KR20030050359A - Mauufacturing method of adhesion paste for coating induding colored acryl resin composed by exothermic polymering ation and the manufactured adhesion paste - Google Patents
Mauufacturing method of adhesion paste for coating induding colored acryl resin composed by exothermic polymering ation and the manufactured adhesion paste Download PDFInfo
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- KR20030050359A KR20030050359A KR1020010080780A KR20010080780A KR20030050359A KR 20030050359 A KR20030050359 A KR 20030050359A KR 1020010080780 A KR1020010080780 A KR 1020010080780A KR 20010080780 A KR20010080780 A KR 20010080780A KR 20030050359 A KR20030050359 A KR 20030050359A
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- acrylic resin
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- coating
- exothermic
- adhesive
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J121/00—Adhesives based on unspecified rubbers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
Description
본 발명은 발열중합반응을 이용한 유색아크릴수지를 함유한 코팅용 점착제의제조방법 및 그 방법에 의해 제조된 점착제에 관한 것으로, 더욱 구체적으로 설명하면, 탈색 또는 변색이 없는 반영구적으로 색상을 유지하는 것이 가능하게 되어 점착제의 상품성을 향상시키며 다양한 용도로 사용가능한 점착제를 제조가능하도록 일정온도로 예열된 투명한 아크릴수지에 소정의 염료 또는 안료를 첨가하여 교반시키면발열반응에 의하여 투명한 아크릴수지가 중합되면서 투명한 아크릴수지가 유색아크릴수지가 되어 이를 수용성점착제인 라텍스에 희석시켜 제조되는 발열중합반응을 이용한 유색아크릴수지를 함유한 점착제의 제조방법 및 그 방법에 의하여 제조된 점착제에 관한 것으로 점착제가 투명하지않고 다양한 색상을 가지게 되므로서 투명한 비닐표지를 갖는 앨범이나 그 밖의 다른 용도에도 널리 쓰이는 것이 가능한 활용도가 넓은 발열중합반응을 이용한 유색아크릴수지를 함유한 점착제의 제조방법 및 그 방법에 의해 제조된 점착제에 관한 것이다.The present invention relates to a method for preparing a pressure-sensitive adhesive for coating containing colored acrylic resin and a pressure-sensitive adhesive prepared by the method, and more specifically, to maintain color semi-permanently without discoloration or discoloration. It is possible to improve the commerciality of the pressure-sensitive adhesive and to add a predetermined dye or pigment to a transparent acrylic resin preheated to a certain temperature to prepare a pressure-sensitive adhesive that can be used for a variety of uses, the transparent acrylic resin is polymerized by the exothermic reaction and the transparent acrylic The present invention relates to a method for preparing an adhesive containing a colored acrylic resin using an exothermic polymerization reaction prepared by diluting the resin into a colored acrylic resin, which is diluted with a water-soluble adhesive latex, and a pressure-sensitive adhesive prepared by the method. Transparent rain The possible utilization is widely used in the album or any other use has a cover relates to a pressure-sensitive adhesive produced by the process and method of the pressure-sensitive adhesive containing an acrylic resin colored by a large exothermic polymerization reaction.
일반적으로 앨범의 대지에 코팅되는 코팅용 점착제는 무색투명한 코팅용 라텍스가 널리 이용되고 있다. 이러한 무색투명한 코팅용 라텍스는 색소나 안료를 첨가할 경우 균일한 질감을 갖는 색상을 안출하기가 용히하지 않으며 변색 및 탈색이 쉽게 발생된다는 문제점이 있다. 또한, 일반적으로 사용되는 앨범용 대지는 백색의 두꺼운 용지의 표면과 이면에 점착제를 도포하고 이러한 대지의 표면과 이면에 투명한 염화비닐이 탈착가능하게 부착시켜 투명한 염화비닐과 대지사이에 사진을 끼우고 염화비닐이 점착층에 부착되어 사진을 고정시키나, 이러한 앨범용 대지는 백색의 용지만이 사용되므로 앨범이 단조롭게 되므로 다양한 색상을 갖게 할 수 없으며, 다양한 색상으로 인쇄하기 위해서는 앨범용 대지의 제조과정이 복잡하게 되고대지의 제조비용이 기하급수적으로 높게 되므로 대지를 다양한 색상으로 인쇄하는 것은 과다한 비용이 들게 되는 문제점이 있었다.Generally, a pressure-sensitive adhesive for coating coated on the album is widely used latex for colorless and transparent coating. Such a colorless and transparent coating latex is not easy to produce a color having a uniform texture when a pigment or pigment is added, there is a problem that discoloration and discoloration easily occur. In addition, the album board generally used is coated with a pressure-sensitive adhesive on the surface and the back side of the white thick paper, and transparent vinyl chloride is detachably attached to the surface and the back side of the sheet so that a picture is sandwiched between the transparent vinyl chloride and the sheet. Vinyl chloride is attached to the adhesive layer to fix the photo, but since the album sheet is made of white paper, the album is monotonous and cannot have various colors. Since it becomes complicated and the manufacturing cost of the earth becomes exponentially high, printing the earth in various colors has an excessive cost.
