KR20030024825A - A method for the treatment of textile materials against fungi and dust mites - Google Patents
A method for the treatment of textile materials against fungi and dust mites Download PDFInfo
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- KR20030024825A KR20030024825A KR10-2003-7001548A KR20037001548A KR20030024825A KR 20030024825 A KR20030024825 A KR 20030024825A KR 20037001548 A KR20037001548 A KR 20037001548A KR 20030024825 A KR20030024825 A KR 20030024825A
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- textile material
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- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 1
- 150000004056 anthraquinones Chemical class 0.000 description 1
- 239000003429 antifungal agent Substances 0.000 description 1
- 208000006673 asthma Diseases 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 description 1
- 229940116226 behenic acid Drugs 0.000 description 1
- OWBTYPJTUOEWEK-UHFFFAOYSA-N butane-2,3-diol Chemical compound CC(O)C(C)O OWBTYPJTUOEWEK-UHFFFAOYSA-N 0.000 description 1
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- 150000001720 carbohydrates Chemical class 0.000 description 1
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- 239000000969 carrier Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
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- 239000013043 chemical agent Substances 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 229960004698 dichlorobenzyl alcohol Drugs 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 239000000986 disperse dye Substances 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical class CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- QVBODZPPYSSMEL-UHFFFAOYSA-N dodecyl sulfate;2-hydroxyethylazanium Chemical compound NCCO.CCCCCCCCCCCCOS(O)(=O)=O QVBODZPPYSSMEL-UHFFFAOYSA-N 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000007046 ethoxylation reaction Methods 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 239000000834 fixative Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000004872 foam stabilizing agent Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 229940075529 glyceryl stearate Drugs 0.000 description 1
- 239000011487 hemp Substances 0.000 description 1
- XJNUECKWDBNFJV-UHFFFAOYSA-N hexadecyl 2-ethylhexanoate Chemical compound CCCCCCCCCCCCCCCCOC(=O)C(CC)CCCC XJNUECKWDBNFJV-UHFFFAOYSA-N 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- VKOBVWXKNCXXDE-UHFFFAOYSA-N icosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCC(O)=O VKOBVWXKNCXXDE-UHFFFAOYSA-N 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 238000004900 laundering Methods 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 229940069822 monoethanolamine lauryl sulfate Drugs 0.000 description 1
- VMGAPWLDMVPYIA-HIDZBRGKSA-N n'-amino-n-iminomethanimidamide Chemical compound N\N=C\N=N VMGAPWLDMVPYIA-HIDZBRGKSA-N 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- 239000001005 nitro dye Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 229940032076 peg-15 glyceryl stearate Drugs 0.000 description 1
- 229940078498 peg-5 glyceryl stearate Drugs 0.000 description 1
- DGBWPZSGHAXYGK-UHFFFAOYSA-N perinone Chemical compound C12=NC3=CC=CC=C3N2C(=O)C2=CC=C3C4=C2C1=CC=C4C(=O)N1C2=CC=CC=C2N=C13 DGBWPZSGHAXYGK-UHFFFAOYSA-N 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 229920001184 polypeptide Polymers 0.000 description 1
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 102000004196 processed proteins & peptides Human genes 0.000 description 1
- 108090000765 processed proteins & peptides Proteins 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- IZMJMCDDWKSTTK-UHFFFAOYSA-N quinoline yellow Chemical compound C1=CC=CC2=NC(C3C(C4=CC=CC=C4C3=O)=O)=CC=C21 IZMJMCDDWKSTTK-UHFFFAOYSA-N 0.000 description 1
- 239000004627 regenerated cellulose Substances 0.000 description 1
- BOLDJAUMGUJJKM-LSDHHAIUSA-N renifolin D Natural products CC(=C)[C@@H]1Cc2c(O)c(O)ccc2[C@H]1CC(=O)c3ccc(O)cc3O BOLDJAUMGUJJKM-LSDHHAIUSA-N 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000012449 sabouraud dextrose agar Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 125000003011 styrenyl group Chemical class [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 125000005504 styryl group Chemical group 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 230000004083 survival effect Effects 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 235000019156 vitamin B Nutrition 0.000 description 1
- 239000011720 vitamin B Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 239000002888 zwitterionic surfactant Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0094—High foaming compositions
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/22—O-Aryl or S-Aryl esters thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/349—Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F11/00—Chemical after-treatment of artificial filaments or the like during manufacture
- D01F11/04—Chemical after-treatment of artificial filaments or the like during manufacture of synthetic polymers
- D01F11/06—Chemical after-treatment of artificial filaments or the like during manufacture of synthetic polymers of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
- D06L1/02—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using organic solvents
- D06L1/04—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using organic solvents combined with specific additives
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
- D06M13/425—Carbamic or thiocarbamic acids or derivatives thereof, e.g. urethanes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
- D06M23/02—Processes in which the treating agent is releasably affixed or incorporated into a dispensing means
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
- D06M23/04—Processes in which the treating agent is applied in the form of a foam
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
- D06M23/06—Processes in which the treating agent is dispersed in a gas, e.g. aerosols
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
- D06M23/10—Processes in which the treating agent is dissolved or dispersed in organic solvents; Processes for the recovery of organic solvents thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/12—Soft surfaces, e.g. textile
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Dispersion Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Biochemistry (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
본 발명에는 화학식 1의 화합물을 패딩법, 분무법 또는 발포 도포법(foam application)으로 또는 드라이 클리닝 공정 동안 직물 재료에 도포함을 포함하는, 항진균성 및/또는 항먼지 진드기성을 향상시키기 위한 직물 재료의 처리방법 및 겔 상태의 폴리아크릴로니트릴 섬유의 처리에 관한 유사한 방법이 기재되어 있다.Textile materials for improving antifungal and / or anti-dust mites, comprising the compound of formula 1 in a padding, spraying or foam application or during the dry cleaning process. Methods of treating and similar methods of treating polyacrylonitrile fibers in the gel state are described.
화학식 1Formula 1
Description
본 발명은 선택된 특정 항진균제 또는 항먼지 진드기제를 특정 도포방법으로 직물 재료에 도포함으로써 항진균성 및/또는 항먼지 진드기성을 향상시키기 위한 직물 재료의 처리방법에 관한 것이다.The present invention relates to a method of treating textile materials to improve antifungal and / or antidust mites by applying selected specific antifungal agents or antidust mites to the textile material by a specific application method.
소비자에게 항진균성이 있는 직물 제품, 특히 항먼지 진드기성이 있는 직물 제품은 매우 호감이 가는 제품이다. 몇몇 부분에서 이러한 특성은 특히 중요하다. 예를 들면, 다양한 연구에 의하면 사람 발은 종종 진균에 감염되어 애틀리트 풋(Athelet's foot)과 같은 각종 질환에 걸린다. 따라서, 항진균성이 있는 직물 재료가 신발 제조용 부재로서 도입되는 경우, 소비자에게 유리할 수 있다. 가정용 직물 부분에서, 매트릭스 및 베개 덮개에 존재하는 먼지 진드기는 알레르기 및 천식 발병 증가와 관련되어 있다. 먼지 진드기의 생존은, 피부 박편(skin flake)을 대사하여 먼지 진드기에게 필수적인 먹이 공급원인 비타민 B를 제공하는 진균 종의 존재에 달려 있으므로, 진균의 억제는 먼지 진드기 성장을 억제하는 데 도움이 되고 따라서 소비자에게 유리하다.Textile products that are antifungal to consumers, particularly textile products that are anti-dust mites, are very appealing. In some respects this characteristic is particularly important. For example, various studies have shown that the human foot is often infected with fungi and causes a variety of diseases, such as Athelet's foot. Thus, when an antifungal textile material is introduced as a member for manufacturing shoes, it may be advantageous to the consumer. In the home textiles sector, dust mites present in the matrix and pillow covers are associated with increased allergy and asthma outbreaks. Since the survival of dust mites depends on the presence of fungal species that metabolize skin flakes and provide vitamin B as a necessary food source for dust mites, suppressing fungi helps to inhibit dust mite growth and thus It is advantageous to the consumer.
위의 견지에서, 이들 특성을 향상시킬 수 있고, 반복되는 세탁에 대해 내구성을 갖는 장기간 지속되는 항진균 활성 및 항먼지 진드기 활성을 제공하는 적합한방법을 찾을 필요가 있다.In view of the above, there is a need to find a suitable method that can improve these properties and provide long-lasting antifungal activity and antidust mite activity that is durable against repeated washing.
