KR20040089979A - fabrication of white Light Emitting Diodes - Google Patents
fabrication of white Light Emitting Diodes Download PDFInfo
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- KR20040089979A KR20040089979A KR1020030023846A KR20030023846A KR20040089979A KR 20040089979 A KR20040089979 A KR 20040089979A KR 1020030023846 A KR1020030023846 A KR 1020030023846A KR 20030023846 A KR20030023846 A KR 20030023846A KR 20040089979 A KR20040089979 A KR 20040089979A
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
- H01L2224/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
- H01L2224/42—Wire connectors; Manufacturing methods related thereto
- H01L2224/47—Structure, shape, material or disposition of the wire connectors after the connecting process
- H01L2224/48—Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
- H01L2224/4805—Shape
- H01L2224/4809—Loop shape
- H01L2224/48091—Arched
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
- H01L2224/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
- H01L2224/42—Wire connectors; Manufacturing methods related thereto
- H01L2224/47—Structure, shape, material or disposition of the wire connectors after the connecting process
- H01L2224/48—Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
- H01L2224/481—Disposition
- H01L2224/48151—Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive
- H01L2224/48221—Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked
- H01L2224/48245—Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being metallic
- H01L2224/48247—Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being metallic connecting the wire to a bond pad of the item
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
- H01L2224/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
- H01L2224/42—Wire connectors; Manufacturing methods related thereto
- H01L2224/47—Structure, shape, material or disposition of the wire connectors after the connecting process
- H01L2224/48—Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
- H01L2224/481—Disposition
- H01L2224/48151—Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive
- H01L2224/48221—Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked
- H01L2224/48245—Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being metallic
- H01L2224/48257—Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being metallic connecting the wire to a die pad of the item
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
- H01L2224/73—Means for bonding being of different types provided for in two or more of groups H01L2224/10, H01L2224/18, H01L2224/26, H01L2224/34, H01L2224/42, H01L2224/50, H01L2224/63, H01L2224/71
- H01L2224/732—Location after the connecting process
- H01L2224/73251—Location after the connecting process on different surfaces
- H01L2224/73265—Layer and wire connectors
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2924/00—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
- H01L2924/15—Details of package parts other than the semiconductor or other solid state devices to be connected
- H01L2924/181—Encapsulation
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Abstract
Description
본 발명은 백색 발광소자의 제조 방법에 관한 것으로 특히, 발광칩의 파장 변화에 민감하지 않은 고휘도의 백색 발광소자 제조 방법에 관한 것이다.The present invention relates to a method of manufacturing a white light emitting device, and more particularly, to a method of manufacturing a high brightness white light emitting device that is not sensitive to the wavelength change of the light emitting chip.
일반적으로, 백색광을 발광하는 다이오드를 제조하기 위하여 청색 발광 다이오드 상에 형광 안료가 혼합된 액상 수지를 봉입하여 백색광 LED를 제조하여 왔다. 백색광이란 일반적으로 그 파장이 400 nm에서 600 nm까지 균일하게 분포된 광을 말한다.In general, a white light LED has been manufactured by encapsulating a liquid resin mixed with a fluorescent pigment on a blue light emitting diode in order to manufacture a diode emitting white light. White light generally refers to light whose wavelength is uniformly distributed from 400 nm to 600 nm.
종래에 백색을 발광하는 LED는 회로가 구성되어 있는 인쇄회로기판 또는 철이나 구리 재질의 리드 프레임 상에 청색 발광칩을 장착하고 칩 상부에 액상 수지와 형광체를 믹싱하여 경화시키는 방법과, 일정한 형상을 갖는 플라스틱 재질의 사출물에 형광 안료를 디스펜서를 이용하여 포팅한 후 에폭시로 마감을 하는 방식과, 리드 프레임에 형광 안료를 포팅하여 램프의 형상을 한 몰드컵을 이용하여 LED 램프로 제조하는 방식 등 다양한 종류의 제조 방법이 있었다.Conventionally, a white LED emits a blue light emitting chip on a printed circuit board having a circuit or a lead frame made of iron or copper, and hardens by mixing a liquid resin and a phosphor on the chip, and a certain shape. Potting fluorescent pigments into plastic injection moldings with a dispenser and finishing them with epoxy, and manufacturing them into LED lamps using a mold cup shaped like a lamp by potting fluorescent pigments on the lead frame. There was a method of preparation.
