌 양이온류 추출, 고체 석출, 고체 회수, 결정화 및, 결정을 회수하는 공정 등을 거쳐 만드는 것이다. In the present invention, the rectangular secondary battery can be made using the ion-containing fullerene, as well as the rectangular secondary battery can be made using the ion-containing fullerene salt. The ion-containing fullerene salt may be subjected to, for example, cluster decomposition, removal of dissolved solids, precipitation, removal of generated salts, removal of empty fullerenes, extraction of atomic-containing fullerene cations, solid precipitation, solid recovery, crystallization, and recovery of crystals. To make.
(B) 이온액체 폴리머(B) Ionic Liquid Polymer
본 발명에 의한 이온액체폴리머는, 충전 시 상기 이온내포풀러렌보다 먼저 반응하여 1차 충전이 이루어지고, 다음으로 풀러렌이 반응하여 2차 충전이 이루어진다. In the ionic liquid polymer according to the present invention, the primary reaction is performed by reacting before the ion-containing fullerene during charging, followed by the secondary charging by the fullerene reaction.
이온액체 폴리머는 쌍극자 타입(이중성 폴리머), 양이온성 폴리머(polycation), 음이온성 폴리머(polyanion), 공중합체(copolymer) 또는 중합체 블렌드(polymer blend)의 형태를 가질 수 있으며, 바람직하게는 음이온성 폴리머가 사용되나, 이에 한정되는 것은 아니다.The ionic liquid polymer may have the form of a dipole type (dual polymer), a cationic polymer, an anionic polymer, a copolymer or a polymer blend, preferably an anionic polymer. Is used, but is not limited thereto.
충전 시에는 이온내포폴리머가 거의 움직이지 않고 이온내포 플러렌만 움직이는데, 이는 용수철에 에너지를 축적하는 과정과 같이 복원(방전)되는 특성이 우수하고, 충전이 빠르게 이루어진다.During charging, the ion-containing polymer hardly moves but only the ion-containing fullerene moves, which is excellent in restoring (discharging) characteristics such as accumulating energy in the spring, and filling is performed quickly.
본 발명의 비수성 전해액에서, 이온액체 폴리머는, 풀러렌 100중량부에 대하여 50 ~ 300중량부, 바람직하게는 100 ~ 250 중량부, 더욱 바람직하게는 90 ~ 120 중량부일 수 있으며, 300 중량부를 초과할 경우에는 농도 조절이 어려운 문제점이 있으며, 50 중량부 미만일 경우에 충전 반응 원활하게 이루어지지 않을 수 있으며, 상당히 고가인 이온내포풀러렌의 비율이 상대적으로 높아져 바람직하지 않다.In the non-aqueous electrolyte solution of the present invention, the ionic liquid polymer may be 50 to 300 parts by weight, preferably 100 to 250 parts by weight, more preferably 90 to 120 parts by weight, more than 300 parts by weight based on 100 parts by weight of fullerene. If it is difficult to control the concentration, there is a problem in the case of less than 50 parts by weight of the filling reaction may not be made smoothly, the ratio of the ion phospho fullerene which is quite expensive is relatively high is not preferable.
본 발명에 따른 상기 이온액체 폴리머는 넓은 온도 변화(-50 내지 400℃)는 물론 압력변화에 견딜 수 있는 장점이 있고, 진공상태에서 견딜 수 있는 장점이 있으며, 전위 량을 넓힐 수도 있다.The ionic liquid polymer according to the present invention has the advantages of being able to withstand a wide temperature change (-50 to 400 ° C.) as well as a pressure change, having the advantage of being able to withstand in a vacuum, and increasing the amount of dislocation.
바람직하게는 겔 타입 또는 고체 타입으로 이루어지고, 보다 바람직하게는 양이온성 폴리머, 음이온성 폴리머 또는 이중성 폴리머를 포함할 수 있다.It is preferably of the gel type or solid type, more preferably cationic polymer, anionic polymer or bipolar polymer.
본 발명에 있어서, 겔 또는 고체 타입의 전해질이 사용될 수 있는 것은 리튬이온내포 폴리머가 구형 대칭성으로 이루어져 있어 겔 타입의 전해질에서도 높은 운동성을 가질 수 있기 때문이다.In the present invention, the gel or solid type electrolyte can be used because the lithium ion-containing polymer is spherical symmetrical and can have high mobility even in the gel type electrolyte.
본 발명에 있어서, 이온액체 폴리머는 화학식 1 또는 화학식 2의 양이온성 폴리머와 Cl-, Br-, BF4 -, PF6 -, (CF3SO2)2N-, HPO3R11-(여기서, R11은 C1~C6알킬기) 및 COOH-로 구성된 군에서 선택된 1종 이상의 음이온이 결합되어 있는 양이온성 이온폴리머를 사용할 수 있다.In the present invention, the ionic liquid polymer is Cl and the cationic polymer of the formula (1) or the formula 2 -, Br -, BF 4 -, PF 6 -, (
[화학식 1][Formula 1]
[화학식 2][Formula 2]
화학식 1 및 2에서 R은 수소 원자, 알킬, 사이클로알킬, 알릴, 아릴 또는 알킬아릴이고, 여기서, 알킬은 C1-C6,사이클로알킬은 C3-C10,알릴은 C2-C20,아릴은 C6-C20이며, n은 5,000 내지 30,000의 정수이다.R in
또한, 상기 이온액체 폴리머는 화학식 6의 음이온성 폴리머와 R4-P+(여기서, R은 수소 원자, 알킬, 사이클로알킬, 알릴, 아릴 또는 알킬아릴이고, 여기서, 알킬은 C1-C6,사이클로알킬은 C3-C10,알릴은 C2-C20,아릴은 C6-C20임) 음이온과 결합되어 있는 음이온성 액체폴리머를 사용할 수 있다.In addition, the ionic liquid polymer is an anionic polymer of
[화학식 3][Formula 3]
화학식 3에서 n은 5,000 내지 500,000의 정수이다.N in the formula (3) is an integer of 5,000 to 500,000.
또한, 상기 이온액체 폴리머는 화학식 4의 이중성 폴리머일 수 있다.In addition, the ionic liquid polymer may be a dual polymer of formula (4).
[화학식 4][Formula 4]
화학식 4에서 A-는 SO3 - 또는 PO3H- 또는 CO2 -이고, n은 5,000 내지 300,000의 정수이다.In formula 4 A - is a SO 3 - or PO 3 H - or CO 2 -, n is an integer of from 5,000 to 300,000.
(C) 비수성 유기용매(C) non-aqueous organic solvent
본 발명에 의한 전해액에서 비수성 유기용매는 내부저항을 억제하는 역할을 한다.In the electrolyte according to the present invention, the non-aqueous organic solvent serves to suppress internal resistance.
상기 비수성 유기용매는 환형(cyclic) 카보네이트, 사슬형(chain) 카보네이트 또는 환형 카보네이트와 사슬형 카보네이트의 혼합물일 수 있으며, 바람직하게는 상기 환형 카보네이트는 상기 환형 카보네이트는 에틸렌 카보네이트(ethyl carbonate, EC), 프로필렌 카보네이트(propylene carbonate, PC), 부틸렌카보네이트(butylene carbonate, BC), 비닐렌 카보네이트(vinylene carbonate, VC), γ-부티로락톤(γ-butyrolactone) 및 이들의 혼합물로 구성된 군에서 선택되는 하나 이상의 카보네이트일 수 있으며, 바람직하게는 에틸렌 카보네이트 또는 프로필렌 카보네이트를 사용한다.The non-aqueous organic solvent may be a cyclic carbonate, a chain carbonate or a mixture of a cyclic carbonate and a chain carbonate. Preferably, the cyclic carbonate is the cyclic carbonate is ethyl carbonate (EC). Selected from the group consisting of propylene carbonate (PC), butylene carbonate (BC), vinylene carbonate (VC), γ-butyrolactone, and mixtures thereof It may be one or more carbonates, preferably ethylene carbonate or propylene carbonate.
본 발명에서 이용하는 사슬형 카보네이트로서는 디메틸카보네이트, 메틸프로필카보네이트, 메틸이소프로필카보네이트, n-부틸메틸카보네이트, 디에틸카보네이트, 에틸메틸카보네이트, 에틸프로필카보네이트, 에틸이소프로필카보네이트, 디프로필카보네이트, 플루오로디메틸카보네이트, 디플루오로디메틸카보네이트, 트리플루오로디메틸카보네이트, 테트라플루오로디메틸카보네이트, 플루오로디메틸카보네이트, 플루오로에틸메틸카보네이트, 디플루오로에틸메틸카보네이트, 트리플루오로에틸메틸카보네이트, 아세트산메틸, 아세트산에틸, 프로피온산메틸, 플루오로아세트산메틸, 디플루오로아세트산메틸, 트리플루오로아세트산메틸, 플루오로아세트산에틸, 디플루오로아세트산에틸, 트리플루오로아세트산에틸, 플루오로프로피온산메틸, 디플루오로프로피온산메틸, 트리플루오로프로피온산메틸 또는 그 혼합물을 예로 들 수 있다.Examples of the chain carbonate used in the present invention include dimethyl carbonate, methyl propyl carbonate, methyl isopropyl carbonate, n-butyl methyl carbonate, diethyl carbonate, ethyl methyl carbonate, ethyl propyl carbonate, ethyl isopropyl carbonate, dipropyl carbonate and fluorodimethyl. Carbonate, difluorodimethyl carbonate, trifluoro dimethyl carbonate, tetrafluoro dimethyl carbonate, fluoro dimethyl carbonate, fluoroethyl methyl carbonate, difluoro ethyl methyl carbonate, trifluoro ethyl methyl carbonate, methyl acetate, ethyl acetate Methyl propionate, methyl fluoroacetate, methyl difluoroacetic acid, methyl trifluoroacetic acid, ethyl fluoroacetic acid, ethyl difluoroacetic acid, ethyl trifluoroacetic acid, methyl fluoropropionate Methyl uropropionate, methyl trifluoropropionate, or mixtures thereof.
(D) 할로겐 치환 방향족 탄화수소(D) halogen substituted aromatic hydrocarbons
본 발명의 전해액에 있어서, 할로겐 치환 방향족 탄화수소는 전해질에 인터칼레이션(intercalation)이 없으며, 탄소와 할로겐 원자와 사이의 다이폴 모멘트에 의하여 파워 밀도가 생성되고 내부저항이 발생한다.In the electrolyte solution of the present invention, the halogen-substituted aromatic hydrocarbons do not have intercalation in the electrolyte, and power density is generated by the dipole moment between carbon and halogen atoms, and internal resistance is generated.
즉, 본 발명은 충전 시에는 1차로 용매의 쌍극자모멘트가 전장에서 반응하여 충전이 이루어지고, 2차로 이온내포 플러렌에 의한 충전이 이루어진다. 순식간에 형성된 π-π 결합으로 쌍극자에 의한 충전이 이루어지고, 이어서 이온내포 플러렌이 움직여 충전된다. 방전 시에는 용매의 쌍극자모멘트에 의하여 먼저 방전되고, 이후에 이온내포 플러렌에 의한 방전이 이루어진다. 이와 같이 2번의 충전이 진행되므로, 결과적으로 파워밀도가 높아지게 되는 효과가 있다.That is, in the present invention, the filling is performed by first reacting the dipole moment of the solvent in the electric field, and the filling is performed by the ion-containing fullerene in the second order. Π-π bonds formed in an instant are charged by dipoles, and then ion-containing fullerenes are moved and charged. At the time of discharge, it discharges first by the dipole moment of a solvent, and then discharges by ion-containing fullerene. Since the two charges proceed in this way, there is an effect that the power density is increased as a result.
인터칼레이션으로 기존의 EDLC가 가지고 있는 문제점, 즉 적은 용량과 짧은 지속시간의 문제점을 해결할 수 있다. 인터칼레이션은 π-π 상호작용에 의해 일어나며, π 전자가 있는 탄소재질 전극에서 발생한다.Intercalation solves the problems of existing EDLCs, namely small capacity and short duration. Intercalation occurs by π-π interactions and occurs at carbonaceous electrodes with π electrons.
본 발명에 있어서, 상기 비수성 유기용매 및 상기 할로겐 치환 방향족 탄화수소의 혼합중량 100중량부에 대하여 상기 이온액체 폴리머는 0.5 내지 50중량부이고, 상기 이온내포 플러렌은 0.5 내지 50중량부를 첨가할 수 있다.In the present invention, the ionic liquid polymer may be 0.5 to 50 parts by weight, and the ion-containing fullerene may be added to 0.5 to 50 parts by weight based on 100 parts by weight of the mixed weight of the non-aqueous organic solvent and the halogen-substituted aromatic hydrocarbon. .
본 발명에 있어서, 상기 비수성 유기용매와 상기 할로겐 치환 방향족 탄화수소의 중량비는 1:0.5~5, 바람직하게는 1:1~5, 가장 바람직하게는 1:1일 수 있다. 상기 중량비가 1: 0.5 미만일 경우에는 내부 저항을 조절하기 어려운 문제가 있고, 1:5 초과할 경우에는 농도 조절이 어려운 문제점이 있다.In the present invention, the weight ratio of the non-aqueous organic solvent and the halogen-substituted aromatic hydrocarbon may be 1: 0.5 to 5, preferably 1: 1 to 5, most preferably 1: 1. When the weight ratio is less than 1: 0.5, there is a problem that it is difficult to control the internal resistance, and when it exceeds 1: 5, there is a problem that the concentration control is difficult.
바람직한 본 발명은 할로겐 치환 방향족 탄화수소 클로로 나프탈렌과, 유기 용매 프로필렌 카보네이트가 1:1로 혼합되는 것이 가장 좋다.According to a preferred embodiment of the present invention, the halogen-substituted aromatic hydrocarbon chloro naphthalene and the organic solvent propylene carbonate are mixed in a 1: 1 ratio.
본 발명에 있어서, 상기 할로겐 치환 방향족 탄화수소는 할로겐 치환 벤젠, 할로겐 치환 나프탈렌 및 할로겐 치환 안트라센으로 구성된 군에서 선택되는 것이 바람직하다. 할로겐은 F, Cl, Br 또는 I이다. In the present invention, the halogen substituted aromatic hydrocarbon is preferably selected from the group consisting of halogen substituted benzene, halogen substituted naphthalene and halogen substituted anthracene. Halogen is F, Cl, Br or I.
상기 할로겐 치환 벤젠은 화학식 1로 표시될 수 있다.The halogen substituted benzene may be represented by the formula (1).
[화학식 5][Formula 5]
화학식 1에서 R1내지 R6는 각각 독립적으로 비치환된 C1~C6알킬기, 할로겐 또는 할로겐 원자로 치환된 C1~C6알킬기이되, 반드시 하나 이상의 할로겐이 치환된다. In formula 1 R 1 to R 6 each independently are a C 1 ~ C 6 alkyl group, a halogen or a C 1 ~ C 6 substituted with a halogen atom alkilgiyi unsubstituted, are necessarily substituted with one or more halogen.
상기 할로겐 치환 나프탈렌은 화학식 6으로 표시될 수 있다.The halogen substituted naphthalene may be represented by the formula (6).
[화학식 6][Formula 6]
화학식 2에서 R1내지 R8는 각각 독립적으로 비치환된 C1~C6알킬기, 할로겐 또는 할로겐 원자로 치환된 C1~C6알킬기이되, 반드시 하나 이상의 할로겐이 치환된다.In Formula 2 R 1 to R 8 each independently are a C 1 ~ C 6 alkyl group, a halogen or a C 1 ~ C 6 substituted with a halogen atom alkilgiyi unsubstituted, are necessarily substituted with one or more halogen.
상기 할로겐 치환 안트라센은 화학식 7로 표시될 수 있다.The halogen substituted anthracene may be represented by the formula (7).
[화학식 7][Formula 7]
화학식 3에서 R1내지 R10는 각각 독립적으로 비치환된 C1~C6알킬기, 할로겐 또는 할로겐 원자로 치환된 C1~C6알킬기이되, 반드시 하나 이상의 할로겐이 치환된다.In Formula 3 R 1 to R 10 are each independently selected from unsubstituted C 1 ~ C 6 alkyl group, a halogen or a halogen atom being substituted with C 1 ~ C 6 alkilgiyi, and be substituted one or more halogen.
바람직하게는 모노할로-벤젠(monohalo-benzene), 디할로-벤젠(dihalo-benzene), 트리할로-벤젠(trihalo-benzene), 모노할로-나프탈렌(monoharo-naphatalene), 디할로-벤젠(diharo-naphatalene) 또는 트리할로-벤젠(trihalo-naphatalene)을 사용할 수 있으며, 보다 바람직하게는 클로로벤젠(chlorobenzene), 1,2-클로로벤젠(1,2-dichlorobenzene), 1,2-3-트리클로로벤젠(1,2-3-trichlorobenzene), 1,2,4-트리클로로벤젠(1,2,4-Trichlorobenzene), 클로로나프탈렌(chloronaphthalene), 1-클로로나프탈렌(1-chloronaphatalene), 1-플루오로나프탈렌(1-fluoronaphatalene) 중 하나 또는 이들의 혼합물을 사용할 수 있다.Preferably monohalo-benzene, dihalo-benzene, trihalo-benzene, monohalo-naphatalene, dihalo-benzene (diharo-naphatalene) or trihalo-naphatalene can be used, more preferably chlorobenzene, 1,2-chlorochloro, 1,2-3 -Trichlorobenzene (1,2-3-trichlorobenzene), 1,2,4-trichlorobenzene (1,2,4-Trichlorobenzene), chloronaphthalene, 1-chloronaphatalene, 1 One or a mixture of 1-fluoronaphatalene may be used.
본 발명의 전해액에 있어서, 할로겐 치환 방향족 탄화수소는 내부 저항을 높이는 반면에, 비수성 전해액은 내부 저항을 낮추는 작용을 하는데, 이와 같이 내부 저항을 제어함으로써 충반전 특성을 제어할 수 있다. 용해도를 결정하는 할로겐 치환 방향족 탄화수소의 비율을 제어함으로써 이온내포 풀러렌이 응집되는 것을 방지하고, 효율적인 충전이 이루어지게 한다.In the electrolyte solution of the present invention, the halogen-substituted aromatic hydrocarbons increase the internal resistance, while the non-aqueous electrolyte solution lowers the internal resistance. Thus, the charge and discharge characteristics can be controlled by controlling the internal resistance. By controlling the proportion of halogen-substituted aromatic hydrocarbons that determine solubility, the agglomerate fullerenes are prevented from agglomerating and efficient filling is achieved.
본 발명에 있어서, 비수성 전해액은 상기 비수성 유기용매와, 할로겐 치환 방향족 탄화수소를 1:1로 혼합하고, 이 혼합물에 대해 이온내포풀러렌 0.1 ∼ 80중량부, 바람직하게는 0.1 ∼ 50중량부, 더욱 바람직하게는 5 ∼ 20 중량부일 수 있다. In the present invention, the non-aqueous electrolyte solution is a 1: 1 mixture of the non-aqueous organic solvent and the halogen-substituted aromatic hydrocarbon, 0.1 to 80 parts by weight, preferably 0.1 to 50 parts by weight, More preferably, it may be 5 to 20 parts by weight.
이온내포풀러렌이 0.1중량부 이하라도 충분히 충전량을 확보할 수 있지만 0.1 중량부 이하에서는 전해액의 농도를 조절하기 어렵고, 상당히 고가인 이온내포풀러렌을 80 중량부 이상을 함유하기에는 경제적인 부담이 큰 단점이 있다. Even if the amount of ion-containing fullerenes is 0.1 parts by weight or less, a sufficient amount of filling can be secured, but it is difficult to control the concentration of the electrolyte at 0.1 parts by weight or less. have.