본 발명은 목적하는 직물 제품에 특정 제제를 사용하여 항진균 효능 및 항먼지 진드기 효능을 제공하는 데 초점을 맞추고 있다. 놀랍게도, 선택된 항진균 물질을, 천연 및 합성 섬유로 제조된 각종 기재에 도입함으로써, 반복되는 세탁, 드라이 클리닝, 풍화(weathering) 및/또는 다른 노화(ageing) 공정에 대해 내구성을 갖는 장기간 지속되는 항진균 활성 및 항먼지 진드기성을 제공할 수 있다는 것이 밝혀졌다. 당해 직물 제품을 선택된 제제 및/또는 당해 제제를 함유하는 제형으로 처리하는 것은 패딩법, 분무법 및 발포 도포법과 같은 각종 방법 뿐만 아니라, 당해 제제로 겔 상태의 폴리아크릴로니트릴 섬유를 처리하는 방법에서 사용할 수 있다는 것이 밝혀졌다.The present invention focuses on providing antifungal efficacy and antidust mite efficacy using specific agents in the desired textile product. Surprisingly, by introducing selected antifungal substances into various substrates made of natural and synthetic fibers, long-lasting antifungal activity that is durable against repeated laundry, dry cleaning, weathering and / or other aging processes And anti-dust mites have been found. Treatment of the textile product with selected formulations and / or formulations containing the formulations can be used in various methods such as padding, spraying and foam coating, as well as in the process of treating polyacrylonitrile fibers in gel form with the formulation. It turns out that you can.
따라서, 본 발명은 화학식 1의 화합물을 패딩법, 분무법 또는 발포 도포법으로 또는 드라이 클리닝 공정 동안 직물 재료에 도포함을 포함하는, 항진균성 및/또는 항먼지 진드기성을 향상시키기 위한 직물 재료의 처리방법에 관한 것이다.Accordingly, the present invention relates to the treatment of textile materials to improve antifungal and / or dust mite properties, comprising applying the compound of formula 1 to padding, spraying or foam coating or to the textile material during a dry cleaning process. It is about a method.
화학식 1의 화합물은 희석, 가용화, 유화 또는 바람직하게는 분산 형태의 수성 제형으로서 도포할 수 있다.The compound of formula 1 may be applied as an aqueous formulation in dilute, solubilized, emulsified or preferably dispersed form.
따라서, 당해 수성 제형은 소량의 유기 용매, 계면활성제, 분산제 및/또는 유화제를 추가로 포함할 수 있다. 이들 성분은 수성 제형 중의 화학식 1의 화합물의 가용화 및 안정화에 유용하다.Thus, the aqueous formulations may further comprise small amounts of organic solvents, surfactants, dispersants and / or emulsifiers. These components are useful for solubilizing and stabilizing the compound of formula 1 in an aqueous formulation.
화학식 1의 화합물을 분산 형태로 도포하는 경우, 통상적으로 수정 구(quartz ball) 및 임펠러를 사용하여 이를 적합한 분산제와 함께 분쇄하여, 예를 들면, 입자 크기가 0.1 내지 4㎛, 특히 0.3 내지 3㎛가 되도록 하는 것이 바람직하다.When the compound of formula 1 is applied in dispersed form, it is usually ground with a suitable dispersant using quartz balls and impellers, for example, with a particle size of 0.1 to 4 μm, in particular 0.3 to 3 μm. It is preferable to
화학식 1의 화합물의 적합한 분산제는Suitable dispersants for the compounds of formula 1
- 산 에스테르 또는 이의 알킬렌 옥사이드 부가물의 염, 전형적으로 산 에스테르 또는 이의, 4 내지 40mol의 에틸렌 옥사이드와 1mol의 페놀과의 중부가물의 염, 또는 6 내지 30mol의 에틸렌 옥사이드와 1mol의 4-노닐페놀, 1mol의 디노닐페놀, 또는 바람직하게는 1mol의 페놀에 1 내지 3mol의 포화 또는 불포화 스티렌을 부가하여 제조한 화합물 1mol과의 인산화 중부가물의 염,Salts of acid esters or alkylene oxide adducts thereof, typically acid esters or salts of heavy adducts of 4 to 40 mol of ethylene oxide with 1 mol of phenol, or 6 to 30 mol of ethylene oxide and 1 mol of 4-nonylphenol Salts of phosphorylated heavy adducts with 1 mol of dinonylphenol, or 1 mol of a compound prepared by adding 1-3 mol of saturated or unsaturated styrene to 1 mol of phenol,
- 폴리스티렌 설포네이트,Polystyrene sulfonates,
- 지방산 타우라이드,Fatty acid taurides,
- 알킬화 디페닐 옥사이드 모노- 또는 디설포네이트,Alkylated diphenyl oxide mono- or disulfonates,
- 폴리카복실레이트의 설포네이트,Sulfonates of polycarboxylates,
- 1 내지 60mol의 에틸렌 옥사이드 및/또는 프로필렌 옥사이드와 지방 아민, 지방산 또는 지방 알콜(각각 알킬 쇄에 8 내지 22개의 탄소를 함유한다), 알킬 쇄에 4 내지 16개의 탄소를 함유하는 알킬페놀 또는 탄소수 3 내지 6의 삼가 내지 육가 알칸올과의 중부가물(당해 중부가물은 유기 디카복실산 또는 무기 다가 염기 산과 함께 산 에스테르로 전환된다),1 to 60 mol of ethylene oxide and / or propylene oxide with fatty amines, fatty acids or fatty alcohols, each containing 8 to 22 carbons in the alkyl chain, alkylphenols or carbon atoms containing 4 to 16 carbons in the alkyl chain Heavy adducts with trivalent to hexavalent alkanols of 3 to 6 (where the heavy adducts are converted to acid esters with organic dicarboxylic acids or inorganic polyvalent basic acids),
- 리그닌설포네이트 및, 가장 바람직하게는,Ligninsulfonate and, most preferably,
- 포름알데하이드 축합물, 예를 들면, 리그닌설포네이트 및/또는 페놀 및 포름알데하이드의 축합물, 포름알데하이드와 방향족 설폰산과의 축합물, 전형적으로 디옥틸 에테르 설포네이트와 포름알데하이드와의 축합물, 나프탈렌설폰산 및/또는 나프톨- 또는 나프틸아민설폰산과 포름알데하이드와의 축합물, 페놀설폰산 및/또는 설폰화 디하이드록시디페닐설폰 및 페놀 또는 크레졸과 포름알데하이드 및/또는 요소와의 축합물 및 디페닐 옥사이드-디설폰산 유도체와 포름알데하이드와의 축합물이다.Formaldehyde condensates, for example ligninsulfonates and / or condensates of phenols and formaldehydes, condensates of formaldehyde with aromatic sulfonic acids, typically condensates of dioctyl ether sulfonates with formaldehyde, naphthalene Condensates of sulfonic acids and / or naphthol- or naphthylaminesulfonic acids with formaldehyde, phenolsulfonic acids and / or sulfonated dihydroxydiphenylsulfones and phenols or cresols with formaldehyde and / or ureas and Condensate of diphenyl oxide-disulfonic acid derivatives with formaldehyde.
바람직하게는, 화학식 1의 화합물은 리그닌설포네이트 및/또는 페놀 및 포름알데하이드와의 축합물, 포름알데하이드와 방향족 설폰산과의 축합물, 나프탈렌설폰산 및/또는 나프톨- 또는 나프틸아민설폰산과 포름알데하이드와의 축합물, 페놀설폰산 및/또는 설폰화 디하이드록시디페닐설폰 및 페놀 또는 크레졸과 포름알데하이드 및/또는 요소와의 축합물 및 디페닐 옥사이드-디설폰산 유도체와 포름알데하이드와의 축합물로 이루어진 그룹으로부터 선택된 하나 이상의 분산제에 의해 분산된다. 나프탈렌설폰산 및/또는 나프톨- 또는 나프틸아민설폰산과 포름알데하이드와의 축합물이 매우 바람직하다.Preferably, the compound of formula 1 is a condensate of ligninsulfonate and / or phenol and formaldehyde, a condensate of formaldehyde with aromatic sulfonic acid, naphthalenesulfonic acid and / or naphthol- or naphthylaminesulfonic acid and formaldehyde Condensates with phenolsulfonic acids and / or sulfonated dihydroxydiphenylsulfones and phenols or cresols with formaldehyde and / or ureas and with condensates of diphenyl oxide-disulfonic acid derivatives with formaldehyde Dispersed by one or more dispersants selected from the group consisting of: Very preferred are condensates of naphthalenesulfonic acid and / or naphthol- or naphthylaminesulfonic acid with formaldehyde.
적합한 가용화제는 음이온성, 비이온성 또는 쯔비터 이온성 및 양쪽성 합성 계면활성제이다.Suitable solubilizers are anionic, nonionic or zwitterionic and amphoteric synthetic surfactants.
