KR20100042320A - The eco-friendly fire-igniter - Google Patents

The eco-friendly fire-igniter Download PDF

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Publication number
KR20100042320A
KR20100042320A KR1020080101410A KR20080101410A KR20100042320A KR 20100042320 A KR20100042320 A KR 20100042320A KR 1020080101410 A KR1020080101410 A KR 1020080101410A KR 20080101410 A KR20080101410 A KR 20080101410A KR 20100042320 A KR20100042320 A KR 20100042320A
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South Korea
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weight
parts
complexing agent
alcohol
eco
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KR1020080101410A
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Korean (ko)
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최재영
배성재
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최재영
배성재
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Priority to KR1020080101410A priority Critical patent/KR20100042320A/en
Publication of KR20100042320A publication Critical patent/KR20100042320A/en

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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L11/00—Manufacture of firelighters
    • C10L11/04—Manufacture of firelighters consisting of combustible material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L5/00—Solid fuels
    • C10L5/02—Solid fuels such as briquettes consisting mainly of carbonaceous materials of mineral or non-mineral origin
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L5/00—Solid fuels
    • C10L5/02—Solid fuels such as briquettes consisting mainly of carbonaceous materials of mineral or non-mineral origin
    • C10L5/26—After-treatment of the shaped fuels, e.g. briquettes
    • C10L5/32—Coating
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L9/00—Treating solid fuels to improve their combustion
    • C10L9/10—Treating solid fuels to improve their combustion by using additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/22—Impregnation or immersion of a fuel component or a fuel as a whole
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/24—Mixing, stirring of fuel components

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Geology (AREA)
  • Combustion & Propulsion (AREA)
  • Manufacturing & Machinery (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)

Abstract

PURPOSE: An environment-friendly complexing agent is provided to be used by being impregnated in the bottom end of charcoal due to harmfulness to a human body and to be used with the charcoal by being mixed with wood dust which is not carbonized. CONSTITUTION: An environment-friendly complexing agent comprises polyvinyl alcohol 0 ~ 70 parts by weight, rosin 0 ~ 70 parts by weight, rosin ester class 0 ~ 70 parts by weight, fatty acids 0 ~ 70 parts by weight, fatty acid salt 0 ~ 70 parts by weight, alcohols 0 ~ 70 parts by weight, polyhydric alcohol series 0 ~ 70 parts by weight, organic acid 0 ~ 70 parts by weight, and solvent 0 ~ 90 parts by weight.

Description

친환경 착화제{The eco-friendly fire-igniter.}Eco-friendly complexing agent {The eco-friendly fire-igniter.}

본 발명은 종래의 화약 재료로 사용되는 질소화합물과 금속염을 사용하지 않고, C, H, O의 원소로만 구성된 알콜 또는 다가알콜류의 화합물을 주원료로 사용하여 제조되는 착화제에 관한 것으로서 연소과정에서 질소산화물(NOx) 같은 2차의 유해물질이 배출되지 않도록 한 것이 특징이다.The present invention relates to a complexing agent prepared using a compound of alcohol or polyalcohols composed only of elements of C, H, O as a main raw material, without using nitrogen compounds and metal salts used as conventional gunpowder materials. It is characterized by preventing the release of secondary harmful substances such as oxides (NOx).

한국 공개특허공보 1989-0001765호 에서는 착화제의 원료로서 질소화합물을 사용하는 것을 소개하고 있다. 이 질소화합물은 그 자체는 무해하다고 하지만 이 질소화합물이 연소될 때에는 일산화질소(NO), 이산화질소(NO2), 일산화이질소(N2O), 삼산화이질소(N2O3), 사산화이질소(N2O4), 오산화이질소(N2O5) 같은 2차적 질소산화물(NOx)을 발생하게 되고 이 2차적 질소산화물(NOx)은 오존층을 파괴할 뿐만이 아니고 우리 인체에 폐기종 및 기관지염을 일으키는 유해한 물질이다. 이러한 이유로 인하여 질소산화물을 발생시키는 화물물을 연료로 하여 음식물을 조리해서는 않된다. 그러나 오늘날 웰빙 식품이라고 하여 숯불구이를 선호하면서 이것은 웰빙 음식문화와 역행하는 전혀 논리가 맞지 않는 현상이 일어나고 있다.Korean Laid-Open Patent Publication No. 1989-0001765 introduces the use of nitrogen compounds as a raw material for complexing agents. The nitrogen compound itself is harmless, but when the nitrogen compound is burned, it is nitrogen monoxide (NO), nitrogen dioxide (NO 2 ), dinitrogen monoxide (N 2 O), dinitrogen trioxide (N 2 O 3 ), dinitrogen tetraoxide ( N 2 O 4 ) and secondary nitrogen oxides (NOx), such as dinitrogen pentoxide (N 2 O 5 ), which not only destroy the ozone layer, but also cause harmful emphysema and bronchitis in our body. It is a substance. For this reason, foods should not be cooked using fuels that produce nitrogen oxides as fuel. Today, however, charcoal grills are preferred as well-being foods, and this is not happening at all contrary to well-being food culture.

