KR20110004617A - Apparatus and method of high efficiency deodorization and air sterilization using advanced oxidation process - Google Patents

Apparatus and method of high efficiency deodorization and air sterilization using advanced oxidation process Download PDF

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Publication number
KR20110004617A
KR20110004617A KR1020090062134A KR20090062134A KR20110004617A KR 20110004617 A KR20110004617 A KR 20110004617A KR 1020090062134 A KR1020090062134 A KR 1020090062134A KR 20090062134 A KR20090062134 A KR 20090062134A KR 20110004617 A KR20110004617 A KR 20110004617A
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KR
South Korea
Prior art keywords
ozone
air
sterilization
radical
deodorizer
Prior art date
Application number
KR1020090062134A
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Korean (ko)
Inventor
유근수
Original Assignee
(주)비트마스터
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Priority to KR1020090062134A priority Critical patent/KR20110004617A/en
Publication of KR20110004617A publication Critical patent/KR20110004617A/en

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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00Disinfection, sterilisation or deodorisation of air
    • A61L9/16Disinfection, sterilisation or deodorisation of air using physical phenomena
    • A61L9/18Radiation
    • A61L9/20Ultra-violet radiation
    • A61L9/205Ultra-violet radiation using a photocatalyst or photosensitiser
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00Disinfection, sterilisation or deodorisation of air
    • A61L9/16Disinfection, sterilisation or deodorisation of air using physical phenomena
    • A61L9/22Ionisation
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24FAIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
    • F24F6/00Air-humidification, e.g. cooling by humidification
    • F24F6/12Air-humidification, e.g. cooling by humidification by forming water dispersions in the air
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2209/00Aspects relating to disinfection, sterilisation or deodorisation of air
    • A61L2209/10Apparatus features
    • A61L2209/11Apparatus for controlling air treatment
    • A61L2209/111Sensor means, e.g. motion, brightness, scent, contaminant sensors
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2209/00Aspects relating to disinfection, sterilisation or deodorisation of air
    • A61L2209/20Method-related aspects
    • A61L2209/21Use of chemical compounds for treating air or the like
    • A61L2209/212Use of ozone, e.g. generated by UV radiation or electrical discharge

Abstract

The present invention relates to a high-efficiency deodorization and air sterilization apparatus using an advanced oxidation process, and more particularly, to mix ozone gas to remove odor-causing substances, harmful components and pathogenic bacteria contained in inlet air. The present invention relates to a high efficiency deodorization and air sterilization apparatus using a highly oxidized process that is structured to improve the contact rate, the dissolution rate, and the generation rate of hydroxyl radical (° OH).

OH radical, ozone, sterilization deodorizer, AOP method, semiconductor cooling, photocatalyst

Description

High efficiency deodorization and air sterilization apparatus using advanced oxidation process and its method {Apparatus and Method of High Efficiency Deodorization and Air Sterilization using Advanced Oxidation Process}

The present invention relates to an air purifier, and to an air sterilization and deodorization device that provides a beneficial environment for the human body by improving the sterilization and deodorization efficiency while reducing the amount of residual ozone.

The air purification structure for sterilizing and deodorizing polluted air includes a filter method using a filter having high adsorption of harmful substances such as activated carbon, an ultraviolet radiation method that emits sterilizing ultraviolet rays, and ozone that emits ozone having sterilization and deodorization properties. Emission systems or mixing systems in which these are combined are used.

Examples of a mixed method in which the ultraviolet irradiation method and the ozone emission method are applied are disclosed in Korean Utility Model Registration No. 0182607, Korean Utility Model Registration No. 0265613, and Korean Utility Model Registration No. 0329780.

In general, ozone (O 3) is a fuselage of pure oxygen, which generates ozone by electric silent discharge and blows it into water, or when used in air, has strong sterilization and oxidizing power. Therefore, it decomposes harmful heavy metals and sterilizes infectious pathogens within seconds. It is a gas which returns to dissolved oxygen in water again.