적합한 음이온성 계면활성제는Suitable anionic surfactants are
- 설페이트, 전형적으로 알킬 쇄에 8 내지 18개의 탄소를 함유하는 지방 알콜 설페이트, 예를 들면, 설페이트화 라우릴 알콜,Sulfates, fatty alcohol sulfates typically containing 8 to 18 carbons in the alkyl chain, for example sulfated lauryl alcohol,
- 지방 알콜 에테르 설페이트, 전형적으로 산 에스테르 또는 이의, 2 내지 30mol의 에틸렌 옥사이드와 1mol의 C8-C22지방 알콜과의 중부가물의 염,Fatty alcohol ether sulfates, typically acid esters or salts of polyadditions of from 2 to 30 mol of ethylene oxide with 1 mol of C 8 -C 22 fatty alcohol,
- 비누로 지칭되는 C8-C20지방산, 전형적으로 코코넛 지방산의 알칼리 금속 염, 암모늄 염 또는 아민 염,Alkali metal salts, ammonium salts or amine salts of C 8 -C 20 fatty acids, typically coconut fatty acids, referred to as soap,
- 알킬아미드 설페이트,Alkylamide sulfates,
- 알킬아민 설페이트, 전형적으로 모노에탄올아민 라우릴 설페이트,Alkylamine sulfates, typically monoethanolamine lauryl sulfate,
- 알킬아미드 에테르 설페이트,Alkylamide ether sulfates,
- 알킬아릴 폴리에테르 설페이트,Alkylaryl polyether sulfates,
- 모노글리세라이드 설페이트,Monoglyceride sulfate,
- 알킬 쇄에 8 내지 20개의 탄소를 함유하는 알칸 설포네이트, 예를 들면, 도데실 설포네이트,Alkanesulfonates containing 8 to 20 carbons in the alkyl chain, for example dodecyl sulfonate,
- 알킬아미드 설포네이트,Alkylamide sulfonates,
- 알킬아릴 설포네이트,Alkylaryl sulfonates,
- α-올레핀 설포네이트,α-olefin sulfonates,
- 설포석신산 유도체, 전형적으로 알킬 설포석시네이트, 알킬 에테르 설포석시네이트 또는 알킬 설포석신아미드 유도체,Sulfosuccinic acid derivatives, typically alkyl sulfosuccinates, alkyl ether sulfosuccinates or alkyl sulfosuccinamide derivatives,
- 화학식 2의 N-[알킬아미도알킬]아미노산 또는N- [alkylamidoalkyl] amino acids of formula (2) or
- 화학식 3의 알킬아릴 에테르 카복실레이트 또는 알킬 에테르 카복실레이트이다.Alkylaryl ether carboxylates or alkyl ether carboxylates of the formula (3).
위의 화학식 2에서,In Formula 2 above,
X는 수소, C1-C4알킬 또는 -COO-M+이고,X is hydrogen, C 1 -C 4 alkyl or -COO - M + ,
Y는 수소 또는 C1-C4알킬이고,Y is hydrogen or C 1 -C 4 alkyl,
Z는(여기서, m1은 1 내지 5이다)이고,Z is (Wherein m 1 is 1 to 5),
n은 6 내지 18의 정수이고,n is an integer from 6 to 18,
M은 알칼리 금속 이온 또는 아민 이온이다.M is an alkali metal ion or an amine ion.
위의 화학식 3에서,In Formula 3 above,
X는,또는의 라디칼(여기서, R은 수소 또는 C1-C4알킬이다)이고,X is , or Is a radical of wherein R is hydrogen or C 1 -C 4 alkyl,
Y는이고,Y is ego,
A는또는(여기서, m2는 1 내지 6이고, M은 알칼리 금속 양이온 또는 아민 양이온이다)이다.A is or (Wherein m 2 is 1 to 6 and M is an alkali metal cation or an amine cation).
또한, 사용된 음이온성 계면활성제는 지방산 메틸 타우라이드, 알킬이소티오네이트, 지방산 폴리펩타이드 축합물 및 지방 알콜 인산 에스테르일 수 있다. 이들 화합물 내의 알킬 라디칼은 바람직하게는 8 내지 24개의 탄소를 함유한다.In addition, the anionic surfactants used may be fatty acid methyl taudes, alkylisothionates, fatty acid polypeptide condensates and fatty alcohol phosphate esters. The alkyl radicals in these compounds preferably contain 8 to 24 carbons.
음이온성 계면활성제는 일반적으로 이의 수용성 염 형태, 예를 들면, 알칼리 금속, 암모늄 또는 아민 염 형태로 수득된다. 당해 염의 전형적인 예는 리튬, 나트륨, 칼륨, 암모늄, 트리에틸아민, 에탄올아민, 디에탄올아민 또는 트리에탄올아민 염이다. 나트륨 염, 칼륨 염 또는 암모늄-(NR1R2R3) 염(여기서, R1, R2및 R3은 각각 서로 독립적으로 수소, C1-C4알킬 또는 C1-C4하이드록시알킬이다)을 사용하는 것이 바람직하다.Anionic surfactants are generally obtained in the form of their water soluble salts, for example alkali metal, ammonium or amine salts. Typical examples of such salts are lithium, sodium, potassium, ammonium, triethylamine, ethanolamine, diethanolamine or triethanolamine salts. Sodium salt, potassium salt or ammonium- (NR 1 R 2 R 3 ) salts wherein R 1 , R 2 and R 3 are each independently of one another hydrogen, C 1 -C 4 alkyl or C 1 -C 4 hydroxyalkyl Is preferably used.
적합한 쯔비터 이온성 및 양쪽성 계면활성제는 이미다졸린 카복실레이트, 알킬암포카복시 카복실산, 알킬암포카복실산(예를 들면, 라우로암포글리시네이트) 및 N-알킬-b-아미노프로피오네이트 또는 N-알킬-b-이미노디프로피오네이트이다.Suitable zwitterionic and amphoteric surfactants include imidazoline carboxylates, alkyl ampocarboxy carboxylic acids, alkyl ampocarboxylic acids (eg lauroampoglycinate) and N-alkyl-b-aminopropionates or N -Alkyl-b-iminodipropionate.
비이온성 계면활성제는 전형적으로, 분자량이 1000 내지 15000인 프로필렌 옥사이드/에틸렌 옥사이드의 부가물의 유도체, 지방 알콜 에톡실레이트(1-50 EO), 알킬페놀 폴리글리콜 에테르(1-50 EO), 에톡시화 탄수화물, 지방산 글리콜 부분(partial) 에스테르, 전형적으로 디에틸렌 글리콜 모노스테아레이트, PEG 5 글리세릴 스테아레이트; PEG 15 글리세릴 스테아레이트; PEG 25 글리세릴 스테아레이트; 세테아릴 옥타노에이트; 지방산 알칸올아미드 및 지방산 디알칸올아미드, 지방산 알칸올아미드 에톡실레이트 및 지방산 아민 옥사이드이다.Nonionic surfactants are typically derivatives of adducts of propylene oxide / ethylene oxide with molecular weights of 1000 to 15000, fatty alcohol ethoxylates (1-50 EO), alkylphenol polyglycol ethers (1-50 EO), ethoxylation Carbohydrates, fatty acid glycol partial esters, typically diethylene glycol monostearate, PEG 5 glyceryl stearate; PEG 15 glyceryl stearate; PEG 25 glyceryl stearate; Cetearyl octanoate; Fatty acid alkanolamides and fatty acid dialkanolamides, fatty acid alkanolamide ethoxylates and fatty acid amine oxides.
추가로, 가용화제로서 포화 및 불포화 C8-C22지방산 염을 그 자체로, 서로 혼합하여 또는 다른 계면활성제와의 혼합물로 사용할 수 있다. 이들 지방산의 예는, 전형적으로 카프르산, 라우르산, 미리스트산, 팔미트산, 스테아르산, 아라크산, 베헨산, 도데켄산, 테트라데켄산, 옥타데켄산, 올레산, 에이코산산 및 에루크산 뿐만 아니라. 이들 산들의 공업용 혼합물, 전형적으로 코코넛 지방산이다. 이들 산은 염 형태로 수득될 수 있고, 적합한 양이온은 알칼리 금속 양이온, 예를 들면, 나트륨 및 칼륨 양이온, 금속 원자, 예를 들면, 아연 원자 및 알루미늄 원자 또는 알칼리도(alkalinity)가 충분한 질소 함유 유기 화합물, 전형적으로 아민 및 에톡시화 아민일 수 있다. 이들 염은 또한 동일반응계 내에서 제조할 수 있다.In addition, saturated and unsaturated C 8 -C 22 fatty acid salts can be used as solubilizers by themselves, in admixture with one another or in admixture with other surfactants. Examples of these fatty acids are typically capric acid, lauric acid, myristic acid, palmitic acid, stearic acid, arachic acid, behenic acid, dodekenic acid, tetradekenic acid, octadekenic acid, oleic acid, eicosanic acid and As well as luc acid. Industrial mixtures of these acids, typically coconut fatty acids. These acids can be obtained in salt form, suitable cations are alkali metal cations such as sodium and potassium cations, metal atoms such as zinc atoms and aluminum atoms or nitrogen containing organic compounds with sufficient alkalinity, Typically may be amines and ethoxylated amines. These salts can also be prepared in situ.
