KR20170012753A - Transmissivity changeable film, display device including the same and method for preparing transmissivity changeable film - Google Patents
Transmissivity changeable film, display device including the same and method for preparing transmissivity changeable film Download PDFInfo
- Publication number
- KR20170012753A KR20170012753A KR1020150104433A KR20150104433A KR20170012753A KR 20170012753 A KR20170012753 A KR 20170012753A KR 1020150104433 A KR1020150104433 A KR 1020150104433A KR 20150104433 A KR20150104433 A KR 20150104433A KR 20170012753 A KR20170012753 A KR 20170012753A
- Authority
- KR
- South Korea
- Prior art keywords
- light transmittance
- transmittance variable
- space
- conductive material
- variable film
- Prior art date
Links
Images
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/165—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on translational movement of particles in a fluid under the influence of an applied field
- G02F1/166—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on translational movement of particles in a fluid under the influence of an applied field characterised by the electro-optical or magneto-optical effect
- G02F1/167—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on translational movement of particles in a fluid under the influence of an applied field characterised by the electro-optical or magneto-optical effect by electrophoresis
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/0001—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems
- G02B6/0011—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems the light guides being planar or of plate-like form
- G02B6/0081—Mechanical or electrical aspects of the light guide and light source in the lighting device peculiar to the adaptation to planar light guides, e.g. concerning packaging
- G02B6/0093—Means for protecting the light guide
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/133345—Insulating layers
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1343—Electrodes
Landscapes
- Physics & Mathematics (AREA)
- Nonlinear Science (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Chemical & Material Sciences (AREA)
- Mathematical Physics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Molecular Biology (AREA)
- Electrochromic Elements, Electrophoresis, Or Variable Reflection Or Absorption Elements (AREA)
Abstract
An upper electrode; A lower electrode including a conductive material layer formed in a linear pattern and spaced apart from the upper electrode; And an ink receiving layer disposed between the upper electrode and the lower electrode, the ink receiving layer containing ink containing colored charged particles in the space, And a bottom surface of the space is formed by a concave surface.
Description
A light transmittance variable film and a display device including the same.
BACKGROUND ART In general, a digital paper display has been spotlighted as a next generation display device following a liquid crystal display, a plasma display panel, and an organic luminescence display. Type display device.
In such a display device, an electrochromic method, a polymer dispersed LC (PDLC) method, or the like can be used as a method of controlling the light transmittance.
One embodiment of the present invention provides a light transmittance variable film that realizes excellent maximum transmittance at high speed.
Another embodiment of the present invention provides a display device including the light transmittance variable film.
In one embodiment of the present invention, an upper electrode; A lower electrode including a conductive material layer formed in a linear pattern and spaced apart from the upper electrode; And an ink receiving layer disposed between the upper electrode and the lower electrode, the ink receiving layer containing ink containing colored charged particles in the space, And a bottom surface of the space is formed by a concave surface.
In another embodiment of the present invention, the light transmittance variable film; And a voltage application means electrically connected to the light transmittance variable film.
The light transmittance variable film can change the transmittance at a high speed and can realize an excellent maximum transmittance.
1 schematically shows a cross section of a light transmittance variable film according to an embodiment of the present invention.
2 is a schematic view of a cross section of a light transmittance variable film according to another embodiment of the present invention when a voltage is applied.
Fig. 3 shows a cross section of a structure deformed so as to be contrasted with the internal structure of the light transmittance variable film.
4 shows a cross section of the light transmittance variable film according to another embodiment of the present invention.
5 shows a cross section of the light transmittance variable film according to another embodiment of the present invention.
Hereinafter, exemplary embodiments of the present invention will be described in detail with reference to the accompanying drawings, which will be readily apparent to those skilled in the art to which the present invention pertains. The present invention may be embodied in many different forms and is not limited to the embodiments described herein.
In order to clearly illustrate the present invention, parts not related to the description are omitted, and the same or similar components are denoted by the same reference numerals throughout the specification.
In the drawings, the thickness is enlarged to clearly represent the layers and regions. In the drawings, for the convenience of explanation, the thicknesses of some layers and regions are exaggerated.