As mentioned above, ozone is an unstable gas, which is highly chemically active, which causes bacteria, viruses, fungi, odors, various harmful gases in the air and water, and organic substances harmful to the human body (solvents, pesticides, heavy metals, etc.). Attack and chemically react with them to oxidize. This property is used to make air or water clean and sterile.

On the other hand, ozone is a colorless and irritating odorous gas with strong oxidizing power and composed of three oxygen atoms. Unlike chlorine, such ozone does not leave any harmful residues when used as an oxidizing agent.

It removes virus bacteria and has strong bleaching power.

In addition, ozone has an excellent effect of reacting with harmless organic substances such as tobacco smoke, other odorous gases, and various harmful organic substances. This ozone is over a hundred years

It has been used in various fields, such as large-scale water purification plants in Europe and the United States for a long time. Naturally, it forms an ozone layer in the global stratosphere to protect humans from strong solar ultraviolet rays.

The ozone allowable concentration of the above-mentioned ozone in a long working environment is 0.1 ppm, fresh air in the beach contains about 0.05 ppm of natural ozone, and fresh air in the forest often contains about 0.03 ppm of ozone. Ordinary people can detect the smell of ozone in the 0.01 ~ 0.03 ppm in the air.

The ozone described above has a sterilizing ability several hundred times faster than chlorine, and it is a pollution-free material having no sterilization power while retaining seven times the sterilizing power of the conventional chlorine sterilizer. The remaining ozone gas itself is gradually decomposed into oxygen.

No harm (ozone concentration half-life: 10-15 hours in air, 20-30 minutes in water).

On the other hand, ozone effects include sterilization and disinfection effect to remove various germs and viruses from indoor air, and to wash food materials such as fruits, fish and vegetables, and kitchen utensils using ozone water to remove bacteria and ticks. Remove it.

By deodorizing effect, organic gas components that cause odors in restaurants, hotels, buildings and homes are decomposed and reacted with ozone gas to create pleasant air and improve working environment by removing ozone from various factories and waste disposal facilities. .

Pesticides, harmful gases and heavy metals are removed to remove residual pesticides such as fruits and vegetables by washing with ozone water to clean them and to remove pesticides and heavy metals from groundwater.

Decomposes and cleanses with ozone and cleans various organic gases that cause pollution.

Decompose into ozone and release safely.

Long-term preservation and freshness can be extended to maintain freshness and preservation period by ozone treatment and meat ozone treatment when storing fruits and vegetables at low temperature.

Bleaching and bleaching effect is the bleaching and bleaching effect of pulp, fiber and food in the paper, textile, food industry.

On the other hand, ozone, which has sterilization and deodorization functions, has been found to be a cause of photochemical smog, and it is known to cause respiratory disorders when inhaled by the human body. The sheep should be such that they are not harmful to living things, such as humans or livestock.

Therefore, considering that the decomposition time of ozone in the natural state is about 2 to 6 hours at room temperature, in the case of an air purifier that introduces air at a constant speed by a fan, a short time for the purifying air to pass through the purifier In other words, ozone must be sufficiently decomposed within seconds.

However, in the above-described conventional apparatuses, the ozone generator and the ultraviolet lamp are disposed to face each other in the same space, so that the decomposition rate of ozone generated by the ozone generator is lowered, thereby increasing the amount of ozone contained in the purified air. Disinfection and deodorization efficiency is low

In addition, a general air purifier uses a dust collecting filter using a nonwoven fabric to remove dust contained in the air, and an activated carbon filter to remove odors and to purify air or collect ionized pollutants by an electric field. Is adopted. Such an air purifier has some effects in removing dust contained in the air, but is not known to have a great effect in reducing air pollution because it does not have a function of sterilizing bacteria contained in the air. In particular, activated carbon filters for removing odors in the air have to be replaced after long-term use, so it is not economical and troublesome replacement work has been pointed out.

