KR19980082144A - Method for manufacturing artificial marble sanitary ware and articles thereof - Google Patents

Method for manufacturing artificial marble sanitary ware and articles thereof Download PDF

Info

Publication number
KR19980082144A
KR19980082144A KR1019980035284A KR19980035284A KR19980082144A KR 19980082144 A KR19980082144 A KR 19980082144A KR 1019980035284 A KR1019980035284 A KR 1019980035284A KR 19980035284 A KR19980035284 A KR 19980035284A KR 19980082144 A KR19980082144 A KR 19980082144A
Authority
KR
South Korea
Prior art keywords
mold
sanitary
biotite
germanium
artificial marble
Prior art date
Application number
KR1019980035284A
Other languages
Korean (ko)
Other versions
KR100284125B1 (en
Inventor
김정근
Original Assignee
김정근
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 김정근 filed Critical 김정근
Priority to KR1019980035284A priority Critical patent/KR100284125B1/en
Publication of KR19980082144A publication Critical patent/KR19980082144A/en
Application granted granted Critical
Publication of KR100284125B1 publication Critical patent/KR100284125B1/en

Links

Landscapes

  • Bathtubs, Showers, And Their Attachments (AREA)
  • Laminated Bodies (AREA)

Abstract

본 발명은 주거공간내에 설치되는 인조대리석으로 된 욕조, 세면기 등의 위생용품의 제조방법 및 그 물건에 관한 것으로, 위생용품 자체가 항균작용과 원적외선, 음이온발생 및 탈취작용을 하도록 하므로서 인체건강에 유익한 위생용품을 제공하고자 한 것이다.The present invention relates to a method for manufacturing sanitary articles such as bathtubs and washbasins made of artificial marble installed in a living space, and the sanitary articles themselves are beneficial to human health by making them antibacterial, far-infrared, anion-generating and deodorizing. To provide hygiene products.

따라서, 위생용품(1)의 내면은 원적외선과 음이온을 발생하여 탈취작용을 하도록 불포화폴리에스테르수지와 석분(탄산칼슘, 흑운모게르마늄, 수산화알루미늄)을 적절히 배합하여 모재료가 되도록하고 이 모재료(2)의 외측표면에는 항균파우더가 배합된 코팅제(3)를 도포시켜 건강에 유익한 위생용품을 얻도록 하였다.Therefore, the inner surface of the sanitary ware 1 is appropriately blended with unsaturated polyester resin and stone powder (calcium carbonate, biotite germanium, aluminum hydroxide) so as to generate far-infrared rays and anions so as to deodorize the parent material. The outer surface of the) was coated with an antimicrobial powder (3) to obtain a sanitary article that is beneficial to health.

Description

인조대리석 위생용품의 제조방법 및 그 물건Method for manufacturing artificial marble sanitary ware and articles thereof

본 발명은 아파트, 다세대주택 혹은 일반주택 등 주거공간에 설치 사용되는 인조대리석 위생용품 예로서 욕조, 세면기 등의 제조방법 및 그 물건에 관한 것으로, 더욱 상세히는 향균작용과 원적외선, 음이온 발생 및 탈취작용을 하는 인조대리석의 위생용품의 제조방법과 물건을 제공하고자 한 것이다.The present invention relates to a method for manufacturing artificial marble sanitary products used in residential spaces such as apartments, multi-family houses or general houses, such as bathtubs, washbasins and the like, and more specifically, antibacterial action and far infrared rays, anion generation and deodorization. To provide a method and article of manufacturing sanitary products of artificial marble.

종래, 인조대리석 위생용품은 마블, 오닉스, 천연석재 등을 이용하여 외관을 미려하게 함과 동시에 고급화를 꾀하여 왔던 것으로 이와같이 제품의 고급화에는 여러면으로 개선을 시켜왔으나 정작 인체건강에는 그렇다 할 개선책이 없었던 것이다.Conventionally, artificial marble sanitary products have been designed to be elegant and elegant at the same time by using marble, onyx, and natural stone. Thus, the product has been improved in many aspects, but there was no improvement in human health. will be.

본원발명은 제품의 고급화는 물론 인체건강에 유익한 위생용품을 제공하므로서 사용자에 건강을 제공하고자 한다.The present invention seeks to provide health to the user by providing hygienic products that are beneficial to human health as well as high-end products.

