KR20030047259A - Aqua stick cosmetic composition - Google Patents

Aqua stick cosmetic composition Download PDF

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Publication number
KR20030047259A
KR20030047259A KR1020010077706A KR20010077706A KR20030047259A KR 20030047259 A KR20030047259 A KR 20030047259A KR 1020010077706 A KR1020010077706 A KR 1020010077706A KR 20010077706 A KR20010077706 A KR 20010077706A KR 20030047259 A KR20030047259 A KR 20030047259A
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South Korea
Prior art keywords
water
cosmetic composition
weight
parts
liquid oil
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KR1020010077706A
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Korean (ko)
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신현종
윤명석
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주식회사 엘지생활건강
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Priority to KR1020010077706A priority Critical patent/KR20030047259A/en
Publication of KR20030047259A publication Critical patent/KR20030047259A/en

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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/817Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
    • A61K8/8182Copolymers of vinyl-pyrrolidones. Compositions of derivatives of such polymers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02Preparations containing skin colorants, e.g. pigments

Abstract

PURPOSE: An aqueous solid cosmetic composition obtained by solidifying polyethylene glycol wax derivatives and water and blending with a PVP/eicosene copolymer and liquid oil is provided. Therefore, the cosmetic composition has excellent water resistance while providing sufficient freshness and moisturization when applied to the skin. CONSTITUTION: An aqueous solid cosmetic composition contains 1 to 50 parts by weight of polyethylene glycol wax derivatives, 5 to 80 parts by weight of water 0.1 to 30 parts by weight of a PVP/eicosene copolymer and 1 to 50 parts by weight of liquid oil. The liquid oil is selected from the group consisting of hydrocarbon-based liquid oil, ester-based liquid oil, lower alcohol and a mixture thereof. The composition is formulated into a foundation, an eye shadow, a lip stick or the like.

Description

수성 고형 화장료 조성물{Aqua stick cosmetic composition}Aqueous solid cosmetic composition

본 발명은 수성 고형 화장료 조성물에 관한 것으로서, 보다 상세하게는 피부에 도포시 충분한 청량감과 촉촉함이 부여될 뿐만 아니라, 내수성도 우수하여 화장 지속성이 양호한 수성 고형 화장료 조성물에 관한 것이다.The present invention relates to an aqueous solid cosmetic composition, and more particularly, to an aqueous solid cosmetic composition which is not only imparted with a sufficient refreshing feeling and moist feeling when applied to the skin, but also excellent in water resistance and has good makeup sustainability.

파운데이션, 아이섀도, 립스틱 등의 화장료의 제형은 파우더 타입이나 유성 타입이 일반적인데, 물을 함유하는 화장료는 극히 제한적으로 제조된다. 또한, 물을 함유하는 화장료라도 유중수형 화장료를 고형화시킨 제형이 대부분이다. 이는 수중유형타입의 화장료의 경우 외상인 물을 고형화시키기 어렵기 때문에 때문이다. 유중수형 화장료의 경우, 고형화가 용이하다는 장점이 있으나, 물의 배합량이 증가하면 내상의 점도가 상승하고, 제형 안정성이 저하되는 등의 문제가 발생하므로 물을 다량 배합하기 어렵다. 따라서, 수중유형 화장료에 비해 청량감, 촉촉함 등이 상대적으로 떨어지는 결점이 있다. 한편, 수중유형의 화장료의 경우, 유중수형의 고형화제인 왁스에 해당하는 적절한 고형화제를 발견하지 못하여 액상 또는 크림상의 제형으로 제조되었으나, 이러한 제형은 휴대성이 좋지 못할 뿐만 아니라 내수성이 떨어져 피부에 도포시 화장 지속성이 불량하다는 단점이 있다.Formulations of cosmetics such as foundation, eye shadow, lipstick, etc. are generally powder or oil type, but cosmetics containing water are extremely limited. Moreover, even the cosmetics containing water are the formulation which solidified the water-in-oil cosmetics. This is because it is difficult to solidify the water in the case of the oil-in-water type cosmetics. In the case of water-in-oil cosmetics, there is an advantage that it is easy to solidify, but when the amount of water is increased, it is difficult to mix a large amount of water since problems such as an increase in viscosity of the inner phase and a decrease in formulation stability occur. Therefore, compared with the oil-in-water cosmetics, there is a disadvantage that the refreshing, moist and the like is relatively inferior. On the other hand, in the case of oil-in-water cosmetics, it was prepared as a liquid or cream formulation because it did not find an appropriate solidifying agent corresponding to wax as a water-in-oil solidifying agent, but such a formulation is not only poorly portable but also has poor water resistance and is applied to the skin. There is a disadvantage that makeup persistence is poor.