Hereinafter, the formation of any structure in the "upper (or lower)" or the "upper (or lower)" of the substrate means that any structure is formed in contact with the upper surface (or lower surface) of the substrate However, the present invention is not limited to not including other configurations between the substrate and any structure formed on (or under) the substrate.
In one embodiment of the present invention, an upper electrode; A lower electrode including a conductive material layer formed in a linear pattern and spaced apart from the upper electrode; And an ink receiving layer disposed between the upper electrode and the lower electrode, the ink receiving layer containing ink containing colored charged particles in the space, A skeleton forming the bottom surface of the space and the space, and the bottom surface of the space is formed as a concave surface.
FIG. 1 schematically shows a cross section of the light
1, the
The light
The ink is contained in the
The
The meaning of micro in the
The ink may further include an insulating medium, and if no voltage is applied to the light transmittance varying film, the colored
When a voltage is applied to the
The colored
2 is a schematic view of a cross section of the light
When the colored
When the voltage is applied, the colored
That is, the light transmittance of the light
The thickness of the skeleton below the concave surface of the bottom surface of the
The variable
Specifically, the concave portion formed by the concave surface may be formed at a depth of about 0.2 탆 to about 1 탆. By forming the concave portion having the depth in the above range, the skeletal material thickness under the bottom surface of the
3 shows a cross section of a structure formed by a flat bottom surface so as to be in contrast to the bottom surface of the
3 is a sectional view assuming that the bottom surface of the
The maximum transmittance of the light
The light transmittance variable film (100, 200) can be changed into a transparent film state having a high light transmittance of about 40% to about 70% when a voltage is applied in a substantially opaque state with a light transmittance of about 0 to about 10% Is a variable film.
The
The
The
The transparent film may be a film having excellent transparency and strength. Examples of the transparent film include polyethylene terephthalate (PET), polyethylene naphthalate (PEN), polyethersulfone (PES), polycarbonate selected from the group comprising poly carbonate (PC), polypropylene (PP), polyimide (PI), cyclo-olefin copolymer, norbornene resin and combinations thereof But is not limited to, a transparent film of a resin containing at least one of them.
The transparent film may be, for example, about 50 탆 to about 500 탆 in thickness. By including the transparent film having the above-mentioned thickness range, it is possible to effectively realize necessary mechanical properties by appropriately adjusting the durability and flexibility without excessively increasing the total thickness of the light
The
The conductive material may be, for example, indium tin oxide (ITO), zinc oxide (ZnO), zinc tin oxide (ZTO), graphene, carbon nanotube (CNT) But is not limited to, at least one selected from the group consisting of fluorine-doped tin oxide (FTO), silver nanowire, metal, conductive polymer, and combinations thereof.
The thickness of the
As described above, since the
The intensity of the voltage applied to form this electric field may be, for example, from about 5 V to about 50 V. [ By applying a voltage in the intensity range, all of the colored charged
The
The
1, the
When the
When the electrical attraction generated between the colored charged
The
The transparent film may be, for example, about 50 탆 to about 500 탆 in thickness. By including the transparent film having the above-mentioned thickness range, it is possible to effectively realize necessary mechanical properties by appropriately adjusting the durability and flexibility without excessively increasing the total thickness of the light transmittance
The
An example of a conductive material that can be used as the material of the
The thickness of the
The
FIG. 4 shows a cross section of the light
The
The colored charged
In addition, the
In FIG. 4, a
Similarly, the
The colored charged
The
The
The
A skeleton exists under the bottom surface of the
The thickness of the skeleton below the bottom surface of the
On the other hand, when the thickness is too thin, there is a fear that the ink and the
The bottom surface of the
Specifically, the light transmittance variable film has a transmittance change (DELTA T) of about 50% (about 10%) at a voltage of about 20 V, and more specifically, % To about 60%) can be realized at a level lower than about 1 second, and the response to the change in the transmittance of about 75% (from about 5% to about 80%) It can be implemented with a speed of about 10 seconds or less.
