KR20150005010A - Apparatus for producing sterilized water comprising chlorine and ozone - Google Patents

Apparatus for producing sterilized water comprising chlorine and ozone Download PDF

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KR20150005010A
KR20150005010A KR20130078126A KR20130078126A KR20150005010A KR 20150005010 A KR20150005010 A KR 20150005010A KR 20130078126 A KR20130078126 A KR 20130078126A KR 20130078126 A KR20130078126 A KR 20130078126A KR 20150005010 A KR20150005010 A KR 20150005010A
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water
ozone
chlorine
treated water
storage tank
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KR20130078126A
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이주봉
김종오
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이주봉
김종오
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    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/24—Halogens or compounds thereof
    • C25B1/26—Chlorine; Compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J19/10—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing sonic or ultrasonic vibrations
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/72—Treatment of water, waste water, or sewage by oxidation
    • C02F1/78—Treatment of water, waste water, or sewage by oxidation with ozone
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/13—Ozone
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/70—Assemblies comprising two or more cells

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  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
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  • Metallurgy (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)
  • Treatment Of Water By Oxidation Or Reduction (AREA)

Abstract

The present invention relates to apparatus for producing sterilized water containing chlorine and ozone capable of generating micro sized chlorine and ozone from treated water using a principle of electrolysis so as to use the treated water as the sterilized water containing the chlorine and ozone for a long time. The apparatus of the present invention comprises a storage rank (10) wherein the water mixed with chlorine ions is stored; a first electrolytic cell (30) which receives the water containing the chlorine ions from the storage tank (10) and stores the water, and electrolyzes the chlorine ions using the power supplied from a first power supply unit (40) so as to generate microbubble type chlorine and produce a first treated water; a second electrolytic cell (50) which receives the first treated water with dissolved chlorine from the first electrolytic cell and stores the water, and generates microbubble type ozone using the power supplied from a second power supply unit (60) so as to produce a second treated water; a storage chamber (80) which receives and stores the second treated water treated in the second electrolytic cell; and an ultrasonic wave oscillator (90) which supplies ultrasonic waves to the inside of the storage chamber (80) so as to reduce the ozone contained in the second treated water and make the ozone into nanobubbles.

Description

염소와 오존을 포함하는 살균수 처리장치{APPARATUS FOR PRODUCING STERILIZED WATER COMPRISING CHLORINE AND OZONE}[0001] APPARATUS FOR PRODUCING STERILIZED WATER COMPRISING CHLORINE AND OZONE [0002]

본 발명은 전기분해원리를 이용하여 처리수로부터 마이크로 크기의 염소와 오존을 발생시켜 염소와 오존이 장기간 보존되는 살균수로 사용할 수 있는 염소와 오존을 포함하는 살균수 처리장치에 관한 것이다.
The present invention relates to a sterilizing water treatment apparatus including chlorine and ozone, which can generate micro-sized chlorine and ozone from treated water using electrolysis principle and can be used as sterilization water for long-term preservation of chlorine and ozone.

일반적으로, 식품공장 및 규모가 큰 식당 등에서는 환경위생과 식재료의 신선도에 대한 관심이 높아지고 있다. 특히 오염 가능성이 있는 기구나 재료를 불충분하게 소독을 하면 세균에 의한 집단감염이 높아 세균이 번창하는 여름철에는 특히 주의가 필요하게 된다. Generally, interest in environmental hygiene and freshness of food is increasing in food factories and large restaurants. In particular, insufficient disinfection of potentially contaminated equipment or materials can cause serious infections caused by bacteria, which may require special attention during summer months when bacteria are prospering.

또한 산업적인 측면에서도 작물재배나 축산업의 전염병 예방 차원에서 쓰는 소독제, 병원 및 화장실 살균세정제, 각종 분수대에서 사용하는 살균소독제 등 이러한 것의 수요는 나날이 증가하고 있는 실정이다. In addition, the demand for such things as industrial disinfectants, hospital and toilet sterilization cleaners and disinfection disinfectants used in various fountains are increasing day by day.

