KR20150016828A - Novel ligand compound and transiton metal compound comprising the same - Google Patents

Novel ligand compound and transiton metal compound comprising the same Download PDF

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KR20150016828A
KR20150016828A KR1020130092762A KR20130092762A KR20150016828A KR 20150016828 A KR20150016828 A KR 20150016828A KR 1020130092762 A KR1020130092762 A KR 1020130092762A KR 20130092762 A KR20130092762 A KR 20130092762A KR 20150016828 A KR20150016828 A KR 20150016828A
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carbon atoms
group
formula
transition metal
alkyl group
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Korean (ko)
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장재권
한효정
한기원
김슬기
이은정
이충훈
박인성
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주식회사 엘지화학
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C08F4/16—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of silicon, germanium, tin, lead, titanium, zirconium or hafnium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof

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Abstract

The present invention relates to a novel ligand compound and a novel transition metal compound comprising the same, and more specifically, to a ligand compound and a transition metal compound which can be used to prepare polyolefin which has wide molecular-weight distribution and excellent mechanical properties and processability. According to the present invention, provided can be a ligand compound represented by chemical formula 1 and a transition metal compound represented by chemical formula 2.

Description

TECHNICAL FIELD [0001] The present invention relates to a novel ligand compound and a transition metal compound containing the same. BACKGROUND OF THE INVENTION < RTI ID = 0.0 >

The present invention relates to a ligand compound and a transition metal compound containing the same, and more particularly, to a ligand compound and a transition metal compound containing the same, which can be used for producing a polyolefin having a broad molecular weight distribution and excellent mechanical properties and processability .

Ziegler-Natta catalysts of titanium or vanadium compounds have been widely used in the commercial production of conventional polyolefins. Ziegler-Natta catalysts have high activity, but because they are multi-site catalysts, the molecular weight distribution of the produced polymers is wide and the composition distribution of the comonomers is not uniform.

Recently, a metallocene catalyst in which a transition metal such as titanium, zirconium, or hafnium and a ligand containing a cyclopentadiene functional group are bonded has been developed and widely used. The metallocene compound is generally activated by using aluminoxane, borane, borate or other activator. For example, a metallocene compound having a ligand containing a cyclopentadienyl group and two sigma chloride ligands uses aluminoxane as an activator. These metallocene catalysts are single active site catalysts having one kind of active site. The molecular weight distribution of the produced polymer is narrow and the molecular weight, stereoregularity, crystallinity, especially reactivity of the comonomer can be greatly controlled depending on the structure of the catalyst and the ligand There is an advantage. However, since the polyolefin polymerized with the metallocene catalyst has a narrow molecular weight distribution, it is difficult to apply the polyolefin in a field, for example, in a case where it is applied to some products, productivity is remarkably decreased due to the influence of extrusion load. I have done a lot.

Particularly, in order to solve the problems of the metallocene catalyst described above, many transition metal compounds in which a ligand compound containing a hetero atom is coordinated have been introduced. Specific examples of such a heteroatom-containing transition metal compound include azaferrocene compound having a cyclopentadienyl group containing a nitrogen atom, a structure in which a functional group such as a dialkylamine is connected to a cyclopentadienyl group as an additional chain Or a titanium (lV) metallocene compound into which a cyclic alkylamine functional group such as piperidine is introduced, and the like.

However, among all of these attempts, the metallocene catalysts actually applied to commercial plants are only a few, and accordingly, polymerization catalysts capable of realizing higher polymerization performance and capable of providing polyolefins with excellent physical properties There is still a need for research on available metallocene compounds.

The present invention provides a ligand compound and a transition metal compound containing the same that can provide a polyolefin having a broad molecular weight distribution and excellent mechanical properties and processability.

According to one aspect of the present invention, there can be provided a ligand compound represented by the following formula (1).

 [Chemical Formula 1]

Figure pat00001

In Formula 1,

n is 1 or 2;

R 1 to R 10 are the same or different and each independently represents hydrogen, an alkyl group having 1 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, an alkenyl group having 2 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms, An arylalkyl group having 7 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, a heterocyclic group having 5 to 20 carbon atoms, or a silyl group, and R 1 to R 10 At least two adjacent to each other may be linked to each other by an alkylidene group containing an alkyl group having 1 to 20 carbon atoms or an aryl group having 6 to 20 carbon atoms to form a ring;

R 11 is hydrogen, halogen, an alkyl group having 1 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, or an aryl group having 6 to 20 carbon atoms;

R 12 represents hydrogen, an alkyl group having 1 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, an alkenyl group having 2 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms, an alkylaryl group having 7 to 20 carbon atoms, An arylalkyl group, a cycloalkyl group having 3 to 20 carbon atoms, or a silyl group;

Q is carbon (C) or silicon (Si);

Y is oxygen (O) or sulfur (S).