본 발명에 있어서, 비수성 전해액은 상기 비수성 유기용매와, 할로겐 치환 방향족 탄화수소를 1:1로 혼합하고, 이 혼합물에 대해 이온내포풀러렌 0.1 ∼ 50중량부 그리고 이온 액체 폴리머 1 ∼ 50중량부가 더 포함될 수 있다.In the present invention, the non-aqueous electrolytic solution is a 1: 1 mixture of the non-aqueous organic solvent and the halogen-substituted aromatic hydrocarbon, and 0.1 to 50 parts by weight of the ionic pore fullerene and 1 to 50 parts by weight of the ionic liquid polymer are further added to the mixture. May be included.
한편 본 발명에 따른 전해액은 하기 이온 액체와, 유기 용매를 추가로 더 포함할 수 있으며, 이러한 일예로서 이온 액체로는, Meanwhile, the electrolyte according to the present invention may further include the following ionic liquid and an organic solvent, and as an example, as the ionic liquid,
1-(2-하이드록시에틸)-3-메틸이미다졸리움 테트라플루오로보레이트 (1- (2-Hydroxyethyl) -3-methylimidazolium tetrafluoroborate)1- (2-hydroxyethyl) -3-methylimidazolium tetrafluoroborate (1- (2-Hydroxyethyl) -3-methylimidazolium tetrafluoroborate)
1-(2-하이드록시에틸)-3-메틸이미다졸리움 트리스 (펜타플루오로에틸설포닐) 트리플루오로 포스페이트(1- (2-Methoxyethyl) -1-methylpyrrolidinium tris (pentafluoroethyl) trifluorophosphate)1- (2-hydroxyethyl) -3-methylimidazolium tris (pentafluoroethylsulfonyl) trifluoro phosphate (1- (2-Methoxyethyl) -1-methylpyrrolidinium tris (pentafluoroethyl) trifluorophosphate)
1-(3-시아노프로필)-3-메틸이미다졸리움 클로라이드 푸럼 (1- (3-Cyanopropyl) -3-methylimidazolium chloride purum)1- (3-cyanopropyl) -3-methylimidazolium chloride purum (1- (3-Cyanopropyl) -3-methylimidazolium chloride purum)
1-(3-시아노프로필)-3-메틸이미다졸리움 디시안아미드(1- (3-Cyanopropyl) -3-methylimidazolium dicyanamide)1- (3-cyanopropyl) -3-methylimidazolium dicyamide (1- (3-Cyanopropyl) -3-methylimidazolium dicyanamide)
1-(3-시아노프로필)-3-메틸이미다졸리움 비스(트리플루오로메틸설포닐) 이미드 (1- (3-Cyanopropyl) -3-methylimidazoliumbis- (trifluormethylsulfonyl) imid)1- (3-cyanopropyl) -3-methylimidazolium bis (trifluoromethylsulfonyl) imide (1- (3-Cyanopropyl) -3-methylimidazoliumbis- (trifluormethylsulfonyl) imid)
1-(3-시아노프로필) 피리디늄 비스 (1- (3-Cyanopropyl) pyridinium bis (trifluoromethylsulfonyl) imide) 1- (3-cyanopropyl) pyridinium bis (1- (3-Cyanopropyl) pyridinium bis (trifluoromethylsulfonyl) imide)
1-(3-시아노프로필) 피리디늄 클로라이드 (1- (3-Cyanopropyl) pyridinium chloride)1- (3-cyanopropyl) pyridinium chloride (1- (3-Cyanopropyl) pyridinium chloride)
1-(시아노메틸) - 3- 메틸이미다졸리움 클로라이드(1- (Cyanomethyl) -3-methylimidazolium chloride)1- (Cyanomethyl)-3-methylimidazolium chloride (1- (Cyanomethyl) -3-methylimidazolium chloride)
1,2,3- 트리메틸이미다졸리움 클로라이드 (1,2,3-Trimethylimidazolium chloride)1,2,3-trimethylimidazolium chloride (1,2,3-Trimethylimidazolium chloride)
1,2,3- 트리메틸이미다졸리움 메틸설페이트 (1,2,3-Trimethylimidazolium methylsulfate)1,2,3-trimethylimidazolium methylsulfate (1,2,3-Trimethylimidazolium methylsulfate)
1,2,4- 트리메틸이미다졸리움 메틸설페이트 (1,2,4-Trimethylpyrazolium methylsulfate)1,2,4-trimethylimidazolium methylsulfate (1,2,4-Trimethylpyrazolium methylsulfate)
1,2-디메틸-3-프로필이미다졸리움 비스 (트리플루오로메틸설포닐) - 이미드 (1,2-Dimethyl-3-propylimidazolium bis (trifluoromethylsulfonyl) -imide)1,2-dimethyl-3-propylimidazolium bis (trifluoromethylsulfonyl) -imide (1,2-Dimethyl-3-propylimidazolium bis (trifluoromethylsulfonyl) -imide)
1,2-디메틸-3-프로필이미다졸리움 트리스 (트리플루오로메틸설포닐) - 메싸이드 (1,2-Dimethyl-3-propylimidazolium tris (trifluoromethylsulfonyl) -methide)1,2-dimethyl-3-propylimidazolium tris (trifluoromethylsulfonyl)-methide (1,2-Dimethyl-3-propylimidazolium tris (trifluoromethylsulfonyl) -methide)
1,3-비스 (3-시아노프로필) 이미다졸리움 비스(트리플루오로메틸설포닐) 이미드 (1,3-Bis (3-cyanopropyl) imidazolium bis (trifluoromethylsulfonyl) imide)1,3-bis (3-cyanopropyl) imidazolium bis (trifluoromethylsulfonyl) imide (1,3-Bis (3-cyanopropyl) imidazolium bis (trifluoromethylsulfonyl) imide)
1,3-비스 (3-시아노프로필) 이미다졸리움 클로라이드 (1,3-Bis (3-cyanopropyl) imidazolium chloride)1,3-bis (3-cyanopropyl) imidazolium chloride (1,3-Bis (3-cyanopropyl) imidazolium chloride)
1,3-비스 (시아노프로필) 이미다졸리움 비스 (트리플루오로메틸설포닐) 이미드 (1,3-Bis (cyanomethyl) imidazolium bis (trifluoromethylsulfonyl) imide)1,3-bis (cyanopropyl) imidazolium bis (trifluoromethylsulfonyl) imide (1,3-Bis (cyanomethyl) imidazolium bis (trifluoromethylsulfonyl) imide)
1,3-비스 (시아노프로필) 이미다졸리움 클로라이드 (1,3-Bis (cyanomethyl) imidazolium chloride)1,3-bis (cyanopropyl) imidazolium chloride (1,3-Bis (cyanomethyl) imidazolium chloride)
1,3- 디부틸이미다졸리움 클로라이드 (1,3-Dibutylimidazolium chloride)1,3-Dibutylimidazolium chloride
1,3- 디부틸이미다졸리움 테트라클로로알루미네이트 (1,3-Dibutylimidazolium tetrachloroaluminate)1,3-Dibutylimidazolium tetrachloroaluminate
1,3-디메틸이미다졸리움 클로라이드 (1,3-Dimethylimidazolium chloride)1,3-Dimethylimidazolium chloride
1,3-디메틸이미다졸리움 디메틸포스페이트(1,3-Dimethylimidazolium dimethylphosphate)1,3-Dimethylimidazolium dimethylphosphate
1,3-디메틸이미다졸리움 하이드로젠카보네이트 (1,3-Dimethylimidazolium hydrogencarbonate)1,3-Dimethylimidazolium hydrogencarbonate
1,3-디메틸이미다졸리움 요오드 (1,3-Dimethylimidazolium iodide)1,3-dimethylimidazolium iodine (1,3-Dimethylimidazolium iodide)
1,3-디메틸이미다졸리움 테트라클로로알루미네이트 (1,3-Dimethylimidazolium tetrachloroaluminate)1,3-Dimethylimidazolium tetrachloroaluminate
1,4-디부틸-3- 페닐이미다졸리움 비스 (트리플루오로메틸설포닐) 아미드 (1,4-Dibutyl-3-phenylimidazoliumbis [trifluoromethylsulfonyl] amide)1,4-Dibutyl-3-phenylimidazolium bis (trifluoromethylsulfonyl) amide (1,4-Dibutyl-3-phenylimidazoliumbis [trifluoromethylsulfonyl] amide)
1-부틸-1-메틸피로리디늄 비스 (트리플루오로메틸설포닐)이미드 (1-Butyl-1-methylpyrrolidinium bis (trifluoromethylsulfonyl) imide)1-Butyl-1-methylpyrrolidinium bis (trifluoromethylsulfonyl) imide (1-Butyl-1-methylpyrrolidinium bis (trifluoromethylsulfonyl) imide)
1-부틸-1-메틸피로리디늄 메틸카보네이트 (1-Butyl-1-methylpyrrolidinium methylcarbonate)1-Butyl-1-methylpyrrolidinium methylcarbonate
1-부틸-1-메틸피로리디늄 테트라시아노보네이트 (1-Butyl-1-methylpyrrolidinium tetracyanoborate)1-Butyl-1-methylpyrrolidinium tetracyanoborate
1-부틸-1-메틸피로리디늄 트리스 (펜타플루오로에틸) 트리플루오로 포스페이트 (1-Butyl-1-methylpyrrolidinium tris (pentafluoroethyl) trifluorophosphate) 1-Butyl-1-methylpyrrolidinium tris (pentafluoroethyl) trifluoro phosphate (1-Butyl-1-methylpyrrolidinium tris (pentafluoroethyl) trifluorophosphate)
1-부틸-2,3-디메틸이미다졸리움 클로라이드(1-Butyl-2,3-dimethylimidazolium chloride) 1-butyl-2,3-dimethylimidazolium chloride (1-Butyl-2,3-dimethylimidazolium chloride)
1-부틸-2,3-디메틸이미다졸리움 요오드 (1-Butyl-2,3-dimethylimidazolium iodide)1-butyl-2,3-dimethylimidazolium iodine (1-Butyl-2,3-dimethylimidazolium iodide)
1-부틸-2,3-디메틸이미다졸리움 트리플루오로메탄설포네이트 (1-Butyl-2,3-dimethylimidazolium trifluoromethanesulfonate)1-Butyl-2,3-dimethylimidazolium trifluoromethanesulfonate
1-부틸-2,3- 메틸이미다졸리움 비스 (트리플루오로메틸설포닐)이미드 (1-Butyl-2,3-methylimidazolium bis (trifluoromethylsulfonyl) imide)1-butyl-2,3-methylimidazolium bis (trifluoromethylsulfonyl) imide (1-Butyl-2,3-methylimidazolium bis (trifluoromethylsulfonyl) imide)
1-부틸-3-메틸이미다졸리움2-(2메톡시에톡시) 메틸 설페이트 (1-Butyl-3-methylimidazolium 2- (2methoxyethoxy) ethyl sulfate)1-Butyl-3-methylimidazolium 2- (2methoxyethoxy) methyl sulfate (1-Butyl-3-methylimidazolium 2- (2methoxyethoxy) ethyl sulfate)
1-부틸-3-메틸이미다졸리움 아세테이트 (1-Butyl-3-methylimidazolium acetate)1-Butyl-3-methylimidazolium acetate
1-부틸-3- 메틸이미다졸리움 비스 (트리플루오로메틸설포닐) 이미드 (1-Butyl-3-methylimidazolium bis (trifluoromethylsulfonyl) imide) 1-Butyl-3-methylimidazolium bis (trifluoromethylsulfonyl) imide (1-Butyl-3-methylimidazolium bis (trifluoromethylsulfonyl) imide)
1-부틸-3-메틸이미다졸리움 브로마이드 (1-Butyl-3-methylimidazolium bromide) 1-Butyl-3-methylimidazolium bromide
1-부틸-3-메틸이미다졸리움 클로라이드 (1-Butyl-3-methylimidazolium chloride)1-Butyl-3-methylimidazolium chloride
1-부틸-3-메틸이미다졸리움 디부틸포스페이트 (1-Butyl-3-methylimidazolium dibutylphosphate)1-butyl-3-methylimidazolium dibutylphosphate (1-Butyl-3-methylimidazolium dibutylphosphate)
1-부틸-3-메틸이미다졸리움 디시안아미드 (1-Butyl-3-methylimidazolium dicyanamide)1-Butyl-3-methylimidazolium dicyanamide
1-부틸-3-메틸이미다졸리움 헵타클로로디알루미네이트 (1-Butyl-3-methylimidazolium heptachlorodialuminate) 1-Butyl-3-methylimidazolium heptachlorodialuminate (1-Butyl-3-methylimidazolium heptachlorodialuminate)
1-부틸-3-메틸이미다졸리움 헥사플루오로포스페이트 (1-Butyl-3-methylimidazolium hexafluorophosphate)1-Butyl-3-methylimidazolium hexafluorophosphate (1-Butyl-3-methylimidazolium hexafluorophosphate)
1-부틸-3-메틸이미다졸리움 하이드로젠카보네이트 (1-Butyl-3-methylimidazolium hydrogencarbonate)1-Butyl-3-methylimidazolium hydrogencarbonate
1-부틸-3-메틸이미다졸리움 하이드로젠설페이트 (1-Butyl-3-methylimidazolium hydrogensulfate)1-Butyl-3-methylimidazolium hydrogensulfate (1-Butyl-3-methylimidazolium hydrogensulfate)
1-부틸-3-메틸이미다졸리움 요오드 (1-Butyl-3-methylimidazolium iodide)1-Butyl-3-methylimidazolium iodine (1-Butyl-3-methylimidazolium iodide)
1-부틸-3-메틸이미다졸리움 메탄설포네이트 (1-Butyl-3-methylimidazolium methanesulfonate)1-Butyl-3-methylimidazolium methanesulfonate
1-부틸-3-메틸이미다졸리움 메틸설포네이트 (1-Butyl-3-methylimidazolium methyl sulfate)1-Butyl-3-methylimidazolium methyl sulfate
1-부틸-3-메틸이미다졸리움 나이트레이트 (1-Butyl-3-methylimidazolium nitrate)1-Butyl-3-methylimidazolium nitrate
1-부틸-3-메틸이미다졸리움 옥틸설페이트(1-Butyl-3-methylimidazolium octylsulfate) 1-butyl-3-methylimidazolium octylsulfate (1-Butyl-3-methylimidazolium octylsulfate)
1-부틸-3-메틸이미다졸리움 테트라클로로알루미네이트 (1-Butyl-3-methylimidazolium tetrachloroaluminate)1-Butyl-3-methylimidazolium tetrachloroaluminate
1-부틸-3-메틸이미다졸리움 테트라클로로페레이트 (1-Butyl-3-methylimidazolium tetrachloroferrate)1-Butyl-3-methylimidazolium tetrachloroferrate
1-부틸-3-메틸이미다졸리움 테트라플루오로보레이트 (1-Butyl-3-methylimidazolium tetrafluoroborate)1-Butyl-3-methylimidazolium tetrafluoroborate
1-부틸-3-메틸이미다졸리움 티오시아네이트 (1-Butyl-3-methylimidazolium thiocyanate)1-Butyl-3-methylimidazolium thiocyanate (1-Butyl-3-methylimidazolium thiocyanate)
1-부틸-3-메틸이미다졸리움 트리플루오로메탄설포네이트 (1-Butyl-3-methylimidazolium trifluoromethanesulfonate)1-Butyl-3-methylimidazolium trifluoromethanesulfonate
1-부틸-3-메틸이미다졸리움 트리요오드 (1-Butyl-3-methylimidazolium triiodide)1-Butyl-3-methylimidazolium triiodide
1-부틸-3-메틸이미다졸리움 트리스 (펜타플루오로에틸설포닐) 트리플루오로포스페이트 (1-Butyl-3-methylimidazolium tris (pentafluoroethyl) trifluorophosphate)1-Butyl-3-methylimidazolium tris (pentafluoroethylsulfonyl) trifluorophosphate (1-Butyl-3-methylimidazolium tris (pentafluoroethyl) trifluorophosphate)
1-부틸-3- 메틸피리디늄 비스(트리플루오르메틸설포닐)이미드 (1-Butyl-3-methylpyridinium bis (trifluoromethylsulfonyl) imide)1-Butyl-3-methylpyridinium bis (trifluoromethylsulfonyl) imide (1-Butyl-3-methylpyridinium bis (trifluoromethylsulfonyl) imide)
1-부틸피리디늄 비스(트리플루오르메틸설포닐)이미드 (1-Butylpyridinium bis (trifluoromethylsulfonyl) imide)1-Butylpyridinium bis (trifluoromethylsulfonyl) imide
1-데실-3-메틸이미다졸리움 클로라이드 (1-Decyl-3-methylimidazolium chloride)1-decyl-3-methylimidazolium chloride (1-Decyl-3-methylimidazolium chloride)
1-도데실-3-메틸이미다졸리움 클로라이드 (1-Dodecyl-3-methylimidazolium chloride)1-Dodecyl-3-methylimidazolium chloride
1-에틸-1-메틸피페리디늄 메틸카보네이트 (1-Ethyl-1-methylpiperidinium methylcarbonate)1-Ethyl-1-methylpiperidinium methylcarbonate
1-에틸-2,3-디메틸이미다졸리움 비스 (펜타플루오로에틸설포닐)이미드 (1-Ethyl-2,3-dimethylimidazolium bis (pentafluoroethylsulfonyl) imide)1-Ethyl-2,3-dimethylimidazolium bis (pentafluoroethylsulfonyl) imide (1-Ethyl-2,3-dimethylimidazolium bis (pentafluoroethylsulfonyl) imide)
1-에틸-2,3-디메틸이미다졸리움 브로마이드 (1-Ethyl-2,3-dimethylimidazolium bromide)1-Ethyl-2,3-dimethylimidazolium bromide
1-에틸-2,3-디메틸이미다졸리움 클로라이드 (1-Ethyl-2,3-dimethylimidazolium chloride)1-ethyl-2,3-dimethylimidazolium chloride (1-Ethyl-2,3-dimethylimidazolium chloride)
1-에틸-2,3-디메틸이미다졸리움 메틸설페이트 (1-Ethyl-2,3-dimethylimidazolium ethylsulfate)1-Ethyl-2,3-dimethylimidazolium methylsulfate
1-에틸-2,3-디메틸이미다졸리움 헥사플루오로포스페이트 (1-Ethyl-2,3-dimethylimidazolium hexafluorophosphate)1-ethyl-2,3-dimethylimidazolium hexafluorophosphate (1-Ethyl-2,3-dimethylimidazolium hexafluorophosphate)
1-에틸-2,3-디메틸이미다졸리움 메틸카보네이트 (1-Ethyl-2,3-dimethylimidazolium methylcarbonate)1-Ethyl-2,3-dimethylimidazolium methylcarbonate
1-에틸-3-메틸-1H-이미다졸리움 테트라플루오로보레이트 (1-Ethyl-3-methyl-1H-imidazolium tetrafluoroborate)1-ethyl-3-methyl-1H-imidazolium tetrafluoroborate (1-Ethyl-3-methyl-1H-imidazolium tetrafluoroborate)
1-에틸-3-메틸이미다졸리움 2 (2-메톡시에톡시) 에틸설페이트 (1-Ethyl-3-methylimidazolium 2 (2-methoxyethoxy) ethylsulfate)1-ethyl-3-methylimidazolium 2 (2-methoxyethoxy) ethylsulfate (1-Ethyl-3-methylimidazolium 2 (2-methoxyethoxy) ethylsulfate)
1-에틸-3-메틸이미다졸리움 아세테이트 (1-Ethyl-3-methylimidazolium acetate)1-Ethyl-3-methylimidazolium acetate
1-에틸-3-메틸이미다졸리움 비스 (펜타플루오로에틸설포닐)이미드 (1-Ethyl-3-methylimidazolium bis (pentafluoroethylsulfonyl) imide)1-ethyl-3-methylimidazolium bis (pentafluoroethylsulfonyl) imide) (1-Ethyl-3-methylimidazolium bis (pentafluoroethylsulfonyl) imide)