도 1은 본 발명의 위생용품인 욕조를 나타낸 단면도1 is a cross-sectional view showing a bath tub hygiene of the present invention

(도면의 주요부분에 대한 부호의 설명)(Explanation of symbols for the main parts of the drawing)

1 : 위생용품(욕조, 세면대)1: Sanitary ware (bathtub, sink)

2 : 모재료2: base material

3 : 코팅제3: coating agent

따라서, 인류건강에 부합되는 신소재의 위생용품 특히 박테리아나 포도상구균, 녹농균 등에 강한 항균작용을 하는 동시에 아파트 마감재에서 나오는 포름알데히드(formaldehyd)와 시멘트에서 발생되는 라든가스 등을 흡착하는 원적외선, 음이온을 발생하게 하고 암모니아나 유해가스를 흡착 분해하는 건강에 유익한 양질의 제품을 제조하는 것으로 인체에 해로운 균에 대한 항균작용을 위생용품 표면(코팅면)에 처리하고, 인체에 유익한 원적외선, 음이온 발생 및 탈취작용은 코팅면 밑부분인 모재료로해서 처리되는 제조방법과 이와같이 제조된 물건인 것으로 이하 각 실시예를 들어 구체적으로 설명하면 다음과 같다.Therefore, hygiene products of new materials suitable for human health, especially bacteria, Staphylococcus aureus and P. aeruginosa, have strong antimicrobial activity and generate far-infrared rays and anions that adsorb formaldehyde and cements from apartment finishes By producing high-quality products that are beneficial to health by adsorbing and decomposing ammonia or harmful gases, antibacterial action against bacteria harmful to human body is treated on the surface (coating surface) of hygiene products, and far-infrared rays, anion generation and deodorizing action beneficial to human body The manufacturing method to be treated with the base material which is the silver coating surface and the article manufactured as described above will be described in detail with reference to the following Examples.

본 발명에 있어서는 혼합식과 부착식이 있는데 제1실시예는 혼합식을 예로하고 있고 제2실시예는 부착식을 예로하고 있는 것으로 이와같은 점을 고려하여 설명한다.In the present invention, there is a mixing type and a sticking type. The first embodiment uses a mixed type and the second embodiment takes a sticking type as an example.

(실시예 1) : 혼합식Example 1 Mixed Formula

제1공정 : FRP로 된 위생용품 예로서 욕조, 세면기 등 소망하는 위생용품의 형틀을 구비하고 성형공간에 해당되는 형틀 내면의 전체면에 걸쳐 이형을 위하여 이형제를 고루 도포한 후 광택처리한다.First step: FRP sanitary products, such as bath tubs, washbasins, etc., are provided with molds of desired sanitary products, and the mold is applied evenly over the entire surface of the inner surface of the mold corresponding to the molding space and then polished.

제2공정 : 제1공정의 이형제가 도포된 형틀의 표면에 항균파우더가 배합된 코팅제(겔코트수지)를 약 0.35-0.8m/m두께가 되도록 골고루 도포 적층 가온경화(약 60℃에서 30분)시킨후 추후 성형완료 되었을때 외곽층(상부표면)이 되도록 한다.Second step: Apply the coating agent (gel coat resin) with antibacterial powder on the surface of the mold coated with the release agent of the first step evenly so that the thickness becomes about 0.35-0.8m / m. Lamination heat curing (about 30 minutes at 60 ℃) After the molding is completed, make the outer layer (upper surface).

이때 상기한 코팅제의 배합비율은 다음과 같다.At this time, the mixing ratio of the coating agent is as follows.

코팅제의 배합비율Mixing ratio of coating agent

PG(Propylene Glycol)······ 8.0중량%PG (Propylene Glycol) 8.0% by weight

NPG(Neopenthyl Glycol)·····13.0중량%NPG (Neopenthyl Glycol)

