KR102387616B1 - Pest repelling composition, and pest repelling method - Google Patents

Pest repelling composition, and pest repelling method Download PDF

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KR102387616B1
KR102387616B1 KR1020187026884A KR20187026884A KR102387616B1 KR 102387616 B1 KR102387616 B1 KR 102387616B1 KR 1020187026884 A KR1020187026884 A KR 1020187026884A KR 20187026884 A KR20187026884 A KR 20187026884A KR 102387616 B1 KR102387616 B1 KR 102387616B1
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pest repelling
preferable
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composition
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KR20190029503A (en
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쇼코 나카지마
코우헤이 마츠모토
타츠야 카메자와
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렉크 가부시키가이샤
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01M—CATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
    • A01M29/00—Scaring or repelling devices, e.g. bird-scaring apparatus
    • A01M29/12—Scaring or repelling devices, e.g. bird-scaring apparatus using odoriferous substances, e.g. aromas, pheromones or chemical agents
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
    • A01N25/10—Macromolecular compounds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/24—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing ingredients to enhance the sticking of the active ingredients
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
    • A01N31/08—Oxygen or sulfur directly attached to an aromatic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/02—Amines; Quaternary ammonium compounds
    • A01N33/12—Quaternary ammonium compounds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/16—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof the nitrogen atom being part of a heterocyclic ring

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Abstract

(A)성분과, (B)성분, (C)성분, 및 (D)성분으로 이루어지는 군에서 선택되는 적어도 1종의 성분을 포함하는 해충 기피 조성물로서, 상기 (A)성분이 기피 유효 성분이고, 상기 (B)성분이 항산화 성분이고, 상기 (C)성분이 킬레이트제이고, 상기 (D)성분이 폴리비닐피롤리돈, 및 아세트산비닐·비닐피롤리돈 공중합체로 이루어지는 군에서 선택되는 적어도 1종의 고분자 화합물인, 해충 기피 조성물.A pest repelling composition comprising (A) component, and at least one component selected from the group consisting of (B) component, (C) component, and (D) component, wherein the (A) component is a repelling active ingredient , the component (B) is an antioxidant component, the component (C) is a chelating agent, and the component (D) is at least selected from the group consisting of polyvinylpyrrolidone and vinyl acetate/vinylpyrrolidone copolymer. A pest repelling composition, which is one type of high molecular compound.

Description

해충 기피 조성물, 및 해충 기피 방법Pest repelling composition, and pest repelling method

본 발명은, 해충 기피(忌避) 조성물, 및 해충 기피 방법에 관한 것이다.The present invention relates to a pest repelling composition and a pest repelling method.

본원은, 2016년 7월 15일에, 일본에 출원된 특원2016-140794호에 의거하여 우선권을 주장하고, 그 내용을 여기에 원용한다.This application claims priority based on Japanese Patent Application No. 2016-140794 for which it applied to Japan on July 15, 2016, The content is used here.

종래, 모기(蚊) 등의 해충에 대한 기피제를 피부에 적용함으로써, 해충을 기피하는 것이 행하여지고 있다.Conventionally, it has been practiced to avoid pests by applying a repellent against pests such as mosquitoes to the skin.

특허 문헌 1에는, 항균성 화합물, 기피 유효 성분을 포함하는 해충 기피 조성물에 관해 제안되어 있다. 특허 문헌 1에 기재된 발명에 의하면, 항균성 화합물에 의해 기피 유효 성분의 기피 효력의 증강이 도모되어 있다.Patent Document 1 proposes a pest repelling composition comprising an antibacterial compound and an effective repelling ingredient. According to the invention described in Patent Document 1, enhancement of the repelling effect of the repelling active ingredient is aimed at by the antimicrobial compound.

특허 문헌 1 : 특개2016-102092호 공보Patent Document 1: Japanese Patent Laid-Open No. 2016-102092

그렇지만, 2014년에 「뎅기열」이 발생하는 등, 국내에서 모기 매개성 감염증에의 감염 리스크가 높아지고 있어서, 해충 기피 조성물에는, 해충 기피 효과의 더한층의 향상이 요구되고 있다. 또한, 해충 기피 조성물을 사용하는 여름철에는, 발한 등에 의해 피부에 적용한 기피 조성물이 떨어지기 쉽고, 해충 기피 효과나 해충 기피 지속 효과가 충분하지가 않다.However, the risk of infection with mosquito-borne infectious diseases is increasing in the country, such as the occurrence of "dengue fever" in 2014, and further improvement of the insect repelling effect is required for pest repelling compositions. In addition, in summer when the pest repelling composition is used, the repellent composition applied to the skin due to sweating or the like is easily removed, and the pest repelling effect or the pest repelling lasting effect is not sufficient.

본 발명은, 해충 기피 효과에 우수한 해충 기피 조성물, 및 이것을 사용한 해충 기피 방법을 목적으로 한다.An object of the present invention is a pest repelling composition excellent in pest repelling effect, and a pest repelling method using the same.

본 발명은, 이하의 양태를 갖는다.The present invention has the following aspects.

[1] (A)성분과, (B)성분, (C)성분, 및 (D)성분으로 이루어지는 군에서 선택되는 적어도 1종의 성분을 포함하는 해충 기피 조성물로서,[1] A pest repelling composition comprising (A) component and at least one component selected from the group consisting of (B) component, (C) component, and (D) component,

상기 (A)성분이 기피 유효 성분이고,The component (A) is an active ingredient to avoid,

상기 (B)성분이 항산화(抗酸化) 성분이고,The component (B) is an antioxidant (抗酸化) component,

상기 (C)성분이 킬레이트제이고,The component (C) is a chelating agent,

상기 (D)성분이 폴리비닐피롤리돈, 및 아세트산비닐·비닐피롤리돈 공중합체로 이루어지는 군에서 선택되는 적어도 1종의 고분자 화합물인, 해충 기피 조성물.The pest repelling composition, wherein the component (D) is at least one polymer compound selected from the group consisting of polyvinylpyrrolidone and vinyl acetate/vinylpyrrolidone copolymer.

[2] 상기 (A)성분이 이카리딘인 [1]에 기재된 해충 기피 조성물.[2] The pest repelling composition according to [1], wherein the component (A) is icaridin.

[3] 상기 (B)성분, 및 상기 (C)성분을 포함하는 [1] 또는 [2]에 기재된 해충 기피 조성물.[3] The pest repelling composition according to [1] or [2], comprising the component (B) and the component (C).

[4] 상기 (B)성분, 상기 (C)성분, 및 상기 (D)성분을 포함하는 [1] 또는 [2]에 기재된 해충 기피 조성물.[4] The pest repelling composition according to [1] or [2], comprising the component (B), the component (C), and the component (D).

[5] 또한, (E)성분 : 항균성 화합물을 포함하는 [1]∼[4]의 어느 한 항에 기재된 해충 기피 조성물.[5] Furthermore, (E) component: The pest repelling composition in any one of [1]-[4] containing an antibacterial compound.

[6] [1]∼[5]의 어느 한 항에 기재된 해충 기피 조성물을 사용하는 것을 특징으로 하는 해충 기피 방법.[6] A method for repelling pests, comprising using the pest repelling composition according to any one of [1] to [5].

본 발명에 의하면, 해충 기피 효과에 우수한 해충 기피 조성물, 및 이것을 사용한 해충 기피 방법을 제공할 수 있다.ADVANTAGE OF THE INVENTION According to this invention, the pest repelling composition excellent in the pest repelling effect, and the pest repelling method using the same can be provided.

도 1은 실시례에서 사용한 연결 케이지의 사시도.1 is a perspective view of a connecting cage used in an embodiment;

≪해충 기피 조성물≫≪Pest repelling composition≫

본 발명의 해충 기피 조성물은, (A)성분과, (B)성분, (C)성분, 및 (D)성분으로 이루어지는 군에서 선택되는 적어도 1종의 성분을 포함한다.The pest repelling composition of this invention contains at least 1 sort(s) of component selected from the group which consists of (A) component, (B) component, (C)component, and (D)component.

[0009][0009]

<(A)성분 : 기피 유효 성분><(A) component: active ingredient to avoid>

(A)성분은, 해충의 기피 효과를 갖는 성분이다.(A) A component is a component which has the repelling effect of pests.

(A)성분으로서는, 특히 한정되지 않고, 예를 들면 이카리딘(1-메틸프로필2-(2-히드록시에틸)-1-피페리딘카르복실레이트), 디이이티(N,N-디에틸-3-메틸벤즈아미드), 3-(N-n-부틸-N-아세틸)아미노프로피온산에틸에스테르(IR3535), p-멘탄-3,8-디올, 레몬유칼리오일, 시트로넬라유 등을 들 수 있다. 이들 중에서도, 피부에 도포한 때의 스킨필성(性)이나 냄새의 점에서, 이카리딘이 바람직하다.(A) It does not specifically limit as a component, For example, Icaridine (1-methylpropyl 2-(2-hydroxyethyl)-1-piperidinecarboxylate), diethyl (N,N-diethyl) -3-methylbenzamide), 3-(N-n-butyl-N-acetyl)aminopropionic acid ethyl ester (IR3535), p-mentane-3,8-diol, lemon eucalyptus oil, and citronella oil. . Among these, Icaridine is preferable from the point of the skin-feeling property at the time of apply|coating to skin, and a smell.