더 나아가서 한국 공개특허공보 1989-0001765호 에서는 화약재료로 사용되는 금속염으로서 금속마그네슘을 사용하였으며, 한국 공개특허공보 89-002833호 에서는 초산바륨, 초산칼륨, 과망간산 칼륨, 중크롬산 칼륨과 같은 다수의 화약재료를 사용하고 있다.Furthermore, in Korean Laid-Open Patent Publication No. 1989-0001765, metal magnesium is used as a metal salt used as a gunpowder material, and in Korean Laid-Open Patent Publication No. 89-002833, a number of gunpowder materials such as barium acetate, potassium acetate, potassium permanganate and potassium dichromate are used. I'm using.

본 발명에서는 이러한 문제점을 해결하기 위하여 인체에 무해한 친환경 착화제를 소개하고자 함이 목적이다.In the present invention, to solve this problem, an object of the present invention is to introduce an environment-friendly complexing agent harmless to the human body.

종래의 착화제는 금속염과 질소화합물을 주로 사용하기 때문에 인체에 해로울 뿐만이 아니고 화약같이 격렬하게 연소하기 때문에 소비자들에게 거부감을 주고 있다. 본 발명에서는 인체에 해롭지 않는 화합물을 사용하는 동시에 화약같이 격렬하게 연소되지 않고 부드럽게 연소되는 착화제를 개발하여 상기의 문제점을 해결하고자 한다.Conventional complexing agents are not only harmful to the human body because they mainly use metal salts and nitrogen compounds, and because they burn violently like gunpowder, give consumers a sense of rejection. In the present invention, to solve the above problems by using a compound that is not harmful to the human body and at the same time develop a complexing agent that does not burn violently like gunpowder and burns gently.

본 발명에서는 인체에 해롭지 않은 친환경적인 화합물을 사용하여 위하여 C, H, O의 원소로 구성된 화합물을 사용하였고 특히 연소 시에 2차적으로 발생하는 질소산화물(NOx)을 발생하는 질소화합물은 전혀 사용하지 않도록 하였으며 그리고 화약재료를 사용되는 금속염을 사용하는 대신에 완전연소가 가능한 알콜류 또는 다가알콜류를 사용하여 문제를 해결하였다.In the present invention, a compound composed of elements of C, H, and O is used in order to use an environment-friendly compound that is not harmful to the human body, and in particular, does not use any nitrogen compounds that generate nitrogen oxides (NOx) generated secondarily upon combustion. Instead of using metal salts that use gunpowder materials, alcohol or polyalcohols that can be burned completely are solved.

본 발명의 친환경 착화제는 인체에 해롭지 않고 격렬하지 연소하지 않는 성질을 가지고 있도록 하였고 종래의 숯, 고형연료, 착화탄에 함침시키거나 혼합하여 성형하여 사용할 수있다. 그리고 새로운 개념으로서, 목분 같은 탄화하지 않은 연료 재료와 혼합하여 숯과 같은 모양으로 성형시키면 종래의 숯과 같이 사용할 수 있도록 하는 것이 특징이다.The eco-friendly complexing agent of the present invention is not harmful to the human body and has a property that does not burn violently and can be used by impregnating or mixing the conventional charcoal, solid fuel, ignition coal. And as a new concept, it is characterized in that it can be used as a conventional charcoal by mixing with a non-carbonized fuel material such as wood powder to form a charcoal-like shape.

본 발명의 친환경 착화제는 폴리비닐알콜, 로진, 로진에스테르류, 지방산, 지방산염, 알콜류, 다가알콜류, 유기산, 그리고 용매을 하나 또는 둘 이상의 혼합물로서 구성되고 있다.The eco-friendly complexing agent of the present invention comprises polyvinyl alcohol, rosin, rosin esters, fatty acids, fatty acid salts, alcohols, polyhydric alcohols, organic acids, and solvents as one or more mixtures.