일반적으로 종래에는 가시광 영역 중 특히 파장 450 ~ 470 nm의 청색 발광칩을 외부와 전기적으로 도전상태가 되도록 실장한 후, 상기 발광칩을 덮도록 Yttrium Aluminum Garnet(Y3Al5O12; 이하 'YAG'라 칭함)계 형광 안료를 포함하는 형광물질층을 형성하는 방법을 이용하였다.Generally, after mounting a blue light emitting chip having a wavelength of 450 to 470 nm in an electrically conductive state in the visible region, the Yttrium Aluminum Garnet (Y 3 Al 5 O 12 ; A method of forming a fluorescent material layer containing a 'based) fluorescent pigment was used.
상술한 바와 같이 제조된 종래의 백색 발광소자는 청색 발광칩의 청색광이 상기 형광물질층 내에 첨가된 YAG계 형광 안료와 반응하여 나오는 적색 및 녹색 가시광과 형광 안료와 반응하지 못하고 투과한 원래 청색광 사이의 색조합에 의하여 백색광을 구현하였다.In the conventional white light emitting device manufactured as described above, the blue light of the blue light emitting chip is separated between the red and green visible light that is reacted with the YAG-based fluorescent pigment added in the fluorescent material layer and the original blue light that does not react with the fluorescent pigment. White light was realized by the hue sum.
그러나, 450 ~ 470 nm의 청색 발광칩은 여기 파워가 약해 자연색에 가까운 조명용 백색광을 형성하기에는 어려운 문제가 있어 현재 광원 파워가 큰 370 ~ 410 nm의 자외선 발광칩을 이용하여 백색광을 형성하고자하는 노력들이 진행되고 있다.However, since the blue light emitting chip of 450 to 470 nm has a weak excitation power, it is difficult to form a white light for illumination close to natural colors. At present, efforts to form white light using an ultraviolet light emitting chip of 370 to 410 nm having a large light source power have been made. It's going on.
따라서, 본 발명의 목적은 청색 발광칩 뿐만 아니라 광원파워가 큰 자외선 칩 등을 이용하여 발광칩의 파장변화에 민감하지 않는 고휘도의 백색 발광소자 제조 방법을 제공함에 있다.Accordingly, an object of the present invention is to provide a method of manufacturing a high brightness white light emitting device that is not sensitive to the wavelength change of the light emitting chip using not only a blue light emitting chip but also an ultraviolet chip having a large light source power.
상기 목적을 달성하기 위한 본 발명에 따른 백색 발광 소자는 외부와 전기적으로 연결되도록 발광칩을 실장하는 단계와, 상기 발광칩을 덮도록 액체 또는 고체수지에 (Sr,Ba)2SiO4:Eu 형광 안료를 첨가하여 형광물질층을 형성하는 단계를 포함하여 이루어진다. 상기 발광칩의 발광영역은 일부 가시광 영역부터 자외선 영역에 이르는 250 ~ 500 nm인 것을 사용하며, 상기 발광칩의 수는 패키지에 따라 상기 파장영역 내의 하나 또는 둘 이상의 것을 사용하는 것을 특징으로 한다.White light emitting device according to the present invention for achieving the above object is a step of mounting a light emitting chip to be electrically connected to the outside, (Sr, Ba) 2 SiO 4 : Eu fluorescence in a liquid or solid resin to cover the light emitting chip Adding a pigment to form a phosphor layer. The light emitting region of the light emitting chip is 250 to 500 nm, ranging from a portion of visible light to an ultraviolet region, and the number of the light emitting chips is one or two or more in the wavelength region depending on the package.
도 1은 백색 발광소자의 일 예를 도시하는 단면도.1 is a cross-sectional view showing an example of a white light emitting element.
도 2는 백색 발광소자의 다른 예를 도시하는 단면도.2 is a cross-sectional view showing another example of a white light emitting element.
도 3은 백색 발광소자의 또 다른 예를 도시하는 단면도.3 is a cross-sectional view showing yet another example of a white light emitting element.