(A)성분은, 1종 단독으로 사용되어도 좋고, 2종 이상이 조합되어 사용되어도 좋다.(A) A component may be used individually by 1 type, and 2 or more types may be combined and it may be used.

(A)성분의 함유량은, 해충 기피 조성물의 총질량에 대해 1∼80질량%가 바람직하고, 5∼30질량%가 더욱 바람직하다. 특히 이카리딘의 경우는 해충 기피 조성물의 총질량에 대해 1∼30질량%가 바람직하고, 5∼20질량%가 보다 바람직하다. 디이이티의 경우는 해충 기피 조성물의 총질량에 대해 5∼50질량%가 바람직하고, 10∼30질량%가 보다 바람직하다. (A)성분의 함유량이 상기 상한치 이하면, 끈적거림이 없고 사용감이 양호하다. 상기 하한치 이상이면, 기피 효과가 발휘되기 쉽다.(A) 1-80 mass % is preferable with respect to the gross mass of a pest repelling composition, and, as for content of component, 5-30 mass % is more preferable. In particular, in the case of icaridin, 1-30 mass % is preferable with respect to the total mass of a pest repelling composition, and 5-20 mass % is more preferable. In the case of DET, 5-50 mass % is preferable with respect to the total mass of a pest repelling composition, and 10-30 mass % is more preferable. (A) When content of a component is below the said upper limit, there will be no stickiness and a usability|use_condition is favorable. The repelling effect is easy to be exhibited as it is more than the said lower limit.

<(B)성분 : 항산화 성분><(B) component: antioxidant component>

(B)성분은, 항산화 작용이 있는 성분이고, 기피 효과를 증강한다.(B) A component is a component with an antioxidant action, and reinforces a repelling effect.

항산화 성분으로서는, 트레할로스, 크실리톨, 소르비톨, 말티톨, 크실로스, 만니톨 등의 당 또는 당알코올 ; 비타민A, 비타민 E, 비타민C 등의 비타민 및 그 유도체 ; 티로신, 트립토판, 메티오닌, 히스티딘 등의 아미노산 및 펩티드 등을 들 수 있다. 이들 중에서도, 트레할로스, 소르비톨, 말티톨이 바람직하다.Examples of the antioxidant component include sugars or sugar alcohols such as trehalose, xylitol, sorbitol, maltitol, xylose and mannitol; Vitamins, such as vitamin A, vitamin E, and vitamin C, and its derivative(s); and amino acids and peptides such as tyrosine, tryptophan, methionine and histidine. Among these, trehalose, sorbitol, and maltitol are preferable.

(B)성분은, 1종 단독으로 사용되어도 좋고, 2종 이상이 조합되어 사용되어도 좋다.(B) A component may be used individually by 1 type, and 2 or more types may be combined and used for it.

본 발명의 해충 기피 조성물이 (B)성분을 포함하는 경우, (B)성분의 함유량은, 해충 기피 조성물의 총질량에 대해 0.1∼10질량%가 바람직하고, 0.5∼5질량%가 보다 바람직하고, 1∼3질량%가 더욱 바람직하다. (B)성분의 함유량이 상기 상한치 이하면, 끈적거림이 없고 사용감이 양호하다. 상기 하한치 이상이면, (B)성분의 효과를 얻기 쉽다.When the pest repelling composition of the present invention contains component (B), the content of component (B) is preferably 0.1 to 10 mass%, more preferably 0.5 to 5 mass%, with respect to the total mass of the pest repelling composition, , more preferably 1-3 mass %. (B) When content of a component is below the said upper limit, there is no stickiness and a usability|use_condition is favorable. It is easy to acquire the effect of (B)component as it is more than the said lower limit.

본 발명의 해충 기피 조성물이 (B)성분을 포함하는 경우, (A)성분/(B)성분으로 표시되는 질량비(이하, A/B비라고도 한다)는, 0.1∼800이 바람직하고, 0.1∼100이 보다 바람직하고, 0.5∼30이 더욱 바람직하다. A/B비가 상기 범위 내라면, 기피 효과가 발휘되기 쉽다.When the pest repelling composition of this invention contains (B) component, 0.1-800 are preferable, as for the mass ratio (henceforth A/B ratio) represented by (A) component / (B) component, 0.1-800 100 is more preferable, and 0.5-30 are still more preferable. If A/B ratio is in the said range, the repelling effect will be exhibited easily.

<(C)성분 : 킬레이트제><(C) component: chelating agent>

(C)성분은, 키레이트 작용이 있는 성분이고, 기피 효과를 증강한다.(C) A component is a component with a chirate action, and reinforces a repelling effect.

(C)성분으로서는, 에틸렌디아민아세트산형(型) 킬레이트제, 유기산형 킬레이트제, 인산형 키레이트제가 바람직하다. 에틸렌디아민아세트산형 키레이트제로서는 에틸렌디아민아세트산 유도체 또는 그 염을 들 수 있다. 예를 들면, 에데트산(에틸렌디아민4아세트산, EDTA), 에틸렌디아민2아세트산(EDDA), 디에틸렌트리아민5아세트산(DTPA), N-(2-히드록시에틸)에틸렌디아민3아세트산(HEDTA) 등을 들 수 있고, 약리학적으로 또는 생리학적으로 허용되는 염(예를 들면, 에틸렌디아민4아세트산나트륨 등의 나트륨염, 칼륨염, 마그네슘염, 칼슘염 등)으로서 사용하여도 좋다. 그 중에서도, 에틸렌디아민4아세트산 또는 그 염이 바람직하고, 구체적으로는, 에틸렌디아민4아세트산2나트륨, 에틸렌디아민4아세트산2나트륨·2수화물(이하, 에데트산나트륨이라고도 한다.) 등을 들 수 있다. 유기산형 키레이트제로서는, 말레인산, 주석산, 구연산, 호박산, 글루콘산 등을 들 수 있고, 약리학적으로 또는 생리학적으로 허용되는 염으로서 사용하여도 좋다. 인산형 키레이트제로서는, 인산, 폴리인산나트륨, 메타인산 등을 들 수 있고, 약리학적으로 또는 생리학적으로 허용되는 염으로서 사용하여도 좋다. 그 중에서도 구연산, 구연산나트륨이 바람직하다.(C) As a component, an ethylenediamineacetic acid type chelating agent, an organic acid type chelating agent, and a phosphoric acid type chelating agent are preferable. Examples of the ethylenediamineacetic acid type chelating agent include an ethylenediamineacetic acid derivative or a salt thereof. For example, edetic acid (ethylenediaminetetraacetic acid, EDTA), ethylenediaminediacetic acid (EDDA), diethylenetriaminepentaacetic acid (DTPA), N-(2-hydroxyethyl)ethylenediaminetriacetic acid (HEDTA), etc. , and may be used as a pharmacologically or physiologically acceptable salt (eg, sodium salt, such as sodium ethylenediaminetetraacetate, potassium salt, magnesium salt, calcium salt, etc.). Among them, ethylenediaminetetraacetic acid or a salt thereof is preferable, and specific examples thereof include disodium ethylenediaminetetraacetic acid and disodium ethylenediaminetetraacetic acid dihydrate (hereinafter also referred to as sodium edetate). Examples of the organic acid-type chelating agent include maleic acid, tartaric acid, citric acid, succinic acid, and gluconic acid, and may be used as a pharmacologically or physiologically acceptable salt. Phosphoric acid, sodium polyphosphate, metaphosphoric acid, etc. are mentioned as a phosphoric acid type chelating agent, You may use as a pharmacologically or physiologically acceptable salt. Among them, citric acid and sodium citrate are preferable.

(C)성분은, 1종 단독으로 사용되어도 좋고, 2종 이상이 조합되어 사용되어도 좋다.(C) A component may be used individually by 1 type, and 2 or more types may be combined and used for it.

(C)성분이 대(對)이온(1나트륨염, 3나트륨염, 3칼륨염 등)의 염 또는 수화물(1수화물 등)이 되는 경우, 질량 변동이 커진다. 그때문에, 본원에서는, 중화(中和)되지 않은 「산」의 상태이면서, 「무수화물」로 환산(이하, 「산환산(酸換算)」이라고도 한다)한 함유량으로 기재한다.(C) When a component turns into the salt or hydrate (monohydrate etc.) of a counter ion (mono-sodium salt, trisodium salt, tripotassium salt, etc.), a mass fluctuation|variation becomes large. Therefore, in this application, it describes as content converted into "anhydride" (hereinafter also referred to as "acid conversion") while in the state of "acid" which is not neutralized.

본 발명의 해충 기피 조성물이 (C)성분을 포함하는 경우, (C)성분의 함유량은, 「산환산」하여, 해충 기피 조성물의 총질량에 대해 0.01∼3질량%가 바람직하고, 0.05∼2질량%가 보다 바람직하다. (C)성분의 함유량이 상기 상한치 이하면, (C)성분이 석출하거나 피부 자극이 생기는 것을 억제하기 쉽다. 상기 하한치 이상이면, (C)성분의 효과를 얻기 쉽다.When the pest repelling composition of this invention contains (C)component, as for content of (C)component, "acid conversion", 0.01-3 mass % is preferable with respect to the total mass of a pest repelling composition, 0.05-2 Mass % is more preferable. (C) It is easy to suppress that content of (C)component is below the said upper limit that (C)component precipitates or a skin irritation arises. It is easy to acquire the effect of (C)component as it is more than the said lower limit.

