KR20130112321A - Draping patten glass, and manufacturing method thereof - Google Patents
Draping patten glass, and manufacturing method thereof Download PDFInfo
- Publication number
- KR20130112321A KR20130112321A KR1020120034592A KR20120034592A KR20130112321A KR 20130112321 A KR20130112321 A KR 20130112321A KR 1020120034592 A KR1020120034592 A KR 1020120034592A KR 20120034592 A KR20120034592 A KR 20120034592A KR 20130112321 A KR20130112321 A KR 20130112321A
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- South Korea
- Prior art keywords
- glass
- ink
- drying
- producing
- dimensional
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M3/00—Printing processes to produce particular kinds of printed work, e.g. patterns
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/02—Surface treatment of glass, not in the form of fibres or filaments, by coating with glass
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/033—Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
Abstract
Description
The present invention relates to a three-dimensional patterned glass and a method of manufacturing the same, in particular to print a low-temperature ultra-fine ink by printing only the low-temperature ultra-fine ink without a separate primer treatment when the front-side printing, low-temperature ultra-fine ink and its manufacturing method and three-dimensional using this low-temperature ultra-fine ink A pattern glass and its manufacturing method are related.
In general, the front surface for the lenticular effect on the glass surface is coated or printed after the primer or printed with lens silk printing, or printed with an organic ink. At this time, when printing with an organic ink, the hardness is low, the scratch resistance, yellowing resistance and the adhesive strength is low. In addition, when using the front-side ink inks should be fired at a high temperature of 500 ℃ or more, and the solid content is low to form a thick dry coating film was not able to obtain a lens effect.
An example of a technique for solving such a problem is disclosed in the following Documents 1 to 3 and the like.
That is, the following Patent Document 1 relates to a liquid electrostatic coating method for the surface of a vitreous container, which method is 0.2 to 3% by weight of silanol, 0.1 to 5% by weight of cationic surfactant, and conductivity enhancement on the outer surface of the antistatic treatment Subsequent to the primer coating layer forming step described above, without the primer coating layer forming step and / or the heating or preheating step of applying and drying a primer solution consisting of 0.2-15% by weight of alkylol ammonium salt of the carboxylic acid ester as an additive and the balance of water. An inner surface charging step of adsorbing one charged gas or liquid selected from the group consisting of acetylene gas, ethanol and water to the inner surface of the vitreous vessel, and then grounding the vitreous vessel; Liquid electrostatic coating step of coating at least one liquid resin selected from the group consisting of polyurethane, polyester, epoxy, acrylic, epoxy polyester and melamine resin with a constant voltage of 45 to 90 KV and a spray pressure of 3 to 5 Kg / cm 2 Posted about
In addition, Patent Document 2 below relates to a decorative glass having a double-sided pattern and a method for manufacturing the same, and having a surface pattern layer in which a vitreous ink is fused to the surface of the glass plate to have abrasion resistance and scratch resistance, and to have a three-dimensional texture and etching. It has an effect and has a back pattern layer screen-printed with silk screen ink on the back of the glass plate, so that when faced directly from the front of the glass plate, the back pattern layer matches the surface pattern layer with the glass plate interposed therebetween, creating an overall three-dimensional aesthetic. It is published about the decorative glass which has a double-sided pattern which can be made, and its manufacturing method.
In addition, Patent Document 3 below relates to a glass having a pattern on both surfaces, and after patterning a desired pattern by a process printing method on an adhesive on either side of the glass, glass powder (beads) on the patterned pressure-sensitive adhesive Apply a mold, and the intaglio or embossed mold is laminated on the other side of the glass so that the patterned surface abuts, heated at 700 to 800 ° C. for 20 to 80 minutes, and then the mold is removed. It is published about the manufacturing method of the double-sided patterned glass which shape | molds an intaglio or embossed pattern simultaneously, and has a beautiful appearance.
However, in the conventional technology as described above, the disadvantages of the organic ink and the porcelain ink are low hardness, low scratch resistance, yellowing resistance and adhesion, and low solids, so that a dry coating film cannot be formed thick, and thus a lens effect cannot be obtained. There was this.
