KR19980018651A - 지지된 화학적 화합물 - Google Patents

지지된 화학적 화합물 Download PDF

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Publication number: KR19980018651A
Authority: KR; South Korea
Prior art keywords: dimethyl; zirconium; methyl; bis; ethyl
Prior art date: 1996-08-13

Application number

KR1019970038623A

Other languages

English (en)

Korean (ko)

Inventor

코르넬리아 프릿츠

프랑크 퀴버

한스 보넨

Original Assignee

아커만, 쿤켈

훽스트 아크티엔게젤샤프트

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1996-08-13

Filing date

1997-08-13

Publication date

1998-06-05

1996-08-13 Priority claimed from DE1996132557 external-priority patent/DE19632557A1/de

1996-08-13 Priority claimed from DE19632558A external-priority patent/DE19632558A1/de

1996-11-14 Priority claimed from DE1996147070 external-priority patent/DE19647070A1/de

1997-08-13 Application filed by 아커만, 쿤켈, 훽스트 아크티엔게젤샤프트 filed Critical 아커만, 쿤켈

1998-06-05 Publication of KR19980018651A publication Critical patent/KR19980018651A/ko

Links

150000001875 compounds Chemical class 0.000 title claims abstract description 42
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229910052799 carbon Inorganic materials 0.000 claims abstract description 26
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 18
150000001336 alkenes Chemical class 0.000 claims abstract description 13
125000006850 spacer group Chemical group 0.000 claims abstract description 10
125000001424 substituent group Chemical group 0.000 claims abstract description 10
150000001768 cations Chemical class 0.000 claims abstract description 9
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims abstract description 9
229920000098 polyolefin Polymers 0.000 claims abstract description 8
-1 sulfonium cation Chemical class 0.000 claims description 184
238000006116 polymerization reaction Methods 0.000 claims description 29
150000003623 transition metal compounds Chemical class 0.000 claims description 13
125000005843 halogen group Chemical group 0.000 claims description 11
230000000737 periodic effect Effects 0.000 claims description 11
239000003446 ligand Substances 0.000 claims description 9
239000000126 substance Substances 0.000 claims description 9
238000004519 manufacturing process Methods 0.000 claims description 5
238000000034 method Methods 0.000 claims description 5
229910052723 transition metal Inorganic materials 0.000 claims description 5
150000003624 transition metals Chemical class 0.000 claims description 5
125000005517 carbenium group Chemical group 0.000 claims description 4
XLYOFNOQVPJJNP-UHFFFAOYSA-O oxonium Chemical compound [OH3+] XLYOFNOQVPJJNP-UHFFFAOYSA-O 0.000 claims description 4
150000003856 quaternary ammonium compounds Chemical class 0.000 claims description 4
230000000379 polymerizing effect Effects 0.000 claims description 3
238000002360 preparation method Methods 0.000 abstract description 8
229910052736 halogen Inorganic materials 0.000 abstract description 3
150000002367 halogens Chemical class 0.000 abstract description 3
229910052726 zirconium Inorganic materials 0.000 description 116
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 84
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GBXQPDCOMJJCMJ-UHFFFAOYSA-M trimethyl-[6-(trimethylazaniumyl)hexyl]azanium;bromide Chemical compound [Br-].C[N+](C)(C)CCCCCC[N+](C)(C)C GBXQPDCOMJJCMJ-UHFFFAOYSA-M 0.000 description 57
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YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 33
239000002904 solvent Substances 0.000 description 29
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 27
239000000725 suspension Substances 0.000 description 19
YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 18
125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 18
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 17
238000006243 chemical reaction Methods 0.000 description 17
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239000010936 titanium Substances 0.000 description 12
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239000002184 metal Substances 0.000 description 8
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 8
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 8
150000003254 radicals Chemical class 0.000 description 8
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 7
125000000217 alkyl group Chemical group 0.000 description 7
229910052786 argon Inorganic materials 0.000 description 7
239000003426 co-catalyst Substances 0.000 description 7
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KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 6
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125000004435 hydrogen atom Chemical group [H]* 0.000 description 5
239000003921 oil Substances 0.000 description 5
239000011148 porous material Substances 0.000 description 5
239000002244 precipitate Substances 0.000 description 5
MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 5
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IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
125000003545 alkoxy group Chemical group 0.000 description 4
229910052796 boron Inorganic materials 0.000 description 4
230000003197 catalytic effect Effects 0.000 description 4