1-에틸-3-메틸이미다졸리움 비스 (트리플루오로메틸설포닐)이미드 (1-Ethyl-3-methylimidazolium bis (trifluoromethylsulfonyl) imide)1-Ethyl-3-methylimidazolium bis (trifluoromethylsulfonyl) imide (1-Ethyl-3-methylimidazolium bis (trifluoromethylsulfonyl) imide)
1-에틸-3-메틸이미다졸리움 브로마이드 (1-Ethyl-3-methylimidazolium bromide) 1-Ethyl-3-methylimidazolium bromide
1-에틸-3-메틸이미다졸리움 클로라이드 (1-Ethyl-3-methylimidazolium chloride)1-Ethyl-3-methylimidazolium chloride
1-에틸-3-메틸이미다졸리움 디부틸포스페이트 (1-Ethyl-3-methylimidazolium dibutylphosphate)1-Ethyl-3-methylimidazolium dibutylphosphate (1-Ethyl-3-methylimidazolium dibutylphosphate)
1-에틸-3-메틸이미다졸리움 디시안아미드 (1-Ethyl-3-methylimidazolium dicyanamide)1-Ethyl-3-methylimidazolium dicyanamide
1-에틸-3-메틸이미다졸리움 디에틸포스페이트 (1-Ethyl-3-methylimidazolium diethylphosphate)1-Ethyl-3-methylimidazolium diethylphosphate
1-에틸-3-메틸이미다졸리움 에틸설페이트 (1-Ethyl-3-methylimidazolium ethylsulfate)1-ethyl-3-methylimidazolium ethylsulfate (1-Ethyl-3-methylimidazolium ethylsulfate)
1-에틸-3-메틸이미다졸리움 헥사플루오로아르세네이트 (1-Ethyl-3-methylimidazolium hexafluoroarsenate) 1-ethyl-3-methylimidazolium hexafluoroarsenate (1-Ethyl-3-methylimidazolium hexafluoroarsenate)
1-에틸-3-메틸이미다졸리움 하이드로젠카보네이트 (1-Ethyl-3-methylimidazolium hydrogencarbonate) 1-Ethyl-3-methylimidazolium hydrogencarbonate
1-에틸-3-메틸이미다졸리움 하이드로젠설페이트 (1-Ethyl-3-methylimidazolium hydrogensulfate)1-Ethyl-3-methylimidazolium hydrogensulfate (1-Ethyl-3-methylimidazolium hydrogensulfate)
1-에틸-3-메틸이미다졸리움 요오드 (1-Ethyl-3-methylimidazolium iodide) 1-Ethyl-3-methylimidazolium iodine (1-Ethyl-3-methylimidazolium iodide)
1-에틸-3-메틸이미다졸리움 메탄설포네이트 (1-Ethyl-3-methylimidazolium methanesulfonate)1-Ethyl-3-methylimidazolium methanesulfonate
1-에틸-3-메틸이미다졸리움 나이트레이트 (1-Ethyl-3-methylimidazolium nitrate) 1-Ethyl-3-methylimidazolium nitrate (1-Ethyl-3-methylimidazolium nitrate)
1-에틸-3-메틸이미다졸리움 옥틸설페이트 (1-Ethyl-3-methylimidazolium octylsulfate) 1-ethyl-3-methylimidazolium octylsulfate (1-Ethyl-3-methylimidazolium octylsulfate)
1-에틸-3-메틸이미다졸리움 테트라브로모알루미네이트 (III) (1-Ethyl-3-methylimidazolium tetrabromoaluminate (III))1-ethyl-3-methylimidazolium tetrabromoaluminate (III) (1-Ethyl-3-methylimidazolium tetrabromoaluminate (III))
1-에틸-3-메틸이미다졸리움 테트라클로로알루미네이트 (1-Ethyl-3-methylimidazolium tetrachloroaluminate)1-Ethyl-3-methylimidazolium tetrachloroaluminate
1-에틸-3-메틸이미다졸리움 테트라클로로갈레이트 (1-Ethyl-3-methylimidazolium tetrachlorogallate)1-Ethyl-3-methylimidazolium tetrachlorogallate
1-에틸-3-메틸이미다졸리움 테트라시아노보레이트 (1-Ethyl-3-methylimidazolium tetracyanoborate)1-Ethyl-3-methylimidazolium tetracyanoborate
1-에틸-3-메틸이미다졸리움 테트라플루오로보레이트 (1-Ethyl-3-methylimidazolium tetrafluoroborate)1-Ethyl-3-methylimidazolium tetrafluoroborate
1-에틸-3-메틸이미다졸리움 티오시아네이트 (1-Ethyl-3-methylimidazolium thiocyanate) 1-ethyl-3-methylimidazolium thiocyanate (1-Ethyl-3-methylimidazolium thiocyanate)
1-에틸-3-메틸이미다졸리움 트리플루오로메탄설포네이트 (1-Ethyl-3-methylimidazolium trifluoromethanesulfonate) 1-ethyl-3-methylimidazolium trifluoromethanesulfonate (1-Ethyl-3-methylimidazolium trifluoromethanesulfonate)
1-에틸-3-메틸이미다졸리움 트리요오드 (1-Ethyl-3-methylimidazolium triiodide) 1-Ethyl-3-methylimidazolium triiodide
1-에틸-3-메틸이미다졸리움 트리스 (펜타플루오로에틸) 트리플루오로포스페이트 (1-Ethyl-3-methylimidazolium tris (pentafluoroethyl) trifluorophosphate) 1-ethyl-3-methylimidazolium tris (pentafluoroethyl) trifluorophosphate (1-Ethyl-3-methylimidazolium tris (pentafluoroethyl) trifluorophosphate)
1-에틸-3-메틸이미다졸리움 트리스 (트리플루오르메틸설포닐) 메싸이드 (1-Ethyl-3-methylimidazolium tris (trifluoromethylsulfonyl) methide) 1-Ethyl-3-methylimidazolium tris (trifluoromethylsulfonyl) mesdeide (1-Ethyl-3-methylimidazolium tris (trifluoromethylsulfonyl) methide)
1-헥실-1-메틸-피로리디늄 테트라시아노보레이트 (1-Hexyl-1-methyl-pyrrolidinium tetracyanoborate)1-hexyl-1-methyl-pyrrolidinium tetracyanoborate
1-헥실-3-메틸 메틸이미다졸리움 비스 (트리플루오르메틸설포닐) 이미드 (1-Hexyl-3-methylimidazolium bis (trifluoromethylsulfonyl) imide)1-hexyl-3-methyl methylimidazolium bis (trifluoromethylsulfonyl) imide (1-Hexyl-3-methylimidazolium bis (trifluoromethylsulfonyl) imide)
1-헥실-3-메틸 메틸이미다졸리움 클로라이드 (1-Hexyl-3-methylimidazolium chloride)1-hexyl-3-methylimidazolium chloride (1-Hexyl-3-methylimidazolium chloride)
1-헥실-3-메틸 메틸이미다졸리움 헥사플루오로포스페이트 (1-Hexyl-3-methylimidazolium hexafluorophosphate)1-hexyl-3-methyl methylimidazolium hexafluorophosphate (1-Hexyl-3-methylimidazolium hexafluorophosphate)
1-헤실-3-메틸 메틸이미다졸리움 테트라시아노보레이트 (1-Hexyl-3-methylimidazolium tetracyanoborate) 1-hexyl-3-methyl imidazolium tetracyanoborate (1-Hexyl-3-methylimidazolium tetracyanoborate)
1-헥실-3-메틸 메틸이미다졸리움 트리플루오르메틸설포닐(1-Hexyl-3-methylimidazolium trifluormethylsulfonat) 1-hexyl-3-methyl imidazolium trifluoromethylsulfonyl (1-Hexyl-3-methylimidazolium trifluormethylsulfonat)
1-헥실-3-메틸 메틸이미다졸리움 트리스 (펜타플루오로에틸) 트리플루오로포스페이트 (1-Hexyl-3-methylimidazolium tris (pentafluoroethyl) trifluorophosphate) 1-hexyl-3-methyl methylimidazolium tris (pentafluoroethyl) trifluorophosphate (1-Hexyl-3-methylimidazolium tris (pentafluoroethyl) trifluorophosphate)
1-헥실록시메틸-3-메틸이미다졸리움 비스 (트리플루오르메틸설포닐) 이미드 (1-Hexyloxymethyl-3-methylimidazolium bis (trifluoromethylsulfonyl) imide)1-hexyloxymethyl-3-methylimidazolium bis (trifluoromethylsulfonyl) imide (1-Hexyloxymethyl-3-methylimidazolium bis (trifluoromethylsulfonyl) imide)
1-헥실록시메틸-3-메틸이미다졸리움 테트라플루오로보레이트 (1-Hexyloxymethyl-3-methylimidazolium tetrafluoroborate)1-hexyloxymethyl-3-methylimidazolium tetrafluoroborate
1-i-프로필-3-메틸-이미다졸리움 비스 (트리플루오르메틸설포닐) 이미드 (1-i-Propyl-3-methyl-imidazolium bis (trifluoromethylsulfonyl) imide)1-i-propyl-3-methyl-imidazolium bis (trifluoromethylsulfonyl) imide (1-i-Propyl-3-methyl-imidazolium bis (trifluoromethylsulfonyl) imide)
1-i-프로필-3-메틸이미다졸리움 요오드 (1-i-Propyl-3-methylimidazolium iodide)1-i-propyl-3-methylimidazolium iodine (1-i-Propyl-3-methylimidazolium iodide)
1-i-프로필-3-메틸-이미다졸리움- 헥사플루오로포스페이트 (1-i-Propyl-3-methyl-imidazolium-hexafluorophosphate)1-i-propyl-3-methyl-imidazolium-hexafluorophosphate (1-i-Propyl-3-methyl-imidazolium-hexafluorophosphate)
1-메틸-3-메틸-이미다졸리움 디메틸포스페이트 (1-Methyl-3-methyl-imidazolium dimethylphosphate)1-Methyl-3-methyl-imidazolium dimethylphosphate
1-메틸-3-메틸-이미다졸리움 메틸설페이트(1-Methyl-3-methyl-imidazolium methylsulfate)1-Methyl-3-methyl-imidazolium methylsulfate
1-메틸-3-프로필이미다졸리움 클로라이드 (1-Methyl-3-propylimidazolium chloride)1-Methyl-3-propylimidazolium chloride
1-메틸-4-옥틸피리디늄 브로마이드 (1-Methyl-4-octylpyridinium bromide)1-methyl-4-octylpyridinium bromide (1-Methyl-4-octylpyridinium bromide)
1-메틸-4-옥틸피리디늄 콜로라이드 (1-Methyl-4-octylpyridinium chloride)1-methyl-4-octylpyridinium colloid (1-Methyl-4-octylpyridinium chloride)
1-메틸-4-옥틸피리디늄 요오드 (1-Methyl-4-octylpyridinium iodide)1-Methyl-4-octylpyridinium iodine (1-Methyl-4-octylpyridinium iodide)
1-메틸이미다졸리움 클로라이드 (1-Methylimidazolium chloride)1-Methylimidazolium chloride
1-메틸이미다졸리움 하이드로젠설페이트 (1-Methylimidazolium hydrogensulfate)1-Methylimidazolium hydrogensulfate
1-n-부틸-3-메틸이미다졸리움 브로마이드 (1-n-Butyl-3-methylimidazolium Bromide)1-n-butyl-3-methylimidazolium bromide (1-n-Butyl-3-methylimidazolium Bromide)
1-n-부틸-3-메틸이미다졸리움 클로라이드 (1-n-Butyl-3-methylimidazolium Chloride)1-n-butyl-3-methylimidazolium chloride (1-n-Butyl-3-methylimidazolium Chloride)
1-n-부틸-3-메틸이미다졸리움 헥사플루오로포스페이트 (1-n-Butyl-3-methylimidazolium Hexafluorophosphate)1-n-butyl-3-methylimidazolium hexafluorophosphate (1-n-Butyl-3-methylimidazolium Hexafluorophosphate)
1-n-부틸-3-메틸이미다졸리움 테트라플루오로보레이트 (1-n-Butyl-3-methylimidazolium Tetrafluoroborate) 1-n-butyl-3-methylimidazolium tetrafluoroborate (1-n-Butyl-3-methylimidazolium Tetrafluoroborate)
1-n-부틸-3-메틸이미다졸리움 트리플루오로메탄설포네이트 (1-n-Butyl-3-methylimidazolium Trifluoromethanesulfonate)1-n-Butyl-3-methylimidazolium trifluoromethanesulfonate
1-n-헵틸-3-메틸이미다졸리움 헥사플루오로포스페이트 (1-n-Heptyl-3-methylimidazolium hexafluorophosphate)1-n-heptyl-3-methylimidazolium hexafluorophosphate (1-n-Heptyl-3-methylimidazolium hexafluorophosphate)
1-n-옥틸-3-메틸이미다졸리움 헥사플루오로포스페이트 (1-n-Octyl-3-methylimidazolium hexafluorophosphate)1-n-octyl-3-methylimidazolium hexafluorophosphate (1-n-Octyl-3-methylimidazolium hexafluorophosphate)
1-n-옥틸-3-메틸이미다졸리움 테트라플루오로보레이트 (1-n-Octyl-3-methylimidazolium tetrafluoroborate) 1-n-octyl-3-methylimidazolium tetrafluoroborate (1-n-Octyl-3-methylimidazolium tetrafluoroborate)
1-n-펜틸-3-메틸이미다졸리움 헥사플루오로포스페이트 (1-n-Pentyl-3-methylimidazolium hexafluorophosphate)1-n-pentyl-3-methylimidazolium hexafluorophosphate (1-n-Pentyl-3-methylimidazolium hexafluorophosphate)
1-n-프로필-2,3-디메틸이미다졸리움 비스 (펜타플루오로에틸설포닐) 아미드 (1-n-Propyl-2,3-dimethylimidazolium bis (pentafluoroethylsulfonyl) imide)1-n-propyl-2,3-dimethylimidazolium bis (pentafluoroethylsulfonyl) amide (1-n-Propyl-2,3-dimethylimidazolium bis (pentafluoroethylsulfonyl) imide)
1-옥틸-3-메틸이미다졸리움 콜로라이드 (1-Octyl-3-methylimidazolium chloride)1-Octyl-3-methylimidazolium chloride (1-Octyl-3-methylimidazolium chloride)
1-옥틸-3-메틸이미다졸리움 트리플루오르메틸설포닐 (1-Octyl-3-methylimidazolium trifluormethylsulfonat)1-octyl-3-methylimidazolium trifluoromethylsulfonyl (1-Octyl-3-methylimidazolium trifluormethylsulfonat)
1-프로필-2,3-디메틸이미다졸리움 클로라이드 (1-Propyl-2,3-dimethylimidazolium chloride)1-propyl-2,3-dimethylimidazolium chloride (1-Propyl-2,3-dimethylimidazolium chloride)
1-프로필-2,3-디메틸이미다졸리움 헥사플루오로포스페이트 (1-Propyl-2,3-dimethylimidazolium hexafluorophosphate) 1-propyl-2,3-dimethylimidazolium hexafluorophosphate (1-Propyl-2,3-dimethylimidazolium hexafluorophosphate)
1-프로필-3-메틸이미다졸리움 테트라클로로알루미네이트 (1-Propyl-3-methylimidazolium tetrachloroaluminate)1-propyl-3-methylimidazolium tetrachloroaluminate (1-Propyl-3-methylimidazolium tetrachloroaluminate)
1-비닐-3-메틸이미다졸리움 하이드로젠카보네이트 (1-Vinyl-3-methylimidazolium hydrogencarbonate)1-vinyl-3-methylimidazolium hydrogencarbonate
2,3 디메틸-1-프로필이미다졸리움 비스 (트리플루오로메틸설포닐) 이미드 (2,3 Dimethyl-1-propylimidazolium bis (trifluormethylsulfonyl) imide)2,3 Dimethyl-1-propylimidazolium bis (trifluoromethylsulfonyl) imide (2,3 Dimethyl-1-propylimidazolium bis (trifluormethylsulfonyl) imide)
2,3 디메틸-1-프로필이미다졸리움 요오드 (2,3 Dimethyl-1-propylimidazolium iodide)2,3 Dimethyl-1-propylimidazolium iodine (2,3 Dimethyl-1-propylimidazolium iodide)
2,3 디메틸-1-n-프로필이미다졸리움 비스 (트리플루오로메틸설포닐) 이미드 (2,3-Dimethyl-1-n-propylimidazolium bis (trifluoromethylsulfonyl) imide)2,3-Dimethyl-1-n-propylimidazolium bis (trifluoromethylsulfonyl) imide (2,3-Dimethyl-1-n-propylimidazolium bis (trifluoromethylsulfonyl) imide)
2,4,5-트리메틸이미다졸리움 클로라이드 (2,4,5-Trimethylimidazolium chloride)2,4,5-trimethylimidazolium chloride (2,4,5-Trimethylimidazolium chloride)
2-하이드록시에틸트리메틸암모늄 아세테이트 (2-Hydroxyethyltrimethylammonium acetate)2-Hydroxyethyltrimethylammonium acetate
2-하이드록시에틸-트리메틸암모늄 디메틸포스페이트 (2-Hydroxyethyl-trimethylammonium dimethylphosphate)2-Hydroxyethyl-trimethylammonium dimethylphosphate
3-메틸-1-프로필이미다졸리움 비스 (트리플루오로메틸설포닐) 이미드 (3-Methyl-1-propylimidazolium bis (trifluormethylsulfonyl) imide)3-Methyl-1-propylimidazolium bis (trifluoromethylsulfonyl) imide)
3-메틸-1-프로필이미다졸리움 요오드 (3-Methyl-1-propylimidazolium iodide)3-Methyl-1-propylimidazolium iodine (3-Methyl-1-propylimidazolium iodide)
3-메틸-1-프로필이미다졸리움 비스 (트리플루오로메틸설포닐) 이미드 (3-Methyl-1-propylpyridinium bis (trifluoromethylsulfonyl) imide)3-Methyl-1-propylimidazolium bis (trifluoromethylsulfonyl) imide (3-Methyl-1-propylpyridinium bis (trifluoromethylsulfonyl) imide)
4-에틸-4-메틸몰포리니윰 메틸 카보네이트 (4-Ethyl-4-methylmorpholinium methylcarbonate)4-Ethyl-4-methylmorpholinium methylcarbonate
4-메틸-N-부틸피리디늄 테트라플루오로보레이트 (4-Methyl-N-butylpyridinium tetrafluoroborate)4-Methyl-N-butylpyridinium tetrafluoroborate
에틸-3-메틸이미다졸리움 트리스 (펜타플루오로에틸) 트리플루오로포스페이트 (Ethyl-3-methylimidazolium tris (pentafluoroethyl) trifluorophosphate)Ethyl-3-methylimidazolium tris (pentafluoroethyl) trifluorophosphate
에틸디메틸 - (2-메톡시에틸) 암모늄 비스 (펜타플루오로에틸) 트리플루오로포스페이트 (Ethyldimethyl- (2-methoxyethyl) ammonium tris (pentafluoroethyl) trifluorophosphat)Ethyldimethyl- (2-methoxyethyl) ammonium tris (pentafluoroethyl) trifluorophosphat) Ethyldimethyl- (2-methoxyethyl) ammonium bis (pentafluoroethyl) trifluorophosphate
에틸-디메틸- 프로필암모늄 비스 (트리플루오로메틸설포닐) 이미드 (Ethyl-dimethyl-propylammonium bis (trifluoromethylsulfonyl) imide)Ethyl-dimethyl-propylammonium bis (trifluoromethylsulfonyl) imide
메틸트리옥틸암모늄 티오살리실레이트 (Methyltrioctylammonium thiosalicylate)Methyltrioctylammonium thiosalicylate
