KR20010007981A - Functional rib seasionings - Google Patents

Functional rib seasionings Download PDF

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KR20010007981A
KR20010007981A KR1020000064509A KR20000064509A KR20010007981A KR 20010007981 A KR20010007981 A KR 20010007981A KR 1020000064509 A KR1020000064509 A KR 1020000064509A KR 20000064509 A KR20000064509 A KR 20000064509A KR 20010007981 A KR20010007981 A KR 20010007981A
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South Korea
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weight
chitosan
rib
chitin
seasoning
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KR1020000064509A
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Korean (ko)
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김숙희
우기민
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김숙희
우기민
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Priority to KR1020000064509A priority Critical patent/KR20010007981A/en
Publication of KR20010007981A publication Critical patent/KR20010007981A/en

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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L23/00Soups; Sauces; Preparation or treatment thereof
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L13/00Meat products; Meat meal; Preparation or treatment thereof
    • A23L13/06Meat products; Meat meal; Preparation or treatment thereof with gravy or sauce
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L27/00Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2200/00Function of food ingredients
    • A23V2200/30Foods, ingredients or supplements having a functional effect on health
    • A23V2200/3262Foods, ingredients or supplements having a functional effect on health having an effect on blood cholesterol
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2250/00Food ingredients
    • A23V2250/28Oligosaccharides
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2250/00Food ingredients
    • A23V2250/50Polysaccharides, gums
    • A23V2250/51Polysaccharide
    • A23V2250/511Chitin, chitosan

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  • Health & Medical Sciences (AREA)
  • Nutrition Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Coloring Foods And Improving Nutritive Qualities (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

PURPOSE: A functional seasoning for ribs of beef or pork containing chitin, chitosan, and derivatives of chitin and chitosan, or chito-oligosaccharide is provided, which prevents hypertension and hypercholesterolemia and has improved storage life. CONSTITUTION: The seasoning comprises 30-50wt% of pear, 10-20wt% of onion, 0.01-1wt% of ground pepper, 1-10wt% of sesame oil, 0.01-1wt% of green onion, 0.01-10wt% of sugar, 0.1-15wt% of soy sauce, 1-10wt% of starch syrup, 0.2-10wt% of cooking oil, 1-5wt% of garlic, 1-5wt% of refined rice wine, 0.1-1wt% of sesame and 0.1-5wt% of starch. The seasoning also contains 0.01-1wt% of chitin, chitosan and the derivatives having a molecular weight of about 10,000-100,000 or chito-oligosaccharide having a molecular weight of less than 10,000.

Description

기능성 갈비양념{Functional rib seasionings}Functional rib seasioning

양념장류는 조미식품 중에서는 신장이 크게 기대되는 분야인데 이는 양념장류의 수요가 가정용과 업무용의 양면에서 증대되고 있기 때문이다. 조리기술이 미흡한 젊은 주부층의 수요증대와 외식산업 특히 기업의 구조조정 등으로 퇴출된 사람들이 신규로 시작하는 소규모 외식업체에서의 업무용 양념장류의 수요 증대가 영향을 미치고 있다. 또한 많은 현대인들은 고염분 섭취와 고콜레스테롤 섭취에 대해 거부감을 가지고 있으므로 본 발명에서는 이들의 흡수를 억제하고, 배설을 촉진시키는 것으로 알려진 키토산을 갈비양념에 첨가하여 보존성 및 기능성을 증대시킨 기능성 갈비양념을 제조하였다.Seasoned spice is an area that is expected to grow significantly among seasoned foods because demand for spice is increasing in both home and business use. Increasing demand for young housewives, who lack cooking skills, and the rise in demand for business seasonings at small restaurants, which are newly launched by those who have been retired from the restaurant industry, especially corporate restructuring, are having an impact. In addition, many modern people have a high sensitivity to high salt intake and high cholesterol intake in the present invention by adding chitosan known to inhibit their absorption and promote excretion in rib seasoning to prepare a functional rib rib seasoning to increase the preservation and functionality It was.