물을 함유하는 고형 화장료 조성물에 대한 종래 문헌들을 살펴보면 다음과 같다. 일본공개특허 소64-79104호에는 실리콘오일, 고형 왁스, 물, 폴리옥시알킬렌 변성 오르가노폴리실록산(organopolysiloxane)을 함유하는 유중수형 유화 조성물이 개시되어 있다. 그러나, 이러한 조성물은 외상에 유분, 유성 고화제를 배합하므로 수중유형 조성물에 비해 끈적임이 있는 등 청량감과 산뜻함이 떨어진다. 일본공개특허 평3-166367호에는 양성 계면활성제와 고급지방산으로 물불용성 복합체를 형성하여 유화 안정성을 확보하고 있으나, 이 또한 신선함, 산뜻함 등이 불량하다.Looking at the conventional literature on a solid cosmetic composition containing water as follows. Japanese Patent Application Laid-Open No. 64-79104 discloses a water-in-oil emulsion composition containing silicone oil, solid wax, water, and polyoxyalkylene-modified organopolysiloxane. However, since such a composition mixes oil and an oil-based hardener on the outer phase, it is inferior in refreshing feeling and neatness such as stickiness compared to the oil-in-water type composition. In Japanese Patent Laid-Open No. 3-166367, water-insoluble complexes are formed with amphoteric surfactants and higher fatty acids to secure emulsification stability, but this is also poor in freshness and freshness.

한편, 일본공개특허 평3-279319호에는 지방산 비누로 외상의 물을 고화시키는 방법이 개시되어 있으나, 이 조성물은 비누를 다량 함유하고 있어 PH가 높으므로, 피부자극성과 안전성에 문제가 있다. 또한, 일본공개특허 평5-178723호 및 평7-17828호에는 한천과 같은 수용성 고분자, 셀룰로오스유도체 및 수용성 점착제를 병용한 고형 화장료를 개시하고 있다. 그러나, 이러한 화장료는 충분한 경도를 형성시키지 못한다.On the other hand, Japanese Patent Laid-Open No. 3-279319 discloses a method of solidifying the water of the trauma with fatty acid soap, but this composition contains a large amount of soap, so the pH is high, there is a problem in skin irritation and safety. In addition, Japanese Patent Laid-Open Nos. Hei 5-178723 and Hei 7-17828 disclose solid cosmetics using water-soluble polymers such as agar, cellulose derivatives and water-soluble adhesives in combination. However, these cosmetics do not form sufficient hardness.

따라서, 본 발명이 이루고자 하는 기술적 과제는 상기 문제점을 해결하여 수성 고형화제인 폴리에칠렌글리콜 밀납 유도체를 사용하여 다량의 물을 고형화시키고, 유성 고분자 성분인 피브이피/에이코신 공중합체(PVP/Eicosene Copolymer)와 액상오일을 안정하게 배합하므로서, 피부에 도포시 충분한 청량감과 촉촉함이 부여될 뿐만 아니라, 내수성도 우수하여 화장 지속성이 양호한 수성 고형 화장료 조성물을 제공하는데 있다.Accordingly, the technical problem to be achieved by the present invention is to solve the above problems and to solidify a large amount of water using a polyethylene glycol beeswax derivative which is an aqueous solidifying agent, PVP / Eicosene Copolymer (PVP / Eicosene Copolymer) By stably blending the liquid oil, not only is it provided with a refreshing feeling and a moist feeling when applied to the skin, but also excellent in water resistance to provide an aqueous solid cosmetic composition having good makeup durability.