본 발명의 해충 기피 조성물이 구연산 또는 구연산나트륨을 포함하는 경우, 구연산 또는 구연산나트륨의 함유량은, 「산환산」하여, 해충 기피 조성물의 총질량에 대해 0.01∼3질량%가 바람직하고, 0.1∼2질량%가 보다 바람직하고, 0.2∼1질량%가 더욱 바람직하다. 구연산 또는 구연산나트륨의 함유량이 상기 상한치 이하면, 구연산 또는 구연산나트륨이 석출하거나, 피부 자극이 생기는 것을 억제할 수 있다. 상기 하한치 이상이면, 기피 효과가 발휘되기 쉽다.When the pest repelling composition of the present invention contains citric acid or sodium citrate, the content of citric acid or sodium citrate is "acid conversion", and is preferably 0.01 to 3 mass% with respect to the total mass of the pest repelling composition, 0.1 to 2 Mass % is more preferable, and 0.2-1 mass % is still more preferable. When content of citric acid or sodium citrate is below the said upper limit, it can suppress that citric acid or sodium citrate precipitates, or skin irritation arises. The repelling effect is easy to be exhibited as it is more than the said lower limit.

본 발명의 해충 기피 조성물이 EDTA 또는 그 염을 포함하는 경우, EDTA 또는 그 염의 함유량은, 「산환산」하여, 해충 기피 조성물의 총질량에 대해 0.03∼0.5질량%가 바람직하고, 0.05∼0.3질량%가 보다 바람직하다. EDTA 또는 그 염이 상기 상한치 이하면, EDTA 또는 그 염이 석출하거나, 피부 자극이 생기는 것을 억제할 수 있다. 상기 하한치 이상이면, 기피 효과가 증강되기 쉽다.When the pest repelling composition of the present invention contains EDTA or a salt thereof, the content of EDTA or a salt thereof is "acid conversion", and is preferably 0.03-0.5 mass % with respect to the total mass of the pest repelling composition, 0.05-0.3 mass % is more preferable. When EDTA or its salt is below the said upper limit, it can suppress that EDTA or its salt precipitates, or skin irritation arises. If it is more than the said lower limit, the repelling effect will be easy to reinforce|strengthen.

본 발명의 해충 기피 조성물이 (C)성분을 포함하는 경우, (C)성분을 「산환산」하여, (A)성분/(C)성분으로 표시되는 질량비(이하, A/C비라고도 한다)는, 0.1∼8000이 바람직하고, 1∼1000이 보다 바람직하고, 더욱이 5∼200이 바람직하다. A/C비가 상기 범위 내라면, 기피 효과가 발휘되기 쉽다.When the pest repelling composition of this invention contains (C)component, (C)component is "acid conversion", and mass ratio represented by (A)component/(C)component (hereinafter also referred to as A/C ratio) 0.1-8000 are preferable, 1-1000 are more preferable, and 5-200 are still more preferable. If the A/C ratio is within the above range, the repelling effect is likely to be exhibited.

본 발명의 해충 기피 조성물이 (B)성분, 및 (C)성분을 포함하는 경우, (C)성분을 「산환산」하여, (B)성분/(C)성분으로 표시되는 질량비(이하, B/C비라고도 한다)는, 0.01∼1000이 바람직하고, 0.1∼200이 보다 바람직하고, 더욱이 1∼50이 바람직하다. B/C비가 상기 범위 내라면, 기피 효과가 발휘되기 쉽다.When the insect pest repelling composition of this invention contains (B) component and (C)component, (C)component is "acid conversion", and mass ratio represented by (B)component/(C)component (hereinafter, B 0.01-1000 are preferable, as for /C ratio), 0.1-200 are more preferable, and 1-50 are still more preferable. If B/C ratio is in the said range, the repelling effect will be exhibited easily.

<(D)성분 : 폴리비닐피롤리돈, 및 아세트산비닐·비닐피롤리돈 공중합체로 이루어지는 군에서 선택되는 적어도 1종의 고분자 화합물><Component (D): at least one polymer compound selected from the group consisting of polyvinylpyrrolidone and vinyl acetate/vinylpyrrolidone copolymer>

(D)성분으로서는, 폴리비닐피롤리돈, 및 아세트산비닐·비닐피롤리돈 공중합체로 이루어지는 군에서 선택되는 적어도 1종의 고분자 화합물을 들 수 있다. (D)성분을 배합함으로써 기피 효과의 지속성을 향상시킬 수 있다.(D) As a component, the at least 1 sort(s) of polymer compound chosen from the group which consists of polyvinylpyrrolidone and a vinyl acetate-vinylpyrrolidone copolymer is mentioned. (D) Durability of a repelling effect can be improved by mix|blending a component.

폴리비닐피롤리돈으로서는, 중량평균분자량이 8,000∼3,000,000의 것을 사용할 수 있고, 특히 중량평균분자량 2,000,000 이하의 것이 용해성, 사용 감촉, 방취(防臭) 효과의 지속성의 점에서 바람직하다. 또한, 중량평균분자량은, 미국 약국방 USP에서 규정된 K값을 광산란법에 의해 측정된 중량평균분자량으로 환산한 것이다.As polyvinylpyrrolidone, those having a weight average molecular weight of 8,000 to 3,000,000 can be used, and those having a weight average molecular weight of 2,000,000 or less are particularly preferable from the viewpoints of solubility, use feeling, and durability of the deodorizing effect. In addition, the weight average molecular weight is a value obtained by converting the K value stipulated by the US Pharmacopeia to the weight average molecular weight measured by the light scattering method.

시판품으로는, 루비스콜 K17(중량평균분자량 : 약 9,000), 루비스콜 K30(중량평균분자량 : 약 45,000), 루비스콜 K90(중량평균분자량 : 약 1,600,000)(이상, BASF사제), PVPK-15(중량평균분자량 : 8,000), PVPK-30(중량평균분자량 : 60,000), PVPK-60(중량평균분자량 : 400,000), PVPK-90(중량평균분자량 : 1, 300,000), PVPK-120(중량평균분자량 : 3,000,000)(이상, ISP사제)로, 바람직하게는, 방취 효과의 지속성의 점에서, 루비스콜 K30(중량평균분자량 : 약 45,000), 루비스콜 K90(중량평균분자량 : 약 1,600,000)이다.As commercially available products, Rubischol K17 (weight average molecular weight: about 9,000), Rubischol K30 (weight average molecular weight: about 45,000), Rubischol K90 (weight average molecular weight: about 1,600,000) (above, manufactured by BASF), PVPK-15 ( Weight average molecular weight: 8,000), PVPK-30 (weight average molecular weight: 60,000), PVPK-60 (weight average molecular weight: 400,000), PVPK-90 (weight average molecular weight: 1, 300,000), PVPK-120 (weight average molecular weight: 3,000,000) (above, manufactured by ISP), preferably, Rubischol K30 (weight average molecular weight: about 45,000), Rubischol K90 (weight average molecular weight: about 1,600,000) in terms of durability of the deodorizing effect.

또한, 아세트산비닐·비닐피롤리돈 공중합체의 비닐피롤리돈과 아세트산비닐의 공중합 몰비(VP/VA)는 7/3∼3/7의 범위가 알맞다. 이들 중, 공중합 몰비(VP/VA)가 7/3 또는 6/4의 것이, 용해성, 사용 감촉, 방취 효과의 지속성의 점에서 바람직하다. 시판품으로는, PVP/VA S-630(VP/VA 몰비 6/4), PVP/VA E-735(VP/VA 몰비 7/3), PVP/VA E-535(VP/VA 몰비 5/5), PVP/VA E-335(VP/VA 몰비 3/7)(이상, ISP사제), 루비스콜 VA37E(VP/VA 몰비 3/7), 루비스콜 VA55I(VP/VA 몰비 5/5), 루비스콜 VA64P(VP/VA 몰비 6/4), 루비스콜 VA73W(VP/VA 몰비 7/3)(이상, BASF사제) 등을 들 수 있고, 그 중에서도, PVP/VA S-630, PVP/VA E-735가 바람직하다.In addition, the preferable copolymer molar ratio (VP/VA) of vinyl pyrrolidone and vinyl acetate in the vinyl acetate/vinylpyrrolidone copolymer is 7/3 to 3/7. Among these, those having a copolymerization molar ratio (VP/VA) of 7/3 or 6/4 are preferable from the viewpoints of solubility, use feeling, and durability of the deodorizing effect. As a commercial item, PVP/VA S-630 (VP/VA molar ratio 6/4), PVP/VA E-735 (VP/VA molar ratio 7/3), PVP/VA E-535 (VP/VA molar ratio 5/5) ), PVP/VA E-335 (VP/VA molar ratio 3/7) (above, manufactured by ISP), Rubischol VA37E (VP/VA molar ratio 3/7), Rubischol VA55I (VP/VA molar ratio 5/5), Rubiscall VA64P (VP/VA molar ratio 6/4), Rubiscol VA73W (VP/VA molar ratio 7/3) (above, manufactured by BASF) etc. are mentioned, Especially, PVP/VA S-630 and PVP/VA are mentioned. E-735 is preferred.