An object of the present invention has been made to solve the problems described above, low temperature super-capacitor ink and its manufacturing method capable of forming an excellent coating film excellent in high hardness, weather resistance and chemical resistance and three-dimensional pattern glass using the low temperature super magnetic ink And a method for producing the same.
In addition, another object of the present invention is to provide a mass-produced and economical three-dimensional pattern glass and a method of manufacturing the same without using a separate primer for front printing.
In order to achieve the above object, the method for preparing a low-temperature supernatant ink according to the present invention may include: a first step of stirring at least one of the cooidal sol among alumina sol, silica sol, or zirconia sol; At least one of TEOS, TMOS, dimethyldimethoxysilane, methyltriethoxysilane, trimethylmethoxysilane, r-glycidoxypropyltrimethoxysilane, or r-glycidoxypropyltriethoxysilane in the first stage preparation A second step of adding and reacting the methyl alkoxide of the species; A third step of adding a dibasic ester of dibasic ester, butyl carbitol and methyl ethylene glycol to the second reaction product; And a fourth step of stirring by adding a leveling agent, an antifoaming agent, and a thickener to the third step product.
In addition, in the method for producing a low temperature candle ink according to the present invention, in the first step, the cooidal sol is stirred at room temperature, and in the second step, the reaction is performed for 3 to 5 hours.
In addition, in the method for producing a low temperature candle ink according to the present invention, the viscosity of the composition produced in the fourth step is characterized in that 60 ~ 120 KU (Krebs Unit).
In addition, in order to achieve the above object, the low temperature candle ink according to the present invention is characterized in that it is prepared by the method for producing a low temperature candle ink.
In addition, the method for producing a three-dimensional pattern glass according to the present invention in order to achieve the above object is a method of manufacturing a three-dimensional pattern glass using the low-temperature superfine ink, (a) cutting the glass disc, (b) the cut glass Washing with a weak acid, (c) designing the front and back patterns to be designed on the glass, (d) printing the front surface using the low temperature candle ink according to the front pattern, (e) the printing It characterized in that it comprises the step of drying and curing the front.
In the manufacturing method of the three-dimensional pattern glass according to the present invention, (f) printing the back pattern design on the back of the glass dried in the step (e), (g) drying and curing the printed back glass Characterized in that it further comprises the step.
In addition, in the manufacturing method of the three-dimensional pattern glass according to the present invention, the step (e) is dried for 10 to 30 minutes at 180 to 250 ℃, characterized in that the drying by quenching or slow cooling.
In addition, in the manufacturing method of the three-dimensional pattern glass according to the present invention, the drying step (e) and (g) is characterized in that it is carried out by oven hot air drying or IR drying.
In addition, in the manufacturing method of the three-dimensional pattern glass according to the present invention, the drying in the step (g) is characterized in that it is carried out for 5 to 10 minutes at 130 to 180 ℃.
In addition, in order to achieve the above object, the three-dimensional pattern glass according to the present invention is characterized by being manufactured by the above-described three-dimensional pattern glass manufacturing method.
As described above, according to the three-dimensional patterned glass according to the present invention and a method for manufacturing the same, it is possible to secure mass production by printing only with a low temperature super-element ink without using a separate primer when printing the front surface, thereby ensuring economic efficiency. Effect is obtained.
In addition, according to the three-dimensional patterned glass according to the present invention and a method for manufacturing the same, the effect of semipermanent use can be obtained by forming an excellent coating film having excellent hardness, weather resistance, and chemical resistance due to the printing of porcelain.
Moreover, according to the three-dimensional pattern glass which concerns on this invention, and its manufacturing method, the effect which can form the three-dimensional deep three-dimensional pattern which is not restrict | limited by a pattern by simple operation is also acquired.
1 is a process chart of the method for producing a low temperature superfine ink used in the present invention,
2 is a process chart showing a manufacturing process of the three-dimensional pattern glass according to the present invention.
