KR20190002574A - Wool / Thamo / Graphene Polyamide blended woolen fabric and its production method - Google Patents

Wool / Thamo / Graphene Polyamide blended woolen fabric and its production method Download PDF

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KR20190002574A
KR20190002574A KR1020187034191A KR20187034191A KR20190002574A KR 20190002574 A KR20190002574 A KR 20190002574A KR 1020187034191 A KR1020187034191 A KR 1020187034191A KR 20187034191 A KR20187034191 A KR 20187034191A KR 20190002574 A KR20190002574 A KR 20190002574A
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wool
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polyamide
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웨이동 장
쉬 황
즈화 천
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지앙수 칼리지 오브 엔지니어링 앤드 테크놀로지
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    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/283—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads synthetic polymer-based, e.g. polyamide or polyester fibres
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D13/00—Woven fabrics characterised by the special disposition of the warp or weft threads, e.g. with curved weft threads, with discontinuous warp threads, with diagonal warp or weft
    • D03D13/008—Woven fabrics characterised by the special disposition of the warp or weft threads, e.g. with curved weft threads, with discontinuous warp threads, with diagonal warp or weft characterised by weave density or surface weight
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/233—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads protein-based, e.g. wool or silk
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/242—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads inorganic, e.g. basalt
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/242—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads inorganic, e.g. basalt
    • D03D15/275—Carbon fibres
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2211/00—Protein-based fibres, e.g. animal fibres
    • D10B2211/01—Natural animal fibres, e.g. keratin fibres
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2211/00—Protein-based fibres, e.g. animal fibres
    • D10B2211/01—Natural animal fibres, e.g. keratin fibres
    • D10B2211/02—Wool
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00—Physical properties
    • D10B2401/13—Physical properties anti-allergenic or anti-bacterial
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00—Physical properties
    • D10B2401/22—Physical properties protective against sunlight or UV radiation
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2501/00—Wearing apparel

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Woven Fabrics (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
  • Artificial Filaments (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

일종의 양모/타모/그래핀폴리아미드 혼방 모직원단과 그 생산방법으로서, 그래핀폴리아미드를 신재료로 적절한 비율로 양모, 타모를 혼방하여 신형 원단을 개발하였고, 이 원단은 경사 70S 양모 100%, 위사 70S 양모, 그래핀폴리아미드 6DTY, 70D/24F, 세타모로 구성된다. 이 원단은 방적, 직조, 후처리 등 공법을 이용하여 제조한다. 해당 모직원단은 우아하고 매끄러우며 아름답고 편안하며 착용감이 우수할 뿐만 아니라 그래핀폴리아미드 섬유를 첨가하여 내마모성이 향상됨으로써 원단이 저온 원적외선 발열, 항자외선, 항균 및 항진드기성 등의 기능을 갖추어, 단일한 양모섬유의 단점인 축융성을 극복하고 기능을 보완할 뿐만 아니라 원가도 낮출 수 있다.A kind of wool / tamo / graphene polyamide wool blend fabric and its production method, well developed a new fabric to blend know wool, and the other at an appropriate ratio to pin polyamide with new material, the fabric is inclined 70 S wool 100% , Weft 70 S wool, graphene polyamide 6DTY, 70D / 24F, and theta. This fabric is manufactured by spinning, weaving, post-processing, etc. The woolen fabrics are elegant and smooth, beautiful, comfortable, and comfortable to wear. Grafted polyamide fibers are added to improve the abrasion resistance, so that the fabric has functions of low-temperature far-infrared heat, anti-ultraviolet rays, antibacterial and anti- It can overcome the disadvantage of a wool fiber and can compensate for its function as well as its cost.

Description

양모/타모/그래핀폴리아미드 혼방 모직원단과 그 생산방법Wool / Thamo / Graphene Polyamide blended woolen fabric and its production method

본 발명은 신형 원단 분야에 관한 것으로서, 구체적으로는 일종의 양모(羊毛)/타모(駝毛)/그래핀폴리아미드 혼방 모직원단과 그 생산방법에 관한 것이다.BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a new fabrics field, and more specifically, to a woolen / wool / graphene polyamide blend fabric and a production method thereof.

2004년, 영국의 물리학자인 안드레가임(AndreGeim)과 콘스탄틴 노보셀로프(Konstantin Novoselov)는 단층으로 원자가 배열된 물질인 그래핀을 분리하는데성공하였다. 그래핀은 슈퍼캐패시터, 투명전극, 해수담수화, 발광다이오드, 센서, 태양전지, 복합재료, 생물약물전달등 분야에 광범위하게 응용되고 있다. 점점 건강과 생태계를 중시하게 되면서 방직제품에 대한 요구도 날로 높아지고, 단일한 기능을 가진 제품으로는 쾌적성, 무공해, 환경보호, 보건등에 대한 소비자의 다원적인 요구에 부응할 수 없게 되었다. 그래핀, 산화그래핀은 항균성이 우수하며 인체에 무해하고, 그래핀 모직원단은 우아하고 매끄러우며 아름답고 편안하며 착용감이 우수할 뿐만아니라 내마모성이 향상되어 원단이 저온원적외선발열, 항자외선, 항균 및 항진드기 기능을 구비하게 됨으로써, 단일한 양모섬유의 단점인 축융성을 극복하고 기능을 보완할 뿐만아니라 원가도 낮출 수 있다.In 2004, British physicists Andre Gem and Konstantin Novoselov succeeded in separating graphene, a monolayer atomically ordered material. Graphene has been extensively used in the fields of supercapacitors, transparent electrodes, seawater desalination, light emitting diodes, sensors, solar cells, composites, and biological drug delivery. As the importance of health and ecosystem has been increasingly increasing, the demand for textile products has increased day by day. As a product with a single function, it has become unable to meet consumer's pluralistic demands on comfort, pollution, environmental protection and health. Graphene and oxidized graphene have excellent antibacterial properties and are harmless to the human body. Grape wool fabrics are graceful and smooth, beautiful and comfortable, have excellent wearing comfort as well as improved abrasion resistance, so that the fabrics have low temperature infrared heat, anti-ultraviolet, By having a mite function, it is possible to overcome the disadvantage of the single wool fiber, which is a disadvantage of the single wool fiber, to complement the function, and to lower the cost.