 An air inlet and an air outlet are formed and flowed in from the air inlet.

 Cooling the air with a semiconductor cooling device Increases the density of oxygen to increase ozone generation

 In the ozone lamp installed along the longitudinal direction of the flow path on the flow path in the housing

 To increase the contact rate of the generated ozone with the UV lamp and the photocatalyst coating surface

 OH radical sterilization deodorizer characterized in that the photocatalyst coating guide is installed

As described above, according to the present invention, by providing an OH radical generating device having a structure that can be installed on an indoor wall of a home, office, hospital, or the like, the contaminated indoor air passes through the inside of the OH radical generating device. It removes bacteria, viruses, pesticides, heavy metals and odors, and makes the indoor air comfortable.

In addition, the present invention through the OH radical generating device installed on the interior wall of the home or office

By passing indoor air to remove bacteria, viruses and odors contained in the indoor air, residual OH radicals are reduced to oxygen to provide a healthy and pleasant indoor environment.

 It is effective to help the health of the human body.

In order to achieve the above object, the OH radical sterilization deodorizer has an air inlet and an air outlet, and a flow path leading from the air inlet to the air outlet is formed at a predetermined length of the housing and the air outlet, so that the air A blowing fan for blowing air from an inlet to the air outlet;

The semiconductor cooling device is installed inside the air inlet of the housing,

An apparatus for increasing the cooling oxygen density. An ozone lamp installed along a longitudinal direction of a flow path on a flow path in the housing and an ultraviolet lamp installed on a flow path between the ozone lamp in the housing and the blower fan: between an air inlet and an outlet in the housing. Installation of Quartz Tube As the water flows, oxygen in the water is generated as OH radicals and equipped with a device that can be sprayed with an ultrasonic humidifier.

In addition, it is preferable that the ozone lamp emits light having a wavelength of 184.9 nanometers and 253.7 nanometers, and the ultraviolet lamp emits light having a wavelength of 253.7 nanometers.

Hereinafter, with reference to the accompanying drawings will be described in more detail the OH radical sterilization deodorizing apparatus according to a preferred embodiment of the present invention.

1 is a cross-sectional view of the combined OH radical sterilization deodorizer according to the present invention.

Referring to FIG. 1, the air sterilization deodorizer 10 includes an air sterilization deodorizer housing 11, a blowing fan 27, an ozone lamp 15, an ultraviolet lamp 17, and a photocatalyst coating guide plate 29. .

The housing 11 is composed of a lower case and a lid formed to be separated from each other and coupled by a coupling member such as a bolt in consideration of the interchangeability of the lamps 15 and 17.

As for the housing 11, it is preferable that stainless steel which is a material with high corrosion resistance with respect to ozone is applied. In the case of stainless, SUS 304 or SUS 316 is preferably applied. The air inlet 12 is formed on the front of the lower case 11, the air outlet 28 is formed on the back.

The blowing fan 27 is installed in the lower case 11 adjacent to the air outlet 28.

The ozone lamp 15 is provided on the air inlet 12 side of the lower case 11 along a flow path that becomes a moving direction of air.

Denoted at 14 is an ozone lamp holder, and 18 is an ozone lamp ballast.

As the ozone lamp 15, the one capable of mainly emitting light having a wavelength of 184.9 nm having high ozone generating efficiency can be applied.

Preferably, the ozone lamp 15 is preferably one that can emit light with a wavelength range of 253.7 nm, which is a high sterilizing power, and a wavelength of 184.9 nm, which has a high ozone generating efficiency.

The ultraviolet lamp 17 is provided between the ozone lamp 15 and the blowing fan 277.

The ultraviolet lamp 17 is capable of mainly emitting light of 253.7 nm, which has a high sterilizing power and high ozone resolution. (26) is ultraviolet lamp holder and (19) is ultraviolet lamp ballast

The ozone lamp 15 and the ultraviolet lamp 17 can be manufactured so that desired short wavelength light or light of a plurality of wavelengths can be emitted by appropriately adjusting the type and mixing ratio of the gas injected into the glass tube.

