KR102120029B1 - Hybrid capsule detergent composition for laundry - Google Patents
Hybrid capsule detergent composition for laundry Download PDFInfo
- Publication number
- KR102120029B1 KR102120029B1 KR1020200052057A KR20200052057A KR102120029B1 KR 102120029 B1 KR102120029 B1 KR 102120029B1 KR 1020200052057 A KR1020200052057 A KR 1020200052057A KR 20200052057 A KR20200052057 A KR 20200052057A KR 102120029 B1 KR102120029 B1 KR 102120029B1
- Authority
- KR
- South Korea
- Prior art keywords
- capsule
- acid
- water
- ethanol
- laundry
- Prior art date
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- 239000002775 capsule Substances 0.000 title claims abstract description 88
- 239000003599 detergent Substances 0.000 title claims abstract description 51
- 239000000203 mixture Substances 0.000 title claims abstract description 48
- 238000005406 washing Methods 0.000 claims abstract description 45
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 31
- 239000004094 surface-active agent Substances 0.000 claims abstract description 28
- 102000004190 Enzymes Human genes 0.000 claims abstract description 22
- 108090000790 Enzymes Proteins 0.000 claims abstract description 22
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 16
- 239000003381 stabilizer Substances 0.000 claims abstract description 12
- 239000008213 purified water Substances 0.000 claims abstract description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 118
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 claims description 43
- 230000002378 acidificating effect Effects 0.000 claims description 38
- 239000011248 coating agent Substances 0.000 claims description 33
- 230000001954 sterilising effect Effects 0.000 claims description 27
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 24
- 229920000747 poly(lactic acid) Polymers 0.000 claims description 24
- 239000004626 polylactic acid Substances 0.000 claims description 24
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 24
- 229940088598 enzyme Drugs 0.000 claims description 21
- 229920002689 polyvinyl acetate Polymers 0.000 claims description 20
- -1 thiosynergist Substances 0.000 claims description 16
- 238000000576 coating method Methods 0.000 claims description 15
- 239000000194 fatty acid Substances 0.000 claims description 15
- 230000000694 effects Effects 0.000 claims description 14
- 239000002994 raw material Substances 0.000 claims description 14
- 241000196324 Embryophyta Species 0.000 claims description 13
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 13
- 229930195729 fatty acid Natural products 0.000 claims description 13
- 239000011118 polyvinyl acetate Substances 0.000 claims description 13
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 12
- 239000002736 nonionic surfactant Substances 0.000 claims description 11
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 10
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 9
- 229910052801 chlorine Inorganic materials 0.000 claims description 9
- 239000000460 chlorine Substances 0.000 claims description 9
- 238000004659 sterilization and disinfection Methods 0.000 claims description 9
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 8
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 claims description 8
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 8
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 8
- 239000001099 ammonium carbonate Substances 0.000 claims description 8
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 8
- WGTYBPLFGIVFAS-UHFFFAOYSA-M tetramethylammonium hydroxide Chemical compound [OH-].C[N+](C)(C)C WGTYBPLFGIVFAS-UHFFFAOYSA-M 0.000 claims description 8
- 125000000129 anionic group Chemical group 0.000 claims description 7
- 150000004665 fatty acids Chemical class 0.000 claims description 7
- 230000007935 neutral effect Effects 0.000 claims description 7
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- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 claims description 4
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- MIJDSYMOBYNHOT-UHFFFAOYSA-N 2-(ethylamino)ethanol Chemical compound CCNCCO MIJDSYMOBYNHOT-UHFFFAOYSA-N 0.000 claims description 2
- ACZGCWSMSTYWDQ-UHFFFAOYSA-N 3h-1-benzofuran-2-one Chemical compound C1=CC=C2OC(=O)CC2=C1 ACZGCWSMSTYWDQ-UHFFFAOYSA-N 0.000 claims description 2
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- 239000002245 particle Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229960003975 potassium Drugs 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 230000017854 proteolysis Effects 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229940057950 sodium laureth sulfate Drugs 0.000 description 1
- SXHLENDCVBIJFO-UHFFFAOYSA-M sodium;2-[2-(2-dodecoxyethoxy)ethoxy]ethyl sulfate Chemical compound [Na+].CCCCCCCCCCCCOCCOCCOCCOS([O-])(=O)=O SXHLENDCVBIJFO-UHFFFAOYSA-M 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 201000008297 typhoid fever Diseases 0.000 description 1
- 229960005356 urokinase Drugs 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
- C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C11D11/0017—
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/08—Liquid soap, e.g. for dispensers; capsuled
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0047—Other compounding ingredients characterised by their effect pH regulated compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/12—Soft surfaces, e.g. textile
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
Description
본 발명은 세탁용 하이브리드 캡슐 세제 조성물에 관한 것으로, 보다 구체적으로는, 수용성 필름에 쌓여 있으면서 내부의 2차적인 캡슐 구조에 포함된 성분으로 세척력을 향상시킬 뿐만 아니라, 살균 효과를 함께 제공하면서도 지속력을 높이도록 하기 위한 세탁용 하이브리드 캡슐 세제 조성물에 관한 것이다. The present invention relates to a hybrid capsule detergent composition for washing, and more specifically, as it is stacked in a water-soluble film and improves the washing power with the components included in the secondary capsule structure inside, and provides a sterilizing effect while providing durability. It relates to a hybrid capsule detergent composition for washing to increase.
