KR20080080885A - Molding magnesium board and manufacturing method thereof - Google Patents

Molding magnesium board and manufacturing method thereof Download PDF

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Publication number
KR20080080885A
KR20080080885A KR1020070021177A KR20070021177A KR20080080885A KR 20080080885 A KR20080080885 A KR 20080080885A KR 1020070021177 A KR1020070021177 A KR 1020070021177A KR 20070021177 A KR20070021177 A KR 20070021177A KR 20080080885 A KR20080080885 A KR 20080080885A
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resin
paper
laminated
impregnated
magnesium board
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KR1020070021177A
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Korean (ko)
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문순기
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유신메라민공업주식회사
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/10Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/04Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/12Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of paper or cardboard
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B29/00Layered products comprising a layer of paper or cardboard
    • B32B29/06Layered products comprising a layer of paper or cardboard specially treated, e.g. surfaced, parchmentised
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B38/0004Cutting, tearing or severing, e.g. bursting; Cutter details
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/02Composition of the impregnated, bonded or embedded layer
    • B32B2260/028Paper layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/04Impregnation, embedding, or binder material
    • B32B2260/046Synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2309/00Parameters for the laminating or treatment process; Apparatus details
    • B32B2309/02Temperature
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2309/00Parameters for the laminating or treatment process; Apparatus details
    • B32B2309/04Time
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2309/00Parameters for the laminating or treatment process; Apparatus details
    • B32B2309/12Pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2317/00Animal or vegetable based
    • B32B2317/12Paper, e.g. cardboard
    • B32B2317/122Kraft paper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2317/00Animal or vegetable based
    • B32B2317/12Paper, e.g. cardboard
    • B32B2317/125Paper, e.g. cardboard impregnated with thermosetting resin

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  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Laminated Bodies (AREA)

Abstract

A molding magnesium board laminated with a pattern sheet and a manufacturing method for the same are provided to secure firm adhesive strength and high incombustibility and to improve gloss by preventing marks on the surface of glossy products. A method for manufacturing a molding magnesium board(1) laminated with a pattern sheet comprises a lamination step for laminating a resin-impregnated kraft paper(13) and a resin-impregnated pattern sheet(14) on both surfaces of a magnesium board(11), wherein resin impregnated in the kraft paper is 35~40%; a boding step for bonding each layer by heating and pressing the laminated board in a press; and a cutting step for cutting the molding magnesium board laminated with the pattern sheet, in the proper size.

Description

모양지가 적층된 성형 마그네슘 보드 및 그 제조방법{Molding magnesium board and manufacturing method thereof}Molded magnesium board and manufacturing method laminated laminated paper

도 1은 본 발명에 따른 모양지가 적층된 성형 마그네슘 보드의 제조방법에 따라 적층된 상태의 단면을 나타내는 단면도이고, 1 is a cross-sectional view showing a cross section of the laminated state according to the manufacturing method of the molded magnesium board laminated with the shape paper according to the present invention,

도 2는 종래의 방법에 따라 모양지가 적층된 성형 마그네슘 보드를 제조하는 방법에 따라 적층된 상태의 단면도이다. Figure 2 is a cross-sectional view of the laminated state according to the method for manufacturing a molded magnesium board laminated with the paper according to the conventional method.

* 도면의 주요부분에 대한 부호의 설명* Explanation of symbols for main parts of the drawings

1 --- 모양지가 적층된 성형 마그네슘 보드1 --- molded magnesium board with laminated shape paper

11 --- 마그네슘 보드 11 --- magnesium board

12 --- 접착제12 --- glue

13 --- 수지 함침 크라프트지13 --- resin impregnated kraft paper

14 --- 수지 함침 모양지14 --- resin impregnated paper

본 발명은 모양지가 적층된 성형 마그네슘 보드 및 그 제조방법에 관한 것으로, 보다 자세하게는 난연성과 표면광택이 우수하고 제조공정이 단순화되고 제조비용이 절감된 모양지가 적층된 성형 마그네슘 보드 및 그 제조방법에 관한 것이다.The present invention relates to a molded magnesium board laminated with the shape paper and a method of manufacturing the same, and more particularly to a molded magnesium board laminated with the shape paper with excellent flame retardancy and surface gloss, simplified manufacturing process and reduced manufacturing cost It is about.