도 4는 백색 발광소자의 또 다른 예를 도시하는 단면도.4 is a cross-sectional view showing still another example of a white light emitting element.
도 5는 본 발명에서 사용된 형광 안료의 발광 특성을 나타내는 그래프.5 is a graph showing the light emission characteristics of the fluorescent pigment used in the present invention.
도 6은 본 발명의 실시 예에 따라 제조된 백색 발광소자를 스펙트로메타로 측정한 그래프.Figure 6 is a graph measured by spectrometer white light emitting device manufactured according to an embodiment of the present invention.
이하에서 첨부된 도 1 내지 도 6의 도면을 참고로 본 발명을 상세히 설명한다.Hereinafter, the present invention will be described in detail with reference to the accompanying drawings of FIGS. 1 to 6.
도 1 내지 도 4에서 도시된 백색 발광소자의 단면도와 같이, 필요에 따라 각각의 재질로 여러 층 도금이 되어 일정한 패턴을 이루고 있는 인쇄회로기판(7)과 이와 비슷한 역할을 하는 리드프레임(6) 상에 발광칩(3)을 접착제(4)를 이용하여 접착 고정하고, 상기 접착제(4)가 경화되도록 일정 온도조건에 일정시간을 방치한다. 본 발명에 따른 백색 발광소자를 제조하기 위해 상기 발광칩(3)으로 청색광 영역에서부터 가시광 영역의 발광다이오드에 이르기까지 250 ~ 500 nm 파장 범위 내에서 사용할 수 있다.As shown in the cross-sectional view of the white light emitting device shown in Figures 1 to 4, the printed circuit board (7) and the lead frame (6) having a similar role to form a predetermined pattern by plating several layers of each material as necessary The light emitting chip 3 is adhered to and fixed by using the adhesive 4 on the light emitting chip 3, and the predetermined time is left at a predetermined temperature condition so that the adhesive 4 is cured. In order to manufacture a white light emitting device according to the present invention, the light emitting chip 3 may be used within a wavelength range of 250 to 500 nm, ranging from a blue light region to a light emitting diode in a visible light region.
이렇게 실장된 발광칩(3)을 전기적으로 도전 상태로 만들기 위하여 도전성 재료로 와이어(5) 본딩한다. 이어서 상기 발광칩(3)을 덮도록 액체 또는 고체수지에 (Sr,Ba)2SiO4:Eu 형광 안료를 첨가하여 형광물질층(2)을 형성한다.In order to make the mounted light emitting chip 3 electrically conductive, the wire 5 is bonded with a conductive material. Subsequently, (Sr, Ba) 2 SiO 4 : Eu fluorescent pigment is added to the liquid or solid resin to cover the light emitting chip 3 to form the fluorescent material layer 2.
상기 형광물질층(2)을 형성하는 방법은 액체수지를 이용하는 방법과, 고체수지를 이용하는 방법으로 크게 분류할 수 있다.The fluorescent material layer 2 may be broadly classified into a method using a liquid resin and a method using a solid resin.
도 1에 도시된 백색 발광소자의 경우는 고체수지를 이용한 것으로서, 상기 과정에 이미 제조된 인쇄회로기판(7)을 알맞은 금형이 설치된 트랜스퍼 몰딩 프레스 상에 배열하고 형광 안료가 첨가된 몰딩 컴파운드 태블릿을 넣고 소정의 압력, 온도 그리고, 시간을 두어 외부와 전기적으로 연결된 상기 발광칩(3)을 덮도록 성형하여 형광물질층(2)을 형성한다. 상기에서 몰딩 컴파운드 태블릿은 고체분말수지에 (Sr,Ba)2SiO4:Eu 형광 안료를 10 ~ 100 % 범위 내에서 상기 발광칩(3)에 따라 적절한 비율로 조절하여 첨가 및 혼합한 후, 0.5 ~ 3 톤의 압력과 50 ~ 180℃의 온도 조건을 맞추어 100 ~ 600 초간 유지하여 형성한다.In the case of the white light emitting device shown in FIG. And a predetermined pressure, temperature, and time are formed to cover the light emitting chip 3 electrically connected to the outside to form the fluorescent material layer 2. In the above molding compound tablet (Sr, Ba) 2 SiO 4 : Eu fluorescent pigment in a solid powder resin in a range of 10 to 100% by adjusting and adding in an appropriate ratio according to the light emitting chip (3), 0.5, It is formed by maintaining it for 100 to 600 seconds under the pressure of ~ 3 ton and the temperature of 50 ~ 180 ℃.