N-(메톡시에틸)-1-메틸피로리디늄 비스 (트리플루오로메틸설포닐)이미드 (N- (Methoxyethyl) -1-methylpyrrolidinium bis (trifluoromethylsulfonyl) imide N- (methoxyethyl) -1-methylpyrrolidinium bis (trifluoromethylsulfonyl) imide (N- (Methoxyethyl) -1-methylpyrrolidinium bis (trifluoromethylsulfonyl) imide
N,N- 디메틸피로리디늄 비스 (트리플루오로메틸설포) 이미드 (N, N-Dimethylpyrrolidinium bis (trifluoromethylsulfonyl) imide)N, N-dimethylpyrrolidinium bis (trifluoromethylsulfonyl) imide
N,N- 디메틸피로리디늄 요오드 (N, N-Dimethylpyrrolidinium iodide)N, N-Dimethylpyrrolidinium Iodide
N-부틸-1-메틸피로리디늄 (트리플루오로메틸설포) 이미드 (N-Butyl-1-methylpyrrolidinium bis (trifluoromethylsulfonyl) imide)N-Butyl-1-methylpyrrolidinium (trifluoromethylsulfonyl) imide)
N-부틸-1-메틸피로리디늄 비스 [옥살레이토 (2 -) - O, O'] 보레이트 (N-Butyl-1-methylpyrrolidinium bis [oxalato (2 -) - O, O'] borate)N-Butyl-1-methylpyrrolidinium bis [oxalato (2-)-O, O '] borate
N-부틸-1-메틸피로리디늄 브라마이드 (N-Butyl-1-methylpyrrolidinium bromide)N-Butyl-1-methylpyrrolidinium bromide
N-부틸-1-메틸피로리디늄 클로라이드 (N-Butyl-1-methylpyrrolidinium chloride)N-Butyl-1-methylpyrrolidinium chloride
N-부틸-1-메틸피로리디늄 디시안아미드 (N-Butyl-1-methylpyrrolidinium dicyanamide)N-Butyl-1-methylpyrrolidinium dicyanamide
N-부틸-1-메틸피로리디늄 트리플루오로메탄설포네이트 (N-Butyl-1-methylpyrrolidinium trifluoromethanesulfonate)N-Butyl-1-methylpyrrolidinium trifluoromethanesulfonate
N-부틸-1-메틸피로리디늄 트리스 (펜타플루오로에틸) 트리플루오로포스페이트 (N-Butyl-1-methylpyrrolidinium tris (pentafluoroethyl) trifluorophosphate)N-Butyl-1-methylpyrrolidinium tris (pentafluoroethyl) trifluorophosphate (N-Butyl-1-methylpyrrolidinium tris (pentafluoroethyl) trifluorophosphate)
N-부틸-4-(N',N'-디메틸암모늄) 피리디늄 비스(트리플루오로메틸설포닐)이미드 (N-Butyl-4- (N',N'-dimethylammonium) pyridinium bis (trifluoromethylsulfonyl) imide) N-Butyl-4- (N ', N'-dimethylammonium) pyridinium bis (trifluoromethylsulfonyl) imide (N-Butyl-4- (N', N'-dimethylammonium) pyridinium bis (trifluoromethylsulfonyl) imide)
N-부틸피리디늄 클로라이드 (N-Butylpyridinium chloride)N-Butylpyridinium chloride
N-부틸피리디늄 테트라플루오로보레이트 (N-Butylpyridinium tetrafluoroborate)N-Butylpyridinium tetrafluoroborate
N-에틸-3-메틸피리디늄 에틸설페이트(N-Ethyl-3-methylpyridinium ethylsulfate)N-Ethyl-3-methylpyridinium ethylsulfate
N-에틸-3-메틸피리디늄 퍼플루오로부탄설포네이트(N-Ethyl-3-methylpyridinium perfluorobutanesulfonate)N-Ethyl-3-methylpyridinium perfluorobutanesulfonate
N-부틸-4-(N',N'-디메틸암모늄) 피리디늄 비스(트리플루오로메틸설포닐)이미드 (N-Ethyl-4- (N',N'-dimethylammonium) pyridinium bis (trifluoromethylsulfonyl) imide)N-butyl-4- (N ', N'-dimethylammonium) pyridinium bis (trifluoromethylsulfonyl) imide (N-Ethyl-4- (N', N'-dimethylammonium) pyridinium bis (trifluoromethylsulfonyl) imide)
N-에틸-N,N-디메틸-2-메톡시에틸 암모늄 트리스 (펜타플루오로에틸) 트리플루오로포스페이트 (N-Ethyl-N, N-dimethyl-2-methoxyethyl ammonium tris (pentafluoroethyl) trifluorophosphate) N-ethyl-N, N-dimethyl-2-methoxyethyl ammonium tris (pentafluoroethyl) trifluorophosphate (N-Ethyl-N, N-dimethyl-2-methoxyethyl ammonium tris (pentafluoroethyl) trifluorophosphate)
N-에틸피리디늄 비스 (트리플루오로메틸설포닐)이미드 (N-Ethylpyridinium bis (trifluoromethylsulfonyl) imide)N-ethylpyridinium bis (trifluoromethylsulfonyl) imide
N-헥실-4-(N',N'-디메틸암모늄) 피리디늄 비스(트리플루오로메틸설포닐)이미드 N-hexyl-4- (N ', N'-dimethylammonium) pyridinium bis (trifluoromethylsulfonyl) imide
N-Hexyl-4- (N',N'-dimethylammonium) pyridinium bis (trifluoromethylsulfonyl) imide N-Hexyl-4- (N ', N'-dimethylammonium) pyridinium bis (trifluoromethylsulfonyl) imide
N-메틸-N-메틸피로리디늄 비스 (트리플루오로메틸설포닐)이미드 (N-Methyl-N-Ethylpyrrolidinium bis (trifluoromethylsulfonyl) imide)N-Methyl-N-methylpyrrolidinium bis (trifluoromethylsulfonyl) imide
N-메틸-Nn-프로필피로리디늄 비스 (트리플루오로메틸설포닐)이미드 (N-Methyl-Nn-propylpyrrolidinium bis (trifluoromethylsulfonyl) imide)N-Methyl-Nn-propylpyrrolidinium bis (trifluoromethylsulfonyl) imide
펜타메이미다졸리움 (트리플루오로메틸설포닐)이미드 (Pentamethylimidazolium bis (trifluoromethylsulfonyl) imide)Pentamididazolium (trifluoromethylsulfonyl) imide
펜타메이미다졸리움 헥사플루오로포스페이트 (Pentamethylimidazolium hexafluorophosphate) Pentamididazolium hexafluorophosphate (Pentamethylimidazolium hexafluorophosphate)
펜타메이미다졸리움 요오드 (Pentamethylimidazolium iodide)Pentamididazolium Iodide (Pentamethylimidazolium iodide)
피리디늄 에톡시에틸설페이트 (Pyridinium ethoxyethylsulfate)Pyridinium ethoxyethylsulfate
테트라부틸암모늄 클로라이드 (Tetrabutylammonium chloride)Tetrabutylammonium chloride
테트라부틸암모늄 비스 (펜타플루오로에틸설포닐)이미드 (Tetraethylammonium bis (pentafluoroethylsulfonyl) imide)Tetrabutylammonium bis (pentafluoroethylsulfonyl) imide)
테트라부틸암모늄 비스 (트리플루오로메틸설포닐)이미드 (Tetraethylammonium bis (trifluoromethylsulfonyl) imide)Tetrabutylammonium bis (trifluoromethylsulfonyl) imide)
테트라부틸암모늄 헥사플루오로포스페이트 (Tetraethylammonium hexafluorophosphate) Tetrabutylammonium hexafluorophosphate
테트라부틸암모늄 테트라플루오로보레이트 (Tetraethylammonium tetrafluoroborate)Tetrabutylammonium tetrafluoroborate
테트라부틸암모늄 트리스 (트리플루오로메틸술포닐) 메싸이드 (Tetraethylammonium tris (trifluoromethylsulfonyl) methide) Tetrabutylammonium tris (trifluoromethylsulfonyl) methide
테트라부틸암모늄 과염소산염 (Tetrahexylammonium perchlorate)Tetrabutylammonium Perchlorate (Tetrahexylammonium perchlorate)
테트라 - iso- 펜틸암모늄요오드 (Tetra-iso-pentylammonium iodide)Tetra-iso-pentylammonium iodide
테트라메틸암모늄 트리스 (펜타플루오로에틸) 트리플루오로포스페이트 (Tetramethylammonium tris (pentafluoroethyl) trifluorophosphate)Tetramethylammonium tris (pentafluoroethyl) trifluorophosphate
테트라-N-부틸암모늄 4- 톨루엔설포네이트 (Tetra-N-butylammonium 4-toluenesulfonate) Tetra-N-butylammonium 4-toluenesulfonate
테트라-N-부틸암모늄 벤젠설포네이트 (Tetra-N-butylammonium benzenesulfonate) Tetra-N-butylammonium benzenesulfonate
테트라-N-부틸암모늄 비스(트리플루오로메틸설포닐) 이미드 (Tetra-n-butylammonium bis (trifluoromethylsulfonyl) imide) Tetra-n-butylammonium bis (trifluoromethylsulfonyl) imide
테트라-N-부틸암모늄 브로마이드 (Tetra-N-butylammonium bromide)Tetra-N-butylammonium bromide
테트라-N-부틸암모늄 부탄설포네이트 (Tetra-N-butylammonium butanesulfonate)Tetra-N-butylammonium butanesulfonate
테트라-N-부틸암모늄 (Tetra-N-butylammonium ethanesulfonate Tetra-N-butylammonium ethanesulfonate
테트라-N-부틸암모늄 메탄설포네이트 (Tetra-N-butylammonium methanesulfonate)Tetra-N-butylammonium methanesulfonate
테트라-N-부틸암모늄 나이트레이트 (Tetra-N-butylammonium nitrate)Tetra-N-butylammonium nitrate
테트라-N-부틸암모늄 나이트라이트 (Tetra-N-butylammonium nitrite)Tetra-N-butylammonium nitrite
테트라-N-부틸암모늄 옥탄설포네이트 (Tetra-N-butylammonium octanesulfonate) Tetra-N-butylammonium octanesulfonate
테트라-N-부틸암모늄 펜타시아노프로페니시드 (Tetra-N-butylammonium pentacyanopropenide) Tetra-N-butylammonium pentacyanopropenide
테트라-N-부틸암모늄 펜타플루오로벤젠설포네이트(Tetra-N-butylammonium pentafluoroenzenesulfonate) Tetra-N-butylammonium pentafluoroenzenesulfonate
테트라-N-부틸암모늄 피크레이트 (Tetra-N-butylammonium picrate) Tetra-N-butylammonium picrate
테트라-N-부틸암모늄 설포메이트 (Tetra-N-butylammonium sulfamate) Tetra-N-butylammonium sulfamate
테트라-N-부틸암모늄 테트라-N-부틸보레이트(Tetra-N-butylammonium tetra-N-butylborate)Tetra-N-butylammonium tetra-N-butylborate
테트라-N-부틸암모늄 티오시아네이트 (Tetra-N-butylammonium thiocyanate)Tetra-N-butylammonium thiocyanate
테트라-N-부틸암모늄 트리플루오로메탄설포네이트 (Tetra-N-butylammonium trifluoromethanesulfonate) Tetra-N-butylammonium trifluoromethanesulfonate
테트라-N-부틸암모늄 트리스 메사이드 (Tetra-n-butylammonium tris (trifluoromethylsulfonyl) methide)Tetra-n-butylammonium tris (trifluoromethylsulfonyl) methide)
테트라-N-부틸암모늄 요오드 (Tetra-N-butylammoniumiodide)Tetra-N-butylammoniumiodide
테트라-N-헵틸암모늄 요오드 (Tetra-N-heptylammoniumiodide)Tetra-N-heptylammoniumiodide
테트라-N-헥실암모늄브로마이드 (Tetra-N-hexylammoniumbromide) Tetra-N-hexylammoniumbromide
테트라-N-헥실암모늄요오드 (Tetra-N-hexylammoniumiodide)Tetra-N-hexylammoniumiodide
테트라-N-헥실암모늄 테트라플루오로보레이트 (Tetra-N-hexylammonium tetrafluoroborate) Tetra-N-hexylammonium tetrafluoroborate
테트라-N-펜틸암모늄요오드 (Tetra-N-pentylammoniumiodide)Tetra-N-pentylammoniumiodide
테트라-N-펜틸암모늄나이트레이트 (Tetra-N-pentylammoniumnitrate)Tetra-N-pentylammonium nitrate
테트라-N-펜틸암모늄 티오시아네이트 (Tetra-N-pentylammonium thiocyanate)Tetra-N-pentylammonium thiocyanate
테트라펜틸암모늄 브로마이드 (Tetrapentylammonium bromide)Tetrapentylammonium bromide
트리부틸메틸암모늄 메틸 카보네이트 (Tributylmethylammonium methylcarbonate) Tributylmethylammonium methylcarbonate
트리부틸메틸암모늄 메틸설페이트 (Tributylmethylammonium methylsulfate)Tributylmethylammonium methylsulfate
트리부틸메틸포스포늄 디부틸포스페이트 (Tributylmethylphosphonium dibutylphosphate) Tributylmethylphosphonium dibutylphosphate
트리부틸메틸포스포늄 메틸카본네이트(Tributylmethylphosphonium methylcarbonate) Tributylmethylphosphonium methylcarbonate
트리에틸아민 하이드로클로라이드 2 AlCl3] (Triethylamine hydrochloride 2 AlCl3])
트리에틸메탈암모늄 디부틸포스페이트 (Triethylmethylammonium dibutylphosphate)Triethylmethylammonium dibutylphosphate
트리에틸메탈암모늄 메탈카본네이트 (Triethylmethylammonium methylcarbonate) Triethylmethylammonium Methylcarbonate
트리에틸메탈포스포늄 디부틸포스페이트 (Triethylmethylphosphonium dibutylphosphate)Triethylmethylphosphonium dibutylphosphate
트리-N-부틸메탈암모늄 부탄설포네이트 (Tri-N-butylmethylammonium butanesulfonate)Tri-N-butylmethylammonium butanesulfonate
트리-N-부틸메탈암모늄 옥탄설포네이트 (Tri-N-butylmethylammonium octanesulfonate) Tri-N-butylmethylammonium octanesulfonate
트리-N-부틸메탈암모늄 퍼플루오로부탄설포네이트 (Tri-N-butylmethylammonium perfluorobutanesulfonate) Tri-N-butylmethylammonium perfluorobutanesulfonate
트리-N-부틸메탈암모늄퍼플루오로옥탄설포네이트 (Tri-N-butylmethylammonium perfluorooctanesulfonate)Tri-N-butylmethylammonium perfluorooctanesulfonate
트리-n-헥실-n-테트라데실포스포늄 클로라이드 (Tri-n-hexyl-n-tetradecylphosphonium chloride)Tri-n-hexyl-n-tetradecylphosphonium chloride
트리옥틸메틸암모늄 티오살리실레이트 (Trioctylmethylammonium thiosalicylate)Trioctylmethylammonium thiosalicylate
트리 (2-하이드록시에틸) 메틸암모늄 메틸설페이트 (Tris (2-hydroxyethyl) methylammonium methylsulfate)Tri (2-hydroxyethyl) methylammonium methylsulfate
또한 유기 용매로는,In addition, as an organic solvent,
1,1,1,3,3,3-헥사플루오로-2-프로파놀 ( 1,1,1,3,3,3-hexafluoro-2-propanol)1,1,1,3,3,3-hexafluoro-2-propanol (1,1,1,3,3,3-hexafluoro-2-propanol)
1,1,1-트리클로로에탄 (1,1,1-trichloroethane)1,1,1-trichloroethane
1,1,2,2 - 테트라클로로에탄 (1,1,2,2-tetrachloroethane)1,1,2,2-tetrachloroethane (1,1,2,2-tetrachloroethane)
1,1,2- 트리클로로트리플루오로에탄(1,1,2-trichlorotrifluoroethane)1,1,2-trichlorotrifluoroethane
1,2,3,5-테트라메틸벤젠(1,2,3,5-tetramethylbenzene)1,2,3,5-tetramethylbenzene (1,2,3,5-tetramethylbenzene)
1,2-부탄디올 (1,2-butanediol)1,2-butanediol (1,2-butanediol)
1,2-디클로로벤진 (1,2-dichlorobenzene)1,2-dichlorobenzene
1,2-디클로로에탄 (1,2-dichloroethane)1,2-dichloroethane
1,2-디메톡시벤젠 (베라트롤) (1,2-dimethoxybenzene (veratrole))1,2-dimethoxybenzene (veratrole)
1,2-디메톡시에탄(모노글라임)(1,2-dimethoxyethane (monoglyme))1,2-dimethoxyethane (monoglyme)
1,2-프로판디올 (1,2-propanediol)1,2-propanediol (1,2-propanediol)
1,3-부탄디올(1,3-butanediol) 1,3-butanediol
1,3-디옥솔란(1,3-dioxolane)1,3-dioxolane (1,3-dioxolane)
1,3-프로판디올(1,3-propanediol)1,3-propanediol
1,4-부탄디올 (1,4-butanediol)1,4-butanediol (1,4-butanediol)
1,4-디메틸피페라진 (1,4-dimethylpiperazine)1,4-dimethylpiperazine (1,4-dimethylpiperazine)
1,4-디옥산 (1,4-dioxane)1,4-dioxane (1,4-dioxane)
1-부탄올 (1-butanol)1-butanol
1-클로로부탄 (1-chlorobutane)1-chlorobutane
1-데칸올 (1-decanol)1-decanol
1-헥산올 (1-hexanol)1-hexanol
1-메틸타프탈린 (1-methylnaphthalene)1-methyltaphthalin (1-methylnaphthalene)
1-메틸피페리딘 (1-methylpiperidine)1-methylpiperidine
1-메틸피롤 (1-methylpyrrole)1-methylpyrrole
1-메틸피롤리딘-2-one (1-methylpyrrolidin-2-one)1-methylpyrrolidin-2-one (1-methylpyrrolidin-2-one)
1-메틸피롤리딘 (1-methylpyrrolidine)1-methylpyrrolidine
1-노난올 (1-nonanol)1-nonanol
1-옥탄올 (1-octanol)1-octanol
1-펜탄올 (1-pentanol)1-pentanol
1-프로판올 (1-propanol)1-propanol
1-운데칸올 (1-undecanol)1-undecanol
2,2,2-트리클로로에탄올 (2,2,2-trichloroethanol)2,2,2-trichloroethanol
2,2,2-트리플루오로에탄올 (2,2,2-trifluoroethanol)2,2,2-trifluoroethanol
2,2,3,3-테트라플루오로-1-프로판올 (2,2,3,3-tetrafluoro-1-propanol)2,2,3,3-tetrafluoro-1-propanol
2,2,3,4,4,4-헥사플루오로-1-부탄올 (2,2,3,4,4,4-hexafluoro-1-butanol)2,2,3,4,4,4-hexafluoro-1-butanol (2,2,3,4,4,4-hexafluoro-1-butanol)
2,2,4- 트리메틸펜탄 (2,2,4-trimethylpentane)2,2,4-trimethylpentane
2,3-부탄디올 (2,3-butanediol)2,3-butanediol
2,4,6-트리메틸피리딘 (2,4,6-trimethylpyridine)2,4,6-trimethylpyridine
2,6-디메틸피리딘 (2,6-dimethylpyridine)2,6-dimethylpyridine
2-부탄올 (2-butanol)2-butanol
2-부탄온 (2-butanone)2-butanone
2-부톡시에탄올 (2-butoxyethanol)2-butoxyethanol
2-클오로에탄올 (2-chloroethanol)2-chloroethanol
2-헥산올 (2-hexanol)2-hexanol
2-메톡시에탄올 (2-methoxyethanol)2-methoxyethanol
2-메톡시에틸 에테르 (2-methoxyethylether (diglyme)) 2-methoxyethylether (diglyme)
2-메틸-1,3-프로판디올 (2-methyl-1,3-propanediol)2-methyl-1,3-propanediol
2-메틸-1-부탄올 (2-methyl-1-butanol)2-methyl-1-butanol
2-메틸-1-펜탄올 (2-methyl-1-pentanol)2-methyl-1-pentanol
2-메틸-1-프로판올 (2-methyl-1-propanol)2-methyl-1-propanol
