KR20010083861A - The manufacturing method of non coloring plaser finishings for EIFS - Google Patents

The manufacturing method of non coloring plaser finishings for EIFS Download PDF

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KR20010083861A
KR20010083861A KR1020010039944A KR20010039944A KR20010083861A KR 20010083861 A KR20010083861 A KR 20010083861A KR 1020010039944 A KR1020010039944 A KR 1020010039944A KR 20010039944 A KR20010039944 A KR 20010039944A KR 20010083861 A KR20010083861 A KR 20010083861A
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mixing
manufacturing
water
eifs
antifoaming agent
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KR1020010039944A
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Korean (ko)
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홍승익
이광철
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정진황
이림산업 주식회사
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    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02—Macromolecular compounds
    • C04B26/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/06—Acrylates
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02—Granular materials, e.g. microballoons
    • C04B14/04—Silica-rich materials; Silicates
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
    • C04B20/02—Treatment
    • C04B20/023—Chemical treatment
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02—Granular materials, e.g. microballoons
    • C04B14/26—Carbonates
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02—Granular materials, e.g. microballoons
    • C04B14/26—Carbonates
    • C04B14/28—Carbonates of calcium
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/40—Surface-active agents, dispersants
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/44—Thickening, gelling or viscosity increasing agents
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/50—Defoamers, air detrainers
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00482—Coating or impregnation materials

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Civil Engineering (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Paints Or Removers (AREA)

Abstract

PURPOSE: Provided is a manufacturing method of uncolored exterior insulation and finishing coatings of 2-liquid type which are used with a colorant on the construction site to express colors unlike a conventional colored coatings. CONSTITUTION: The finishing coatings are prepared by the following steps: mixing 2.51wt.% of water with 0.10wt.% of retardant, 0.04wt.% of dispersant, 0.08wt.% of silicon-based defoamer, 0.06wt.% of preservative and 0.17wt.% of plasticizer; adding 19.27wt.% of pure acrylic emulsion resin, 5.24wt.% of CaCO3 and 5wt.% of methyl cellulose as a thickener; adding 66.20wt.% of dolomite and silica, then mixing for 15min.; adding NH4OH to adjust pH8-9 and 0.08wt.% of silicon-based antifoaming agent.

Description

조색하지 않은 기능성 외벽단열 바탕 마감재 제조방법 {The manufacturing method of non coloring plaser finishings for EIFS}The manufacturing method of non coloring plaser finishings for EIFS}

본 발명은 건축 외벽단열마감시스템(EIFS)의 마감재의 경우에 기존 제품과는 달리 제조 공장에서 조색을 하지 않고 칼라는 나중에 시공 현장에서 미리 조성된 칼라 조색제를 본 발명의 마감재에 투입한 후에 교반하여 골고루 혼합하여 부여하거나 칼라가 부여된 상도마감재로 상도 도장하여 칼라를 부여하되 마감재 자체는 미리 조색을 하지 않고 조색제의 혼합과 도장이 원활하고, 문양 내기가 용이하도록 자재 성분을 조정하였으며 여러 가지 기능성을 별도로 부여한 외벽 단열 바탕 마감재를 제조 방법을 제공한다.According to the present invention, in the case of the finishing material of the building exterior thermal insulation finishing system (EIFS), unlike the existing product, the color is not adjusted in the manufacturing plant, and the color is added to the finishing material of the present invention by adding a color colorant prepared in the construction site later to the stirring material. It is applied by mixing evenly or by applying top coat with colored top coat. But the finish itself is not pre-colored but the mixing and painting of the colorant is smooth and the material composition is adjusted to make the pattern easier. Provides a method for producing a separately provided exterior wall insulation base finish.

기존의 EIFS 마감재를 보면, 소위 드라이비트(미국 건축 자재 제조하는 특정 회사의 상호 및 상품명)이라고 하기도 하는데 단열 효과 측면에서는 미주 대륙의 경우에 신축 건물의 경우 거의 전부 채택하는 등 상당한 효과가 있는 것으로실증되고 있지만 의장 효과 측면에 있어서는 제조공장에 색상별로 주문하여 조색된 상태로 납품을 받아 현장시공 도구인 기고대 등으로 밀어서 큰 규사 혹은 돌로마이트 알갱이가 긁힌 형태의 무늬를 내는 것이 거의 유일한 시공 방법으로 초보적인 상태를 벗어 나지 못하고 있다.Existing EIFS finishes are also called drybits (trade names and brand names of certain companies that manufacture US building materials), but in terms of thermal insulation, they have significant effects, such as the adoption of almost all new buildings in the Americas. However, in terms of the design effect, it is almost the only construction method to order by color to the manufacturing factory, receive the delivery in color, and push it to the flagging platform, which is a field construction tool, to form a pattern of scratches in the form of large silica sand or dolomite grains. It is not getting out of state.