여기서 지방산은 0 내지 70 중량부를 사용함이 바람직하고 팔미트산, 스테아린산, 올레산, 리놀레산 등이 있으며 이것에 국한하는 것이 아니다.The fatty acid is preferably 0 to 70 parts by weight and include, but are not limited to, palmitic acid, stearic acid, oleic acid, linoleic acid, and the like.

지방산 염은 0 내지 70 중량부를 사용함이 바람직하고 나트륨, 칼슘, 칼륨 같은 금속지방산염과 glycerinmonostearate 같은 에스테르 지방산염을 말한다.The fatty acid salt is preferably used in an amount of 0 to 70 parts by weight, and refers to metal fatty acid salts such as sodium, calcium and potassium and ester fatty acid salts such as glycerinmonostearate.

알콜류는 0 내지 70 중량부를 사용함이 바람직하고, 메틸알콜, 에틸알콜, 이소프로필알콜, 부탄올, 헥사놀, 사이크로헥사놀, 등이 있으며 이것에 국한하는 것은 아니다.Alcohols are preferably used in an amount of 0 to 70 parts by weight, and include, but are not limited to, methyl alcohol, ethyl alcohol, isopropyl alcohol, butanol, hexanol, cyclohexanol, and the like.

다가알콜류는 1 내지 70 중량부를 사용함이 바람직 하고, 에틸렌글리콜, 글리세린. 폴리에틸렌글리시딜, 폴리프로필렌글리콜, 글루코스, 솔비톨, 솔비탄, 전분, 맥아당, 덱스트린, 글리코겐, 과당, trimethylol propane, trimethylol ethane, pentaerythritol 등이 있으며 이것에 국한하는 것은 아니다.Polyhydric alcohols are preferably used 1 to 70 parts by weight, ethylene glycol, glycerin. Polyethylene glycidyl, polypropylene glycol, glucose, sorbitol, sorbitan, starch, maltose, dextrin, glycogen, fructose, trimethylol propane, trimethylol ethane, pentaerythritol, and the like.

유기산은 0 내지 70 중량부를 사용함이 바람직하고, 구연산과 글루코닉산 등 이 있으며 이것에 국한하는 것은 아니다.It is preferable to use 0-70 weight part of organic acids, and there are, but is not limited to, citric acid, gluconic acid, and the like.

용매는 0 내지 90 중량부를 사용함이 바람직하고, 물, 알콜, 또는 물-알콜 혼합물을 사용함이 바람직하다.It is preferable to use 0 to 90 parts by weight of the solvent, preferably water, alcohol, or a water-alcohol mixture.

이하 적용예를 통하여 상세히 설명한다.It will be described in detail through the following application examples.

[적용예 1][Application Example 1]

로진 50g, 구연산 30g, 에틸렌글리콜 20g, 글리세린 20g, trimethylol ethane 50g, 탄산칼슘 20g을 부탄올 100g에 용해시킨 조성물 중에서 10g을 발취하여 종래의 숯 하단부에 함침시켜서 착화숯으로 적용하였다.50 g of rosin, 30 g of citric acid, 20 g of ethylene glycol, 20 g of glycerin, 50 g of trimethylol ethane, and 20 g of calcium carbonate were extracted from the composition dissolved in 100 g of butanol and impregnated at the bottom of a conventional charcoal to be applied as a complex charcoal.

[적용예 2][Application Example 2]

로진 50g, 구연산 30g, 에틸렌글리콜 20g, 글리세린 20g, trimethylol ethane 50g, 탄산칼슘 20g을 부탄올 100g에 용해시킨 조성물 중에서 10g을 발취하여 종래의 구멍탄 하단부에 함침시켜서 착화탄으로 적용하였다.50 g of rosin, 30 g of citric acid, 20 g of ethylene glycol, 20 g of glycerin, 50 g of trimethylol ethane, and 20 g of calcium carbonate were extracted from the composition dissolved in 100 g of butanol, and impregnated into the lower portion of the conventional hole coal to be applied as a complex coal.