2-메틸-2-부탄올 (2-methyl-2-butanol)2-methyl-2-butanol
2-메틸-2-프로판올 (2-methyl-2-propanol)2-methyl-2-propanol
2-메틸부탄 (2-methylbutane)2-methylbutane
2-메틸부티르 산 (2-methylbutiric acid)2-methylbutiric acid
2-메틸퓨란 (2-methylfuran)2-methylfuran
2-메틸피리딘 (2-methylpyridine)2-methylpyridine
2-메틸테트라히드로푸란 (2-methyltetrahydrofuran)2-methyltetrahydrofuran
2-옥탄올 (2-octanol)2-octanol
2-펜탄올 (2-pentanol)2-pentanol
2-펜탄온 (2-pentanone)2-pentanone
2-페닐에탄올 (2-phenylethanol)2-phenylethanol
2-프로판올 (2-propanol)2-propanol
2-피롤리디논 (2-pyrrolidinone) 2-pyrrolidinone
3,5,5- 트리메틸-2-시클로헥센온 (이소포론) (3,5,5-trimethyl-2-cyclohexenone (isophorone) 3,5,5-trimethyl-2-cyclohexenone (isophorone) (3,5,5-trimethyl-2-cyclohexenone (isophorone)
3-헥산올 (3-hexanol)3-hexanol
3-메틸-1-부탄올 (3-methyl-1-butanol)3-methyl-1-butanol
3-메틸-2-부탄올 (3-methyl-2-butanol)3-methyl-2-butanol
3-펜탄올 (3-pentanol)3-pentanol
3-펜탄온 (3-pentanone)3-pentanone
4-메틸-2-펜탄온 (4-methyl-2-pentanone )4-methyl-2-pentanone (4-methyl-2-pentanone)
아세트 산 (acetic acid)Acetic acid
아세톤 (acetone)Acetone
아세토나이트릴 (acetonitrile)Acetonitrile
아세토페논 (acetophenone)Acetophenone
알릴알코올 (2-프로페놀) (allyl alcohol (2-propenol))Allyl alcohol (2-propenol)
아니솔 (메틸페닐에테르) (anisol (methyl phenyl ether))Anisol (methyl phenyl ether)
벤젠 (benzene)Benzene
벤존나이트릴 (benzonitrile)Benzonitrile
벤질 알코올 (benzyl alcohol)Benzyl alcohol
브로모벤젠 (bromobenzene)Bromobenzene
부티로니트릴 (butyronitrile)Butyronitrile
카본 디술피드 (carbon disulfide)Carbon disulfide
클로로에세토나이트릴 (chloroacetonitrile)Chloroacetonitrile
클로로벤젠 (chlorobenzene)Chlorobenzene
클로로폼 (chloroform)Chloroform
시네올 (cineole)Cineole
시스-데칼린 (cis-decaline)Cis-decaline
사이클로헵테인 (cycloheptane)Cycloheptane
시클로헵탄올 (cycloheptanol)Cycloheptanol
시클로헥세인 (cyclohexane)Cyclohexane
시클로헥산올 (cyclohexanol)Cyclohexanol
시클로헥사논 (cyclohexanone)Cyclohexanone
시클로헥실아민 (cyclohexylamine)Cyclohexylamine
시클로옥탄 (cyclooctane)Cyclooctane
시클로옥탄올 (cyclooctanol)Cyclooctanol
시클로펜탄 (cyclopentane)Cyclopentane
시클로펜탄올 (cyclopentanol)Cyclopentanol
시클로펜탄온 (cyclopentanone)Cyclopentanone
데칼린 (decaline)Decaline
데칸 (decane)Decane
디벤질 에테르 (dibenzyl ether)Dibenzyl ether
디클로로아세트산 (dichloroacetic acid)Dichloroacetic acid
디클로로메틸렌 (dichloromethane)Dichloromethane
디에틸 에테르 (diethyl ether)Diethyl ether
디이소프로필 에테르 (diisopropyl ether)Diisopropyl ether
디메톡시메탄 (dimethoxymethane)Dimethoxymethane
디메틸 카보네이트 (dimethyl carbonate)Dimethyl carbonate
디메틸 설파이트 (dimethyl sulphite)Dimethyl sulphite
디메틸 술폭시드 (dimethyl sulfoxide)Dimethyl sulfoxide
디-n-부틸 에테르 (di-n-butyl ether)Di-n-butyl ether
디-n-부틸 옥살레이트 (di-n-butyl oxalate)Di-n-butyl oxalate
디-n-부틸아민 (di-n-butylamine)Di-n-butylamine
디-n-헥실 에테르 (di-n-hexyl ether)Di-n-hexyl ether
디-n-펜틸 에테르 (di-n-pentyl ether)Di-n-pentyl ether
디-n-프로필 에테르 (di-n-propyl ether)Di-n-propyl ether
도데칸 (dodecane)Dodecane
에탄올 (ethanol)Ethanol
에틸2-메톡시 아세테이트 (ethyl 2-methoxy acetate)Ethyl 2-methoxy acetate
에틸 아세테이트 (ethyl acetate)Ethyl acetate
에틸 벤조에이트 (ethyl benzoate)Ethyl benzoate
에틸 살리실네이트 (ethyl salicylate)Ethyl salicylate
에틸벤젠 (ethylbenzene)Ethylbenzene
에틸 시클로헥산 (ethylcyclohexane)Ethylcyclohexane
에틸렌글리콜 (1,2-에탄디올)ethylen glycol (1,2-ethanediol) Ethylene glycol (1,2-ethanediol)
에틸렌디아민 (ethylenediamine)Ethylenediamine
플루오로벤젠 (fluorobenzene)Fluorobenzene
포름아미드 (formamide)Formamide
프름산 (formic acid)Formic acid
퓨란 (furan)Furan
가스 (gas)Gas
g-부틸로락톤 (g-butyrolactone)g-butyrolactone
글리세롤 (glycerol (1,2,3-propanetriol))Glycerol (glycerol (1,2,3-propanetriol))
헵탄 (heptane)Heptane
헵탄산 (heptanoic acid)Heptanoic acid
헥사데칸 (hexadecane)Hexadecane
헥사플루오로벤젠 (hexafluorobenzene)Hexafluorobenzene
헥산 (hexane)Hexane
헥산산 (hexanoic acid)Hexanoic acid
헥사메틸포스포릭 산 트리아미드 (HMPA (hexamethylphosphoric acid triamide))Hexamethylphosphoric acid triamide (HMPA)
요오도벤젠 (iodobenzene)Iodobenzene
요오도화에틸 (iodoethane)Ethyl iodide
이소아밀아세테이트 (isoamyl acetate)Isoamyl acetate
이소부티르산 (isobutiric acid)Isobutiric acid
이소부티로니트릴 (isobutyronitrile)Isobutyronitrile
이소발레르산 (isovaleric acid)Isovaleric acid
m-크레졸 (m-cresol)m-cresol
메시틸렌 (mesitylene)Mesitylene
메탄올 (methanol) Methanol
아세트산 메틸(methyl acetate)Methyl acetate
벤조산메틸 (methyl benzoate)Methyl benzoate
포름산메틸 (methyl formate)Methyl formate
살리실산메틸 (methyl salicylate)Methyl salicylate
메틸시클로헥산 (methylcyclohexane)Methylcyclohexane
메틸렌 클로라이드 (Methylene chloride)Methylene chloride
모르폴린 (morpholine)Morpholine
m-크실렌 (m-xylene)m-xylene
N, N'-디메틸프로필렌우레아 (N, N'-dimethylpropyleneurea)N, N'-dimethylpropyleneurea
N, N- 디메틸아세트아미드 (N, N-diethylacetamide)N, N-dimethylacetamide (N, N-diethylacetamide)
N, N-디에틸포름아미드 (N, N-diethylformamide)N, N-diethylformamide
N, N-디메틸아세트아미드 (N, N-dimethylacetamide)N, N-dimethylacetamide
N, N-디메틸아닐린 (N, N-dimethylaniline)N, N-dimethylaniline
N, N-디메틸시클로헥실아민 (N, N-dimethylcyclohexylamine)N, N-dimethylcyclohexylamine
N, N-디메틸포름아미드 (N, N-dimethylformamide)N, N-dimethylformamide
n-아세트산부틸 (n-butyl acetate)n-butyl acetate
n-부틸 메틸 아민 (butyl methyl amine)n-butyl methyl amine
n-부틸메틸에테르 (n-butyl methyl ether)n-butyl methyl ether
n-부틸아민 (n-butylamine)n-butylamine
n-부틸벤젠 (n-butylbenzene)n-butylbenzene
n-부틸시클로헥산 (n-butylciclohexane)n-butylcyclohexane (n-butylciclohexane)
n- 부티르산 (n-butyric acid)n-butyric acid
니트로벤젠 (nitrobenzene)Nitrobenzene
니트로에탄 (nitroethane)Nitroethane
니트로메탄 (nitromethane)Nitromethane
N-메틸아세트아미드 (N-methylacetamide)N-methylacetamide
N-메틸아닐린 (N-methylaniline)N-methylaniline
N-메틸시클로헥실아민 (N-methylcyclohexylamine)N-methylcyclohexylamine
N-메틸포름아미드 (N-methylformamide)N-methylformamide
N-메틸이미다졸 (N-methylimidazole)N-methylimidazole
노난 (nonane)Nonane
노난산 (nonanoic acid)Nonanoic acid
n-프로필 아세테이트 (n-propyl acetate)n-propyl acetate
n-프로필 포메이트 (n-propyl formate)n-propyl formate
n-프로필벤젠 (n-propylbenzene)n-propylbenzene
n-프로필시클로헥산 (n-propylcyclohexane)n-propylcyclohexane
옥탄 (octane)Octane
옥탄산 (octanoic acid)Octanoic acid
자일렌 (o-xylene)Xylene (o-xylene)
펜타데케인 (pentadecane)Pentadecane (pentadecane)
펜타플루오로프로피닉 산 (pentafluoropropionic acid)Pentafluoropropionic acid
펜탄 (pentane)Pentane
퍼플루오로헥산 (perfluorohexane)Perfluorohexane
퍼플루오루피리딘 (perfluoropyridine)Perfluoropyridine
석유 에테르 (petroleum ether) Petroleum ether
피페리딘 (piperidine)Piperidine
프로파길알코올 (propargyl alcohol (2-propynol))Propargyl alcohol (2-propynol)
프로피온산 (propionic acid)Propionic acid
프로피오니트릴 (propionitrile)Propionitrile
프로피오페논 (propiophenone)Propiophenone
프로필렌 카보네이트 (propylene carbonate)Propylene carbonate
p-크실렌 (p-xylene)p-xylene
피라딘 (pyridine)Pyridine
피롤 (pyrrole)Pyrrole
피롤리딘 (pyrrolidine)Pyrrolidine
술포란 (sulfolane)Sulfolane
tert-부틸메틸에테르 (tert-butyl methyl ether)tert-butyl methyl ether
tert-부틸벤젠 (tert-butylbenzene)tert-butylbenzene
tert-부틸시클로헥산 (tert-butylcyclohexane)tert-butylcyclohexane
테트라클로로메탄 (tetrachloromethane)Tetrachloromethane
테트라히드로푸란 (tetrahydrofuran)Tetrahydrofuran
테트라히드로피란 (tetrahydropyran)Tetrahydropyran
테트라히드로티오펜 (tetrahydrothiophene)Tetrahydrothiophene
테트랄린 (tetraline)Tetraline
테트라메틸구아니딘 (tetramethylguanidine)Tetramethylguanidine
테트라메틸요소 (tetramethylurea)Tetramethylurea
티오아니솔 (thioanisole)Thioanisole
톨루엔 (toluene)Toluene
트라이아세틴 (triacetin)Triacetin
트리클로로에텐 (trichloroethene)Trichloroethene
트라이에틸 인산염 (triethyl phosphate)Triethyl phosphate
트라이에틸 아인산염 (triethyl phosphite)Triethyl phosphite
트리에틸아민 (triethylamine)Triethylamine
트리플루오로아세트산 (trifluoroacetic acid)Trifluoroacetic acid
트리플루오로-m-크레졸 (trifluoro - m-cresol)Trifluoro-m-cresol
트리플루오로메틸벤진 (trifluoromethylbenzene)Trifluoromethylbenzene
트리메틸 trimethyl orthoformate Trimethyl trimethyl orthoformate
트리메틸 trimethyl phosphate Trimethyl trimethyl phosphate
트리메틸 trimethyl phosphite Trimethyl trimethyl phosphite
트리메틸아세트 산 (trimethylacetic acid)Trimethylacetic acid
트리-N-부틸아민(tri-n-butylamine)Tri-n-butylamine
트리-n-프로필아민 (tri-n-propylamine)Tri-n-propylamine
운데칸 (undecane)Undecane
발레르 산 (valeric acid)Valeric acid
발레로니트릴 (valeronitrile) Valeronitrile
또는 이들의 혼합물을 사용할 수 있다.Or mixtures thereof.
본 발명의 캐퍼시터용 전해액은 통상 -20∼50℃의 온도 범위, 더 넓게는 -50∼400℃에서도 안정한 특성을 유지한다. 본 발명의 전해액은 전기 이중층 캐퍼시터 또는 의사 캐퍼시터 등에 적용될 수 있다.The electrolyte solution for capacitors of the present invention maintains stable characteristics even at a temperature range of -20 to 50 ° C, more broadly at -50 to 400 ° C. The electrolyte of the present invention can be applied to an electric double layer capacitor or a pseudo capacitor.
기체(1)Gas (1)
본 발명에 따른 각형 2차 전지의 기체(1)는 기본 외형을 구성하고, 내부에 수용되는 전해질 및 전해액을 보호하는 것으로, 철, 합금강, 니켈 도금강, 합성수지 등 여러 재질이 선택적으로 사용될 수 있고, 직사각, 정사각 등의 기본 형태는 몰론 마름모, 사다리꼴, 평형사변형, 삼각형 등 각(角)진 형태는 어떠한 형상으로도 제작될 수 있다. The
예를 들어 첨부된 도 1은 자동차 등에 사용되는 각형 2차 전지의 일예이고, 첨부된 도 4는 핸드폰 등에 사용되는 형태이다. For example, FIG. 1 is an example of a rectangular secondary battery used in an automobile and the like, and FIG. 4 is attached to a cellular phone.
또한 본 발명은 전극과 세퍼레이터가 교호로 세워지는 형태와, 도 3같이 감아지는 형태 또는 지그 재기 형태로 접어지는 구성으로 이루어질 수 있다. In addition, the present invention may be made of a configuration in which the electrode and the separator is erected alternately, and folded in a wound form or a jig measuring form as shown in FIG.
도면 부호 200은 스위치이다.
이 스위치는 본 발명이 적용되는 장치에 끼워졌을 때 이 스위치가 접속하여 ON 상태가 되었을 때만 충전 또는 방전이 이루어지도록 하는 것으로, 대용량을 충전하고 있는 발명의 전지가 외부적인 요인에 의해 순간 방전으로 폭발할 수 있는 위험을 방지하기 위한 것이다. When the switch is plugged into a device to which the present invention is applied, the switch can be charged or discharged only when the switch is connected to the ON state. The battery of the present invention, which is charged with a large capacity, is exploded by instant discharge due to external factors. It is to prevent the danger that can be done.
여기서 스위치는 접촉식, 누름 방식 등 어떠한 것도 가능하며, 도면과 같이 상면에만 위치하는 것이 아니라 기체 어느 위치에 있어도 무방하며, 본 발명이 사용되는 장치에는 스위치와 접속하는 수단이 구비되는 것은 당연한 것이다.In this case, the switch can be any type such as a contact type or a push method, and may be located at any position of the gas as well as the upper surface as shown in the drawing, and it is natural that the device to which the present invention is used is provided with means for connecting to the switch.
집전체(10)Current collector (10)
본 발명에 따른 집전체(10)는 대향 배치되는 양극(+)집전체와, 음극(-)집전체로 구성되고, 이들은 알루미늄(Al), 구리(Cu), 금(AU) 또는 다른 여러 종의 금속으로 구성될 수 있으며, 본 발명에서는 구리를 양극집전체로, 알루미늄을 음극집전체로 사용하는 것이 바람직하다.The
상기 양극집전체와 음극집전체는 서로 마주보는 형태로, 각각에는 전극이 접합되도록 하되, 필요에 따라서는 도포, 증착 방법으로도 구성될 수 있다. The positive electrode current collector and the negative electrode current collector are in the form of facing each other, so that the electrodes are bonded to each other, if necessary, it may also be configured as a coating, deposition method.
한편, 첨부된 도 5 내지 7은 본 발명의 다른 실시 예를 도시한 것이다.On the other hand, Figures 5 to 7 attached to illustrate another embodiment of the present invention.
이 실시 예는 단 시간에 많은 량의 에너지가 충전 또는 방전되는 것을 대비하여 위한 것으로, 접속 면적을 크게 증가시킨 구조이다. This embodiment is to prepare for the charging or discharging of a large amount of energy in a short time, and has a structure of greatly increasing the connection area.
예를 들어, 각형 2차 전지를 포함하는 2차 전지에는 얇고 폭이 좁은 단자가 집전체와 연결되어 이를 통해 충전 및 방전이 이루어진다. For example, in a secondary battery including a rectangular secondary battery, a thin and narrow terminal is connected to a current collector to thereby charge and discharge the battery.
그러나 이러한 형태는 충전 용량이 대단히 크고, 충전 및 방전이 급속도로 이루어지는 본 발명에서 단자가 끓어질 우려가 있다. However, this type has a very large charge capacity, and there is a fear that the terminal will boil in the present invention in which charging and discharging are rapidly performed.
따라서 본 발명은 접속 면적을 증가시키는 방법으로, 도면과 같이 음극집전체와 양극집전체를 서로 엇갈리게 배치하고, 상부 및 하부로 돌출된 각 집전체 전체가 외부 단자와 연결되도록 하는 것이다. Accordingly, the present invention is a method of increasing the connection area, and as shown in the drawing, the negative electrode current collector and the positive electrode current collector are alternately arranged so that each of the current collectors projecting to the upper and lower portions is connected to the external terminals.
물론 돌출된 집전체에 별도의 캡을 씌우고, 이 캡과 외부 단자를 연결하는 예도 가능하다. 여기서 캡은 돌출된 집전체를 강제로 누르며 씌워지는 캡과, 캡 안쪽으로 벽을 세워 이 벽들 사이 사이에 집전체를 끼워져 접속 면적을 증가시키는 구성도 있다.Of course, a separate cap is put on the protruding current collector, and an example of connecting the cap and the external terminal is also possible. Here, the cap has a configuration in which a cap is covered by forcibly pressing the protruding current collector, and a wall is formed inside the cap to insert a current collector between the walls to increase the connection area.
