KR20080093905A - Herbicidal composition - Google Patents
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- KR20080093905A KR20080093905A KR1020080035304A KR20080035304A KR20080093905A KR 20080093905 A KR20080093905 A KR 20080093905A KR 1020080035304 A KR1020080035304 A KR 1020080035304A KR 20080035304 A KR20080035304 A KR 20080035304A KR 20080093905 A KR20080093905 A KR 20080093905A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/36—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
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- C07D413/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms
- C07D413/14—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing three or more hetero rings
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Abstract
Description
본 발명은 벼용의 제초 조성물 및 제초방법에 관한 것이다.The present invention relates to a herbicidal composition and a herbicidal method for rice.
화합물 (A)는 제초활성을 나타내는 화합물로서 개시되어 있다(예를 들어, 특허문헌 1).Compound (A) is disclosed as a compound which exhibits herbicidal activity (for example, patent document 1).
[특허문헌 1] 국제특허출원공개 제2005/103044호 팜플렛[Patent Document 1] International Patent Application Publication No. 2005/103044 Pamphlet
현재, 벼용 제초제로서 수많은 화합물이 실용화되고 있으나, 기존의 약제는 벼에 약해를 미치지 않고, 대상 잡초만을 선택적으로 방제한다는 요구를 반드시 완전히 만족하는 것은 아니다. Currently, many compounds have been put to practical use as herbicides for rice, but existing drugs do not necessarily satisfy the demand of selectively controlling only the target weeds without harming rice.
다이므론(daimuron/일반명, 이하 화합물 (1)이라 기재한다.), 디메타메트린(dimethametryn/일반명, 이하 화합물 (2)라 기재한다.), 벤조비시클론(benzobicyclon/일반명, 이하 화합물 (3)이라 기재한다.), AVH-301(시험명, 테푸릴트리온(tefuryltrione), 이하 화합물 (4)라 기재한다.), 메소트리온(mesotrione/일반명, 이하 화합물 (5)라 기재한다.), 클로메프로프(clomeprop/일반명, 이하 화합물 (6)이라 기재한다.), 브로모부티드(bromobutide/일반명, 이하 화합물 (7)이라 기재한다.), 부타클로르(butachlor/일반명, 이하 화합물 (8)이라 기재한다.), 프레틸라클로르(pretilachlor/일반명, 이하 화합물 (9)라 기재한다.), 펜톡사존(pentoxazone/일반명, 이하 화합물 (10)이라 기재한다.), 피라클로닐(pyraclonil/일반명, 이하 화합물 (11)이라 기재한다.), 펜트라자미드(fentrazamide/일반명, 이하 화합물 (12)라 기재한다.), 메페나세트(mefenacet/일반명, 이하 화합물 (13)이라 기재한다.), 인다노판(indanofan/일반명, 이하 화합물 (14)라 기재한다.), 옥사지클로메폰(oxaziclomefone/일반명, 이하 화합물 (15)라 기재한다.), 카펜스트롤(cafenstrole/일반명, 이하 화합물 (16)이라 기재한다.), 피라졸리네이트(pyrazolynate/일반명, 이하 화합물 (17)이라 기재한다.), 벤조 페나프(benzofenap/일반명, 이하 화합물 (18)이라 기재한다.), MCPB(일반명, 이하 화합물 (19)라 기재한다.), 피리프탈리드(pyriftalid/일반명, 이하 화합물 (20)이라 기재한다.), 페녹스술람(penoxsulam/일반명, 이하 화합물 (21)이라 기재한다.), 디티오피르(dithiopyr/일반명, 이하 화합물 (22)라 기재한다.), 벤프레세이트(benfuresate/일반명, 이하 화합물 (23)이라 기재한다.), 피라조술푸론에틸(pyrazosulfuron-ethyl/일반명, 이하 화합물 (24)라 기재한다.), 할로술푸론메틸(halosulfuron-methyl/일반명, 이하 화합물 (25)라 기재한다.) 및 에스프로카르브(Esprocarb/일반명, 이하 화합물 (26)이라 기재한다.)는 벼용 제초제로서 이미 실용화 또는 시험되고 있으나, 일부의 잡초에 효과가 떨어지는 것이 있다.Dimuron (general name, hereinafter referred to as compound (1)), dimethametry (general name, hereinafter referred to as compound (2)), benzobicyclon (benzobicyclon / general name, The following is referred to as compound (3)), AVH-301 (test name, tefuryltrione, hereinafter referred to as compound (4)), mesotrione (mesotrione / general name, the following compound (5) ), Clomeprop (hereinafter referred to as compound (6)), bromobutide (hereinafter referred to as compound (7)), butachlor ( butachlor / generic name, hereinafter referred to as compound (8)), pretilachlor (pretilachlor / generic name, hereinafter referred to as compound (9)), pentoxazone / general name, hereinafter referred to as compound (10) ), Pyraclonil (hereinafter referred to as generic name, compound (11)), pentrazamide (hereinafter referred to as "pentazamide / generic name, compound (12)), Phenacet (mefenacet / general name, hereinafter referred to as compound (13)), indanophan (indanofan / general name, hereinafter referred to as compound (14)), oxaziclomefone / general name, hereinafter compound (15)), carpenstrol (cafenstrole / general name, hereinafter referred to as compound (16)), pyrazolynate (generic name, hereinafter referred to as compound (17)), benzo Phenaf (benzofenap / general name, hereinafter referred to as compound (18)), MCPB (generic name, hereinafter referred to as compound (19)), pyriftalid / general name, hereinafter compound (20) ), Phenoxsulam (penoxsulam / general name, hereinafter referred to as compound (21)), dithiopyr (general name, hereinafter referred to as compound (22)), benpresate ( benfuresate / general name, hereinafter referred to as compound (23)), pyrazosulfuron-ethyl / generic name, hereinafter referred to as compound (24)), halosulfu Methyl (halosulfuron-methyl / generic name, hereinafter referred to as compound (25)) and esprocarb (Esprocarb / generic name, hereinafter referred to as compound (26)) are already being used or tested as rice herbicides. Some of these weeds are less effective.
본 발명자들은 상기 과제를 고려하여 예의 검토한 결과, 화합물(A):MEANS TO SOLVE THE PROBLEM As a result of earnestly examining in view of the said subject, the compound (A):
[화학식 1][Formula 1]
및 화합물 (1), 화합물 (2), 화합물 (3), 화합물 (4), 화합물 (5), 화합물 (6), 화합물 (7), 화합물 (8), 화합물 (9), 화합물 (10), 화합물 (11), 화합물 (12), 화합물 (13), 화합물 (14), 화합물 (15), 화합물 (16), 화합물 (17), 화합물 (18), 화합물 (19), 화합물 (20), 화합물 (21), 화합물 (22), 화합물 (23), 화합물 (24), 화합물 (25) 및 화합물 (26), 중에서 선택되는 1종 이상을 동시에 사용하면, 이들 화합물을 단독으로 사용한 경우의 결점이 보충될 뿐만 아니라, 상승 효과를 나타내는 등에 의한 시용 약량의 저감을 도모할 수 있고, 광범위한 잡초를 동시에 방제할 수 있음을 발견하고, 본 발명을 완성하였다.And compound (1), compound (2), compound (3), compound (4), compound (5), compound (6), compound (7), compound (8), compound (9), compound (10) , Compound (11), compound (12), compound (13), compound (14), compound (15), compound (16), compound (17), compound (18), compound (19), compound (20) When at least one selected from compound (21), compound (22), compound (23), compound (24), compound (25) and compound (26) is used simultaneously, these compounds may be used alone. Not only were the defects compensated for, but it was found that the amount of the applied drug due to the synergistic effect and the like can be reduced, and a wide range of weeds can be controlled at the same time.