그리고 위와 같은 EIFS 마감재의 문양내기의 제한성을 탈피하기 위하여 현장에서 다양한 문양내기가 용이한 텍스처드 마감재(Textured finishing coatings) 제품들이 많이 나오고 있는데 이것들도 결국 모두 1액형 타입의 최종 마감재로서 칼라를 미리 부여하는 것을 전제로 하기 때문에 결국 주문생산이라는 생산적인 측면에서 제한성을 갖게 된다. 그리고 현장에서 백색 마감재를 구입하여 작업자가 직접 원색의 조색제를 구입하여 조색하는 경우가 있는데 이 경우에는 비록 백색 마감재라고 하더라도 생산과정에서 백색 안료가 투입되기 때문에 다른 조색안료가 들어가면 주로 백색안료가 다른 칼라를 죽이는 현상이 나타나기 때문에 제대로 된 일률적이고 항상성 있는 칼라 부여를 부여하기가 상당히 어렵다.In order to overcome the limitations of the EIFS finishes, there are a number of textured finish coatings that can be easily patterned in the field. Because of the premise of doing so, there is a limit in the productive aspect of order production. In addition, a white finishing material is purchased at the site, and a worker directly purchases a coloring agent of primary colors. In this case, even if a white finishing material is used, white pigment is introduced in the production process. Because of the phenomenon of killing, it is very difficult to give proper uniformity and homeostasis.

따라서 본 발명은 건축 외벽단열마감시스템(EIFS)의 마감재의 경우에 기존 제품과는 달리 칼라에 관한 한 2액형 타입으로 처리하도록 하여 제조공장에 조색을 하여 출시하지 않고 칼라는 나중에 작업 현장에서 칼라를 임의로 조합하도록 하되 최소의 노력으로 쉽게 믹싱하여 이색없이 마감 도장을 할 수 있도록 하려면 여기에 사용될 상도 마감재는 현장에서 여러가지 조색제와 쉽게 혼합되어 일률적인 조색 효과를 얻을 수 있어야 하고, 기타 상도 마감재 고유의 접착 및 도장이 원활하고, 문양 내기가 용이하도록 자재 성분을 조정하고 여기에 여러 가지 기능성, 즉 내수성, 발수성, 내오염성 등을 별도로 부여한 조색하지 않은 마감재로 설계되고 제조될 필요성이 있다.Therefore, in the case of the finishing material of the building exterior thermal insulation finishing system (EIFS), unlike the existing product, the color is treated as a two-component type as far as color is concerned in the manufacturing plant and the color is not released and the collar is later released on the job site. If you want to mix them arbitrarily, but you can easily mix them with minimal effort and finish them without any unusual color, the top finishes to be used should be easily mixed with various colorants in the field to achieve uniform coloring effect. And there is a need to be designed and manufactured with an uncolored finish that adjusts the material composition so that the coating is smooth, and the pattern is easy to apply, and which has various functions added thereto, namely, water resistance, water repellency, and stain resistance.

본 발명은 위와 같은 새로운 타입의 표준 마감재에 대한 기술적인 수요를 충족시키는 제품을 제조하는 방법을 제공하는데 그 목적이 있다.It is an object of the present invention to provide a method for manufacturing a product that meets the technical demand for such a new type of standard finish.

상기 목적을 달성하기 위한 본 발명의 조색하지 않은 기능성 외벽단열 바탕 마감재 제조방법은 혼합 믹서에 물에다가 도막 건조시간을 조정하기 위한 지연제를 투입하여 교반한 후에, 분산제, 실리콘계 소포제, 방부제 도막 경화를 위한 가소제 등을 투입한 후에 혼합하는 공정과 바인더로서 푸어(pure) 아크릴 에먼젼 수지를 투입하여 다시 혼합한 후에 석회질 필러를 넣고 혼합하고, 여기에 칙소성을 높이기 위한 증점제를 물에 미리 충분히 혼합한 후에 투입하여 혼합시키고 돌로마이트 및 규사를 입도별로 구별하여 넣아 혼합한 후에 암모니아를 투입하여 ph 8~9정도로 조정한다. 그런 후에 다시 실리콘계 소포제를 다시 투입하여 기포를 적정 수준까지 없앤 후에 포장한다.In order to achieve the above object, the present invention provides a method of manufacturing a non-colored functional outer wall insulation base finish of the present invention by adding a retarder for adjusting the coating drying time to water in a mixing mixer, followed by stirring, followed by dispersing agent, silicone antifoaming agent, and preservative film curing. After adding a plasticizer and the like, the mixture and a pure acrylic emulsion resin as a binder were added and mixed again, followed by adding a lime filler and mixing the thickener to increase thixotropy in water in advance. After mixing, add dolomite and silica sand by particle size, mix and mix, and add ammonia to adjust pH 8 ~ 9. After that, the silicon-based antifoaming agent is added again to remove bubbles to an appropriate level and then packed.