본 발명의 목적은 종래 모직원단의 품종이 단일하고 기능성이 낮으며, 항균, 방충 기능이 부족한 등의 기술적 단점을 해결하는 일종의 양모/타모/그래핀폴리아미드 혼방 모직원단과 그 생산방법을 제공함으로써, 우아하고 매끄러우며 편안하고 착용감이 우수할 뿐만 아니라 내마모성이 양호하고 저온 원적외선 발열, 항자외선, 항균, 항진드기 기능이 구비된 모직원단을 얻는 것이다.An object of the present invention is to provide a kind of wool / hair / graphene polyamide blend wool fabric which is a single type of conventional woolen fabric and has a low functionality and lacks antimicrobial and insect repellent functions and its production method , Wool fabrics which are elegant, smooth, comfortable and excellent in wear resistance as well as good abrasion resistance and have low-temperature far-infrared heat, anti-ultraviolet rays, antibacterial and anti-tick functions.

일종의 양모/타모/그래핀폴리아미드 혼방 모직원단으로서 그래핀폴리아미드를 신재료로 하여, 적절한 비율로 양모, 타모를 혼방하여 신형 원단을 개발하며, 이 원단은 경사 70S양모 100%, 위사 70S양모, 그래핀폴리아미드 6 DTY, 70D/24F, 세타모(細駝毛)로 구성된다. 위사양모/타모/그래핀폴리아미드의 혼방 비율은 85/5/10, 65/5/30, 50/5/45 중 하나 또는 다수이며, 상기 모직원단의 경사밀도는 10cm당 180가닥 내지 200가닥이고, 위사밀도는 10cm당 140가닥 내지 170가닥이다. 완제품의 원단 폭은 153cm이고, 중량은 m2당 340g 내지 360g이다.Kind of wool / tamo / graphene in the polyamide blend as a wool fabric graphene polyamide with new material, and the blends do not know wool, and the other at an appropriate ratio develop a new fabric, the fabric is inclined 70 S 100% wool, the weft 70 S wool, graphene polyamide 6 DTY, 70D / 24F, and detergent. Wherein the blend ratio of wool / hair / graphene polyamide is one or more of 85/5/10, 65/5/30, 50/5/45, and the warp density of the woolen fabric is from 180 to 200 strands per 10 cm And the weft density is from 140 to 170 strands per 10 cm. The fabric width of the finished product is 153 cm and the weight is 340 g to 360 g per m 2 .

상기 양모/타모/그래핀폴리아미드 혼방 모직원단의 생산방법으로서, 그래핀폴리아미드와 양모/타모의 처리, 직조공법 및 후처리 가공을 포함하며, 그 중 배합비율에 따라 선택하여 사용하는 그래핀폴리아미드와 양모/타모는 (1)정련(精練), (2)개모(開毛), (3)혼합(混合), (4) 밀폐(密閉),(5) 소융(梳絨), (6) 연조(練條), (7)로터방적(轉杯紡) 공정을 거쳐 처리한다. 여기에서 정련공법의 유제는 방모유(wool oil) CT-201D 0.4% 내지 0.6%이고, SELBANA 4611 0.1% 내지 0.4%이며, 정전기방지제 4%, 실리카겔이다. 털을 24시간 숙성시킨 뒤, 타모와 양모를 혼합하고 그래핀폴리아미드 단섬유를 개모한 뒤 양모와 혼합한다.A method for producing woolen / wool / graphene / polyamide blended woolen fabrics comprising graphene polyamide and wool / shoemaking, weaving, and post-processing, wherein graphene Polyamide and wool / tamo are used for the purpose of (1) refining, (2) opening hair, (3) mixing, (4) sealing, (5) 6) soft yarn, and (7) rotor spinning process. Here, the emulsion of the refining method is 0.4% to 0.6% of wool oil CT-201D, 0.1% to 0.4% of SELBANA 4611, 4% of antistatic agent, silica gel. After the hair is aged for 24 hours, the hair and wool are mixed and the graphene polyamide staple fibers are raised and mixed with the wool.

