KR102532638B1 - Super elasto-plastic asphalt based waterproof coating layer composition and construction method for waterproof coating layer using the same - Google Patents
Super elasto-plastic asphalt based waterproof coating layer composition and construction method for waterproof coating layer using the same Download PDFInfo
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- KR102532638B1 KR102532638B1 KR1020220127627A KR20220127627A KR102532638B1 KR 102532638 B1 KR102532638 B1 KR 102532638B1 KR 1020220127627 A KR1020220127627 A KR 1020220127627A KR 20220127627 A KR20220127627 A KR 20220127627A KR 102532638 B1 KR102532638 B1 KR 102532638B1
- Authority
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- South Korea
- Prior art keywords
- asphalt
- synthetic polymer
- styrene
- coating film
- composition
- Prior art date
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- 239000010426 asphalt Substances 0.000 title claims abstract description 65
- 239000000203 mixture Substances 0.000 title claims abstract description 46
- 238000010276 construction Methods 0.000 title description 8
- 229920003023 plastic Polymers 0.000 title description 2
- 239000004033 plastic Substances 0.000 title description 2
- 239000011247 coating layer Substances 0.000 title 2
- 239000011248 coating agent Substances 0.000 claims abstract description 50
- 238000000576 coating method Methods 0.000 claims abstract description 50
- 229920001059 synthetic polymer Polymers 0.000 claims abstract description 43
- 239000000463 material Substances 0.000 claims abstract description 34
- 239000004793 Polystyrene Substances 0.000 claims abstract description 27
- FACXGONDLDSNOE-UHFFFAOYSA-N buta-1,3-diene;styrene Chemical compound C=CC=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 FACXGONDLDSNOE-UHFFFAOYSA-N 0.000 claims abstract description 27
- 229920002223 polystyrene Polymers 0.000 claims abstract description 27
- VSKJLJHPAFKHBX-UHFFFAOYSA-N 2-methylbuta-1,3-diene;styrene Chemical compound CC(=C)C=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 VSKJLJHPAFKHBX-UHFFFAOYSA-N 0.000 claims abstract description 26
- 229920001684 low density polyethylene Polymers 0.000 claims abstract description 26
- 239000004702 low-density polyethylene Substances 0.000 claims abstract description 26
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 claims abstract description 26
- 229920002857 polybutadiene Polymers 0.000 claims abstract description 25
- 239000005062 Polybutadiene Substances 0.000 claims abstract description 23
- 229920001971 elastomer Polymers 0.000 claims abstract description 18
- 239000005060 rubber Substances 0.000 claims abstract description 18
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 15
- 239000004567 concrete Substances 0.000 claims abstract description 11
- 238000004078 waterproofing Methods 0.000 claims description 47
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims description 27
- 239000005038 ethylene vinyl acetate Substances 0.000 claims description 26
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 claims description 25
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 claims description 16
- 239000004342 Benzoyl peroxide Substances 0.000 claims description 10
- 235000019400 benzoyl peroxide Nutrition 0.000 claims description 10
- 239000003999 initiator Substances 0.000 claims description 10
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims description 7
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 7
- 238000002844 melting Methods 0.000 claims description 5
- 230000008018 melting Effects 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- OZAIFHULBGXAKX-VAWYXSNFSA-N AIBN Substances N#CC(C)(C)\N=N\C(C)(C)C#N OZAIFHULBGXAKX-VAWYXSNFSA-N 0.000 claims description 4
- 239000004745 nonwoven fabric Substances 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 229920000642 polymer Polymers 0.000 abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 7
- 239000011384 asphalt concrete Substances 0.000 abstract description 6
- 230000035699 permeability Effects 0.000 abstract description 4
- 229920003229 poly(methyl methacrylate) Polymers 0.000 abstract description 4
- 239000004926 polymethyl methacrylate Substances 0.000 abstract description 4
- 230000001681 protective effect Effects 0.000 abstract description 2
- 229920000219 Ethylene vinyl alcohol Polymers 0.000 abstract 2
- 239000004715 ethylene vinyl alcohol Substances 0.000 abstract 2
- RZXDTJIXPSCHCI-UHFFFAOYSA-N hexa-1,5-diene-2,5-diol Chemical compound OC(=C)CCC(O)=C RZXDTJIXPSCHCI-UHFFFAOYSA-N 0.000 abstract 2
- 229910052799 carbon Inorganic materials 0.000 description 19
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 10
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 10
- 150000003254 radicals Chemical class 0.000 description 10
- 239000000178 monomer Substances 0.000 description 9
- 229920001577 copolymer Polymers 0.000 description 7
- RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 239000002253 acid Substances 0.000 description 5
- 230000035515 penetration Effects 0.000 description 4
- 230000000379 polymerizing effect Effects 0.000 description 4
- 230000002194 synthesizing effect Effects 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- 239000005977 Ethylene Substances 0.000 description 3
- -1 Polyethylene Polymers 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 230000003014 reinforcing effect Effects 0.000 description 3
- 229920001169 thermoplastic Polymers 0.000 description 3
- 239000004416 thermosoftening plastic Substances 0.000 description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
- 229920002554 vinyl polymer Polymers 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 2
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 229920001400 block copolymer Polymers 0.000 description 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 2
- 150000001723 carbon free-radicals Chemical class 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 229940125904 compound 1 Drugs 0.000 description 2
- 229940125782 compound 2 Drugs 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000008602 contraction Effects 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 229920000578 graft copolymer Polymers 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229920001903 high density polyethylene Polymers 0.000 description 2
- 239000004700 high-density polyethylene Substances 0.000 description 2
- 229920000092 linear low density polyethylene Polymers 0.000 description 2
- 239000004707 linear low-density polyethylene Substances 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 238000010526 radical polymerization reaction Methods 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- YKJYKKNCCRKFSL-RDBSUJKOSA-N (-)-anisomycin Chemical compound C1=CC(OC)=CC=C1C[C@@H]1[C@H](OC(C)=O)[C@@H](O)CN1 YKJYKKNCCRKFSL-RDBSUJKOSA-N 0.000 description 1
- QPILHXCDZYWYLQ-UHFFFAOYSA-N 2-nonyl-1,3-dioxolane Chemical compound CCCCCCCCCC1OCCO1 QPILHXCDZYWYLQ-UHFFFAOYSA-N 0.000 description 1
- FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 description 1
- REEBWSYYNPPSKV-UHFFFAOYSA-N 3-[(4-formylphenoxy)methyl]thiophene-2-carbonitrile Chemical compound C1=CC(C=O)=CC=C1OCC1=C(C#N)SC=C1 REEBWSYYNPPSKV-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 101000851593 Homo sapiens Separin Proteins 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 102100036750 Separin Human genes 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 229920000800 acrylic rubber Polymers 0.000 description 1
- 125000005250 alkyl acrylate group Chemical group 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- JRKOSYZXHJZKLA-UHFFFAOYSA-N buta-1,3-diene styrene Chemical compound C=CC=C.C=Cc1ccccc1.C=Cc1ccccc1.C=Cc1ccccc1 JRKOSYZXHJZKLA-UHFFFAOYSA-N 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 239000000306 component Substances 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000007342 radical addition reaction Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 229920002725 thermoplastic elastomer Polymers 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D195/00—Coating compositions based on bituminous materials, e.g. asphalt, tar, pitch
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/08—Styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F236/10—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated with vinyl-aromatic monomers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
- C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/04—Azo-compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C08L23/0853—Vinylacetate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/08—Copolymers of styrene
- C08L25/10—Copolymers of styrene with conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/10—Homopolymers or copolymers of methacrylic acid esters
- C08L33/12—Homopolymers or copolymers of methyl methacrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
Abstract
Description
본 발명은 고탄소성 아스팔트 도막 방수재 및 이의 시공방법에 관한 것으로, 더욱 상세하게는 도로, 교량, 교면, 아스팔트 콘크리트 구조물 등의 미세균열 및 모세관 공극으로의 침투성능이 우수한 고탄소성 아스팔트 도막 방수재 및 이의 시공방법에 관한 것이다.The present invention relates to a high-carbon asphalt coating waterproofing material and its construction method, and more particularly, to a high-carbon asphalt coating waterproofing material excellent in penetration into microcracks and capillary pores of roads, bridges, bridge surfaces, asphalt concrete structures, etc., and its construction It's about how.