본 발명의 목적은 이러한 문제점을 해결하기 위한 것으로, 앨범용 대지에 필수적으로 코팅되는 점착층을 탈색 또는 변색이 없이 반영구적으로 착색되는 다양한 색상으로 코팅하는 것이 가능하게 되어 다양한 색상을 갖는 앨범용 대지를 용이하게 코팅하는 것이 가능한 발열중합반응을 이용한 유색아크릴수지를 함유한 점착제의 제조방법 및 그 방법에 의하여 제조된 점착제를 제공하는 것이다.An object of the present invention is to solve this problem, it is possible to coat the adhesive layer which is essentially coated on the sheet for the album in a variety of colors that are semi-permanently colored without discoloration or discoloration, the mount for the album having a variety of colors It is to provide a method for producing a pressure-sensitive adhesive containing a colored acrylic resin using an exothermic polymerization reaction that can be easily coated and a pressure-sensitive adhesive prepared by the method.
본 발명의 이러한 목적은 일정한 온도로 예열된 투명한 아크릴수지에 염료 또는 안료를 첨가하여 발열반응에 의하여 중합되면서 투명한 아크릴수지가 유색아크릴수지가 되어 이를 수용성점착제인 라텍스에 희석시켜 제조되는 본 발명에 따른 발열중합반응을 이용한 유색아크릴수지를 함유한 점착제의 제조방법 및 그 방법에 의하여 제조된 점착제에 의하여 달성된다.The object of the present invention is to add a dye or pigment to the transparent acrylic resin preheated to a certain temperature, polymerized by exothermic reaction and the transparent acrylic resin is colored acrylic resin prepared according to the present invention by diluting it in latex which is a water-soluble adhesive It is achieved by a method for producing a pressure-sensitive adhesive containing a colored acrylic resin using an exothermic polymerization reaction and the pressure-sensitive adhesive prepared by the method.
본 발명에 따른 발열중합반응을 이용한 유색아크릴수지를 함유한 점착제의 제조방법 및 그 방법에 의하여 제조된 점착제를 이하에 상세히 기술되는 실시예에 의하여 그 특징 및 장점들을 보다 명백하게 이해할 수 있을 것이다.The method and method of preparing a pressure-sensitive adhesive containing colored acrylic resin using the exothermic polymerization reaction according to the present invention and the pressure-sensitive adhesive prepared by the method will be more clearly understood by the embodiments described below.
도1은 본 발명에 따른 발열중합반응을 이용한 유색아크릴수지를 함유한 점착제로 코팅된 앨범용 대지를 사용한 앨범의 사시도1 is a perspective view of an album using a sheet for the album coated with a pressure-sensitive adhesive containing a colored acrylic resin using an exothermic polymerization reaction according to the present invention
도2는 도1에 도시된 앨범의 앨범용 대지의 부분확대종단면도FIG. 2 is an enlarged vertical sectional view of the album sheet of the album shown in FIG.