추가로, 적합한 가용화제는 이가 알콜, 바람직하게는 알킬렌 라디칼에 2 내지 6개의 탄소원자를 함유하는 것들, 전형적으로 에틸렌 글리콜, 1,2- 또는 1,3-프로판디올, 1,3-, 1,4- 또는 2,3-부탄디올, 1,5-펜탄디올 및 1,6-헥산디올, 일가 알콜, 예를 들면, 메탄올, 에탄올 및 프로판올, 및 아세톤이다.In addition, suitable solubilizers are dihydric alcohols, preferably those containing 2 to 6 carbon atoms in the alkylene radical, typically ethylene glycol, 1,2- or 1,3-propanediol, 1,3-, 1 , 4- or 2,3-butanediol, 1,5-pentanediol and 1,6-hexanediol, monohydric alcohols such as methanol, ethanol and propanol, and acetone.
당해 수성 제형, 특히 분산액에서, 화학식 1의 화합물의 농도는, 제형의 중량을 기준으로 하여, 일반적으로 0.001 내지 30중량%, 특히 0.1 내지 20중량%이다. 화학식 1의 화합물의 농도는 매우 바람직하게는 0.1 내지 10중량%, 특히 1 내지 5중량%이다.In such aqueous formulations, in particular dispersions, the concentration of the compound of formula 1 is generally from 0.001 to 30% by weight, in particular from 0.1 to 20% by weight, based on the weight of the formulation. The concentration of the compound of formula 1 is very preferably 0.1 to 10% by weight, in particular 1 to 5% by weight.
추가로 첨가되는 성분, 예를 들면, 분산제 또는 계면활성제의 양은, 수성 제형의 중량을 기준으로 하여, 바람직하게는 0.1 내지 30중량%, 특히 1 내지 20중량%이다.The amount of additionally added components, for example dispersants or surfactants, is preferably from 0.1 to 30% by weight, in particular from 1 to 20% by weight, based on the weight of the aqueous formulation.
수성 제형, 특히 위의 방법으로 제조된 분산액은 거의 임의의 비율로 희석될 수 있다.Aqueous formulations, in particular dispersions prepared by the above methods, can be diluted in almost any ratio.
아래의 모든 도포의 경우, 화학식 1의 화합물을 당해 수성 제형, 특히 분산액 형태로 가하는 것이 바람직하다.For all of the applications below, it is preferred to add the compound of formula 1 in the form of the aqueous formulation, in particular dispersion.
패딩은 통상적인 패딩방법에 따라 수행할 수 있다. 예를 들면, 직물 재료를 화학식 1의 화합물을 함유하는 수성 리커를 통해 통과시키고, 당해 직물 재료를 한정된 리커 픽업 비율(pick-up rate)로 짠 후, 고정 단계, 바람직하게는 열처리를 수행한다.Padding may be performed according to a conventional padding method. For example, the fabric material is passed through an aqueous liquor containing the compound of formula 1 and the fabric material is woven at a defined liquor pick-up rate, followed by a fixing step, preferably a heat treatment.
수성 리커(패딩 리커) 중의 화학식 1의 화합물의 양은, 수성 리커의 중량을 기준으로 하여, 일반적으로 0.001 내지 10중량%, 특히 0.01 내지 10중량%이다. 화학식 1의 화합물의 양은 바람직하게는 0.01 내지 5중량%이다.The amount of the compound of formula 1 in the aqueous liquor (padding liquor) is generally from 0.001 to 10% by weight, in particular from 0.01 to 10% by weight, based on the weight of the aqueous liquor. The amount of the compound of formula 1 is preferably 0.01 to 5% by weight.
리커 픽업 비율은, 직물 재료의 중량을 기준으로 하여, 일반적으로 40 내지 200중량%, 특히 50 내지 150중량%이다.The liquor pick up ratio is generally from 40 to 200% by weight, in particular from 50 to 150% by weight, based on the weight of the fabric material.
일반적으로 고정 단계는, 예를 들면, 60 내지 150℃, 특히 90 내지 150℃의 온도에서 열처리하여 수행한다.Generally, the fixing step is carried out by heat treatment at a temperature of, for example, 60 to 150 ° C, in particular 90 to 150 ° C.
패딩은 일반적으로 연속 공정으로 수행하며, 여기서 직물 재료는 화학식 1의화합물을 함유하는 수성 리커를 통해 연속적으로 통과시킨다.Padding is generally carried out in a continuous process, where the fabric material is passed continuously through an aqueous liquor containing the compound of formula (1).
바람직한 방법에 따라서, 화학식 1의 화합물은 패딩법으로 직물 재료에 도포되고, 여기서 직물 재료는, 수성 리커의 중량을 기준으로 하여, 0.001 내지 10중량%의 화학식 1의 화합물을 함유하는 수성 리커를 통해 연속적으로 통과시킨다.According to a preferred method, the compound of formula 1 is applied to the fabric material by padding, wherein the fabric material is via an aqueous liquor containing 0.001 to 10% by weight of the compound of formula 1, based on the weight of the aqueous liquor. Pass it continuously.
분무는 통상적인 분무방법에 따라서 수행할 수 있다. 당해 방법에 따라서, 화학식 1의 화합물을 함유하는 수성 액체를 직물 재료에 분무한다. 수성 리커 중의 화학식 1의 화합물의 양은, 수성 리커의 중량을 기준으로 하여, 일반적으로 0.001 내지 10중량%, 특히 0.01 내지 10중량%이다. 화학식 1의 화합물의 양은 바람직하게는 0.1 내지 10중량%이다. 당해 분무방법은 카펫과 같은 직물 재료에 화학식 1의 화합물을 도포하는 데 특히 적합하다. 당해 바람직한 방법에 따라서, 다수의 분무 노즐을, 예를 들면, 카펫의 이동 방향에 직각 방향인 분무 선 상에 배치시킨다. 화학식 1의 화합물을, 예를 들면, 압력을 사용하여 분무 노즐로 수성 리커로서 도포한다.Spraying can be carried out according to conventional spraying methods. According to this method, an aqueous liquid containing the compound of formula 1 is sprayed onto the fabric material. The amount of the compound of formula 1 in the aqueous liquor is generally from 0.001 to 10% by weight, in particular from 0.01 to 10% by weight, based on the weight of the aqueous liquor. The amount of the compound of formula 1 is preferably 0.1 to 10% by weight. The spraying method is particularly suitable for applying the compound of formula 1 to textile materials such as carpets. According to this preferred method, a plurality of spray nozzles are arranged, for example, on a spray line perpendicular to the direction of movement of the carpet. The compound of formula 1 is applied as an aqueous liquor with a spray nozzle, for example using pressure.
분무 후, 일반적으로 고정 단계를 수행하며, 이는 패딩법에 대해 위에서 기재한 바와 같은 열처리로 수행할 수 있다.After spraying, a fixing step is generally carried out, which can be carried out by heat treatment as described above for the padding method.
또한, 분무방법은 소파 또는 구두와 같은 가죽을 포함하는 직물 재료의 표면에 수성 리커 형태로 화학식 1의 화합물을 도포하는 데 사용할 수 있다.The spraying method can also be used to apply the compound of formula 1 in the form of an aqueous liquor to the surface of a textile material, including leather such as sofas or shoes.
또 다른 바람직한 방법에 따라서, 화학식 1의 화합물을 분무법으로 직물 재료에 도포하고, 여기서 수성 리커의 중량을 기준으로 하여, 0.001 내지 10중량%의화학식 1의 화합물을 함유하는 수성 리커가 직물 재료에 분무된다.According to another preferred method, the compound of formula 1 is applied to the fabric material by spraying, wherein an aqueous liquor containing 0.001 to 10% by weight of the compound of formula 1 is sprayed onto the fabric material, based on the weight of the aqueous liquor. do.
또한, 화학식 1의 화합물을 발포 도포법으로 직물 재료에 도포할 수 있다. 당해 방법의 경우, 분무법에 대해 위에서 기재한 모든 조건 및 바람직한 사항들이 적용된다. 그러나, 화학식 1의 화합물은, 일반적으로 발포 안정화제를 추가로 함유하는 수성 발포체 형태로 도포된다. 또한, 당해 방법은 카펫 처리에 특히 적합하다.In addition, the compound of formula 1 may be applied to the fabric material by a foam coating method. For this method, all the conditions and preferences described above for the spraying method apply. However, the compounds of formula (1) are generally applied in the form of aqueous foams which further contain foam stabilizers. The method is also particularly suitable for carpet treatment.