본 발명은 갈비양념에 키틴, 키토산, 키틴·키토산 유도체 또는 그 올리고당을 첨가하여 유통기한을 연장하고, 고혈압, 고콜레스테롤혈증을 예방할 수 있는 기능성 갈비양념의 제조에 관한 것이다.The present invention relates to the preparation of a functional rib marinade that can extend the shelf life by adding chitin, chitosan, chitin chitosan derivatives or oligosaccharides thereof to the rib marinade, and to prevent hypertension and hypercholesterolemia.

키틴은 식용으로 할 수 있는 게 또는 새우를 원료로 하여 묽은 수산화나트륨 용액으로 단백질을 제거시킨 후 이를 묽은 염산용액으로 칼슘을 제거시켜 얻어진 N-아세틸글루코사민의 폴리머이며 이를 다시 진한 수산화나트륨 수용액으로 탈아세틸화하여 얻어지는 것이 키토산이다. 키토올리고당은 아세틸글루코사민 또는 디아세틸글루코사민의 단당체로 2당 내지는 10당의 중합도를 가지는 단일 중합체로서 키틴, 키토산을 산가수분해 또는 효소 분해하여 생성되는 것이다.Chitin is a polymer of N-acetylglucosamine obtained by removing protein with dilute sodium hydroxide solution by using crab or shrimp which can be eaten and then decalcifying it with concentrated sodium hydroxide solution. It is chitosan obtained by converting. Chitooligosaccharide is a monosaccharide of acetylglucosamine or diacetylglucosamine, a single polymer having a degree of polymerization of 2 to 10 sugars, which is produced by acid hydrolysis or enzymatic digestion of chitin and chitosan.

키틴, 키토산은 공업용 재료로서 폐수처리제 혹은 중금속 흡착제, 생물공학적 재료로서 효소고정화용 담체, 크로마토그래피용 수지 및 기능성막, 농업용 재료로서 병충해 예방제, 의료용 재료로서 인공피부 등 대부분 고분자물질로서 이용되어 왔다. 그러나 최근 키틴, 키토산 및 그 유도체가 면역증강 및 부활작용에 의한 항암활성, 항균활성, 체내 콜레스테롤 개선작용 및 고혈압 억제작용 등 여러 가지 생리활성을 가지고 있다는 사실이 밝혀짐으로써 현재 생리기능성 신소재로서 연구개발이 활발히 진행되고 있다.Chitin and chitosan have been mostly used as polymer materials such as wastewater treatment agents or heavy metal adsorbents as industrial materials, enzyme fixation carriers as biological materials, chromatography resins and functional membranes, pest control agents as agricultural materials, and artificial skin as medical materials. However, it has been recently discovered that chitin, chitosan and its derivatives have various physiological activities such as anticancer activity, antibacterial activity, body cholesterol improvement effect and hypertension suppression by immunopotentiation and reactivation. This is actively going on.