(D)성분은, 1종 단독으로 사용되어도 좋고, 2종 이상이 조합되어 사용되어도 좋다.(D) A component may be used individually by 1 type, and 2 or more types may be combined and used for it.

아세트산비닐·비닐피롤리돈 공중합체의 중량평균분자량은, 200∼80,000이 바람직하고, 40,000∼70,000이 보다 바람직하다. 또한, 중량평균분자량은, 미국 약국방 USP에서 규정된 K값을 광산란법에 의해 측정된 중량평균분자량으로 환산한 것이다.200-80,000 are preferable and, as for the weight average molecular weight of a vinyl acetate/vinylpyrrolidone copolymer, 40,000-70,000 are more preferable. In addition, the weight average molecular weight is a value obtained by converting the K value stipulated by the US Pharmacopeia to the weight average molecular weight measured by the light scattering method.

본 발명의 해충 기피 조성물이 (D)성분을 포함하는 경우, (D)성분의 함유량은, 해충 기피 조성물의 총질량에 대해 0.1∼3질량%가 바람직하고, 0.2∼1질량%가 보다 바람직하다.When the pest repelling composition of this invention contains (D) component, 0.1-3 mass % is preferable with respect to the gross mass of the pest repelling composition, and, as for content of (D) component, 0.2-1 mass % is more preferable .

(D)성분의 함유량이 상기 범위 내라면, 기피 효과의 지속성이 높고, 끈적거림이 없고 사용감이 양호하다.(D) When content of a component is in the said range, the durability of a repelling effect is high, there is no stickiness, and a usability|use_condition is favorable.

본 발명의 해충 기피 조성물이 (D)성분을 포함하는 경우, (A)성분/(D)성분으로 표시되는 질량비(이하, A/D비라고도 한다)는, 0.1∼800이 바람직하고, 1∼200이 보다 바람직하고, 5∼50이 더욱 바람직하다. A/D비가 상기 범위 내라면, 기피 효과가 발휘되기 쉽다.When the pest repelling composition of this invention contains (D)component, 0.1-800 are preferable, as for the mass ratio (henceforth A/D ratio) represented by (A) component/(D)component, 1-800 200 is more preferable, and 5-50 are still more preferable. If the A/D ratio is within the above range, the repelling effect is likely to be exhibited.

본 발명의 해충 기피 조성물이 (B)성분, 및 (D)성분을 포함하는 경우, (B)성분/(D)성분으로 표시되는 질량비(이하, B/D비라고도 한다)는, 0.01∼200이 바람직하고, 1∼100이 보다 바람직하고, 1∼30이 더욱 바람직하다. B/D비가 상기 범위 내라면, 기피 효과가 발휘되기 쉽다.When the pest repelling composition of this invention contains (B) component and (D) component, the mass ratio (henceforth B/D ratio) represented by (B) component/(D)component is 0.01-200 This is preferable, 1-100 are more preferable, and 1-30 are still more preferable. If B/D ratio is in the said range, the repelling effect will be exhibited easily.

본 발명의 해충 기피 조성물이 (C)성분, 및 (D)성분을 포함하는 경우, (C)성분을 「산환산」하여, (C)성분/(D)성분으로 표시되는 질량비(이하, C/D비라고도 한다)는, 0.001∼50이 바람직하고, 0.005∼30이 보다 바람직하고, 0.1∼10이 더욱 바람직하다. C/D비가 상기 범위 내라면, 기피 효과가 발휘되기 쉽다.When the pest repelling composition of this invention contains (C)component and (D)component, (C)component is "acid conversion", and mass ratio represented by (C)component/(D)component (hereinafter, C) 0.001-50 are preferable, as for /D ratio), 0.005-30 are more preferable, 0.1-10 are still more preferable. When the C/D ratio is within the above range, the repelling effect is likely to be exhibited.

<다른 성분><Other ingredients>

(A)∼(D)성분을 제외한, 다른 성분으로서는, 예를 들면, 항균성 화합물(이하, (E)성분이라고도 한다), 계면활성제(이하, (F)성분이라고도 한다), 용제, 보습제, 증점제, 색소, pH 조정제, 향료, 자외선 흡수제, 자외선 산란제 등의 첨가제 등을 들 수 있다.As other components except (A)-(D) component, for example, an antimicrobial compound (henceforth (E) component), surfactant (henceforth (F) component), a solvent, a moisturizing agent, a thickener Additives, such as a pigment|dye, a pH adjuster, a fragrance|flavor, a ultraviolet absorber, and a ultraviolet scattering agent, etc. are mentioned.

(E)성분으로서는, 페놀계 항균 성분, 4급암모늄염계의 항균 성분, 비구아나이드계 항균 성분, 유기질소유황계 항균 성분, 등 각종의 화합물을 들 수 있다. 페놀계 항균 성분으로서는, 이소프로필메틸페놀(3-메틸-4-이소프로 페놀), 오르토-페닐페놀 등을 들 수 있다. 4급암모늄염계 항균 성분으로서는 벤잘코늄염화물, 염화벤제토늄 등을 들 수 있다. 비구아나이드계 항균 성분으로서는 염산클로로헥시딘, 폴리헥사메틸렌렌비구아니드염산염 등을 들 수 있다. 유기질소유황계 항균 성분으로서는 5-클로로-2-메틸-4-이소티아졸린-3-온, 2-메틸-4-이소티아졸린-3-온, 2-메르캅토벤조티아졸, 2-n-옥틸-4-이소티아졸린-3-온, 1,2-벤조이소티아졸린-3-온 등을 들 수 있다. 그 밖의 (E)성분으로서는, 트리클로산, 디클로산, 2-브로모-2-니트로프로판-1,3-디올, 리클로로카르바닐리드, 피록톤올라민, 혀초 엑기스 등을 들 수 있다.(E) As a component, various compounds, such as a phenol type antibacterial component, a quaternary ammonium salt type antibacterial component, a biguanide type antibacterial component, an organic nitrogen sulfur type antibacterial component, are mentioned. Examples of the phenolic antibacterial component include isopropylmethylphenol (3-methyl-4-isopropphenol) and ortho-phenylphenol. Benzalkonium chloride, benzethonium chloride, etc. are mentioned as a quaternary ammonium salt type antibacterial component. Examples of the biguanide-based antibacterial component include chlorhexidine hydrochloride and polyhexamethylenebiguanide hydrochloride. As the organic nitrogen-sulfur antibacterial component, 5-chloro-2-methyl-4-isothiazolin-3-one, 2-methyl-4-isothiazolin-3-one, 2-mercaptobenzothiazole, 2-n- Octyl-4-isothiazolin-3-one, 1,2-benzoisothiazolin-3-one, etc. are mentioned. As another component (E), triclosan, diclosan, 2-bromo-2-nitropropane-1,3-diol, rechlorocarbanilide, piroctonolamine, tongue vinegar extract, etc. are mentioned.

이들 중에서 페놀계 항균 성분, 4급암모늄염계 항균 성분이 바람직하고, 이소프로필메틸페놀, 벤잘코늄염화물이 보다 바람직하다.Among these, a phenol type antibacterial component and a quaternary ammonium salt type antibacterial component are preferable, and isopropylmethylphenol and benzalkonium chloride are more preferable.

항균성 화합물은, 1종 단독으로 사용되어도 좋고, 2종 이상이 조합되어 사용되어도 좋고, 페놀계 항균 성분과 4급암모늄염계 항균 성분을 병용하는 것이 바람직하고, 이소프로필메틸페놀과 벤잘코늄염화물을 병용하는 것이 보다 바람직하다.Antibacterial compound may be used individually by 1 type, or 2 or more types may be used in combination, It is preferable to use a phenol type antibacterial component and a quaternary ammonium salt type antibacterial component together, and isopropylmethylphenol and benzalkonium chloride are used together It is more preferable to

본 발명의 해충 기피 조성물이 (E)성분을 포함하는 경우, (E)성분의 함유량은, 해충 기피 조성물의 총질량에 대해 0.001∼1질량%가 바람직하고, 0.01∼0.5질량%가 보다 바람직하다. (E)성분의 함유량이 상기 범위 내라면, 기피 효과가 발휘되기 쉽다.When the pest repelling composition of this invention contains (E) component, 0.001-1 mass % is preferable with respect to the total mass of the pest repelling composition, and, as for content of (E) component, 0.01-0.5 mass % is more preferable . (E) If content of a component is in the said range, a repelling effect will be exhibited easily.

본 발명의 해충 기피 조성물이 (B)성분, 및 (E)성분을 포함하는 경우, (B)성분/(E)성분으로 표시되는 질량비(이하, B/E비라고도 한다)는, 0.01∼1000이 바람직하고, 1∼500이 보다 바람직하고, 더욱이 5∼200이 바람직하다. B/E비가 상기 범위 내라면, 기피 효과가 발휘되기 쉽다.When the pest repelling composition of this invention contains (B) component and (E) component, the mass ratio (henceforth B/E ratio) represented by (B) component / (E) component is 0.01-1000 This is preferable, 1-500 are more preferable, and 5-200 are still more preferable. If B/E ratio is in the said range, the repelling effect will be exhibited easily.