추가의 바람직한 방법에 따라서, 화학식 1의 화합물은 발포 도포법으로 직물 재료에 도포되고, 여기서 수성 발포체의 중량을 기준으로 하여, 0.001 내지 10중량%의 화학식 1의 화합물 및 임의로 발포 안정화제를 함유하는 수성 발포체가 직물 재료에 도포된다.According to a further preferred method, the compound of formula 1 is applied to the textile material by foam coating method, wherein it contains from 0.001 to 10% by weight of the compound of formula 1 and optionally a foam stabilizer, based on the weight of the aqueous foam An aqueous foam is applied to the fabric material.
패딩, 분무 또는 발포 도포는 염료와 함께 직물 재료에 화학식 1의 화합물을 도포함으로써 수행하거나(예를 들면, 염색 공정에서), 피니싱 공정과 같은 다른 직물 관련 공정에서 수행할 수 있다. 염료의 존재하에 화학식 1의 화합물로 처리하는 것이 바람직하다.Padding, spraying or foaming application can be carried out by applying the compound of formula 1 to the textile material together with the dye (eg in a dyeing process) or in other textile related processes such as finishing processes. Preference is given to treating with the compound of formula 1 in the presence of a dye.
당해 방법을 염료의 부재하에 수행하는 경우, 피니싱 공정에서 화학식 1의 화합물을 도포하는 것이 바람직하다.If the process is carried out in the absence of dyes, it is preferred to apply the compound of formula 1 in the finishing process.
직물 산업에서 통상적으로 사용되는 일부 중합체성 및 올리고머성 물질을 사용하는 경우, 목적하는 항진균 효능 및 항먼지 진드기 효능의 내구성을 추가로 향상시키는 데 도움이 될 수 있다. 이러한 물질은 각종 직물 재료에 용이한 보호 및/또는 다른 특성을 제공하는 수지 피닝싱제, 유연화제, 피복재, 고정화제 및/또는 다른 피니싱제, 예를 들면, 친수성 및 친유성 제제, 난연제 등을 포함하지만, 이로 제한되는 것은 아니다. 경제성 및 공정 용이성의 관점에서, 항미생물 처리를, 직물 산업에서 사용하는 다수의 다른 상이한 유형의 처리와 함께 수행할 수 있다.The use of some polymeric and oligomeric materials commonly used in the textile industry can help to further enhance the durability of the desired antifungal and anti-dust mite efficacy. Such materials include resin pinning agents, softening agents, coatings, fixatives and / or other finishing agents, such as hydrophilic and lipophilic agents, flame retardants, and the like, which provide easy protection and / or other properties to various textile materials. However, this is not limiting. In view of economics and ease of processing, antimicrobial treatment can be performed in conjunction with a number of other different types of treatments used in the textile industry.
또한, 화학식 1의 화합물의 도포는 염색 공정에서 수행할 수 있으며, 이는 패딩법, 분무법 또는 발포 도포법으로 수행된다. 이들 방법의 경우, 위의 조건 및 바람직한 사항들이 적용된다. 적합한 염료는 분산 염료, 염기성 염료, 산 염료, 직접 염료 또는 반응성 염료이다. 반응성 염료는 천연 폴리아미드- 또는 셀룰로스 함유 직물 재료에 특히 적합하다. 직접 염료는 셀룰로스 함유 직물 재료에 특히 적합하다. 염료는 아크리돈, 아조, 안트라퀴논, 쿠마린, 포르마잔, 메틴, 페리논, 나프토퀴논-이민, 퀴노프탈론, 스티릴 또는 니트로 염료를 포함하는 다양한 염료 부류에 속한다. 염료들의 혼합물도 사용할 수 있다.In addition, the application of the compound of formula 1 may be carried out in a dyeing process, which is carried out by a padding method, spraying method or foam coating method. For these methods, the above conditions and preferences apply. Suitable dyes are disperse dyes, basic dyes, acid dyes, direct dyes or reactive dyes. Reactive dyes are particularly suitable for natural polyamide- or cellulose containing textile materials. Direct dyes are particularly suitable for cellulose containing textile materials. Dyes belong to a variety of dye classes, including acridon, azo, anthraquinone, coumarin, formazan, methine, perinone, naphthoquinone-imine, quinophthalone, styryl or nitro dyes. Mixtures of dyes may also be used.
화학식 1의 화합물을 염색 공정에서 사용하는 경우, 당해 과정에서는 먼저 직물 재료를 화학식 1의 화합물로 처리한 후, 염색을 수행하거나, 바람직하게는 직물 재료를 화학식 1의 화합물 및 염료로 동시에 처리하도록 한다. 그러나, 먼저 염색 공정을 수행한 후, 이어서 화학식 1의 화합물을 도포할 수도 있다.When the compound of formula 1 is used in a dyeing process, the process first treats the fabric material with the compound of formula 1 and then dyes, or preferably the fabric material is treated simultaneously with the compound of formula 1 and a dye. . However, the dyeing process may be performed first, and then the compound of formula 1 may be applied.
처리액은 또한 추가의 성분, 예를 들면, 염색 보조제, 분산제, 담체, 울 보호제 및 습윤화제 뿐만 아니라 소포제를 함유할 수 있다The treatment liquid may also contain additional components such as dyeing aids, dispersants, carriers, wool protectants and wetting agents as well as defoamers.
처리액은 또한 광산, 전형적으로 황산 또는 인산이거나 통상적으로, 전형적으로 지방족 카복실산을 포함하는 유기산, 예를 들면, 포름산, 아세트산, 옥살산또는 시트르산 및/또는 염, 예를 들면, 암모늄 아세테이트, 황산암모늄 또는 나트륨 아세테이트를 함유할 수 있다. 산은 특히 리커의 pH를, 예를 들면, 3 내지 6으로 조정하는 데 사용한다.The treatment liquid is also a mineral acid, typically sulfuric acid or phosphoric acid or is typically an organic acid, typically containing an aliphatic carboxylic acid such as formic acid, acetic acid, oxalic acid or citric acid and / or salts such as ammonium acetate, ammonium sulfate or May contain sodium acetate. Acids are used in particular to adjust the pH of the liquor, for example to 3-6.
화학식 1의 화합물을 포함하는 염료 공정을 수행한 후, 직물 재료에 위에 기재된 바와 같은 열처리와 같은 고정 단계를 수행할 수 있다.After carrying out the dye process comprising the compound of formula 1, a fixing step such as heat treatment as described above on the fabric material can be performed.
위의 도포 공정 이외에, 염료의 존재 또는 부재하에 보통의 배기(exhaustion) 공정에 따라 화학식 1의 화합물을 도포할 수도 있다.In addition to the above application process, it is also possible to apply the compound of formula 1 in the presence or absence of a dye according to the usual exhaustion process.
또한, 화학식 1의 화합물을 드라이 클리닝 공정 동안 도포할 수 있다. 드라이 클리닝 공정에 따라서, 전형적으로 유기 용매, 특히 휘발성 유기 용매, 예를 들면, 퍼클로로에틸렌 또는 트리클로로에틸렌을 클리닝 매질로서 사용한다. 전형적인 드라이 클리닝 공정은 세척, 세정 및 건조 사이클로 이루어진다. 유기 용매의 중량을 기준으로 하여, 0.001 내지 10중량%의 화학식 1의 화합물을 함유하는 유기 용매를 사용하는 것이 바람직하다. 화학식 1의 화합물의 양에 관해서는, 패딩법에 대해 위에서 기재한 바와 같은 바람직한 사항이 적용된다.In addition, the compound of formula 1 may be applied during the dry cleaning process. Depending on the dry cleaning process, organic solvents, in particular volatile organic solvents such as perchloroethylene or trichloroethylene, are typically used as cleaning medium. Typical dry cleaning processes consist of washing, cleaning and drying cycles. Preference is given to using organic solvents containing from 0.001 to 10% by weight of the compound of formula 1, based on the weight of the organic solvent. Regarding the amount of the compound of formula 1, the preferences as described above for the padding method apply.
바람직한 양태에 따라서, 화학식 1의 화합물을 드라이 클리닝 공정 동안 직물 재료에 도포하고, 여기서 직물 재료는, 유기 용매의 중량을 기준으로 하여, 0.001 내지 10중량%의 화학식 1의 화합물을 함유하는 유기 용매, 바람직하게는 퍼클로로에틸렌 또는 트리클로로에틸렌으로 처리된다.According to a preferred embodiment, the compound of formula 1 is applied to the fabric material during a dry cleaning process, wherein the fabric material comprises from 0.001 to 10% by weight of an organic solvent, based on the weight of the organic solvent, It is preferably treated with perchloroethylene or trichloroethylene.