YNEOILNOYXEUJZ-UHFFFAOYSA-N chloro-dimethyl-(2,3,5,6-tetrafluorophenoxy)silane Chemical compound C[Si](C)(Cl)OC1=C(F)C(F)=CC(F)=C1F YNEOILNOYXEUJZ-UHFFFAOYSA-N 0.000 description 4
239000000706 filtrate Substances 0.000 description 4
125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 description 4
239000007788 liquid Substances 0.000 description 4
230000007935 neutral effect Effects 0.000 description 4
229910052757 nitrogen Inorganic materials 0.000 description 4
239000002245 particle Substances 0.000 description 4
125000000538 pentafluorophenyl group Chemical group FC1=C(F)C(F)=C(*)C(F)=C1F 0.000 description 4
150000003839 salts Chemical class 0.000 description 4
238000003786 synthesis reaction Methods 0.000 description 4
238000010792 warming Methods 0.000 description 4
125000001637 1-naphthyl group Chemical group [H]C1=C([H])C([H])=C2C(*)=C([H])C([H])=C([H])C2=C1[H] 0.000 description 3
ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 3
239000002841 Lewis acid Substances 0.000 description 3
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
229910003849 O-Si Inorganic materials 0.000 description 3
229910003872 O—Si Inorganic materials 0.000 description 3
229910052782 aluminium Inorganic materials 0.000 description 3
RMVKLSURSIYQTI-UHFFFAOYSA-N bis(2,3,4,5,6-pentafluorophenyl)boron Chemical compound FC1=C(F)C(F)=C(F)C(F)=C1[B]C1=C(F)C(F)=C(F)C(F)=C1F RMVKLSURSIYQTI-UHFFFAOYSA-N 0.000 description 3
125000004432 carbon atom Chemical group C* 0.000 description 3
125000001485 cycloalkadienyl group Chemical group 0.000 description 3
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
125000000524 functional group Chemical group 0.000 description 3
125000003106 haloaryl group Chemical group 0.000 description 3
150000007517 lewis acids Chemical class 0.000 description 3
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229910052710 silicon Inorganic materials 0.000 description 3
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FAQYAMRNWDIXMY-UHFFFAOYSA-N trichloroborane Chemical compound ClB(Cl)Cl FAQYAMRNWDIXMY-UHFFFAOYSA-N 0.000 description 3
VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 3
125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 description 3
VPGLGRNSAYHXPY-UHFFFAOYSA-L zirconium(2+);dichloride Chemical compound Cl[Zr]Cl VPGLGRNSAYHXPY-UHFFFAOYSA-L 0.000 description 3
125000000027 (C1-C10) alkoxy group Chemical group 0.000 description 2
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RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 description 2
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PBYIIRLNRCVTMQ-UHFFFAOYSA-N 2,3,5,6-tetrafluorophenol Chemical compound OC1=C(F)C(F)=CC(F)=C1F PBYIIRLNRCVTMQ-UHFFFAOYSA-N 0.000 description 2
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238000007872 degassing Methods 0.000 description 2
CDVLGXIOFUDJHM-UHFFFAOYSA-N dibromo-(4-dibromoboranyl-2,3,5,6-tetrafluorophenyl)borane Chemical compound FC1=C(F)C(B(Br)Br)=C(F)C(F)=C1B(Br)Br CDVLGXIOFUDJHM-UHFFFAOYSA-N 0.000 description 2
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125000000468 ketone group Chemical group 0.000 description 1
229910003002 lithium salt Inorganic materials 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
CPOFMOWDMVWCLF-UHFFFAOYSA-N methyl(oxo)alumane Chemical compound C[Al]=O CPOFMOWDMVWCLF-UHFFFAOYSA-N 0.000 description 1
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150000002902 organometallic compounds Chemical class 0.000 description 1
230000001590 oxidative effect Effects 0.000 description 1
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238000001556 precipitation Methods 0.000 description 1
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125000003718 tetrahydrofuranyl group Chemical group 0.000 description 1
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150000003568 thioethers Chemical class 0.000 description 1
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238000006276 transfer reaction Methods 0.000 description 1
VHOBAVSVXOKJLC-UHFFFAOYSA-N triethoxy-[(2,3,5,6-tetrafluorophenoxy)methyl]silane Chemical compound CCO[Si](OCC)(OCC)COC1=C(F)C(F)=CC(F)=C1F VHOBAVSVXOKJLC-UHFFFAOYSA-N 0.000 description 1
RIGHSQASRZUCPK-UHFFFAOYSA-N trimethyl-(2,3,5,6-tetrafluoro-4-trimethylsilylphenyl)silane Chemical compound C[Si](C)(C)C1=C(F)C(F)=C([Si](C)(C)C)C(F)=C1F RIGHSQASRZUCPK-UHFFFAOYSA-N 0.000 description 1
LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 1
OBAJXDYVZBHCGT-UHFFFAOYSA-N tris(pentafluorophenyl)borane Chemical compound FC1=C(F)C(F)=C(F)C(F)=C1B(C=1C(=C(F)C(F)=C(F)C=1F)F)C1=C(F)C(F)=C(F)C(F)=C1F OBAJXDYVZBHCGT-UHFFFAOYSA-N 0.000 description 1
OLFPYUPGPBITMH-UHFFFAOYSA-N tritylium Chemical compound C1=CC=CC=C1[C+](C=1C=CC=CC=1)C1=CC=CC=C1 OLFPYUPGPBITMH-UHFFFAOYSA-N 0.000 description 1
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Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/02—Boron compounds
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61908—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61916—Component covered by group C08F4/60 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
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- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not