이런 경우 대부분은 소독제나 열에 의한 수단을 사용하게 되는데 여기에는 여러 가지 문제점이 나타나게 된다. 살균소독제로는 차아염소산나트륨(NaOCl), 과산화수소(H2O2), 알코올, 오존(O3), Peracetic Acid(Oxonia) 등이 알려져 있다. 이중 가장 많이 사용하는 살균소독제는 차아염소산나트륨(NaOCl)인데 인체와 환경에 미치는 부담이 크기 때문에 많은 량을 사용하기에는 제한적일 수밖에 없다. Most of these cases use disinfectants or other means of heat, which causes several problems. Sodium hypochlorite (NaOCl), hydrogen peroxide (H 2 O 2 ), alcohol, ozone (O 3 ), and peracetic acid (Oxonia) are known as disinfectant. The most commonly used disinfectant is sodium hypochlorite (NaOCl), which is a burden on the human body and the environment.

이에 대한 대안으로 오존(O3)을 용해시킨 오존수가 많이 검토되었으나 오존수는 수중 잔류시간이 매우 짧고 사용 중에 오존이 비산되어 사용자들의 건강에 나쁜 영향을 주게 되므로 대규모 수처리설비 외에는 널리 보급되지 못하였다. As an alternative, ozone water in which ozone (O 3 ) has been dissolved has been extensively investigated. However, since ozone water has a very short residence time in water and ozone is scattered during use, it adversely affects health of users.

본 발명의 배경기술은 "오존농도 조절이 가능한 오존살균수 제조장치"가 대한민국 특허청에 출원되어 등록번호 30-0393384호(3005.08.11)가 개시되어 있다.
BACKGROUND OF THE INVENTION [0002] The present invention relates to an ozone sterilizing water producing apparatus capable of controlling the ozone concentration, which is filed in the Korean Intellectual Property Office (KIPO), and is disclosed in Korean Patent Registration No. 30-0393384 (3005.08.11).

본 발명의 해결하고자 하는 과제는, 전기분해원리를 이용하여 처리수로부터 마이크로 크기의 염소와 오존을 발생시켜 염소와 오존이 장기간 보존되는 살균수로 사용할 수 있는 염소와 오존을 포함하는 살균수 처리장치를 제공하고자 하는 것이다.
Disclosure of the Invention A problem to be solved by the present invention is to provide a disinfection water treatment apparatus including chlorine and ozone which can be used as sterilization water in which chlorine and ozone are stored for a long time by generating micro- .

본 발명의 일실시예에 따른 염소와 오존을 포함하는 살균수 처리장치는, 염소이온이 혼합된 물이 저장되는 저장탱크(10)와; 저장탱크(10)로부터 염소이온이 함유된 함유수를 제공받아 저장하며 제1전원공급장치(40)로부터 공급받은 전압으로 염소이온을 전기분해하여 마이크로버블형태의 염소를 발생시켜 제1처리수로 생성하는 제1전해조(30)와; 제1전해조에서 염소가 용해된 제1처리수를 제공받아 저장하며 제2전원공급장치(60)로부터 전압을 제공받아 함유수에서 마이크로버블형태의 오존을 발생시켜 제2처리수로 생성하는 제2전해조(50)와; 제2전해조에서 처리된 제2처리수를 제공받아 저장하는 저장조(80)와; 저장조(80)의 내측에 초음파를 제공하여 제2처리수에 포함된 오존을 나노버블 상태로 축소시키는 초음파발진기(90)를 포함하는 것을 특징으로 한다.The apparatus for treating water containing chlorine and ozone according to an embodiment of the present invention includes a storage tank 10 storing water mixed with chlorine ions; Containing water containing chlorine ions is supplied from the storage tank 10 and stored, and chlorine ions are electrolyzed by the voltage supplied from the first power supply unit 40 to generate microbubble-type chlorine, A first electrolytic bath (30) for generating the electrolytic water; The first electrolytic bath receives and stores the first treated water containing chlorine dissolved therein and receives the voltage from the second power supply unit 60 to generate microbubble-shaped ozone in the water containing water to generate the second treated water. An electrolytic bath (50); A storage tank (80) for receiving and storing the second treated water treated in the second electrolytic bath; And an ultrasonic oscillator 90 for reducing the ozone contained in the second treated water to a nano bubble state by providing ultrasonic waves to the inside of the storage tank 80.