건축 내장재로는 일반적으로 무늬목 시트지, 모양지, 크라프트지로 이루어진 시트를 합판이나 MDF 등의 기재에 부착하여 사용되어 왔으며, 자세하게는 페놀수지, 멜라민수지 등의 수지 함침액에 크라프트지나 모양지를 함침시켜 건조시킨 후에 합판이나 MDF 등의 기재의 상부에 안치시킨 후에, 일정한 온도 및 압력 하에 열가압 성형하여 제조하여 왔다. 그런데, 상기한 종래의 건축 내장재들은 내화, 내구성, 방충성 및 친환경성 등의 제반요건을 충분하게 충족하지는 못하였다는 단점이 제기되었으며, 따라서 이러한 문제를 해결하기 위해 마그네슘 보드가 제안되어 광범위하게 사용되어 오고 있다.As a building interior material, sheets made of veneer sheet, pattern paper, and kraft paper have been generally used to adhere to plywood or MDF substrates, and in detail, the resin impregnation solution such as phenol resin and melamine resin is impregnated with kraft paper or pattern paper and dried. After being laid down on top of a substrate such as plywood, MDF, or the like, it has been produced by thermopressing molding under a constant temperature and pressure. However, the above-mentioned conventional building interior materials have been raised the disadvantage that they did not sufficiently meet all requirements such as fire resistance, durability, insect repellent and environmental friendliness, and thus magnesium boards have been proposed and widely used to solve these problems. It has been.

일반적으로 마그네슘 보드는 천연 무기질인 마그네슘을 주 원료로 한 친환경 건축자재로써 내화, 내수 및 내구성을 가지고 있으며, 인체에 유해한 독소가 전혀없고 방충, 방균성이 뛰어나며, 또한 2차 가공성이 매우 우수하여 자재비 및 시공비 절감 효과가 큰 다기능성 제품이다. 자세하게는 마그네슘 보드는 인체 친화적인 보드로서 흰개미와 같은 해충의 침투방지 기능과 도장 및 도배, 시트지 등으로 표 면 마감처리가 우수하고, 화재시 유독 가스가 전혀 발생하지 않고 또한, 물과 습기에 강한 방수성 및 팽창력 유지, 결로 및 습기의 침투를 차단하여 쾌적한 환경을 유지하고, 항곰팡이, 방충의 우수한 물성유지, 치수변화의 안정성과 난연성이 우수하다는 장점이 있어 벽판넬, 주방 불연판넬, 다중이용시설, 욕실,화장실 등 내부 장식재로 많이 사용되고 있는 것이다.In general, magnesium board is an eco-friendly building material based on magnesium, which is a natural inorganic material. It has fire resistance, water resistance, and durability. It is free from harmful toxins, has excellent insect repellent and anti-bacterial properties, and has excellent secondary workability. And it is a multifunctional product with a large effect of reducing construction costs. In detail, magnesium board is a human-friendly board, which prevents the penetration of pests such as termites, and has excellent surface finish by painting, papering, sheeting, etc. Maintains a comfortable environment by maintaining waterproofness and expansion force, blocking condensation and moisture, maintaining excellent properties of anti-mold, insect, and stability and flame retardancy of dimensional change. Wall panel, kitchen nonflammable panel, multi-use facility It is widely used as interior decoration materials such as bathrooms and toilets.