소융: 소융작업장의 온도는 28℃ 이상이고, 상대습도는 80% 이상이며, 소융기 원형 콤(circular comb)의 속도는 분당 370회이고, 리커인(licker-in) 속도는 분당 800회 내지 1000회이며, 도퍼 속도는 분당 10회 내지 20회이고, 슬라이버(sliver)정량은 5m당 20g이며, 슬라이버사균제도(yarn evenness) CV값은 6.0% 내지 6.5%이다.Melting: The temperature of the melting shop is above 28 ° C, the relative humidity is above 80%, the speed of the bulb circular comb is 370 per minute and the licker-in speed is between 800 and 1000 per minute , The doper speed is 10 to 20 times per minute, the sliver quantitation is 20 g per 5 m, and the slice warp evenness CV value is 6.0% to 6.5%.

연조: 연조는 2채널 병합을 사용하며, 그래핀폴리아미드 단섬유를 예비연조하고, 채널 하나에 슬라이버 8개씩 피딩하며, 출사 속도는 분당 70m 내지 90m이고, 연조 슬라이버의 슬라이버사 균제도 CV값은 3.0% 내지 3.5%이다. Soft Tissue: The soft Tissue uses two channel merging, pre-softening the graphene polyamide staple fibers, feeding eight slivers to one channel, outputting speed of 70 to 90 m / min, Is from 3.0% to 3.5%.

바람직하게는, 직조공법의 프로세스가 (1) 정경(整經), (2) 천종(穿綜), (3) 직조(織造)로서, 여기에서 생산된 제품 폭은 153cm이고, 리드(reed) 수는 10cm당 36개 내지 44개이며, 리드당 4가닥이 들어가며, 종편(綜片) 수는 8개이고, 경사(經絲) 밀도는 10cm당 180가닥 내지 200가닥이며, 위사(緯絲) 밀도는 10cm당 140가닥 내지 170가닥이다.Preferably, the process of the weaving process is (1) setting, (2) padding, (3) weaving, the product width being 153 cm, reed, And the number of pieces is 8, the warp density is 180 to 200 strands per 10 cm, and the number of weft yarn densities Is from 140 to 170 strands per 10 cm.

바람직하게는, 후처리 가공이세척 → 탈수 → 축융→ 연화 → 탈수 → 열 건조로서, 여기에서 세척: 세척시간은 15분이고, 수온은 50℃ 내지 55℃이며, 세척제: Goon102는 3% 내지 5%(직물대비 중량비)이고, 축융: 축융계수는 2 내지 2.5이고, 폭 은 153cm이며, 축융제 MP-20은 3% 내지 4%(직물대비 중량)이고, 축융시간은 10분 내지 20분이며; 연화: 연화에는 이하의 후처리제를 사용한다. 연화제 CS-82D-73은 5분 내지 8분이고, 보풀 및 필링 방지제 TK-750은 1분 내지 2분이며, 공법 설정: 함침은 1회이고 픽업(pick-up)은 1회이며, 픽업비율은 100% 내지 120%이고, 열풍건조는 150℃내지 160℃에서 정형(定型)한다.Preferably, the post-treatment is washing → dehydration → fusing → softening → dehydration → heat drying, wherein the washing time is 15 minutes, the water temperature is 50 ° C. to 55 ° C., the cleaning agent: Goon 102 is 3% to 5% (Weight ratio to fabric), fusing: the consolidation factor is from 2 to 2.5, the width is 153 cm, the fusant MP-20 is from 3% to 4% (weight to fabric) and the fusing time is from 10 minutes to 20 minutes; Softening: The following post treatment is used for softening. The softener CS-82D-73 is 5 minutes to 8 minutes, the lint and anti-peeling agent TK-750 is 1 minute to 2 minutes, the construction method is 1 time of impregnation, 1 time of pick-up, 100% to 120%, and hot air drying is performed at a temperature of 150 to 160 ° C.

본 발명에 따른 모직원단은 우아하고 매끄러우며 아름답고 편안하며 착용감이 우수할 뿐만 아니라 그래핀폴리아미드 섬유를 첨가하여 내마모성이 향상되고, 원단에 저온 원적외선 발열, 항자외선, 항균, 항진드기 기능을 갖추게 되어, 단일한 양모섬유의 단점인 축융성을 개선하고 기능을 보완할 뿐만 아니라 원가를 낮출 수 있다. 본 원단은 주로 기능성 의류에 사용되는 고급원단에 속한다. The woolen fabric according to the present invention is graceful, smooth, beautiful, comfortable, and excellent in wearing comfort, and also has improved abrasion resistance by adding graphene polyamide fiber, and has low-temperature far-infrared heat, anti-ultraviolet rays, antibacterial and anti- , It is possible to improve the meritability of a single wool fiber, to complement the function, and to lower the cost. This fabric belongs to high quality fabric mainly used for functional garments.

이하는 구체적인 실시예를 통해 본 발명을 더욱 상세히 설명한다.Hereinafter, the present invention will be described in more detail with reference to specific examples.