도 2 및 도 4의 백색 발광소자는 액체수지를 이용하여 형성한 예로서, 액체수지에 (Sr,Ba)2SiO4:Eu 형광 안료를 10 ~ 50 % 혼합하여 믹싱(Mixing) 한 후 디스펜서로 몰딩 또는 스크린 인쇄하여 형성한다.The white light emitting device of FIGS. 2 and 4 is an example formed using a liquid resin, and mixed with 10-50% of (Sr, Ba) 2 SiO 4 : Eu fluorescent pigment in a liquid resin, followed by mixing with a dispenser. Form by molding or screen printing.
상기 형광물질층(2)을 액체수지를 이용할 경우의 또 다른 예로는 액체수지에 실리콘(Si)과 고체분말수지를 15 : 1 : 4 정도의 비율로 혼합한 후, 여기에 (Sr,Ba)2SiO4:Eu 형광 안료를 1 ~ 50 %를 혼합하고 믹싱하여 몰딩하는 방법이 있다. 상기에서 실리콘(Si)은 상기 형광물질층(2)과 발광칩(3)의 완충작용을 위해 첨가하고, 상기 고체분말수지는 고체수지에 형광물질을 첨가할 때 사용하는 것과 동일한 종류의 것으로서 여기서 고체분말수지는 액체수지와 혼합하였을 때 경화를 촉진한다.Another example of the case where the fluorescent material layer 2 uses a liquid resin is after mixing silicon (Si) and a solid powder resin in a ratio of about 15: 1: 1 to the liquid resin, and then (Sr, Ba) There is a method of mixing and mixing 2 SiO 4 : Eu fluorescent pigments with 1 to 50% and molding them. In the above, silicon (Si) is added to buffer the fluorescent material layer (2) and the light emitting chip (3), and the solid powder resin is the same kind as used when adding a fluorescent material to a solid resin. Solid powder resins promote curing when mixed with liquid resins.
첨부된 도면에서 도 1은 칩 발광다이오드(Chip LED), 도 2는 탑 발광다이오드(Top LED), 도 3은 램프 발광다이오드(Lamp LED) 그리고, 도 4는 COB(Chip On Board)를 개략적으로 도시한 단면도로서, 각각의 구조에 맞춘 인쇄회로기판 또는 리드프레임 상에 외부와 전기적으로 도전되도록 청색 또는 가시광 영역의 발광파장을 갖는 발광칩을 실장한 후, 상기 발광칩을 덮도록 액체 또는 고체수지에 (Sr,Ba)2SiO4:Eu 형광 안료를 포함시킨 형광물질층을 형성하는 본 발명의 실시 예를 적용하여 각각의 목적과 쓰임새에 맞춘 다양한 백색 발광소자를 제조할 수 있다.In the accompanying drawings, FIG. 1 shows a chip LED, FIG. 2 shows a top LED, FIG. 3 shows a lamp LED, and FIG. 4 schematically shows a chip on board. As a cross-sectional view of the present invention, a light emitting chip having a light emission wavelength in a blue or visible light region is mounted on a printed circuit board or lead frame according to each structure, and then the liquid or solid resin is covered to cover the light emitting chip. By applying an embodiment of the present invention to form a fluorescent material layer containing (Sr, Ba) 2 SiO 4 : Eu fluorescent pigment in the various white light emitting device can be manufactured to suit each purpose and purpose.
도 5는 본 발명의 실시 예에 적용된 (Sr,Ba)2SiO4:Eu 형광 안료의 발광 특성 테이터로, 상기 형광 안료의 고체시료에 45˚방향으로 광을 쏘아주어 여기되는 파장 변화를 도시하는 그래프이다.FIG. 5 is a light emission characteristic data of (Sr, Ba) 2 SiO 4 : Eu fluorescent pigment applied to an embodiment of the present invention, and illustrates a wavelength change excited by emitting light in a 45 ° direction to a solid sample of the fluorescent pigment. It is a graph.