키틴과 키토산을 동물에게 경구투여하여도 독성이 거의 없고 장내의 세균이 개선되며 염소이온이나 담즙산과 결합되어 이들을 체외로 배설시킴으로써 혈청 콜레스테롤 값을 저하시킴과 동시에 혈압강하 효과도 나타낸다. 키토산의 항균력을 조사한 연구결과에 의하면 분자량 2,800,000의 고분자 키토산은 2,000ppm의 농도로 대장균의 증식을 억제시킬 수 있었으며, 토양에서 분리한 Aspergillus CHS1과 Penicillium CHS2균주가 생산한 키토산 분해효소로 키토산을 가수분해시킬 때 분해가 진행됨에 따라 항균력이 증대되었는데. 키토산 1% 용액의 상대점도가 3.0∼1.6일때는 100ppm의 농도로 대장균의 증식을 억제시킬 수 있다. 탈아세틸화 처리시 50% 수산화 나트륨 용액에서 146℃로 8시간 처리하여 얻은 분자량 35,000의 저분자 키토산은 75ppm으로 대장균의 증식을 억제시킬 수 있어 고분자 키토산에 비해 20배 가량 항균력이 증대되었고, 항균력이 높은 키토산의 분자량 범위는 60,000 내지 100,000이다. 한편 이 분자량 범위를 벗어나면 항균력은 저하되었다. 또한 키토산은 분자량이 저하됨에 따라 고유의 떫은 맛이 감소하며, 높은 항균력의 저분자 키토산은 고분자 키토산에 비해 떫은 맛이 매우 약하였다. 즉, 키틴, 키토산의 신맛과 끝에 나타나는 떫은 맛을 고려하여 생리적 기능이 있는 범위에서 최소한의 첨가로 식품의 맛을 저하시키지 않도록 함량을 조절할 필요가 있다.Oral administration of chitin and chitosan to animals produces little toxicity, intestinal bacteria are improved, and combined with chlorine ions or bile acids to excrete them in vitro to lower serum cholesterol and lower blood pressure. According to the study results of testing the antimicrobial activity of the chitosan molecular weight chitosan with a molecular weight of 2,800,000 were able to inhibit the growth of E. coli at a concentration of 2,000ppm, the chitosan in the chitosan-decomposing enzyme by an Aspergillus and Penicillium CHS 2 CHS 1 strain isolated from soil produces When hydrolysis, the antibacterial activity increased as the decomposition proceeds. When the relative viscosity of the chitosan 1% solution is 3.0 to 1.6, the growth of E. coli can be suppressed at a concentration of 100 ppm. The low molecular weight chitosan with a molecular weight of 35,000 obtained at 8 hours at 146 ℃ in 50% sodium hydroxide solution at 75% deacetylation can inhibit the growth of Escherichia coli. The molecular weight range of chitosan is 60,000 to 100,000. On the other hand, when out of this molecular weight range, antimicrobial activity fell. In addition, as the molecular weight of chitosan decreases intrinsic astringent taste, low molecular weight chitosan of high antimicrobial activity was very weak astringent taste compared to polymer chitosan. That is, in consideration of the sour taste and the astringent taste of chitin and chitosan, it is necessary to adjust the content so as not to deteriorate the taste of food with minimal addition in the range of physiological functions.

또한 키토산은 콜레스테롤 개선작용을 하는데, 이는 콜레스테롤에서 만들어지는 담즙산이 지방의 소화를 위해 십이지장으로 분비되었을때 키토산의 유리 아미노기가 담즙산의 음이온 전하 부위인 카르복실기와 이온결합을 하여 담즙산의 재흡수를 방해하여 체내 콜레스테롤치를 감소시키는 작용을 한다.In addition, chitosan improves cholesterol. When bile acids made from cholesterol are secreted into the duodenum for digestion of fat, the free amino group of chitosan ionizes carboxyl groups, which are anion charge sites of bile acids, thereby preventing the resorption of bile acids. It works by reducing cholesterol in the body.

본 발명은 키토산의 상기에서 설명한 기능성을 첨가하기 위하여 저분자 키토산이 첨가된 양념류에 관한 것으로 강한 신맛과 끝에 나는 떫은맛을 줄일 수 있도록 여러 가지 강한 식재료로 양념류를 만들고, 키토산을 2,000 내지 100,000의 범위로 분자량을 조절하였다. 또한 상기의 분자량을 갖는 키토산을 사용함으로써 양념류와 함께 섭취하게 되는 육류 섭취에 따른 고혈압의 위험도를 낮출 수 있고 식품보존 효과를 가져올 수 있도록 하였다.The present invention relates to a spice added low-molecular chitosan in order to add the above-described functionality of chitosan, to make spices with various strong ingredients to reduce the strong acidity and astringent taste at the end, the chitosan molecular weight in the range of 2,000 to 100,000 Was adjusted. In addition, by using chitosan having a molecular weight of the above can reduce the risk of hypertension according to the intake of meat to be ingested with spices and to bring food preservation effect.

키토산의 독특한 신맛과 끝에 나는 떫은 맛 때문에 갈비양념의 맛을 손상시켜 상품적 가치를 떨어뜨릴 염려가 있을 뿐 만아니라 장기보존의 효과를 높이기 위해서는 키토산을 저분자화 할 필요가 있으며 키토산류의 점성 때문에 양념류와 소스류의 물리적 점도를 변화시키고 색깔을 변질시키는 단점이 있기 때문에 저분자 키토산을 사용해야한다.Chitosan's unique sourness and astringent taste make it not only possible to damage the taste of ribs and reduce its product value, but also to lower the molecular weight of chitosan to enhance the long-term preservation effect. Low molecular weight chitosan should be used because it has the disadvantage of changing the physical viscosity and color of the sauce.