즉, 본 발명은 이하의 [1] 및 [2]에 관한 것이다.That is, the present invention relates to the following [1] and [2].
[1] 화합물 (A) 및 화합물 (1), 화합물 (2), 화합물 (3), 화합물 (4), 화합물 (5), 화합물 (6), 화합물 (7), 화합물 (8), 화합물 (9), 화합물 (10), 화합물 (11), 화합물 (12), 화합물 (13), 화합물 (14), 화합물 (15), 화합물 (16), 화합물 (17), 화합물 (18), 화합물 (19), 화합물 (20), 화합물 (21), 화합물 (22), 화합물 (23), 화합물 (24), 화합물 (25) 및 화합물 (26) 중에서 선택되는 1종 이상을 유효 성분으로 함유하는 제초 조성물(이하, 본 발명 조성물이라 기재한다.).[1] Compound (A) and Compound (1), Compound (2), Compound (3), Compound (4), Compound (5), Compound (6), Compound (7), Compound (8), Compound ( 9), Compound (10), Compound (11), Compound (12), Compound (13), Compound (14), Compound (15), Compound (16), Compound (17), Compound (18), Compound ( 19), a herbicidal containing at least one selected from compound (20), compound (21), compound (22), compound (23), compound (24), compound (25) and compound (26) as an active ingredient A composition (hereinafter, referred to as the composition of the present invention).
[2] 화합물 (A), 및 화합물 (1), 화합물 (2), 화합물 (3), 화합물 (4), 화합물 (5), 화합물 (6), 화합물 (7), 화합물 (8), 화합물 (9), 화합물 (10), 화합물 (11), 화합물 (12), 화합물 (13), 화합물 (14), 화합물 (15), 화합물 (16), 화합물 (17), 화합물 (18), 화합물 (19), 화합물 (20), 화합물 (21), 화합물 (22), 화합물 (23), 화합물 (24), 화합물 (25) 및 화합물 (26) 중에서 선택되는 1종 이상을 동시에 사용하는 제초방법(이하, 본 발명 방법이라 기재한다.).[2] Compound (A) and Compound (1), Compound (2), Compound (3), Compound (4), Compound (5), Compound (6), Compound (7), Compound (8), Compound (9), Compound (10), Compound (11), Compound (12), Compound (13), Compound (14), Compound (15), Compound (16), Compound (17), Compound (18), Compound A herbicidal method using at least one selected from (19), compound (20), compound (21), compound (22), compound (23), compound (24), compound (25) and compound (26) simultaneously. (Hereinafter, it will be described as the method of the present invention.)
본 발명 조성물 및 본 발명 방법은 보다 폭 넓은 스펙트럼을 가지고, 또한, 벼의 영향은 인식되지 않는다. The composition of the present invention and the method of the present invention have a broader spectrum and the influence of rice is not recognized.
화합물 (A)는, 하기 식으로 표시되는 화합물을 불순물로서 포함하는 경우가 있으나, 그 경우에도 본원 기재의 화합물 (A)의 정의에 포함된다.Although a compound (A) may contain the compound represented by a following formula as an impurity, it is included in the definition of the compound (A) of this application also in that case.
[화학식 2][Formula 2]
또, 여하한 결정다형, 광학 이성체, 이들의 혼합물도, 본원 기재의 화합물 (A)의 정의에 포함된다.In addition, any crystal polymorphs, optical isomers, and mixtures thereof are also included in the definition of the compound (A) described in the present application.
화합물 (A)와 동시에 사용될 수 있는 화합물로서는, 화합물 (1), 화합물 (2), 화합물 (3), 화합물 (4), 화합물 (5), 화합물 (6), 화합물 (7), 화합물 (8), 화합물 (9), 화합물 (10), 화합물 (11), 화합물 (12), 화합물 (13), 화합물 (14), 화합물 (15), 화합물 (16), 화합물 (17), 화합물 (18), 화합물 (19), 화합물 (20), 화합물 (21), 화합물 (22), 화합물 (23), 화합물 (24), 화합물 (25) 및 화합물 (26) 중에서 선택되는 1종 이상 이외에도, 식물 생장 조절제, 살충제, 살균제, 비 료 등을 들 수 있다. 또, 화합물 (A)와 화합물 (1), 화합물 (2), 화합물 (3), 화합물 (4), 화합물 (5), 화합물 (6), 화합물 (7), 화합물 (8), 화합물 (9), 화합물 (10), 화합물 (11), 화합물 (12), 화합물 (13), 화합물 (14), 화합물 (15), 화합물 (16), 화합물 (17), 화합물 (18), 화합물 (19), 화합물 (20), 화합물 (21), 화합물 (22), 화합물 (23), 화합물 (24), 화합물 (25) 및 화합물 (26) 중에서 선택되는 1종 이상을 동시에 사용하는 경우에, 추가로 식물 생장 조절제, 살충제, 살균제, 비료 등을 동시에 사용할 수도 있다. 사용에 있어서는, 각 화합물을 개별로 사용하여도, 혼합 조성물로서 사용하여도 좋다.Examples of the compound that can be used simultaneously with compound (A) include compound (1), compound (2), compound (3), compound (4), compound (5), compound (6), compound (7), and compound (8 ), Compound (9), Compound (10), Compound (11), Compound (12), Compound (13), Compound (14), Compound (15), Compound (16), Compound (17), Compound (18 ), Compound (19), Compound (20), Compound (21), Compound (22), Compound (23), Compound (24), Compound (25) and Compound (26) in addition to at least one selected from Growth regulators, insecticides, fungicides, fertilizers and the like. Further, compound (A), compound (1), compound (2), compound (3), compound (4), compound (5), compound (6), compound (7), compound (8), compound (9 ), Compound (10), Compound (11), Compound (12), Compound (13), Compound (14), Compound (15), Compound (16), Compound (17), Compound (18), Compound (19 ), When one or more selected from compound (20), compound (21), compound (22), compound (23), compound (24), compound (25) and compound (26) are used simultaneously, As a result, plant growth regulators, insecticides, fungicides, fertilizers and the like may be used simultaneously. In use, each compound may be used individually or may be used as a mixed composition.
화합물 (A)와 식물 생장 조절제, 살충제, 살균제, 비료 등을 동시에 사용함으로써, 또는, 화합물 (1), 화합물 (2), 화합물 (3), 화합물 (4), 화합물 (5), 화합물 (6), 화합물 (7), 화합물 (8), 화합물 (9), 화합물 (10), 화합물 (11), 화합물 (12), 화합물 (13), 화합물 (14), 화합물 (15), 화합물 (16), 화합물 (17), 화합물 (18), 화합물 (19), 화합물 (20), 화합물 (21), 화합물 (22), 화합물 (23), 화합물 (24), 화합물 (25) 및 화합물 (26) 중에서 선택되는 1종 이상을 동시에 사용함에 있어서, 추가로 식물 생장 조절제, 살충제, 살균제, 비료 등을 동시에 사용함으로써, 살초 스펙트럼의 확대, 시용 약량의 저감, 제초효과의 지속, 병충해 방제 등이 기대된다.Compound (A) and plant growth regulators, insecticides, fungicides, fertilizers, etc. are used simultaneously, or compound (1), compound (2), compound (3), compound (4), compound (5), compound (6) ), Compound (7), Compound (8), Compound (9), Compound (10), Compound (11), Compound (12), Compound (13), Compound (14), Compound (15), Compound (16 ), Compound (17), Compound (18), Compound (19), Compound (20), Compound (21), Compound (22), Compound (23), Compound (24), Compound (25), and Compound (26 In simultaneously using at least one selected from), by using simultaneously plant growth regulators, insecticides, fungicides, fertilizers, etc., it is expected to increase the herbicidal spectrum, to reduce the amount of application, to continue herbicide effect, to control pests, etc. do.