바람직하게, 염소이온은 염화나트륨(NaCl), 염산(HCl), 염화칼슘(KCl), 염화마그네슘(MgCl2), 염화칼슘(CaCl2) 중의 어느 하나인 것을 특징으로 한다.Preferably, the chloride ion is any one of NaCl, HCl, KCl, MgCl 2 and CaCl 2 .

바람직하게, 제1전원공급장치(40)는 1~2V의 전압을 제1전해조(30)에 제공하는 것을 특징으로 한다. Preferably, the first power supply device 40 provides a voltage of 1 to 2V to the first electrolyzer 30. [

바람직하게, 제2전원공급장치(60)는 5~6V의 전압을 제2전해조(50)에 제공하는 것을 특징으로 한다. Preferably, the second power supply 60 provides a voltage of 5 to 6 V to the second electrolyzer 50.

바람직하게, 저장조의 상부 일측에 제2처리수에 포함된 수소가스(H2), 염소가스(Cl2), 오존가스(O3)를 배출하는 배출관(81)이 형성된 것을 특징으로 한다.Preferably, a discharge pipe 81 for discharging hydrogen gas (H2), chlorine gas (Cl 2 ) and ozone gas (O 3 ) contained in the second treatment water is formed on one side of the upper part of the reservoir.

바람직하게, 제2전해조(50)와 저장조(80) 사이에는 유입된 제2처리수 포함된 염소와 오존을 고르게 혼합시키는 스타틱믹서(70)가 더 위치하는 것을 특징으로 한다.Preferably, a static mixer 70 is further disposed between the second electrolytic bath 50 and the storage tank 80 to evenly mix the chlorine and ozone contained in the second treated water.

바람직하게, 스타틱믹서의 전단 또는 저장조에는 제2처리수의 pH를 약산성으로 유지하기 위하여 중탄산나트륨 등의 pH조절제(100)가 혼합되는 것을 특징으로 한다.
Preferably, the pH adjusting agent 100 such as sodium bicarbonate is mixed in the shear or storage tank of the static mixer in order to keep the pH of the second treated water slightly acidic.

본 발명의 살균수 제조장치는 전기분해원리를 이용하여 염소와 오존을 발생시키고, 발생된 염소와 오존이 장기간 보존될 수 있는 살균수를 제조할 수 있어서, 세균까지 살균이 가능하여 살균소독효과가 높고, 환경부담이 적으며, 경제성이 높고, 2차 오염이 없으며, 안전성이 확보됨에 따라, 식품공장이나 식당 등에서 널리 사용될 수 있다.
The sterilizing water producing apparatus of the present invention can produce chlorine and ozone by using electrolysis principle and can produce sterilized water in which generated chlorine and ozone can be stored for a long time, High environmental impact, economic efficiency, no secondary pollution, and safety, it can be widely used in food factories, restaurants, and the like.

도 1은 본 발명에 따른 염소와 오존을 포함하는 살균수 처리장치의 개략도.
도 2는 본 발명에 의해 생성된 오존나노버블에 용존전해질이 감싸는 모습을 나타낸 개략도.BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a schematic view of a sterilizing water treatment apparatus comprising chlorine and ozone according to the present invention; FIG.
2 is a schematic view showing a state in which a dissolved electrolyte is enclosed in an ozone nano bubble generated by the present invention.

이하, 첨부된 도면을 참조하여 본 발명에 따른 염소와 오존을 포함하는 살균수 처리장치를 자세히 설명하면 아래와 같다. Hereinafter, a sterilizing water treatment apparatus including chlorine and ozone according to the present invention will be described in detail with reference to the accompanying drawings.