상기한 바와 같은 우수한 특성으로 인하여 광범위하게 사용되어 온 마그네슘 보드는 외관의 품위를 유지하기 위해 크라프트지와 모양지를 적층하여 사용되어 오고 있는데, 이러한 크라프트지와 모양지를 적층하는 방법으로는, 예를 들어 대한민국특허출원 제2004-0042892호의 "불연성 판넬 및 그 제조방법"에서는, "제1공정(모양지 제조공정); 멜라민수지40중량%, 요소수지 40중량%, 메틸에틸알콜 2중량%, 이형제 0.5중량%, 계면활성제 0.5중량%, 물 10중량%, 메탄올 7중량%,을 혼합하여 통상의 방법으로 멜라민수지 함침액을 제조한 뒤, 모양지(80g/㎡)를 상기 멜라민수지 함침액에 함침시켜 수지함침량이 55±5%가 되도록 함침시킨 다음 110℃에서 건조시켜 멜라민수지 모양지를 제조 한 다음, 제2공정(보드제조공정); 탄산칼슘10g, 산화규소 30g, 경석30g, 산화마그네슘2g, 염화마그네슘5g,을 교반기에 투입하여 교반한 다음, 물30g을 넣어 충분히 혼합한 후에, 성형틀에 투입하여 보드를 성형한 다음, 20시간 양생시킨 후에, 불연성 보드를 제조한 다음, 제3공정(판넬제조공정); 상기 제2공정에서 제조한 보드의 상부에 접착제를 도포한 다음, 그 상부에 상기 1공정에서 제조한 멜라민수지 모양지 1장을 적층한 다음, 120℃ 내지 150℃에서 2000kg/㎠의 압력으로 2시간 열가압한 다음, 24시간에 걸쳐 상온으로 냉각 한 다음 탈형하여 불연판넬을 제조 한 후에, 제4공정(가공공정); 상기와 같이 제조된 불연판넬을 런닝쇼(톱을 이용한 재단기의 일종임)로 규격별로 절단한 뒤에, 테로나(홈이나 측면의 일부를 절단하는 기계임)로 상부와 측면에 홈을 형성하고, 다른 측면과 하부에는 돌기를 형성한 다음, 불연성페인트를 분무기로 가공된 부분을 도장하여 제조함을 특징으로 하는 불연성 판넬의 제조방법"을 개시하고 있다. Magnesium boards, which have been widely used due to the excellent properties as described above, have been used by laminating kraft paper and shape paper to maintain the appearance of appearance. As a method of laminating kraft paper and shape paper, for example, In the "non-flammable panel and its manufacturing method" of Korean Patent Application No. 2004-0042892, "the first process (shape paper manufacturing process); melamine resin 40% by weight, urea resin 40% by weight, methyl ethyl alcohol 2% by weight, release agent 0.5 To prepare a melamine resin impregnation solution in a conventional manner by mixing the weight%, 0.5% by weight surfactant, 10% by weight water, 7% by weight methanol, and then impregnated with the melamine resin impregnation liquid (80g / ㎡) After impregnating the resin impregnation to 55 ± 5%, and dried at 110 ℃ to prepare a melamine resin paper, the second step (board manufacturing process): calcium carbonate 10g, silicon oxide 30g, pumice 30g, magnesium oxide 2g,5 g of magnesium chloride was added to the stirrer and stirred, 30 g of water was added to the mixture, and then mixed into a mold, and then the board was molded and cured for 20 hours, after which the non-flammable board was manufactured. Panel manufacturing process); After applying the adhesive on the upper part of the board manufactured in the second step, and laminated one sheet of melamine resin-shaped paper prepared in the first step on the upper part, and then 2000kg / at 120 ℃ to 150 ℃ After 2 hours of heat pressurization at a pressure of cm 2, cooling to room temperature over 24 hours, and then demolding to produce a non-combustible panel, the fourth step (processing step); After cutting according to the standard by using a cutting machine used), a groove is formed in the upper side and the side with a terona (a machine that cuts a part of the groove or the side), and protrusions are formed in the other side and the lower side, and then the non-combustible paint Machined with sprayer Discloses a method for producing a non-flammable panel characterized by coating powder.

그러나, 상기한 종래의 방법은 제3공정에서 나타난 바와 같이 필수적으로 접착제의 사용을 요하며 이에 의해 난연 테스트에 불리하고 유광제품의 경우 표면에 자국이 남아 광택이 저하할 뿐 아니라 접착제를 보다 균일하게 도포되도록 하기 위해 가압조건이 높은 온도에서 장시간 동안 수행하여야 하므로 작업공정이 복잡하다는 단점이 있다.However, the conventional method described above essentially requires the use of an adhesive, as shown in the third step, which is disadvantageous to flame retardant testing, and in the case of a glossy product, marks remain on the surface to reduce gloss and make the adhesive more uniform. In order to be applied, the pressurization condition has to be performed for a long time at a high temperature, so there is a disadvantage that the work process is complicated.