도시된 바와 같이 상기 형광 안료는 250 ~ 500 nm 범위의 빛을 여기시킴을 알 수 있다. 즉 상기 (Sr,Ba)2SiO4:Eu를 형장 안료로 사용하였을 때, 발광칩은 일부 가시광 영역에서부터 자외선 영역에 이르는 파장 범위의 것을 제한 없이 이용할 수 있음을 알 수 있다. 따라서, 도 1 내지 도 4에는 발광칩을 하나를 이용하여 제조한 백색 발광소자를 도시하였으나, 각각 파장이 다른 두 개 이상의 발광칩을 집적시켜몰딩한 백색 발광소자의 제작에도 적용이 가능하다.As shown, it can be seen that the fluorescent pigment excites light in the range of 250 to 500 nm. That is, when the (Sr, Ba) 2 SiO 4 : Eu is used as a shape pigment, it can be seen that the light emitting chip can be used without limitation in the wavelength range from some visible light region to the ultraviolet region. Thus, although FIG. 1 to FIG. 4 illustrate a white light emitting device manufactured by using one light emitting chip, the present invention is also applicable to fabrication of a white light emitting device in which two or more light emitting chips having different wavelengths are integrated and molded.
도 6은 본 발명의 일 실시 예로 470 nm 청색 발광다이오드 칩에 (Sr,Ba)2SiO4:Eu 형광 안료를 도포하여 제조한 백색 발광소자의 스펙트로미터 데이터이다.FIG. 6 is spectrometer data of a white light emitting device manufactured by coating a (Sr, Ba) 2 SiO 4 : Eu fluorescent pigment on a 470 nm blue light emitting diode chip according to an embodiment of the present invention.
도시된 바와 같이 청색 발광칩에서 나오는 450 ~ 500 nm의 청색광과 여기된 형광 안료의 550 ~ 620 nm의 노란색광이 혼합되어 백색광을 얻었음을 알 수 있다.As shown, it can be seen that 450 to 500 nm of blue light emitted from the blue light emitting chip and yellow light of 550 to 620 nm of the excited fluorescent pigment were mixed to obtain white light.
상술한 바와 같이 본 발명은 청색 발광칩 뿐만 아니라 광원파워가 큰 자외선 발광칩을 이용하여 백색 발광소자를 제조하여 여기 광원칩의 파장범위 변화에 민감하지 않은 안정된 고휘도의 백색 발광소자를 얻을 수 있는 이점이 있다.As described above, the present invention manufactures a white light emitting device using not only a blue light emitting chip but also an ultraviolet light emitting chip having a large light source power, thereby obtaining a stable high luminance white light emitting device which is not sensitive to a change in the wavelength range of the excitation light source chip. There is this.
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KR100771806B1 (en) * | 2005-12-20 | 2007-10-30 | 삼성전기주식회사 | White light emitting device |
KR101047795B1 (en) * | 2005-01-05 | 2011-07-07 | 엘지이노텍 주식회사 | Semiconductor light emitting device |
KR20150098350A (en) * | 2014-02-20 | 2015-08-28 | 엘지이노텍 주식회사 | Light Emitting Device Package |
KR20160055417A (en) * | 2014-11-10 | 2016-05-18 | 엘지이노텍 주식회사 | Light emitting device pachage and lighting system having the same |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
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KR101047795B1 (en) * | 2005-01-05 | 2011-07-07 | 엘지이노텍 주식회사 | Semiconductor light emitting device |
KR100771806B1 (en) * | 2005-12-20 | 2007-10-30 | 삼성전기주식회사 | White light emitting device |
KR20150098350A (en) * | 2014-02-20 | 2015-08-28 | 엘지이노텍 주식회사 | Light Emitting Device Package |
KR20160055417A (en) * | 2014-11-10 | 2016-05-18 | 엘지이노텍 주식회사 | Light emitting device pachage and lighting system having the same |
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