도 1에 도시된 바와 같이 본 발명의 일실시예에 따른 염소와 오존을 포함하는 살균수 제조장치는, 저장탱크(10)와, 제1전해조(30)와, 제1전원공급장치(40)와, 제2전해조(50)와, 제2전원공급장치(60)와, 저장조(80) 및 초음파발진기(90)를 포함한다. 1, the apparatus for producing sterilized water containing chlorine and ozone according to an embodiment of the present invention includes a storage tank 10, a first electrolyzer 30, a first power supply device 40, A second electrolytic bath 50, a second power supply unit 60, a storage tank 80, and an ultrasonic oscillator 90. [

저장탱크(10)는 물에 염소이온을 혼합하여 저장한다. 염소이온은 염화나트륨(NaCl), 염산(HCl), 염화칼슘(KCl), 염화마그네슘(MgCl2), 염화칼슘(CaCl2) 등이 물에 첨가되면서 용해되어 HCl의 전해물질로 함유수가 포함된다. The storage tank 10 stores chlorine ions in water. Chloride ions are dissolved in water by adding sodium chloride (NaCl), hydrochloric acid (HCl), calcium chloride (KCl), magnesium chloride (MgCl 2 ) and calcium chloride (CaCl 2 )

제1전해조(30)는 펌프(20)를 통해 저장탱크(10)로부터 염소이온이 함유된 함유수를 제공받아 저장하며 제1전원공급장치(40)로부터 제공받은 전압으로 염소이온을 전기분해하여 마이크로버블형태의 염소를 발생시켜 제1처리수로 생성한다. 이때, 제1전해조(30)는 소정간격으로 이격되는 셀형태이면서 이리듐의 양전극이 내장되며, 양전극과 음전극은 0.2~0.5mm의 간격으로 이격되는 것이 바람직하다. The first electrolyzer 30 receives and stores the water containing chlorine ions from the storage tank 10 through the pump 20 and electrolyzes the chlorine ions with the voltage supplied from the first power supply unit 40 Chlorine in the form of microbubbles is generated to produce the first treated water. At this time, it is preferable that the first electrolytic bath 30 is a cell type which is spaced apart by a predetermined interval, and a positive electrode of iridium is built in, and the positive electrode and the negative electrode are spaced apart by an interval of 0.2 to 0.5 mm.

제1전원공급장치(40)는 1~2V의 전압을 제1전해조(30)에 제공한다. The first power supply unit 40 supplies a voltage of 1 to 2 V to the first electrolytic bath 30.

이와 같이, 제1전해조(30)의 이리듐의 양전극과 음전극에 제1전원공급장치(40)를 통해 1~2V의 전압이 제공되면 함유수에 용해된 염소이온이 전기분해되면서 전극면에서 염소가 마이크로버블로 생성된 제1처리수로 생성된다. 이때, 생성된 염소는 용해도가 매우 높기 때문에 거의 전부가 제1처리수에 용해되어 살균력이 높은 차아염소산(HOCL)이 된다.When a voltage of 1 to 2 V is supplied to the positive electrode and the negative electrode of the iridium in the first electrolytic bath 30 through the first power supply device 40, chlorine ions dissolved in the contained water are electrolyzed, And is generated as the first process water generated by the micro bubble. At this time, since the produced chlorine has a very high solubility, almost all of the produced chlorine is dissolved in the first treated water and becomes hypochlorous acid (HOCL) having high sterilizing power.