따라서, 본 발명의 목적은 상기한 종래의 문제점을 해결하기 위해 안출된 것으로, 모양지가 적층된 성형 마그네슘 보드의 제조 방법에 있어서 접착제의 사용을 배제하면서도 각층 간의 박리가 발생하지 않고 또한 균일한 표면을 갖는 성형 마그네슘 보드의 제조 방법을 제공하기 위한 것이다. Accordingly, an object of the present invention is to solve the above-mentioned conventional problems, in the manufacturing method of the molded magnesium board laminated shape paper, while eliminating the use of the adhesive, peeling between each layer does not occur and even surface It is to provide a method for producing a molded magnesium board having.

본 발명의 다른 목적은 상기 방법에 의해 제조된 모양지가 적층된 성형 마그네슘 보드를 제공하기 위한 것이다.Another object of the present invention is to provide a molded magnesium board laminated with the shape paper produced by the above method.

본 발명자 등은 상기 목적을 달성하기 위하여 예의 연구한 결과 마그네슘 보드와 접하는 크라프트지의 수지함량과, 가압온도 및 가압력 등의 각층의 접합조건을 적의 조절함으로 상기한 종래의 문제점을 해결할 수 있음을 알게 되어 본 발명을 완성하게 되었다.As a result of intensive studies to achieve the above object, the present inventors have found that the above-mentioned problems can be solved by adjusting the resin content of kraft paper and the bonding conditions of each layer such as pressurization temperature and pressing force. The present invention has been completed.

상기한 본 발명의 목적을 달성하기 위한 모양지가 적층된 성형 마그네슘 보드의 제조방법은;Method for producing a molded magnesium board laminated with paper for achieving the above object of the present invention;

모양지가 적층된 성형 마그네슘 보드의 제조에 있어서,In the manufacture of the molded magnesium board laminated | stacked the shape paper,

마그네슘 보드 위에 수지 함침 크라프트지와 수지 함침 모양지를 보드 양면에 동일하게 적층하는 적층공정, 여기서 상기 크라프트지에 함침되는 수지 함량은 35 내지 40%임;A lamination process of laminating the resin impregnated kraft paper and the resin impregnated shape paper on both sides of the board on a magnesium board, wherein the resin content impregnated in the kraft paper is 35 to 40%;

상기 공정에서 적층된 보드를 프레스에 넣어 가열 및 가압하여 접착하는 각층의 접착공정; 및Bonding the laminated layers by pressing and heating and pressing the laminated boards in the above step; And

접착공정에 의해 얻어진 모양지가 적층된 성형 마그네슘 보드를 적절한 사이즈로 절단하는 재단공정으로 구성됨을 특징으로 한다.It is characterized by consisting of a cutting step of cutting the molded magnesium board laminated with the shape paper obtained by the bonding process to an appropriate size.

본 발명의 다른 구성에 따르면, 상기 적층공정에서는 수지 함침 모양지 상에 오버레이지를 더 적층함을 특징으로 한다.According to another configuration of the present invention, the lamination step is characterized in that the overlay paper is further laminated on the resin impregnated paper.

본 발명의 또 다른 구성에 따르면, 상기 적층공정에서는 수지 함침 크라프트지 대신에 멜라민 수지가 함침된 오버레이지를 적층함을 특징으로 한다.According to another configuration of the present invention, the lamination step is characterized in that the overlay paper impregnated with the melamine resin instead of the resin impregnated kraft paper.

본 발명의 또 다른 구성에 따르면, 상기 접착공정은 150 내지 250℃에서 10 내지 30kgf/㎠의 압력으로 300 내지 600초 동안 프레싱함을 특징으로 한다.According to another configuration of the present invention, the bonding process is characterized in that the pressing for 300 to 600 seconds at a pressure of 10 to 30kgf / ㎠ at 150 to 250 ℃.