여기서는, 본 개시에 관한 배경기술이 제공되며, 이들이 반드시 공지기술을 의미하는 것은 아니다.BACKGROUND OF THE INVENTION Here, background art related to the present disclosure is provided, and they are not necessarily meant to be prior art.
일반적으로 콘크리트 교면은 교통 차량에 의한 반복하중, 진동, 충격 및 전단 등의 작용과 온도 변화에 의한 수축 팽창 등이 복잡하게 작용하고 있다. 이러한 콘크리트 교면의 공용년수가 증가하면 빗물 침투와 제설재의 침투, 누적된 하중 등에 의해 재료간의 결합력이 저하되고 온도변화에 의한 물의 체적변화에 따라 균열 등의 손상이 발생한다. 이러한 손상은 시간경과에 따라 균열 및 변형이 확대되어 구조물의 강도저하 및 수명저하를 초래하며, 우수 등이 아스팔트 공극 균열부분과 중앙분리대 및 조인트 부위의 틈새를 통해 침투함으로써 콘크리트 내부의 철근을 부식시켜 구조물의 수명단축 및 붕괴를 초래할 수 있다.In general, concrete bridge surfaces are subjected to complex actions such as repeated loads, vibrations, shocks, and shears caused by traffic vehicles, and contraction and expansion due to temperature changes. When the number of years of use of such a concrete bridge increases, the bonding strength between materials decreases due to rainwater penetration, snow removal material penetration, and accumulated load, and damage such as cracks occurs due to the volume change of water due to temperature change. This damage causes cracks and deformations to expand over time, resulting in a decrease in the strength and life of the structure, and rainwater penetrates through cracks in asphalt voids, median strips, and joints, corroding reinforcing bars inside concrete. It may shorten the life of the structure and cause collapse.
따라서 콘크리트 교면에 적용되는 방수시공은 이러한 손상을 방지하고자 적용되는 것으로, 아스팔트 포장으로부터 침투되는 물과 염화물에 의한 바닥판 콘크리트의 열화 및 철근의 부식 등을 방지하기 위하여 필수적으로 수행되어야 한다.Therefore, waterproof construction applied to concrete bridge surfaces is applied to prevent such damage, and must be performed in order to prevent deterioration of deck concrete and corrosion of reinforcing bars by water and chloride penetrating from asphalt pavement.
본 발명은 콘크리트 구조물의 포장면 상부 표면에 가열식 도막 방수를 목적으로 적용할 수 있고 현장에 적용시에는 상부 표면에 가열식 고탄소성 아스팔트 도막 방수재를 도포하고 상면에 부직포를 덮어 차량 및 건설장비 진입시 아스팔트 도막의 손상을 예방할 수 있는 고탄소성 아스팔트 도막 방수재 조성물 및 이의 시공방법 제공하고자 한다. The present invention can be applied for the purpose of waterproofing a heated coating film on the upper surface of the pavement surface of a concrete structure, and when applied in the field, a heated high-carbon asphalt coating waterproofing material is applied to the upper surface and a non-woven fabric is covered on the upper surface to prevent asphalt coating when entering vehicles and construction equipment. It is intended to provide a high-carbon asphalt coating waterproofing material composition that can prevent damage and a construction method thereof.
그러나 본 발명의 목적들은 상기에 언급된 목적으로 제한되지 않으며, 언급되지 않은 또 다른 목적들은 아래의 기재로부터 당업자에게 명확하게 이해될 수 있을 것이다.However, the objects of the present invention are not limited to the above-mentioned objects, and other objects not mentioned will be clearly understood by those skilled in the art from the description below.
본 발명은 아스팔트(asphalt), EVA(Ethylene-Vinyl Acetate), SBS(Styrene Butadiene Styrene), LDPE(Low-density polyethylene), SIS(Styrene Isoprene Styrene) 및 합성 고분자를 포함하고, 상기 합성 고분자는 폴리스티렌(Polystyrene), 폴리부타디엔(Polybutadiene), 폴리메틸메타크릴산(Polymethylmethacrylate) 및 아크릴레이트 고무(Acrylate rubber)로 구성되는 군에서 선택되는 2종 이상을 합성한 고분자를 포함하는 아스팔트 도막 방수재 조성물을 제공한다. The present invention includes asphalt, EVA (Ethylene-Vinyl Acetate), SBS (Styrene Butadiene Styrene), LDPE (Low-density polyethylene), SIS (Styrene Isoprene Styrene), and a synthetic polymer, wherein the synthetic polymer is polystyrene ( Polystyrene), polybutadiene, polymethylmethacrylate, and acrylate rubber (Acrylate rubber) to provide an asphalt coating film waterproofing composition containing a polymer synthesized.
또한 상기 조성물 전체 중량에 대해 상기 아스팔트는 78.5 내지 95.7 wt%, 상기 EVA는 0.5 내지 2.5 wt%, 상기 SBS는 0.5 내지 2.5 wt%, 상기 LDPE는 1.5 내지 4.5 wt%, 상기 SIS는 1.5 내지 4.5 wt%, 상기 합성 고분자는 0.2 내지 7 wt% 포함되는 것을 특징으로 한다.In addition, with respect to the total weight of the composition, the asphalt is 78.5 to 95.7 wt%, the EVA is 0.5 to 2.5 wt%, the SBS is 0.5 to 2.5 wt%, the LDPE is 1.5 to 4.5 wt%, the SIS is 1.5 to 4.5 wt% %, the synthetic polymer is characterized in that it is contained in 0.2 to 7 wt%.
또한 상기 합성 고분자는 폴리부타디엔 및 폴리스티렌을 합성한 제1 합성 고분자와 폴리메틸메타크릴산 및 아크릴레이트 고무를 합성한 제2 합성 고분자를 포함하는 것을 특징으로 한다.In addition, the synthetic polymer may include a first synthetic polymer obtained by synthesizing polybutadiene and polystyrene, and a second synthetic polymer obtained by synthesizing polymethylmethacrylic acid and acrylate rubber.
또한 상기 제1 합성 고분자는 상기 폴리부타디엔을 30 내지 40 wt%, 상기 폴리스티렌을 60 내지 70wt% 포함하는 것을 특징으로 한다.In addition, the first synthetic polymer may include 30 to 40 wt% of the polybutadiene and 60 to 70 wt% of the polystyrene.
또한 상기 합성 고분자는 AIBN(Azo-bisisobutyronitrile; 아조비스이소부티로니트릴) 또는 BPO(Benzoyl peroxide; 벤조일퍼옥사이드)를 포함하는 개시제를 사용하여 합성된 것을 특징으로 한다.In addition, the synthetic polymer is characterized in that it is synthesized using an initiator including AIBN (Azo-bisisobutyronitrile; azobisisobutyronitrile) or BPO (Benzoyl peroxide; benzoyl peroxide).