본 발명의 해충 기피 조성물이 (C)성분, 및 (E)성분을 포함하는 경우, (C)성분을 「산환산」하여, (C)성분/(E)성분으로 표시되는 질량비(이하, C/E비라고도 한다)는, 0.005∼300이 바람직하고, 0.1∼100이 바람직하다. C/E비가 상기 범위 내라면, 기피 효과가 발휘되기 쉽다.When the pest repelling composition of this invention contains (C)component and (E)component, (C)component is "acid conversion", and mass ratio represented by (C)component/(E)component (hereinafter, C) 0.005-300 are preferable and, as for /E ratio), 0.1-100 are preferable. If C/E ratio is in the said range, the repelling effect will be exhibited easily.

본 발명의 해충 기피 조성물이 (D)성분, 및 (E)성분을 포함하는 경우, (D)성분/(E)성분으로 표시되는 질량비(이하, D/E비라고도 한다)는, 0.05∼100이 바람직하고, 0.5∼10이 바람직하다. D/E비가 상기 범위 내라면, 기피 효과가 발휘되기 쉽다.When the pest repelling composition of this invention contains (D)component and (E)component, the mass ratio (henceforth D/E ratio) represented by (D)component/(E)component is 0.05-100 This is preferable, and 0.5-10 are preferable. If D/E ratio is in the said range, the repelling effect will be exhibited easily.

(F)성분으로서는, 아니온 계면활성제, 비이온 계면활성제, 양성 계면활성제가 사용될 수 있다. 아니온 계면활성제로서는, 예를 들면 지방산 비누, 알킬벤젠술폰산염, 직쇄알킬벤젠술폰산염, 알킬황산염, 알파올레핀술폰산염, 알킬인산에스테르염, 폴리옥시에틸렌알킬에테르황산염, 폴리옥시에틸렌알킬에테르카르본산염, 폴리옥시에틸렌알킬페닐에테르황산염, 폴리옥시에틸렌알킬에테르인산염, 알킬술포호박산염, 폴리옥시에틸렌알킬술포호박산염 등을 들 수 있다. 비이온 계면활성제로서는, 예를 들면 폴리옥시알킬렌알킬에테르, 폴리옥시에틸렌알킬페닐에테르, 폴리옥시에틸렌고급지방산에스테르, 폴리옥시에틸렌소르비탄지방산에스테르, 폴리옥시에틸렌글리세린지방산에스테르, 폴리옥시에틸렌경화피마자유, 야자유지방산디에탄올아미드, 지방산알카놀아미드, 아민옥시드 등을 들 수 있다. 양성 계면활성제로서는 알킬카르보베타인, 알킬아미드카르보베타인, 알킬술포베타인, 알킬히드록시술포베타인, 알킬아미드술포베타인, 알킬아미드히드록시술포베타인 등을 들 수 있다.(F) As a component, an anionic surfactant, a nonionic surfactant, and an amphoteric surfactant can be used. Examples of the anionic surfactant include fatty acid soap, alkylbenzenesulfonate, linear alkylbenzenesulfonate, alkylsulfate, alphaolefinsulfonate, alkylphosphate ester salt, polyoxyethylenealkylethersulfate, polyoxyethylenealkylethercarbonate acid salts, polyoxyethylene alkylphenyl ether sulfates, polyoxyethylene alkyl ether phosphates, alkyl sulfosuccinates, polyoxyethylene alkyl sulfosuccinates, and the like. Examples of the nonionic surfactant include polyoxyalkylene alkyl ether, polyoxyethylene alkylphenyl ether, polyoxyethylene higher fatty acid ester, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene glycerin fatty acid ester, polyoxyethylene hydrogenated castor. and oil, palm oil fatty acid diethanolamide, fatty acid alkanolamide, and amine oxide. Examples of the amphoteric surfactant include alkylcarbobetaine, alkylamidecarbobetaine, alkylsulfobetaine, alkylhydroxysulfobetaine, alkylamidesulfobetaine, and alkylamidehydroxysulfobetaine.

피부에의 자극성, 저온에 둘 수 있는 안정성 향상의 관점에서 비이온 계면활성제가 바람직하고, 폴리옥시에틸렌경화피마자유가 보다 바람직하다. 비이온 계면활성제의 옥시에틸렌기는 저온에서의 안정성의 관점에서 평균 10∼100몰 부가품이 바람직하다.A nonionic surfactant is preferable from a viewpoint of irritation|stimulation to skin and stability improvement which can be put at low temperature, and polyoxyethylene hydrogenated castor oil is more preferable. The oxyethylene group of the nonionic surfactant is preferably 10 to 100 moles on average from the viewpoint of stability at low temperature.

(F)성분은, 1종 단독으로 사용되어도 좋고, 2종 이상이 조합되어 사용되어도 좋다.(F) A component may be used individually by 1 type, and 2 or more types may be combined and used for it.

본 발명의 해충 기피 조성물이 (F)성분을 포함하는 경우, (F)성분의 함유량은, 해충 기피 조성물의 총질량에 대해 0.1∼10질량%가 바람직하고, 0.1∼5질량%가 더욱 바람직하다. (F)성분의 함유량이 상기 범위 내라면 (F)성분에 의한 끈적거림을 억제하고, 저온에서의 안정성을 향상한다.When the pest repelling composition of this invention contains (F) component, 0.1-10 mass % is preferable with respect to the total mass of the pest repelling composition, and, as for content of (F) component, 0.1-5 mass % is more preferable . (F) If content of component is in the said range, the stickiness by (F) component will be suppressed and stability in low temperature will be improved.

용제로서는, 에탄올 등의 알코올계 용제, n-파라핀, 이소파라핀 등의 탄화수소계 용제, 프로필렌글리콜, 1,3-부틸렌글리콜, 디프로필렌글리콜, 디에틸렌글리콜모노부틸에테르 등의 글리콜류나 글리콜에테르류, 케톤계 용제, 에스테르계 용제, 물(水) 등을 배합할 수 있다.Examples of the solvent include alcohol solvents such as ethanol, hydrocarbon solvents such as n-paraffin and isoparaffin, glycols such as propylene glycol, 1,3-butylene glycol, dipropylene glycol, and diethylene glycol monobutyl ether, and glycol ethers , ketone-based solvents, ester-based solvents, water, and the like can be blended.

용제는, 1종 단독으로 사용되어도 좋고, 2종 이상이 조합되어 사용되어도 좋다.A solvent may be used individually by 1 type, and 2 or more types may be combined and used for it.

피부에의 자극성이나 냄새, 사용감(마르기 쉬움) 및 기피 효과의 관점에서 에탄올이 바람직하다.Ethanol is preferable from the viewpoint of irritation to the skin, odor, feeling of use (easy to dry), and repellent effect.

본 발명의 해충 기피 조성물이 에탄올을 포함하는 경우, 에탄올의 함유량은, 해충 기피 조성물의 총질량에 대해 0∼90질량%가 바람직하고, 30∼50질량%가, 사용 감촉(마르기 쉬움), 피부 자극성의 점에서 보다 바람직하다. 에탄올의 함유량이 상기 범위 내라면, 기피 효과가 발휘되기 쉽다.When the pest repelling composition of the present invention contains ethanol, the content of ethanol is preferably 0 to 90% by mass, and 30 to 50% by mass relative to the total mass of the pest repelling composition, the feeling of use (easy to dry), skin It is more preferable from the point of stimulation. If the content of ethanol is within the above range, the repelling effect is likely to be exhibited.

본 발명의 해충 기피 조성물에는 알맞은 물을 배합할 수 있다.Suitable water can be blended with the pest repelling composition of the present invention.