일반적으로 천연의 식물로부터 세제성분을 추출하는 방법으로서 일반에 알려진 방법은 알코올에 침지시켜, 세제성분으로 사용할 수 있는 산을 추출하는 방법이 사용되고 있다. 그러나 천연의 세제성분은 극히 적으며 따라서 세제성분을 추출하기 위하여 대량의 재료를 사용해야 하기 때문에 세제의 가격이 증가하게 된다.In general, as a method of extracting a detergent component from a natural plant, a method known in general is used to extract an acid that can be used as a detergent component by immersing in alcohol. However, the natural detergent component is very small, and therefore, the price of the detergent increases because a large amount of materials must be used to extract the detergent component.
이에 따라 해당 기술분야에 있어서는 천연의 식물로부터 세제성분을 추출하는 것이 아닌 친환경적인 소재의 사용을 확대하면서도 세척력과 함께 살균력을 향상시키기 위한 기술 개발이 요구되고 있다. Accordingly, in the related art field, there is a need to develop a technology for improving the sterilizing power along with washing power while expanding the use of eco-friendly materials rather than extracting detergent components from natural plants.
본 발명은 상기의 문제점을 해결하기 위한 것으로, 세척력을 향상시킬 뿐만 아니라, 살균 효과를 함께 제공하도록 하기 위한 세탁용 하이브리드 캡슐 세제 조성물을 제공하기 위한 것이다.The present invention is to solve the above problems, as well as to improve the washing power, to provide a hybrid capsule detergent composition for washing to provide a sterilizing effect together.
또한, 본 발명은 친환경 소재로 제조될 뿐만 아니라, 중성 내지 약알칼리성(pH7 내지 9)으로, 피부 자극성이 거의 없으며, 강력하고 깨긋한 세척 효과외에 살균효과, 그리고 무형광, 무색소로 제조되는 세탁용 하이브리드 캡슐 세제 조성물을 제공하기 위한 것이다.In addition, the present invention is not only made of an eco-friendly material, it is neutral to weakly alkaline (pH7 to 9), has little skin irritation, and has a sterilizing effect in addition to a strong and clean washing effect, and a washing hybrid made of fluorescence and colorless It is intended to provide a capsule detergent composition.
또한, 본 발명은 세탁기에서 살균제가 오래동안 지속되기 위해 캡슐 타입으로 제조되어 효과를 극대화하도록 하기 위한 세탁용 하이브리드 캡슐 세제 조성물을 제공하기 위한 것이다.In addition, the present invention is to provide a hybrid capsule detergent composition for washing in order to maximize effectiveness by being manufactured in a capsule type for long-lasting fungicide in the washing machine.
그러나 본 발명의 목적들은 상기에 언급된 목적으로 제한되지 않으며, 언급되지 않은 또 다른 목적들은 아래의 기재로부터 당업자에게 명확하게 이해될 수 있을 것이다.However, the objects of the present invention are not limited to the above-mentioned objects, and other objects not mentioned will be clearly understood by those skilled in the art from the following description.