IPA(Isophtalic Acid)······10.0중량%IPA (Isophtalic Acid) 10.0% by weight

FA(Fumalic Acid)········18.0중량%FA (Fumalic Acid) 18.0 wt%

SM(Styrene Monomer)······ 32.0중량%SM (Styrene Monomer) ... 32.0 wt%

TiO2··············11.0중량%TiO 2 11.0% by weight

Aerosil············ 3.0중량%Aerosil ... 3.0% by weight

항균파우더···········1.0-5.0중량%Antibacterial Powder ... 1.0-5.0% by weight

제3공정 : 상기 2공정이 완료된 상태에서 불포화폴리에스테르수지와 석분 (탄산칼슘, 흑운모게르마늄, 수산화알루미늄)이 혼합된 모재료를 일정두께로 형틀에 주입, 진동, 고형화시킨다. 이때 상기한 모 재료의 두께정도는 제품의 중량 또는 그 기능에 알맞는 두께로 임의 조정할 수 있는 것이며 모재료의 배합비율은 다음과 같다.Third step: After the two steps are completed, the parent material mixed with unsaturated polyester resin and stone powder (calcium carbonate, biotite germanium, aluminum hydroxide) is injected into the mold to a certain thickness, vibrated, and solidified. At this time, the thickness of the parent material can be arbitrarily adjusted to a thickness suitable for the weight of the product or its function, and the blending ratio of the parent material is as follows.

모재료의 배합비율Mixing ratio of parent material

불포화폴리에스테르수지 : 석분의 혼합비율 = 1 : 2.0-2.5Unsaturated polyester resin: mixing ratio of stone powder = 1: 2.0-2.5

A) 불포화폴리에스테르수지A) unsaturated polyester resin

PA(Phtalic Acid) : 12.0중량%PA (Phtalic Acid): 12.0 wt%

PG(Propylene Glycol) : 8.0중량%PG (Propylene Glycol): 8.0% by weight

MA(Malican Hydride) : 34.0중량%MA (Malican Hydride): 34.0 wt%

SM(Styrene Monomer) : 16.0중량%SM (Styrene Monomer): 16.0 wt%

ETC : 30.0중량%ETC: 30.0 wt%

B) 석분B) stone powder

탄산칼슘 : 70.0중량%Calcium Carbonate: 70.0 wt%

흑운모게르마늄 : 15.0-20.0중량%Biotite germanium: 15.0-20.0% by weight

수산화알루미늄 : 10.0-15.0중량%Aluminum hydroxide: 10.0-15.0 wt%

제4공정 : 제3공정에서의 고형화된 성형품을 약 60℃에서 30분 가온 경화시 킨후 형틀로부터 탈형, 마감하여 완성된 위생용품을 얻는다.4th step: The solidified molded product of the 3rd process is cured at about 60 degreeC for 30 minutes, and after demolding and finishing from a mold, the finished sanitary goods are obtained.

(실시예 2) : 부착식Example 2 Adhesive

본 발명의 다른 실시예로 제1, 2 및 제4공정은 상기 혼합식의 실시예 1과 동일한 공정을 취하지만 제3공정을 다음과 같이 행하고 동시에 별도의 제5공정을 행할 수 있는 것으로 이는 본 발명의 범위내에 속한다.In another embodiment of the present invention, the first, second, and fourth steps take the same steps as in Example 1 of the mixing formula, but the third step can be performed as follows and a separate fifth step can be performed at the same time. It falls within the scope of the invention.

제1공정 : 실시예 1의 혼합식과 동일1st process: same as the mixing formula of Example 1

제2공정 : 실시예 1의 혼합식과 동일2nd process: same as the mixing formula of Example 1

제3공정 : 제2공정이 완료된 상태에서 불포화폴리에스테르수지와 흑운모게 르마늄을 제외한 석분(탄산칼슘, 수산화알루미늄)이 혼합된 모재 료를 일정두께로 형틀에 주입, 진동, 고형화 시킨다. 이때 모재 료의 배합비율은 다음과 같다.Third step: In the state where the second step is completed, inject, vibrate, and solidify the base material mixed with stone powder (calcium carbonate, aluminum hydroxide) excluding unsaturated polyester resin and biotite germanium to a certain thickness. At this time, the mixing ratio of the base material is as follows.

모재료의 배합비율Mixing ratio of parent material

불포화폴리에스테르수지 : 석분 = 상기 실시예 1의 혼합식과 동일Unsaturated polyester resin: stone powder = same as the mixing formula of Example 1

A) 불포화폴리에스테르수지 = 상기 실시예 1의 혼합식과 동일A) unsaturated polyester resin = same as the mixing formula of Example 1

B) 석분B) stone powder

탄산칼슘 : 80중량%Calcium Carbonate: 80% by weight

수산화알루미늄 : 20중량%Aluminum hydroxide: 20 wt%

제4공정 : 고형화된 제품을 약 60℃에서 30분 가온 경화시킨후 형틀로부터 탈형마감한다.Step 4: The solidified product is cured for 30 minutes at about 60 ℃, and then demolded from the mold.