본 발명의 또 다른 구성에 따르면, 상기 접착공정은 120 내지 180℃에서 100 내지 160kgf/㎠의 압력으로 600 내지 1,800초 동안 프레싱함을 특징으로 한다.According to another configuration of the present invention, the bonding process is characterized in that the pressing for 600 to 1,800 seconds at a pressure of 100 to 160kgf / ㎠ at 120 to 180 ℃.

본 발명의 또 다른 구성에 따르면, 상기 크라프트지 또는 모양지가 함침되어 지는 함침용 수지는 멜라민수지, DAF(Diallyl phthalate)수지나 요소수지, 멜라민-요소 공축합수지, 페놀 수지, 아크릴 수지, 우레탄 수지에서 선택된 것임을 특징으로 한다.According to another configuration of the present invention, the impregnating resin impregnated with the kraft paper or paper is melamine resin, DAF (Diallyl phthalate) resin or urea resin, melamine-urea co-condensation resin, phenol resin, acrylic resin, urethane resin It is characterized in that selected from.

상기한 바와 같이 본 발명에 따라 상기 크라프트지에 함침되는 수지 함량은 35 내지 40%로 되는데, 만일 35% 미만으로 되면 마그네슘 보드와 크라프트지 사이의 접착이 원활하게 이루어지지 않아 재단 공정 등에서 마그네슘 보드와 크라프트지 층간의 박리가 일어나 바람직하지 않고, 반대로 40%를 초과하면 수지가 표면으로 베어 나와 표면에 얼룩 등이 형성되어 광택이 하락하는 단점이 있어 바람직하지 않다.As described above, the resin content impregnated in the kraft paper is 35 to 40% according to the present invention. If it is less than 35%, the adhesion between the magnesium board and the kraft paper is not smoothly performed. Delamination between layers is not preferable, and if it exceeds 40%, the resin is drawn off to the surface and stains are formed on the surface, which is not preferable because the gloss decreases.

또한, 상기한 바와 같이 본 발명에 따르면, 상기 마그네슘 보드 위에 수지 함침 크라프트지와 수지 함침 모양지를 보드 양면에 동일하게 적층하게 되는데, 만일 보드의 양면에 동일 사양으로 적층하지 않을 경우 각층의 밴딩력의 차이에 기인하여 완성된 제품의 휨 현상이 발생할 수 있어 바람직하지 않다. In addition, according to the present invention as described above, the resin impregnated kraft paper and resin impregnated shape paper is laminated on both sides of the board on the magnesium board, if not laminated to the same specifications on both sides of the board of the bending force of each layer Due to the difference, warpage of the finished product may occur, which is undesirable.

상기와 같이 구성되는 모양지가 적층된 성형 마그네슘 보드의 제조방법은 일 정함량의 수지가 함침된 크라프트지를 사용하여 일정한 온도와 압력으로 열융착함으로 접착제를 사용하지 않으면서도 각층 간의 박리가 발생하지 않는 단단한 접착력을 얻을 수 있고, 접착제의 사용을 배제하여 난연성이 우수하고 유광제품의 경우 표면에 자국을 전혀 남기지 않아 광택이 우수할 뿐 아니라 제조공정이 단순화되고 제조비용이 크게 줄어든다.The manufacturing method of the molded magnesium board with the shape paper laminated as described above is made by using a kraft paper impregnated with a certain amount of resin and heat-sealed at a constant temperature and pressure, so that peeling does not occur between layers without using an adhesive. Adhesion can be obtained, and flame retardancy is eliminated by eliminating the use of adhesives. Glossy products do not leave any marks on the surface, which is excellent in gloss, and the manufacturing process is simplified and manufacturing costs are greatly reduced.