The
The ink containing the colored charged
The
In order to form the bottom surface of the
The specific size of the
The spacing of the
The width of the
The overall height of the
The total thickness of the light transmittance
If the height of the
By forming the size of the
For example, when the ratio of the area occupied by the
The specific standard design of the
The skeleton may include, for example, a transparent photocurable resin, a transparent thermosetting resin, or both, and a photocurable or thermosetting resin capable of realizing transparency may be used without limitation. For example, a resin having a light transmittance of 90% or more, specifically, about 90 to about 100% after curing can be used.
The transparent photocurable resin may be, for example, a transparent acrylic resin such as urethane acrylate or epoxy acrylate, but is not limited thereto.
The transparent thermosetting resin included in the resin composition may be, for example, a polyamide resin, a polyimide resin, a silicone resin, an epoxy resin, an acrylic resin, a polyester resin, or the like, but is not limited thereto.
The photocurable or thermosetting resin for forming the skeleton should have excellent adhesion with the
On the other hand, the photocurable or thermosetting resin forming the skeleton has excellent adhesion to the
In addition, the photocurable or thermosetting resin forming the skeleton forms a
In addition, the photocurable or thermosetting resin forming the skeletal material must have stain resistance to colored particles such as carbon black which may be contained in the ink. For example, in order to increase the stain resistance to the colored particles, an additive for lowering the surface tension inside the resin may be added to the resin composition for skeletal reformation. The surface tension inside the resin forming the skeleton may be equal to or higher than the surface tension of the ink.
The skeleton of the
The coating composition for forming an ink receiving layer may further include, for example, a photocuring agent, a heat curing agent, or both. The photocuring agent and the thermosetting agent may be variously used in accordance with the object and nature of the invention without any particular limitation.
The colored charged
The colored charged
In addition, for example, the colored charged
The material capable of having such charge includes, for example, an organic compound containing a hydrocarbon group; A complex compound containing a halogen element; A coordination compound comprising at least one member selected from the group consisting of an amine group, a thiol group, a phosphine group, or a combination thereof; And a combination thereof. The charge-imparting substance may be a compound having a charge imparted thereto by forming a radical in a substance including at least one selected from the group consisting of:
The hydrocarbon group may include at least one functional group selected from the group consisting of, for example, carboxylic acid, ester, acyl, and combinations thereof.
The ink contained in the
For example, the insulating medium may be a material having a low dielectric constant, and specifically may include an alkyl silicone oil such as a hydrocarbon solvent such as dodecane, a halocarbon oil, a dimethyl silicone oil, and the like.
Also, for example, the insulating medium may be a material having a polarity index of higher than about 1, and specifically, it may be formed of at least one material selected from the group consisting of dodecane, trichlorethylene, carbon tetrachloride, Di-iso-propyl ether, toluene, methyl-t-butyl ether, xylene, benzene, diethyl ether, Dichloromethane, 1,2-Dichloroethane, Butyl Acetate, Iso-Propanol, n-Butanol, tetrahydrofuran, But are not limited to, tetrahydrofuran, n-propanol, chloroform, ethylacetate, 2-butanone, dioxane, acetone, ), Ethanol, acetonitrile, acetic acid, dimethylformamide, dimethylsulfoxide (Dimeth (such as N, N-dimethyl sulfoxide, N, N-dimethyl sulfoxide, N, N-dimethylformamide, N-methylpyrrolodone) 1 < / RTI >
The insulating medium may be, for example, a transparent material, but is not limited thereto, and the colored charged
The light transmittance variable film may be formed by attaching the
5 shows a cross section of the light
4, the sealing
The sealing
5, a sealing
For example, the sealing
The sealing
The thickness of the sealing film 150 may be, for example, from about 1 [mu] m to about 20 [mu] m.
In another embodiment of the present invention, the light transmittance variable film; And a voltage application means electrically connected to the light transmittance variable film.
The display device may be, for example, a display device of an electronic device such as a TV, a smart phone, a computer, a notebook computer, or the like, but the present invention is not limited thereto. .
The light transmittance variable film may be formed by applying a resin composition for forming a skeleton of an ink receiving layer so that the conductive material layer is embedded on an upper portion of a lower electrode on which a linear conductive material layer is formed on a transparent substrate, To form the ink receiving layer on which the space is formed.