상기와 같은 목적을 달성하기 위해, 본 발명은 폴리에틸렌글리콜 밀납 유도체 1 내지 50중량부, 물 5 내지 80중량부, 피브이피/에이코신 공중합체 0.1 내지 30중량부 및 액상 오일 1 내지 50중량부를 함유하는 것을 특징으로 하는 수성 고형 화장료 조성물을 제공한다.In order to achieve the above object, the present invention contains 1 to 50 parts by weight of polyethylene glycol beeswax derivative, 5 to 80 parts by weight of water, 0.1 to 30 parts by weight of the fib / Eicosine copolymer and 1 to 50 parts by weight of liquid oil It provides an aqueous solid cosmetic composition, characterized in that.

본 발명의 수성 고형 화장료 조성물에 있어서, 액상 오일로는 탄화수소계 액상 오일, 에스테르계 액상 오일, 고급 알코올 등의 비휘발성 액상 오일을 단독으로 또는 혼합하여 사용할 수 있다.In the aqueous solid cosmetic composition of the present invention, as the liquid oil, nonvolatile liquid oils such as hydrocarbon-based liquid oils, ester-based liquid oils and higher alcohols may be used alone or in combination.

이하, 본 발명의 수성 고형 화장료 조성물에 대하여 상세히 설명한다.Hereinafter, the aqueous solid cosmetic composition of the present invention will be described in detail.

본 발명에 따른 수성 고형 화장료 조성물은 폴리에틸렌글리콜 밀납 유도체 1 내지 50중량부, 물 5 내지 80중량부, 피브이피/에이코신 공중합체 0.1 내지 30중량부 및 액상 오일 1 내지 50중량부를 함유한다.The aqueous solid cosmetic composition according to the present invention contains 1 to 50 parts by weight of polyethylene glycol beeswax derivative, 5 to 80 parts by weight of water, 0.1 to 30 parts by weight of fib / eicosine copolymer and 1 to 50 parts by weight of liquid oil.

본 발명에 따른 수성 고형 화장료 조성물에 함유되는 폴리에칠렌글리콜 밀납 유도체는 에칠렌옥사이드가 밀납(Bees' Wax)에 부가중합되어 이루어진 유도체를 말하는데, 에칠렌옥사이드의 평균부가 몰(mole) 수가 6 내지 20인 것이 바람직하다. 이러한 폴리에칠렌글리콜 밀납 유도체는 수성 고형 화장료 조성물에 다량 함유되는 물과 그 외 보습제 등의 수상 성분을 고형화시키는 기능을 나타낸다. 수성 고형 화장료 조성물에 함유되는 폴리에칠렌글리콜 밀납 유도체의 함량이 1중량부 미만이면 적정한 경도를 형성하기 어렵고, 50중량부를 초과하면 경도가 너무 높아 사용성이 만족스럽지 못하다.Polyethylene glycol beeswax derivatives contained in the aqueous solid cosmetic composition according to the present invention refers to a derivative formed by addition polymerization of ethylene oxide to bees'wax, preferably having an average mole number of 6 to 20 moles of ethylene oxide. Do. Such a polyethylene glycol beeswax derivative exhibits a function of solidifying water-based components such as water and other moisturizers contained in a large amount in the aqueous solid cosmetic composition. If the content of the polystyrene glycol beeswax derivative contained in the aqueous solid cosmetic composition is less than 1 part by weight, it is difficult to form an appropriate hardness. If it exceeds 50 parts by weight, the hardness is too high and the usability is not satisfactory.