화학식 1의 화합물로 처리할 수 있는 직물 재료는, 예를 들면, 천연 또는 합성 폴리아미드(예를 들면, 울, 실크 및 나일론), 폴리우레탄, 폴리에스테르, 폴리프로필렌, 폴리에틸렌, 폴리아크릴로니트릴 및, 예를 들면, 천연 셀룰로스 섬유(예를 들면, 면, 린넨, 황마 및 대마) 및 비스코스 스테이플 섬유 및 재생 셀룰로스를 포함하는 모든 종류의 셀룰로스 함유 직물 재료; 또는 상기 섬유 재료의 블렌드, 예를 들면, 폴리아크릴로니트릴/폴리에스테르, 폴리아미드/폴리에스테르, 폴리에스테르/면, 폴리에스테르/비스코스 및 폴리에스테르/울을 포함하는 재료이다.Textile materials that can be treated with the compound of formula 1 include, for example, natural or synthetic polyamides (eg, wool, silk and nylon), polyurethanes, polyesters, polypropylene, polyethylene, polyacrylonitrile and Cellulose-containing textile materials of all kinds, including, for example, natural cellulose fibers (eg, cotton, linen, jute and hemp) and viscose staple fibers and regenerated cellulose; Or blends of such fiber materials, for example polyacrylonitrile / polyester, polyamide / polyester, polyester / cotton, polyester / viscose and polyester / wool.
바람직한 직물 재료는 울, 합성 폴리아미드, 폴리에스테르, 폴리프로필렌, 폴리에틸렌 및 셀룰로스 함유 직물 재료, 바람직하게는 면 또는 울, 특히 면을 포함하는 것들이다.Preferred textile materials are wool, synthetic polyamides, polyesters, polypropylene, polyethylene and cellulose containing textile materials, preferably cotton or wool, especially those comprising cotton.
직물 재료는 직물, 편물 또는 피스 제품(piece good), 예를 들면, 니트 제품, 부직물, 카펫, 사(yarn) 또는 스테이플 섬유로서, 상이한 형태로 제공될 수 있다. 부직물 재료, 특히 카펫이 바람직하다.The fabric material may be provided in different forms, as a woven, knitted or piece good, such as a knitted product, nonwoven, carpet, yarn or staple fiber. Nonwoven materials, in particular carpet, are preferred.
처리된 직물 또는 처리된 재료로부터 제조된 제품에 대해 다수의 최종 용도제품을 명명한다. 예를 들면, 카펫 및 넝마(rag), 베개 덮개, 침대 안감, 침대 시트, 매트릭스 및 매트릭스 아마포(ticking), 커튼, 깃털 이불(duvet) 및 깃털 이불 덮개, 엎호스테리(uphostery), 양말 및 의복이 포함되지만, 이로 제한되는 것은 아니다.A number of end use products are named for products made from treated fabrics or treated materials. For example, carpets and rags, pillow covers, bed linings, bed sheets, matrices and matrix tickings, curtains, duvet and duvet covers, uphostery, socks and apparel Include, but are not limited to.
추가로, 본 발명은 화학식 1의 화합물을 겔 상태의 폴리아크릴로니트릴 섬유에 도포함을 포함하는, 항진균성 및/또는 항먼지 진드기성을 향상시키기 위한 폴리아크릴로니트릴 섬유의 처리방법에 관한 것이다.Further, the present invention relates to a method for treating polyacrylonitrile fibers for improving antifungal and / or anti-dust mite, comprising coating a compound of formula 1 in a polyacrylonitrile fiber in a gel state. .
화학식 1Formula 1
폴리아크릴로니트릴 섬유의 겔 상태는 섬유의 제조 직후 팽창된 상태로서 이해된다(방금 방사된 섬유; 전형적으로, 섬유 제조에 사용된 비-수성 방적 용매의 벌크 제거 후). 이는 미국 특허 제4,563,191호에 기재되어 있다.The gel state of the polyacrylonitrile fiber is understood as the expanded state immediately after the preparation of the fiber (the fiber just spun; typically after bulk removal of the non-aqueous spinning solvent used to make the fiber). This is described in US Pat. No. 4,563,191.
이러한 처리는 통상적인 방법에 따라 수행할 수 있다. 예를 들면, 폴리아크릴로니트릴 섬유를, 수성 리커의 중량을 기준으로 하여, 0.001 내지 10중량%, 특히 0.01 내지 5중량%의 화학식 1의 화합물을 함유하는 수성 리커 속에서 처리한다. 화학식 1의 화합물의 양은 바람직하게는 0.01 내지 1중량%이다. 바람직하게는, 처리는 20 내지 100℃, 특히 40 내지 80℃의 온도에서 수행한다. 처리를 위해 수성 리커의 pH는 3 내지 6인 것이 바람직하다. 경우에 따라, 섬유를 처리 후에 압착시켜 특정 액체의 픽업 비율이, 예를 들면, 50 내지 300%, 특히 100 내지 300%가 되게 할 수 있다. 이어서, 처리된 섬유를, 예를 들면, 60 내지 200℃, 특히 90 내지 200℃의 온도에서 건조시키는 열처리를 수행할 수 있다.Such treatment can be carried out according to conventional methods. For example, polyacrylonitrile fibers are treated in an aqueous liquor containing 0.001 to 10% by weight, in particular 0.01 to 5% by weight, based on the weight of the aqueous liquor. The amount of the compound of formula 1 is preferably 0.01 to 1% by weight. Preferably, the treatment is carried out at a temperature of 20 to 100 ° C, in particular 40 to 80 ° C. The pH of the aqueous liquor is preferably 3-6 for the treatment. If desired, the fibers may be compressed after treatment so that the pick-up ratio of the particular liquid is, for example, from 50 to 300%, in particular from 100 to 300%. The heat treatment can then be carried out, for example, to dry the treated fibers at a temperature of from 60 to 200 ° C, in particular from 90 to 200 ° C.
또한, 위의 처리를 당해 섬유의 염색 공정 동안 수행할 수 있다. 이 경우, 겔 상태의 당해 섬유를 염색시키는 통상적인 염색방법을 적용한다. 사용할 염료는 염기성 염료를 포함한다. 이렇게 하여, 처리에 사용된 수성 리커에 염료가 존재한다.In addition, the above treatment can be carried out during the dyeing process of the fibers. In this case, the conventional dyeing method of dyeing the fiber in a gel state is applied. Dyes to be used include basic dyes. In this way, dye is present in the aqueous liquor used in the treatment.
또한, 화학식 1의 화합물을 사용하는 처리는, 섬유에 다양한 이점을 제공하여 다양한 기능을 제공하는 다른 화학적 제제와 함께 수행할 수 있다. 화학식 1의 화합물의 존재하에 항미생물 제제, 특히 그램 포지티브 및 그램 네가티브 세균을 포함하는 세균의 성장을 억제하는 데 양호한 활성을 나타내는 항미생물 물질을 함께 사용하여 처리하는 것이 바람직하다.In addition, treatments using the compound of Formula 1 may be performed with other chemical agents that provide a variety of benefits to the fiber to provide a variety of functions. Preference is given to using antimicrobial agents together with antimicrobial substances which exhibit good activity in inhibiting the growth of bacteria, including gram positive and gram negative bacteria, in the presence of a compound of formula (1).
위에 기재한 화학식 1의 화합물의 모든 도포방법에서, 항진균성을 향상시키기 위한 방법이 바람직하다. 마찬가지로, 항먼지 진드기성을 향상시키기 위한 방법이 바람직하다. 항진균성 및 항먼지 진드기성을 향상시키기 위한 방법이 매우 바람직하다.In all the application methods of the compound of the formula (1) described above, a method for improving antifungal properties is preferred. Similarly, a method for improving anti-dust mites is desirable. Very preferred are methods for improving antifungal and antidust mites.
아래의 실시예에서, 백분율은 중량 기준이다.In the examples below, the percentages are by weight.
실시예 1: 제형 1의 제조Example 1: Preparation of Formulation 1
규사 1000g을 미리 가한 적합한 용기 속에서 톨나프타트(Tolnaftat)[2-나프틸-N-메틸-N-(3-톨릴) 티오노카바메이트, Cas No. 2398-96-1) 35g, 나프탈렌설폰산/포름알데하이드 축합 생성물 105g 및 물 560㎖를 혼합한다. 이어서, 당해 혼합물을 텀블링기로 24시간 동안 균질화한다. 이어서, 규사를 여과 제거하고, 수득된 제형 1은 톨나프타트 5%를 함유한다. 당해 제형 중의 톨나프타트의 메디안(median) 입자 크기는 약 2㎛로 측정되고, 비표면적은 3.73m2/g이다.Tolnaftat [2-naphthyl-N-methyl-N- (3-tolyl) thionocarbamate, Cas No. 2398-96-1) 35 g, 105 g naphthalenesulfonic acid / formaldehyde condensation product and 560 ml of water are mixed. The mixture is then homogenized for 24 hours with a tumbling machine. The silica sand is then filtered off and the resulting formulation 1 contains 5% tolnaftat. The median particle size of tolnaftat in this formulation is measured at about 2 μm and the specific surface area is 3.73 m 2 / g.