According to another aspect of the present invention, there can be provided a transition metal compound including the ligand compound and represented by the following formula (2).

 (2)

Figure pat00002

In Formula 2,

n is 1 or 2,

R 1 to R 10 are the same or different and each independently represents hydrogen, an alkyl group having 1 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, an alkenyl group having 2 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms, An arylalkyl group having 7 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, a heterocyclic group having 5 to 20 carbon atoms, or a silyl group, and R 1 to R 10 At least two adjacent to each other may be linked to each other by an alkylidene group containing an alkyl group having 1 to 20 carbon atoms or an aryl group having 6 to 20 carbon atoms to form a ring;

R 11 is hydrogen, halogen, an alkyl group having 1 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, or an aryl group having 6 to 20 carbon atoms;

R 12 represents hydrogen, an alkyl group having 1 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, an alkenyl group having 2 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms, an alkylaryl group having 7 to 20 carbon atoms, An arylalkyl group, a cycloalkyl group having 3 to 20 carbon atoms, or a silyl group;

Q is carbon (C) or silicon (Si);

Y is oxygen (O) or sulfur (S);

M is a Group 4 transition metal;

X 1 and X 2 are the same or different and are each independently selected from the group consisting of halogen, an alkyl group having 1 to 20 carbon atoms, an alkenyl group having 2 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms, an alkylaryl group having 7 to 20 carbon atoms, An alkylamino group having 1 to 20 carbon atoms, an arylamino group having 6 to 20 carbon atoms, or an alkylidene group having 1 to 20 carbon atoms.

According to the present invention, there can be provided a novel ligand compound and a transition metal compound containing the same, which can provide a polyolefin having a broad molecular weight distribution and excellent mechanical properties and processability.

The terminology used herein is for the purpose of describing exemplary embodiments only and is not intended to be limiting of the invention. The singular expressions include plural expressions unless the context clearly dictates otherwise. In this specification, the terms "comprising," "comprising," or "having ", and the like are intended to specify the presence of stated features, But do not preclude the presence or addition of one or more other features, integers, steps, components, or combinations thereof.

While the invention is susceptible to various modifications and alternative forms, specific embodiments thereof are shown by way of example in the drawings and will herein be described in detail. It should be understood, however, that the invention is not intended to be limited to the particular forms disclosed, but includes all modifications, equivalents, and alternatives falling within the spirit and scope of the invention.

Hereinafter, the present invention will be described in detail.

The ligand compound according to one aspect of the present invention can be represented by the following formula (1).

[Chemical Formula 1]

Figure pat00003

In Formula 1,

n is 1 or 2,

R 1 to R 10 are the same or different and each independently represents hydrogen, an alkyl group having 1 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, an alkenyl group having 2 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms, An arylalkyl group having 7 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, a heterocyclic group having 5 to 20 carbon atoms, or a silyl group, and R 1 to R 10 At least two adjacent to each other may be linked to each other by an alkylidene group containing an alkyl group having 1 to 20 carbon atoms or an aryl group having 6 to 20 carbon atoms to form a ring;

R 11 is hydrogen, halogen, an alkyl group having 1 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, or an aryl group having 6 to 20 carbon atoms;

R 12 represents hydrogen, an alkyl group having 1 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, an alkenyl group having 2 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms, an alkylaryl group having 7 to 20 carbon atoms, An arylalkyl group, a cycloalkyl group having 3 to 20 carbon atoms, or a silyl group;

Q is carbon (C) or silicon (Si);

Y is oxygen (O) or sulfur (S).

Each of the substituents defined in the present specification will be described in detail as follows.

The alkyl group includes a linear or branched alkyl group.

The alkenyl group includes a linear or branched alkenyl group.

The alkylaryl group means an aryl group substituted by the alkyl group.

The arylalkyl group means an alkyl group substituted by the aryl group.