제2전해조(50)는 제1전해조에서 염소가 용해된 제1처리수를 제공받아 저장하며 제2전원공급장치(60)로부터 전압을 제공받아 함유수에서 마이크로버블형태의 오존을 발생시켜 제2처리수로 생성한다. 이때, 제2전해조(50)는 제1처리수를 전기분해하기 위해 외부전원을 입력하며 소정간격으로 이격되는 셀형태이면서 이산화납의 양전극이 내장된다. 여기서, 양전극과 음전극은 0.2~0.5mm의 간격으로 이격되는 것이 바람직하다. The second electrolytic bath 50 receives and stores chlorine-dissolved first treated water in the first electrolyzer, receives a voltage from the second power supply 60, generates microbubble-shaped ozone in the water containing water, And generates it as a process water. At this time, the second electrolytic bath 50 is a cell type in which external power is input to electrolyze the first treated water and is spaced apart by a predetermined interval, and a positive electrode of lead dioxide is built in. Here, it is preferable that the positive electrode and the negative electrode are spaced apart by an interval of 0.2 to 0.5 mm.

제2전원공급장치(60)는 5~6V의 전압을 제2전해조(50)에 제공한다. The second power supply 60 supplies a voltage of 5 to 6 V to the second electrolytic bath 50.

이와 같이, 제2전해조(50)의 이산화납의 양전극과 음전극에 제2전원공급장치(60)를 통해 5~6V의 전압이 제공되면 전극면에서 제2처리수의 물이 전기분해되면서 오존이 마이크로버블 상태로 생성된다. 이때, 생성된 오존은 수중에 부유하게 된다. When a voltage of 5 to 6 V is supplied to the positive electrode and the negative electrode of the lead dioxide of the second electrolytic bath 50 through the second power supply unit 60, the water of the second treated water is electrolyzed on the electrode surface, Bubble state. At this time, the generated ozone floats in water.

저장조(80)는 제2전해조에서 처리된 제2처리수를 제공받아 저장한다. 저장조의 상부에는 배출관(81)이 형성되어 제2처리수에 포함된 수소가스(H2), 염소가스(Cl2), 오존가스(O3) 등을 배출한다.The storage tank 80 receives and stores the second treated water processed in the second electrolytic bath. A discharge pipe 81 is formed in the upper part of the storage tank to discharge hydrogen gas (H2), chlorine gas (Cl 2 ), ozone gas (O 3 ), etc. contained in the second treated water.

초음파발진기(90)는 저장조(80)의 내측에 초음파를 제공하여 제2처리수에 포함된 오존을 나노버블 상태로 축소시킨다. 즉, 저장조(80)의 수중에 부유하는 오존은 시간이 경과하면 수중에 용해되어 피산화성 물질과 반응하거나 자기분해과정을 거쳐 용존 오존농도가 감소하나, 초음파발진기(90)에서 발진되는 초음파에 의해 마이크로버블이 나노버블크기로 축소된다. 이때, 도 2에 도시된 바와 같이 나노버블크기의 오존(NB)은 초미세기포로 형성되면서 표면에 마이너스 전하가 형성되어 수소이온(H+), 염소이온(Cl-), 나트륨이온(Na+) 및 기타의 용존전해질이 외측을 감싸게 되면서 수중에 용해되지 않고 장기간(약1~3개월)동안 보존될 수 있다. The ultrasonic oscillator 90 supplies ultrasonic waves to the inside of the storage tank 80 to reduce ozone contained in the second treated water to a nano bubble state. That is, the ozone floating in the water of the storage tank 80 dissolves in the water over time and reacts with the oxidizing substance or decomposes the dissolved ozone to decrease the concentration of dissolved ozone. By the ultrasonic wave oscillated in the ultrasonic oscillator 90 Micro bubbles are reduced to nano bubble size. At this time, ozone (NB) of the nano-bubbles in size, as shown in Figure 2 as forming micro-intensity prisoner is formed with negative electric charges on the surface of the hydrogen ion (H +), chloride ion (Cl -), sodium ion (Na +) And other dissolved electrolytes can be stored for a long period of time (about 1 to 3 months) without being dissolved in water as they are wrapped around the outside.