BRIEF DESCRIPTION OF THE DRAWINGS The advantages and features of the present invention, and how to accomplish them, will become apparent by reference to the embodiments described in detail below with reference to the accompanying drawings. However, the present invention is not limited to the embodiments disclosed below, but may be implemented in various forms, and only the present embodiments are intended to complete the disclosure of the present invention and those skilled in the art to which the present invention pertains. It is provided to fully inform the scope of the invention, and the invention is defined only by the scope of the claims.
Hereinafter, the present invention will be described in detail by the following examples.
First, a method of manufacturing a low temperature candle ink used in the present invention will be described with reference to FIG. 1.
1 is a process chart of the method for producing a low temperature superfine ink used in the present invention.
In the method for producing a low-temperature supernatant ink according to the present invention, first, at least one of the cooidal sol among alumina sol, silica sol or zirconia sol is stirred (S1). When the sol is stirred at a high temperature, the solvent contained in the sol may be volatilized or seed may be generated. Therefore, the sol is preferably stirred at room temperature.
Next, tetraethly orthosilicate (TEOS), tetramethylorthosilicate (TMOS), dimethyldimethoxysilane, methyltriethoxysilane, trimethylmethoxysilane, r-glycidoxypropyltrimethoxysilane or r-glycol were added to the first step preparation. At least one methyl alkoxide in the cydoxy propyl triethoxysilane is added and reacted (S2).
At this time, during the input and reaction, it is preferable to react 10 to 50% by weight of the input for 3 to 5 hours. If the reaction time exceeds 5 hours, the sol and alkoxide are overreactioned, so there is no secondary group, and thus the adhesion decreases significantly. When the reaction time is less than 3 hours, only the unreacted material The product cannot be finished by blending.
Thereafter, a slow-drying solvent of dibasic ester, butyl carbitol and methyl ethylene glycol is added to the reactant of step S2 (S3). The slow-drying solvent is added 1 to 20% by weight. If the fast-drying solvent or the general solvent is added instead of the slow-drying solvent, the printability (for example, plate drying, sealing, and ink dropping) is very poor due to rapid drying.
Next, a leveling agent, an antifoaming agent and a thickener, which are basic additives, are added to the product of step S3 for mass productivity and workability, and stirred to obtain a composition having a KU (Krebs Unit) viscosity of 60 to 120 KU (S4). At this time, the input is administered 0.5 to 2% by weight. There is a problem with reliability and quality when administered outside 0.5 to 2% by weight.
Through the process as described above, the low-temperature super magnetic ink for the thick film according to the present invention is obtained.
Next, the process of manufacturing the three-dimensional pattern glass using the low temperature super magnetic ink prepared as described above will be described with reference to FIG. 2.
Figure 2 is a process chart for explaining the manufacturing process of the three-dimensional pattern glass using the low temperature super-magnetic ink according to the present invention.
First, in order to manufacture a three-dimensional patterned glass according to the present invention, the original plate of the glass is cut to meet the desired standard (S10), and the water is washed with a weak acid to remove foreign substances on the front surface of the glass to be printed (S20). .
Next, the front and rear print portions are divided among the patterns to be printed to design the front and rear patterns, respectively (S30). At this time, it is good to design the front to maximize the three-dimensional effect in consideration of the back design in various types, areas and sizes, such as round, square, triangular. It is good to design the pattern by giving the gradation effect to the back side to be combined with the front design or precisely and precisely adjusting the size and depth of the three-dimensional effect.
Thereafter, the front pattern design is printed on glass (S40). At this time, using the low-temperature supernatant ink for the thick film prepared as described above without processing a separate primer during the printing, the glass silkscreen printing or digital printing printing.
After the front printing step as described above, the printed glass is dried (S50).
In the drying of the step S50, the drying is preferably dried for 1 to 40 minutes at 100 to 400 ℃, preferably, 10 to 30 minutes at 180 to 250 ℃ using oven hot air drying or IR drying. Optionally, drying is performed by quenching when strengthening, and by slow cooling when unreinforcing.
As described above, after the drying step of the front surface is made, the back surface is printed in the same manner as the front surface (S60), and then dried and cured (S70). In the back drying, it is preferable to dry-cure for 1 to 15 minutes at 60 to 250 ° C., preferably at 130 to 180 ° C. for 5 to 10 minutes using oven hot air drying or IR drying.