본 발명에 관한 화합물 (A)와, 화합물 (1), 화합물 (2), 화합물 (3), 화합물 (4), 화합물 (5), 화합물 (6), 화합물 (7), 화합물 (8), 화합물 (9), 화합물 (10), 화합물 (11), 화합물 (12), 화합물 (13), 화합물 (14), 화합물 (15), 화합물 (16), 화합물 (17), 화합물 (18), 화합물 (19), 화합물 (20), 화합물 (21), 화합물 (22), 화합물 (23), 화합물 (24), 화합물 (25) 및 화합물 (26) 중에서 선택되는 1종 이상과의 사용 비율은 각각의 화합물의 성능을 실질적으로 훼손하지 않는 범위에서 적절하게 선택할 수 있다. Compound (A) according to the present invention, Compound (1), Compound (2), Compound (3), Compound (4), Compound (5), Compound (6), Compound (7), Compound (8), Compound (9), compound (10), compound (11), compound (12), compound (13), compound (14), compound (15), compound (16), compound (17), compound (18), The use ratio with one or more selected from compound (19), compound (20), compound (21), compound (22), compound (23), compound (24), compound (25) and compound (26) is It can select suitably in the range which does not substantially impair the performance of each compound.
본 발명에 있어서, 바람직한 제초 효과를 나타내는 것은, 화합물 (A) 1중량부당, 화합물 (1), 화합물 (2), 화합물 (3), 화합물 (4), 화합물 (5), 화합물 (6), 화합물 (7), 화합물 (8), 화합물 (9), 화합물 (10), 화합물 (11), 화합물 (12), 화합물 (13), 화합물 (14), 화합물 (15), 화합물 (16), 화합물 (17), 화합물 (18), 화합물 (19), 화합물 (20), 화합물 (21), 화합물 (22), 화합물 (23), 화합물 (24), 화합물 (25) 및 화합물 (26) 중에서 선택되는 1종 이상의 화합물을 0.002~1000중량부인 경우이고, 0.05~40중량부의 경우는 더욱 바람직한 효과가 기재된다.In the present invention, the preferred herbicidal effect is compound (1), compound (2), compound (3), compound (4), compound (5), compound (6), per 1 part by weight of compound (A), Compound (7), compound (8), compound (9), compound (10), compound (11), compound (12), compound (13), compound (14), compound (15), compound (16), Among compounds (17), compound (18), compound (19), compound (20), compound (21), compound (22), compound (23), compound (24), compound (25) and compound (26). It is a case where it is 0.002-1000 weight part of 1 or more types of compounds chosen, and a more preferable effect is described in the case of 0.05-40 weight part.
본 발명에 관한 화합물의 바람직한 처리량은 방제하고자 하는 대상 잡초의 종류 등에 따라 좌우되지만, 화합물 (A)가 5g~500g/hA이고, 화합물 (1), 화합물 (2), 화합물 (3), 화합물 (4), 화합물 (5), 화합물 (6), 화합물 (7), 화합물 (8), 화합물 (9), 화합물 (10), 화합물 (11), 화합물 (12), 화합물 (13), 화합물 (14), 화합물 (15), 화합물 (16), 화합물 (17), 화합물 (18), 화합물 (19), 화합물 (20), 화합물 (21), 화합물 (22), 화합물 (23), 화합물 (24), 화합물 (25) 및 화합물 (26) 중에서 선택되는 1종 이상의 화합물이 1g~5kg/hA인 경우가 바람직하고, 화합물 (A)가 10g~200g/hA이고, 화합물 (1), 화합물 (2), 화합물 (3), 화합물 (4), 화합물 (5), 화합물 (6), 화합물 (7), 화합물 (8), 화합물 (9), 화합물 (10), 화합물 (11), 화합물 (12), 화합물 (13), 화합물 (14), 화합물 (15), 화합물 (16), 화합물 (17), 화합물 (18), 화합물 (19), 화합물 (20), 화합물 (21), 화합물 (22), 화합물 (23), 화합물 (24), 화합물 (25) 및 화합물 (26) 중에서 선택되는 1종 이상의 화합물이 10g~4kg/hA인 경우는 더욱 바람직한 효과가 기대된다.Although the preferable throughput of the compound which concerns on this invention depends on the kind of weed to be controlled, etc., Compound (A) is 5g-500g / hA, Compound (1), Compound (2), Compound (3), Compound ( 4), Compound (5), Compound (6), Compound (7), Compound (8), Compound (9), Compound (10), Compound (11), Compound (12), Compound (13), Compound ( 14), Compound (15), Compound (16), Compound (17), Compound (18), Compound (19), Compound (20), Compound (21), Compound (22), Compound (23), Compound ( It is preferable that at least one compound selected from 24), compound (25) and compound (26) is 1 g to 5 kg / hA, and compound (A) is 10 g to 200 g / hA, and compound (1) and compound ( 2), Compound (3), Compound (4), Compound (5), Compound (6), Compound (7), Compound (8), Compound (9), Compound (10), Compound (11), Compound ( 12), compound (13), compound (14), compound (15), compound (16), compound (17), compound (18), compound ( 19 g, 10 g-4 kg / hA of at least one compound selected from compound (20), compound (21), compound (22), compound (23), compound (24), compound (25) and compound (26). In the case of, more preferable effects are expected.
본 발명에서는, 화합물 (A), 및 화합물 (1), 화합물 (2), 화합물 (3), 화합물 (4), 화합물 (5), 화합물 (6), 화합물 (7), 화합물 (8), 화합물 (9), 화합물 (10), 화합물 (11), 화합물 (12), 화합물 (13), 화합물 (14), 화합물 (15), 화합물 (16), 화합물 (17), 화합물 (18), 화합물 (19), 화합물 (20), 화합물 (21), 화합물 (22), 화합물 (23), 화합물 (24), 화합물 (25) 및 화합물 (26) 중에서 선택되는 1종 이상은 각각 개별로 시용할 수도, 혼합 조성물로서 시용할 수도 있다. 각각 개별로 시용하는 경우는, 완전히 동시에 시용하여도, 시간적으로 근접하여 있다면 별도로 처리하여도 좋으며, 어느 경우에도 본 발명 방법에 포함된다.In the present invention, compound (A), compound (1), compound (2), compound (3), compound (4), compound (5), compound (6), compound (7), compound (8), Compound (9), compound (10), compound (11), compound (12), compound (13), compound (14), compound (15), compound (16), compound (17), compound (18), At least one selected from compound (19), compound (20), compound (21), compound (22), compound (23), compound (24), compound (25) and compound (26) is applied individually. It may also be applied as a mixed composition. In the case of applying each of them individually, they may be applied simultaneously or may be treated separately as long as they are close in time, and in any case, they are included in the method of the present invention.