따라서 키틴, 키토산, 키틴·키토산 유도체 또는 그 올리고당을 첨가한 갈비양념을 발명하게 되었다.Therefore, the inventors have invented a rib spice added with chitin, chitosan, chitin chitosan derivatives or oligosaccharides thereof.

본 발명에서 사용한 저분자 키틴, 키토산, 키틴·키토산 유도체 또는 그 올리고당은 양념의 전체 배합량의 0.0001 내지 10.0중량%, 특히 0.01 내지 1%로 하는 것이 바람직하다.The low molecular chitin, chitosan, chitin chitosan derivatives or oligosaccharides thereof used in the present invention are preferably 0.0001 to 10.0% by weight, particularly 0.01 to 1%, based on the total amount of the seasoning.

상기의 키토산 갈비양념의 장기 보존성을 예측하기 위하여 키토산을 시료로 하여 아래와 같은 방법으로 항균력을 측정하였다.In order to predict the long-term preservation of the chitosan rib seasoning, the antimicrobial activity was measured by the following method using chitosan as a sample.

실험균액에 시료를 250ppm, 350ppm, 500ppm으로 가한 후 멸균한 다음 25℃에서 24시간 배양 후 균수를 측정하였다. 그 결과는 표 1과 같다.Samples were added to the test bacterial solution at 250ppm, 350ppm, 500ppm and then sterilized, followed by incubation at 25 ° C. for 24 hours to determine the number of bacteria. The results are shown in Table 1.

균주Strain 공시균Specimen 250ppm250 ppm 350ppm350 ppm 500ppm500 ppm 접종직후Right after vaccination 5.6×103 5.6 × 10 3 5.6×103 5.6 × 10 3 5.6×103 5.6 × 10 3 5.6×103 5.6 × 10 3 24시간후24 hours later 2.7×105 2.7 × 10 5 2.2×102 2.2 × 10 2 1.8×102 1.8 × 10 2 1.1×102 1.1 × 10 2 접종직후Right after vaccination 7.4×103 7.4 × 10 3 7.4×103 7.4 × 10 3 7.4×103 7.4 × 10 3 7.4×103 7.4 × 10 3 24시간후24 hours later 3.6×105 3.6 × 10 5 2.3×102 2.3 × 10 2 2.1×102 2.1 × 10 2 1.6×102 1.6 × 10 2

①E. Coli IFO 3301, ② S. aureus①E. Coli IFO 3301, ② S. aureus

표 1에서 보는 바와 같이 실험에 사용한 저분자 키토산은 식중독을 이르킬 수 있는 균인 E. Coli IFO 3301과 S. aureus 균에 대해 강력한 항균작용이 있기 때문에 양념류의 장기보존성이 있을 것으로 기대한다.As shown in Table 1, the low-molecular chitosan used in the experiment is expected to have long-term preservation of seasonings because it has strong antimicrobial activity against E. Coli IFO 3301 and S. aureus, which can lead to food poisoning.

이하 본 발명을 설명하기 위해 실시예를 예시한다. 본 발명의 주요 구성물질인 저분자 키틴, 키토산, 키토올리고당 및 키틴칼슘 혹은 키틴, 키토산의 유도체 물질 등은 적어도 한 종류에서 두 종류 이상으로 선택될 수 있으며 본 발명의 주제물질과 각종의 첨가되는 재료, 제조방법, 주제물질의 첨가시기 등은 선택적으로 가감 내지는 응용 조정될 수 있다.Examples will be described below to illustrate the present invention. Low molecular chitin, chitosan, chitooligosaccharide and chitin calcium or chitin, chitosan derivatives, etc., which are the main constituents of the present invention, may be selected from at least one kind or two or more kinds, and the subject matter of the present invention and various added materials, The production method, the timing of addition of the subject matter, and the like may be selectively adjusted or adjusted.