증점제((D)성분을 제외한다)로서는, 화장품·의약 부외품·의약품에 사용되는 것이면 특히 한정되지 않고, 천연의 수용성 고분자, 반합성(半合成)의 수용성 고분자, 합성의 수용성 고분자, 무기의 수용성 고분자 등을 들 수 있다. 천연의 수용성 고분자로서는, 예를 들면 아라비아고무, 트라간트고무, 갈락탄, 구아고무, 크산탄고무, 캐로브고무, 로커스트빈고무, 카라야고무, 카라기난, 펙틴, 한천, 퀸스시드, 앨지 콜로이드, 전분 등의 식물계 고분자, 덱스트란, 덱스트린, 숙시노글루칸, 플루란 등의 미생물계 고분자, 콜라겐, 카세인, 알부민, 젤라틴 등의 동물계 고분자 등을 들 수 있다. 반합성의 수용성 고분자로서는, 예를 들면 카복시메틸전분, 메틸히드록시프로필전분 등의 전분계 고분자, 메틸셀룰로스, 니트로셀루로스, 에틸셀룰로스, 메틸히드록시프로필셀룰로스, 히드록시에틸셀룰로스, 셀룰로스황산나트륨, 히드록시프로필셀룰로스, 카복시메틸셀룰로스나트륨(CMC), 결정(結晶)셀룰로스, 셀룰로스말(末) 등의 셀룰로스계 고분자, 알긴산나트륨, 알긴산프로필렌글리콜에스테르 등의 알긴산계 고분자 등을 들 수 있다. 합성의 수용성 고분자로서는, 예를 들면 폴리비닐알코올, 폴리비닐메틸에테르, 카르복시비닐폴리머(카르보머) 등의 비닐계 고분자, 폴리에틸렌글리콜(분자량 1500, 4000, 6000 등) 등의 폴리옥시에틸렌계 고분자, 폴리옥시에틸렌폴리옥시프로필렌 공중합계 고분자, 폴리아크릴산나트륨, 폴리에틸아크릴레이트 등의 아크릴계 고분자, 폴리에틸렌이민, 카티온 폴리머 등을 들 수 있다. 무기의 수용성 고분자로서는, 예를 들면 벤토나이트, 규산AlMg, 라포나이트, 헥트라이트, 무수규산 등을 들 수 있다.The thickener (excluding component (D)) is not particularly limited as long as it is used in cosmetics, quasi-drugs, and pharmaceuticals. Natural water-soluble polymers, semi-synthetic water-soluble polymers, synthetic water-soluble polymers, and inorganic water-soluble polymers and the like. Natural water-soluble polymers include, for example, gum arabic, gum traganth, galactan, guar gum, xanthan gum, carob gum, locust bean gum, karaya gum, carrageenan, pectin, agar, queen's seed, algae colloid, and plant-based polymers such as starch, microbial polymers such as dextran, dextrin, succinoglucan, and fullulan, and animal-based polymers such as collagen, casein, albumin, and gelatin. Examples of the semi-synthetic water-soluble polymer include starch-based polymers such as carboxymethyl starch and methyl hydroxypropyl starch, methyl cellulose, nitrocellulose, ethyl cellulose, methyl hydroxypropyl cellulose, hydroxyethyl cellulose, sodium cellulose sulfate, hydroxy and cellulose-based polymers such as propyl cellulose, sodium carboxymethyl cellulose (CMC), crystalline cellulose, and cellulose powder, and alginic acid-based polymers such as sodium alginate and propylene glycol alginate. Examples of the synthetic water-soluble polymer include vinyl polymers such as polyvinyl alcohol, polyvinyl methyl ether, and carboxyvinyl polymer (carbomer), polyoxyethylene polymers such as polyethylene glycol (molecular weights 1500, 4000, 6000, etc.); Polyoxyethylene polyoxypropylene copolymer-type polymer|macromolecule, acryl-type polymer|macromolecule, such as sodium polyacrylate and polyethyl acrylate, polyethyleneimine, a cationic polymer, etc. are mentioned. Examples of the inorganic water-soluble polymer include bentonite, AlMg silicate, laponite, hectrite, and silicic anhydride.

증점제는, 1종 단독으로 사용되어도 좋고, 2종 이상이 조합되어 사용되어도 좋다.A thickener may be used individually by 1 type, and may be used in combination of 2 or more type.

향료로서는, 페퍼민트유, 스피어민트유, 아니스유, 유칼리유, 윈터그린유, 카시아유, 쿠로부유, 타임유, 샐비어유, 레몬유, 오렌지유, 박하유, 카르다몬유, 코리안더유, 만다린유, 라임유, 라벤더유, 로즈마리유, 로렐유, 카모밀유, 카라웨이유, 마조람유, 헤이유, 레몬그라스유, 올리가눔유, 파인니들유, 네롤리유, 로즈유, 자스민유, 이리스콘크리트, 압솔루트페퍼민트, 압솔루트로즈, 오렌지플라워 등의 천연 향료 성분 ; 이들 천연 향료 성분의 가공 처리한 향료 성분 ; 멘톨, 카르본, 아네톨, 시네올, 살리실산메틸, 신나믹알데히드, 오이게놀, 2-디올, 피넨, 옥틸알데히드, 시트랄, 풀레곤, 카르빌아세테이트, 아니스알데히드 등의 단품 향료 성분 등을 들 수 있다.As fragrances, peppermint oil, spearmint oil, anise oil, eucalyptus oil, winter green oil, cassia oil, kurobu oil, thyme oil, sage oil, lemon oil, orange oil, peppermint oil, cardamom oil, coriander oil, mandarin oil, lime oil, Lavender oil, rosemary oil, laurel oil, chamomile oil, caraway oil, marjoram oil, hey, lemongrass oil, oliganum oil, pine needle oil, neroli oil, rose oil, jasmine oil, iris concrete, abssolut peppermint, Natural fragrance components, such as absoltrose and orange flower; Perfume components which processed these natural fragrance components; Individual fragrance ingredients such as menthol, carbon, anethol, cineol, methyl salicylate, cinnamic aldehyde, eugenol, 2-diol, pinene, octylaldehyde, citral, fulegon, carbyl acetate, and anisaldehyde can be heard

향료는, 1종 단독으로 사용되어도 좋고, 2종 이상이 조합되어 사용되어도 좋다.A fragrance|flavor may be used individually by 1 type, and may be used in combination of 2 or more type.

본 발명의 해충 기피 조성물에 있어서, (A)성분과, (B)성분, (C)성분, 및 (D)성분으로 이루어지는 군에서 선택되는 적어도 1종의 성분과의 합계의 함유량은 100질량%를 초과하지 않는다.In the pest repelling composition of the present invention, the total content of the component (A) and at least one component selected from the group consisting of component (B), component (C), and component (D) is 100% by mass. does not exceed

본 발명의 해충 기피 조성물의 25℃에서의 pH로서는, 기피 효과, 및 피부에의 자극의 적음의 점에서, 3∼9가 바람직하고, 5∼8이 보다 바람직하다. 또한, 상기 pH는, pH 미터(도아전파공업주식회사제, HM-30G)를 이용하여 통상의 방법으로 측정할 수 있다.As pH at 25 degreeC of the pest repelling composition of this invention, 3-9 are preferable and 5-8 are more preferable from the point of a repelling effect and little irritation to skin. In addition, the said pH can be measured by a normal method using the pH meter (The Doa Electric Wave Industrial Co., Ltd. make, HM-30G).

본 발명의 해충 기피 조성물은, (A)성분과, (B)성분, (C)성분, 및 (D)성분으로 이루어지는 군에서 선택되는 적어도 1종의 성분을 포함하고, 상기 (A)성분이 이카리딘 및 디이이티로 이루어지는 군에서 선택되는 적어도 1종이고, 상기 (B)성분이 트레할로스, 소르비톨, 및 말티톨로 이루어지는 군에서 선택되는 적어도 1종이고, 상기 (C)성분이 구연산 및 구연산나트륨으로 이루어지는 군에서 선택되는 적어도 1종이고, 상기 (D)성분이 폴리비닐피롤리돈, 및 아세트산비닐·비닐피롤리돈 공중합체로 이루어지는 군에서 선택되는 적어도 1종인 것이 바람직하다.The pest repelling composition of this invention contains (A) component, and at least 1 sort(s) of component selected from the group which consists of (B) component, (C)component, and (D)component, said (A) component At least one member selected from the group consisting of icaridin and DIET, the component (B) is at least one member selected from the group consisting of trehalose, sorbitol, and maltitol, and the component (C) is citric acid and sodium citrate. It is at least 1 type selected from the group which consists of, It is preferable that the said (D) component is at least 1 type chosen from the group which consists of polyvinyl pyrrolidone and a vinyl acetate/vinyl pyrrolidone copolymer.

본 발명의 해충 기피 조성물은, (A)성분과, (B)성분, (C)성분, 및 (D)성분으로 이루어지는 군에서 선택되는 적어도 1종의 성분을 포함하고, 상기 (A)성분이 이카리딘 및 디이이티로 이루어지는 군에서 선택되는 적어도 1종이고, 상기 (B)성분이 트레할로스, 소르비톨, 및 말티톨로 이루어지는 군에서 선택되는 적어도 1종이고, 상기 (C)성분이 구연산 및 구연산나트륨으로 이루어지는 군에서 선택되는 적어도 1종이고, 상기 (D)성분이 폴리비닐피롤리돈, 및 아세트산비닐·비닐피롤리돈 공중합체로 이루어지는 군에서 선택되는 적어도 1종이고, 해충 기피 조성물의 총질량에 대해, 상기 (A)성분의 함유량이 1∼80질량%이고, 상기 (B)성분의 함유량이 0.1∼10질량%이고, 상기 (C)성분의 함유량이 「산환산」하여, 0.01∼3질량%이고, 상기 (D)성분의 함유량이 0.1∼3질량%인 것이 바람직하다.The pest repelling composition of this invention contains (A) component, and at least 1 sort(s) of component selected from the group which consists of (B) component, (C)component, and (D)component, said (A) component At least one member selected from the group consisting of icaridin and DIET, the component (B) is at least one member selected from the group consisting of trehalose, sorbitol, and maltitol, and the component (C) is citric acid and sodium citrate. at least one selected from the group consisting of, the component (D) is at least one selected from the group consisting of polyvinylpyrrolidone and vinyl acetate/vinylpyrrolidone copolymer, and On the other hand, content of the said (A) component is 1-80 mass %, content of the said (B) component is 0.1-10 mass %, content of the said (C)component is "acid conversion", and 0.01-3 mass %, and it is preferable that content of the said (D)component is 0.1-3 mass %.