실시예 1Example 1

일종의 양모/타모/그래핀폴리아미드 혼방 모직원단으로서, 그래핀폴리아미드를 신재료로 하여 적절한 비율로 양모와 타모를 혼방하여 신형 원단을 개발하여, 이 원단은 경사: 70S양모 100%, 위사: 70S양모, 그래핀폴리아미드 6 DTY, 70D/24F, 세타모로 구성된다. 위사양모/타모/그래핀폴리아미드의 혼방 비율은 85/5/10, 65/5/30, 50/5/45 중 하나 또는 다수이며, 해당 모직원단의 경사밀도는 10cm당 180가닥이고, 위사밀도는 10cm당 140가닥이다. 완제품의 원단 폭은 153cm이고, 중량은 m2당 340g이다.As a kind of wool / turquoise / graphene polyamide blended wool fabric, we have developed a new type of fabric by mixing wool and cotton with an appropriate ratio of graphene polyamide as a new material. This fabric has slope: 70 S wool 100% : 70 S wool, graphene polyamide 6 DTY, 70D / 24F, and theta. The blend ratio of wool / wool / graphene / polyamide is one or more of 85/5/10, 65/5/30, 50/5/45, the warp density of the woolen fabric is 180 strands per 10 cm, The density is 140 strands per 10 cm. The fabric width of the finished product is 153cm, and the weight is 340g per m 2 .

상기 양모/타모/그래핀폴리아미드 혼방 모직원단의 생산방법으로서, 그래핀폴리아미드와 양모/타모의 처리, 직조공법 및 후처리 가공을 포함하며, 그 중 배합비율에 따라 선택하여 사용하는 그래핀폴리아미드와 양모/타모는 (1) 정련, (2) 개모, (3) 혼합, (4) 밀폐, (5) 소융, (6) 연조, (7) 로터방적 공정을 거쳐 처리한다. 여기에서 정련공법 유제는 방모유 CT-201D 0.4%, SELBANA 4611 0.1%, 정전기방지제 4%, 실리카겔이다. 털을 24시간 숙성시킨 뒤, 타모와 양모를 혼합하고 그래핀폴리아미드 단섬유를 개모한 뒤 양모와 혼합한다.A method for producing woolen / wool / graphene / polyamide blended woolen fabrics comprising graphene polyamide and wool / shoemaking, weaving, and post-processing, wherein graphene Polyamides and wool / towers are treated by (1) refining, (2) scouring, (3) mixing, (4) sealing, (5) melting, (6) softening, and (7) rotor spinning. Here, refining method emulsion is 0.4% of breast milk CT-201D, 0.1% of SELBANA 4611, 4% of antistatic agent, silica gel. After the hair is aged for 24 hours, the hair and wool are mixed and the graphene polyamide staple fibers are raised and mixed with the wool.

소융: 소융 작업장의 온도는 28℃이상이고, 상대습도는 80%이상이며, 소융기 원형 콤의 속도는 분당 370회이고, 리커인 속도는 분당 800회이며, 도퍼 속도는 분당 10회이고, 슬라이버 정량은 5m당 20g이며, 슬라이버사 균제도 CV값은 6.0%이다.Melting: The temperature of the melting chamber is above 28 ° C and the relative humidity is above 80%. The speed of the ridge circular comb is 370 revolutions per minute. The recurrence rate is 800 revolutions per minute. The amount of burr is 20 g per 5 m, and the CV value of the slurry is uniformly 6.0%.

연조: 연조는 2채널 병합을 사용하며, 그래핀폴리아미드 단섬유를 예비연조하고, 채널 하나에 슬라이버 8가닥씩 피딩하며, 출사 속도는 분당 70m이고, 연조 슬라이버의 슬라이버사 균제도 CV값은 3.0%이다.Soft tone: The soft tone is using 2 channel merging, preliminarily softening the graphene polyamide staple fibers, feeding one sliver to each channel, and the output speed is 70 m / min. The CV value of the soft sliver slice is 3.0%.

직조공법의 프로세스는 (1) 정경, (2) 천종, (3) 직조로서, 여기에서 생산된 제품 폭은 153cm이고, 리드 수는 10cm당 36개이며, 리드당 4가닥이 들어가며, 종편 수는 8개이고, 경사 밀도는 10cm당 180가닥이며, 위사 밀도는 10cm당 140가닥이다.The process of weaving process is (1) canonical process, (2) thousand kinds, (3) weaving, product width is 153cm, lead number is 36 per 10cm, 4 strands per lead, 8, the warp density is 180 strands per 10 cm, and the weft density is 140 strands per 10 cm.

처리 가공은 세척 → 탈수 → 축융 →연화 → 탈수 → 열 건조로서, 여기에서 세척: 세척시간은 15분이고, 수온은 50℃이며, 세척제는 Goon102 3%(직물대비 중량비)이고; 축융: 축융계수는 2이고, 폭은 153cm이며, 축융제 MP-20은 3%(직물대비 중량)이고, 축융시간은 10분이며; 연화: 연화에는 이하의 후처리제를 사용한다. 연화제 CS-82D-73은 5분이고, 보풀 및 필링 방지제 TK-750은 1분이며, 공법 설정: 함침은 1회이고 픽업은 1회이며, 픽업비율은 100%이고, 열풍건조하고, 150℃에서 정형한다.The processing is as follows: washing → dehydration → fusing → softening → dehydration → heat drying, where the washing time is 15 minutes, the water temperature is 50 ° C., the cleaning agent is Goon 102 3% (weight ratio to fabric); Fusion: The coefficient of consolidation is 2, the width is 153 cm, the molten MP-20 is 3% (weight to fabric) and the fusing time is 10 minutes; Softening: The following post treatment is used for softening. Curing: CS-82D-73 is 5 minutes. Lint and anti-peeling agent TK-750 is 1 minute. Method setting: 1 time of impregnation, 1 time of pick-up, 100% pick up rate, Formal.