위와 같은 공정으로 조색하지 않은 기능성 외벽단열 바탕 마감재를 제조할 수 있다.The above process can produce a functional exterior wall insulation base finish that is not toned.

이하 본 발명의 실시예를 상세히 설명하면 다음과 같다.Hereinafter, an embodiment of the present invention will be described in detail.

우선 혼합 믹서에 물 2.51 중량%에다가 도막 건조시간을 조정하기 위한 지연제 0.10 중량%를 투입하여 교반한 후에, 분산제 0.04 중량%, 실리콘계 소포제 0.08 중량%, 방부제 0.06 중량%, 도막 경화를 위한 가소제 0.17 중량% 등을 투입한 후에 3분 정도 교반하여 혼합하는 공정과 바인더로서 푸어(pure) 아크릴 에먼젼 수지 19.27 중량%를 투입하여 5분 정도 교반하여 다시 혼합한 후에 석회질 필러인 탄산칼슘 5.24 중량%를 넣고 5분 정도 교반하여 혼합하고, 여기에 칙소성을 높이기 위한 증점제 메칠 셀루로즈 5 중량%를 물에 미리 충분히 혼합한 후에 투입하여 2분 정도 교반하여 혼합시키고 돌로마이트 및 규사를 입도별로 구별하여 합쳐서 66.20 중량%투입하여 15분 정도 교반하여 혼합한 후에 암모니아를 0.12 중량% 정도 투입하여 ph 8~9정도로 조정한다. 그런 후에 다시 실리콘계 소포제 0.08 중량%를 다시 투입하여 기포를 적정 수준까지 없앤 후에 포장한다.First, 2.51% by weight of water and 0.10% by weight of a retarder for adjusting the film drying time were added to the mixer, followed by stirring, followed by 0.04% by weight of a dispersant, 0.08% by weight of an antifoaming agent, 0.06% by weight of a preservative, and a plasticizer 0.17 for curing the film. After adding about 3% by weight, the mixture was stirred for about 3 minutes and 19.27% by weight of a pure acrylic emulsion resin was added as a binder, and the mixture was stirred for about 5 minutes and mixed again. Add 5% by weight of the thickener methyl cellulose in advance to increase thixotropy in water, and add it after stirring for 2 minutes, mix and mix Dolomite and silica sand separately by particle size. Add 15% by weight, stir for 15 minutes, mix, and add 0.12% by weight of ammonia to adjust the pH to about 8-9. Then, 0.08% by weight of the silicone antifoaming agent is added again to remove bubbles to an appropriate level, and then packaged.

위 공정에서 사용하는 필러는 석회질 필러인 탄산칼슘과 돌로마이트가 미세한 가루분을 포함하고 있어 마감재를 시공한 후에 칼라상도의 흡착이 용이하도록 하고 바인더로는 위 필러에 대한 강력한 접착력과 자체 내수성을 부여하며 내마모성 및 방수성, 내후성이 우수할 뿐만 아니라 위 석회질 필러, 돌로마이트 및 규사 등에 혼화성이 양호한 푸어 아크릴 에멀젼 수지를 사용하는 것이 바람직하다.The filler used in the above process includes calcium carbonate, calcium carbonate and dolomite, which are finely powdered to facilitate the adsorption of color coating after finishing the finishing material. And it is preferable to use the pure acrylic emulsion resin which is excellent in water resistance and weather resistance as well as good miscibility with gastric filler, dolomite, and silica sand.

기타 추가로 설게되는 기능성에 대하여는기능 부여를 위한 첨가제를 추가로 첨가할 수 있을 것이다.With respect to the additional functionalities, additional additives for imparting functionality may be added.

이러한 공정을 통하여 조색하지 않은 기능성 외벽단열 바탕 마감재가 완성된다.Through this process, an uncolored functional exterior wall insulation base finish is completed.