In addition, during the dry curing step of step S70, the drying time may be increased depending on the thickness of the glass.
As described above, the three-dimensional patterned glass manufacturing method according to the present invention does not undergo a primer treatment and has mass productivity, and is economical.
When the dry hardening as mentioned above is completed, the three-dimensional pattern glass S80 which concerns on this invention is obtained.
As described above, when the low-temperature supernatant ink according to the present invention is dried and cured for 10 to 30 minutes at 180 to 250 ° C. through silkscreen printing on tempered or unreinforced glass, hardness of 7H or more, chemical resistance, weather resistance, and adhesion A coating film excellent in properties is obtained.
After the printing of low temperature candle ink, the drying temperature is less than 180 ℃, the drying is not done, the adhesive strength is weak, and the basic reliability (hardness, chemical resistance, etc.) as the candle ink is not reached. We cannot exhibit physical property as
The three-dimensional patterned glass thus formed forms a three-dimensional deep three-dimensional pattern.
Although the present invention has been described in detail with reference to the above embodiments, it is needless to say that the present invention is not limited to the above-described embodiments, and various modifications may be made without departing from the spirit of the present invention.
Claims (10)
At least one of TEOS, TMOS, dimethyldimethoxysilane, methyltriethoxysilane, trimethylmethoxysilane, r-glycidoxypropyltrimethoxysilane, or r-glycidoxypropyltriethoxysilane in the first stage preparation A second step of adding and reacting the methyl alkoxide of the species;
A third step of adding a dibasic ester of dibasic ester, butyl carbitol and methyl ethylene glycol to the second reaction product;
And a fourth step of stirring by adding a leveling agent, an antifoaming agent and a thickener to the third step product.
In the first step, the cooidal sol is stirred at room temperature,
In the second step, the reaction is a low-temperature candle ink, characterized in that for performing 3 to 5 hours.
The viscosity of the composition produced in the fourth step is a method of producing a low-temperature choji ink, characterized in that 60 ~ 120 KU (Krebs Unit).
(a) cutting the glass disc,
(b) washing the cut glass with a weak acid,
(c) designing the front and back patterns to be designed on the glass,
(d) printing a front surface using the low temperature supernatant ink according to the front surface pattern,
(e) drying and curing the printed entire surface.
(f) printing the back pattern design on the back surface of the glass dried in the step (e),
(g) drying and curing the printed back glass further comprising the step of producing a three-dimensional pattern glass.
The step (e) is dried for 10 to 30 minutes at 180 to 250 ℃, and then dried by quenching or slow cooling method of producing a three-dimensional patterned glass.
The (e) and (g) drying step is a method of producing a three-dimensional pattern glass, characterized in that carried out by oven hot air drying or IR drying.
Drying in the step (g) is a method for producing a three-dimensional pattern glass, characterized in that performed for 5 to 10 minutes at 130 to 180 ℃.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020120034592A KR20130112321A (en) | 2012-04-03 | 2012-04-03 | Draping patten glass, and manufacturing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020120034592A KR20130112321A (en) | 2012-04-03 | 2012-04-03 | Draping patten glass, and manufacturing method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR20130112321A true KR20130112321A (en) | 2013-10-14 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020120034592A KR20130112321A (en) | 2012-04-03 | 2012-04-03 | Draping patten glass, and manufacturing method thereof |
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| KR (1) | KR20130112321A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102317022B1 (en) * | 2020-09-14 | 2021-10-25 | 김성태 | Manufacturing Method For Decorative Glass Panel And Decorative Tile Panel Having Three Dimensional Pattern On The Surface |
-
2012
- 2012-04-03 KR KR1020120034592A patent/KR20130112321A/en not_active Application Discontinuation
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102317022B1 (en) * | 2020-09-14 | 2021-10-25 | 김성태 | Manufacturing Method For Decorative Glass Panel And Decorative Tile Panel Having Three Dimensional Pattern On The Surface |
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