실시예 2Example 2

일종의 양모/타모/그래핀폴리아미드 혼방 모직원단으로서, 그래핀폴리아미드를 신재료로 하여 적절한 비율로 양모와 타모를 혼방하여 신형 원단을 개발하여, 이 원단은 경사: 70S 양모 100%, 위사: 70S 양모, 그래핀폴리아미드 6 DTY, 70D/24F, 세타모로 구성된다. 위사 양모/타모/그래핀폴리아미드의 혼방 비율은 85/5/10, 65/5/30, 50/5/45 중 하나 또는 다수이며, 상기 모직원단의 경사밀도는 10cm당 200가닥이고, 위사밀도는 10cm당 170가닥이다. 완제품의 원단 폭은 153cm이고, 중량은 m2당 360g이다.As a kind of wool / turquoise / graphene polyamide blended wool fabric, we have developed a new type of fabric by mixing wool and cotton with an appropriate ratio of graphene polyamide as a new material. This fabric has slope: 70 S wool 100% : 70 S wool, graphene polyamide 6 DTY, 70D / 24F, and theta. The blend ratio of wool / wool / graphene / polyamide is one or more of 85/5/10, 65/5/30, 50/5/45, the warp density of the woolen fabric is 200 strands per 10cm, The density is 170 strands per 10 cm. The fabric width of the finished product is 153cm, and the weight is 360g per m 2 .

상기 양모/타모/그래핀폴리아미드 혼방 모직원단의 생산방법으로서, 그래핀폴리아미드와 양모/타모의 처리, 직조공법 및 후처리 가공을 포함하며, 그 중 배합비율에 따라 선택하여 사용하는 그래핀폴리아미드와 양모/타모는 (1) 정련, (2) 개모, (3) 혼합, (4) 밀폐, (5) 소융, (6) 연조, (7) 로터방적 공정을 거쳐 처리한다. 여기에서 정련공법 유제는 방모유 CT-201D 0.6%, SELBANA 4611 0.6%, 정전기방지제 4%, 실리카겔이다. 털을 24시간 숙성시킨 뒤,타모와 양모를 혼합하고 그래핀폴리아미드 단섬유를 개모한 뒤 양모와 혼합한다.A method for producing woolen / wool / graphene / polyamide blended woolen fabrics comprising graphene polyamide and wool / shoemaking, weaving, and post-processing, wherein graphene Polyamides and wool / towers are treated by (1) refining, (2) scouring, (3) mixing, (4) sealing, (5) melting, (6) softening, and (7) rotor spinning. Here, refining method emulsion is 0.6% of breast milk CT-201D, 0.6% of SELBANA 4611, 4% of antistatic agent, silica gel. After the hair is aged for 24 hours, the hair and wool are mixed and the graphene polyamide staple fibers are raised and mixed with the wool.

소융: 소융 작업장의 온도는 28℃이상이고, 상대습도는 80% 이상이며, 소융기 원형 콤의 속도는 분당 370회이고, 리커인(licker-in) 속도는 분당 1,000회이며, 도퍼 속도는 분당 20회이고, 슬라이버 정량은 5m당 20g이며, 슬라이버사 균제도 CV값은 6.5%이다.Melting: The temperature of the melting chamber is above 28 ° C and the relative humidity is above 80%. The speed of the ridge circular comb is 370 revolutions per minute, the licker-in speed is 1,000 revolutions per minute, 20 times, the sliver amount is 20g per 5m, and the slicer uniformity CV value is 6.5%.

연조: 연조는 2채널 병합을 사용하며, 그래핀폴리아미드 단섬유를 예비연조하고, 채널 하나에 슬라이버 8가닥씩 피딩하며, 출사 속도는 분당 90m이고, 연조 슬라이버의 슬라이버사 균제도 CV값은 3.0% 내지 3.5%이다.Soft tone: The soft tone uses two channel merging, preliminary softening of the graphene polyamide staple fibers, feeding one sliver to each channel, the output speed is 90 m / min, and the softness sliver CV value 3.0% to 3.5%.

직조공법의 프로세스는 (1) 정경, (2) 천종, (3) 직조로서, 여기에서 생산된 제품 폭은 153cm이고, 리드 수는 10cm당 44개이며, 리드당 4가닥이 들어가며, 종편 수는 8개이고, 경사 밀도는 10cm당200가닥이며, 위사 밀도는 10cm당 170가닥이다.The process of weaving process is (1) canonical process, (2) thousand kinds, (3) weaving, product width is 153cm, lead number is 44 per 10cm, 4 strands per lead, 8, the warp density is 200 strands per 10 cm, and the weft density is 170 strands per 10 cm.