상기한 본 발명에 구성에 따른 모양지가 적층된 성형 마그네슘 보드의 제조방법에서 적층공정에 따라 적층된 각층의 구성을 보다 용이하게 이해되도록 하기 위해 첨부 도면을 참고로 하여 보다 자세하게 설명하면 다음과 같다. Referring to the accompanying drawings in order to more easily understand the configuration of each layer laminated in accordance with the lamination process in the manufacturing method of the molded magnesium board laminated with the shape paper according to the present invention as described above are as follows.

도 1은 본 발명에 따른 모양지가 적층된 성형 마그네슘 보드의 제조방법에 따라 적층된 상태의 단면을 나타내는 단면도이고, 도 2는 종래의 방법에 따라 모양지가 적층된 성형 마그네슘 보드를 제조하는 방법에 따라 적층된 상태의 단면도이다. 도 1에 도시된 바와 같이, 본 발명에 따른 모양지가 적층된 성형 마그네슘 보드는 마그네슘 보드(11)의 양면에, 도 2에 도시된 종래의 방법에 따라 적층되는 접착제(12)를 적층하지 않고 바로 일정비율의 수지가 함침된 크라프트지(13)를 적층하는 것이 특징적인 것이다. 1 is a cross-sectional view showing a cross-section of the laminated state according to the manufacturing method of the molded magnesium board laminated shape paper according to the present invention, Figure 2 is a method of manufacturing a molded magnesium board laminated shape paper according to a conventional method It is sectional drawing of the laminated state. As shown in Fig. 1, the molded magnesium board on which the shape paper is laminated according to the present invention is directly on both sides of the magnesium board 11, without laminating the adhesive 12 laminated according to the conventional method shown in Fig. It is characteristic to laminate kraft paper 13 impregnated with a certain ratio of resin.

이하, 본 발명을 실시예 및 실험예에 의해 보다 자세히 설명하지만, 본 발명이 여기에 한정되는 것이 아님은 물론이다.Hereinafter, the present invention will be described in more detail with reference to Examples and Experimental Examples, but the present invention is not limited thereto.

실시예 1Example 1

크라프트지를 페놀 수지에 수지의 함량이 35%가 되도록 함침하여 페놀수지 함침 크라프트지를 얻고, 모양지를 멜라민 수지에 함침하여 멜라민 수지 함침 모양지를 얻었다. 다음으로 상기와 같이 얻은 페놀수지 함침 크라프트지와 멜라민 수지 함침 모양지를 마그네슘 보드의 양면에 순차로 적층하여 프레스에 넣어 200℃에서 20kgf/㎠의 압력으로 450초 동안 단기 프레싱하여 모양지가 적층된 성형 마그네슘 보드를 얻었다.Kraft paper was impregnated with phenol resin so that the content of resin was 35% to obtain phenol resin impregnated kraft paper, and the paper was impregnated with melamine resin to obtain melamine resin impregnated paper. Next, the phenolic resin impregnated kraft paper and melamine resin impregnated shaped paper obtained as described above were sequentially laminated on both sides of the magnesium board, put into a press, and pressed for a short time at 200 ° C. at a pressure of 20 kgf / ㎠ for 450 seconds to form a molded magnesium. Got a board.

실시예 2Example 2

열압착을 150℃에서 130kgf/㎠의 압력으로 1,200초 동안 멀티 오프닝(Multi-opening) 프레싱하는 것을 제외하고는 실시예 1과 동일하게 하여 모양지가 적층된 성형 마그네슘 보드를 얻었다.The molded magnesium board was laminated in the same manner as in Example 1 except that the thermocompression was pressed for 1,200 seconds at a pressure of 130 kgf / cm 2 at 150 ° C. for multi-opening.

실시예 3Example 3

크라프트지를 페놀 수지에 수지의 함량이 40%가 되도록 함침한 페놀수지 함침 크라프트지를 사용하는 것을 제외하고는 실시예 1과 동일하게 하여 모양지가 적층된 성형 마그네슘 보드를 얻었다.A molded magnesium board was obtained in the same manner as in Example 1 except that phenol resin-impregnated kraft paper impregnated with kraft paper so that the resin content was 40%.