본 발명에 따른 수성 고형 화장료 조성물에 함유되는 물은 주된 수상성분으로서 보습제 등을 더 첨가하여 사용할 수 있다. 수성 고형 화장료 조성물에 함유되는 물의 함량이 5중량부 미만이면 청량감, 촉촉함을 충분히 부여하지 못하고, 80중량부를 초과하면 적정한 경도형성이 어렵다.The water contained in the aqueous solid cosmetic composition according to the present invention can be used by further adding a moisturizer or the like as a main aqueous phase component. If the amount of water contained in the aqueous solid cosmetic composition is less than 5 parts by weight, it does not sufficiently provide a refreshing feeling and moist feeling. If it exceeds 80 parts by weight, it is difficult to form an appropriate hardness.

또한, 본 발명의 수성 고형 화장료 조성물에 함유되는 유성 고분자인 피브이피/에이코신 공중합체는 액상 오일과 함께 피부에 도포시, 피부 위에 내수성 피막을 형성하므로써 종래의 수성 고형 화장료 조성물의 단점인 내수성 불량을 개선한다. 수성 고형 화장료 조성물에 함유되는 피브이피/에이코신 공중합체의 함량이 0.1중량부 미만이면 충분한 내수성을 나타내기 어렵고, 30중량부를 초과하면 사용감이 저하되어 부드럽지 못하다.In addition, the fibpy / Eicosine copolymer, which is an oil-based polymer contained in the aqueous solid cosmetic composition of the present invention, when applied to the skin together with liquid oil, forms a water-resistant coating on the skin, thereby impairing water resistance, which is a disadvantage of the conventional aqueous solid cosmetic composition. To improve. If the content of the fip / eicosine copolymer contained in the aqueous solid cosmetic composition is less than 0.1 part by weight, it is difficult to exhibit sufficient water resistance. If it exceeds 30 parts by weight, the feeling of use decreases and it is not soft.

또한, 본 발명의 수성 고형 화장료 조성물에 함유되는 액상 오일로는 상온에서 액상인 탄화수소계 액상 오일, 에스테르계 액상 오일, 고급 알코올과 같은 비휘발성 액상 오일을 사용하는 것이 바람직하다. 이러한 탄화수소계 액상 오일로는 유동파라핀, 스쿠알란 등이 있으며, 에스테르계 액상 오일로는 17 내지 38의 탄소수를 갖는 오일을 사용하는 것이 바람직하다. 수성 고형 화장료 조성물에 함유되는 액상 오일의 함량이 1중량부 미만이면 내수성 및 사용감이 저하되고, 50중량부를 초과하면 청량감이 저하되며 적정한 경도확보가 어렵다.In addition, as the liquid oil contained in the aqueous solid cosmetic composition of the present invention, it is preferable to use non-volatile liquid oils such as hydrocarbon-based liquid oils, ester-based liquid oils and higher alcohols which are liquid at room temperature. Such hydrocarbon-based liquid oils include liquid paraffin, squalane and the like, and it is preferable to use an oil having 17 to 38 carbon atoms as the ester-based liquid oil. If the content of the liquid oil contained in the aqueous solid cosmetic composition is less than 1 part by weight, water resistance and usability are reduced, and if it exceeds 50 parts by weight, the cooling feeling is lowered and it is difficult to secure proper hardness.

이 외에도, 본 발명의 수성 고형 화장료 조성물에는 본 발명의 목적을 저해하지 않는 한도 내에서 여러 물질, 예를 들어 보습제, 체질 안료, 색소, 자외선 차단제, 변색 방지제, 산화 방지제 등을 적량 첨가할 수 있으며, 사용 목적에 따라파운데이션, 아이새도, 립스틱 등의 다양한 제형으로 제조될 수 있다.In addition to the aqueous solid cosmetic composition of the present invention, various substances such as humectants, extender pigments, pigments, sunscreens, anti-tarnish agents, antioxidants, and the like can be appropriately added to the extent not impairing the object of the present invention. Depending on the purpose of use, it can be prepared in various formulations, such as foundation, eye shadow, lipstick.