한편, 전술한 제2전해조(50)와 저장조(80) 사이에는 스타틱믹서(70)가 위치하는 것이 바람직하다. 스타틱믹서(Static Mixer)(70)의 내부에는 내부로 유입된 제2처리수 포함된 염소와 오존을 고르게 혼합시키는 스크류(71)가 형성된다. 이때, 스타틱믹서의 전단에는 제2처리수의 pH를 약산성으로 유지하기 위하여 중탄산나트륨 등의 pH조절제(100)가 혼합되는 것이 바람직하다. 이러한 pH조절제(100)는 저장조(80)에 혼합되어 제2처리수의 pH를 조절할 수도 있다.Meanwhile, it is preferable that the static mixer 70 is disposed between the second electrolytic bath 50 and the storage tank 80. Inside the static mixer 70, a screw 71 for uniformly mixing ozone with the chlorine contained in the second treated water introduced into the inside of the static mixer 70 is formed. At this time, it is preferable that a pH adjusting agent 100 such as sodium bicarbonate is mixed in the front end of the static mixer in order to keep the pH of the second treated water slightly acidic. The pH adjusting agent 100 may be mixed with the reservoir 80 to adjust the pH of the second treated water.

이와 같이, 본 발명은 염소이온이 함유된 함유수가 펌프(20)에 의해 강제로펌핑되어 제1전해조(30)에 공급되어서 제1전원공급장치(40)에서 인가되는 1~2V의 전압에 의해 함유수에서 염소가 발생된 후, 제2전해조(50)에 공급되어서 제2전원공급장치(60)에서 인가되는 5~6V의 전압에 의해 함유수에서 오존이 발생된다. 계속해서, 스타틱믹서(70)에 의해 믹싱되면서 고르게 혼합된다. 마지막으로, 초음파발진기(90)의 초음파가 발진되는 저장조(80)에서 오존을 나노버블상태로 형성시킨다. 따라서, 최종적으로 저장조에 위치하는 처리수에는 살균력이 강한 염소가 용해되어 있으면서 역시 살균력이 강한 오존이 나노버블 형태로 고르게 혼합되어 있어 탈취수나 살균수 또는 세정수로 사용될 수 있다. As described above, in the present invention, the water containing chlorine ions is forcibly pumped by the pump 20 and supplied to the first electrolytic cell 30, and is supplied to the first electrolytic cell 30 by the voltage of 1 to 2 V applied from the first power supply device 40 After the chlorine is generated in the water containing water, ozone is generated in the water containing water by the voltage of 5 to 6 V which is supplied to the second electrolytic bath 50 and applied by the second power supply device 60. Subsequently, they are mixed by the static mixer 70 and mixed evenly. Finally, the ozone is formed in the nano bubble state in the storage tank 80 where the ultrasonic waves of the ultrasonic oscillator 90 are oscillated. Therefore, finally, the treated water located in the storage tank is mixed with ozone having high sterilizing power and having strong sterilizing power evenly in the form of nano bubbles, so that it can be used as deodorizing water, sterilizing water or washing water.

이와 같은, 본 발명은 수중에 염소가 혼합되어 있으면서 수중에 용해되지 않는 오존도 장기간 보존되는 살균수를 연속적으로 제조할 수 있어서, 세균까지 살균이 가능하여 살균소독효과가 높고, 환경부담이 적으며, 경제성이 높고, 2차 오염이 없으며, 안전성이 확보됨에 따라 식품공장이나 규모가 큰 식당 등에서 널리 사용될 수 있는 매우 유용한 발명이라 할 수 있다.
As described above, the present invention can continuously produce sterilized water for long-term preservation of ozone which is not dissolved in water while chlorine is mixed in water, so that it is possible to sterilize even germs so that the sterilizing effect is high, , It is a very useful invention that can be widely used in food factories and large restaurants due to its high economic efficiency, no secondary pollution, and secured safety.