전극(20)
본 발명의 상기 전극(20)은 분극성 또는/및 전도성으로 구성될 수 있으며, 하나의 각형 2차 전지에 동일한 형태로 구비되거나 서로 다른 형태로 전극이 구비될 수 있다. The
예를 들어, 양극집전체 또는 음극집전체에 접합된 전극 중 어느 하나는 분극성 전극으로 구성되고, 다른 집전체에는 분극성과 전도성을 모두 갖는 전극이 접합되는 것이다.For example, any one of the electrodes bonded to the positive electrode current collector or the negative electrode current collector is composed of a polarizable electrode, and the electrode having both polarity and conductivity is bonded to the other current collector.
상기 전극(20)은 활성탄, 그래핀, 흑연 또는 탄소나노튜브, 풀러렌, 테프론 중 어느 하나가 사용되며, 동일한 재질 또는 음극과 양극이 서로 다른 재질로 구성될 수 있다. The
또한 톱밥 활성탄, 야시가라 활성탄, 피치ㆍ코크스(pichcokes)계 활성탄, 페놀 수지계 활성탄, 폴리아크릴로니트릴계 활성탄, 셀룰로오스계 활성탄 등으로 제조될 수 있으며, 여기에 금속 산화물계 재료로, 예를 들면 산화루테늄, 산화망간, 산화코발트 등을 들 수 있다. 도전성 고분자 재료도 사용될 수 잇으며, 예를 들면 폴리아닐린막, 폴리피롤막, 폴리티오펜막, 폴리(3,4-에틸렌디옥시티오펜)막 등을 예로 들 수 있다.It may also be made of sawdust activated carbon, yashigara activated carbon, pichcokes activated carbon, phenolic resin activated carbon, polyacrylonitrile activated carbon, cellulose activated carbon, and the like. Ruthenium, manganese oxide, cobalt oxide, etc. are mentioned. Conductive polymer materials may also be used, and examples thereof include polyaniline membranes, polypyrrole membranes, polythiophene membranes, poly (3,4-ethylenedioxythiophene) membranes, and the like.
이온내포풀러렌에 대해 분극성을 갖는 전극은, 활성탄이나 테프론을 접합제(Binder)를 사용하여 집전체에 접합시켜 구성하거나, 또는 그래핀이나 풀러렌이 분극성을 갖도록 접합하는 것이 바람직하다.It is preferable that the electrode which has polarization with respect to ion-containing fullerene is comprised by bonding activated carbon and Teflon to a collector using a binder, or bonding so that graphene or fullerene may have polarization.
이온내포풀러렌에 대해 분극성과 전도성을 모두 갖는 전극은, 집전체에 활성탄, 그래핀, 탄소나노튜브, 또는 풀러렌이 분극성과 전도성을 갖도록 접합하여 구성한다.The electrode having both polarization and conductivity with respect to the ion-containing fullerene is formed by bonding an activated carbon, graphene, carbon nanotube, or fullerene to the current collector so as to have polarization and conductivity.
여기서 분극성을 갖는 다공질의 활성탄은 야자열매 섬유를 탄소화시켜 만든다. 이렇게 만들어진 활성탄을 접합제를 사용하여 집전체에 접합시키면 이온내포풀러렌에 대해 분극성을 갖는 전극이 만들어지게 된다. 예를 들어 이온내포풀러렌에 대해 분극성과 전도성을 갖는 활성탄은, 분극성을 갖는 활성탄에 요오드(I3)와 같은 할로젠 원소 등을 도핑하여 만든다. Porous activated carbon having polarity is made by carbonizing coconut fiber. When the activated carbon is bonded to the current collector using a binder, an electrode having polarization with respect to ion-containing fullerene is produced. For example, activated carbon having polarity and conductivity with respect to ion-containing fullerene is made by doping a polarized activated carbon with a halogen element such as iodine (I3).
이렇게 만들어진 활성탄을 접합제를 사용하여 집전체에 접합시키면 이온내포풀러렌에 대해 분극성과 전도성을 갖는 전극이 만들어지게 되는 것이다.When the activated carbon is bonded to the current collector using a binder, an electrode having polarity and conductivity with respect to ion-containing fullerene is made.
다른 예로, 본 발명에 적용되는 그래핀은 탄소가 육각형의 형태로 서로 연결되어 벌집 모양의 2차원 평면 구조를 이루는 물질로, 도면에 표시되는 바와 같이, 2차원 평면인 x-y축으로는 전자가 흐를 수 있어 전도성을 갖지만, z축으로는 비전도성을 갖는 특성이 있는 물질이다.As another example, the graphene applied to the present invention is a material in which carbon is connected to each other in the form of a hexagon to form a honeycomb two-dimensional planar structure. As shown in the drawing, electrons flow in the xy axis, which is a two-dimensional plane. It can be conductive, but the z-axis is a non-conductive material.
따라서 도8b에서 도시되는 바와 같이, 집전체 면에 그래핀의 2차원 평면이 평행하게 놓이도록 접합하면 이온내포풀러렌에 대해 분극성을 갖는 전극이 만들어지고, 도8c에서 도시되는 바와 같이 집전체에 그래핀의 2차원 평면이 수직이 되도록 접합하면 이온내포풀러렌에 대해 분극성과 전도성을 갖는 전극이 만들어지는 것이다.Therefore, as shown in FIG. 8B, when the two-dimensional plane of graphene is bonded in parallel to the current collector surface, an electrode having polarization with respect to the ion-containing fullerene is formed, and the current collector is shown in FIG. 8C. When the two-dimensional plane of the graphene is bonded to be perpendicular to each other, an electrode having polarity and conductivity with respect to the ion-containing fullerene is formed.
또 다른 전극으로 본 발명은 탄소나노튜브가 사용될 수 있다. As another electrode of the present invention, carbon nanotubes may be used.
이 탄소나노튜브는 이미 알려진 바와 같이, 탄소 6개로 이루어진 육각 모양이 서로 연결되어 관 모양을 이루고 있는 것으로 합성 조건에 따라 관의 지름을 다르게 할 수 있다. As known, the carbon nanotubes are hexagonal shapes of six carbons connected to each other to form a tubular shape. The carbon nanotubes may have different diameters according to synthetic conditions.
도 9에 도시되는 바와 같이 키랄성(Chirality)를 제어하여 전기적 특성을 제어할 수 있는데 이를 이용하여 탄소나노튜브가 이온내포풀러렌에 대해 분극성만 갖도록 하거나, 또는 분극성과 전도성 모두를 갖도록 만들 수 있다. 따라서 집전체에 탄소나노튜브를 성장시킬 시 키랄성을 제어하여 전도성이 없도록 성장시키면 이온내포풀러렌에 대해 분극성만 갖는 전극이 만들어지며, 키랄성을 제어하여 전도성을 갖도록 성장시키면 이온내포풀러렌에 대해 분극성과 전도성을 모두 갖는 전극을 만들 수 있다.As shown in FIG. 9, the chirality may be controlled to control electrical characteristics, and the carbon nanotubes may be made to have only polarity with respect to the ion-containing fullerene, or may have both polarity and conductivity. Therefore, when growing carbon nanotubes on a current collector, the chirality is controlled so that there is no conductivity, and an electrode having only polarity with respect to the ion-pooferene is made. It is possible to make an electrode having both conductivity.
다시 말해, 탄소나노튜브의 키랄성은 형성된 6각형의 구조에 따른 키랄 벡터(chiral vector) 지수로, 의자형(n=m), 나선형(n,m), 지그재그형(n,O) 등이 있다. 탄소나노튜브는 각각의 형태에 따라 반도체 또는 금속과 같은 전기적인 특성을 나타내는 것이다.In other words, the chirality of carbon nanotubes is a chiral vector index according to the hexagonal structure formed, and includes a chair type (n = m), a spiral shape (n, m), and a zigzag shape (n, O). . Carbon nanotubes exhibit electrical characteristics such as semiconductors or metals according to their respective forms.
또 다른 예로 본 발명은 상기 전극(20)으로 풀러렌이 사용될 수 있다.In another example, in the present invention, fullerene may be used as the
이 풀러렌은 레이저를 조사하면 풀러렌을 결합시킬 수 있다. 도6a는 2개의 풀러렌이 결합되는 것을 나타낸 것이고, 도 6b와 도 6c는 x-y 평면으로 결합된 것을 나타낸 것이다. 두 개 이상의 풀러렌이 결합된 풀러렌은 결합 방향과 인가되는 전압에 따라 전기전도도가 달라지며 이를 조절하여 분극성만 가지는 전극, 또는 분극성과 전도성을 모두 가지는 전극을 만들 수 있다.The fullerenes can bind fullerenes by irradiating a laser. Figure 6a shows that the two fullerenes are combined, Figures 6b and 6c shows the combined in the x-y plane. Fullerenes in which two or more fullerenes are combined have different electrical conductivity depending on the coupling direction and the voltage applied thereto, thereby making it possible to make an electrode having only polarity or an electrode having both polarity and conductivity.
풀러렌과 집전체와의 결합은 풀러렌이 구리(Cu)나 금(Au)의 표면에 흡착되는 성질을 이용하여 결합시킬 수 있다. 즉, 밀러 지수(Miller index)를 갖는 구리(Cu)나 금(Au)의 밀러면 위에 풀러렌을 놓으면, 도7에 도시되는 바와 같이, 풀러렌이 집전체로 사용되는 금(Au)이나 구리(Cu)에 흡착되는 되는데 이를 이용하여 집전체 위에 풀러렌 전극을 형성하는 것이다. 이와는 별도로 풀러렌을 집전체 위에 접합제를 사용하여 접합시킬 수도 있다.The fullerene may be bonded to the current collector by using the property that the fullerene is adsorbed on the surface of copper (Cu) or gold (Au). That is, when fullerene is placed on the mirror surface of copper (Cu) or gold (Au) having a Miller index, as shown in FIG. 7, gold or copper (Cu) in which fullerene is used as a current collector. Is used to form a fullerene electrode on the current collector. Separately, fullerene can also be bonded on a collector using a binder.
또한 본 발명의 각형 2차 전지는 세퍼레이터가 포함되며, 이 세퍼레이터로서는 전자 절연성이 높고, 전해액의 습윤성이 우수하여 이온 투과성이 높은 것이 바람직하고, 또한 인가 전압 범위 내에 있어서 전기 화학적으로 안정될 필요가 있다. 세퍼레이터의 재질은 특별히 한정은 없지만, 레이온이나 마닐라삼 등을 포함하는 초지; 폴리올레핀계 다공질 필름; 폴리에틸렌 부직포; 폴리프로필렌 부직포, 유리 섬유 등이 바람직하게 이용된다. Moreover, the rectangular secondary battery of this invention contains a separator, It is preferable that this separator has high electronic insulation, excellent wettability of electrolyte solution, and high ion permeability, and it needs to be electrochemically stable within the applied voltage range. . The material of the separator is not particularly limited, but includes paper made of rayon or manila hemp; Polyolefin porous film; Polyethylene nonwovens; Polypropylene nonwovens, glass fibers and the like are preferably used.
한편, 본 발명은 탄소나노튜브 전극을 구성할 수 있다. On the other hand, the present invention can constitute a carbon nanotube electrode.
음극집전체 및 양극집전체로 이루어지는 본 발명에서, 이들 집전체 중 어느 하나에 탄소나노튜브를 성장 또는 접합하여 전극으로 구성하고, 다른 집전체에는 활성탄 등의 제2전극이 접합하는 것이다. In the present invention comprising a negative electrode current collector and a positive electrode current collector, carbon nanotubes are grown or bonded to any one of these current collectors to form an electrode, and a second electrode such as activated carbon is bonded to the other current collector.
당연하게도 상기 탄소나노튜브 전극은 분극성 또는 분극성과 전도성을 모두 갖는 전극이 선택될 수 있으며, 제2전극 역시 분극성 또는 분극성과 전도성을 모두는 전극이 선택적으로 사용될 수 있다. Naturally, the carbon nanotube electrode may be an electrode having both polarity or polarity and conductivity, and the second electrode may also be selectively used as an electrode having both polarity or polarity and conductivity.
상기 탄소나노튜브 전극은 상기한 바와 같이 키랄성(Chirality)를 제어하여 전기적 특성을 제어하고, 제 2전극은 활성탄 또는 테프론으로 분극성을 구성한다.As described above, the carbon nanotube electrode controls chirality to control electrical properties, and the second electrode is polarized with activated carbon or Teflon.
또한 제 2전극은 상기한 바와 같이, 그래핀의 접합 방향을 제어하여 분극성을 갖도록 구성하거나, 탄소나노튜브의 키랄성을 제어하여 분극성을 갖도록 구성하거나, 또는 풀러렌의 접합 방향을 제어하는 것으로 분극성을 갖도록 한다. In addition, as described above, the second electrode may be configured to have polarization by controlling the bonding direction of graphene, or may be configured to have polarity by controlling chirality of carbon nanotubes, or to control the bonding direction of fullerene. Make it polar.
상기 제 2전극은 활성탄에 할로겐 원소를 도핑하여 상기 활성탄이 전도성을 갖도록 함으로써 상기 이온내포풀러렌에 대해 분극성과 전도성을 갖도록 하거나, 그래핀의 접합 방향을 제어하거나 또는 풀러렌의 접합 방향을 제어하여 상기 그래핀 또는 풀러렌이 전도성을 갖도록 하는 것이다. The second electrode is doped with a halogen element to the activated carbon so that the activated carbon has conductivity to have polarity and conductivity to the ion-containing fullerene, to control the bonding direction of graphene or to control the bonding direction of fullerene The fin or fullerene is to be conductive.
본 발명의 또 다른 특징은 상기 탄소나노튜브의 전극에 이온내포풀러렌이 주입되는 것이다. 이온내포풀러렌이 주입됨으로서 이온과 전극이 최단 거리에 위치하고, 따라서 충전 특성 및 방전 특성이 비약적으로 향상된다. Another feature of the present invention is that ion-encapsulated fullerene is injected into the electrode of the carbon nanotube. By implanting the iontophorus fullerene, the ions and the electrode are positioned at the shortest distance, and thus the charging and discharging characteristics are remarkably improved.
바람직하기로 상기 이온내포풀러렌은 리튬이온내포풀러렌이 좋다. Preferably, the ion containing fullerene is preferably lithium ion containing fullerene.
진공챔버(12)Vacuum Chamber (12)
한편 본 발명의 각형 2차 전지의 내부에는 진공챔버를 구비하여, 전하의 충전 작용이 진공 중에서 이루어지도록 함으로써, 아주 낮은 전압부터 수십만 kV에 이르는 전압에 이르기까지 충전이 가능함은 물론, 충전 용량을 비약적으로 향상시키고, 충전 특성 및 방전 특성을 향상시키도록 한다. On the other hand, the inside of the rectangular secondary battery of the present invention is provided with a vacuum chamber, so that the charging operation of the charge is carried out in a vacuum, it is possible to charge from a very low voltage to a voltage of up to several hundred thousand kV, as well as to increase the charging capacity To improve the charging and discharging characteristics.
본 발명에 따른 진공챔버는 탄화규소, 유리, 석영 또는 플라스틱, 비철금속 중 어느 하나로 형성되도록 하되, 본 발명에서는 탄소나노튜브가 성장할 수 있는 탄화규소를 이용하여 진공챔버를 성형하는 것이 바람직하다.The vacuum chamber according to the present invention is formed of any one of silicon carbide, glass, quartz or plastic, and non-ferrous metal, but in the present invention, it is preferable to mold the vacuum chamber using silicon carbide capable of growing carbon nanotubes.
본 발명의 진공챔버는 기체와 동일 유사하게 사각 형상으로 성형 또는 다른 여러 방식으로 제작될 수 있다. The vacuum chamber of the present invention can be molded or otherwise produced in a square shape similarly to gas.
상기 진공챔버를 이용한 본 발명의 2차 전지는, 탄화수소로 진공챔버를 성형하는 단계와, 상기 진공챔버의 내면에 집전체를 접합하는 단계와, 상기 집전체에 탄소나노튜브를 형성하는 단계와, 상기 탄소나노튜브에 전해질을 구성하는 이온내포풀러렌을 주입하는 단계와, 상기 진공 단계와, 밀봉 단계;로 구성된다. In the secondary battery of the present invention using the vacuum chamber, forming a vacuum chamber with hydrocarbon, bonding a current collector to the inner surface of the vacuum chamber, forming a carbon nanotube on the current collector, Injecting the ion-containing fullerene constituting the electrolyte to the carbon nanotubes, the vacuum step, and the sealing step.
다른 실시 예로 본 발명은, 탄화수소 또는 유리로 진공챔버를 성형하는 단계와, 베이스판에 집전체를 설치하고 이 집전체에 전극을 접합하는 단계와, 상기 베이스판을 상기 진공챔버에 조립하여 집전체가 진공챔버에 끼워지도록 하는 단계와, 상기 베이스판과 진공챔버를 열 융착하는 단계와, 상기 진공 단계와, 밀봉 단계;로 구성된다. In another embodiment, the present invention, forming a vacuum chamber with a hydrocarbon or glass, installing a current collector on the base plate and bonding the electrode to the current collector, and assembling the base plate to the vacuum chamber Is inserted into the vacuum chamber, heat-sealing the base plate and the vacuum chamber, the vacuum step, and the sealing step.
또 다른 실시 예로 본 발명은, 탄화수소 또는 유리로 진공챔버를 성형하는 단계와, 베이스판에 음극집전체와 양극집전체를 설치하는 단계와, 상기 집전체 중 어느 하나에는 탄소나노튜브가 형성되고 다른 집전체에는 제 2전극을 형성하는 단계와, 상기 베이스판을 상기 진공챔버에 조립하여 집전체가 진공챔버에 끼워지도록 하는 단계와, 상기 베이스판과 진공챔버를 열 융착하는 단계와, 상기 진공 단계와, 밀봉 단계;로 구성된다. In another embodiment, the present invention, the step of forming a vacuum chamber with a hydrocarbon or glass, the step of installing a negative electrode current collector and a positive electrode current collector on the base plate, carbon nanotubes are formed on any one of the current collector and other Forming a second electrode on a current collector, assembling the base plate to the vacuum chamber so that a current collector is fitted into the vacuum chamber, heat-sealing the base plate and the vacuum chamber, and the vacuum step And a sealing step.
여기서 상기 탄소나노튜브에는 특징적으로 이온내포풀러렌이 주입되고, 상기 제 2전극은 활성탄, 그래핀, 흑연 또는 탄소나노튜브, 풀러렌, 테프론 중 어느 하나가 사용되며, 상기한 바와 같이 분극성 또는 분극성과 전도성 모두를 갖는 전극 중 하나가 선택된다. Here, the carbon nanotubes are characterized by implanting ion-encapsulated fullerenes, and the second electrode may be any one of activated carbon, graphene, graphite, carbon nanotubes, fullerenes, and teflon. One of the electrodes with both conductivity is selected.
한편, 본 발명은 공기를 빼내는 진공 작업 중 주입된 전해질의 음이온과 양이온이 서로 작용하여 외부로 유출되지 않는 특성을 갖는다. 따라서 본 발명은 전해질의 유출 없이 자연스럽게 진공을 진행 할 수 있다.On the other hand, the present invention has the characteristic that the anion and cation of the electrolyte injected during the vacuum operation to extract the air does not flow to the outside by interacting with each other. Therefore, the present invention can proceed with the vacuum naturally without the outflow of the electrolyte.
첨부된 도 3 및 도 4는 본 발명에 따른 진공챔버의 예를 도시한 것이다. 3 and 4 show an example of a vacuum chamber according to the present invention.