[적용예 3][Application Example 3]

구연산 50g, 에틸렌글리콜 20g, 글리세린 20g, trimethylol ethane 50g, glycerinmonostearate 50g, 폴리비닐알콜5％ 수용액 50g, 을 부탄올 20g의 조성물을 탄화하지 않은 목분 300g과 혼합한 것을 종래의 숯의 대용품으로 적용하였다.A mixture of 50 g citric acid, 20 g ethylene glycol, 20 g glycerin, 50 g trimethylol ethane, 50 g glycerinmonostearate, 50 g polyvinyl alcohol 5% aqueous solution, and 20 g butanol was mixed with 300 g of uncarbonized wood powder as a substitute for conventional charcoal.

Claims (5)

본 발명은 인체에 무해하고 부드럽게 연소되는 친환경 착화제로서 종래의 숯 또는 착화탄의 하단 부분에 함침하여 사용되거나 탄화하지 않은 자연상태의 목분과 혼합되어 종래의 숯과 같이 사용되도록 한 것이 특징이며, 폴리비닐알콜, 로진, 로진에스테르류, 지방산, 지방산 염, 알콜류, 다가알콜류, 유기산, 그리고 용매을 하나 또는 둘 이상을 혼합하여 다음과 같이The present invention is an environmentally friendly complexing agent that is harmless to the human body and burns smoothly. Polyvinyl alcohol, rosin, rosin esters, fatty acids, fatty acid salts, alcohols, polyhydric alcohols, organic acids, and solvents by mixing one or two or more as follows 폴리비닐알콜 0 내지 70 중량부  0 to 70 parts by weight of polyvinyl alcohol 로진 0 내지 70 중량부          0 to 70 parts by weight of rosin 로진에스테르류 0 내지 70 중량부0 to 70 parts by weight of rosin esters 지방산류 0 내지 70 중량부      0 to 70 parts by weight of fatty acids 지방산 염류 0 내지 70 중량부   0 to 70 parts by weight of fatty acid salt 알콜류 0 내지 70 중량부        Alcohol 0-70 parts by weight 다가알콜류 0 내지 70 중량부    0 to 70 parts by weight of polyhydric alcohols 유기산류 0 내지 70 중량부      0 to 70 parts by weight of organic acids 용매 0 내지 90 중량부          0 to 90 parts by weight of solvent 구성됨을 특징으로 하는 친환경 착화제Eco-friendly complexing agent characterized in that 제 1항에 있어서, 알콜류는 메틸알콜, 에틸알콜, 이소프로필알콜, 부탄올, 헥사놀, 사이크로헥사놀 등을 하나 또는 둘 이상을 사용함을 특징으로 하여 제조되 는 친환경 착화제.The environmentally friendly complexing agent of claim 1, wherein the alcohols are prepared by using one or more of methyl alcohol, ethyl alcohol, isopropyl alcohol, butanol, hexanol, cyclohexanol and the like. 제 1항에 있어서, 상기의 다가알콜류는 에틸렌글리콜, 글리세린. 폴리에틸렌글리시딜, 폴리프로필렌글리콜, 글루코스, 솔비톨, 솔비탄, 전분, 맥아당, 덱스트린, 글리코겐, 과당, trimethylol propane, trimethylol ethane, pentaerythritol 등을 하나 또는 둘 이상을 사용함을 특징으로 하여 제조되는 친환경 착화제.The method of claim 1, wherein the polyhydric alcohols are ethylene glycol, glycerin. Eco-friendly complexing agent produced by using one or more of polyethyleneglycidyl, polypropylene glycol, glucose, sorbitol, sorbitan, starch, maltose, dextrin, glycogen, fructose, trimethylol propane, trimethylol ethane, pentaerythritol . 제 1항에 있어서, 상기의 유기산은 구연산과 글루코닉산 등을 하나 또는 둘 이상을 사용함을 특징으로 하여 제조되는 친환경 착화제.The environmentally friendly complexing agent of claim 1, wherein the organic acid is prepared by using one or more of citric acid, gluconic acid, and the like. 제 1항에 있어서, 상기의 용매는 물, 알콜, 또는 물-알콜 혼합물을 사용함을 특징으로 하여 제조되는 친환경 착화제.The eco-friendly complexing agent of claim 1, wherein the solvent is water, an alcohol, or a water-alcohol mixture.
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10273424B2 (en) 2012-03-09 2019-04-30 B.C.B. International Limited Alcohol-containing compositions useful as solid fuels and processes for their manufacture

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10273424B2 (en) 2012-03-09 2019-04-30 B.C.B. International Limited Alcohol-containing compositions useful as solid fuels and processes for their manufacture

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