The halogen means a fluorine group, a chlorine group, a bromine group or an iodine group.

The silyl group includes trimethylsilyl, triethylsilyl, tripropylsilyl, tributylsilyl, trihexylsilyl, triisopropylsilyl, triisobutylsilyl, triethoxysilyl, triphenylsilyl, tris (trimethylsilyl) , But are not limited to these examples.

The aryl group preferably has 6 to 20 carbon atoms, and specifically includes phenyl, naphthyl, anthracenyl, pyridyl, dimethylanilinyl, anisolyl, and the like, but is not limited thereto.

The heterocyclic group means a monovalent aliphatic or aromatic hydrocarbon group having 5 to 20 carbon atoms and containing at least one heteroatom, and may be a single ring or a condensed ring of two or more rings. The heterocyclic group may be substituted or unsubstituted with an alkyl group. Examples thereof include indoline, tetrahydroquinoline and the like, but the present invention is not limited thereto.

According to one embodiment of the present invention, in order to control the steric factors and electronic factors of the transition metal compound that can be synthesized from the ligand, R 1 to R 10 in the formula (1) are each independently hydrogen or an alkyl group having 1 to 20 carbon atoms It is preferable that R 11 is an alkyl group having 1 to 20 carbon atoms or an aryl group having 6 to 20 carbon atoms, and R 12 is preferably an alkyl group having 1 to 20 carbon atoms or an aryl group having 6 to 20 carbon atoms Lt; / RTI >

The present inventors have newly synthesized a transition metal compound containing a ligand compound which has not been previously known and can appropriately control the substituents which can be introduced into the ligand compound to easily control the electronic and stereoscopic environment around the transition metal , It is possible to provide a transition metal catalyst which can exhibit high reactivity in the polyolefin polymerization reaction and easily control the characteristics such as the chemical structure, the molecular weight distribution, and the mechanical properties of the synthesized polyolefin.

In particular, the ligand compound of formula (1) has two indenyl groups connected by a silicon or carbon bridge, and one indenyl group has a C1 symmetrical bridge structure to which a heterocyclic ring is connected, It is possible to produce an isotactic polymer and it is possible to produce a polyolefin having excellent stereoregularity.

The ligand compound according to one embodiment of the present invention can be produced, for example, by the following method. A compound represented by the following general formula (5) can be prepared by reacting a compound represented by the following general formula (3) and a compound represented by the following general formula (4).

(3)

Figure pat00004

[Chemical Formula 4]

Figure pat00005

[Chemical Formula 5]

Figure pat00006

In the above formulas 3 to 5,

n, R 1 to R 10 , and Y are as defined in Formula 1,

Z is halogen.

More specifically, the compound represented by Formula 5 may be prepared by forming a CN bond through a coupling reaction between the hetero-bicyclic compound represented by Formula 3 and the indenyl compound represented by Formula 4, It is not.

Here, the reaction of the compound represented by Formula 3 and the compound represented by Formula 4 may be carried out in the presence of palladium-containing catalyst. The palladium-containing catalyst is a compound containing palladium. The catalyst for the coupling reaction which can be generally used in the technical field of the present invention can be used without any particular limitation. For example, tetrakis (triphenylphosphine) palladium (Pd (PPh 3) 4) , palladium chloride (PdCl 2), palladium acetate (Pd (OAc) 2), bis (dibenzylideneacetone) palladium (Pd (dba) 2), Pd (tBu 3 P 2) The ligand compound of the present invention can be produced more efficiently and economically.

In addition, the step of preparing the compound represented by Formula 5 may further include a base. The base can effectively form the compound of formula (5) by effectively mediating the coupling reaction between the compound of formula (3) and the compound of formula (4), thereby reducing the overall reaction time, It is possible to exhibit the effect of being excellent.

Examples of usable bases include, but are not limited to, metal hydroxide salts such as NaOH, alkoxy lithium such as t-BuOLi, potassium tribasic acid (K 3 PO 4 ), potassium carbonate (K 2 CO 3 ) (Cs 2 CO 3 ), potassium fluoride (KF), sodium fluoride (NaF), cesium fluoride (CsF), tetrabutylammonium fluoride (TBAF), or mixtures thereof.