본 발명의 해충 기피 조성물은, (A)성분과, (B)성분, (C)성분, 및 (D)성분으로 이루어지는 군에서 선택되는 적어도 1종의 성분을 포함하고, 상기 (A)성분이 이카리딘 및 디이이티로 이루어지는 군에서 선택되는 적어도 1종이고, 상기 (B)성분이 트레할로스이고, 상기 (C)성분이 구연산 및 구연산나트륨으로 이루어지는 군에서 선택되는 적어도 1종이고, 상기 (D)성분이 아세트산비닐·비닐피롤리돈 공중합체인 것이 바람직하다. 본 발명의 해충 기피 조성물은, (A)성분과, (B)성분, (C)성분, 및 (D)성분으로 이루어지는 군에서 선택되는 적어도 1종의 성분을 포함하고, 상기 (A)성분이 이카리딘 및 디이이티로 이루어지는 군에서 선택되는 적어도 1종이고, 상기 (B)성분이 트레할로스이고, 상기 (C)성분이 구연산 및 구연산나트륨으로 이루어지는 군에서 선택되는 적어도 1종이고, 상기 (D)성분이 아세트산비닐·비닐피롤리돈 공중합체이고, 해충 기피 조성물의 총질량에 대해, 상기 (A)성분의 함유량이 1∼80질량%이고, 상기 (B)성분의 함유량이 0.1∼10질량%이고, 상기 (C)성분의 함유량이 「산환산」하여, 0.01∼3질량%이고, 상기 (D)성분의 함유량이 0.1∼3질량%인 것이 바람직하다.The pest repelling composition of this invention contains (A) component, and at least 1 sort(s) of component selected from the group which consists of (B) component, (C)component, and (D)component, said (A) component At least one member selected from the group consisting of icaridin and DIET, the component (B) is trehalose, and the component (C) is at least one member selected from the group consisting of citric acid and sodium citrate, and (D) It is preferable that the component is a vinyl acetate/vinylpyrrolidone copolymer. The pest repelling composition of this invention contains (A) component, and at least 1 sort(s) of component selected from the group which consists of (B) component, (C)component, and (D)component, said (A) component At least one member selected from the group consisting of icaridin and DIET, the component (B) is trehalose, and the component (C) is at least one member selected from the group consisting of citric acid and sodium citrate, and (D) A component is a vinyl acetate/vinylpyrrolidone copolymer, content of the said (A) component is 1-80 mass % with respect to the total mass of a pest repelling composition, and content of the said (B) component is 0.1-10 mass % And it is preferable that content of the said (C)component performs "acid conversion", and is 0.01-3 mass %, and that content of the said (D)component is 0.1-3 mass %.

본 발명의 해충 기피 조성물은, (A)성분과, (B)성분, (C)성분, 및 (D)성분으로 이루어지는 군에서 선택되는 적어도 1종의 성분과, (E)성분을 포함하고, 상기 (A)성분이 이카리딘 및 디이이티로 이루어지는 군에서 선택되는 적어도 1종이고, 상기 (B)성분이 트레할로스이고, 상기 (C)성분이 구연산 및 구연산나트륨으로 이루어지는 군에서 선택되는 적어도 1종이고, 상기 (D)성분이 아세트산비닐·비닐피롤리돈 공중합체이고, 상기 (E)성분이 벤잘코늄염화물, 및 이소프로필메틸페놀로 이루어지는 군에서 선택되는 적어도 1종인 것이 바람직하다. 본 발명의 해충 기피 조성물은, (A)성분과, (B)성분, (C)성분, 및 (D)성분으로 이루어지는 군에서 선택되는 적어도 1종의 성분과, (E)성분을 포함하고, 상기 (A)성분이 이카리딘 및 디이이티로 이루어지는 군에서 선택되는 적어도 1종이고, 상기 (B)성분이 트레할로스이고, 상기 (C)성분이 구연산 및 구연산나트륨으로 이루어지는 군에서 선택되는 적어도 1종이고, 상기 (D)성분이 아세트산비닐·비닐피롤리돈 공중합체 있고, 상기 (E)성분이 벤잘코늄염화물, 및 이소프로필메틸페놀로 이루어지는 군에서 선택되는 적어도 1종이고, 해충 기피 조성물의 총질량에 대해, 상기 (A)성분의 함유량이 1∼80질량%이고, 상기 (B)성분의 함유량이 0.1∼10질량%이고, 상기 (C)성분의 함유량이 「산환산」하여, 0.01∼3질량%이고, 상기 (D)성분의 함유량이 0.1∼3질량%이고, 상기 (E)성분의 함유량이 0.001∼1질량%인 것이 바람직하다.The pest repelling composition of the present invention comprises (A) component, at least one component selected from the group consisting of (B) component, (C) component, and (D) component, and (E) component, The component (A) is at least one selected from the group consisting of icaridin and DIET, the component (B) is trehalose, and the component (C) is at least one selected from the group consisting of citric acid and sodium citrate. And, it is preferable that the said (D)component is a vinyl acetate-vinylpyrrolidone copolymer, and it is at least 1 sort(s) chosen from the group which the said (E)component consists of benzalkonium chloride and isopropylmethylphenol. The pest repelling composition of the present invention comprises (A) component, at least one component selected from the group consisting of (B) component, (C) component, and (D) component, and (E) component, The component (A) is at least one selected from the group consisting of icaridin and DIET, the component (B) is trehalose, and the component (C) is at least one selected from the group consisting of citric acid and sodium citrate. and the component (D) is a vinyl acetate/vinylpyrrolidone copolymer, and the component (E) is at least one selected from the group consisting of benzalkonium chloride and isopropylmethylphenol, With respect to mass, content of the said (A) component is 1-80 mass %, content of the said (B) component is 0.1-10 mass %, content of the said (C)component is "acid conversion," 0.01- It is 3 mass %, content of the said (D)component is 0.1-3 mass %, and it is preferable that content of the said (E) component is 0.001-1 mass %.

≪해충 기피 조성물의 조제 방법≫≪Method for preparing pest repellent composition≫

본 발명의 해충 기피 조성물의 조제 방법은, (A)성분과, (B)성분, (C)성분, 및 (D)성분으로 이루어지는 군에서 선택되는 적어도 1종을 혼합하는 방법을 들 수 있다. 나아가서는, (A)성분과, (B)성분, (C)성분, 및 (D)성분으로 이루어지는 군에서 선택되는 적어도 1종과, 필요에 응하여 다른 성분을 용제에 용해시키는 방법을 들 수 있다.The preparation method of the pest repelling composition of this invention is the method of mixing (A) component, and at least 1 sort(s) selected from the group which consists of (B)component, (C)component, and (D)component. Furthermore, at least 1 sort(s) chosen from the group which consists of (A) component, (B)component, (C)component, and (D)component, and the method of melt|dissolving another component in a solvent as needed is mentioned .

≪해충 기피 방법≫≪Pest repellent method≫

본 발명의 해충 기피 조성물은, 예를 들면, 유액(乳液), 크림, 젤, 스프레이(액제(液劑)) 등의 제형(劑型)으로 사용할 수 있다. 예를 들면, 유액, 크림, 또는 젤에서의 본 발명의 해충 기피 조성물의 함유량은, 유액, 크림, 또는 젤의 총질량에 대해, 1∼100질량%가 바람직하다. 액제에서의 본 발명의 해충 기피 조성물의 함유량은, 액제의 총질량에 대해, 1∼100질량%가 바람직하다.The pest repelling composition of the present invention can be used in formulations such as emulsions, creams, gels, sprays (liquids), and the like, for example. For example, the content of the pest repelling composition of the present invention in the emulsion, cream, or gel is preferably 1 to 100% by mass based on the total mass of the emulsion, cream, or gel. As for content of the pest repelling composition of this invention in a liquid agent, 1-100 mass % is preferable with respect to the total mass of a liquid agent.

본 발명의 해충 기피 조성물은, 예를 들면 피부에 도포됨으로써, 해충에 대해 기피 효과를 발휘한다. 본 발명의 해충 기피 조성물의 사용 방법은, 본 발명의 해충 기피 조성물의 유효량을, 해충 기피가 필요한 대상의 피부 또는 착의(着衣)에 부착시키는 공정을 포함한다. 여기서 유효량이란, 0.1∼10㎎/㎠가 바람직하고, 0.5∼5㎎/㎠가 보다 바람직하다. 해충 기피가 필요한 대상으로서는, 인간, 및 동물을 들 수 있다. 부착시키는 방법으로서는, 도포, 및 스프레이 등을 들 수 있다.The pest repelling composition of the present invention exhibits a repelling effect against pests, for example, by being applied to the skin. The method of using the pest repelling composition of the present invention includes a step of adhering an effective amount of the pest repelling composition of the present invention to the skin or clothing of a target in need of pest repelling. 0.1-10 mg/cm<2> is preferable with an effective amount here, and 0.5-5 mg/cm<2> is more preferable. Examples of objects requiring pest repelling include humans and animals. As a method of making it adhere, application|coating, spraying, etc. are mentioned.

본 발명의 해충 기피 조성물에 의해 기피 대상이 되는 해충으로서는, 예를 들면 모기, 파리매, 쇠파리, 진드기, 빈대(빈대), 진드기, 벌진드기 등을 들 수 있다. 그 중에서도 모기가 바람직하다.Examples of pests to be repelled by the pest repelling composition of the present invention include mosquitoes, fly falcons, small flies, mites, bedbugs (bedbugs), mites, and bee mites. Among them, mosquitoes are preferable.

실시례Example

이하에 실시례를 이용하여 본 발명을 더욱 상세하게 설명하지만, 본 발명은 이들 실시례로 한정되는 것이 아니다.Hereinafter, the present invention will be described in more detail using examples, but the present invention is not limited to these examples.

본 실시례에서 사용하는 원료는 하기한 에 표시하는 바와 같다The raw materials used in this example are as indicated below.