또한 본 발명은 가열 용융된 아스팔트에 EVA(Ethylene-Vinyl Acetate), SBS(Styrene Butadiene Styrene), LDPE(Low-density polyethylene) 및 SIS(Styrene Isoprene Styrene)를 혼입하여 용융시키는 단계; 및 상기 합성 고분자를 중합하여 상기 아스팔트 혼합물에 혼입하는 단계;를 포함하는 아스팔트 도막 방수재 조성물의 제조방법을 제공한다. In addition, the present invention includes the steps of mixing and melting EVA (Ethylene-Vinyl Acetate), SBS (Styrene Butadiene Styrene), LDPE (Low-density polyethylene) and SIS (Styrene Isoprene Styrene) into the heated and melted asphalt; and polymerizing the synthetic polymer and incorporating it into the asphalt mixture.
또한 본 발명은 상기 조성물을 포함하여 형성된 아스팔트 도막 방수재를 제공한다.In addition, the present invention provides an asphalt coating film waterproofing material formed by including the composition.
또한 본 발명은 상기 조성물을 가열 용융된 상태로 콘크리트 구조물 표면에 도포하고 상면에 부직포를 덮는 아스팔트 도막 방수재의 시공방법을 제공한다.In addition, the present invention provides a method for constructing an asphalt coating film waterproofing material in which the composition is applied to the surface of a concrete structure in a heated and melted state and the non-woven fabric is covered on the upper surface.
본 발명은 일반 아스팔트에 개질 성분을 첨가하여 고온에서 강한 탄성 유지로 변형 저항성이 우수하고 저온 균열에 강한 고탄소성 아스팔트(Super Elasto-plastic Asphalt : SEPA) 도막 방수재 조성물 및 이를 이용한 도막형 방수재 시공방법을 제공한다. The present invention is a high-carbon asphalt (Super Elasto-plastic Asphalt: SEPA) coating film waterproofing composition that is resistant to cracking at low temperatures and has excellent deformation resistance by maintaining strong elasticity at high temperatures by adding a modifying component to general asphalt, and a coating film-type waterproofing construction method using the same to provide.
이에 적용하고자 하는 표면, 예를 들면 도로, 교량, 교면, 아스팔트 콘크리트 구조물의 미세균열 및 모세관 공극 등으로의 침투성능이 우수한 아스팔트계 도막 방수재를 적용함으로써 추가적 보호막을 형성할 수 있고, 외부하중이나 충격 등으로 손상받기 쉬운 아스팔트 콘크리트 교면과 방수재 계면의 결합을 공고히 할 수 있을 뿐만 아니라 내투수 저항성을 향상시킬 수 있어 아스팔트 콘크리트 교면의 내구성을 대폭 향상시킬 수 있다.An additional protective film can be formed by applying an asphalt-based coating film waterproofing material with excellent penetration performance into the surface to be applied, such as roads, bridges, bridges, and fine cracks and capillary pores of asphalt concrete structures, and an external load or impact It not only strengthens the bond between the asphalt concrete bridge surface, which is easily damaged by fire, and the interface of the waterproofing material, but also improves the water permeability resistance, thereby significantly improving the durability of the asphalt concrete bridge surface.
본 명세서에 사용되는 모든 기술용어 및 과학용어는 다른 언급이 없는 한은 기술적으로 통상의 기술을 가진 자에게 일반적으로 이해되는 것과 동일한 의미를 가진다. 또한 본 명세서 및 청구범위의 전반에 걸쳐, 다른 언급이 없는 한 포함(comprise, comprises, comprising)이라는 용어는 언급된 물건, 단계 또는 일군의 물건, 및 단계를 포함하는 것을 의미하고, 임의의 어떤 다른 물건, 단계 또는 일군의 물건 또는 일군의 단계를 배제하는 의미로 사용된 것은 아니다.All technical and scientific terms used herein have the same meaning as commonly understood by a person of ordinary skill in the art unless otherwise specified. Also throughout this specification and claims, the terms "comprise", "comprising", and "comprising", unless stated otherwise, are meant to include a stated object, step or group of objects, and steps, and any other It is not intended to exclude an object, step or group of objects or steps.
이하에 본 발명을 상세하게 설명하기에 앞서, 본 명세서에 사용된 용어는 특정의 실시예를 기술하기 위한 것일 뿐 첨부하는 특허청구의 범위에 의해서만 한정되는 본 발명의 범위를 한정하려는 것은 아님을 이해하여야 한다.Prior to describing the present invention in detail below, it is understood that the terms used herein are intended to describe specific embodiments and are not intended to limit the scope of the present invention, which is limited only by the appended claims. shall.
한편, 본 발명의 여러 가지 실시예들은 명확한 반대의 지적이 없는 한 그 외의 어떤 다른 실시예들과 결합될 수 있다. 특히 바람직하거나 유리하다고 지시하는 어떤 특징도 바람직하거나 유리하다고 지시한 그 외의 어떤 특징 및 특징들과 결합될 수 있다. 이하, 첨부된 도면을 참조하여 본 발명의 실시예 및 이에 따른 효과를 설명하기로 한다.On the other hand, various embodiments of the present invention can be combined with any other embodiments unless clearly indicated to the contrary. Any feature indicated as being particularly desirable or advantageous may be combined with any other features and characteristics indicated as being particularly desirable or advantageous. Hereinafter, embodiments of the present invention and effects thereof will be described with reference to the accompanying drawings.
본 발명의 일실시예에 따른 고탄소성 아스팔트 도막 방수재 조성물은 아스팔트(asphalt), EVA(Ethylene-Vinyl Acetate), SBS(Styrene Butadiene Styrene), LDPE(Low-density polyethylene), SIS(Styrene Isoprene Styrene) 및 합성 고분자를 포함한다. 상기 고탄소성 개질 아스팔트 도막 방수재는 고탄소성 성능을 좀 더 향상시키고 도막의 성능을 개선하기 위해 EVA, SBS, LDPE, SIS와의 결합력을 증진시킬 목적으로 합성 고분자를 포함하며, 아스팔트, EVA, SBS, LDPE, SIS와 구조적 안정성을 확보하기 위해 개시제를 사용하여 합성 고분자를 중합한다.The high-carbon asphalt coating film waterproofing composition according to an embodiment of the present invention includes asphalt, EVA (Ethylene-Vinyl Acetate), SBS (Styrene Butadiene Styrene), LDPE (Low-density polyethylene), SIS (Styrene Isoprene Styrene) and Contains synthetic polymers. The high-carbon modified asphalt coating film waterproofing material includes a synthetic polymer for the purpose of enhancing the bonding strength with EVA, SBS, LDPE, and SIS to further improve the high-carbon performance and improve the performance of the coating film, and asphalt, EVA, SBS, and LDPE , polymerizes a synthetic polymer using an initiator to secure structural stability with SIS.
상기 아스팔트는 석유를 구성하고 있는 성분 중에서 경질 유분이 제거되고 남은 최종 잔사물로서 천연 아스팔트와 원유 정제 후 얻어지는 석유 아스팔트로 구분할 수 있다. 아스팔트는 상온에서 흑갈색 반고체 성질을 가진 점탄성이 우수하며, 접착력 및 방수성능이 탁월한 물질이다. 또한 각종 탄화수소가 주성분이고 그밖에 유황, 질소, 산소와 미량의 금속화합물로 이루어진 화학적으로 매우 복잡한 구조를 가진다. 아스팔트의 주성분은 포화탄화수소, 방향족 화합물, 수지, 아스팔텐으로서 아스팔텐을 제외한 세가지 성분을 말텐으로 분류한다. 순수 아스팔트 자체의 물성은 저온에서 유리화 되어 쉽게 깨지며, 고온에서 흘러내림이 커서 사용상의 주의가 필요하다. 이로 인해 아스팔트를 기반으로 한 도막 방수재는 합성 고분자를 활용하여 재료의 물리적 성질을 개선할 필요가 있다. The asphalt is a final residue remaining after light oil is removed from components constituting petroleum, and can be classified into natural asphalt and petroleum asphalt obtained after crude oil refining. Asphalt is a material with excellent viscoelasticity, blackish-brown semi-solid properties at room temperature, and excellent adhesion and waterproof performance. In addition, it has a chemically very complex structure consisting of various hydrocarbons as the main component and sulfur, nitrogen, oxygen and trace amounts of metal compounds. The main components of asphalt are saturated hydrocarbons, aromatic compounds, resins, and asphaltenes, and three components excluding asphaltenes are classified as maltenes. The physical properties of pure asphalt itself are vitrified at low temperatures and are easily broken. For this reason, it is necessary to improve the physical properties of asphalt-based coating film waterproofing materials by utilizing synthetic polymers.