The compound represented by the following formula (6) or its lithium salt is reacted with a compound represented by the following formula (7) to prepare a compound represented by the following formula (8), and the compound represented by the formula (5) 8 can be finally reacted to obtain the ligand compound represented by the above formula (1). As described above, the lithium salt of the indenyl compound represented by Formula 5 may be prepared by adding an organic lithium compound such as n-BuLi to an indenyl compound.

[Chemical Formula 6]

Figure pat00007

(7)

Q (A) 2 (R < 11 >) 2

[Chemical Formula 8]

Figure pat00008

In the above formulas (6) to (8)

R 6 to R 12 are as defined in Formula 1,

Q is carbon (C) or silicon (Si);

A is halogen.

More specifically, after the compound represented by the formula (5) or the lithium salt thereof and the compound represented by the formula (8) are mixed, the mixture is reacted while stirring. The reaction product is then filtered to wash the resulting precipitate and dried under reduced pressure to obtain a compound represented by the formula (1) wherein the compound represented by the formula (5), which is an indenyl group derivative, is C1-symmetrically crosslinked by Q Lt; / RTI > can be obtained.

The above production method can be represented by, for example, the following Reaction Schemes 1 to 3, but is not limited thereto.

[Reaction Scheme 1]

Figure pat00009

[Reaction Scheme 2]

Figure pat00010

[Reaction Scheme 3]

Figure pat00011

According to an embodiment of the present invention, the mixing ratio of the rac: meso type ligand compound represented by Formula 1 may be about 1: 9 to 9: 1. This is because the compound represented by the formula (5) and the compound represented by the formula (6) may be produced as a racemic mixture without a specific stereoselectivity in the reaction, or may be produced as a meso compound.

Meanwhile, the ligand compound of the present invention can be prepared by applying conventional organic synthesis conditions known in the art. For example, the reactants are mixed and reacted at a temperature of about 100 ° C to about 300 ° C, a pressure of about 1 to about 30 atmospheres, usually about 24 hours until the reaction is completed, to obtain the ligand compound Can be prepared.

According to an embodiment of the present invention, the ligand compound represented by Formula 1 may be represented by one of the following structural formulas, but is not limited thereto.

Figure pat00012
Figure pat00013
Figure pat00014

Figure pat00015
Figure pat00016
Figure pat00017

Figure pat00018
Figure pat00019
Figure pat00020

Figure pat00021
Figure pat00022
Figure pat00023

Figure pat00024
Figure pat00025
Figure pat00026

Figure pat00027
Figure pat00028
Figure pat00029

Figure pat00030
Figure pat00031
Figure pat00032

Figure pat00033
Figure pat00034
Figure pat00035

Figure pat00036
Figure pat00037
Figure pat00038

Figure pat00039
Figure pat00040
Figure pat00041

Figure pat00042
Figure pat00043
Figure pat00044

Figure pat00045
Figure pat00046
Figure pat00047

Meanwhile, the transition metal compound according to another aspect of the present invention can be represented by the following formula (2).

 (2)

Figure pat00048

In Formula 2,

n is 1 or 2;

R 1 to R 10 are the same or different and each independently represents hydrogen, an alkyl group having 1 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, an alkenyl group having 2 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms, An arylalkyl group having 7 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, a heterocyclic group having 5 to 20 carbon atoms, or a silyl group, and R 1 to R 10 At least two adjacent to each other may be linked to each other by an alkylidene group containing an alkyl group having 1 to 20 carbon atoms or an aryl group having 6 to 20 carbon atoms to form a ring;

R 11 is hydrogen, halogen, an alkyl group having 1 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, or an aryl group having 6 to 20 carbon atoms;

R 12 represents hydrogen, an alkyl group having 1 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, an alkenyl group having 2 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms, an alkylaryl group having 7 to 20 carbon atoms, An arylalkyl group, a cycloalkyl group having 3 to 20 carbon atoms, or a silyl group;

Q is carbon (C) or silicon (Si);

Y is oxygen (O) or sulfur (S);

M is a Group 4 transition metal;

X 1 and X 2 are the same or different and are each independently selected from the group consisting of halogen, an alkyl group having 1 to 20 carbon atoms, an alkenyl group having 2 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms, an alkylaryl group having 7 to 20 carbon atoms, An alkylamino group having 1 to 20 carbon atoms, an arylamino group having 6 to 20 carbon atoms, or an alkylidene group having 1 to 20 carbon atoms.