이중 도 3은 상부에 확관(14)이 마련되고, 이 확관(14)의 하부에 병목부(16)가 마련된 구성으로, 내부에 전극을 형성한 상태에서, 확관에 진공펌프가 연결되어 공기를 빼내고, 진공 작업 후 병목부에 열을 가해 용접하여 밀봉하는 것이다 3 is a configuration in which an
다른 예로 도 3의 진공챔버에서 저면이 개방된 상태로 구성하고, 이 저면의 개방부를 통해 집전체와 전극을 형성한 다음, 동일한 재질의 바닥판으로 열융착하여 밀봉하는 것이다.As another example, the bottom surface is opened in the vacuum chamber of FIG. 3, the current collector and the electrode are formed through the opening of the bottom surface, and then heat-sealed and sealed with a bottom plate of the same material.
또 다른 에로 본 발명은 도 4와 같이, 저면이 개방된 진공부재를 마련하고, 베이스판을 이용하여 전극이 수납되도록 한 다음 베이스판과 진공부재를 열 융착하는 것이다.According to another embodiment of the present invention, as shown in FIG. 4, a vacuum member having an open bottom is provided, an electrode is accommodated using a base plate, and then the base plate and the vacuum member are heat-sealed.
예컨대, 유리 등으로 이루어진 베이스판을 구성하고, 이 베이스판 위에 양극집전체와 음극집전체를 세워 구성하는 것이다. 상기 양극 및 음극집전체 중 어느 하나에는 탄소나노튜브가 형성되고, 다른 집전체에는 활성탄으로 이루어진 제2전극이 접합된다. 또한 상기 탄소나노튜브에는 이온내포풀러렌이 주입되며, 상기 탄소나노튜브와 제2전극은 분극성 또는 분극성과 전도성을 모두 갖는 전극 중 선택적으로 구성된다. For example, a base plate made of glass or the like is formed, and a positive electrode current collector and a negative electrode current collector are placed on the base plate to constitute it. Carbon nanotubes are formed on any one of the positive electrode and the negative electrode current collector, and a second electrode made of activated carbon is bonded to the other current collector. In addition, the ion nanoporous fullerene is injected into the carbon nanotubes, and the carbon nanotubes and the second electrode are selectively configured among electrodes having polarization or polarity and conductivity.
이 상태에서 상기 베이스판을 진공부재의 저면 개방부에 끼워지며, 양극집전체와 음극집전체는 진공챔버 내부에 위치하고, 베이스판과 개방부를 열 융착하는 것으로 마무리한다. 이후 베이스판에 구비된 확관을 통해 빼낸 다음 밀봉하여 2차 전지를 제조하는 것이다. In this state, the base plate is fitted to the bottom opening of the vacuum member, and the positive electrode collector and the negative electrode collector are positioned inside the vacuum chamber, and the base plate and the open portion are thermally fused. After the extraction through the expansion pipe provided in the base plate is sealed to manufacture a secondary battery.
한편, 본 발명은, 진공챔버에 음극 및 양극집전체가 접합 또는 수납되는 것으로 설명되고 있으나, 경우에 따라서는 여러 겹의 집전체와 전극이 코일형 또는 동심원으로 감아진 상태로 진공챔버에 넣어지거나 평판 형태의 집전체 및 전극 여려 겹이 끼워지는 것도 당연하게 구성될 수 있다.On the other hand, the present invention has been described that the negative electrode and the positive electrode current collector is bonded or housed in the vacuum chamber, in some cases, the current collector and the electrode of several layers are put in the vacuum chamber in a coiled or concentric state Naturally, the current collector in the form of a plate and a plurality of electrodes may also be fitted.
이하 본 발명에 따른 각형 2차 전지의 실시 예를 설명한다. Hereinafter, an embodiment of a square secondary battery according to the present invention will be described.
[제1실 시예][Example 1 room]
본 발명의 제 1실시 예는 비수성 전해액(E)을 이용한 각형 2차 전지이다. (도 14 참조)A first embodiment of the present invention is a rectangular secondary battery using a non-aqueous electrolyte (E). (See Figure 14)
기체는 도 1 및 도 4와 같이 정육면체 또는 직육면체로 구성되고, 이 기체 내부에 집전체와 전극 그리고 비수성 전해액이 충진되는 것이다. The base is composed of a cube or a cube, as shown in Figs. 1 and 4, in which a current collector, an electrode, and a non-aqueous electrolyte are filled.
상기 기체(1)의 내부에 집전체(10) 즉 구리(CU) 이루어진 양극집전체, 알루미늄(Al)으로 음극집전체를 구성하되, 경우에 따라 도 4 및 도 7에 도시된 바와 같이 음극집전체와 양측집전체를 서로 엇갈리게 배치하고, 각각의 돌출 부위에 접속 캡을 씌운 다음 외부 단자와 연결하는 구성도 있다. The negative electrode current collector is composed of a positive electrode current collector made of a
상기 각 집전체에는 분극성 또는 분극성과 전도성을 모두 가지는 전극(20)이 선택적으로 접합된다.Each of the current collectors is selectively bonded to the
구체적으로 본 발명은 알루미늄으로 이루어진 음극집전체와 구리로 이루어진 양극집전체 위에 활성탄을 접합제로 접합한 후, 할로젠 원소인 요오드를 도핑하여 분극성과 전도성을 갖는 전극을 만들 수 있다. Specifically, after bonding the activated carbon to the anode current collector made of aluminum and the cathode current collector made of copper with a binder, the electrode having polarization and conductivity can be made by doping iodine which is a halogen element.
여기에 이온내포풀러렌(30)을 포함하는 비수성 전해액이 충진된다. It is filled with a non-aqueous electrolyte solution containing the ion-containing
비수성 전해액은 (A) 이온내포 풀러렌 또는 그 염 또는/및 (B) 이온액체 폴리머; (C) 비수성 유기용매; (D) 할로겐 치환 방향족 탄화수소를 포함한다. The non-aqueous electrolyte solution includes (A) ion-containing fullerene or salt thereof and / or (B) ionic liquid polymer; (C) a non-aqueous organic solvent; (D) halogen substituted aromatic hydrocarbons.
이중 하나의 실시 예는 상기 비수성 유기 용매와 할로겐 치환 방향족 탄화수소를 1:1로 혼합하고, 이 유기 용매 혼합물 100중량부에 대하여 전해질 리튜이온내포풀러렌 0.1 ∼ 50중량부가 포함하는 전해액을 충진한다.In one embodiment, the non-aqueous organic solvent and the halogen-substituted aromatic hydrocarbon are mixed 1: 1, and an electrolyte solution containing 0.1-50 parts by weight of the electrolyte lithium ion-pofullerene is filled with respect to 100 parts by weight of the organic solvent mixture.
또 다른 실시 예는 상기 비수성 유기 용매와 할로겐 치환 방향족 탄화수소를 1:1로 혼합하고, 이 유기 용매 혼합물 100중량부에 대하여 전해질 리튜이온내포풀러렌 0.1 ∼ 50중량부, 양이온 폴리머 또는 음이온 폴리머 또는 이중성 폴리머 중 어느 하나의 폴리머 1 ∼ 50중량부가 더 포함된 비수성 전해액을 충진하는 것이다.In another embodiment, the non-aqueous organic solvent and the halogen-substituted aromatic hydrocarbon are mixed in a 1: 1 ratio, and 0.1-50 parts by weight of the electrolyte litionic ionpofullerene, a cationic polymer or an anionic polymer, or a duplex with respect to 100 parts by weight of the organic solvent mixture It fills the non-aqueous electrolyte solution which 1-50 weight part of any one polymers further contain.
여기서 이온내포풀러렌은 리튬이온내포풀러렌이며, 별도로 설명하지 않아도 이에 대응하는 음이온이 포함하고 있는 것이다.Here, the ion-containing fullerene is lithium-ion-containing fullerene, and an anion corresponding thereto is included even if not described separately.
전해액을 상기 전극 사이에 충진한 후 기체를 밀봉하여 본 실시 예에 의한 각형 2차 전지를 만드는 것이다.After filling the electrolyte between the electrodes to seal the gas to make a rectangular secondary battery according to the present embodiment.
다음은 본 발명의 충전 과정을 설명한다. The following describes the charging process of the present invention.
본 발명의 2차 전지에 전압이 인가되기 시작하면, 두 전극 사이에 전기장이 형성되고, 가장 먼저 움직임 거의 없는 이온액체폴리머에 1충전이 이루어진다. When voltage is applied to the secondary battery of the present invention, an electric field is formed between the two electrodes, and the first charge is made to the ionic liquid polymer which has almost no movement.
다음 상기 전기장에 이끌려 이온내포풀러렌은 음전극 쪽으로 이동되고, 함께 주입된 음이온은 양전극 쪽으로 이동되어 전기이중층을 형성하게 되며, 이온내포풀러렌에 내포된 이온에 의한 2차 충전이 이루어지게 된다.Next, the ion-encapsulated fullerene is moved to the negative electrode by the electric field, and the negative ions injected together move to the positive electrode to form an electric double layer, and secondary charging is performed by the ions contained in the ion-containing fullerene.
이온내포풀러렌에 내포된 이온에 의한 2차 충전이 이루어진 후에는, 음극집전체를 통해 이동되어온 전자가 음전극을 통해 이온내포풀러렌의 축퇴된 분자궤도에 주입되어 이온내포풀러렌의 분자궤도에 의한 3차 충전이 이루어지게 되는 것이다. After the secondary charging is performed by the ions contained in the iontofullerene, the electrons transferred through the negative electrode current collector are injected into the degenerate molecular orbitals of the iontofullerene through the negative electrode, thereby tertiary by the molecular orbital of the iontofullerene. Charging will be made.
이를 다시 설명하면 다음과 같다.This will be described as follows.
풀러렌에는 축퇴된 분자궤도가 5개 존재하고, 이 분자궤도 각각에 전자가 1개씩 들어갈 수 있다. There are five degenerate molecular orbits in fullerene, and each of these molecular orbits may contain one electron.
도 16은 리튬이온풀러렌의 CV(Cyclic Voltammetry) 곡선을 나타낸 것으로, 도면에서 도시되는 바와 같이, CV 곡선을 따라 전자의 환원과 산화가 이루어지게 된다. 즉, 화살표 ① 내지 화살표 ⑤가 가리키는 지점마다 전자가 하나씩 들어가 충전이 이루어진 후, 화살표 ⑥ 내지 화살표 ⑩이 가리키는 지점에서 전자가 하나씩 나와 방전이 이루어지게 된다. 16 shows a cyclic voltammetry (CV) curve of lithium ion fullerene. As shown in the figure, reduction and oxidation of electrons are performed along the CV curve. That is, after the charge is made by entering electrons at each point indicated by the
따라서 본 발명은 이온액체폴리머에 의한 1차 충전과, 리튬이온내포풀러렌에 의한 2차 충전이 이루어진 다음, 전압이 점점 상승하여 리튬이온내포풀러렌에 존재하는 분자궤도의 환원전위 이상의 전압이 인가되면, 도면에 도시되는 바와 같은 그래프를 따라 다음과 같이 순차적으로 전자가 이동하여 3차 충전이 이루어지게 된다(① 내지 ⑤). 이때 상기 음전극의 전도성을 이용한다. Therefore, in the present invention, when the primary charge by the ionic liquid polymer and the secondary charge by the lithium ion containing fullerene are made, when the voltage is gradually increased and a voltage higher than the reduction potential of the molecular orbit present in the lithium ion containing fullerene is applied, The electrons are sequentially moved along the graph as shown in the drawing as follows, whereby the third charge is made (① to ⑤). At this time, the conductivity of the negative electrode is used.
Li@C60 <-> Li@C60-¹<-> Li@C60-²<-> Li@C60-³<-> Li@C60-⁴<-> Li@C60-5 Li @ C60 <-> Li @
또한, 풀러렌 중공에 리튬이온이 내포되면 풀러렌의 분자궤도에 대한 환원전위가 0.7eV 만큼 낮아지는데, 이로 인해 충방전 효율이 더욱 향상된다.In addition, when lithium ions are contained in the fullerene hollow, the reduction potential with respect to the molecular orbital of the fullerene is lowered by 0.7 eV, thereby further improving charge and discharge efficiency.
이때 충전되는 충전량은 리튬이온에 의한 충전량의 6배가 된다. 또한 1나노 크기의 C60 풀러렌을 이용하여 충전과 방전을 행하므로 에너지 저장 밀도가 현격히 높아진다. 또한, 화학반응을 이용한 에너지 저장이 아니므로 에너지 손실 및 열 발생이 없고, 순간 충전 및 순간 방전이 가능하게 된다. 이때 전해액의 성분 및 성분비를 제어하여 충방전 특성을 제어할 수 있다. At this time, the amount of charge to be charged is six times the amount of charge by the lithium ion. In addition, charging and discharging are performed using 1 nm C60 fullerene, which significantly increases the energy storage density. In addition, since it is not an energy storage using a chemical reaction, there is no energy loss and heat generation, and instant charging and instant discharge are possible. At this time, the charge and discharge characteristics can be controlled by controlling the components and the component ratio of the electrolyte solution.
한편 스위치(SW)가 오프 되면, 충전할 때와는 반대의 과정을 거쳐 방전이 이루어지게 된다. 즉 도6의 ⑥ 내지 ⑩ 그래프의 경로를 따라 방전이 이루어진 후, 리튬 이온에 의해 충전된 전하도 방전되게 되는 것으로, 상기와 같은 과정을 반복하여 충전 과정 방전 과정을 행하게 된다.On the other hand, when the switch (SW) is turned off, the discharge is made through the reverse process as when charging. That is, after the discharge is made along the path of ⑥ to 의 graph of FIG. 6, the charge charged by the lithium ions is also discharged. The above process is repeated to perform the discharge process.
상기의 실시예에 있어서는 C60 풀러렌을 사용하여 이온내포풀러렌을 구성하였으나, 본 발명의 기술적 사상은 이에 한정되지 않음을 밝혀둔다. 즉, C60, C70, C72, C78, C82, C90, C94, C96 등의 풀러렌을 사용할 수 있음은 물론, 풀러렌 염을 사용하여 본 발명의 기술적 사상을 구성할 수 있음을 밝혀둔다.In the above embodiment, the ion-containing fullerene is configured using C60 fullerene, but the technical spirit of the present invention is not limited thereto. In other words, fullerenes such as C60, C70, C72, C78, C82, C90, C94, and C96 may be used, as well as the fullerene salt may be used to configure the technical idea of the present invention.
[제 2실시 예]Second Embodiment
본 발명의 제 2실시 예는 탄소나노튜브 전극으로 2차 전지를 구성하는 것이다. (도 14 참조)A second embodiment of the present invention is to construct a secondary battery with a carbon nanotube electrode. (See Figure 14)
상기 기체(1)의 내부에 집전체(10) 즉 구리(CU) 이루어진 양극집전체, 알루미늄(Al)으로 음극집전체를 서로 대향측에 접합한다. The negative electrode current collector is bonded to the opposite side with the
이 음극집전체와, 양측집전체 중 어느 하나에 탄소나노튜브가 형성되고, 이 탄소나노튜브에 이온내포풀러렌을 주입한다. Carbon nanotubes are formed on either of the negative electrode current collector and both current collectors, and ion-containing fullerene is injected into the carbon nanotubes.
이온내포풀러렌은 리튬이온내포풀러렌이 주입되며, 탄소나노튜브 전극의 대향측 집전체에는 활성탄으로 이루어진 제 2전극이 접합된다.The ion-containing fullerene is injected with lithium-ion-containing fullerene, and a second electrode made of activated carbon is bonded to the current collector on the opposite side of the carbon nanotube electrode.
상기 탄소나노튜브 전그과, 제 2전극은 분극성 또는 분극성과 전도성을 모두 가지는 전극(20)이 선택적으로 구성되는 것이다. The carbon nanotube jig and the second electrode are selectively configured of an
여기에 더하여 본 발명은 상기 전극 사이에 상기 비수성 전해액이 더 충진될 수 있다. In addition to the present invention, the non-aqueous electrolyte may be further filled between the electrodes.
즉 비수성 전해액은 (A) 탄소나노튜브에 주입된 상기 이온내포 풀러렌 또는 그 염 또는/및 (B) 이온액체 폴리머; (C) 비수성 유기용매; (D) 할로겐 치환 방향족 탄화수소를 포함한다. That is, the non-aqueous electrolyte solution includes (A) the ion-containing fullerene or a salt thereof and / or (B) an ionic liquid polymer injected into a carbon nanotube; (C) a non-aqueous organic solvent; (D) halogen substituted aromatic hydrocarbons.
예를 들어 상기 비수성 유기 용매와 할로겐 치환 방향족 탄화수소를 1:1로 혼합하고, 이 유기 용매 혼합물 100중량부에 대하여 전해질 리튜이온내포풀러렌 0.1 ∼ 50중량부가 포함하는 전해액을 충진한다.For example, the non-aqueous organic solvent and the halogen-substituted aromatic hydrocarbon are mixed in a 1: 1 ratio, and an electrolyte solution containing 0.1 to 50 parts by weight of the electrolyte lithium ion poplarene is added to 100 parts by weight of the organic solvent mixture.
또 다른 실시 예는 상기 비수성 유기 용매와 할로겐 치환 방향족 탄화수소를 1:1로 혼합하고, 이 유기 용매 혼합물 100중량부에 대하여 전해질 리튜이온내포풀러렌 0.1 ∼ 50중량부, 양이온 폴리머 또는 음이온 폴리머 또는 이중성 폴리머 중 어느 하나의 폴리머 1 ∼ 50중량부가 더 포함된 비수성 전해액을 충진하는 것이다.In another embodiment, the non-aqueous organic solvent and the halogen-substituted aromatic hydrocarbon are mixed in a 1: 1 ratio, and 0.1-50 parts by weight of the electrolyte litionic ionpofullerene, a cationic polymer or an anionic polymer, or a duplex with respect to 100 parts by weight of the organic solvent mixture It fills the non-aqueous electrolyte solution which 1-50 weight part of any one polymers further contain.
여기서 이온내포풀러렌은 리튬이온내포풀러렌이며, 별도로 설명하지 않아도 이에 대응하는 음이온이 포함하고 있는 것이다.Here, the ion-containing fullerene is lithium-ion-containing fullerene, and an anion corresponding thereto is included even if not described separately.
전해액을 상기 전극 사이에 충진한 후 기체를 밀봉하여 본 실시 예에 의한 각형 2차 전지를 만드는 것이다.After filling the electrolyte between the electrodes to seal the gas to make a rectangular secondary battery according to the present embodiment.
[제 3실시 예]Third Embodiment
본 발명의 2차 전지는 전해질 및 진공챔버를 이용하여 각형 2차 전지를 제조할 수 있다. 이하, 일례로서 진공 2차 전지의 구조에 대해서 설명한다.(도 15 참조)The secondary battery of the present invention can produce a rectangular secondary battery using an electrolyte and a vacuum chamber. Hereinafter, the structure of a vacuum secondary battery will be described as an example. (See FIG. 15).
진공챔버 성형 단계Vacuum chamber forming step
사각 기체 내부에 설치되는 진공챔버(12)는 탄화규소, 유리, 석영, 합성수지, 또는 비철금속 중 어느 하나를 성형하여 제조하되, 본 발명에서는 탄화규소를 성형하여 제조한다. The vacuum chamber 12 installed inside the rectangular gas is manufactured by molding any one of silicon carbide, glass, quartz, synthetic resin, or non-ferrous metal, but in the present invention, it is manufactured by molding silicon carbide.
진공챔버는 저면이 개방된 형태이고, 확관은 진공챔버 상부에 구비되거나 별도로 구비되는 저면을 막는 커버에 구비될 수 있다. The vacuum chamber may have an open bottom surface, and the expansion pipe may be provided on a cover that blocks the bottom surface provided on the vacuum chamber or separately provided.