이하, 본 발명을 구체적으로 설명하기 위해 실시예를 들어 상세하게 설명하기로 한다. 그러나, 본 발명에 따른 실시예들은 여러 가지 다른 형태로 변형될 수 있으며, 본 발명의 범위가 아래에서 상술하는 실시예들에 한정되는 것으로 해석되어져서는 안 된다. 본 발명의 실시예들은 당업계에서 평균적인 지식을 가진 자에게 본 발명을 보다 완전하게 설명하기 위해서 제공되어지는 것이다.Hereinafter, the present invention will be described in detail with reference to Examples. However, embodiments according to the present invention can be modified in many different forms, the scope of the invention should not be construed as limited to the embodiments described below. Embodiments of the present invention are provided to more completely explain the present invention to those skilled in the art.

실시예 1 ~ 3 및 비교예 1 ~ 2Examples 1-3 and Comparative Examples 1-2

하기 표 1에 따른 성분과 함량으로 파운데이션 조성물을 다음과 같이 제조하였다. 즉, 하기 표 1에 기재된 수상 성분 1 내지 6을 가열, 혼합하고, 여기에 미리 혼합, 분쇄시킨 안료 7 내지 12를 가하여 균일하게 분산시켰다. 이어서, 미리 가열, 용해시킨 유상 성분 13 내지 24를 첨가하여 분산시킨 후, 이 결과물을 탈포한 후 냉각, 충진시켜 파운데이션을 제조하였다.To the composition and the content according to Table 1, the foundation composition was prepared as follows. That is, the water phase components 1-6 shown in the following Table 1 were heated and mixed, and the pigments 7-12 which were previously mixed and pulverized were added to it, and it disperse | distributed uniformly. Subsequently, the oil-based components 13-24 which were previously heated and dissolved were added and dispersed, and the resultant was defoamed, cooled, and filled to prepare a foundation.

비교예 3Comparative Example 3

하기 표 1에 기재된 유상 성분 18 내지 23을 가열, 용해시키고, 여기에 미리 혼합, 분쇄시킨 안료 7 내지 12를 가하여 균일하게 분산시켰다. 이어서, 수상 성분 1 및 2를 첨가하여 혼합, 유화시킨 후, 이 결과물을 탈포하여 냉각, 충진시켜 파운데이션을 제조하였다.The oily components 18 to 23 shown in the following Table 1 were heated and dissolved, and the pigments 7 to 12, which had been mixed and pulverized in advance, were added thereto and uniformly dispersed. Subsequently, water phase components 1 and 2 were added, mixed and emulsified, and the resultant was degassed, cooled, and filled to prepare a foundation.