According to one embodiment of the present invention, in order to control the steric factor and the electronic factor of the transition metal compound, R 1 to R 10 in the general formulas (1) and (2) are each independently hydrogen or an alkyl group having 1 to 20 carbon atoms R 11 is preferably an alkyl group having 1 to 20 carbon atoms or an aryl group having 6 to 20 carbon atoms, and R 12 is preferably an alkyl group having 1 to 20 carbon atoms or an aryl group having 6 to 20 carbon atoms.

The inventors of the present invention prepared the transition metal compound represented by the above formula (2) in which a Group 4 transition metal was coordinated to the compound represented by Chemical Formula 1 as a ligand. When the polyolefin is used as a catalyst in the olefin polymerization reaction, it can exhibit high reactivity, and by controlling the steric factors depending on the substituent of the transition metal compound, the characteristics of the polyolefin synthesized, such as the chemical structure, molecular weight distribution and mechanical properties, It is thought that it can be controlled.

In particular, as described above, the transition metal compound represented by the general formula (2) has a structure in which two indenyl groups are connected by a silicon or carbon bridge, and one indenyl group has a C1 symmetric cross-linked ligand connected to a heterocyclic ring group When the indenyl group of the ligand includes a chemical structure bound to a transition metal atom, it is possible to produce an isotactic polymer when it is used as a catalyst for an olefin polymerization reaction, It becomes possible to produce such an excellent polyolefin.

According to an embodiment of the present invention, the Group 4 transition metal corresponding to M may be titanium (Ti), zirconium (Zr), hafnium (Hf) or the like, but is not limited thereto.

More specifically, the transition metal compound represented by Formula 2 may be prepared by mixing the ligand compound represented by Formula 1 or a lithium salt thereof and a metal compound represented by Formula 7, and reacting the mixture by stirring. Then, the reaction product is filtered to wash out the resulting precipitate, and dried under reduced pressure to obtain a transition metal compound represented by the general formula (2) in the form of a complex in which a transition metal atom is bonded to the ligand compound.

(7)

Q (A) 2 (R < 11 >) 2

In Formula 7,

R 11 is as defined in Formula 2;

Q is carbon (C) or silicon (Si);

A is halogen.

The ligand compound represented by the formula (1) may be used as a lithium salt by reacting with an organic lithium compound such as n-BuLi. When the ligand compound is transformed into a salt form and reacted with a transition metal compound, the reaction can proceed more efficiently, the side reaction is relatively progressed, and the reaction can proceed efficiently.

The above production method can be represented by, for example, the following Reaction Scheme 4, but is not limited thereto.

 [Reaction Scheme 4]

Figure pat00049

The ligand compound represented by Formula 1 may be mixed with rac: meso at a ratio of 1: 9 to 9: 1. The ligand compound may be reacted with the compound represented by Formula 7 as described above, , A racemic compound represented by the formula (2) can be obtained. As described above, a racemic-type compound can be prepared by reacting a mixture of a racemic-type compound and a meso-type compound. The racemic mixture and the meso-type compound differ in solubility, and only the racemic mixture This is because they can be separated.

Particularly, racemic transition metal compounds prepared by the above-mentioned method can produce isotactic polymers, and thus it is possible to produce polyolefins having excellent stereoregularity.

Meanwhile, the step of preparing the transition metal compound represented by the formula (2) may be carried out by applying conventional organic synthesis conditions known in the art. For example, a mixture of the compound of formula 1 and the compound of formula 7 is mixed and heated to a temperature of about -100 to about 300 < 0 > C and a pressure of about 1 to about 30 atm The compound represented by Formula 2 can be prepared.

Also, according to one embodiment of the present invention, the transition metal compound represented by Formula 2 may be represented by one of the following structural formulas, but is not limited thereto.