제5공정 : 제4공정에 완료된 상태에서 인조대리석 위생용품 뒷면에 흑운모게 르마늄을 8-10m/m크기로 특수접착제로 촘촘히 부착시키거나 두께 15-20m/m, 폭 50-80m/m정도의 길이로 절단 부착시킨다.5th process: In the state of completion of the 4th process, biotite germanium is closely attached to the back of artificial marble hygiene product with 8-10m / m size with special adhesive or 15-20m / m thick and 50-80m / m wide. Cut to length and attach.

이와같은 각 공정에 의해 제작된 위생용품은 실제 물품에 있어서는 도 1과 같이 구성된다. 즉 위생용품(1)을 설치했을 때 외부표면에는 항균파우더가 배합된 코팅제(3)가 소정의 두께로 도포되어 항균작용을 하게되고, 위생용품의 내부면에는 인체에 유익한 원적외선 및 음이온을 발생하는 모재료(2) 즉 불포화폴리에스테르와 석분(탄산칼슘, 흑운모게르마늄, 수산화알루미늄)등이 적절히 혼합된 모재료가 소정의 두께로 형성된 구조의 위생용품이 되는 것이다.The sanitary article produced by each of these processes is configured as shown in FIG. That is, when the sanitary article 1 is installed, the coating agent 3 containing the antimicrobial powder is applied to the outer surface to have a predetermined thickness to act as an antimicrobial agent, and the inner surface of the sanitary article generates far infrared rays and anions that are beneficial to the human body. The mother material 2, that is, the unsaturated material and the mother powder (calcium carbonate, biotite germanium, aluminum hydroxide), etc., are suitably mixed and become a sanitary article having a structure having a predetermined thickness.

이상의 제조공정에 따른 각 실시예(혼합식 및 부착식)에 있어서, 제1공정에서 사용되는 형틀은 FRP소재를 이용하고 이형제를 사용하는 것은 성형이 완료된 제품이 형틀로부터 쉽게 탈형(이형)되도록 하기 위한 것이며, 제2공정에 있어서의 겔코트 코팅층은 제품의 외관이 되어 실제 인체와 접촉하는 부분이 되어 항균효과를 주게되는 것이다.In each embodiment (mixing and sticking) according to the above manufacturing process, the mold used in the first process uses a FRP material and using a release agent so that the molded product is easily demolded (released) from the mold. The gel coat coating layer in the second step is to be the appearance of the product to be in contact with the actual human body to give an antibacterial effect.

특히 제3공정에서는 코팅면(겔코트수지층)바로 밑부분인 모재료에서 인체에 유익한 원적외선과 음이온을 발생하여 인체에 흡수되는 체내온도를 상승시키고 땀과 각종 노폐물을 몸밖으로 배출시키게 하고 화장실내의 암모니아가스와 유해가스를 흡착 분해시키는 역할을 하는 것이다.Particularly, in the third process, the base material immediately under the coating surface (gel coat resin layer) generates far-infrared rays and negative ions which are beneficial to the human body, thereby increasing the body temperature absorbed by the human body, and discharging sweat and various waste products out of the body. It serves to adsorb and decompose ammonia gas and harmful gas.

또한 실시예 2에 있어서 제5공정을 거친 위생용품은 원적외선과 음이온을 발생하는 흑운모게르마늄이 모재료에 혼합되지 아니하고 모재료 뒷면에 접착이 된 상태로서 직접 외부로 노출된 구조로 되므로 흑운모게르마늄이 모재료에 혼합된 상기 실시예 1의 제품보다는 그 효과가 크다고 할 수 있다.In addition, the hygienic article passed through the fifth step in Example 2 has a structure in which the biotite germanium, which generates far infrared rays and anions, is not mixed with the mother material and is bonded to the back side of the mother material so that the structure is directly exposed to the outside. It can be said that the effect is greater than the product of Example 1 mixed in the material.