후처리 가공은 세척 → 탈수 → 축융 → 연화 → 탈수 → 열 건조로서, 여기에서 세척: 세척시간은 15분이고, 수온은 55℃이며, 세척제 Goon102는 5%(직물대비 중량비)이고, 축융: 축융계수는 2.5이고, 폭은 153cm이며, 축융제 MP-20은 4%(직물대비 중량)이고, 축융시간은 20분이며; 연화: 연화에는 이하의 후처리제를 사용한다. 연화제 CS-82D-73은 8분이고, 보풀 및 필링 방지제 TK-750는 2분이고; 공법 설정: 함침은 1회이고 픽업은 1회이며, 픽업비율은 120%이며, 열풍건조하고, 160℃에서 정형한다.Washing time: 15 minutes, water temperature: 55 ° C. Cleaning agent: Goon 102: 5% (weight ratio to fabric). Finishing: Finishing factor: Is 2.5, the width is 153 cm, the molten MP-20 is 4% (weight to fabric) and the fusing time is 20 minutes; Softening: The following post treatment is used for softening. The softener CS-82D-73 is 8 minutes, the nappy and anti-peeling agent TK-750 is 2 minutes; Construction method: impregnation is one time, pickup is one time, pickup ratio is 120%, hot air drying, and shaping at 160 ° C.

실시예 3Example 3

일종의 양모/타모/그래핀폴리아미드 혼방 모직원단으로서, 그래핀폴리아미드를 신재료로 하여 적절한 비율로 양모와 타모를 혼방하여 신형 원단을 개발하여, 상기 원단은 경사: 70S 양모 100%, 위사: 70S 양모, 그래핀폴리아미드 6 DTY, 70D/24F, 세타모로 구성된다. 위사 양모/타모/그래핀폴리아미드의 혼방 비율은 85/5/10, 65/5/30, 50/5/45 중 하나 또는 다수이며, 상기 모직원단의 경사밀도는 10cm당 190가닥이고, 위사밀도는 10cm당 160가닥이다. 완제품의 원단 폭은 153cm이고, 중량은 m2당 350g이다.As a kind of wool / towel / graphene polyamide blend wool fabric, a new type of fabric was developed by blending wool and cotton with a proper ratio of graphene polyamide as a new material, and the fabric was sloped: 70 S wool 100% : 70 S wool, graphene polyamide 6 DTY, 70D / 24F, and theta. Wherein the warp density of the woolen fabric is 190 strands per 10 cm, and the warp density of the wool / oat / graphene polyamide is at least one of 85/5/10, 65/5/30, 50/5/45, The density is 160 strands per 10 cm. The fabric width of the finished product is 153cm, and the weight is 350g per m 2 .

상기 양모/타모/그래핀폴리아미드 혼방 모직원단의 생산방법으로서, 그래핀폴리아미드와 양모/타모의 처리, 직조공법 및 후처리 가공을 포함하며, 그 중 배합비율에 따라 선택하여 사용하는 그래핀폴리아미드와 양모/타모는 (1) 정련, (2) 개모, (3) 혼합, (4) 밀폐, (5) 소융, (6) 연조, (7) 로터방적 공정을 거쳐 처리한다. 여기에서 정련공법 유제는 방모유 CT-201D 0.5%, SELBANA 4611 0.3%, 정전기방지제 4%, 실리카겔이다. 털을 24시간 숙성시킨 뒤 타모와 양모를 혼합하고 그래핀폴리아미드 단섬유를 개모한 뒤 양모와 혼합한다.A method for producing woolen / wool / graphene / polyamide blended woolen fabrics comprising graphene polyamide and wool / shoemaking, weaving, and post-processing, wherein graphene Polyamides and wool / towers are treated by (1) refining, (2) scouring, (3) mixing, (4) sealing, (5) melting, (6) softening, and (7) rotor spinning. Here, refining method emulsion is 0.5% of breast milk CT-201D, 0.3% of SELBANA 4611, 4% of antistatic agent, and silica gel. After the hair is aged for 24 hours, the hair and wool are mixed and the graphene polyamide staple fibers are raised and mixed with the wool.

소융: 소융 작업장의 온도는 28℃이상이고, 상대습도는 80% 이상이며, 소융기 원형 콤의 속도는 분당 370회이고, 리커인 속도는 분당 900회이며, 도퍼 속도는 분당 14회이고, 슬라이버 정량은 5m당 20g이며, 슬라이버사 균제도 CV값은 6.3%이다.Melting: The temperature of the melting shop is above 28 ° C and the relative humidity is above 80%. The speed of the ridge circular comb is 370 revolutions per minute. The recurrence rate is 900 revolutions per minute. The amount of burr is 20 g per 5 m, and the CV value of the slicer is 6.3%.

연조: 연조는 2채널 병합을 사용하며, 그래핀폴리아미드 단섬유를 예비연조하고, 채널 하나에 슬라이버 8가닥씩 피딩하며, 출사 속도는 분당 80m이고, 연조 슬라이버의 슬라이버사 균제도 CV값은 3.2%이다.Soft tone: The soft tone is using two channels merging, preliminary softening of graphene polyamide staple fibers, feeding one sliver to each channel, the output speed is 80m per minute, and the softness sliver CV value 3.2%.

직조공법의 프로세스는 (1) 정경, (2) 천종, (3) 직조로서, 여기에서 생산된 제품 폭은 153cm이고, 리드 수는 10cm당 41개이며, 리드당 4가닥이 들어가며, 종편 수는 8개이고, 경사 밀도는 10cm당 190가닥이며, 위사 밀도는 10cm당 160가닥이다.The process of the weaving process is (1) canonical process, (2) thousand kinds, (3) weaving, the product width here is 153cm, the number of leads is 41 per 10cm, there are 4 strands per lead, 8, the warp density is 190 strands per 10 cm, and the weft density is 160 strands per 10 cm.