Figure pat00050
Figure pat00051
Figure pat00052

Figure pat00053
Figure pat00054
Figure pat00055

Figure pat00056
Figure pat00057
Figure pat00058

Figure pat00059
Figure pat00060
Figure pat00061

Figure pat00062
Figure pat00063
Figure pat00064

Figure pat00065
Figure pat00066
Figure pat00067

Figure pat00068
Figure pat00069
Figure pat00070

Figure pat00071
Figure pat00072
Figure pat00073

Figure pat00074
Figure pat00075
Figure pat00076

Figure pat00077
Figure pat00078
Figure pat00079

Figure pat00080
Figure pat00081
Figure pat00082

Figure pat00083
Figure pat00084

Figure pat00086
Figure pat00087
Figure pat00088

Figure pat00089
Figure pat00090
Figure pat00091

Figure pat00092
Figure pat00093
Figure pat00094

Figure pat00095
Figure pat00096
Figure pat00097

Figure pat00098
Figure pat00099
Figure pat00100

Figure pat00101
Figure pat00102
Figure pat00103

Figure pat00104
Figure pat00105
Figure pat00106

Figure pat00107
Figure pat00108
Figure pat00109

Figure pat00110
Figure pat00111
Figure pat00112

Figure pat00113
Figure pat00114
Figure pat00115

Figure pat00116
Figure pat00117
Figure pat00118

Figure pat00119
Figure pat00120
Figure pat00121

Hereinafter, the present invention will be described in more detail with reference to the following examples. These examples are provided to aid understanding of the present invention and the scope of the present invention is not limited thereto.

In the following examples, the term " overnight "or" overnight "means about 12 to 16 hours and" normal temperature "refers to a temperature of about 20 to about 30 ° C. The organic reagents and solvents used were purchased from Aldrich and Merck and purified by standard methods. At every stage of the synthesis, the contact between air and moisture was blocked to improve the reproducibility of the experiment. Spectra were obtained using a 500 MHz nuclear magnetic resonance (NMR) system to demonstrate the structure of the resulting compound.

Ligand  Synthesis of compounds

[ Example  One]

1 - ((R) -3- ( dimethyl ((R) -2- methyl -4( naphthalen -One- yl ) -1H- inden -One- yl ) silyl) -2- methyl -3H-inden-7-yl) -2,3-dihydro-1H-benzo [b] [1,4] oxazine

5 g (23.9 mmol) of 4-bromo-2-methylindene and 3 ml (1.05 equiv.) Of 3,4-dihydro-2H-benzo [b] [1,4] oxazine were placed in a well- And vacuum-dried at room temperature for 1 hour. In the glove box, 5.8 g (3 equiv.) Of lithium tert-butoxide and bis (tri- (tert-butyl) phosphime) palladium (0) were added and brought back to the hood. In an Ar-purge state, 106 ml of anhydrous toluene was added. The mixture was placed in a water-cooled condenser, placed in an oil bath at 130 ° C, and refluxed for 1 day. After confirming the completion of the reaction conversion by TLC analysis, the reaction mixture was cooled to room temperature, and 100 ml of distilled water was added to terminate the reaction. The organic layer was separated and the aqueous layer was extracted with diethyl ether (50 ml, twice). The organic layer was collected, dried over Na- 2 SO 4, filtered and then evaporated to give the crude product brown solid. Purification by flash column chromatography (MC: n-Hx = 1: 10) yielded 5.1 g of pure white solid (19.4 mmol, 81% yield). Anhydrous methyl tert-butyl ether (44 ml) was added to the resultant product (16.8 mmol), and 7.4 ml (2.5 M in n-hexane, 1.1 equiv.) Of n-butyl lithium was added thereto at -78 ° C. After warming to room temperature, the mixture was stirred overnight. The solvent was removed by vacuum drying, and anhydrous n-hexane (50 ml) was added. After stirring for 10 minutes at room temperature, 4.4 g of white solid product was obtained (16.2 mmol, 97% yield). Then, 2.95 g (10.9 mmol) of [2-Me-4-DBO-Ind] Li and 3.6 g (1 equiv.) Of Me2Si [2-Me-4-Naph- Ind] Cl in a well- dried 100 ml Schlenk flask in a glove box. ) and copper cyanide (40 mg, 0.04 equiv.) were taken in a hood and vacuum-dried at -78 ° C for 10 minutes. 70 ml of anhydrous diethyl ether was added at -78 deg. C and Ar-purge state, and the mixture was stirred for 10 minutes, then warmed to room temperature and stirred for 1 day. After a certain period of time, distilled water (50 ml) was added to terminate the reaction. After separating the organic layer, the water layer was extracted twice with diethyl ether (20 ml). The organic layers were combined, washed with brine, dried over MgSO 4 , filtered and evaporated to give 6.17 g (10.7 mmol, 98% yield) of a yellow solid.