본 발명이 속하는 기술분야의 당업자는 본 발명이 그 기술적 사상이나 필수적 특징을 변경하지 않고서 다른 구체적인 형태로 실시될 수 있다는 것을 이해할 수 있을 것이다. 그러므로 이상에서 기술한 실시예는 모든 면에서 예시적인 것이며 한정적인 것이 아닌 것으로서 이해되어야 하고, 본 발명의 범위는 상세한 설명보다는 후술하는 청구범위에 의하여 나타내어지며, 청구범위의 의미 및 범위 그리고 그 등가개념으로부터 도출되는 모든 변경 또는 변형된 형태가 본 발명의 범위에 포함되는 것으로 해석되어야 한다.
It will be understood by those skilled in the art that the present invention may be embodied in other specific forms without departing from the spirit or essential characteristics thereof. It is to be understood, therefore, that the embodiments described above are to be considered in all respects as illustrative and not restrictive, the scope of the invention being indicated by the appended claims rather than the foregoing description, and the meaning and scope of the claims and their equivalents It is to be understood that all changes and modifications that come within the meaning and range of equivalency of the claims are to be embraced within their scope.

10 : 저장탱크 20 : 펌프
30 : 제1전해조 40 : 제1전원공급장치
50 : 제2전해조 60 : 제2전원공급장치
70 : 스타틱믹서 80 : 저장조
90 : 초음파발진기 100 : pH조절제10: Storage tank 20: Pump
30: first electrolytic bath 40: first power supply
50: second electrolytic bath 60: second power supply
70: Static mixer 80: Storage tank
90: ultrasonic oscillator 100: pH adjusting agent

Claims (7)