본 발명의 화합물을 시용하는 경우에는, 통상 적당한 고체 담체 또는 액체 담체와 혼합하고, 나아가 필요에 따라 계면활성제, 침투제, 전착제, 동결방지제, 결합제, 고결방지제, 붕괴제 및 분해방지제 등을 첨가하여, 액제, 유제, 수화제, 수용제, 과립 수화제, 과립 수용제, 현탁제, 유탁제, 서스포에멀젼, 마이크로에멀젼, 분제, 입제 및 겔제 등 임의의 제형의 제제로서 시용에 제공할 수 있다.When the compound of the present invention is applied, it is usually mixed with a suitable solid carrier or liquid carrier, and further, if necessary, a surfactant, a penetrant, an electrodeposition agent, an antifreeze agent, a binder, an anticaking agent, a disintegrating agent, an antidegradant, and the like are added. It may be provided for application as a formulation of any formulation such as liquids, emulsions, hydrates, water solubles, granule hydrates, granule solubles, suspensions, emulsions, suspo emulsions, microemulsions, powders, granules and gels.
또, 성력화 및 안정성 향상의 관점에서, 상기 임의의 제형의 제제를 수용성 포장체에 주입하여 제공할 수도 있다.In addition, from the standpoint of enhancing the potency and improving stability, the formulation of any of the above-mentioned formulations may be injected into a water-soluble package and provided.
고체 담체로서는, 예를 들어, 석영, 카올리나이트, 파이로필라이트, 셀리사 이트, 탈크, 벤토나이트, 산성백토, 아타풀자이트, 제올라이트 및 규조토 등의 전연 광물질류, 탄산칼슘, 황산암모늄, 황산나트륨 및 염화칼륨 등의 무기염류, 합성 규산 및 합성 규산염을 들 수 있다.As the solid carrier, for example, all minerals such as quartz, kaolinite, pyrophyllite, selite, talc, bentonite, acidic clay, attapulgite, zeolite and diatomaceous earth, calcium carbonate, ammonium sulfate, sodium sulfate and potassium chloride Inorganic salts, synthetic silicic acid, and synthetic silicates, such as these, are mentioned.
액체 담체로서는, 예를 들어, 에틸렌글리콜, 프로필렌글리콜 및 이소프로판올 등의 알코올류, 크실렌, 알킬벤젠 및 알킬나프탈렌 등의 방향족 탄화수소류, 부틸셀로솔부 등의 에테르류, 시클로헥사논 등의 케톤류, γ-부티로락톤 등의 에스테르류, N-메틸피롤리돈, N-옥틸피롤리돈 등의 산아미드류, 대두유, 채종유, 면실유 및 피마자유 등의 식물유 및 물을 들 수 있다.Examples of the liquid carrier include alcohols such as ethylene glycol, propylene glycol and isopropanol, aromatic hydrocarbons such as xylene, alkylbenzene and alkylnaphthalene, ethers such as butyl cellosol moiety, ketones such as cyclohexanone, and Esters such as butyrolactone, acid amides such as N-methylpyrrolidone and N-octylpyrrolidone, vegetable oils such as soybean oil, rapeseed oil, cottonseed oil and castor oil, and water.
이들 고체 및 액체 담체는 단독으로 사용하여도, 2종 이상을 병용하여도 좋다.These solid and liquid carriers may be used independently or may use 2 or more types together.
계면활성제로서는, 예를 들어, 폴리옥시에틸렌알킬에테르, 폴리옥시에틸렌알킬아릴에테르, 폴리옥시에틸렌스티릴페닐에테르, 폴리옥시에틸렌폴리옥시프로필렌블록코폴리머, 폴리옥시에틸렌지방산에스테르, 소르비탄 지방산 에스테르 및 폴리옥시에틸렌소르비탄 지방산에스테르 등의 논이온성 계면활성제, 알킬황산염, 알킬벤젠술폰산염, 리그닌술폰산염, 알킬술포호박산염, 나프탈렌술폰산염, 알킬나프탈렌술폰산염, 나프탈렌술폰산의 포르말린 축합물의 염, 알킬나프탈렌술폰산의 포르말린 축합물의 염, 폴리옥시에틸렌알킬아릴에테르 황산 및 인산염, 폴리옥시에틸렌스티릴페닐에테르 황산 및 인산염, 폴리카르본산염 및 폴리스티렌술폰산염 등의 안이온성 계면활성제, 알킬아민염 및 알킬4급암모늄염 등의 카티온성 계면활성제 및 아미노산형 및 베타인형 등의 양성 계면활성제를 들 수 있다.As surfactant, For example, polyoxyethylene alkyl ether, polyoxyethylene alkyl aryl ether, polyoxyethylene styryl phenyl ether, polyoxyethylene polyoxypropylene block copolymer, polyoxyethylene fatty acid ester, sorbitan fatty acid ester, and Nonionic surfactants such as polyoxyethylene sorbitan fatty acid esters, alkyl sulfates, alkylbenzenesulfonates, lignin sulfonates, alkylsulfovacates, naphthalenesulfonates, alkylnaphthalenesulfonates, salts of formalin condensates of naphthalenesulfonic acids, alkyls Salts of formalin condensates of naphthalenesulfonic acid, polyoxyethylene alkylarylether sulfates and phosphates, anionic surfactants such as polyoxyethylene styrylphenylether sulfates and phosphates, polycarbonates and polystyrenesulfonates, alkylamine salts and alkyl4 Cationic surfactants and amino acids such as quaternary ammonium salts Amphoteric surfactants, such as a mold | type and a betaine type | mold, are mentioned.
이들 계면활성제의 함유량은 특별히 한정되는 것은 아니지만, 본 발명의 제제 100중량부에 대하여, 통상 0.05~20중량부의 범위가 바람직하다. 또, 이들 계면활성제는 단독으로도, 2종 이상을 병용하여도 좋다.Although content of these surfactant is not specifically limited, Usually, the range of 0.05-20 weight part is preferable with respect to 100 weight part of formulations of this invention. Moreover, these surfactant may be independent or may use 2 or more types together.
다음에 제제의 배합예를 나타낸다. 단 본 발명의 배합예는 이들만으로 한정되는 것은 아니다. 또, 이하의 배합예에서 「부」는 중량부를 의미한다.Next, the formulation example of a formulation is shown. However, the compounding example of this invention is not limited only to these. In addition, "part" means a weight part in the following mixing examples.
[수화제][Hydrating]
유효성분 0.1-80부0.1-80 parts of active ingredient
고체담체 5-98.9부Solid Carriers 5-98.9
계면활성제 1-10부1-10 parts surfactant
기타 0-5부Other 0-5
기타로서는, 예를 들어, 고결방지제, 분해방지제 등을 들 수 있다.As others, an anti-caking agent, an antidegradation agent, etc. are mentioned, for example.
[유제][emulsion]
유효성분 0.1-30부0.1-30 parts of active ingredient
액체담체 55-95부Liquid carrier 55-95 parts
계면활성제 4.9-15부Surfactants 4.9-15 parts
기타 0-10부Others 0-10
기타로서는, 예를 들어, 전착제, 분해방지제 등을 들 수 있다.As others, an electrodeposition agent, an antidegradation agent, etc. are mentioned, for example.