1H-NMR (CDCl 3)

4H in rac- and meso isomers, 3.85-3.60 (m, 8H in rac- and meso isomers), 2.31 (m, ~ 2.02 (m, 12H in rac- and meso isomers), -0.15 ~ -0.25 (m, 12H in rac- and meso- isomers)

1 - ((R) -3- ( dimethyl ((R) -2- methyl -4( naphthalen -One- yl ) -1H- inden -One- yl ) silyl) -2- methyl -3H-inden-7-yl) -2,3-dihydro-1H-benzo [b] [1,4] thiazine

Synthesis of transition metal compounds

[ Example  2]

rac - dimethylsilylene -1 - ((R) -3- (dimethyl ((R) -2- methyl -4( naphthalen -One- yl ) -1H- inden -1-yl) silyl) -2-methyl-3H-inden-7-yl) -2,3-dihydro-1H-benzo [b] [1,4] oxazine zirconium dichloride  synthesis

3.03 g (5.26 mmol) of the ligand compound prepared in Example 1 was added to a well-dried 100 ml Schlenk flask and vacuum dried for 10 minutes. Then, 48 ml of anhydrous methyl tert-butyl ether was added to dissolve the starting material. 4.5 ml (2.5 M in hexane, 2.1 equiv.) Of n-butyl lithium was added in the Ar-purge state at -78 ° C and stirred for 10 minutes. The mixture was warmed to room temperature, stirred overnight, Was removed to obtain a yellow lithium salt, which was placed in a glove box. In the glove box, 1.35 g (1.1 equiv.) Of zirconium (IV) chloride was placed in a flask with lithium salt, sealed well and brought back to the hood. 48 ml of anhydrous toluene was added at -78 ° C and Ar-Purge state, and the mixture was stirred for 10 minutes, then heated to room temperature, and stirred overnight. No slurry was formed in the solution, and 48 ml of diethyl ether was added to induce dialysis. The resulting precipitate was filtered with 4G glass frit, extracted with toluene, and recrystallized several times to obtain rac: meso = 12: 1 transition metal compound.

1 H-NMR (CDCl 3) :

3H), 1.82 (s, 3H), 0.82 (s, 6H), 2.82 (s, 2H)

Claims (11)

A ligand compound represented by the following formula (1):
[Chemical Formula 1]
Figure pat00122

In Formula 1,
n is 1 or 2;
R 1 to R 10 are the same or different and each independently represents hydrogen, an alkyl group having 1 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, an alkenyl group having 2 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms, An arylalkyl group having 7 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, a heterocyclic group having 5 to 20 carbon atoms, or a silyl group, and R 1 to R 10 At least two adjacent to each other may be linked to each other by an alkylidene group containing an alkyl group having 1 to 20 carbon atoms or an aryl group having 6 to 20 carbon atoms to form a ring;
R 11 is hydrogen, halogen, an alkyl group having 1 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, or an aryl group having 6 to 20 carbon atoms;
R 12 represents hydrogen, an alkyl group having 1 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, an alkenyl group having 2 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms, an alkylaryl group having 7 to 20 carbon atoms, An arylalkyl group, a cycloalkyl group having 3 to 20 carbon atoms, or a silyl group;
Q is carbon (C) or silicon (Si).
The method according to claim 1,
R 1 to R 10 in the formula (1) are each independently hydrogen or an alkyl group having 1 to 20 carbon atoms.
The method according to claim 1,
Wherein R < 11 > is an alkyl group having 1 to 20 carbon atoms or an aryl group having 6 to 20 carbon atoms.
The method according to claim 1,
The ligand compound represented by Formula 1 is a ligand compound having a rac: meso type mixing ratio of 1: 9 to 9: 1.
The method according to claim 1,
The compound represented by Formula 1 is a ligand compound having a structure selected from the group consisting of the following structural formulas:
Figure pat00123
Figure pat00124
Figure pat00125

Figure pat00126
Figure pat00127
Figure pat00128

Figure pat00129
Figure pat00130
Figure pat00131


Figure pat00132
Figure pat00133
Figure pat00134

Figure pat00135
Figure pat00136
Figure pat00137

Figure pat00138
Figure pat00139
Figure pat00140

Figure pat00141
Figure pat00142
Figure pat00143

Figure pat00144
Figure pat00145
Figure pat00146

Figure pat00147
Figure pat00149

Figure pat00150
Figure pat00151
Figure pat00152

Figure pat00153
Figure pat00154
Figure pat00155

Figure pat00156
Figure pat00157
Figure pat00158


 A transition metal compound represented by the following formula (2):
(2)
Figure pat00159