이상 살펴본 바와같이 본 발명의 제조방법으로부터 얻어진 제품(위생용품 : 세면기 욕조 등)은 기존 인조대리석 위생용품의 특징이라 할 수 있는 외관의 미려함과 내구성이외에 항균작용과 인체에 유익한 원적외선과 음이온이 발생하므로서 건강에 유익할 뿐만아니라 암모니아가스와 같은 유해가스를 흡착 분해하는 기능을 갖는 것으로 새로운 위생용품을 제공할 수 있는 것이다.As described above, the product obtained from the manufacturing method of the present invention (sanitary article: washbasin bathtub, etc.) is characterized by antibacterial action and beneficial far-infrared rays and anions, which are beneficial to the human body, in addition to the beauty and durability of the existing artificial marble sanitary ware. As well as being beneficial to health, having a function of adsorption and decomposition of harmful gases such as ammonia gas can provide new hygiene products.

Claims (4)

소망하는 위생용품의 형틀을 구비하고 형틀내면의 전체면에 이형제를 도포후 광택처리하는 통상의 제1공정후, 이형제가 도포된 형틀의 표면에 항균파우더가 배합된 코팅제를 도포하여 가온 경화시키는 제2공정과, 불포화폴리에스테르수지와 석분(탄산칼슘, 흑운모게르마늄, 수산화알루미늄)이 혼합된 모재료를 소정의 두께로 형틀에 주입 진동, 고형화시키는 제3공정과, 통상의 방법으로 고형화된 성형품을 약 60℃에서 30분간 가온 경화후 탈형 마감하여 완성품을 얻는 제4공정으로 이루어진 것을 특징으로 하는 인조대리석 위생용품의 제조방법After the normal first step of applying a mold release agent to the entire surface of the mold inner surface of the mold and polished after the desired first step of the sanitary article, by applying a coating agent containing an antibacterial powder to the surface of the mold to which the mold release agent is applied to heat curing 2nd step, the third step of injecting vibration and solidifying the mother material mixed with unsaturated polyester resin and stone powder (calcium carbonate, biotite germanium, aluminum hydroxide) into a mold at a predetermined thickness, and a molded product solidified by a conventional method. Method of manufacturing artificial marble sanitary ware comprising the fourth step of obtaining a finished product after demolding after heating and curing at about 60 ℃ 30 minutes 소망하는 위생용품의 형틀을 구비하고 형틀내면의 전체면에 이형제를 도포후 광택처리하는 통상의 제1공정후, 이형제가 도포된 형틀의 표면에 항균파우더가 배합된 코팅제를 도포하여 가온 경화시키는 제2공정과, 불포화폴리에스테르수지와 석분(탄산칼슘, 수산화알루미늄)을 혼합한 모재료를 소정의 두께로 형틀에 주입 진동, 고형화시키는 제3공정과, 통상의 방법으로 고형화된 제품을 약 60℃에서 30분간 가온 경화시킨후 탈형 마감하는 제4공정후, 마감제품(위생용품)의 뒷면에 흑운모게르마늄을 8-10m/m크기로 부착시키거나 혹은 두께 15-20m/m, 폭 50-80m/m길이로 절단 부착시키는 제5공정으로 이루어진 것을 특징으로 하는 인조대리석 위생용품의 제조방법After the normal first step of applying a mold release agent to the entire surface of the mold inner surface of the mold and polished after the desired first step of the sanitary article, by applying a coating agent containing an antibacterial powder to the surface of the mold to which the mold release agent is applied to heat curing 2nd step, the 3rd step of injecting vibration and solidifying the mold material which mixed unsaturated polyester resin and stone powder (calcium carbonate, aluminum hydroxide) to a mold with predetermined thickness, and about 60 degreeC of the product solidified by the conventional method After warming and curing for 30 minutes at 4 ° C, the biotite germanium is attached to the back of the finished product (sanitary goods) with a size of 8-10m / m or a thickness of 15-20m / m and a width of 50-80m /. Manufacturing method of artificial marble sanitary ware, comprising the fifth step of cutting and attaching to m 불포화에스테르수지와 석분(탄산칼슘, 흑운모게르마늄, 수산화알루미늄)을 혼합하여 모재료(2)를 형성하고, 상기한 외측표면(설치사용시 외부표면)에 항균파우더가 배합된 코팅제(3)를 일정두께로 도포시켜서 된 것을 특징으로 하는 인조대리석 위생용품Unsaturated ester resin and stone powder (calcium carbonate, biotite germanium, aluminum hydroxide) are mixed to form the parent material (2), and the coating agent (3) having antimicrobial powder is blended on the outer surface (outer surface during installation). Artificial marble hygiene products, characterized in that by applying 제3항에 있어서,The method of claim 3, 모재료(2)의 석분은 탄산칼슘과 수산화알류미늄으로 혼합구성되며, 흑운모게르마늄은 모재료 뒷부분에 별도로 부착시켜 외부로 노출시킨 것을 특징으로 하는 인조대리석 위생용품The stone powder of the parent material (2) is composed of calcium carbonate and aluminum hydroxide, and the biotite germanium is attached to the back of the parent material to be exposed to the outside.
KR1019980035284A 1998-08-28 1998-08-28 Method for manufacturing artificial marble sanitary ware and articles thereof KR100284125B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1019980035284A KR100284125B1 (en) 1998-08-28 1998-08-28 Method for manufacturing artificial marble sanitary ware and articles thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1019980035284A KR100284125B1 (en) 1998-08-28 1998-08-28 Method for manufacturing artificial marble sanitary ware and articles thereof