성분명(중량%)Ingredient Name (wt%) 실시예Example 비교예Comparative example 1One 22 33 1One 22 33 1One 이온교환수Ion exchange water to 100to 100 to 100to 100 to 100to 100 to 100to 100 to 100to 100 9.09.0 22 1,3-부틸렌글리콜1,3-butylene glycol 3.03.0 3.03.0 3.03.0 3.03.0 3.03.0 3.03.0 33 한천Agar -- -- -- 3.03.0 -- -- 44 규산나트륨마그네슘Sodium silicate -- -- -- -- 3.03.0 -- 55 폴리에틸렌글리콜 밀납 유도체Polyethylene Glycol Wax Derivative 10.010.0 15.015.0 25.025.0 -- -- -- 66 방부제antiseptic 적량Quantity 적량Quantity 적량Quantity 적량Quantity 적량Quantity 적량Quantity 77 적색산화철Red iron oxide 1.01.0 1.01.0 1.01.0 1.01.0 1.01.0 1.01.0 88 황색산화철Yellow iron oxide 3.03.0 3.03.0 3.03.0 3.03.0 3.03.0 3.03.0 99 흑색산화철Black iron oxide 0.20.2 0.20.2 0.20.2 0.20.2 0.20.2 0.20.2 1010 이산화티탄Titanium dioxide 10.010.0 10.010.0 10.010.0 10.010.0 10.010.0 10.010.0 1111 카올린kaoline 5.05.0 5.05.0 5.05.0 5.05.0 5.05.0 5.05.0 1212 탈크Talc 16.016.0 16.016.0 16.016.0 16.016.0 16.016.0 16.016.0 1313 스테아린산Stearic acid -- -- -- 2.02.0 2.02.0 -- 1414 이소헥사데실알코올Isohexadecyl alcohol -- -- -- 7.07.0 7.07.0 -- 1515 모노스테아린산글리세린Glycerin Monostearate -- -- -- 2.02.0 2.02.0 -- 1616 라놀린lanolin 2.02.0 2.02.0 2.02.0 2.02.0 2.02.0 -- 1717 유동파라핀Liquid paraffin 5.05.0 5.05.0 5.05.0 8.08.0 8.08.0 -- 1818 데카메틸사이크로펜타실록산Decamethylcyclopentasiloxane -- -- -- -- -- to 100to 100 1919 메틸폴리실록산Methylpolysiloxane -- -- -- -- -- 10.010.0 2020 스쿠알란Squalane -- -- -- -- -- 3.03.0 2121 폴리옥시에틸렌변성메틸폴리실록산Polyoxyethylene Modified Methyl Polysiloxane -- -- -- -- -- 2.02.0 2222 고형파라핀Solid paraffin -- -- -- -- -- 4.04.0 2323 칸데릴라왁스Candelilla wax -- -- -- -- -- 1.01.0 2424 피브이피/에이코신 공중합체FV / Eicosin Copolymer 5.05.0 10.010.0 10.010.0 -- -- --

상기 표 1에서, 폴리에칠렌글리콜 밀납 유도체는 에틸렌옥사이드가 12몰 부가된 폴리에칠렌글리콜600 밀납유도체이고, 피브이피/에이코신 공중합체의 구입처 및 제품명은 Antaron V220,ISP임.In Table 1, the polyethylene glycol beeswax derivative is a polyethylene glycol 600 beeswax derivative with 12 moles of ethylene oxide added, and the place of purchase and product name of the IPV / Eicosin copolymer is Antaron V220, ISP.

실시예 1 내지 3 및 비교예 1 내지 3에 따라 제조한 파운데이션 조성물에 대하여 청량감, 촉촉함, 내수성을 평가하여 그 결과를 표 2에 나타냈다.Cooling, moist and water resistance of the foundation compositions prepared according to Examples 1 to 3 and Comparative Examples 1 to 3 were evaluated, and the results are shown in Table 2.

<평가방법><Evaluation Method>

20대 여성 10명을 대상으로 실시예 및 비교예에 따라 제조한 조성물로 3회 이상 화장을 실시하도록 하고, 청량감, 촉촉함, 내수성을 관능 평가하도록 한 후, 하기 기준에 따라 평가하였다.Ten women in their twenties were subjected to make-up three or more times with the compositions prepared according to Examples and Comparative Examples, and were subjected to the sensory evaluation of cooling, moist and water resistance, and then evaluated according to the following criteria.