[현탁제][Suspension]
유효성분 0.1-70부0.1-70 parts of active ingredient
액체담체 15-98.89부Liquid carrier 15-98.89
계면활성제 1-12부Surfactants 1-12 parts
기타 0.01-30부Other 0.01-30 part
기타로서는, 예를 들어, 동결방지제, 증점제 등을 들 수 있다.As another, a cryoprotectant, a thickener, etc. are mentioned, for example.
[과립수화제][Granulating Hydrating Agent]
유효성분 0.1-90부0.1-90 parts of active ingredient
고체담체 0-98.9부Solid Carrier 0-98.9
계면활성제 1-20부1-20 parts surfactant
기타 0-10부Others 0-10
기타로서는, 예를 들어, 결합제, 분해방지제 등을 들 수 있다.As others, a binder, an antidegradation agent, etc. are mentioned, for example.
[입제][Participation]
유효성분 0.01-30부0.01-30 parts of active ingredient
고체담체 70-99.9부Solid Carrier 70-99.9
기타 0-10부Others 0-10
기타로서는, 예를 들어, 결합제, 분해방지제 등을 들 수 있다.As others, a binder, an antidegradation agent, etc. are mentioned, for example.
사용하는 경우는 상기 제제를 그대로, 또는 물로 1 내지 1000배로 희석하여 산포한다.When used, the preparation is dispersed as it is, or diluted 1 to 1000 times with water.
이하, 본 발명을 구체적으로 설명하지만, 본 발명에 관한 화합물, 제제량, 제형 등은 이하에 한정되는 것은 아니다.Hereinafter, although this invention is demonstrated concretely, the compound, formulation amount, a dosage form, etc. which concern on this invention are not limited to the following.
또, 「부」는 모두 중량부를 의미한다.In addition, all "parts" mean a weight part.
[배합예 1] Formulation Example 1
화합물 (A) 1부1 part of compound (A)
화합물 (1) 20부20 parts of compound (1)
화합물 (3) 2부2 parts of compound (3)
벤토나이트 50부Bentonite Part 50
탈크 27부Talc 27
이상을 균일하게 혼합 분쇄한 후, 소량의 물을 첨가하여 교반 혼합 날화(捏和)하고, 압출식 조립기로 조립하고, 건조하여 입제로 한다.After mixing and grinding the above uniformly, a small amount of water is added, stirring and mixing and kneading, it is granulated by an extrusion granulator, it is made to dry and granulate.
[배합예 2] 과립 수화제(드라이 플로어블제)[Combination Example 2] Granule Hydration (Dry Floorable)
화합물 (A) 20부20 parts of compound (A)
화합물 (3) 40부40 parts of compound (3)
화합물 (25) 10부10 parts of compound (25)
하이데놀 NE-15 5부Hydenol NE-15 Part 5
(아니온성 계면활성제: 다이이찌공업제약㈜ 상품명)(Anionic surfactant: Daiichi Pharmaceutical Co., Ltd.)
바니렉스 N 20부Bany Rex N Part 20
(아니온성 계면활성제: 니폰제지㈜ 상품명)(Anionic surfactant: Nippon Paper Co., Ltd. product name)
카프렉스 #80D 5부Caprex # 80D Part 5
(합성 함수 규산: 시오노기제약㈜ 상품명)(Synthetic hydrous silicic acid: Shionogi Pharmaceutical Co., Ltd.)
이상을 균일하게 혼합 분쇄한 후, 소량의 물을 첨가하여 교반 혼합 날화하고, 압출식 조립기로 조립하고, 건조하여 입제로 한다.After uniformly mixing and grinding the above, a small amount of water is added to stir mixed and kneaded, granulated with an extruded granulator, dried to obtain granules.
[배합예 3] 수화제Formulation Example 3 Hydration
화합물 (A) 1부1 part of compound (A)
화합물 (1) 20부20 parts of compound (1)
화합물 (3) 2부2 parts of compound (3)
소르폴 5039 2부Sorpol 5039, part two
(비이온성 계면활성제와 아니온성 계면활성제의 혼합물:토호화학공업㈜ 상품명(A mixture of nonionic surfactant and anionic surfactant: Toho Chemical Co., Ltd.
카프렉스 #80 2부Caprex # 80 Part 2
(합성 함수 규산: 시오노기제약㈜ 상품명)(Synthetic hydrous silicic acid: Shionogi Pharmaceutical Co., Ltd.)
파이로필라이트 73부Pyrophyllite Part 73
이상을 균일하게 혼합분쇄하여 수화제로 한다.The above is mixed and pulverized uniformly to obtain a hydrate.
[배합예 4] 현탁제(플로어블제)Formulation Example 4 Suspending Agent (Floable)
화합물 (A) 1부1 part of compound (A)
화합물 (1) 20부20 parts of compound (1)
화합물 (3) 2부2 parts of compound (3)
아그리졸 S-710 10부Agrisol S-710 part 10
(비이온성 계면활성제: 카오㈜ 상품명)(Nonionic Surfactant: Kao Corporation)
루녹스 1000C 0.5부Lunox 1000C0.5part
아니온성 계면활성제: 토호화학공업㈜ 상품명)Anionic surfactant: Toho Chemical Co., Ltd.
키산탄감 0.2부0.2 parts of chishan bullet
물 66.3부66.3 parts of water
이상을 균일하게 혼합한 후, 혼식분쇄하여 현탁제로 한다.After mixing the above uniformly, it mix-mills and makes it a suspension agent.
[실시예] EXAMPLE
본 발명의 유용성을 이하의 실험예에 의하여 구체적으로 설명한다.The usefulness of this invention is demonstrated concretely by the following experimental example.
[실험예 1] 담수 조건에 의한 잡초 생육기 처리에 의한 제초효과 시험Experimental Example 1 Herbicide Effect Test by Weed Growth Stage Treatment by Fresh Water Condition
1/10000아르의 플라스틱제 포트에 충적토양을 넣은 후, 물을 넣어 혼화하여, 4cm의 담수 조건으로 하였다. 그 포트에 피(稗, 노비에), 올챙이고랭이(Scirpus juncoides vAr. ohwiAnus, 이누호타루이), 물달개비(MonochoriA vAginAlis, 코나기)의 종자를 혼파한 후, 2.5엽기의 벼모를 이식하고, 25 내지 30?의 온실 내에 두어 식물을 육성하였다. 피, 이누호타루이 및 코나기가 1 내지 2엽기에 도달할 때, 배합예에 준하여 조제한 수화제를 소정 약량으로 되도록 물에 희석하고, 수면에 처리하였다. 약제 처리 3주간 후에, 각 식물에 대한 제초효과를 하기의 판정기준에 따라 조사하였다.An alluvial soil was put in a 1/10000 plastic pot, and water was mixed, and it was made into fresh water of 4 cm. Blood (a稗, Novi) to the port, the ladle goraeng (Scirpus juncoides vAr. ohwiAnus , Inuhotaru), Pinnacle ( MonochoriA) vAginAlis (Konagi) seeds were mixed, and 2.5 leaves of rice seedlings were transplanted and placed in a greenhouse of 25 to 30? to grow plants. When blood, Inuhotaru and Conagi reached the 1 to 2 leaf stage, the hydrous prepared according to the blending example was diluted in water so as to be a predetermined dose, and treated with water. After 3 weeks of drug treatment, the herbicidal effect on each plant was examined according to the following criteria.