In Formula 2,
n is 1 or 2;
R 1 to R 10 are the same or different and each independently represents hydrogen, an alkyl group having 1 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, an alkenyl group having 2 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms, An arylalkyl group having 7 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, a heterocyclic group having 5 to 20 carbon atoms, or a silyl group, and R 1 to R 10 At least two adjacent to each other may be linked to each other by an alkylidene group containing an alkyl group having 1 to 20 carbon atoms or an aryl group having 6 to 20 carbon atoms to form a ring;
R 11 is hydrogen, halogen, an alkyl group having 1 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, or an aryl group having 6 to 20 carbon atoms;
R 12 represents hydrogen, an alkyl group having 1 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, an alkenyl group having 2 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms, an alkylaryl group having 7 to 20 carbon atoms, An arylalkyl group, a cycloalkyl group having 3 to 20 carbon atoms, or a silyl group;
Q is carbon (C) or silicon (Si);
Y is oxygen (O) or sulfur (S);
M is a Group 4 transition metal;
X 1 and X 2 are the same or different and are each independently selected from the group consisting of halogen, an alkyl group having 1 to 20 carbon atoms, an alkenyl group having 2 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms, an alkylaryl group having 7 to 20 carbon atoms, An alkylamino group having 1 to 20 carbon atoms, an arylamino group having 6 to 20 carbon atoms, or an alkylidene group having 1 to 20 carbon atoms.
The method according to claim 6,
Wherein each of R 1 to R 10 in Formula 2 is independently hydrogen or an alkyl group having 1 to 20 carbon atoms.
The method according to claim 6,
Wherein R < 11 > in the above formula (2) is an alkyl group having 1 to 20 carbon atoms or an aryl group having 6 to 20 carbon atoms.
The method according to claim 6,
Wherein M is selected from the group consisting of titanium (Ti), zirconium (Zr), and hafnium (Hf).
The method according to claim 6,
Wherein the transition metal compound represented by Formula 2 is a racemic type transition metal compound.
The method according to claim 6,
The transition metal compound represented by Formula 2 is a transition metal compound having a structure selected from the group consisting of the following structural formulas:
Figure pat00160
Figure pat00161
Figure pat00162

Figure pat00163
Figure pat00164
Figure pat00165

Figure pat00166
Figure pat00167
Figure pat00168

Figure pat00169
Figure pat00170
Figure pat00171

Figure pat00172
Figure pat00173
Figure pat00174

Figure pat00175
Figure pat00176
Figure pat00177

Figure pat00178
Figure pat00179
Figure pat00180

Figure pat00181
Figure pat00182
Figure pat00183

Figure pat00184
Figure pat00185
Figure pat00186

Figure pat00187
Figure pat00188
Figure pat00189

Figure pat00190
Figure pat00191
Figure pat00192

Figure pat00193
Figure pat00194
Figure pat00195

Figure pat00196
Figure pat00197
Figure pat00198

Figure pat00199
Figure pat00200
Figure pat00201

Figure pat00202
Figure pat00203
Figure pat00204

Figure pat00205
Figure pat00206
Figure pat00207

Figure pat00208
Figure pat00209
Figure pat00210

Figure pat00211
Figure pat00212
Figure pat00213

Figure pat00214
Figure pat00215
Figure pat00216

Figure pat00217
Figure pat00218
Figure pat00219

Figure pat00220
Figure pat00221
Figure pat00222

Figure pat00223
Figure pat00224
Figure pat00225

Figure pat00226
Figure pat00227
Figure pat00228

Figure pat00229
Figure pat00230
Figure pat00231
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018106029A1 (en) * 2016-12-06 2018-06-14 한화케미칼 주식회사 Transition metal compound for olefin polymerization catalyst, olefin polymerization catalyst comprising same, and polyolefin polymerized using same

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018106029A1 (en) * 2016-12-06 2018-06-14 한화케미칼 주식회사 Transition metal compound for olefin polymerization catalyst, olefin polymerization catalyst comprising same, and polyolefin polymerized using same

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