The ink receiving layer may be formed such that the partition and the space are formed by imprinting using a mold or a roll having a pattern formed thereon. In this case, the ink and the lower electrode may not be in direct contact with each other only when the lower surface of the space is formed to have a thickness.
As described above, the concave portion of the bottom surface of the space may be formed by forming the shape of the portion corresponding to the bottom surface of the space of the forming mold or the roll for imprinting to be a convex portion, By controlling the degree of curing of the center of the bottom surface of the space during photocuring or thermosetting of the composition, uncalcified cargo is allowed to exist so that uncured cargo is adhered to the imprinting mold when the imprinting mold is removed.
The resin composition for skeletal reformation of the ink receiving layer includes at least one selected from the group consisting of a transparent photocurable resin, a transparent thermosetting resin, and a combination thereof, and the detailed description thereof is as described above.
The imprinting process will be described in more detail. A resin composition for skeletal reformation of the ink receiving layer is applied on top of the lower electrode between two rolls, The pattern of the roll is transferred to the side where the ink receiving layer is to be formed, thereby forming the ink receiving layer in which the pattern of the partition and the space is formed.
The imprinting is performed so that the ink receiving layer is laminated on the lower electrode while the pattern is formed.
When the imprinting is performed, a recess formed by the concave surface is formed at a depth of about 0.2 탆 to about 1 탆 on the bottom surface of the space while laminating the lower electrode, and the thickness of the skeleton below the concave surface is about 0.001 Mu] m to about 1 [mu] m, the viscosity of the resin composition for skeletal reformation of the ink receiving layer should be controlled and the temperature condition at the time of imprinting be adjusted.
The resin composition for skeletal reformation of the ink receiving layer may be a solvent type containing a solvent or a solventless type which does not contain a solvent.
When the resin composition for skeletal reformation of the ink receptive layer contains a solvent, the viscosity at about 25 ° C should be about 10 cP to about 50 cP. In case of the solvent type, the solvent is volatilized by drying after the film formation, and imprinting is performed. Therefore, the viscosity is further increased during imprinting. In the case of the solvent type, drying after film formation can be carried out specifically at about 80 to 130 DEG C for 1 to 5 minutes.
When the resin composition for skeletal reformation of the ink receiving layer does not contain a solvent, the viscosity at about 25 ° C should be about 150 cP to about 500 cP.
When the resin composition for skeletal reformation of the ink receiving layer contains a solvent, the imprinting is performed at about 80 to about 130 캜. When the resin composition for skeletal reformation of the ink receiving layer does not contain a solvent, 30 to about 70 < 0 > C.
The resin composition for skeletal reformation of the ink receptive layer having the viscosity in the above range is applied to the upper surface of the lower electrode to perform imprinting in the temperature range to form the concave surface on the bottom surface of the space Is formed at a depth of about 0.2 탆 to about 1 탆 while the skeletal material below the lowest point of the concave name is formed to have a thickness of about 0.001 탆 to about 1 탆.
When the imprinting is performed, the concave portion formed by the concave surface on the bottom surface of the space is laminated at a depth of about 0.2 탆 to about 1 탆 while laminating the lower electrode, and the thickness of the skeleton below the concave surface Appropriate pressure must be applied in order to achieve a thickness of about 0.001 탆 to about 1 탆. One example of an approach for adjusting such a suitable pressure to be applied is to adjust the spacing between the rolls.
For example, the layer formed by applying the resin composition for skeletal reformation of the ink receiving layer may be passed between imprinting rolls having an interval of about 1 m to about 50 m. The interval between the imprinting rolls can be controlled to be thin when the layer formed by the resin composition for skeletal reformation is passed through and the layer can be appropriately expanded to about 50 탆 in consideration of the transparent base layer. By performing imprinting using the roll of the interval, it is possible to produce a predetermined ink receiving layer shape while laminating by applying appropriate pressure.
The ink receiving layer may be manufactured by imprinting as described above or after forming or forming a skeletal shape of the ink receiving layer having a space and a space and then curing the skeletal material by photo-curing or thermosetting. For example, a mold with a pattern formed thereon during imprinting is thermally cured by applying heat in a pressed state, or light cured by light irradiation to cure the resin, followed by release from the mold.