실시예 1Example 1

키토산 갈비양념 :Chitosan Spare Ribs:

배 70g, 양파 30g, 후추 1g, 참기름 10g, 대파 2g, 설탕 7g, 간장 15g, 물엿 5g, 식용유 3g, 마늘 5g, 청주 5g, 참깨 1g, 전분 3g으로 만들때 각 재료는 다지고 1g의 저분자 키토산을 첨가하여 키토산 갈비양념을 완성하였다.70g pear, 30g onion, 1g pepper, sesame oil 10g, leek 2g, sugar 7g, soy sauce 15g, starch syrup 5g, cooking oil 3g, garlic 5g, sake 5g, sesame 1g, starch 3g Addition was completed chitosan rib seasoning.

갈비양념의 유통기한을 연장시켜 줄 수 있고, 고혈압, 고콜레스테롤혈증을 예방하여 기능성을 강화시켜줄 수 있다.Galbi seasoning can extend the shelf life, hypertension, hypercholesterolemia can be prevented to enhance functionality.

Claims (5)

갈비양념에 키틴, 키토산, 키틴·키토산 유도체 또는 그 올리고당이 포함된 것을 특징으로 하는 기능성 갈비양념.A functional rib marinade characterized in that the chibi, chitosan, chitin chitosan derivatives or oligosaccharides thereof are contained in the rib seasoning. 제 1항에 있어서 갈비양념은 배 30내지 50중량%, 양파 10내지 20중량%, 후추 0.01내지 1중량%, 참기름 1내지 10중량%, 대파 0.01내지 1중량%, 설탕 0.01내지 10중량%, 간장 0.1내지 15중량%, 물엿 1내지 10중량%, 식용유 0.2내지 10중량%, 마늘 1내지 5중량%, 청주 1내지 5중량%, 참깨 0.1내지 1중량%, 전분 0.1내지 5중량% 함유된 것을 특징으로 하는 갈비양념.According to claim 1, the rib seasoning is 30 to 50% by weight, onion 10 to 20% by weight, pepper 0.01 to 1% by weight, sesame oil 1 to 10% by weight, leek 0.01 to 1% by weight, sugar 0.01 to 10% by weight, Soy 0.1 to 15% by weight, starch syrup 1 to 10% by weight, cooking oil 0.2 to 10% by weight, garlic 1 to 5% by weight, sake 1 to 5% by weight, sesame 0.1 to 1% by weight, starch 0.1 to 5% by weight Spare ribs characterized in that. 제 1항에 있어서 키틴, 키토산, 키틴·키토산 유도체는 분자량 10,000내지 100,000범위와 올리고당은 10,000이하의 분자량을 사용하고 갈비양념의 중량에 대하여 0.0001내지 10중량%를 함유한 것을 특징으로 하는 갈비양념.The rib sauce according to claim 1, wherein the chitin, chitosan, chitin chitosan derivatives have a molecular weight ranging from 10,000 to 100,000 and oligosaccharides having a molecular weight of 10,000 or less and contain 0.0001 to 10% by weight based on the weight of the rib seasoning. 제 1항에 있어서 갈비양념에서 파생된 돼지갈비양념, 쇠갈비양념.The pork rib sauce, beef rib sauce of claim 1, which is derived from rib sauce. 제 1항에 있어서 갈비양념으로 만든 육류제품 및 즉석 육류제품.The meat product and instant meat product according to claim 1, which is made of rib sauce.
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002011565A1 (en) * 2000-07-27 2002-02-14 Idebio, S.L. Chitosan-based diet sauces
KR20030016808A (en) * 2001-08-22 2003-03-03 최용우 Manufacturing method meat with chitosan
KR20040032027A (en) * 2002-10-08 2004-04-14 백창용 First Processing Method of Pork-rib and Pork-rib Thereby for Grill

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002011565A1 (en) * 2000-07-27 2002-02-14 Idebio, S.L. Chitosan-based diet sauces
KR20030016808A (en) * 2001-08-22 2003-03-03 최용우 Manufacturing method meat with chitosan
KR20040032027A (en) * 2002-10-08 2004-04-14 백창용 First Processing Method of Pork-rib and Pork-rib Thereby for Grill

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