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Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Crystallography & Structural Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Agricultural Chemicals And Associated Chemicals (AREA)
Catalysts (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Polymerization Catalysts (AREA)

KR1019970038623A 1996-08-13 1997-08-13 지지된 화학적 화합물 KR19980018651A (ko)

Applications Claiming Priority (6)

Application Number	Priority Date	Filing Date	Title
DE19632557.9		1996-08-13
DE1996132557 DE19632557A1 (de)	1996-08-13	1996-08-13	Chemische Verbindung
DE19632558.7		1996-08-13
DE19632558A DE19632558A1 (de)	1996-08-13	1996-08-13	Geträgerte chemische Verbindung
DE1996147070 DE19647070A1 (de)	1996-11-14	1996-11-14	Geträgerte chemische Verbindung
DE19647070.6		1996-11-14

Publications (1)

Publication Number	Publication Date
KR19980018651A true KR19980018651A (ko)	1998-06-05

Family

ID=27216553

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
KR1019970038623A KR19980018651A (ko)	1996-08-13	1997-08-13	지지된 화학적 화합물

Country Status (12)

Country	Link
US (1)	US6329313B1 (fr)
EP (1)	EP0824112B1 (fr)
JP (1)	JPH10158269A (fr)
KR (1)	KR19980018651A (fr)
CN (1)	CN1182093A (fr)
AT (1)	ATE325821T1 (fr)
AU (1)	AU3413397A (fr)
BR (1)	BR9704354A (fr)
CA (1)	CA2212668A1 (fr)
DE (1)	DE59712644D1 (fr)
NO (1)	NO973707L (fr)
TW (1)	TW408138B (fr)

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DE10208252A1 (de)	2002-02-26	2003-09-04	Celanese Ventures Gmbh	Konvalent fixierte Non-Metallocene, Verfahren zur Herstellung von diesen und deren Verwendung zur Polymerisation von Olefinen
US7700707B2 (en)	2002-10-15	2010-04-20	Exxonmobil Chemical Patents Inc.	Polyolefin adhesive compositions and articles made therefrom
WO2004046214A2 (fr)	2002-10-15	2004-06-03	Exxonmobil Chemical Patents Inc.	Systeme catalyseur multiple pour la polymerisation d'olefines et polymeres ainsi produits
WO2004076504A2 (fr)	2003-02-21	2004-09-10	Dow Global Technologies, Inc.	Procede pour la homo- ou copolymerisation d'olefines conjuguees
US7217676B2 (en) *	2004-01-16	2007-05-15	Exxon Mobil Chemical Patents Inc.	Hydrophobization and silica for supported catalyst
US7456021B2 (en) *	2004-01-16	2008-11-25	Exxonmobil Chemical Patents Inc.	Analysis method
US7285608B2 (en)	2004-04-21	2007-10-23	Novolen Technology Holdings C.V.	Metallocene ligands, metallocene compounds and metallocene catalysts, their synthesis and their use for the polymerization of olefins
US7598329B2 (en) *	2005-11-04	2009-10-06	Ticona Gmbh	Process for manufacturing ultra high molecular weight polymers using novel bridged metallocene catalysts
US8034886B2 (en)	2005-11-04	2011-10-11	Ticona Gmbh	Process for manufacturing high to ultra high molecular weight polymers using novel bridged metallocene catalysts
JP5034371B2 (ja) *	2006-02-10	2012-09-26	富士通株式会社	Ｒｆｉｄタグの製造方法およびｒｆｉｄタグ
EP1847555A1 (fr) *	2006-04-18	2007-10-24	Borealis Technology Oy	Polypropylène à ramifications multiples
EP2235071A2 (fr)	2007-10-25	2010-10-06	Novolen Technology Holdings, C.V.	Composés métallocènes, catalyseurs les comportant, procédé de fabrication d'un polymère d'oléfine à l'aide des catalyseurs et homopolymères et copolymères d'oléfines
MX2010004470A (es)	2007-10-25	2010-07-28	Lummus Novolen Technology Gmbh	Sintesis racemoselectiva de compuestos de ansa-metaloceno, compuestos de ansa-metaloceno catalizadores que los comprenden, procesos para producir un polimero de olefina mediante el uso de los catalizadores y homo- y co-polimeros de olefina.
US8299287B2 (en) *	2007-10-25	2012-10-30	Lammus Novolen Technology GmbH	Metallocene compounds, catalysts comprising them, process for producing an olefin polymer by use of the catalysts, and olefin homo- and copolymers
WO2009082546A2 (fr)	2007-12-18	2009-07-02	Exxonmobil Chemical Patents Inc.	Films de polyéthylène et procédé pour leur production
JP5532434B2 (ja) *	2008-03-07	2014-06-25	独立行政法人産業技術総合研究所	有機無機複合材料およびその利用
EP2630168A4 (fr)	2010-10-21	2014-10-29	Exxonmobil Chem Patents Inc	Polyéthylène et son procédé de fabrication
CN112041351B (zh)	2018-03-30	2023-12-29	陶氏环球技术有限责任公司	高度可溶的双硼酸盐作为烯烃聚合的双核助催化剂
JP2021519362A (ja)	2018-03-30	2021-08-10	ダウグローバルテクノロジーズエルエルシー	オレフィン重合活性化剤
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KR20200142513A (ko)	2018-03-30	2020-12-22	다우 글로벌 테크놀로지스 엘엘씨	올레핀 중합을 위한 공-촉매로서 고도 가용성 알킬 치환된 카르베늄 보레이트
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1997
- 1997-08-01 AT AT97113300T patent/ATE325821T1/de not_active IP Right Cessation
- 1997-08-01 EP EP97113300A patent/EP0824112B1/fr not_active Expired - Lifetime
- 1997-08-01 DE DE59712644T patent/DE59712644D1/de not_active Expired - Fee Related
- 1997-08-11 CA CA002212668A patent/CA2212668A1/fr not_active Abandoned
- 1997-08-11 TW TW086111464A patent/TW408138B/zh not_active IP Right Cessation
- 1997-08-12 US US08/907,938 patent/US6329313B1/en not_active Expired - Fee Related
- 1997-08-12 NO NO973707A patent/NO973707L/no not_active Application Discontinuation
- 1997-08-12 AU AU34133/97A patent/AU3413397A/en not_active Abandoned
- 1997-08-12 CN CN97117378A patent/CN1182093A/zh active Pending
- 1997-08-13 KR KR1019970038623A patent/KR19980018651A/ko not_active Application Discontinuation
- 1997-08-13 JP JP9218716A patent/JPH10158269A/ja active Pending
- 1997-08-13 BR BR9704354A patent/BR9704354A/pt not_active Application Discontinuation