본 발명에서의 고탄소성 아스팔트 도막 방수재 조성물은 상기 아스팔트를 조성물 전체 중량에 대해 78.5 내지 95.7 wt%로 포함한다. 더욱 바람직하게는 83.2 내지 91.2 wt% 포함되는 것이 좋다. The high-carbon asphalt coating film waterproofing composition in the present invention includes the asphalt in an amount of 78.5 to 95.7 wt% based on the total weight of the composition. More preferably, it is good to include 83.2 to 91.2 wt%.
상기 EVA는 고압반응기에서 에틸렌(Ethylene)과 비닐 아세테이트(Vinyl acetate; VA)이 자유라디칼(Free-radical) 첨가 중합을 통해서 연속공정(Continuous process)으로 생산된다. 예를 들어, LDPE에 VA를 첨가하여 중합 가능하며 VA의 함량에 따라 성질이 달라질 수 있다. 예를 들어 VA의 함량이 증가시 강도, 결정화도, 녹는점, 화학적 내구성이 감소하며, 충격강도, 투명도, 마찰계수는 증가 할 수 있다.The EVA is produced in a continuous process through free-radical addition polymerization of ethylene and vinyl acetate (VA) in a high-pressure reactor. For example, LDPE can be polymerized by adding VA, and properties may vary depending on the content of VA. For example, when the content of VA increases, strength, crystallinity, melting point, and chemical durability decrease, while impact strength, transparency, and friction coefficient may increase.
EVA의 종류에는 비닐 아세테이트의 비율이 약 2%로 낮은 비닐 아세테이트 변성 폴리머 에틸렌이 있으며 열가소성 에틸렌-아세트산비닐 공중합체로 비닐 아세테이트가 4~15% 포함된 가황되지 않은 열가소성 엘라스토머 소재가 있다. 마지막으로 에틸렌-비닐 아세테이트(Ethylene-Vinyl Acetate) 고무는 비닐 아세테이트 함량이 20% 이상인 EVA 공중합체이다. Types of EVA include ethylene, a vinyl acetate-modified polymer with a low vinyl acetate ratio of about 2%, and unvulcanized thermoplastic elastomer materials containing 4 to 15% of vinyl acetate as a thermoplastic ethylene-vinyl acetate copolymer. Finally, ethylene-vinyl acetate rubber is an EVA copolymer with a vinyl acetate content of 20% or more.
본 발명에서의 고탄소성 아스팔트 도막 방수재 조성물은 VA 함량이 6 내지 10 wt%인 EVA을 사용하고, 상기 EVA를 조성물 전체 중량에 대해 0.5 내지 2.5 wt% 포함하여 도막 방수재의 강성증진의 효과를 제공한다. 더욱 바람직하게는 1 내지 2 wt% 포함되는 것이 좋다. The high-carbon asphalt coating film waterproofing composition of the present invention uses EVA having a VA content of 6 to 10 wt%, and contains 0.5 to 2.5 wt% of the EVA with respect to the total weight of the composition to provide an effect of enhancing the stiffness of the coating film waterproofing material. . More preferably, it is good to include 1 to 2 wt%.
상기 SBS는 스티렌(Styrene)과 부타디엔(Butadiene)이 연결된 블록 공중합체로서 유연한 폴리부타디엔 매트릭스(Polybutadiene matrix)의 연속상과 경질 폴리스티렌 도메인(Polystyrene domain) 분산상의 이중형태를 가진 스티렌-부타디엔-스티렌(Styrene-butadiene-styrene) 삼중블록 체인(triblock chain)들로 구성된다. 여기에서 폴리스티렌과 폴리부타디엔 블록들 간의 화학적 연결은 매트릭스 내 도메인들을 효과적으로 고정시킬수 있다. SBS에서 폴리스티렌 사슬은 강하고 딱딱하여 내구성을 증진시키는 역할을 하는 반면 폴리부타디엔은 고무처럼 거동할 수 있다. 폴리스티렌 사슬은 서로 덩어리지려는 경향이 있어, SBS에 있는 하나의 스티렌기가 하나의 덩어리로 뭉치면 같은 SBS에 있는 다른 폴리스티렌 사슬은 다른 덩어리들을 형성한다. 결국 서로 다른 각각의 덩어리들이 폴리부타디엔과 함께 묶여짐으로써, SBS에 힘을 가해 늘린 후에도 힘을 풀면 원상태로 복원할 수 있게 된다. The SBS is a block copolymer in which styrene and butadiene are connected, and has a dual form of a continuous phase of a flexible polybutadiene matrix and a dispersed phase of a rigid polystyrene domain. Styrene-butadiene-styrene (Styrene) It consists of -butadiene-styrene) triblock chains. Here, chemical linkages between the polystyrene and polybutadiene blocks can effectively immobilize the domains in the matrix. In SBS, polystyrene chains are strong and stiff, which increases durability, while polybutadiene can behave like rubber. Polystyrene chains tend to clump together, so when one styrene group on an SBS clumps together, other polystyrene chains on the same SBS form other clumps. As a result, each different lump is bound together with polybutadiene, so that even after stretching by applying force to SBS, it can be restored to its original state when the force is released.
본 발명에서의 고탄소성 아스팔트 도막 방수재 조성물은 상기 SBS를 조성물 전체 중량에 대하여 0.5 내지 2.5 wt% 포함하여 도막방수재의 강성증진의 효과를 제공하며, 고온에서 아스팔트와 용융함으로써 고탄성 및 복원성능이 부여될 수 있으며 구조물에 도막 방수재로 시공 시 구조물의 신축에 쉽게 적응하여 표면균열에 대한 저항성능을 확보할 수 있다. 더욱 바람직하게는 1.5 내지 2.4 wt% 포함되는 것이 좋다. The high-carbon asphalt coating film waterproofing composition of the present invention includes 0.5 to 2.5 wt% of the SBS based on the total weight of the composition to provide an effect of increasing the stiffness of the coating waterproofing material, and is melted with asphalt at a high temperature to impart high elasticity and restoring performance. It can be easily adapted to the expansion and contraction of a structure when it is constructed as a coating film waterproofing material on a structure to secure resistance to surface cracks. More preferably, it is good to include 1.5 to 2.4 wt%.
상기 LDPE는 밀도가 0.910~0.92g/cm3인 분자구조가 가장 간단한 수지 중의 하나로 LLDPE(Linear low-density polyethylene)나 HDPE(high-density polyethylene)가 전이금속계 촉매를 이용하여 중·저압에서 중합하는 방식으로 제조되는 반면, LDPE는 고압라디칼 중합방식에 의해 제조되기 때문에 장쇄 분지가 많은 것이 특징이라 할 수 있다. 폴리에틸렌은 자유라디칼중합 공정을 통해 고압조건(1,000~3,000 기압, 80~300℃)에서 생산되며 분자는 4,000~40,000개의 정도의 탄소원자로 구성되며 측쇄를 구성하는 사슬은 짧은 가지가 많다. The LDPE is one of the simplest resins with a molecular structure having a density of 0.910 to 0.92 g / cm 3 , and LLDPE (Linear low-density polyethylene) or HDPE (high-density polyethylene) is polymerized at medium and low pressure using a transition metal-based catalyst. On the other hand, LDPE is produced by high-pressure radical polymerization, so it can be characterized by many long-chain branches. Polyethylene is produced under high pressure conditions (1,000 to 3,000 atm, 80 to 300 °C) through a free radical polymerization process. The molecule is composed of about 4,000 to 40,000 carbon atoms, and the chain constituting the side chain has many short branches.