표 1 중, 그레이드의 난의 「외원규」는 의약 부외품 원료 규격의 약칭이다. 「일국」은 일본 약국방의 약칭이다.In Table 1, "Oe Won-gyu" in the column of grade is an abbreviation of the standard for a quasi-drug raw material. 「Ilguk」is an abbreviation for Japanese Pharmacy.

[표 1][Table 1]

Figure 112018092290319-pct00001
Figure 112018092290319-pct00001

[해충 기피 조성물의 조제][Preparation of a pest repelling composition]

표 2에 표시하는 조성(질량%로 기재)에 따라, 각 성분을 혼합하여 각 예의 해충 기피 조성물을 조정하였다.According to the composition (described in mass %) shown in Table 2, each component was mixed to adjust the pest repelling composition of each example.

얻어진 해충 기피 조성물에 관해, 이하의 순서로 기피 효과의 평가를 행하였다.About the obtained pest repelling composition, the following procedure evaluated the repelling effect.

[기피 효과의 평가][Evaluation of avoidance effect]

도 1에 도시하는 바와 같이, 50cm×50cm×50cm의 아크릴 박스를 칸막이판(4)을 통하여 2개 연결하여, 연결 케이지(10)을 작성하였다. 연결 케이지(10)의 우측 케이지(2)에 흰줄숲모기(암컷)(5)를 50마리(匹) 방중(放中) 하였다. 전문 패널러 1명의 팔(腕)부터 손끝의 범위에 각 기피 조성물을 약 2g 도포하고 건조시켰다. 30℃ 조건하에서 10분간 에어로바이크(등록상표)에 의한 운동을 행하여, 강제 발한(發汗)시킨 후, 스타킹제의 통(3) 안에 팔(腕)을 넣고, 칸막이판(4) 개구부를 개방하고, 5분간에 좌측 케이지(1) 안에 침입한 모기의 엔트리수(數)를 측정하였다(발한 직후). 기피 조성물을 도포 후 발한하고 나서 2시간, 및 4시간 경과한 팔(腕) 통(3) 안에 넣고, 모기의 엔트리수를 측정하였다. 이것을 도포시(塗布時) 엔트리수로 하였다.As shown in FIG. 1 , two 50 cm x 50 cm x 50 cm acrylic boxes were connected through a partition plate 4 to form a connecting cage 10 . 50 Aedes Aedes mosquitoes (females) (5) were left in the cage (2) on the right side of the connection cage (10). About 2 g of each repellent composition was applied from the arm to the fingertip of one professional paneler and dried. After performing exercise with an aerobike (registered trademark) for 10 minutes under 30 ° C conditions, forced sweating, put the arm in the stocking container 3, open the partition plate 4 opening, , the number of entries of mosquitoes entering the cage 1 on the left in 5 minutes was measured (immediately after sweating). After applying the repellent composition, it was put in the arm barrel 3 after 2 hours and 4 hours after sweating, and the number of entry of mosquitoes was measured. This was made into the number of entries at the time of application|coating.

기피 조성물을 도포하지 않은 팔(腕)로 마차가지의 평가를 행하고, 모기의 엔트리수를 측정하였다. 이것을 무도포시 엔트리수로 하였다.The horse carriage was evaluated with the arm to which the repellent composition was not applied, and the number of entry of mosquitoes was measured. This was made into the number of entries in the case of no application.

얻어진 도포시 엔트리수와 무도포시 엔트리수로부터, 이하의 식에 의해 기피율을 산출하고, 하기 평가 기준에 의해 기피 효과를 평가하였다.From the obtained number of entries at the time of application|coating and the number of entries at the time of no application, the repelling rate was computed by the following formula, and the repelling effect was evaluated by the following evaluation criteria.

기피율(%)={1-(도포시 엔트리수-보정 엔트리수)/(무도포시 엔트리수-보정 엔트리수)}×100Evasion rate (%) = {1-(Number of entries when applied - Number of corrected entries)/(Number of entries when not applied - Number of corrected entries)}×100

보정 엔트리수란, 팔(腕)을 넣지 않은 조건하에서의 모기의 엔트리수이다. 보정 후, 엔트리수가 마이너스가 된 경우, 0으로서 평가하였다.The number of corrected entries is the number of entries of mosquitoes under the condition that arms are not inserted. After correction, when the number of entries became negative, it was evaluated as 0.

(평가 기준)(Evaluation standard)

◎ : 기피율이 90% 이상∼100%.(double-circle): Rejection rate is 90% or more - 100%.

○ : 기피율이 70% 이상∼90% 미만.(circle): Rejection rate is 70% or more - less than 90%.

△ : 기피율이 50% 이상∼70 미만.(triangle|delta): The avoidance rate is 50 % or more - less than 70.

× : 기피율이 50% 미만.x: Rejection rate is less than 50 %.

[표 2][Table 2]

Figure 112018092290319-pct00002
Figure 112018092290319-pct00002

실시례 1∼8 이외의 본 발명의 해충 기피 조성물의 처방례를 표 3에 표시한다.Table 3 shows formulation examples of the pest repelling compositions of the present invention other than Examples 1 to 8.

[표 3][Table 3]

Figure 112018092290319-pct00003
Figure 112018092290319-pct00003

본 발명을 적용한 실시례 1∼8에서는, 높은 기피 효과가 얻어졌다. 한편, (B)∼(D)성분을 모두 포함하지 않는 비교례 1, 2 및 3에서는, 기피 효과에 있어서 뒤떨어져 있다.In Examples 1 to 8 to which the present invention was applied, a high repelling effect was obtained. On the other hand, in the comparative examples 1, 2, and 3 which do not contain all (B)-(D) component, it is inferior in the repelling effect.

이상의 결과로부터, 본 발명의 해충 기피 조성물에 의하면, 높은 해충 기피 효과를 얻을 수 있음을 알았다.From the above results, it was found that, according to the pest repelling composition of the present invention, a high pest repelling effect can be obtained.

[산업상의 이용 가능성][Industrial Applicability]

본 발명에 의하면, 해충 기피 효과에 우수한 해충 기피 조성물, 및 이것을 사용한 해충 기피 방법을 제공할 수 있다.ADVANTAGE OF THE INVENTION According to this invention, the pest repelling composition excellent in the pest repelling effect, and the pest repelling method using the same can be provided.

10 : 연결 케이지
1 : 좌측 케이지
2 : 우측 케이지
3 : 통
4 : 칸막이판
5 : 흰줄숲모기10: connecting cage
1: Left cage
2: Right cage
3: barrel
4: partition plate
5: Aedes aegypti mosquito

Claims (6)

(A)성분과, (B)성분, (C)성분, 및 (D)성분으로 이루어지는 군에서 선택되는 적어도 1종의 성분을 포함하는 해충 기피 조성물로서,
상기 (A)성분이 이카리딘, 및 디이이티로 이루어지는 군에서 선택되는 적어도 1종이고,
상기 (B)성분이 트레할로스, 및 말티톨로 이루어지는 군에서 선택되는 적어도 1종이고,
상기 (C)성분이 구연산, 및 구연산나트륨으로 이루어지는 군에서 선택되는 적어도 1종이고, 상기 (C)성분을 포함하는 경우, 상기 (C)성분의 함유량은, 산환산하여, 해충 기피 조성물의 총 질량에 대해 0.1∼0.46질량%이고,
상기 (D)성분이 아세트산비닐·비닐피롤리돈 공중합체인 것을 특징으로 하는 해충 기피 조성물.A pest repelling composition comprising (A) component and at least one component selected from the group consisting of (B) component, (C) component, and (D) component,
The component (A) is at least one selected from the group consisting of icaridin and DI,
The component (B) is at least one selected from the group consisting of trehalose and maltitol,
When the component (C) is at least one selected from the group consisting of citric acid and sodium citrate, and the component (C) is included, the content of the component (C) is calculated in terms of the total amount of the pest repelling composition. 0.1-0.46 mass % with respect to the mass,
The pest repelling composition, characterized in that the component (D) is a vinyl acetate/vinylpyrrolidone copolymer. 제1항에 있어서,
상기 (A)성분이 이카리딘인 것을 특징으로 하는 해충 기피 조성물.According to claim 1,
The pest repelling composition, characterized in that the component (A) is icaridin. 제1항 또는 제2항에 있어서,
상기 (B)성분, 및 상기 (C)성분을 포함하는 것을 특징으로 하는 해충 기피 조성물.3. The method of claim 1 or 2,
The said (B) component and the said (C) component are included, The pest repelling composition characterized by the above-mentioned. 제1항 또는 제2항에 있어서,
상기 (B)성분, 상기 (C)성분, 및 상기 (D)성분을 포함하는 것을 특징으로 하는 해충 기피 조성물.3. The method of claim 1 or 2,
Said (B) component, said (C)component, and said (D)component are included, The pest repelling composition characterized by the above-mentioned. 제1항 또는 제2항에 있어서,
또한, (E)성분 : 항균성 화합물을 포함하는 것을 특징으로 하는 해충 기피 조성물.3. The method of claim 1 or 2,
In addition, (E) component: A pest repelling composition comprising an antibacterial compound. 제1항 또는 제2항에 기재된 해충 기피 조성물을 사용하는 것을 특징으로 하는 해충 기피 방법.A method for repelling pests, characterized in that the pest repelling composition according to claim 1 or 2 is used.
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