따라서 본 발명은 건축 외벽단열마감시스템(EIFS)의 마감재의 경우에 기존 제품이 만약 시공현장에서 현장작업자가 조색제를 투입하여 칼라 조색을 하면 칼라의 균일성이 없기 때문에 제조공장에 주문을 하여 제한된 종류의 조색을 한 제품을 납품받으며 단순한 패턴의 문양내기 방식으로 시공하고 있는데 위와 같은 기존의 작업 형태에서 벗어나 칼라는 나중에 현장에서 별도의 액상의 상도 마감재로 자유스럽게 마감할 수 있도록 하거나 원색이 아니고 별도의 미리 혼합하여 설계 조성된 조색제를 혼합하여 교반하여 사용하는 바탕 바름 용도의 마감재를 만들려면 우선적으로 여러 가지 타입의 칼라 조색제의 혼합이 잘되고 자체 접착력이 강하며 도장이 원활하고, 문양 내기가 용이하도록 자재 성분을 조정하고 여러 가지 기능성, 즉 내수성, 발수성, 내오염성 등을 별도로 부여한 조색하지 않은 마감재로 설계되고 제조될 필요성이 있는데 본 발명은 위와 같은 새로운 타입의 표준 마감재에 대한 기술적인 수요를 충족시키는 제품을 제조하는 방법을 제공하는데 그 효과가 있다.Therefore, the present invention is a limited type of existing products in the case of the finishing material of the building exterior insulation thermal insulation system (EIFS) because the uniformity of the color if the field worker puts the colorant at the construction site because there is no uniformity of the color The product is delivered in the form of a simple pattern glyph, and the color can be freely finished later in the field with a liquid top coat finish or it is not the primary color. In order to make the finishing material for the grounding application that mixes and mixes the colorant prepared by mixing in advance, it is necessary to mix various types of color colorant first, and to make the self-adhesive, smooth, and easy to pattern. To adjust the components and to various functionalities: water resistance, water repellency, There is a need to be designed and made of a non-tinted finish gave the stain resistance, etc. The present invention can additionally have the effect to provide a method of manufacturing products that meet the technical demand for the above standard finish of such a new type.

Claims (1)

혼합 믹서에 물에다가 도막 건조시간을 조정하기 위한 지연제를 투입하여 교반한 후에, 분산제, 실리콘계 소포제, 방부제 도막 경화를 위한 가소제 등을 투입한 후에 혼합하는 공정과;Adding a retarder for adjusting the coating film drying time to water in the mixing mixer, followed by stirring, and then adding a dispersant, a silicone-based antifoaming agent, a plasticizer for curing the preservative coating film, and then mixing; 바인더로서 푸어(pure) 아크릴 에먼젼 수지를 투입하여 다시 혼합한 후에 석회질 필러를 넣고 혼합하고, 여기에 칙소성을 높이기 위한 증점제를 물에 미리 충분히 혼합한 후에 투입하여 혼합시키는 공정과;Adding a pure acrylic emulsion resin as a binder and mixing the mixture, followed by mixing and adding a calcareous filler, and adding and mixing a thickener for improving thixotropy with water in advance before mixing; 돌로마이트 및 규사를 입도별로 구별하여 넣아 혼합한 후에 암모니아를 투입하여 ph 8~9정도로 조정한 후에 다시 실리콘계 소포제를 다시 투입하여 기포를 적정 수준까지 없애는 공정을 특징으로 하는 조색하지 않은 기능성 외벽단열 바탕 마감재의 제조 방법.After mixing dolomite and silica sand by particle size and mixing, adjust the pH to 8 ~ 9 by adding ammonia, and then add silicon-based antifoaming agent again to remove bubbles to an appropriate level. Method of preparation.
KR1020010039944A 2001-07-05 2001-07-05 The manufacturing method of non coloring plaser finishings for EIFS KR20010083861A (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0229467A (en) * 1988-07-19 1990-01-31 Shinpo Hachirou Film finishing agent
US5753036A (en) * 1997-04-21 1998-05-19 Air Products And Chemicals, Inc. Poly(vinyl alcohol) stabilized acrylic polymer modified hydraulic cement systems
JPH10245255A (en) * 1997-03-05 1998-09-14 Fujikawa Kenzai Kogyo Kk Highly moisture-permeable inorganic diatomaceous earth-based finish agent and execution using the same
KR20010007808A (en) * 2000-09-27 2001-02-05 홍승익 The manufacturing method of mono-fluid type plaster finishings
KR100298679B1 (en) * 1999-07-12 2001-09-13 김승배 Finishing composition comprising Fluororesin
KR100320917B1 (en) * 2000-05-10 2002-01-23 오봉석 Coating and finish-processing material using the inorganic compound powder as the main component

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0229467A (en) * 1988-07-19 1990-01-31 Shinpo Hachirou Film finishing agent
JPH10245255A (en) * 1997-03-05 1998-09-14 Fujikawa Kenzai Kogyo Kk Highly moisture-permeable inorganic diatomaceous earth-based finish agent and execution using the same
US5753036A (en) * 1997-04-21 1998-05-19 Air Products And Chemicals, Inc. Poly(vinyl alcohol) stabilized acrylic polymer modified hydraulic cement systems
KR100298679B1 (en) * 1999-07-12 2001-09-13 김승배 Finishing composition comprising Fluororesin
KR100320917B1 (en) * 2000-05-10 2002-01-23 오봉석 Coating and finish-processing material using the inorganic compound powder as the main component
KR20010007808A (en) * 2000-09-27 2001-02-05 홍승익 The manufacturing method of mono-fluid type plaster finishings

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