(평가기준)(Evaluation standard)

○ : 양호(양호하다고 평가한 사람 수/불량하다고 평가한 사람 수:10/0~7/3)○: Good (number of people who considered good / number of people who evaluated poor: 10/0-7/3)

△ : 보통(양호하다고 평가한 사람 수/불량하다고 평가한 사람 수:6/4~4/6)(Triangle | delta): Moderate (the number of people who evaluated good / the number of people who evaluated poor: 6/4-4/6)

× : 불량(양호하다고 평가한 사람 수/불량하다고 평가한 사람 수:3/7~0/10)X: Poor (number of people who evaluated good / number of people who evaluated poor: 3/7-0/10)

평가항목Evaluation item 실시예 1Example 1 실시예 2Example 2 실시예 3Example 3 비교예 1Comparative Example 1 비교예 2Comparative Example 2 비교예 3Comparative Example 3 청량감Refreshing feeling ×× 촉촉함Moist ×× 내수성Water resistance ×× ××

표 2에 나타난 바와 같이, 본 발명에 따른 수성 고형 파운데이션은 청량감, 촉촉함, 내수성 모두 매우 우수함을 알 수 있다. 한편, 수중유형 고형 파운데이션인 비교예 1 및 비교예 2의 화장료는 내수성이 매우 불량하며, 유중수형 고형 파운데이션인 비교예 3의 화장료는 청량감과 촉촉함이 좋지 않다.As shown in Table 2, it can be seen that the aqueous solid foundation according to the present invention is very excellent in both refreshing, moist and water resistance. On the other hand, the cosmetics of Comparative Examples 1 and 2, which are oil-in-water solid foundations, are very poor in water resistance, and the cosmetics of Comparative Example 3, which are water-in-oil solid foundations, are not good in freshness and moisture.

본 발명의 수성 고형 화장료 조성물은 표 1의 파운데이션 외에도 다양한 제형으로 제조할 수 있는데, 하기 실시예 4 및 5는 각각 아이새도 및 자외선 차단 고형 스틱형 조성물의 제조예를 나타낸 것이다.The aqueous solid cosmetic composition of the present invention can be prepared in a variety of formulations in addition to the foundation of Table 1, Examples 4 and 5 below shows an example of the preparation of the eye shadow and the sunscreen solid stick composition.

실시예 4 ~ 5Examples 4-5

하기 표 3에 따른 성분과 함량으로 각각 아이새도 및 자외선 차단 고형 스틱형 조성물을 다음과 같이 제조하였다. 즉, 하기 표 2에 기재된 수상 성분 1 내지 5를 75 ~ 80℃로 가열, 용해시키고, 여기에 미리 혼합, 분쇄시킨 안료 6 내지 8을 가하여 균일하게 분산시켰다. 이어서, 미리 가열, 용해시킨 유상 성분 9 내지 11을 첨가하여 분산시킨 후, 이 결과물을 탈포한 후 성형, 냉각시켜 화장료를 제조하였다.To the components and contents according to the following Table 3, respectively, was prepared as the Edo Island and the sunscreen solid stick-like composition. That is, the water phase components 1 to 5 described in Table 2 below were heated and dissolved at 75 to 80 ° C., and pigments 6 to 8 mixed and pulverized in advance were added thereto and uniformly dispersed. Subsequently, after adding and disperse | distributing the oily components 9-11 which were heated and dissolved previously, this resultant was defoamed, shape | molded and cooled, and the cosmetics were manufactured.

성분명(중량%)Ingredient Name (wt%) 실시예4Example 4 실시예 5Example 5 1One 정제수Purified water to 100to 100 to 100to 100 22 1,3-부틸렌글리콜1,3-butylene glycol 10.010.0 10.010.0 33 글리세린glycerin 5.05.0 5.05.0 44 폴리에틸렌글리콜 밀납 유도체Polyethylene Glycol Wax Derivative 25.025.0 20.020.0 55 방부제antiseptic 적량Quantity 적량Quantity 66 탈크Talc 10.010.0 5.05.0 77 착색안료Pigmentation Pigment 5.05.0 1.01.0 88 미세산화티탄Titanium Oxide -- 10.010.0 99 라놀린lanolin 2.02.0 2.02.0 1010 옥틸도데칸올Octyldodecanol 5.05.0 5.05.0 1111 피브이피/에이코신 공중합체FV / Eicosin Copolymer 10.010.0 10.010.0