염소이온이 혼합된 물이 저장되는 저장탱크(10)와;
저장탱크(10)로부터 염소이온이 함유된 함유수를 제공받아 저장하며 양전극과 음전극으로 제1전원공급장치(40)로부터 공급받은 전압으로 염소이온을 전기분해하여 마이크로버블형태의 염소를 발생시켜 제1처리수로 생성하는 제1전해조(30)와;
제1전해조에서 염소가 용해된 제1처리수를 제공받아 저장하며 제2전원공급장치(60)로부터 전압을 제공받아 함유수에서 마이크로버블형태의 오존을 발생시켜 제2처리수로 생성하는 제2전해조(50)와;
제2전해조에서 처리된 제2처리수를 제공받아 저장하는 저장조(80)와;
저장조(80)의 내측에 초음파를 제공하여 제2처리수에 포함된 오존을 나노버블 상태로 축소시키는 초음파발진기(90)를 포함하는 것을 특징으로 하는 염소와 오존을 포함하는 살균수 처리장치.
A storage tank (10) in which chlorine ion mixed water is stored;
The chlorine ion is electrolyzed by the voltage supplied from the first power supply unit 40 through the positive electrode and the negative electrode to generate chlorine in the form of microbubbles, 1 < / RTI > treated water;
The first electrolytic bath receives and stores the first treated water containing chlorine dissolved therein and receives the voltage from the second power supply unit 60 to generate microbubble-shaped ozone in the water containing water to generate the second treated water. An electrolytic bath (50);
A storage tank (80) for receiving and storing the second treated water treated in the second electrolytic bath;
And an ultrasonic oscillator (90) for reducing the ozone contained in the second treated water to a nano bubble state by supplying ultrasonic waves to the inside of the storage tank (80).
청구항 1에 있어서, 염소이온은 염화나트륨(NaCl), 염산(HCl), 염화칼슘(KCl), 염화마그네슘(MgCl2), 염화칼슘(CaCl2) 중의 어느 하나인 것을 특징으로 하는 염소와 오존을 포함하는 살균수 처리장치.
The method according to claim 1, wherein the chlorine ion is any one of sodium chloride (NaCl), hydrochloric acid (HCl), calcium chloride (KCl), magnesium chloride (MgCl 2 ), and calcium chloride (CaCl 2 ) Water treatment device.
청구항 1에 있어서, 제1전원공급장치(40)는 1~2V의 전압을 제1전해조(30)에 제공하는 것을 특징으로 하는 염소와 오존을 포함하는 살균수 처리장치.
The sterilizing water treatment device according to claim 1, wherein the first power supply device (40) provides a voltage of 1 to 2V to the first electrolyzer (30).
청구항 1에 있어서, 제2전원공급장치(60)는 5~6V의 전압을 제2전해조(50)에 제공하는 것을 특징으로 하는 염소와 오존을 포함하는 살균수 처리장치.
The sterilizing water treatment device according to claim 1, wherein the second power supply (60) supplies a voltage of 5 to 6 V to the second electrolyzer (50).
청구항 1에 있어서, 저장조의 상부 일측에 제2처리수에 포함된 수소가스(H2), 염소가스(Cl2), 오존가스(O3)을 배출하는 배출관(81)이 형성된 것을 특징으로 하는 염소와 오존을 포함하는 살균수 처리장치.
The method according to claim 1, wherein a discharge pipe (81) for discharging hydrogen gas (H2), chlorine gas (Cl 2 ) and ozone gas (O 3 ) contained in the second treatment water is formed on one side of the upper part of the reservoir And a sterilizing water treatment device including ozone.
청구항 1에 있어서, 제2전해조(50)와 저장조(80) 사이에는 유입된 제2처리수 포함된 염소와 오존을 고르게 혼합시키는 스타틱믹서(70)가 더 위치하는 것을 특징으로 하는 염소와 오존을 포함하는 살균수 처리장치.
The method of claim 1, further comprising a statik mixer (70) between the second electrolyzer (50) and the reservoir (80) to evenly mix the ozone with the chlorine contained in the second treated water. And a sterilizing water treatment device.
청구항 1에 있어서, 스타틱믹서의 전단 또는 저장조에는 제2처리수의 pH를 약산성으로 유지하기 위하여 중탄산나트륨의 pH조절제(100)가 혼합되는 것을 특징으로 하는 염소와 오존을 포함하는 살균수 처리장치.The pretreatment or storage tank of claim 1, wherein the pH adjusting agent (100) of sodium bicarbonate is mixed in the shear or storage tank of the static mixer to maintain the pH of the second treated water to be slightly acidic. Device.
KR20130078126A 2013-07-04 2013-07-04 Apparatus for producing sterilized water comprising chlorine and ozone KR20150005010A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016153145A1 (en) * 2015-03-26 2016-09-29 주식회사 블루텍 Device for preparing sterilized water for livestock
KR20180053144A (en) * 2016-11-11 2018-05-21 대구대학교 산학협력단 Deodorizing apparatus for spraying oxidant complex mist and Deodorizing method thereof
KR20190011951A (en) * 2017-07-26 2019-02-08 조병옥 Deodorization and sterilization device using ozone mist
CN109936980A (en) * 2017-03-14 2019-06-25 纳米技术公司 Purification system
CN112358075A (en) * 2020-09-24 2021-02-12 昆明理工大学 Device for treating chlorine-containing wastewater by using ultrasonic wave and ozone and application method thereof
WO2022031256A1 (en) * 2020-08-05 2022-02-10 Андрей Михайлович МАНУЙЛОВ Device for generating antiseptic solution based on silver atoms and water

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016153145A1 (en) * 2015-03-26 2016-09-29 주식회사 블루텍 Device for preparing sterilized water for livestock
KR20180053144A (en) * 2016-11-11 2018-05-21 대구대학교 산학협력단 Deodorizing apparatus for spraying oxidant complex mist and Deodorizing method thereof
CN109936980A (en) * 2017-03-14 2019-06-25 纳米技术公司 Purification system
KR20190011951A (en) * 2017-07-26 2019-02-08 조병옥 Deodorization and sterilization device using ozone mist
WO2022031256A1 (en) * 2020-08-05 2022-02-10 Андрей Михайлович МАНУЙЛОВ Device for generating antiseptic solution based on silver atoms and water
CN112358075A (en) * 2020-09-24 2021-02-12 昆明理工大学 Device for treating chlorine-containing wastewater by using ultrasonic wave and ozone and application method thereof

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