* 도면의 주요부분에 대한 부호의 설명 *Explanation of symbols on the main parts of the drawings
1. 앨범용 대지 2. 점착층1. Album board 2. Adhesive layer
본 발명의 일실시예에 따른 발열중합반응을 이용한 유색아크릴수지를 함유한 점착제의 제조방법은 투명한 아크릴수지를 50℃~80℃로 예열시키고 예열된 투명한 아크릴수지에 색소나 안료를 혼합하고 2내지 4시간 교반시키면서 발열에 의한 중합반응을 유도하여 유색아크릴수지를 제조하는 제1단계와, 중합반응에 의하여 제조된 상기 유색아크릴수지를 라텍스에 희석하여 유색의 코팅용 점착제를 제조하는 제2단계를 포함한다.According to an embodiment of the present invention, a method of preparing a pressure-sensitive adhesive containing a colored acrylic resin using a pyrolytic polymerization reaction may be performed by preheating a transparent acrylic resin to 50 ° C. to 80 ° C., mixing a pigment or a pigment with a preheated transparent acrylic resin, and adding 2 to The first step of preparing a colored acrylic resin by inducing a polymerization reaction by heating with stirring for 4 hours and the second step of preparing a colored coating adhesive by diluting the colored acrylic resin prepared by a polymerization reaction in latex Include.
실시예1Example 1
투명한 아크릴수지를 70℃로 예열하고 예열된 아크릴수지 99.8wt%에 핑크색 안료0.2wt%를 혼합하고 이를 약 3시간 교반시키면 발열에 의한 중합반응이 유도시키어 원하는 색상이 발휘되는가를 판단하여 중합전후처리를 하여 핑크색아크릴수지가 제조되고, 중합반응에 의하여 유도된 핑크색아크릴수지40wt%를 라텍스 60wt%에 희석시켜 핑크색 코팅용 점착제를 제조하였다. 상기 안료는 고속교반기에서 5000rpm이상으로 회전되면서 투명한 아크릴수지에 교반되게 된다. 또한, 상기 핑크색 아크릴수지도 라텍스에 희석되어 교반기에서 5000rpm이상으로 교반되어 제조된다.After preheating the transparent acrylic resin to 70 ℃ and mixing 0.2wt% of the pink pigment with 99.8wt% of the preheated acrylic resin and stirring it for about 3 hours, the polymerization reaction is induced by exotherm to determine whether the desired color is exhibited. The pink acrylic resin was prepared, and the pink acrylic resin 40 wt% induced by the polymerization reaction was diluted in 60 wt% of latex to prepare a pink coating adhesive. The pigment is stirred in a transparent acrylic resin while rotating at 5000 rpm or more in a high speed stirrer. In addition, the pink acrylic resin is also prepared by diluting in latex and stirring at 5000rpm or more in a stirrer.
상기 실시예에서는 안료가 0.2wt%가 혼합되었으나 필요한 색상의 농도차이에 따라 중합되는 과정에서 중합전후처리에 의하여 투여량이 증감되는등의 투여량이 달라질 수 있을 것이며, 핑크색 아크릴수지와 라텍스의 희석비율이 2:3으로 실시되었으나 원하는 점착제의 물성에 따라 변화될 수 있을 것이다.In the above embodiment, 0.2 wt% of the pigment is mixed, but the dosage may be changed by the pre and post-polymerization treatment in the process of polymerization according to the concentration difference of the required color, and the dilution ratio of the pink acrylic resin and the latex is 2: 2 but may be changed depending on the properties of the desired pressure-sensitive adhesive.
이와같이 제조된 본 발명에 따른 점착제를 사용하여 앨범용 대지(1)에 코팅할 경우 앨범용 대지상에 유색의 점착제를 코팅하면 앨범용 대지(1)상에는 자연스럽게 유색으로 착색된 점착층(2)이 도포되므로 용이하게 원하는 색상으로 앨범용 대지를 코팅할 수 있게 되는 것이다.When coating on the album sheet (1) using the adhesive according to the present invention prepared in this way, when the colored adhesive is coated on the album sheet, the adhesive layer (2) colored naturally colored on the album sheet (1) is applied. It will be easy to coat the pasteboard for the album in the desired color.
본 발명에서는 앨범용 대지를 코팅하는 것만을 기술하였으나 그 밖에 다른 용도로도 널리 사용할 수 있음은 물론이다.In the present invention, only the coating of the mount for the album is described, but can be widely used for other purposes as well.