후처리 가공은 세척 → 탈수 → 축융 → 연화 → 탈수 → 열 건조로서, 여기에서 세척: 세척시간은 15분이고, 수온은 53℃이며, 세척제 Goon102는 4%(직물대비 중량비)이고; 축융: 축융계수는 2.3이고, 폭은 153cm이며, 축융제 MP-20은 3.5%(직물대비 중량)이며, 축융시간은 17분이고; 연화: 연화에는 이하의 후처리제를 사용한다. 연화제 CS-82D-73은 7분이고, 보풀 및 필링 방지제 TK-750은 1.4분이며, 공법 설정: 함침은 1회이고 픽업은 1회이며, 픽업비율은 110%이고, 열풍건조는 154℃에서정형한다.The post-treatment process is as follows: washing → dehydration → fusing → softening → dehydration → heat drying, wherein the washing time is 15 minutes, the water temperature is 53 ° C., the cleaning agent Goon 102 is 4% (weight ratio to fabric); Fusion: The coefficient of consolidation is 2.3, the width is 153 cm, the molten MP-20 is 3.5% (weight to fabric), the fusing time is 17 minutes; Softening: The following post treatment is used for softening. The softening agent CS-82D-73 is 7 minutes, the lint and anti-peeling agent TK-750 is 1.4 minutes, the setting method is 1 time of impregnation, 1 time of pickup, 110% of pickup ratio, do.

본 발명에 따른 모직원단은 우아하고 매끄러우며 아름답고 편안하며 착용감이 우수할 뿐만 아니라 그래핀폴리아미드 섬유를 첨가하여 내마모성이 향상되고, 원단에 저온 원적외선 발열, 항자외선, 항균, 항진드기 기능을 갖추게 되어, 단일한 양모섬유의 단점인 축융성을 개선하고 기능을 보완할 뿐만 아니라 원가를 낮출 수 있다. 본 원단은 주로 기능성 의류에 사용되는 고급원단에 속한다.The woolen fabric according to the present invention is graceful, smooth, beautiful, comfortable, and excellent in wearing comfort, and also has improved abrasion resistance by adding graphene polyamide fiber, and has low-temperature far-infrared heat, anti-ultraviolet rays, antibacterial and anti- , It is possible to improve the meritability of a single wool fiber, to complement the function, and to lower the cost. This fabric belongs to high quality fabric mainly used for functional garments.

본 발명은 상기 가장 바람직한 실시방식에 한정되지 않으며, 본 발명을 계기로 하여 누구라도 각종 형식의 다른 제품을 얻을 수 있으나, 형상 또는 구조에 어떠한 변화가 있더라도 본 출원과 동일하거나 유사한 기술적 방안을 구비하고 있는 모든 변화는 본 발명의 보호범위에 속한다.The present invention is not limited to the above-described most preferred embodiment, and anyone can obtain other products of various types on the basis of the present invention. However, even if there is any change in shape or structure, All changes that fall within the scope of the present invention.

Claims (4)