본 발명에서의 고탄소성 아스팔트 도막 방수재 조성물은 상기 LDPE를 조성물 전체 중량에 대하여 1.5 내지 4.5 wt% 포함하여 도막 방수재의 강성을 보강하는 효과를 제공한다. 더욱 바람직하게는 2.5 내지 3.5 wt% 포함되는 것이 좋다. The high-carbon asphalt coating film waterproofing composition of the present invention includes 1.5 to 4.5 wt% of the LDPE based on the total weight of the composition to provide an effect of reinforcing the stiffness of the coating film waterproofing material. More preferably, it is good to include 2.5 to 3.5 wt%.
상기 SIS는 열가소성 3-블록공중합체이며 폴리스타이렌 블록이 폴리이소프렌 블록의 사슬꼬임에 분산된 구조를 이루며, 스티렌 함량은 15~40% 사이에서 다양하다. 융점이하로 냉각시 모든 폴리스티렌 블록 고분자 중에서 우수한 열가소성 공정성을 가진다. The SIS is a thermoplastic 3-block copolymer and has a structure in which a polystyrene block is dispersed in a chain twist of a polyisoprene block, and the styrene content varies between 15% and 40%. When cooled below the melting point, it has excellent thermoplastic processability among all polystyrene block polymers.
본 발명에서의 고탄소성 아스팔트 도막 방수재 조성물은 스티렌 함량이 15 내지 20 wt%인 SIS을 사용하고, 상기 SIS를 조성물 전체 중량에 대하여 1.5 내지 4.5 wt% 포함하여 가열 아스팔트에 적용시 부착성능이 우수하여 도막 방수재의 구조물 부착성능을 향상시키는 효과를 제공한다. 더욱 바람직하게는 2.5 내지 4 wt% 포함되는 것이 좋다. The high-carbon asphalt coating film waterproofing composition of the present invention uses SIS having a styrene content of 15 to 20 wt%, and contains 1.5 to 4.5 wt% of the SIS based on the total weight of the composition, so that when applied to hot asphalt, the adhesion performance is excellent It provides the effect of improving the structure adhesion performance of the coating film waterproofing material. More preferably, it is good to include 2.5 to 4 wt%.
상기 합성 고분자는 고탄소성 성능을 향상시키고 EVA, SBS, LDPE, SIS 와의 결합력을 증진시키는 역할을 하는 화합물로서, 폴리스티렌(Polystyrene), 폴리부타디엔(Polybutadiene), 폴리메틸메타크릴산(Polymethylmethacrylate) 및 아크릴레이트 고무(Acrylate rubber)로 구성되는 군에서 선택되는 2종 이상을 합성한 고분자를 포함한다. 본 발명에서의 고탄소성 아스팔트 도막 방수재 조성물은 상기 합성 고분자를 조성물 전체 중량에 대하여 0.2 내지 7 wt% 포함하여 고탄소성 성능을 향상시키고 EVA, SBS, LDPE, SIS 와의 결합력을 증진시킬 수 있다. 더욱 바람직하게는 1 내지 4.5 wt% 포함되는 것이 좋다. The synthetic polymer is a compound that serves to improve high carbon performance and enhances bonding strength with EVA, SBS, LDPE, and SIS, and includes polystyrene, polybutadiene, polymethylmethacrylate and acrylate It includes a polymer synthesized from two or more selected from the group consisting of rubber (Acrylate rubber). The high-carbon asphalt coating film waterproofing composition of the present invention includes 0.2 to 7 wt% of the synthetic polymer based on the total weight of the composition to improve high-carbon performance and enhance bonding strength with EVA, SBS, LDPE, and SIS. More preferably, it is good to include 1 to 4.5 wt%.
상기 합성 고분자는 바람직하게는 폴리부타디엔 및 폴리스티렌을 합성한 제1 합성 고분자와 폴리메틸메타크릴산 및 아크릴레이트 고무를 합성한 제2 합성 고분자를 포함한다. The synthetic polymer preferably includes a first synthetic polymer obtained by synthesizing polybutadiene and polystyrene and a second synthetic polymer obtained by synthesizing polymethylmethacrylic acid and acrylate rubber.
상기 제1 합성 고분자는 폴리부타디엔 및 폴리스티렌을 합성한 고분자로써 자유 라디칼(Free radical)을 이용하여 단량체를 중합하는 방법으로 합성된다. 더욱 구체적으로 스티렌 단량체를 중합하는 도중, 같은 반응기에 이미 중합된 폴리부타디엔 고무를 섞어 놓으면 폴리부타디엔의 주사슬에는 중합될 수 있는 이중결합이 남게 된다. 폴리부타디엔을 스티렌 단량체와 함께 공중합시키면 그라프트 공중합체(graft copolymer)라 부르는 공중합체가 얻어지고, 이는 폴리스티렌의 주사슬에 폴리부타디엔 사슬이 결합되어 얻어진 형태가 될 수 있다. 여기서 폴리부타디엔은 30 내지 40 wt%, 폴리스티렌은 60 내지 70wt% 포함된다.The first synthetic polymer is a polymer synthesized from polybutadiene and polystyrene, and is synthesized by polymerizing monomers using free radicals. More specifically, during the polymerization of the styrene monomer, when the polybutadiene rubber already polymerized is mixed in the same reactor, double bonds that can be polymerized remain in the main chain of the polybutadiene. When polybutadiene is copolymerized with a styrene monomer, a copolymer called a graft copolymer is obtained, which may be obtained by bonding a polybutadiene chain to a main chain of polystyrene. Here, 30 to 40 wt% of polybutadiene and 60 to 70 wt% of polystyrene are included.
이렇게 폴리스티렌 주사슬에 결합된 폴리부타디엔 고무는 폴리스티렌에게 중요한 능력을 부여한다. 여기서, 폴리스티렌과 폴리부타디엔은 서로 섞이지 않는다는 점에 집중해야 한다. 따라서 폴리부타디엔 가지는 폴리스티렌과 가능하면 멀리 떨어져 있으려고 하여 상분리를 유도함으로써 자신만의 공간을 만들고자 한다. 그러나 공간은 주성분인 폴리스티렌에 의해 단단히 갇혀 있다. 이렇게 특수한 구조로 되어 있는 그라프트 공중합체에 힘을 가하면 그 에너지는 고무 상인 폴리부타디엔이 먼저 흡수하게 된다. 폴리부타디엔은 폴리스티렌이 갖지 못한 고무 탄성을 공중합체에 부여하여 공중합체는 더욱 강해질 수 있어 도막 방수재의 탄성력을 증가시킬 수도 있다. The polybutadiene rubber bonded to the main polystyrene chain gives polystyrene important properties. Here, it should be noted that polystyrene and polybutadiene do not mix with each other. Therefore, the polybutadiene branch tries to make its own space by inducing phase separation by trying to stay as far away from the polystyrene as possible. However, the space is tightly confined by the main component, polystyrene. When force is applied to the graft copolymer having such a special structure, the energy is first absorbed by polybutadiene, which is a rubber phase. Polybutadiene imparts rubber elasticity, which polystyrene does not have, to the copolymer, so that the copolymer can be stronger, thereby increasing the elasticity of the coating film waterproofing material.