이상과 같이 본 발명에 따른 발열중합반응을 이용한 유색아크릴수지를 함유한 코팅용 점착제의 제조방법 및 그 방법에 의해 제조된 점착제는 투명한 아크릴수지에 소정의 색소 또는 안료를 첨가하여 발열반응에 의하여 중합되면서 투명한 아크릴수지가 유색아크릴수지가 되어 이를 수용성점착제인 라텍스에 희석시켜 제조되므로서 용이하게 점착제의 착색이 가능하게 되어 저렴하면서도 탈색이나 변색이 없는 반영구적으로 색상이 지속되는 양질의 점착제를 공급하는 것이 가능함과 아울러 점착제의 상품성을 향상시키며 다양한 용도로 사용이 가능하다.As described above, a method for preparing a pressure-sensitive adhesive for coating containing a colored acrylic resin using an exothermic polymerization reaction according to the present invention and a pressure-sensitive adhesive prepared by the method polymerize by exothermic reaction by adding a predetermined pigment or pigment to a transparent acrylic resin. As the transparent acrylic resin becomes colored acrylic resin and is diluted with latex, which is a water-soluble adhesive, it is possible to easily color the adhesive, so it is inexpensive to supply a high quality adhesive that lasts semi-permanently without discoloration or discoloration. In addition to improving the commercialization of the pressure-sensitive adhesive can be used for various purposes.
Claims (2)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020010080780A KR20030050359A (en) | 2001-12-18 | 2001-12-18 | Mauufacturing method of adhesion paste for coating induding colored acryl resin composed by exothermic polymering ation and the manufactured adhesion paste |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020010080780A KR20030050359A (en) | 2001-12-18 | 2001-12-18 | Mauufacturing method of adhesion paste for coating induding colored acryl resin composed by exothermic polymering ation and the manufactured adhesion paste |
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| Publication Number | Publication Date |
|---|---|
| KR20030050359A true KR20030050359A (en) | 2003-06-25 |
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| Application Number | Title | Priority Date | Filing Date |
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| KR1020010080780A KR20030050359A (en) | 2001-12-18 | 2001-12-18 | Mauufacturing method of adhesion paste for coating induding colored acryl resin composed by exothermic polymering ation and the manufactured adhesion paste |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR950012769A (en) * | 1993-10-14 | 1995-05-17 | 에프. 제이. 스미트 | Semiconductor device |
| WO2000023285A1 (en) * | 1998-10-22 | 2000-04-27 | H.B. Fuller Licensing & Financing, Inc. | Photo album page adhesive with color stability |
| KR20000059816A (en) * | 1999-03-09 | 2000-10-05 | 한형수 | Acrylic emulsion adhesive composition for album |
| KR200268693Y1 (en) * | 2001-12-18 | 2002-03-18 | 박명원 | Album backing paper coated colored adhesion paste composed by colored acryl resin |
| KR100362531B1 (en) * | 2000-10-09 | 2002-11-29 | 한국신발피혁연구소 | Method of stopping discoloration of latex-tackifier composite for album |
| KR20030044209A (en) * | 2001-11-29 | 2003-06-09 | 서석홍 | Manufacturing method for adhesive |
-
2001
- 2001-12-18 KR KR1020010080780A patent/KR20030050359A/en not_active Application Discontinuation
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR950012769A (en) * | 1993-10-14 | 1995-05-17 | 에프. 제이. 스미트 | Semiconductor device |
| WO2000023285A1 (en) * | 1998-10-22 | 2000-04-27 | H.B. Fuller Licensing & Financing, Inc. | Photo album page adhesive with color stability |
| KR20000059816A (en) * | 1999-03-09 | 2000-10-05 | 한형수 | Acrylic emulsion adhesive composition for album |
| KR100362531B1 (en) * | 2000-10-09 | 2002-11-29 | 한국신발피혁연구소 | Method of stopping discoloration of latex-tackifier composite for album |
| KR20030044209A (en) * | 2001-11-29 | 2003-06-09 | 서석홍 | Manufacturing method for adhesive |
| KR200268693Y1 (en) * | 2001-12-18 | 2002-03-18 | 박명원 | Album backing paper coated colored adhesion paste composed by colored acryl resin |
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