The photocatalyst coating guide plate 29 was provided with a strong catalyst coating film 30 in close proximity to the ozone lamp 15 and the ultraviolet lamp 17.

In addition, the photocatalyst coating guide plate 29 may increase the contact efficiency with the lamps 15 and 17 while the contaminated air introduced through the air inlet 12 stays sufficiently in the ozone lamp 15 in the housing 11. The vortices are provided to the lamps 15 and 17 so as to form vortices.

The photocatalyst guide plate 29 is fastened with a bolt or the like so as to facilitate washing or cleaning, and is installed in the lower case 11.

Power supply line and humidity sensor (21) Gas sensor (20) Temperature sensor (22) Ultrasonic humidifier (26) from power cord to ball (15, 17) through ballast (18, 19) and lamp holder (14, 16) And an operation switch for interrupting power supply to the blowing fan 17 has been omitted.

In addition, it is a matter of course that a timer can be installed to operate the power supply to the lamp (15, 17) according to a set time.

Look at the operation of the air purifier of this structure.

When the blower fan 27 is operated, air is sucked in through the air inlet 12, and the air sucked into the housing 11 first increases the density of cooling oxygen by the semiconductor cooling device 13, and then, in the ozone lamp 15. Ozone is generated by the emitted light of 184.9nm wavelength to sterilize and deodorize, and OH radical is generated by sterilization by light of 253.7nm wavelength.

The undecomposed ozone in the ozone generated in this process is moved along the flow path leading to the ultraviolet lamp 17 by the airflow, and the ozone is decomposed by the light and the photocatalyst coating film 30 having a wavelength of 253.7 nm emitted from the ultraviolet lamp 17. OH radicals are generated. As is known, OH radicals have significantly higher bactericidal properties than ozone.

Therefore, in the process of passing through the flow path where the ultraviolet lamp 17 and the photocatalyst coating film 30 are formed, the residual ozone is mostly decomposed to generate OH radicals, and the air contaminated with the sole is sterilized and deodorized secondarily. As a result, the purified air passed through the OH radical sterilization deodorization apparatus 10 mainly contains oxygen and OH radicals, and ozone can be reduced to less than 0.1 ppm.

Air purification device 10 of this structure is contaminated air ozone lamp (15), ultraviolet lamp (17)

Since the photocatalyst coating film 30 is sequentially passed, it was confirmed that the generation efficiency and sterilization deodorization efficiency of OH radicals were much better than the case in which the ozone lamp and the ultraviolet lamp were arranged in parallel in the related art.

The ozone lamp 15, the ultraviolet lamp 17, and the ultrasonic humidifier 26 operate according to the indoor pollution and humidity detected by the gas sensor 20 and the humidity sensor 21 installed outside the housing 11. By the microcomputer to control the operating state of the load driving means in accordance with the pollution degree and humidity is provided. Here, the microcomputer controls the operation state of the load driving means according to the indoor pollution and humidity detected by the gas sensor 20 and the humidity sensor 21, respectively, the indoor pollution and humidity to one or more preset reference values, respectively. In comparison, the sterilization deodorizing apparatus is driven at different operating times according to the result, and the gas sensor 20 is

It includes a gas sensor 20 so that the resistance value is changed by the density of particles in the air adsorbed on the surface and the humidity sensor 21 includes a humidity sensor 21 to change the resistance value in accordance with the humidity in the air Therefore, when the OH radical sterilization deodorizer 10 is operated, the ozone lamp 15, the ultraviolet lamp 17, and the like are controlled on / off to extend the service life of the OH radical sterilization deodorizer 10 and to prevent unnecessary energy waste. It becomes possible.

In addition, the water flowing in the quartz tube 25 installed in the housing 10 is in contact with the ozone lamp 15 so that the oxygen contained in the water is converted into OH radicals so that the high and low humidity set in conjunction with the humidity sensor 21 is set. It is atomized by ultrasonic humidifier and sprayed into the air to increase sterilization and deodorization performance.