본 발명에서의 고탄소성 아스팔트 도막 방수재 조성물은 상기 제1 합성 고분자를 조성물 전체 중량에 대하여 0.1 내지 3 wt% 포함하여 도막 방수재에서 요구하는 고탄성 능력을 부여할 수 있다. 더욱 바람직하게는 0.5 내지 1.5 wt% 포함되는 것이 좋다. The high-carbon asphalt coating film waterproofing composition of the present invention includes 0.1 to 3 wt% of the first synthetic polymer based on the total weight of the composition, so that high elasticity required for the coating film waterproofing material can be imparted. More preferably, it is good to include 0.5 to 1.5 wt%.
상기 제2 합성 고분자는 폴리메틸메타크릴산 및 아크릴레이트 고무를 합성한 고분자이다. 폴리메틸메타크릴산(Polymethylmethacrylaye)은 가볍고 강도가 우수하며 가공성과 내구성이 우수하여 자동차, 항공기 등의 바람막이, 광학용 제품, 디스플레이, 조명기구, 화장품, 의약품, 건축, 전기전자, 장신구, 잡화 등 다양한 산업분야에 적용되고 있다. The second synthetic polymer is a polymer synthesized from polymethyl methacrylic acid and acrylate rubber. Polymethylmethacrylaye is lightweight, has excellent strength, and has excellent processability and durability, so it is used in a wide range of products such as windshields for automobiles and aircraft, optical products, displays, lighting fixtures, cosmetics, medicines, architecture, electrical and electronic products, accessories, and miscellaneous goods. It is applied in the industrial field.
메타크릴산의 에스테르인 폴리메틸메타크릴산은 중요한 아크릴 수지계열에 속하며 프로필렌과 벤젠이 함께 반응하여 큐멘 또는 이소프로필 벤젠을 형성한다. 큐멘은 산으로 처리되어 아세톤을 형성하는 큐멘 하이드로퍼 옥사이드로 산화되고 아세톤은 3단계 공정을 거쳐 메틸메타크릴레이트 인화성 액체가 된다. 이를 자유 라디칼 개시제의 영향으로 중합되어 고체 폴리메틸메타크릴레이트 형태로 존재할 수도 있다. Polymethylmethacrylic acid, an ester of methacrylic acid, is an important family of acrylic resins, and propylene and benzene react together to form cumene or isopropyl benzene. Cumene is treated with an acid to oxidize to cumene hydroperoxide to form acetone, which in a three-step process becomes methyl methacrylate, a flammable liquid. It may be polymerized under the influence of a free radical initiator to exist in the form of solid polymethyl methacrylate.
폴리메틸메타크릴산(Polymethylmethacrylaye)은 탁월한 투명성과 내후성을 지니고 있지만, 충격에 쉽게 손상이 되는 특징으로 본 발명에서는 아크릴레이트 고무를 이용하여 도막 방수재가 내후성과 더불어 충격 손상에 대한 저항성이 향상될 수 있다. Polymethyl methacrylic acid (Polymethylmethacrylaye) has excellent transparency and weather resistance, but it is easily damaged by impact. In the present invention, by using acrylate rubber, the coating film waterproofing material can improve resistance to impact damage as well as weather resistance. .
여기서 사용된 아크릴레이트 고무의 주성분이 아크릴산 알킬에스터인데 이중 에틸 아크릴레이트나 n-부틸 아크릴레이트 또는 그 외의 아크릴레이트와 아크릴로니트릴의 공중합물을 ANM라 하고 에틸아크릴레이트나 n-부틸 아크릴레이트 또는 그 외의 아크릴레이트와 소량의 염소원자를 포함하는 단량체의 공중합물을 ACM라는 약어로 부르며 이들 고무는 매우 뛰어난 내열성과 내유성을 가지며 150~175℃의 고온에서 사용이 가능할 수 있다. 아크릴 고무는 염소를 포함하는 ACM(acrylic alkyl ester와 2-chloroethyl vinyl ether의 공중합체)와 염소를 포함하지 않은 ANM(acrylic alkyl ester와 acrylonitrile의 공중합체)로 분류될 수 있다. ACM은 가공성이 현저히 개선과 더불어 내수성, 내한성 및 금속부식성이 개선이 가능할 수 있고 가황시간도 단축시킬 수 있다. The main component of the acrylate rubber used here is alkyl acrylate. A copolymer of ethyl acrylate, n-butyl acrylate or other acrylates and acrylonitrile is called ANM, and ethyl acrylate, n-butyl acrylate or its Copolymers of other acrylates and monomers containing a small amount of chlorine atoms are called ACM, and these rubbers have excellent heat resistance and oil resistance and can be used at high temperatures of 150 to 175 ° C. Acrylic rubber can be classified into chlorine-containing ACM (copolymer of acrylic alkyl ester and 2-chloroethyl vinyl ether) and chlorine-free ANM (copolymer of acrylic alkyl ester and acrylonitrile). ACM can significantly improve processability, improve water resistance, cold resistance, and metal corrosion, and shorten vulcanization time.
여기서 폴리메틸메타크릴산은 30 내지 40 wt%, 아크릴레이트 고무는 60 내지 70wt% 포함된다.Here, 30 to 40 wt% of polymethylmethacrylic acid and 60 to 70 wt% of acrylate rubber are included.
본 발명에서의 고탄소성 아스팔트 도막 방수재 조성물은 상기 제2 합성 고분자를 조성물 전체 중량에 대하여 0.1 내지 4 wt% 포함하여 도막 방수재로서 필요한 접착성을 개선시킬 수 있다. 더욱 바람직하게는 0.5 내지 3 wt% 포함되는 것이 좋다. The high-carbon asphalt coating film waterproofing composition of the present invention includes 0.1 to 4 wt% of the second synthetic polymer based on the total weight of the composition, so that the adhesion required as a coating film waterproofing material can be improved. More preferably, it is good to include 0.5 to 3 wt%.
본 발명에 따른 합성 고분자는 단량체 중합을 돕기 위한 개시제를 이용하여 합성된 것을 사용할 수 있다. 상기 개시제는 AIBN(Azo-bisisobutyronitrile; 아조비스이소부티로니트릴) 또는 BPO(Benzoyl peroxide; 벤조일퍼옥사이드)를 포함한다. AIBN은 열 또는 자외선에 의해 질소 가스(N2)와 2분자의 이소부틸니트릴(isobutylnitrile) 라디칼로 분리될 수 있고, Benzoyl peroxide는 2분자의 이산화탄소(CO2)와 페닐(phenyl) 라디칼로 분리될 수 있다.The synthetic polymer according to the present invention may be synthesized using an initiator for assisting monomer polymerization. The initiator includes AIBN (Azo-bisisobutyronitrile; azobisisobutyronitrile) or BPO (Benzoyl peroxide; benzoyl peroxide). AIBN can be separated into nitrogen gas (N 2 ) and two isobutylnitrile radicals by heat or ultraviolet light, and benzoyl peroxide can be separated into two molecules of carbon dioxide (CO 2 ) and phenyl radicals. can
이 라디칼은 하나의 전자를 가지고 있으므로 굉장히 불안정하다. 따라서 전자 하나를 받아들여 안정한 상태를 이루려고 하므로, 근처에 공유받을 수 있는 전자가 존재하면 바로 반응하고자 한다.This radical has one electron and is therefore very unstable. Therefore, since it tries to achieve a stable state by accepting one electron, it wants to react immediately if there is an electron that can be shared nearby.