The method of manufacturing the light transmittance variable film according to the present invention includes the steps of forming the ink receiving layer by imprinting on the lower electrode as described above and then injecting ink into the space of the ink receiving layer, And the light transmittance variable film can be manufactured.
Hereinafter, examples and comparative examples of the present invention will be described. The following embodiments are only examples of the present invention, and the present invention is not limited to the following embodiments.
( Example )
Example One
A lower electrode was fabricated by forming a metal in a grid pattern on the PET transparent substrate to form a conductive material layer. The thickness of the metal grid pattern was 12 mu m and the interval was 300 mu m.
A mixed solvent such as urethane acrylate resin (Ebecryl® 220, Ebecryl® 600, etc.), acrylate monomer (DPHA, PETA and the like), MEK, IPA and ethyl cellosolve as solvents, Irg 184 , 907, etc. were mixed to prepare a resin composition for skeletal reformation of the ink receiving layer so that the viscosity became 10 cP at 25 ° C.
The resin composition for forming a skeleton of the ink receiving layer was coated on the upper electrode by using a coating bar having a thickness of 3 μm to 4 μm and then dried at 110 ° C. for 1.5 minutes to volatilize the solvent. Imprinting was performed at a temperature of 100 占 폚 at an interval of 30 占 퐉. The imprinting rolls were irradiated with UV to cure them, and then they were released from the rolls to form an ink receiving layer laminated on the lower electrode.
A corresponding surface of the imprinting roll is formed as a convex portion so that the bottom surface of the space of the ink receiving layer formed by the imprinting roll forms a concave surface.
Subsequently, ink containing a mixture of carbon black and a dodecane solvent was injected into the space of the ink receiving layer, and an upper electrode was adhered to the upper portion of the ink receiving layer to prepare a light transmittance variable film.
Example 2
The imprinting roll having the convex height of the imprinting roll lower than that of the imprinting roll of Example 1 was used so that the depth of the concave surface of the space of the ink receiving layer was changed. In manufacturing the lower electrode, the thickness of the metal grid pattern Was 5 mu m and the interval was 100 mu m, a light transmittance variable film was prepared in the same manner as in Example 1. [
Comparative Example One
The light-transmittable variable film was prepared in the same manner as in Example 1, except that an imprinting roll having no convex portions was formed so that the bottom surface of the ink-receptive layer formed by the imprinting roll was formed as a flat surface. .
Comparative Example 2
The light-transmittance variable film was prepared in the same manner as in Example 2, except that the imprinting roll formed by the imprinting roll was not provided with a convex portion so that the bottom surface of the space was formed as a flat surface. .
evaluation
Experimental Example One
In the light transmittance variable film produced in Example 1-2 and Comparative Example 1-2, the depth of the concave portion formed by the concave surface on the bottom surface of the space was measured and described in Table 1 below.
Experimental Example 2
Light transmittance The aperture ratio of the variable film is a theoretical value excluding the metal mesh portion in the entire area. However, due to the loss of transmittance due to the PET film and the ink, the maximum transmittance value is actually less than theoretically calculated aperture ratio.
The light transmittance variable films prepared in Example 1-2 and Comparative Example 1-2 were repeatedly subjected to + 20V / 30 seconds and -20V / 10 seconds using a bipolar power supply (PBZ40-10) manufactured by KIKUSUI Co., And the real time transmittance was measured, and the maximum transmittance according to the measured transmittance was shown in Table 1 below.
From the results shown in Table 1, it was confirmed that the maximum transmittance of Example 1-2 was higher than that of Comparative Example 1-2.
While the present invention has been particularly shown and described with reference to exemplary embodiments thereof, it is to be understood that the invention is not limited to the disclosed exemplary embodiments, Of the right.
100, 200, 300, 400: light transmittance variable film
110: upper electrode
120: Lower electrode
111, 121: Transparent film
112: conductive material layer of the upper electrode
122: conductive material layer of the lower electrode
113, 123: protective layer
130:
131:
131a:
132: Space
134: colored charged particles
135: sealing film
X: Thickness of the skeleton below the space bottom
A: Overall thickness of the ink receiving layer
Claims (17)
A lower electrode including a conductive material layer formed in a linear pattern and spaced apart from the upper electrode; And
An ink receiving layer which contains a space partitioned by the barrier and accommodates ink containing colored charged particles in the space, the ink receiving layer being located between the upper electrode and the lower electrode;
/ RTI >
Wherein the ink receiving layer is composed of a skeleton forming the partition and a bottom surface of the space and the space,
The bottom surface of the space is formed with a concave surface
Light transmittance variable film.