그래핀폴리아미드를 신재료로 하여, 적절한 비율로 양모, 타모를 혼방하여 신형 원단을 개발하며, 상기 원단은 경사 70S양모 100%, 위사 70S양모, 그래핀폴리아미드 6 DTY, 70D/24F, 세타모(細駝毛)로 구성되고; 위사양모/타모/그래핀폴리아미드의 혼방 비율은 85/5/10, 65/5/30, 50/5/45 중 하나 또는 다수이며, 상기 모직원단의 경사밀도는 10cm당 180가닥 내지 200가닥이고, 위사밀도는 10cm당 140가닥 내지 170가닥이며, 완제품의 원단 폭은 153cm이고, 중량은 m2당 340g 내지 360g인 것을 특징으로 하는 양모/타모/그래핀폴리아미드 혼방 모직원단.So by the pin polyamide with new materials, and blends of wool, you do not know the other at an appropriate ratio to develop a new fabric, the fabric is inclined 70 S 100% wool, the weft 70 S wool, graphene polyamide 6 DTY, 70D / 24F , ≪ / RTI > and serums; Wherein the blend ratio of wool / hair / graphene polyamide is one or more of 85/5/10, 65/5/30, 50/5/45, and the warp density of the woolen fabric is from 180 to 200 strands per 10 cm By weight, the weft density is from 140 to 170 strands per 10 cm, the fabric width of the finished product is 153 cm, and the weight is from 340 g to 360 g per m 2 of wool / graft / graphene polyamide blended woolen fabric. 그래핀폴리아미드와 양모/타모의 처리, 직조공법 및 후처리 가공을 포함하며, 그 중에서, 배합비율에 따라 선택하여 사용하는 그래핀폴리아미드와 양모/타모는 (1)정련(精練), (2)개모(開毛), (3)혼합(混合), (4) 밀폐(密閉),(5) 소융(梳絨), (6) 연조(練條), (7)로터방적(轉杯紡) 공정을 거쳐 처리하고;
여기에서 정련공법의 유제는 방모유(wool oil) CT-201D 0.4% 내지 0.6%이고, SELBANA 4611 0.1% 내지 0.4%이며, 정전기방지제 4%, 실리카겔이고; 털을 24시간 숙성시킨 뒤, 타모와 양모를 혼합하고 그래핀폴리아미드 단섬유를 개모한 뒤 양모와 혼합하며;
소융: 소융작업장의 온도는 28℃ 이상이고, 상대습도는 80% 이상이며, 소융기 원형 콤(circular comb)의 속도는 분당 370회이고, 리커인(licker-in) 속도는 분당 800회 내지 1000회이며, 도퍼 속도는 분당 10회 내지 20회이고, 슬라이버(sliver)정량은 5m당 20g이며, 슬라이버사균제도(yarn evenness) CV값은 6.0% 내지 6.5%이며;
연조: 연조는 2채널 병합을 사용하며, 그래핀폴리아미드 단섬유를 예비연조하고, 채널 하나에 슬라이버 8개씩 피딩하며, 출사 속도는 분당 70m 내지 90m이고, 연조 슬라이버의 슬라이버사 균제도 CV값은 3.0% 내지 3.5%이며;
를 포함하는 것을 특징으로 하는 제1항의 상기 양모/타모/그래핀폴리아미드 혼방 모직원단의 생산방법.Graphene polyamides and wool / trim, woven and post-processing, among which graphene polyamides and wool / tammons selected according to the blend ratio are (1) refined, (3) mixing, (4) sealing, (5) melting, (6) softening, (7) rotor spinning, Spinning) process;
Here, the emulsion of the refining method is 0.4% to 0.6% of wool oil CT-201D, 0.1% to 0.4% of SELBANA 4611, 4% of antistatic agent, silica gel; After the hair is aged for 24 hours, the hair and wool are mixed, the graphene polyamide staple fibers are raised and mixed with the wool;
Melting: The temperature of the melting shop is above 28 ° C, the relative humidity is above 80%, the speed of the bulb circular comb is 370 per minute and the licker-in speed is between 800 and 1000 per minute , The doper speed is 10 to 20 times per minute, the sliver quantitation is 20 g per 5 m, and the slicer evenness CV value is 6.0% to 6.5%;
Soft Tissue: The soft Tissue uses two channel merging, pre-softening the graphene polyamide staple fibers, feeding eight slivers to one channel, outputting speed of 70 to 90 m / min, Is from 3.0% to 3.5%;
The method of claim 1, wherein the wool / oat / graphene polyamide blend wool fabric is produced by the method of any one of the preceding claims. 제2항에 있어서,
직조공법의 프로세스가 (1) 정경(整經), (2) 천종(穿綜), (3) 직조(織造)로서, 여기에서 생산된 제품 폭은 153cm이고, 리드(reed) 수는 10cm당 36개 내지 44개이며, 리드당 4가닥이 들어가며, 종편(綜片) 수는 8개이고, 경사(經絲) 밀도는 10cm당 180가닥 내지 200가닥이며, 위사(緯絲) 밀도는 10cm당 140가닥 내지 170가닥인 것을 특징으로 하는 양모/타모/그래핀폴리아미드 혼방 모직원단의 생산방법.3. The method of claim 2,
The process of the weaving process is (1) the arrangement (2), (3) weaving, (3) the product width is 153cm, the number of reed is 10cm 36 to 44, with 4 strands per lead, 8 pieces, the warp yarn density is 180 to 200 strands per 10 cm, and the weft yarn density is 140 per 10 cm. Strand / graft / polyamide blended woolen fabric. 제2항에 있어서,
후처리 가공이세척 → 탈수 → 축융 → 연화 → 탈수 → 열 건조로서, 여기에서 세척: 세척시간은 15분이고, 수온은 50℃ 내지 55℃이며, 세척제 Goon102은 3% 내지 5%(직물대비 중량비)이고, 축융: 축융계수는 2 내지 2.5이고, 폭은 153cm이며, 축융제 MP-20은 3% 내지 4%(직물대비 중량)이고, 축융시간은 10분 내지 20분이며, 연화: 연화에는 이하의 후처리제를 사용하고; 연화제 CS-82D-73은 5분 내지 8분이고, 보풀 및 필링 방지제 TK-750은 1분 내지 2분이며, 공법 설정: 함침은 1회이고, 픽업(pick-up)은 1회이며, 픽업비율은 100% 내지 120%이고, 열풍건조는 150℃ 내지 160℃에서 정형(定型)하는 것을 특징으로 하는 양모/타모/그래핀폴리아미드 혼방 모직원단의 생산방법.3. The method of claim 2,
The cleaning time is 15 minutes, the water temperature is 50 ° C to 55 ° C, the cleaning agent Goon 102 is 3% to 5% (weight ratio to fabric) 20 to 20%; softening: softening: softening: softening: softening: softening: softening: softening: Of a post-treatment agent; The softening agent CS-82D-73 is 5 minutes to 8 minutes, the napping and peeling inhibitor TK-750 is 1 minute to 2 minutes, the setting method is one time, the picking up is one time, Is 100% to 120%, and hot air drying is carried out at a temperature of 150 to 160 ° C. The method of producing a wool / tohomo / graphene polyamide blended woolen fabric according to claim 1,
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