이상과 같이, 본 발명의 수성 고형 화장료는 수성 고형화제인 폴리에칠렌글리콜 밀납 유도체를 사용하여 다량의 물을 고형화시키고, 유성 고분자 성분인 피브이피/에이코신 공중합체(PVP/Eicosene Copolymer)와 액상오일을 안정하게 배합시킨 것으로서, 본 발명에 따른 수성 고형 화장료를 피부에 도포시 충분한 청량감과 촉촉함이 부여될 뿐만 아니라, 내수성도 우수하므로 화장 지속성도 양호하다.As described above, the aqueous solid cosmetic composition of the present invention solidifies a large amount of water using a polyethylene glycol beeswax derivative which is an aqueous solidifying agent, and stabilizes the PVP / Eicosene Copolymer and the liquid oil as oily polymer components. It is formulated in such a way that, when applying the aqueous solid cosmetics according to the present invention to the skin, not only is it given sufficient refreshing and moist feeling, but also excellent in water resistance, and thus the makeup persistence is good.

Claims (2)

폴리에틸렌글리콜 밀납 유도체 1 내지 50중량부, 물 5 내지 80중량부, 피브이피/에이코신 공중합체 0.1 내지 30중량부 및 액상 오일 1 내지 50중량부를 함유하는 것을 특징으로 하는 수성 고형 화장료 조성물.An aqueous solid cosmetic composition comprising 1 to 50 parts by weight of a polyethylene glycol beeswax derivative, 5 to 80 parts by weight of water, 0.1 to 30 parts by weight of a fib / eicosine copolymer, and 1 to 50 parts by weight of a liquid oil. 제1항에 있어서, 상기 액상 오일은 탄화수소계 액상 오일, 에스테르계 액상 오일, 고급 알코올 및 이들의 혼합물로 이루어진 군으로부터 선택된 어느 하나의 비휘발성 액상 오일인 것을 특징으로 하는 수성 고형 화장료 조성물.The aqueous solid cosmetic composition according to claim 1, wherein the liquid oil is any one nonvolatile liquid oil selected from the group consisting of hydrocarbon liquid oil, ester liquid oil, higher alcohol and mixtures thereof.
KR1020010077706A 2001-12-10 2001-12-10 Aqua stick cosmetic composition KR20030047259A (en)

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Cited By (1)

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KR20180130178A (en) 2017-05-29 2018-12-07 주식회사 엘지생활건강 Liposome and cosmetic composition comprising the same

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US4814165A (en) * 1987-03-03 1989-03-21 Kolmar Laboratories Inc. Emulsified hydrated stick product
US5597849A (en) * 1994-11-14 1997-01-28 Medical Polymer Technologies, Inc. Stick formulations for topical drug delivery of therapeutic agents and uses thereof
JPH1067618A (en) * 1996-07-17 1998-03-10 L'oreal Sa Composition containing mixture of volatile compound and polyvinylpyrrolidone polymer and use of the mixture
KR19980053454A (en) * 1996-12-26 1998-09-25 성재갑 Stick-type pack cosmetics and preparation method thereof
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US4814165A (en) * 1987-03-03 1989-03-21 Kolmar Laboratories Inc. Emulsified hydrated stick product
US5597849A (en) * 1994-11-14 1997-01-28 Medical Polymer Technologies, Inc. Stick formulations for topical drug delivery of therapeutic agents and uses thereof
JPH1067618A (en) * 1996-07-17 1998-03-10 L'oreal Sa Composition containing mixture of volatile compound and polyvinylpyrrolidone polymer and use of the mixture
KR19980053454A (en) * 1996-12-26 1998-09-25 성재갑 Stick-type pack cosmetics and preparation method thereof
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