비교예 1 Comparative Example 1

크라프트지를 페놀 수지에 수지의 함량이 30%가 되도록 함침한 페놀수지 함 침 크라프트지를 사용하는 것을 제외하고는 실시예 1과 동일하게 하여 모양지가 적층된 성형 마그네슘 보드를 얻었다.Except for using phenol resin-impregnated kraft paper impregnated with phenolic resin so that the kraft paper is 30% of the resin content in the same manner as in Example 1 to obtain a molded magnesium board laminated with the shape paper.

비교예 2Comparative Example 2

크라프트지를 페놀 수지에 수지의 함량이 45%가 되도록 함침한 페놀수지 함침 크라프트지를 사용하는 것을 제외하고는 실시예 1과 동일하게 하여 모양지가 적층된 성형 마그네슘 보드를 얻었다.A molded magnesium board was obtained in the same manner as in Example 1 except that phenol resin-impregnated kraft paper impregnated with kraft paper so that the resin content was 45%.

실험예.Experimental Example

상기 각 실시예 및 비교에에 따라 얻어진 모양지가 적층된 성형 마그네슘 보드를 적절한 사이즈로 재단하여 각층 간의 박리 현상의 발생 여부와 표면 상태를 육안으로 검사하여 그 결과를 다음 표 1에 나타냈다. 자세하게는 재단된 말단 부분을 손으로 까보았을 때 쉽게 박리되면 접착 불량으로, 그렇지 않으면 접착 양호로 나타냈으며, 표면 상태는 육안으로 관찰하였을 때 표면에 평탄화 정도와 광택의 상태를 평가하였다.The molded magnesium board on which the pattern paper obtained according to each of the above examples and the comparison was laminated was cut to an appropriate size to visually inspect the occurrence and the surface state of the peeling phenomenon between the layers, and the results are shown in Table 1 below. In detail, when the peeled terminal part was easily peeled by hand, it was shown to be poor in adhesion and otherwise in good adhesion, and the surface state was evaluated by the degree of flatness and gloss on the surface when visually observed.

구분division 실시예 1Example 1 실시예 2Example 2 실시예 3Example 3 비교예 1Comparative Example 1 비교예 2Comparative Example 2 접착상태Bonding state 양호Good 양호Good 양호Good 불량Bad 양호Good 표면거칠기Surface roughness 양호Good 양호Good 양호Good 양호Good 불량Bad 표면광택Surface gloss 양호Good 양호Good 양호Good 양호Good 흐림blur

상기와 같이 구성되는 본 발명의 모양지가 적층된 성형 마그네슘 보드의 제조방법은 접착제를 사용하지 않으면서도 각층 간의 박리가 발생하지 않는 단단한 접착력을 얻을 수 있고, 난연성이 우수하고 유광제품의 경우 표면에 자국을 전혀 남기지 않아 광택이 우수할 뿐 아니라 제조공정이 단순화되고 제조비용이 크게 줄어든 성형 마그네슘 제조 방법을 제공하는 유용한 발명이다.The method of manufacturing a molded magnesium board laminated with the pattern paper of the present invention configured as described above can obtain a firm adhesive force without peeling between layers without using an adhesive, and has excellent flame retardancy and marks on the surface of a glossy product. It is a useful invention that provides a method for producing molded magnesium, which leaves not at all excellent in gloss, but also simplifies the manufacturing process and greatly reduces the manufacturing cost.

Claims (6)