Also Published As

Publication number	Publication date
TW408138B (en)	2000-10-11
AU3413397A (en)	1998-02-19
US6329313B1 (en)	2001-12-11
DE59712644D1 (de)	2006-06-14
EP0824112B1 (fr)	2006-05-10
CN1182093A (zh)	1998-05-20
JPH10158269A (ja)	1998-06-16
NO973707D0 (no)	1997-08-12
BR9704354A (pt)	1999-01-12
ATE325821T1 (de)	2006-06-15
NO973707L (no)	1998-02-16
EP0824112A1 (fr)	1998-02-18
CA2212668A1 (fr)	1998-02-13

Legal Events

Date	Code	Title	Description
2004-07-20	WITN	Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid

Publication	Publication Date	Title
KR19980018651A (ko)	1998-06-05	지지된 화학적 화합물
KR100479253B1 (ko)	2005-08-04	올레핀 중합용촉매성분으로서적합한중성또는이온성화합물및이의제조방법
JP4105783B2 (ja)	2008-06-25	担持された触媒システム、その調製方法、及びオレフィンを重合させるための前記触媒システムの使用
KR100576195B1 (ko)	2006-05-03	촉매 시스템
JP4652343B2 (ja)	2011-03-16	担持メタロセン触媒、その製造方法及びそれを利用したポリオレフィンの製造方法
US6500908B1 (en)	2002-12-31	Catalyst system
JP4334136B2 (ja)	2009-09-30	化合物
US6949614B1 (en)	2005-09-27	Catalyst system
RU2142466C1 (ru)	1999-12-10	Металлоцены, содержащая их каталитическая система, способ полимеризации олефинов, полиолефин, формованное изделие
KR19980070899A (ko)	1998-10-26	메탈로센 촉매계를 제조하는 방법
US5792819A (en)	1998-08-11	Process for the preparation of an olefin polymer
US5767300A (en)	1998-06-16	Metallocene compound
JP2002516359A (ja)	2002-06-04	触媒組成物
KR100394892B1 (ko)	2003-11-10	쯔비터이온성전이금속화합물,이의제조방법및당해화합물을포함하는촉매성분
DE19632558A1 (de)	1998-02-19	Geträgerte chemische Verbindung
DE19632557A1 (de)	1998-02-19	Chemische Verbindung
DE19647070A1 (de)	1998-05-20	Geträgerte chemische Verbindung
KR19980064290A (ko)	1998-10-07	작용성화된 중합체 제조용 촉매