판정기준Criteria
5 - 살초율 90% 이상5-90% higher kill rate
4 - 살초율 70% 이상 90% 미만4-70% or more kill rate less than 90%
3 - 살초율 40% 이상 70% 미만3-40% or more kill rate less than 70%
2 - 살초율 20% 이상 40% 미만2-20% or more kill rate less than 40%
1 - 살초율 5% 이상 20% 미만1-5% or more, less than 20%
0 - 살초율 5% 이하 (거의 효력 없음)0-less than 5% kill rate (almost no effect)
결과를 제 1표에 나타낸다.The results are shown in the first table.
[제 1표][Table 1]
――――――――――――――――――――――――――――――――――-―――――――――――――――――――――――――――――――――――
화합물 No. 약량(g/hA) 피 올챙이고랭이 코나기 벼Compound no. Amount (g / hA) blood tadpole Konagi rice
―――――――――――――――――――――――――――――――――-――――――――――――――――――――――――――――――――――――
(A)+(1)+(2) 50+1000+60 5 5 5 0(A) + (1) + (2) 50 + 1000 + 60 5 5 5 0
(A)+(1)+(3) 50+1000+100 5 5 5 0(A) + (1) + (3) 50 + 1000 + 100 5 5 5 0
(A)+(2)+(3) 50+60+100 5 5 5 0(A) + (2) + (3) 50 + 60 + 100 5 5 5 0
(A)+(1)+(2)+(3) 50+1000+60+100 5 5 5 0(A) + (1) + (2) + (3) 50 + 1000 + 60 + 100 5 5 5 0
(A)+(3)+(8) 50+100+750 5 5 5 0(A) + (3) + (8) 50 + 100 + 750 5 5 5 0
(A)+(1)+(3)+(8) 50+1000+100+750 5 5 5 0(A) + (1) + (3) + (8) 50 + 1000 + 100 + 750 5 5 5 0
(A)+(3)+(9) 50+100+300 5 5 5 0(A) + (3) + (9) 50 + 100 + 300 5 5 5 0
(A)+(1)+(3)+(9) 50+1000+100+300 5 5 5 0(A) + (1) + (3) + (9) 50 + 1000 + 100 + 300 5 5 5 0
(A)+(3)+(10) 50+100+200 5 5 5 0(A) + (3) + (10) 50 + 100 + 200 5 5 5 0
(A)+(1)+(3)+(10) 50+1000+100+200 5 5 5 0(A) + (1) + (3) + (10) 50 + 1000 + 100 + 200 5 5 5 0
(A)+(3)+(11) 50+100+100 5 5 5 0(A) + (3) + (11) 50 + 100 + 100 5 5 5 0
(A)+(1)+(3)+(11) 50+1000+100+100 5 5 5 0(A) + (1) + (3) + (11) 50 + 1000 + 100 + 100 5 5 5 0
(A)+(3)+(12) 50+100+200 5 5 5 0(A) + (3) + (12) 50 + 100 + 200 5 5 5 0
(A)+(1)+(3)+(12) 50+1000+100+200 5 5 5 0(A) + (1) + (3) + (12) 50 + 1000 + 100 + 200 5 5 5 0
(A)+(3)+(13) 50+100+500 5 5 5 0(A) + (3) + (13) 50 + 100 + 500 5 5 5 0
(A)+(1)+(3)+(13) 50+1000+100+500 5 5 5 0(A) + (1) + (3) + (13) 50 + 1000 + 100 + 500 5 5 5 0
(A)+(3)+(14) 50+100+100 5 5 5 0(A) + (3) + (14) 50 + 100 + 100 5 5 5 0
(A)+(1)+(3)+(14) 50+1000+100+100 5 5 5 0(A) + (1) + (3) + (14) 50 + 1000 + 100 + 100 5 5 5 0
(A)+(3)+(15) 50+100+50 5 5 5 0(A) + (3) + (15) 50 + 100 + 50 5 5 5 0
(A)+(1)+(3)+(15) 50+1000+100+50 5 5 5 0(A) + (1) + (3) + (15) 50 + 1000 + 100 + 50 5 5 5 0
(A)+(3)+(16) 50+100+200 5 5 5 0(A) + (3) + (16) 50 + 100 + 200 5 5 5 0
(A)+(1)+(3)+(16) 50+1000+100+200 5 5 5 0(A) + (1) + (3) + (16) 50 + 1000 + 100 + 200 5 5 5 0
(A)+(17) 50+2000 5 5 5 0(A) + (17) 50 + 2000 5 5 5 0
(A)+(3)+(17) 50+100+2000 5 5 5 0(A) + (3) + (17) 50 + 100 + 2000 5 5 5 0
(A)+(1)+(3)+(17) 50+1000+100+2000 5 5 5 0(A) + (1) + (3) + (17) 50 + 1000 + 100 + 2000 5 5 5 0
(A)+(18) 50+800 5 5 5 0(A) + (18) 50 + 800 5 5 5 0
(A)+(3)+(18) 50+100+800 5 5 5 0(A) + (3) + (18) 50 + 100 + 800 5 5 5 0
(A)+(1)+(3)+(18) 50+1000+100+800 5 5 5 0(A) + (1) + (3) + (18) 50 + 1000 + 100 + 800 5 5 5 0
(A)+(3)+(19) 50+100+200 5 5 5 0(A) + (3) + (19) 50 + 100 + 200 5 5 5 0
(A)+(1)+(3)+(19) 50+1000+100+200 5 5 5 0(A) + (1) + (3) + (19) 50 + 1000 + 100 + 200 5 5 5 0
(A)+(20) 50+150 5 5 5 0(A) + (20) 50 + 150 5 5 5 0
(A)+(3)+(20) 50+100+150 5 5 5 0(A) + (3) + (20) 50 + 100 + 150 5 5 5 0
(A)+(1)+(3)+(20) 50+1000+100+150 5 5 5 0(A) + (1) + (3) + (20) 50 + 1000 + 100 + 150 5 5 5 0
(A)+(21) 50+30 5 5 5 0(A) + (21) 50 + 30 5 5 5 0
(A)+(3)+(21) 50+100+30 5 5 5 0(A) + (3) + (21) 50 + 100 + 30 5 5 5 0
(A)+(1)+(3)+(21) 50+1000+100+30 5 5 5 0(A) + (1) + (3) + (21) 50 + 1000 + 100 + 30 5 5 5 0
(A)+(3)+(22) 50+100+60 5 5 5 0(A) + (3) + (22) 50 + 100 + 60 5 5 5 0
(A)+(1)+(3)+(22) 50+1000+100+60 5 5 5 0(A) + (1) + (3) + (22) 50 + 1000 + 100 + 60 5 5 5 0
(A)+(23) 50+300 5 5 5 0(A) + (23) 50 + 300 5 5 5 0
(A)+(3)+(23) 50+100+300 5 5 5 0(A) + (3) + (23) 50 + 100 + 300 5 5 5 0
(A)+(1)+(3)+(23) 50+1000+100+300 5 5 5 0(A) + (1) + (3) + (23) 50 + 1000 + 100 + 300 5 5 5 0
(A)+(3)+(24) 50+100+30 5 5 5 0(A) + (3) + (24) 50 + 100 + 30 5 5 5 0
(A)+(1)+(3)+(24) 50+1000+100+30 5 5 5 0(A) + (1) + (3) + (24) 50 + 1000 + 100 + 30 5 5 5 0
(A)+(3)+(25) 50+100+60 5 5 5 0(A) + (3) + (25) 50 + 100 + 60 5 5 5 0
(A)+(1)+(3)+(25) 50+1000+100+60 5 5 5 0(A) + (1) + (3) + (25) 50 + 1000 + 100 + 60 5 5 5 0
(A)+(3)+(6) 50+100+200 5 5 5 0(A) + (3) + (6) 50 + 100 + 200 5 5 5 0