Publications (2)

Publication Number Publication Date
KR19980082144A true KR19980082144A (en) 1998-11-25
KR100284125B1 KR100284125B1 (en) 2001-03-02

Family

ID=65899443

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019980035284A KR100284125B1 (en) 1998-08-28 1998-08-28 Method for manufacturing artificial marble sanitary ware and articles thereof

Country Status (1)

Country Link
KR (1) KR100284125B1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20010079250A (en) * 2001-06-27 2001-08-22 김영두 the Method for fabricating a Bathroom's Apparatus
KR101224216B1 (en) * 2009-12-24 2013-01-18 전재석 Artificial stone

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100382119B1 (en) * 1999-11-15 2003-05-01 서재균 The manufacturing process of a tooth brush.
KR100803387B1 (en) 2006-11-14 2008-02-13 김용범 Bathtub and method of manufacturing the same

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20010079250A (en) * 2001-06-27 2001-08-22 김영두 the Method for fabricating a Bathroom's Apparatus
KR101224216B1 (en) * 2009-12-24 2013-01-18 전재석 Artificial stone

Also Published As

Publication number Publication date
KR100284125B1 (en) 2001-03-02

Similar Documents

Publication Publication Date Title
KR100832051B1 (en) Method of preparing cushion bath tub or washbasin and bath tub or washbasin prepared thereby
KR19980082144A (en) Method for manufacturing artificial marble sanitary ware and articles thereof
CN108821725B (en) Gypsum jade-imitating product and preparation method thereof
TW201236601A (en) Toothbrush having far infrared and anion and manufacturing method thereof
ATE178833T1 (en) ROTATIONAL MOLDING PROCESS AND MOLDED BODIES PRODUCED BY THE PROCESS
KR200425182Y1 (en) Bathtub
KR100272421B1 (en) Artificial marble with a loess and zeolite as a miain ingredient and method thereof
KR100356279B1 (en) A method for manufacturing silver tiles and Silver tiles
KR20070105727A (en) Bath and a methode of making it
KR100245530B1 (en) Process for the preparation of whangto mat
KR200405473Y1 (en) The function artificial marble
JPH0433810Y2 (en)
KR200345463Y1 (en) Sanitation article have figured
KR20050024767A (en) Washbowl and manufacturing method thereof
KR200412857Y1 (en) Health functional anion necklace with natural substance and fragrance
KR200175211Y1 (en) A bath
TW201236613A (en) Chopstick having far infrared and anion and manufacturing method thereof
CN101954699A (en) Manufacture method of integral filming foaming profile
JP3299788B2 (en) Antibacterial and antifungal resin products
KR20050034361A (en) Memory foam for pillow
KR100428393B1 (en) the Method for Fabricating a Sanitation
KR20050025000A (en) Washbowl and manufacturing method thereof
CN1069082C (en) Toilet appliance and its manufacture
KR200394555Y1 (en) Nano silver and contain perfume a brick
KR200353194Y1 (en) a bathtub

Legal Events

Date Code Title Description
A201 Request for examination
G15R Request for early opening
E902 Notification of reason for refusal
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
FPAY Annual fee payment

Payment date: 20031215

Year of fee payment: 4

LAPS Lapse due to unpaid annual fee