The ink contained in the space is separated from the lower electrode by the skeleton material formed below the bottom surface of the space,
Light transmittance variable film.
Wherein the thickness of the skeleton below the concave surface is from 0.001 mu m to 1 mu m
Light transmittance variable film.
The concave portion formed by the concave surface is formed at a depth of 0.2 mu m to 1 mu m
Light transmittance variable film.
Wherein the distance between the two spaced apart spaces is 5 占 퐉 to 20 占 퐉 and the distance between the two spaced apart walls is 100 占 퐉 to 2000 占 퐉 as the width of the space, 5 mu m to 50 mu m, and the height of the conductive material layer of the lower electrode is 0.01 mu m to 2.0 mu m
Light transmittance variable film.
Wherein the lower electrode comprises a transparent material; And a layer of a conductive material formed in a linear pattern on the transparent substrate
Light transmittance variable film.
Wherein the upper electrode comprises a transparent material; And a conductive material layer formed below the transparent substrate
Light transmittance variable film.
The conductive material layer may be formed on the surface of the transparent substrate, or may be formed in a linear pattern
Light transmittance variable film.
The conductive material layer may include at least one of indium tin oxide (ITO), zinc oxide (ZnO), zinc tin oxide (ZTO), graphene, carbon nanotube (CNT), fluorine- doped Tin Oxide (FTO), silver nanowire, metal, conductive polymer, and combinations thereof.
Light transmittance variable film.
Wherein the skeleton material comprises at least one selected from the group consisting of a transparent photocurable resin, a transparent thermosetting resin, and combinations thereof
Light transmittance variable film.
Wherein the upper electrode, the lower electrode or both all further comprise a protective layer on the conductive material layer
Light transmittance variable film.
The protective layer may be made of the same material as the skeleton
Light transmittance variable film.
When the voltage is applied, the conductive material layer of the lower electrode is charged, and the colored charged particles have a charge opposite to the charge of the conductive material layer
Light transmittance variable film.
Wherein the ink further comprises an insulating medium
Light transmittance variable film.
The ink-receiving layer may further include a sealing film formed on an upper portion of the barrier rib. The barrier ribs of the ink-receiving layer and the upper electrode,
Light transmittance variable film.
The sealing film is formed only on the uppermost outermost barrier ribs outside the side surface of the ink receiving layer
Light transmittance variable film.
And a voltage application means electrically connected to the light transmittance variable film.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020150104433A KR20170012753A (en) | 2015-07-23 | 2015-07-23 | Transmissivity changeable film, display device including the same and method for preparing transmissivity changeable film |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020150104433A KR20170012753A (en) | 2015-07-23 | 2015-07-23 | Transmissivity changeable film, display device including the same and method for preparing transmissivity changeable film |
Publications (1)
Publication Number | Publication Date |
---|---|
KR20170012753A true KR20170012753A (en) | 2017-02-03 |
Family
ID=58156539
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1020150104433A KR20170012753A (en) | 2015-07-23 | 2015-07-23 | Transmissivity changeable film, display device including the same and method for preparing transmissivity changeable film |
Country Status (1)
Country | Link |
---|---|
KR (1) | KR20170012753A (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20210075921A (en) * | 2021-04-29 | 2021-06-23 | 주식회사 나노브릭 | Electrically variable transmittance film and manufacturing method for the same |
WO2022025474A1 (en) * | 2020-07-28 | 2022-02-03 | 엘지이노텍 주식회사 | Optical path control member and display device comprising same |
EP3848743A4 (en) * | 2018-09-06 | 2022-05-11 | LG Innotek Co., Ltd. | Optical path control member and display device comprising same |
US11680443B2 (en) | 2018-04-20 | 2023-06-20 | Lg Chem, Ltd. | Variable transmittance film and smart window including same |