(A)+(1)+(3)+(6) 50+1000+100+200 5 5 5 0(A) + (1) + (3) + (6) 50 + 1000 + 100 + 200 5 5 5 0
(A)+(3)+(26) 50+100+1500 5 5 5 0(A) + (3) + (26) 50 + 100 + 1500 5 5 5 0
(A)+(1)+(3)+(26) 50+1000+100+1500 5 5 5 0(A) + (1) + (3) + (26) 50 + 1000 + 100 + 1500 5 5 5 0
(A)+(1)+(7) 50+1000+600 5 5 5 0(A) + (1) + (7) 50 + 1000 + 600 5 5 5 0
(A)+(2)+(7) 50+60+600 5 5 5 0(A) + (2) + (7) 50 + 60 + 600 5 5 5 0
(A)+(1)+(2)+(7) 50+1000+60+600 5 5 5 0(A) + (1) + (2) + (7) 50 + 1000 + 60 + 600 5 5 5 0
(A)+(7)+(8) 50+600+750 5 5 5 0(A) + (7) + (8) 50 + 600 + 750 5 5 5 0
(A)+(1)+(7)+(8) 50+1000+600+750 5 5 5 0(A) + (1) + (7) + (8) 50 + 1000 + 600 + 750 5 5 5 0
(A)+(7)+(9) 50+600+300 5 5 5 0(A) + (7) + (9) 50 + 600 + 300 5 5 5 0
(A)+(1)+(7)+(9) 50+1000+600+300 5 5 5 0(A) + (1) + (7) + (9) 50 + 1000 + 600 + 300 5 5 5 0
(A)+(7)+(10) 50+600+200 5 5 5 0(A) + (7) + (10) 50 + 600 + 200 5 5 5 0
(A)+(1)+(7)+(10) 50+1000+600+200 5 5 5 0(A) + (1) + (7) + (10) 50 + 1000 + 600 + 200 5 5 5 0
(A)+(7)+(11) 50+600+100 5 5 5 0(A) + (7) + (11) 50 + 600 + 100 5 5 5 0
(A)+(1)+(7)+(11) 50+1000+600+100 5 5 5 0(A) + (1) + (7) + (11) 50 + 1000 + 600 + 100 5 5 5 0
(A)+(7)+(12) 50+600+200 5 5 5 0(A) + (7) + (12) 50 + 600 + 200 5 5 5 0
(A)+(1)+(7)+(12) 50+1000+600+200 5 5 5 0(A) + (1) + (7) + (12) 50 + 1000 + 600 + 200 5 5 5 0
(A)+(7)+(13) 50+600+500 5 5 5 0(A) + (7) + (13) 50 + 600 + 500 5 5 5 0
(A)+(1)+(7)+(13) 50+1000+600+500 5 5 5 0(A) + (1) + (7) + (13) 50 + 1000 + 600 + 500 5 5 5 0
(A)+(7)+(14) 50+600+100 5 5 5 0(A) + (7) + (14) 50 + 600 + 100 5 5 5 0
(A)+(1)+(7)+(14) 50+1000+600+100 5 5 5 0(A) + (1) + (7) + (14) 50 + 1000 + 600 + 100 5 5 5 0
(A)+(7)+(15) 50+600+50 5 5 5 0(A) + (7) + (15) 50 + 600 + 50 5 5 5 0
(A)+(1)+(7)+(15) 50+1000+600+50 5 5 5 0(A) + (1) + (7) + (15) 50 + 1000 + 600 + 50 5 5 5 0
(A)+(7)+(16) 50+600+200 5 5 5 0(A) + (7) + (16) 50 + 600 + 200 5 5 5 0
(A)+(1)+(7)+(16) 50+1000+600+200 5 5 5 0(A) + (1) + (7) + (16) 50 + 1000 + 600 + 200 5 5 5 0
(A)+(7)+(17) 50+600+2000 5 5 5 0(A) + (7) + (17) 50 + 600 + 2000 5 5 5 0
(A)+(1)+(7)+(17) 50+1000+600+2000 5 5 5 0(A) + (1) + (7) + (17) 50 + 1000 + 600 + 2000 5 5 5 0
(A)+(7)+(18) 50+600+800 5 5 5 0(A) + (7) + (18) 50 + 600 + 800 5 5 5 0
(A)+(1)+(7)+(18) 50+1000+600+800 5 5 5 0(A) + (1) + (7) + (18) 50 + 1000 + 600 + 800 5 5 5 0
(A)+(7)+(19) 50+600+200 5 5 5 0(A) + (7) + (19) 50 + 600 + 200 5 5 5 0
(A)+(1)+(7)+(19) 50+1000+600+200 5 5 5 0(A) + (1) + (7) + (19) 50 + 1000 + 600 + 200 5 5 5 0
(A)+(7)+(20) 50+600+150 5 5 5 0(A) + (7) + (20) 50 + 600 + 150 5 5 5 0
(A)+(1)+(7)+(20) 50+1000+600+150 5 5 5 0(A) + (1) + (7) + (20) 50 + 1000 + 600 + 150 5 5 5 0
(A)+(7)+(21) 50+600+30 5 5 5 0(A) + (7) + (21) 50 + 600 + 30 5 5 5 0
(A)+(1)+(7)+(21) 50+1000+600+30 5 5 5 0(A) + (1) + (7) + (21) 50 + 1000 + 600 + 30 5 5 5 0
(A)+(7)+(22) 50+600+60 5 5 5 0(A) + (7) + (22) 50 + 600 + 60 5 5 5 0
(A)+(1)+(7)+(22) 50+1000+600+60 5 5 5 0(A) + (1) + (7) + (22) 50 + 1000 + 600 + 60 5 5 5 0
(A)+(7)+(23) 50+600+300 5 5 5 0(A) + (7) + (23) 50 + 600 + 300 5 5 5 0
(A)+(1)+(7)+(23) 50+1000+600+300 5 5 5 0(A) + (1) + (7) + (23) 50 + 1000 + 600 + 300 5 5 5 0
(A)+(7)+(24) 50+600+30 5 5 5 0(A) + (7) + (24) 50 + 600 + 30 5 5 5 0
(A)+(1)+(7)+(24) 50+1000+600+30 5 5 5 0(A) + (1) + (7) + (24) 50 + 1000 + 600 + 30 5 5 5 0
(A)+(7)+(25) 50+600+60 5 5 5 0(A) + (7) + (25) 50 + 600 + 60 5 5 5 0
(A)+(1)+(7)+(25) 50+1000+600+60 5 5 5 0(A) + (1) + (7) + (25) 50 + 1000 + 600 + 60 5 5 5 0
(A)+(7)+(6) 50+600+200 5 5 5 0(A) + (7) + (6) 50 + 600 + 200 5 5 5 0
(A)+(1)+(7)+(6) 50+1000+600+200 5 5 5 0(A) + (1) + (7) + (6) 50 + 1000 + 600 + 200 5 5 5 0
(A)+(7)+(26) 50+600+1500 5 5 5 0(A) + (7) + (26) 50 + 600 + 1500 5 5 5 0
(A)+(1)+(7)+(26) 50+1000+600+1500 5 5 5 0(A) + (1) + (7) + (26) 50 + 1000 + 600 + 1500 5 5 5 0
(A)+(1)+(5) 50+1000+50 5 5 5 0(A) + (1) + (5) 50 + 1000 + 50 5 5 5 0
(A)+(2)+(5) 50+60+50 5 5 5 0(A) + (2) + (5) 50 + 60 + 50 5 5 5 0
(A)+(1)+(2)+(5) 50+1000+60+50 5 5 5 0(A) + (1) + (2) + (5) 50 + 1000 + 60 + 50 5 5 5 0
(A)+(5)+(8) 50+50+750 5 5 5 0(A) + (5) + (8) 50 + 50 + 750 5 5 5 0
(A)+(1)+(5)+(8) 50+1000+50+750 5 5 5 0(A) + (1) + (5) + (8) 50 + 1000 + 50 + 750 5 5 5 0
(A)+(5)+(9) 50+50+300 5 5 5 0(A) + (5) + (9) 50 + 50 + 300 5 5 5 0
(A)+(1)+(5)+(9) 50+1000+50+300 5 5 5 0(A) + (1) + (5) + (9) 50 + 1000 + 50 + 300 5 5 5 0