모양지가 적층된 성형 마그네슘 보드의 제조에 있어서,In the manufacture of the molded magnesium board laminated | stacked the shape paper, 마그네슘 보드 위에 수지 함침 크라프트지와 수지 함침 모양지를 보드 양면에 동일하게 적층하는 적층공정, 여기서 상기 크라프트지에 함침되는 수지 함량은 35 내지 40%임;A lamination process of laminating the resin impregnated kraft paper and the resin impregnated shape paper on both sides of the board on a magnesium board, wherein the resin content impregnated in the kraft paper is 35 to 40%; 상기 공정에서 적층된 보드를 프레스에 넣어 가열 및 가압하여 접착하는 각층의 접착공정; 및Bonding the laminated layers by pressing and heating and pressing the laminated boards in the above step; And 접착공정에 의해 얻어진 모양지가 적층된 성형 마그네슘 보드를 적절한 사이즈로 절단하는 재단공정으로 구성됨을 특징으로 하는 모양지가 적층된 성형 마그네슘 보드의 제조방법.A method for producing a molded magnesium board laminated with the shape paper, characterized in that it consists of a cutting step of cutting the molded magnesium board laminated on the shape paper obtained by the bonding process to an appropriate size. 제 1항에 있어서, 상기 적층공정에서는 수지 함침 모양지 상에 오버레이지를 더 적층함을 특징으로 하는 모양지가 적층된 성형 마그네슘 보드의 제조방법.2. The method of claim 1, wherein in the lamination step, the overlay paper is further laminated on the resin-impregnated paper. 제 1항에 있어서, 상기 적층공정에서는 수지 함침 크라프트지 대신에 멜라민 수지가 함침된 오버레이지를 적층함을 특징으로 하는 모양지가 적층된 성형 마그네슘 보드의 제조방법.2. The method of claim 1, wherein in the laminating step, overlay papers with a melamine resin are laminated instead of the resin-impregnated kraft paper. 제 1항에 있어서, 상기 접착공정은 150 내지 250℃에서 10 내지 30kgf/㎠의 압력으로 300 내지 600초 동안 프레싱함을 특징으로 하는 모양지가 적층된 성형 마그네슘 보드의 제조방법.The method of claim 1, wherein the bonding process is performed at a pressure of 10 to 30 kgf / cm 2 at 150 to 250 ° C. for 300 to 600 seconds. 제 1항에 있어서, 상기 접착공정은 120 내지 180℃에서 100 내지 160kgf/㎠의 압력으로 600 내지 1,800초 동안 프레싱함을 특징으로 하는 모양지가 적층된 성형 마그네슘 보드의 제조방법.The method of claim 1, wherein the bonding process is performed at 600 to 1,800 seconds at 120 to 180 ° C. at a pressure of 100 to 160 kgf / cm 2. 제 1항 내지 제5항 중 어느 한 한에 있어서, 상기 크라프트지 또는 모양지가 함침되어 지는 함침용 수지는 멜라민수지, DAF(Diallyl phthalate)수지나 요소수지, 멜라민-요소 공축합수지, 페놀 수지, 아크릴 수지, 우레탄 수지에서 선택된 것임을 특징으로 하는 모양지가 적층된 성형 마그네슘 보드의 제조방법.The impregnating resin in which the kraft paper or the pattern paper is impregnated is melamine resin, DAF (Diallyl phthalate) resin or urea resin, melamine-urea co-condensation resin, phenol resin, Method for producing a molded magnesium board laminated with the shape paper, characterized in that selected from acrylic resin, urethane resin.
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KR100912799B1 (en) * 2009-01-12 2009-08-18 주식회사 광성테크 Multi-layered magnesium pannel for interior decoration
KR101440993B1 (en) * 2013-08-08 2014-11-03 박지은 Decorative Board Impregnated Acrylic Resin For Inner and Outer Finishing Materials And Manufacturing Method thereof
KR101440992B1 (en) * 2013-08-08 2014-11-03 박지은 Panel for waterproof interior and outerior materials using short wood veneer and manufacturing method thereof
WO2015020252A1 (en) * 2013-08-08 2015-02-12 Park Ji-Eun Waterproof-type interior material and manufacturing method therefor
WO2015020251A1 (en) * 2013-08-08 2015-02-12 Park Ji-Eun Water-proof panel for interior and exterior materials using wooden veneer and manufacturing method therefor
WO2015020249A1 (en) * 2013-08-08 2015-02-12 Park Ji-Eun Acrylic resin-impregnated decorative sheet for inner and outer finishing materials, and manufacturing method therefor
KR20170135053A (en) * 2016-05-30 2017-12-08 이기원 Magnesium board and method of forming the same
KR102334799B1 (en) * 2021-01-29 2021-12-07 최석현 Antibacterial and antiviral surface material for attaching wood and manufacturing method for furniture panel using the same

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