CN116360174A (en) * | 2023-03-14 | 2023-06-30 | 重庆惠科金渝光电科技有限公司 | Display panel, manufacturing method of display panel and display device |
WO2023158003A1 (en) * | 2022-02-21 | 2023-08-24 | 엘지전자 주식회사 | Display module and display device |
-
2015
- 2015-07-23 KR KR1020150104433A patent/KR20170012753A/en active Search and Examination
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11680443B2 (en) | 2018-04-20 | 2023-06-20 | Lg Chem, Ltd. | Variable transmittance film and smart window including same |
EP3848743A4 (en) * | 2018-09-06 | 2022-05-11 | LG Innotek Co., Ltd. | Optical path control member and display device comprising same |
WO2022025474A1 (en) * | 2020-07-28 | 2022-02-03 | 엘지이노텍 주식회사 | Optical path control member and display device comprising same |
US12007643B2 (en) | 2020-07-28 | 2024-06-11 | Lg Innotek Co., Ltd. | Optical path control member and display device comprising same |
KR20210075921A (en) * | 2021-04-29 | 2021-06-23 | 주식회사 나노브릭 | Electrically variable transmittance film and manufacturing method for the same |
WO2022231387A1 (en) * | 2021-04-29 | 2022-11-03 | 주식회사 나노브릭 | Film with electrically controllable transparency and method for manufacturing same |
WO2023158003A1 (en) * | 2022-02-21 | 2023-08-24 | 엘지전자 주식회사 | Display module and display device |
CN116360174A (en) * | 2023-03-14 | 2023-06-30 | 重庆惠科金渝光电科技有限公司 | Display panel, manufacturing method of display panel and display device |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
KR101971874B1 (en) | Transmissivity changeable film, display device including the same and method for preparing transmissivity changeable film | |
KR101756506B1 (en) | Transmissivity changeable film and display device including the same | |
KR20170012753A (en) | Transmissivity changeable film, display device including the same and method for preparing transmissivity changeable film | |
US12038666B2 (en) | Method of forming a top plane connection in an electro-optic device | |
KR20150126515A (en) | Transmissivity changeable film and display device including the same | |
US8830559B2 (en) | Electro-optic media produced using ink jet printing | |
US9603257B2 (en) | Pattern substrate, method of producing the same, information input apparatus, and display apparatus | |
US9244325B2 (en) | Display sheet, method for producing display sheet, display apparatus, and electronic device | |
TWI614660B (en) | Transparent conductive film and touch panel therewith and display device | |
KR20130062176A (en) | Substrate films for transparent electrode films | |
JP5845765B2 (en) | Transparent conductive laminate and method for producing the same | |
US11782322B2 (en) | Anisotropically conductive moisture barrier films and electro-optic assemblies containing the same | |
KR20230133386A (en) | Sealing layer containing conductive filler for sealing microcells of electrophoretic displays | |
JP2024505888A (en) | Sealing layer for sealing microcells in electro-optic devices | |
US10824042B1 (en) | Electro-optic display and composite materials having low thermal sensitivity for use therein | |
KR102004026B1 (en) | Transparent conductor and display apparatus comprising the same | |
US11934081B2 (en) | Transferrable light-transmissive electrode films for electro-optic devices | |
TWI755081B (en) | Electro-optic display and composite materials having low thermal sensitivity for use therein | |
KR20140007221A (en) | Optical film with improved visibility of ag nanowire | |
CN102362247A (en) | Newton ring preventing sheet, and touch panel using same | |
KR20200132459A (en) | Stacked structure and window for electronic device and electronic device | |
KR102578744B1 (en) | Customized Reflective Color Display Device | |
KR20240096792A (en) | Sealing film composition for sealing microcells of electro-optical devices | |
CN116420116A (en) | Electro-optic displays and composites with low thermal sensitivity for use therein | |
KR102004025B1 (en) | Transparent conductor and display apparatus comprising the same |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A201 | Request for examination | ||
AMND | Amendment | ||
E902 | Notification of reason for refusal | ||
AMND | Amendment | ||
E601 | Decision to refuse application | ||
AMND | Amendment |