(A)+(5)+(10) 50+50+200 5 5 5 0(A) + (5) + (10) 50 + 50 + 200 5 5 5 0
(A)+(1)+(5)+(10) 50+1000+50+200 5 5 5 0(A) + (1) + (5) + (10) 50 + 1000 + 50 + 200 5 5 5 0
(A)+(5)+(11) 50+50+100 5 5 5 0(A) + (5) + (11) 50 + 50 + 100 5 5 5 0
(A)+(1)+(5)+(11) 50+1000+50+100 5 5 5 0(A) + (1) + (5) + (11) 50 + 1000 + 50 + 100 5 5 5 0
(A)+(5)+(12) 50+50+200 5 5 5 0(A) + (5) + (12) 50 + 50 + 200 5 5 5 0
(A)+(1)+(5)+(12) 50+1000+50+200 5 5 5 0(A) + (1) + (5) + (12) 50 + 1000 + 50 + 200 5 5 5 0
(A)+(5)+(13) 50+50+500 5 5 5 0(A) + (5) + (13) 50 + 50 + 500 5 5 5 0
(A)+(1)+(5)+(13) 50+1000+50+500 5 5 5 0(A) + (1) + (5) + (13) 50 + 1000 + 50 + 500 5 5 5 0
(A)+(5)+(14) 50+50+100 5 5 5 0(A) + (5) + (14) 50 + 50 + 100 5 5 5 0
(A)+(1)+(5)+(14) 50+1000+50+100 5 5 5 0(A) + (1) + (5) + (14) 50 + 1000 + 50 + 100 5 5 5 0
(A)+(5)+(15) 50+50+50 5 5 5 0(A) + (5) + (15) 50 + 50 + 50 5 5 5 0
(A)+(1)+(5)+(15) 50+1000+50+50 5 5 5 0(A) + (1) + (5) + (15) 50 + 1000 + 50 + 50 5 5 5 0
(A)+(5)+(16) 50+50+200 5 5 5 0(A) + (5) + (16) 50 + 50 + 200 5 5 5 0
(A)+(1)+(5)+(16) 50+1000+50+200 5 5 5 0(A) + (1) + (5) + (16) 50 + 1000 + 50 + 200 5 5 5 0
(A)+(5)+(17) 50+50+2000 5 5 5 0(A) + (5) + (17) 50 + 50 + 2000 5 5 5 0
(A)+(1)+(5)+(17) 50+1000+50+2000 5 5 5 0(A) + (1) + (5) + (17) 50 + 1000 + 50 + 2000 5 5 5 0
(A)+(5)+(18) 50+50+800 5 5 5 0(A) + (5) + (18) 50 + 50 + 800 5 5 5 0
(A)+(1)+(5)+(18) 50+1000+50+800 5 5 5 0(A) + (1) + (5) + (18) 50 + 1000 + 50 + 800 5 5 5 0
(A)+(5)+(19) 50+50+200 5 5 5 0(A) + (5) + (19) 50 + 50 + 200 5 5 5 0
(A)+(1)+(5)+(19) 50+1000+50+200 5 5 5 0(A) + (1) + (5) + (19) 50 + 1000 + 50 + 200 5 5 5 0
(A)+(5)+(20) 50+50+150 5 5 5 0(A) + (5) + (20) 50 + 50 + 150 5 5 5 0
(A)+(1)+(5)+(20) 50+1000+50+150 5 5 5 0(A) + (1) + (5) + (20) 50 + 1000 + 50 + 150 5 5 5 0
(A)+(5)+(21) 50+50+30 5 5 5 0(A) + (5) + (21) 50 + 50 + 30 5 5 5 0
(A)+(1)+(5)+(21) 50+1000+50+30 5 5 5 0(A) + (1) + (5) + (21) 50 + 1000 + 50 + 30 5 5 5 0
(A)+(5)+(22) 50+50+60 5 5 5 0(A) + (5) + (22) 50 + 50 + 60 5 5 5 0
(A)+(1)+(5)+(22) 50+1000+50+60 5 5 5 0(A) + (1) + (5) + (22) 50 + 1000 + 50 + 60 5 5 5 0
(A)+(5)+(23) 50+50+300 5 5 5 0(A) + (5) + (23) 50 + 50 + 300 5 5 5 0
(A)+(1)+(5)+(23) 50+1000+50+300 5 5 5 0(A) + (1) + (5) + (23) 50 + 1000 + 50 + 300 5 5 5 0
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――――――――――――――――――――――――――――――――――――――――――――――――――――――――――――――――――――
본 발명 조성물 및 본 발명 방법은 보다 폭 넓은 살초 스펙트럼을 가지며, 벼용의 잡초 방제제로서 유용하다.The composition of the present invention and the method of the present invention have a broader weed spectrum and are useful as weed control agents for rice.
Claims (2)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JPJP-P-2007-00109092 | 2007-04-18 | ||
| JP2007109092A JP2008266170A (en) | 2007-04-18 | 2007-04-18 | Herbicide composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR20080093905A true KR20080093905A (en) | 2008-10-22 |
Family
ID=40046185
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020080035304A KR20080093905A (en) | 2007-04-18 | 2008-04-16 | Herbicidal composition |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JP2008266170A (en) |
| KR (1) | KR20080093905A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20140037860A (en) * | 2011-05-31 | 2014-03-27 | 구미아이 가가쿠 고교 가부시키가이샤 | Method for controlling diseases in rice plant |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5553682B2 (en) * | 2009-05-29 | 2014-07-16 | 三井化学アグロ株式会社 | Herbicidal composition |
| CN103222471A (en) * | 2013-05-20 | 2013-07-31 | 联保作物科技有限公司 | Paddy field herbicidal composite and preparation thereof |
| CN104255749A (en) * | 2014-09-10 | 2015-01-07 | 广东中迅农科股份有限公司 | Herbicide composition containing pyraclonil and benzobicylon |
-
2007
- 2007-04-18 JP JP2007109092A patent/JP2008266170A/en active Pending
-
2008
- 2008-04-16 KR KR1020080035304A patent/KR20080093905A/en not_active Application Discontinuation
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20140037860A (en) * | 2011-05-31 | 2014-03-27 | 구미아이 가가쿠 고교 가부시키가이샤 | Method for controlling diseases in rice plant |
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| Publication number | Publication date |
|---|---|
| JP2008266170A (en) | 2008-11-06 |
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