(톨나프타트의 분자 구조)(Molecular structure of tolnafart)
실시예 2: 제형 1의 도입Example 2: Introduction of Formulation 1
제형 1 10g을 물 500㎖에 가한다. 면 섬유 100%로 제조된 편물을 당해 욕에 함침시킨 후, 액체 픽업 비율이 80% o.w.f(직물 중량 기준; on the weight fabric)가 되도록 랩 패딩 머신(Lab Padding Machine)[마티아스(Mathias)]으로 압착시킨다. 이어서, 수득된 직물을 팬 장착된 오븐(fan assisted oven) 속에서 5분 동안 120℃에서 건조시킨다.10 g of formulation 1 is added to 500 ml of water. The fabric made of 100% cotton fibers was impregnated in the bath and then with a Lab Padding Machine (Mathias) so that the liquid pickup ratio was 80% owf (on the weight fabric). Squeeze. The fabric obtained is then dried at 120 ° C. for 5 minutes in a fan assisted oven.
실시예 3: 제형 1의 도입Example 3: Introduction of Formulation 1
제형 1 10g을 디실란(Dicylan) AS[직물 위에 박막을 형성시킬 수 있는 제품, 제조사: 시바 스페셜티 케미칼스 인크.(Ciba Specialty Chemicals Inc.)(스위스 소재)] 40g과 함께 물 450㎖에 가한다. 면 섬유 100%로 제조된 편물을 당해 욕에 함침시킨 후, 액체 픽업 비율이 80% o.w.f가 되도록 랩 패딩 머신(마티아스)으로 압착시킨다. 이어서, 수득된 직물을 팬 장착된 오븐 속에서 5분 동안 120℃에서 건조시킨다.10 g of Formulation 1 is added to 450 ml of water with 40 g of Dilanlan AS (product capable of forming a thin film on the fabric, Ciba Specialty Chemicals Inc., Switzerland). . The knitted fabric made of 100% cotton fiber is impregnated in the bath and then pressed with a wrap padding machine (Matthias) so that the liquid pickup ratio is 80% o.w.f. The resulting fabric is then dried at 120 ° C. for 5 minutes in a fan mounted oven.
실시예 4: 제형 1의 도입Example 4: Introduction of Formulation 1
제형 1 10g을 물 500㎖에 가한다. 울 섬유 100%로 제조된 직물을 당해 욕에 함침시킨 후, 액체 픽업 비율이 80% o.w.f가 되도록 랩 패딩 머신(마티아스)으로 압착시킨다. 이어서, 수득된 직물을 팬 장착된 오븐 속에서 5분 동안 120℃에서건조시킨다.10 g of formulation 1 is added to 500 ml of water. The fabric made of 100% wool fibers is impregnated in the bath and then pressed with a wrap padding machine (Matthias) so that the liquid pickup ratio is 80% o.w.f. The fabric obtained is then dried at 120 ° C. for 5 minutes in a fan mounted oven.
실시예 5: 제형 1의 도입Example 5 Introduction of Formulation 1
제형 1을 물을 사용하여 1:1의 비율(중량/중량)로 희석시킨다. 이어서, 희석된 제형을 울 섬유 100%로 제조된 직물에, 직물의 중량을 기준으로 하여, 2%의 도입량으로 실온에서 분무한다. 처리된 직물을 오븐 속에서 10분 동안 70℃에서 건조시킨다.Formulation 1 is diluted with water in a ratio of 1: 1 (weight / weight). The diluted formulation is then sprayed onto a fabric made of 100% wool fibers at room temperature with an introduction amount of 2% based on the weight of the fabric. The treated fabric is dried at 70 ° C. for 10 minutes in an oven.
실시예 6: 제형 2의 제조 (비교 실시예)Example 6: Preparation of Formulation 2 (Comparative Example)
2,4-디클로로벤질 알콜 10g을 1,2-프로필렌 글리콜 87g에 용해시킨 후, 음이온성 계면활성제인 나트륨 라우릴 설페이트 3g을 가한다. 수득된 제형은 투명한 용액이다. 물로 추가로 희석할 때, 제형은 유백색 분산액이 된다.After dissolving 10 g of 2,4-dichlorobenzyl alcohol in 87 g of 1,2-propylene glycol, 3 g of sodium lauryl sulfate, an anionic surfactant, is added. The formulation obtained is a clear solution. Upon further dilution with water, the formulation becomes a milky dispersion.
실시예 7: 제형 2의 도입 (비교 실시예)Example 7: Introduction of Formulation 2 (Comparative Example)
제형 2 200g을 물 800㎖로 추가로 희석시켜 분산액을 제조한다. 면 직물을 픽업 비율 100%로 당해 분산액으로 패딩시킨다. 추가로, 패딩된 직물을 팬 장착된 오븐 속에서 70℃에서 건조시킨다.200 g of Formulation 2 are further diluted with 800 ml of water to prepare a dispersion. Cotton fabrics are padded with the dispersion at a pickup rate of 100%. In addition, the padded fabric is dried at 70 ° C. in a fan mounted oven.
실시예 8: 제형 3의 제조 (비교 실시예)Example 8: Preparation of Formulation 3 (Comparative Example)
a-(2-(4-클로로페닐)에틸)-a-(1,1-디메틸에틸)-1H-1,2,4-트리아졸-1-에탄올(CAS N0. 107534-96-3) 10g을 1,2-프로필렌 글리콜 30g 및 마를리폴(Marlipol) 24/99(비이온성 계면활성제) 60g에 가한다. 수득된 생성물을 제형 3으로서 표시한다.10 g of a- (2- (4-chlorophenyl) ethyl) -a- (1,1-dimethylethyl) -1H-1,2,4-triazole-1-ethanol (CAS N0.107534-96-3) Is added to 30 g of 1,2-propylene glycol and 60 g of Marlipol 24/99 (nonionic surfactant). The obtained product is shown as Formula 3.
실시예 9: 제형 3의 도입 (비교 실시예)Example 9 Introduction of Formulation 3 (Comparative Example)
제형 3 20g을 물 1000㎖에 가한다. 면 섬유 100%로 제조된 편물을 액체 픽업 비율이 80 내지 100%가 되도록 랩 패딩 머신(마티아스)으로 패딩시킨다. 추가로, 패딩된 직물을 팬 장착된 오븐 속에서 5분 동안 120℃에서 건조시킨다.20 g of formulation 3 is added to 1000 ml of water. Knitted fabrics made of 100% cotton fibers are padded with a wrap padding machine (Matthias) such that the liquid pick up ratio is 80-100%. In addition, the padded fabric is dried at 120 ° C. for 5 minutes in a fan mounted oven.
실시예 10: 제형 1의 도입Example 10 Introduction of Formulation 1
실시예 10에서는, 방금 방사된 습윤(수분 함량 약 170%) 폴리아크릴로니트릴 섬유를 처리한다. 처리 욕을 준비하고 이는 아래 성분으로 이루어진다:In Example 10, the just spun wet (water content about 170%) polyacrylonitrile fiber is treated. Prepare a treatment bath, which consists of the following ingredients:
제형 1 50gFormulation 1 50 g
티노산(Tinosan) AM 100[항미생물 제제, 제조사: 시바 스페셜티 케미칼스 인크.(스위스 소재)] 50gTinosan AM 100 [antimicrobial agent, manufacturer: Ciba Specialty Chemicals Inc. (Switzerland)] 50 g
물을 가하여 1000㎖가 되게 한다.Add water to make 1000 ml.
처리 욕의 pH는 4.5로 조정한다.The pH of the treatment bath is adjusted to 4.5.
처리 욕을 55 내지 60℃로 가열하고, 방금 방사된 습윤 폴리아크릴로니트릴 섬유를 당해 욕에 침지시키고 약 5초 동안 유지시킨 후, 총 습윤 픽업 비율이 약 200%가 되도록, 처리된 섬유를 랩 패딩 머신으로 압착시킨다. 이어서, 처리된 습윤 섬유를 오븐 속에서 15분 동안 160℃에서 건조시킨다.The treated bath is heated to 55-60 ° C. and the wet spun polyacrylonitrile fiber just immersed in the bath and held for about 5 seconds, and then the treated fiber is wrapped so that the total wet pick up ratio is about 200%. Press with a padding machine. The treated wet fibers are then dried at 160 ° C. for 15 minutes in an oven.