10 OH radical sterilization deodorizer 11 OH radical sterilization deodorizer housing 12 air inlet 13 semiconductor cooling panel 14 ozone lamp socket 15 ozone lamp 16 ultraviolet lamp socket

17 UV Lamp 18 Ozone Lamp Stabilizer 19 UV Lamp Stabilizer 20 Gas Sensor

21 Humidity sensor 22 Temperature sensor 23 Quartz tube 24 In-line mixer 25 Humidifier supply water 26 Ultrasonic humidifier 27 Blower fan 28 Air outlet 29 Photocatalyst coating guide 30 Photocatalyst coating film

Claims (4)

An air inlet and an air outlet are formed, and the air flowing in from the air inlet is increased by using a semiconductor cooling device to increase the density of cooling oxygen, thereby increasing the amount of ozone generated. OH radical sterilization deodorizer, characterized in that the photocatalyst coating guide is installed to increase the contact rate of the ozone generated in the ozone lamp along the longitudinal direction of the flow path with the ultraviolet lamp and the photocatalyst coating surface on the flow path in the housing.  The quartz tube according to claim 1 is mounted inside the OH radical sterilizing deodorizer. OH radical sterilization deodorizer characterized in that the water is introduced into the quartz tube to generate OH radical water, and then atomized with an ultrasonic humidifier and equipped with a sterilization deodorization and humidification device according to the airflow of the blowing fan. The method according to claim 1, wherein the operation state of the load driving means is controlled according to the pollution level of the room detected by the gas detection sensor, and the sterilization and deodorization apparatuses are respectively compared to the preset one or more reference values. OH radical sterilization deodorizer, characterized in that driven by different operating time The method of claim 1, wherein the operation state of the load driving means is controlled according to the high and low of the humidity of the room detected by the humidity detection sensor, and the indoor humidity is compared to one or more preset reference values, respectively, and the sterilization and OH radical sterilization deodorizer, characterized in that the deodorizer is driven with different operating time
KR1020090062134A 2009-07-08 2009-07-08 Apparatus and method of high efficiency deodorization and air sterilization using advanced oxidation process KR20110004617A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105536524A (en) * 2016-02-03 2016-05-04 河海大学常州校区 Air purifying device and operating method thereof
KR102094915B1 (en) * 2018-10-29 2020-03-31 주식회사 웰리스 Air sterilizer
CN113289466A (en) * 2021-05-26 2021-08-24 杭州昂途生物科技有限公司 Passive direct drinking water and air purification integrated equipment
WO2021234406A1 (en) * 2020-05-22 2021-11-25 Airtura Limited Air purifying device
IT202000016927A1 (en) * 2020-07-13 2022-01-13 Comex Group S R L EQUIPMENT FOR SANITIZING ROOMS AND PROCEDURE FOR SANITIZING ROOMS USING SUCH EQUIPMENT

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105536524A (en) * 2016-02-03 2016-05-04 河海大学常州校区 Air purifying device and operating method thereof
KR102094915B1 (en) * 2018-10-29 2020-03-31 주식회사 웰리스 Air sterilizer
US20210236683A1 (en) * 2018-10-29 2021-08-05 Guodong Du Air sterilizing device
US11806450B2 (en) * 2018-10-29 2023-11-07 Guodong Du Air sterilizing device
WO2021234406A1 (en) * 2020-05-22 2021-11-25 Airtura Limited Air purifying device
IT202000016927A1 (en) * 2020-07-13 2022-01-13 Comex Group S R L EQUIPMENT FOR SANITIZING ROOMS AND PROCEDURE FOR SANITIZING ROOMS USING SUCH EQUIPMENT
CN113289466A (en) * 2021-05-26 2021-08-24 杭州昂途生物科技有限公司 Passive direct drinking water and air purification integrated equipment

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