즉, 에틸렌과 같은 비닐 단량체에 있는 C=C 이중결합의 π전자들은 이 자유라디칼과 쉽게 반응할 수 있다. 라디칼이 이중결합 근처로 오면 이중결합에 있는 전자 하나가 라디칼과 반응하게 된다. 이처럼 개시제가 외부 자극에 의해 분해되어 생긴 라디칼이 비닐계 단량체를 공격하고, 단량체 한 분자가 포함된 새로운 라디칼을 형성하는 과정이 진행될 수 있다. That is, the π electrons of the C=C double bond in vinyl monomers such as ethylene can easily react with these free radicals. When a radical comes near a double bond, one electron in the double bond reacts with the radical. As such, a radical generated when the initiator is decomposed by an external stimulus attacks the vinyl-based monomer, and a process of forming a new radical containing one molecule of the monomer may proceed.
단량체 라디칼 역시 안정하지 않으므로 같은 반응을 일으킨다. 새로운 단량체가 결합하며 라디칼이 새로운 말단으로 이전되고, 이러한 반응이 반복되며 사슬의 길이가 성장(Chain reaction)할 수 있다.Monomer radicals are also not stable, so they cause the same reaction. As new monomers are combined, radicals are transferred to new ends, and this reaction is repeated, and the length of the chain can grow (Chain reaction).
사슬 말단의 탄소 라디칼이 다른 사슬의 C-H 결합의 전자와 반응하고, 새로이 생성된 사슬 중간의 탄소 라디칼이 단량체와 반응하는 경우 가지형 고분자(branched polymer) 형태를 가질 수 있어 분자 간의 결합력을 증대시켜 도막 방수재의 강성이 보강될 수 있다. When the carbon radical at the end of a chain reacts with electrons of the C-H bond of another chain and the newly created carbon radical in the middle of the chain reacts with a monomer, it can have a branched polymer form, increasing the bonding force between molecules to form a coating film. The rigidity of the waterproofing material may be reinforced.
상기 개시제는 합성 고분자 중량 대비 8 내지 20wt% 사용될 수 있다.The initiator may be used in an amount of 8 to 20 wt% based on the weight of the synthetic polymer.
본 발명에 따른 고탄소성 아스팔트 도막 방수재 조성물은 가열 용융된 아스팔트에 EVA, SBS, LDPE 및 SIS를 혼입하여 용융시키는 단계 및 합성 고분자를 중합하여 상기 아스팔트 혼합물에 혼입하는 단계를 포함하여 제조된다. 상기 합성 고분자를 아스팔트 혼합물에 혼입할 때 충분한 혼합시간을 갖는 것이 좋다. The high-carbon asphalt coating film waterproofing composition according to the present invention is prepared by mixing and melting EVA, SBS, LDPE, and SIS into hot-melted asphalt, and polymerizing a synthetic polymer to incorporate it into the asphalt mixture. It is good to have a sufficient mixing time when incorporating the synthetic polymer into the asphalt mixture.
상기 합성 고분자를 중합하여 상기 아스팔트 혼합물에 혼입하는 단계는 더욱 구체적으로 제1 합성 고분자 및 제2 합성 고분자를 중합하여 상기 아스팔트 혼합물에 각각 혼입하며, 각각 100 내지 150분간 혼합시간을 갖거나 한꺼번에 투입 후 100 내지 150분간 혼합시간을 갖는 것이 좋다. In the step of polymerizing the synthetic polymer and incorporating it into the asphalt mixture, more specifically, the first synthetic polymer and the second synthetic polymer are polymerized and incorporated into the asphalt mixture, respectively, after having a mixing time of 100 to 150 minutes or adding them all at once It is good to have a mixing time of 100 to 150 minutes.
상기와 같이 제조된 도막 방수재 조성물을 가열 용융된 상태로 콘크리트 구조물 표면에 도포하고 상면에 부직포를 덮음으로써 건설기계 이동시 발생되는 타이어 손상으로부터 도막재를 보호할 수 있다. 또한, 물리적 부착성능이 우수하여 콘크리트 구조물 상에 도막 방수재 시공이 가능하다. The coating film waterproofing material composition prepared as described above can be applied to the surface of a concrete structure in a heated and melted state and covered with a non-woven fabric on the upper surface to protect the coating material from tire damage occurring during movement of construction machinery. In addition, it has excellent physical adhesion performance, so it is possible to construct a coating film waterproofing material on a concrete structure.
실시예Example
하기 표 1에 나타낸 것과 같은 조성으로 도막 방수재 조성물을 제조하였다. EVA는 VA 함량이 6~10 wt% 인 것을 사용하였고, SIS 는 스티렌 함량이 15~18 wt% 인 것을 사용하였고, 화합물 ①은 폴리부타디엔 30~40 wt% 및 폴리스티렌 60~70 wt% 포함하고, 화합물 ②는 폴리메틸메타크릴산 30~40 wt% 및 아크릴레이트 고무(ACM) 60~70wt% 포함한다. A coating film waterproofing composition was prepared with the same composition as shown in Table 1 below. EVA with a VA content of 6 to 10 wt% was used, SIS with a styrene content of 15 to 18 wt% was used, and compound ① contained 30 to 40 wt% of polybutadiene and 60 to 70 wt% of polystyrene, Compound ② includes 30 to 40 wt% of polymethyl methacrylic acid and 60 to 70 wt% of acrylate rubber (ACM).
180℃로 가열 용융된 아스팔트에 상기와 같은 함량으로 EVA, SBS, LDPE 및 SIS를 혼입하여 용융시키고, 개시제를 이용하여 화합물 ①, ②를 각각 중합한 후 상기 아스팔트 혼합물에 혼입 후 2시간 이상 혼합하였다. EVA, SBS, LDPE, and SIS were mixed and melted in the same amount as above in the asphalt heated and melted at 180 ° C, and the compounds ① and ② were respectively polymerized using an initiator, and then mixed with the asphalt mixture for 2 hours or more. .
실험예Experimental example
하기와 같은 물성을 측정하기 위하여 상기 제조된 도막 방수재 조성물을 이용하여 시험용 밑판 위에 방수재를 도포한 후 아스팔트 포장용 역청 혼합물 50mm 두께로 포설 다짐하여 168시간 표준양생 후 100*100mm의 상부 및 하부 인장용 지그를 접착제로 접착한 후 충분히 경화 시켜 인장 및 전단시험용 시편을 제작하였다. In order to measure the physical properties as described below, the waterproofing material was applied on the test base using the above-prepared coating film waterproofing composition, and then the bituminous mixture for asphalt paving was laid and compacted to a thickness of 50mm, and after standard curing for 168 hours, 100*100mm upper and lower tension jigs were bonded with an adhesive and sufficiently cured to prepare specimens for tensile and shear tests.
제조된 도막 방수재에 대하여 도막 방수재에 요구되는 성능(인장성능, 전단접착성능, 인장접착강도, 내투수성, 내열치수 안정성)에 대한 평가를 실시하였고, 그 결과를 하기 표 2에 나타내었다. For the manufactured coating film waterproofing material, the performance required for the coating film waterproofing material (tensile performance, shear adhesion performance, tensile adhesion strength, water permeability resistance, heat resistance dimensional stability) was evaluated, and the results are shown in Table 2 below.
(N/㎟)tensile strength
(N/㎟)
(%)elongation
(%)
강도(N/㎟)Shear bonding
Strength (N/㎟)
변형률(%)Shear bonding
Strain (%)
상기 표 2에 나타나는 것과 같이, 비교예의 경우 아스팔트의 기본적 성능으로 인해 인장강도 및 신장률에 대한 기준은 만족할 수 있지만 접착강도가 기준을 겨우 상회하거나 미달하였다. 하지만 본 특허의 제조방법을 적용시에는 실시예1, 실시예2와 같이 인장성능을 충분히 만족하면서도 방수재에 필요한 접착성능을 기준치 이상 만족하도록 조절이 가능하다.As shown in Table 2, in the comparative example, the criteria for tensile strength and elongation could be satisfied due to the basic performance of asphalt, but the adhesive strength barely exceeded or fell short of the criteria. However, when the manufacturing method of this patent is applied, it is possible to adjust the adhesive performance required for the waterproofing material to satisfy the standard value or more while sufficiently satisfying the tensile performance as in Examples 1 and 2.