실시예 11: 직물 및 섬유의 세척Example 11: Washing of Fabrics and Fibers
처리된 직물 및/또는 섬유를 통상적인 세탁방법으로 가끔 세척하여, 각종 제제를 사용한 각종 처리에 의해 제공된 항미생물 활성 및/또는 항먼지 진드기 활성의 세척 내구성을 조사한다. 달리 언급하지 않는 한, 세척 조건은 아래와 같다:The treated fabrics and / or fibers are occasionally washed by conventional laundering methods to investigate the wash durability of the antimicrobial and / or anti-dust mite activity provided by various treatments with various formulations. Unless otherwise noted, cleaning conditions are as follows:
세척 조건: 표준방법에 따름(BS 4923 4A 표준)Cleaning conditions: according to standard method (BS 4923 4A standard)
세제: 페르실(Persil) 2.25% o.w.f.Detergent: Persil 2.25% o.w.f.
세탁기: 바스카터(Wascator) FOM 71 MPWashing machine: Wascator FOM 71 MP
온도: 50±3℃Temperature: 50 ± 3 ℃
주기 시간: 50분Cycle time: 50 minutes
리커 비율: 1:10Liquer Ratio: 1:10
헹굼: 4주기, 실온Rinsing: 4 cycles, room temperature
교반: 온화하게Agitation: gently
건조: 텀블 건조기Drying: Tumble Dryer
샘플을 다양한 주기, 예를 들면, 5주기, 10주기 및 20주기 동안 세척한다.Samples are washed for various cycles, for example 5, 10 and 20 cycles.
실시예 12: 제형 1로 처리된 직물의 항미생물 활성Example 12 Antimicrobial Activity of Fabrics Treated with Formulation 1
(a) 방법 원칙(a) Method principle
샘플로부터 직경이 2cm인 직물 원반을 펀칭한다. 원반을 진균 현탁액을 함유하는 고화된 한천의 상부 층에 도포한다(세척된 한천 슬랜트 5㎖를 용융 한천 500㎖에 가하고 5 내지 6㎖를 저부 층 상에 분포시킨다). 이어서, 모든 플레이트를 28℃에 방치한다. 배양 후, 샘플(20mm 원반) 주위의 억제 영역을 측정하고, 원반 아래에서의 성장을 평가하고[빈슨 평가(Vinson rating)] 표 1에 기재한다.Punch a fabric disc 2 cm in diameter from the sample. The disc is applied to the top layer of solidified agar containing the fungal suspension (5 ml of washed agar slant is added to 500 ml of molten agar and 5-6 ml is distributed on the bottom layer). Then all plates are left at 28 ° C. After incubation, the inhibition zone around the sample (20 mm disc) is measured, the growth under the disc is evaluated (Vinson rating) and listed in Table 1.
진균: 아스퍼질러스 나이거(Aspergillus niger) ATCC 6275Fungus: Aspergillus niger ATCC 6275
배지: Sabouraud agar + 4% 글루코스(2개 층의 한천: 균이 없는 저부 층 15㎖와 진균을 함유하는 상부 층 6㎖)Medium: Sabouraud agar + 4% glucose (two layers of agar: 15 ml bottom layer without bacteria and 6 ml top layer containing fungi)
배양: 28℃에서 5일Incubation: 5 days at 28 ° C
모든 시험은 2회 수행하며 두 개의 모든 결과는 위의 표에 기재되어 있다.All tests are performed twice and all two results are listed in the table above.
범례: ZI = 억제 영역 (단위: mm)Legend: ZI = zone of inhibition in mm
VR = 원반 아래에서의 성장에 대한 빈슨 평가VR = Vinson's assessment of growth under the disc
[참조: L.J. Vinson et al., J. Pharm. Sci. 50, 827-830, 1961][L.J. Vinson et al., J. Pharm. Sci. 50, 827-830, 1961]
0 = 원반 아래에서의 성장이 활발함(활성을 갖지 않음)0 = active growth under disc (no activity)
4 = 원반 아래에서 성장하지 못함(활성이 양호함)4 = no growth under the disc (good activity)
실시예 13: 제형 1로 처리된 직물의 항미생물 활성Example 13: Antimicrobial Activity of Fabrics Treated with Formulation 1
또한 실시예 10에 기재된 바와 같이 제조된 폴리아크릴로니트릴 섬유의 항미생물 성능을 평가한다. 시험용으로 진균 균주 이외에, 대표적인 세균(그램 포지티브 및 그램 네가티브)도 선택한다. 세균에 관련된 시험을 수행하는 경우 배양은 하룻밤 동안 수행한다(18 내지 24시간). 그 외의 시험 방법은 실시예 12에 기재된 바와 동일하다. 억제 영역으로 나타낸 결과를 아래의 표 2에 나타내었다.The antimicrobial performance of polyacrylonitrile fibers prepared as described in Example 10 is also evaluated. In addition to fungal strains for testing, representative bacteria (gram positive and gram negative) are also selected. Cultures are performed overnight (18-24 hours) when performing tests involving bacteria. Other test methods are the same as described in Example 12. The results represented by the inhibitory region are shown in Table 2 below.
실시예 14: 제형 2로 처리된 직물의 항미생물 활성 (비교 실시예)Example 14 Antimicrobial Activity of Fabrics Treated with Formulation 2 (Comparative Example)
제형 2로 처리된 샘플의 항미생물 성능을 실시예 12에 기재된 방법에 따라서 평가한다. 이렇게 하여 아래의 결과를 수득한다:The antimicrobial performance of the sample treated with Formulation 2 is evaluated according to the method described in Example 12. This gives the following results:
모든 시험은 2회 수행하며 두 개의 모든 결과는 위의 표에 기재되어 있다.All tests are performed twice and all two results are listed in the table above.
실시예 15: 제형 3으로 처리된 직물의 항미생물 활성 (비교 실시예)Example 15 Antimicrobial Activity of Fabrics Treated with Formulation 3 (Comparative Example)
실시예 12에 기재된 방법에 따라서 시험을 수행한다.The test is carried out according to the method described in Example 12.
모든 시험은 2회 수행하며 두 개의 모든 결과는 위의 표에 기재되어 있다.All tests are performed twice and all two results are listed in the table above.
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ES2472427T3 (en) | 2010-03-18 | 2014-07-01 | Recuperación De Materiales Textiles, S.A. | Process and installation for the continuous treatment of solid fibrous materials in bulk |
CN102304854A (en) * | 2011-06-24 | 2012-01-04 | 江苏阳光股份有限公司 | Probiotics-worsted fabric and production method thereof |
US10531814B2 (en) * | 2013-07-25 | 2020-01-14 | Medtronic Navigation, Inc. | Method and apparatus for moving a reference device |
CN103556477B (en) * | 2013-10-24 | 2016-03-02 | 武汉纺织大学 | A kind of method of down fiber surface recombination function nano particle |
CN104433705A (en) * | 2014-12-23 | 2015-03-25 | 常熟市洁倍特地毯有限公司 | Acarid-proof and antibacterial carpet |
US10412962B2 (en) * | 2015-11-25 | 2019-09-17 | North Carolina Agricultural And Technical State University | Antifungal compositions and methods of use thereof |
CN105463842A (en) * | 2015-12-15 | 2016-04-06 | 桐乡市濮院毛针织技术服务中心 | Moth-proofing finishing agent for wool fabric |
CN108642877A (en) * | 2018-04-19 | 2018-10-12 | 田秋珍 | A kind of preparation method of natural fabric long-acting special mite-proof agent |
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US3653234A (en) * | 1970-11-05 | 1972-04-04 | Stauffer Chemical Co | Control injection system for drycleaning apparatus in systems |
US3926831A (en) * | 1972-07-12 | 1975-12-16 | Erhard Sonnengruber | Dry-cleaning agent |
DE2338633A1 (en) * | 1973-07-30 | 1975-02-20 | Peter Dr Med Schneider | Antimycotic impregnation of textiles - by applying antimycotic agents as aq. solns. or emulsions |
US4769013A (en) * | 1982-09-13 | 1988-09-06 | Hydromer, Inc. | Bio-effecting medical material and device |
US4494956A (en) * | 1982-12-14 | 1985-01-22 | Ciba-Geigy Corporation | Process for pad dyeing cellulosic textile materials |
US4601716A (en) * | 1985-04-11 | 1986-07-22 | Smith Lonnie W | Disposable sanitary sheath for males |
US5632727A (en) * | 1988-10-03 | 1997-05-27 | Atrix Laboratories, Inc. | Biodegradable film dressing and method for its formation |
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US5238682A (en) * | 1990-11-30 | 1993-08-24 | Mitsubishi Rayon Co., Ltd. | Insectproofing fibers and method for preparing the same |
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US6117119A (en) * | 1998-08-28 | 2000-09-12 | Silipos, Inc. | Gelatinous body protection article having a therapeutic additive |
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