집전체, 전극 접합 단계Current collector, electrode bonding step
상기 진공챔버의 내면에 음극집전체와 양극집전체가 대향측 각각에 접합되고, 각 집전체에 분극성 또는 분극성과 전도성을 모두 갖는 전극이 선택적으로 접합된다. 바람직하기로는 활성탄 전극이 접합된다. A negative electrode current collector and a positive electrode current collector are joined to opposite sides on the inner surface of the vacuum chamber, and electrodes having both polarization or polarity and conductivity are selectively bonded to each current collector. Preferably, the activated carbon electrode is joined.
전해질 주입 단계Electrolyte injection stage
본 발명에 따른 전해질은 이온내포풀러렌 특히 리튬이온내포풀러렌이 사용되다. As the electrolyte according to the present invention, ion-containing fullerenes, in particular lithium-ion-containing fullerenes, are used.
진공 및 밀봉 단계 Vacuum and sealing step
전해질 주입 후, 진공챔버의 저면을 커버로 막아 열 융착한다. After electrolyte injection, the bottom surface of the vacuum chamber is covered with a cover and heat-sealed.
다음 상기 진공챔버의 확관에 진공펌프와 연결되는 밸브가 설치되고, 이 밸브를 개방하여 공기를 빼낸다. 이때 전해질은 음극과 양극이 서로 상호 작용으로 외부로 유출되지 않으며, 진공 작업 후 밸브를 폐쇄한 다음 병목부에 열을 가해 용접, 밀봉하는 것이다. Next, a valve connected to the vacuum pump is installed in the expansion pipe of the vacuum chamber, and the valve is opened to draw out air. At this time, the electrolyte is not leaked to the outside by the negative electrode and the positive electrode interaction with each other, the valve is closed after the vacuum operation, and then heated and welded to the bottleneck to seal.
[제 4실시 예]Fourth Embodiment
본 발명의 2차 전지는 전해질 및 진공챔버 그리고, 진공챔버에 형성되는 탄소나노튜브를 이용하여 각형 2차 전지를 제조할 수 있다. 이하, 일례로서 진공 2차 전지의 구조에 대해서 설명한다.(도 16참조)In the secondary battery of the present invention, a rectangular secondary battery can be manufactured using an electrolyte, a vacuum chamber, and carbon nanotubes formed in the vacuum chamber. Hereinafter, the structure of a vacuum secondary battery will be described as an example. (See FIG. 16).
기체 제조 단계Gas manufacturing step
본 발명에 따른 기체는 정사각, 직사각 형상을 기본으로 하며, 여기에 다른 형태의 사각 기체를 구성할 수 있다. The gas according to the present invention is based on a square and rectangular shape, and may form a square gas of another form.
기체는 합금, 비철금속, 합성수지로 구성될 수 있으며, 성형 또는 절곡, 용접 작업을 통해 제조될 수 있다. The base may be composed of alloys, nonferrous metals, synthetic resins, and may be manufactured by forming or bending or welding operations.
진공챔버 성형 단계Vacuum chamber forming step
본 발명에 따른 진공챔버(12)는 탄화규소, 유리, 석영, 합성수지, 또는 비철금속 중 어느 하나를 성형하여 제조하되, 본 발명에서는 탄화규소를 성형하여 제조한다. Vacuum chamber 12 according to the present invention is manufactured by molding any one of silicon carbide, glass, quartz, synthetic resin, or non-ferrous metal, in the present invention is produced by molding silicon carbide.
진공챔버는 저면이 개방된 형태이고, 확관은 진공챔버 상부에 구비되거나 별도로 구비되는 베이스판에 확관이 구비하는 형태 등 어떠한 것도 무방하다. The vacuum chamber may have an open bottom surface, and the expansion pipe may be any type, such as a shape in which the expansion pipe is provided on the base plate provided on the upper portion of the vacuum chamber or separately provided.
집전체, 전극 접합 단계Current collector, electrode bonding step
상기 진공챔버를 탄화규소로 형성할 경우에는 진공챔버 외부에 집전체를 접합한 후, 그 내면에 탄소나노튜브를 성장시켜 전극을 형성할 수 있으며, 이때 대향측에는 상기 집전체와 다른 극성의 집전체가 구비되고, 이 집전체에 활성탄으로 이루어진 제 2전극이 접합되는 구성이다. When the vacuum chamber is formed of silicon carbide, the current collector may be bonded to the outside of the vacuum chamber, and carbon nanotubes may be grown on the inner surface thereof to form electrodes, and at the opposite side, a current collector having a different polarity than the current collector may be formed. And a second electrode made of activated carbon is bonded to the current collector.
다른 한편으로 본 발명은 베이스판이 사용될 수 있다. On the other hand, the base plate can be used in the present invention.
상기 진공챔버를 유리로 형성하고, 유리로 이루어진 베이스판 위에, 이 베이스판을 관통하는 전선을 통해 상부에 세워진 양극집전체와 음극집전체를 연결하고, 상기 양극집전체와 음극집전체 중 어느 하나에 탄소나노튜브가 접합 또는 성장되며, 대향측에는 제 2전극이 접합된다. The vacuum chamber is formed of glass, and a positive electrode current collector and a negative electrode current collector that are erected thereon are connected to a base plate made of glass through a wire passing through the base plate, and any one of the positive electrode current collector and the negative electrode current collector The carbon nanotubes are bonded or grown to the second electrode, and the second electrode is bonded to the opposite side.
전해질 주입 단계Electrolyte injection stage
본 발명에 따른 전해질은 이온내포풀러렌 특히 리튬이온내포풀러렌이 사용되며, 이 리튬이온내포풀러렌이 탄소나노튜브에 주입된다. In the electrolyte according to the present invention, ion-containing fullerenes, in particular, lithium-ion-containing fullerenes are used, and the lithium-ion-containing fullerenes are injected into carbon nanotubes.
진공 및 밀봉 단계 Vacuum and sealing step
전해질 주입 후, 진공챕버의 저면을 막게되며, 베이스판의 경우 진공챔버의 저면 개방부에 끼워져 집전체를 수납하고, 열융착 한다. After the electrolyte is injected, the bottom of the vacuum chapter is blocked, and in the case of the base plate, it is inserted into the bottom opening of the vacuum chamber to accommodate the current collector and heat-seaze.
다음 상기 진공챔버의 확관에 진공펌프와 연결되는 밸브가 설치되고, 이 밸브를 개방하여 공기를 빼낸다. 이때 전해질은 음극과 양극이 서로 상호 작용으로 외부로 유출되지 않으며, 진공 작업 후 밸브를 폐쇄한 다음 병목부에 열을 가해 용접, 밀봉하는 것이다. Next, a valve connected to the vacuum pump is installed in the expansion pipe of the vacuum chamber, and the valve is opened to draw out air. At this time, the electrolyte is not leaked to the outside by the negative electrode and the positive electrode interaction with each other, the valve is closed after the vacuum operation, and then heated and welded to the bottleneck to seal.
한편 본 발명에서 진공챔버를 이용하는 2차 전지는, 리튬이온내포풀러렌만 전해질로 사용하는 것이 바람직하지만, 경우에 따라서, 진공챔버 내부에 본 발명의 비수성 전해액이 선택적으로 더 주입될 수 있다.On the other hand, in the secondary battery using the vacuum chamber in the present invention, it is preferable to use only lithium ion-containing fullerene as an electrolyte, but in some cases, the non-aqueous electrolyte solution of the present invention may be selectively injected into the vacuum chamber.
이와 같이 본 발명의 각형 2차 전지는 이온내포풀러렌과 이온폴리머 그리고 방향족탄화수소와 비수성 유기 용매를 포함하고, 전극 구조를 개선하며 진공챔버를 사용함으로써, 충전 용량을 비약적으로 증가시키고, 충전 및 방전 특성을 향상시키며, 경량화 초형화가 가능하여 범용성이 뛰어난 2차 전지이다. As described above, the rectangular secondary battery of the present invention contains an ion-containing fullerene, an ion polymer, an aromatic hydrocarbon and a non-aqueous organic solvent, improves the electrode structure and uses a vacuum chamber, thereby dramatically increasing the charging capacity, and charging and discharging. It is a secondary battery with improved versatility, light weight, miniaturization, and excellent general purpose.
이상에서 설명한 바와 같이, 본 발명이 속하는 기술 분야의 당업자는 본 발명이 그 기술적 사상이나 필수적 특징을 변경하지 않고서 다른 구체적인 형태로 실시될 수 있다는 것을 이해할 수 있을 것이다. 그러므로 이상에서 기술한 실시예는 모두 예시적인 것이며 한정적인 것이 아닌 것으로서 이해해야만 한다. 본 발명의 범위는 상기 상세한 설명보다는 후술하는 특허청구범위의 의미 및 범위 그리고 그 등가개념으로부터 도출되는 모두 변경 또는 변형된 형태가 본 발명의 범위에 포함되는 것으로 해석되어야 한다. As described above, those skilled in the art to which the present invention pertains will understand that the present invention may be implemented in other specific forms without changing the technical spirit or essential features. Therefore, it should be understood that the embodiments described above are all illustrative and not restrictive. The scope of the present invention should be construed as being included in the scope of the present invention all changes or modifications derived from the meaning and scope of the claims to be described later rather than the detailed description and equivalent concepts thereof.
10 : 본체
20 : 전극
30 : 이온 내포 풀러렌 10: main body 20: electrode
30: ion-containing fullerene
Claims (36)
사각의 육면체로 구성되는 기체;
상기 기체의 내부에 구비되는 음극집전체와 양극집전체;
상기 각 집전체에 접합 또는 성장되는 전극;
상기 전극 사이에 충진되는 이온내포풀러렌으로 이루어진 전해질;로 구성된 것을 포함하는 각형 2차 전지.As a secondary battery made of a square,
A gas consisting of a square hexahedron;
A negative electrode current collector and a positive electrode current collector provided inside the gas;
Electrodes bonded or grown on the respective current collectors;
A primitive secondary battery comprising a; consisting of an electrolyte made of ion-encapsulated fullerene filled between the electrodes.
사각의 육면체로 구성되는 기체;
상기 기체의 내부에 구비되는 진공 챔버;
상기 진공 챔버의 내면 또는 외면에 접합되는 양극집전체와 음극집전체로 구성된 집전체;
상기 각 집전체에 접합 또는 성장되는 전극;
상기 전극 사이에 충진되는 이온내포풀러렌으로 이루어진 전해질;로 구성된 것을 포함하는 각형 2차 전지.As a secondary battery made of a square,
A gas consisting of a square hexahedron;
A vacuum chamber provided inside the gas;
A current collector including a positive electrode current collector and a negative electrode current collector bonded to an inner surface or an outer surface of the vacuum chamber;
Electrodes bonded or grown on the respective current collectors;
A primitive secondary battery comprising a; consisting of an electrolyte consisting of ion-encapsulated fullerenes filled between the electrodes.
상기 음극집전체와 양극집전체 중 어느 하나에 탄소나노튜브를 성장시켜 전극으로 구성하고, 대향측 집전체에 활성탄 전극이 구비되도록 하되, 상기 탄소나노튜브 전극에 이온내포풀러렌이 주입된 것을 포함하는 각형 2차 전지.The method according to claim 1 or 2,
Carbon nanotubes are grown on any one of the negative electrode current collector and the positive electrode current collector to form an electrode, and an activated carbon electrode is provided on the opposite current collector, and the ion nanoporous fullerene is injected into the carbon nanotube electrode. Rectangular secondary battery.
상기 탄소나노튜브 전극과 활성탄 전극은, 분극성 또는 분극성과 전도성을 모두 갖는 전극 중 어느 하나로 선택되는 것을 포함하는 각형 2차 전지.The method of claim 3,
The carbon nanotube electrode and the activated carbon electrode, the rectangular secondary battery comprising any one selected from the electrode having polarity or both polarity and conductivity.
상기 전해질에 할로겐치환방향족탄화수소가 더 포함되는 것을 특징으로 하는 각형 2차 전지.The method according to claim 1 or 2,
Square secondary battery, characterized in that the electrolyte further comprises a halogen-substituted aromatic hydrocarbon.
상기 기체는 정 사각, 직 사각, 마름모, 평행사변형 또는 사다리꼴 또는 삼각형 중 어느 하나로 제작되는 것을 포함하는 각형 2차 전지.The method according to claim 1 or 2,
The gas is a rectangular secondary battery comprising a one made of square, rectangular, rhombus, parallelogram or trapezoid or triangle.
상기 이온내포풀러렌은, 내포되는 이종 원자로서, 리튬, 나트륨, 칼륨, 세슘, 마그네슘, 칼슘,스트론튬 중 어느 하나인 것을 포함하는 이온내포풀러렌을 이용한 각형 2차 전지.The method according to claim 1 or 2,
The ion-containing fullerene is a rectangular secondary battery using ion-containing fullerenes, including any one of lithium, sodium, potassium, cesium, magnesium, calcium, and strontium as the hetero atom contained.
상기 이온내포풀러렌에 내포되는 원자 이온은 금속인 것을 포함하는 각형 2차 전지.The method according to claim 1 or 2,
A rectangular secondary battery comprising an atomic ion contained in the ion-containing fullerene is a metal.
상기 기체의 집전체 접합된 전극 사이에 비수성 전해액이 주입되며,
상기 비수성 전해액은
(A) 이온내포 풀러렌 또는 그 염;
(B) 이온액체 폴리머;
(C) 비수성 유기용매; 및
(D) 할로겐 치환 방향족 탄화수소인 것을 포함하는 각형 2차 전지.The method according to claim 1 or 2,
A non-aqueous electrolyte is injected between the electrode bonded to the current collector of the gas,
The non-aqueous electrolyte solution
(A) ion-containing fullerenes or salts thereof;
(B) an ionic liquid polymer;
(C) a non-aqueous organic solvent; And
(D) A rectangular secondary battery containing what is a halogen substituted aromatic hydrocarbon.
상기 비수성 전해액은,
(A) 이온내포 풀러렌 또는 그 염;
(C) 비수성 유기용매; 및
(D) 할로겐 치환 방향족 탄화수소인 것을 포함하는 각형 2차 전지.A non-aqueous electrolyte is injected between the electrode bonded to the current collector of the gas,
The non-aqueous electrolyte solution,
(A) ion-containing fullerenes or salts thereof;
(C) a non-aqueous organic solvent; And
(D) A rectangular secondary battery containing what is a halogen substituted aromatic hydrocarbon.
상기 비수성 유기 용매와 할로겐 치환 방향족 탄화수소를 1: 0.5 ∼ 3으로 혼합하고, 상기 혼합물 100중량부에 대하여 이온내포풀러렌 0.5 ∼ 50중량부를 첨가한 포함하는 각형 2차 전지.The method of claim 20,
A rectangular secondary battery comprising the nonaqueous organic solvent and the halogen-substituted aromatic hydrocarbon in a ratio of 1: 0.5 to 3, and adding 0.5 to 50 parts by weight of ion-containing fullerene to 100 parts by weight of the mixture.
[화학식 1]
[화학식 2]
화학식 1 및 2에서 R은 수소 원자, 알킬, 사이클로알킬, 알릴, 아릴 또는 알킬아릴이고, 여기서, 알킬은 C1-C6,사이클로알킬은 C3-C10,알릴은 C2-C20,아릴은 C6-C20이며, n은 5,000 내지 30,000의 정수이다.The method of claim 20 wherein the ionic liquid polymer is Cl and the cationic polymer of the formula (1) or the formula 2 -, Br -, BF 4 -, PF 6 -, (CF 3 SO 2) 2 N -, HPO 3 R 11- (Wherein R 11 is a C 1 ~ C 6 alkyl group) and one or more anions selected from the group consisting of COOH - is bonded to the secondary battery.
[Formula 1]
[Formula 2]
R in formulas 1 and 2 is a hydrogen atom, alkyl, cycloalkyl, allyl, aryl or alkylaryl, wherein alkyl is C 1 -C 6 , cycloalkyl is C 3 -C 10 , allyl is C 2 -C 20, Aryl is C 6 -C 20 and n is an integer from 5,000 to 30,000.
[화학식 3]
화학식 3에서 n은 5,000 내지 500,000의 정수이다.The method of claim 20, wherein the ionic liquid polymer is an anionic polymer of Formula 3 and R 4 -P + , wherein R is a hydrogen atom, alkyl, cycloalkyl, allyl, aryl or alkylaryl, wherein alkyl is C 1 - C 6, cycloalkyl is C 3- C 10, allyl is C 2- C 20, aryl is prismatic secondary battery including that it is combined with a C 6- C 20 Im) anion.
[Formula 3]
N in the formula (3) is an integer of 5,000 to 500,000.
[화학식 4]
화학식 4에서 A-는 SO3 - 또는 PO3H- 또는 CO2 -이고, n은 5,000 내지 300,000의 정수이다.21. The rectangular secondary battery of claim 20, wherein the ionic liquid polymer is a dual polymer of Formula 4.
[Formula 4]
In formula 4 A - is a SO 3 - or PO 3 H - or CO 2 -, n is an integer of from 5,000 to 300,000.
비수성 유기 용매와 할로겐 치환 방향족 탄화수소를 1:0.5 ∼ 3으로 혼합하고, 이 유기 용매 혼합물 100중량부에 대하여 전해질 리튜이온내포풀러렌 0.1 ∼ 50중량부, 양이온 폴리머 또는 음이온 폴리머 또는 이중성 폴리머 중 어느 하나의 이온액체폴리머 0.5 ∼ 50중량부를 더 포함하는 각형 2차 전지.The method of claim 20, wherein the non-aqueous electrolyte,
The non-aqueous organic solvent and the halogen-substituted aromatic hydrocarbon are mixed at 1: 0.5 to 3, and 0.1-50 parts by weight of the electrolyte lithium ionpofullerene, a cationic polymer or an anionic polymer or a double polymer with respect to 100 parts by weight of the organic solvent mixture. A rectangular secondary battery further comprises 0.5 to 50 parts by weight of the ionic liquid polymer.
[화학식 5]
화학식 1에서 R1내지 R6는 각각 독립적으로 비치환된 C1~C6알킬기, 할로겐 또는 할로겐 원자로 치환된 C1~C6알킬기이되, 반드시 하나 이상의 할로겐이 치환된다.The rectangular secondary battery of claim 24, wherein the halogen-substituted benzene is represented by Chemical Formula 5. 25.
[Formula 5]
In formula 1 R 1 to R 6 each independently are a C 1 ~ C 6 alkyl group, a halogen or a C 1 ~ C 6 substituted with a halogen atom alkilgiyi unsubstituted, are necessarily substituted with one or more halogen.
[화학식 6]
화학식 2에서 R1내지 R8는 각각 독립적으로 비치환된 C1~C6알킬기, 할로겐 또는 할로겐 원자로 치환된 C1~C6알킬기이되, 반드시 하나 이상의 할로겐이 치환된다.The rectangular secondary battery of claim 24, wherein the halogen-substituted naphthalene is represented by Chemical Formula 6. 25.
[Formula 6]
In Formula 2 R 1 to R 8 each independently are a C 1 ~ C 6 alkyl group, a halogen or a C 1 ~ C 6 substituted with a halogen atom alkilgiyi unsubstituted, are necessarily substituted with one or more halogen.
[화학식 7]
화학식 3에서 R1내지 R10는 각각 독립적으로 비치환된 C1~C6알킬기, 할로겐 또는 할로겐 원자로 치환된 C1~C6알킬기이되, 반드시 하나 이상의 할로겐이 치환된다.The rectangular secondary battery of claim 24, wherein the halogen-substituted anthracene is represented by Chemical Formula 7. 25.
[Formula 7]
In Formula 3 R 1 to R 10 are each independently selected from unsubstituted C 1 ~ C 6 alkyl group, a halogen or a halogen atom being substituted with C 1 ~ C 6 alkilgiyi, and be substituted one or more halogen.
36. A rectangular rechargeable battery according to claim 35, comprising improving charging duration by preventing natural discharge by the intercalation.
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