전술한 각 실시예에서 예시된 특징, 구조, 효과 등은 실시예들이 속하는 분야의 통상의 지식을 가지는 자에 의하여 다른 실시예들에 대해서도 조합 또는 변형되어 실시 가능하다. 따라서 이러한 조합과 변형에 관계된 내용들은 본 발명의 범위에 포함되는 것으로 해석되어야 할 것이다.The features, structures, effects, etc. illustrated in each of the above-described embodiments can be combined or modified with respect to other embodiments by those skilled in the art in the field to which the embodiments belong. Therefore, contents related to these combinations and variations should be construed as being included in the scope of the present invention.
Claims (8)
상기 합성 고분자는 폴리부타디엔 30~40 wt% 및 폴리스티렌 60~70 wt%를 합성한 제1 합성 고분자와 폴리메틸메타크릴산 30~40 wt% 및 아크릴레이트 고무 60~70 wt%를 합성한 제2 합성 고분자를 포함하고,
상기 조성물 전체 중량에 대해 상기 아스팔트는 78.5 내지 95.7 wt%, 상기 EVA는 0.5 내지 2.5 wt%, 상기 SBS는 0.5 내지 2.5 wt%, 상기 LDPE는 1.5 내지 4.5 wt%, 상기 SIS는 1.5 내지 4.5 wt%, 상기 제1 합성 고분자는 0.1 내지 3 wt%, 상기 제2 합성 고분자는 0.1 내지 4 wt% 포함하는 아스팔트 도막 방수재 조성물.
Including asphalt, EVA (Ethylene-Vinyl Acetate), SBS (Styrene Butadiene Styrene), LDPE (Low-density polyethylene), SIS (Styrene Isoprene Styrene) and synthetic polymers,
The synthetic polymer is a first synthetic polymer synthesized from 30 to 40 wt% of polybutadiene and 60 to 70 wt% of polystyrene, and a second synthetic polymer synthesized from 30 to 40 wt% of polymethyl methacrylic acid and 60 to 70 wt% of acrylate rubber. Including synthetic polymers,
78.5 to 95.7 wt% of the asphalt, 0.5 to 2.5 wt% of the EVA, 0.5 to 2.5 wt% of the SBS, 1.5 to 4.5 wt% of the LDPE, and 1.5 to 4.5 wt% of the SIS based on the total weight of the composition , The asphalt coating film waterproofing composition comprising 0.1 to 3 wt% of the first synthetic polymer and 0.1 to 4 wt% of the second synthetic polymer.
상기 합성 고분자는 AIBN(Azo-bisisobutyronitrile; 아조비스이소부티로니트릴) 또는 BPO(Benzoyl peroxide; 벤조일퍼옥사이드)를 포함하는 개시제를 사용하여 합성된 것을 특징으로 하는 아스팔트 도막 방수재 조성물.
According to claim 1,
The synthetic polymer is an asphalt coating film waterproofing composition, characterized in that synthesized using an initiator containing AIBN (Azo-bisisobutyronitrile; azobisisobutyronitrile) or BPO (Benzoyl peroxide; benzoyl peroxide).
폴리부타디엔 30~40 wt% 및 폴리스티렌 60~70 wt%을 합성한 제1 합성 고분자와 폴리메틸메타크릴산 30~40 wt% 및 아크릴레이트 고무 60~70 wt%를 합성한 제2 합성 고분자를 중합하여 상기 아스팔트 혼합물에 각각 혼입하는 단계;를 포함하고,
상기 혼입 비율은 조성물 전체 중량에 대해 상기 아스팔트는 78.5 내지 95.7 wt%, 상기 EVA는 0.5 내지 2.5 wt%, 상기 SBS는 0.5 내지 2.5 wt%, 상기 LDPE는 1.5 내지 4.5 wt%, 상기 SIS는 1.5 내지 4.5 wt%, 상기 제1 합성 고분자는 0.1 내지 3 wt%, 상기 제2 합성 고분자는 0.1 내지 4 wt% 인 것을 특징으로 하는 아스팔트 도막 방수재 조성물의 제조방법.
mixing and melting EVA (Ethylene-Vinyl Acetate), SBS (Styrene Butadiene Styrene), LDPE (Low-density polyethylene), and SIS (Styrene Isoprene Styrene) into the hot-molten asphalt; and
A first synthetic polymer synthesized from 30 to 40 wt% of polybutadiene and 60 to 70 wt% of polystyrene and a second synthetic polymer composed of 30 to 40 wt% of polymethyl methacrylic acid and 60 to 70 wt% of acrylate rubber are polymerized. And incorporating each into the asphalt mixture;
The mixing ratio is 78.5 to 95.7 wt% of the asphalt, 0.5 to 2.5 wt% of the EVA, 0.5 to 2.5 wt% of the SBS, 1.5 to 4.5 wt% of the LDPE, and 1.5 to 2.5 wt% of the SIS, based on the total weight of the composition. 4.5 wt%, the first synthetic polymer is 0.1 to 3 wt%, the second synthetic polymer is a method for producing an asphalt coating film waterproofing composition, characterized in that 0.1 to 4 wt%.
An asphalt coating film waterproofing material formed by including the composition according to claim 1 or 5.
Priority Applications (1)
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| KR20060128833A (en) * | 2003-09-10 | 2006-12-14 | 사토머 테크놀로지 컴퍼니, 인코포레이티드 | Polybutadiene (meth) acrylate composition and method |
| JP2010174229A (en) * | 2009-02-02 | 2010-08-12 | Emulsion Technology Co Ltd | Modified asphalt composition, hardened film using the same, and waterproofing method |
| KR101776893B1 (en) * | 2017-02-20 | 2017-09-08 | 주식회사 라온건설기술 | A Eco-friendly Waterproofing Treatment Composition for Road and Waterproofing Methods using Thereof |
| KR101893794B1 (en) * | 2018-05-08 | 2018-08-31 | 주식회사 지케이기술연구소 | Waterproof Asphalt Concrete Composition Comprising LDPE and SIS and Constructing Methods Using Thereof |
| KR102170361B1 (en) * | 2020-06-26 | 2020-10-28 | (주)씨제이건설기술 | super elasto-plasticity asphalt concrete composition and construction method of using the same |
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| KR20060128833A (en) * | 2003-09-10 | 2006-12-14 | 사토머 테크놀로지 컴퍼니, 인코포레이티드 | Polybutadiene (meth) acrylate composition and method |
| JP2010174229A (en) * | 2009-02-02 | 2010-08-12 | Emulsion Technology Co Ltd | Modified asphalt composition, hardened film using the same, and waterproofing method |
| KR101776893B1 (en) * | 2017-02-20 | 2017-09-08 | 주식회사 라온건설기술 | A Eco-friendly Waterproofing Treatment Composition for Road and Waterproofing Methods using Thereof |
| KR101893794B1 (en) * | 2018-05-08 | 2018-08-31 | 주식회사 지케이기술연구소 | Waterproof Asphalt Concrete Composition Comprising LDPE and SIS and Constructing Methods Using Thereof |
| KR102170361B1 (en) * | 2020-06-26 | 2020-10-28 | (주)씨제이건설기술 | super elasto-plasticity asphalt concrete composition and construction method of using the same |
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