상기의 목적을 달성하기 위해 본 발명의 실시예에 따른 세탁용 하이브리드 캡슐 세제 조성물은, 세탁용 하이브리드 캡슐 세제 조성물은 계면활성제, 안정화제, 효소, 산도조절제, 수용성 필름제, 정제수가 미리 설정된 중량비로 구성되는 것을 특징으로 할 수 있다.In order to achieve the above object, the hybrid capsule detergent composition for washing according to the embodiment of the present invention, the hybrid capsule detergent composition for washing is a surfactant, a stabilizer, an enzyme, an acidity regulator, a water-soluble film agent, and purified water in a preset weight ratio. It can be characterized by being configured.
이때, 상기 계면활성제는, 제 1 비이온 계면활성제(비이온 알코올계), 음이온 계면활성제(음이온 알코올계), 제 2 비이온 계면활성제(비이온 지방산계)가 전체 계면활성제 내에서 2.5 내지 3 : 2.3 내지 2.7 : 1.2 내지 1.5 중량비로 형성되는 것을 특징으로 할 수 있다.At this time, the surfactant, the first nonionic surfactant (nonionic alcohol-based), anionic surfactant (anionic alcohol-based), the second nonionic surfactant (nonionic fatty acid-based) 2.5 to 3 in the total surfactant : 2.3 to 2.7: It may be characterized by being formed in a weight ratio of 1.2 to 1.5.
본 발명의 실시예에 따른 세탁용 하이브리드 캡슐 세제 조성물은, 세척력을 향상시킬 뿐만 아니라, 살균 효과를 함께 제공할 수 있다.Hybrid capsule detergent composition for laundry according to an embodiment of the present invention, as well as to improve the washing power, may provide a sterilizing effect together.
또한, 본 발명의 다른 실시예에 따른 세탁용 하이브리드 캡슐 세제 조성물은, 친환경 소재로 제조될 뿐만 아니라, 중성 내지 약알칼리성(pH7 내지 9)으로, 피부 자극성이 거의 없으며, 강력하고 깨긋한 세척 효과외에 살균효과, 그리고 무형광, 무색소로 제조될 수 있다. In addition, the hybrid capsule detergent composition for laundry according to another embodiment of the present invention is not only made of an eco-friendly material, but also has neutral to weak alkalinity (pH7 to 9), has little skin irritation, and has a strong and clean washing effect. It can be manufactured with sterilizing effect and fluorescence-free and colorless.
뿐만 아니라, 본 발명의 다른 실시예에 따른 세탁용 하이브리드 캡슐 세제 조성물은, 세탁기에서 살균제가 오래동안 지속되기 위해 캡슐 타입으로 제조되어 효과를 극대화할 수 있는 효과가 있다. In addition, the hybrid capsule detergent composition for washing according to another embodiment of the present invention has an effect of maximizing the effect by being manufactured in a capsule type in order to last a long time in the washing machine.
도 1 및 도 2는 본 발명의 실시예에 따른 세탁용 하이브리드 캡슐 세제 조성물에 의해 제조된 세탁용 하이브리드 캡슐 세제를 나타내는 도면이다.1 and 2 are views illustrating a hybrid capsule detergent for laundry prepared by a hybrid capsule detergent composition for laundry according to an embodiment of the present invention.
이하, 본 발명의 바람직한 실시예의 상세한 설명은 첨부된 도면들을 참조하여 설명할 것이다. 하기에서 본 발명을 설명함에 있어서, 관련된 공지 기능 또는 구성에 대한 구체적인 설명이 본 발명의 요지를 불필요하게 흐릴 수 있다고 판단되는 경우에는 그 상세한 설명을 생략할 것이다.Hereinafter, a detailed description of a preferred embodiment of the present invention will be described with reference to the accompanying drawings. In the following description of the present invention, when it is determined that a detailed description of related known functions or configurations may unnecessarily obscure the subject matter of the present invention, the detailed description will be omitted.
세탁용 하이브리드 캡슐 세제 조성물은 계면활성제, 안정화제, 효소, 산도조절제, 수용성 필름제, 정제수가 미리 설정된 중량비로 구성될 수 있다. 여기서 미리 설정된 중량비로 계면활성제, 안정화제, 효소, 산도조절제, 수용성 필름제, 정제수, 그리고 소독형 캡슐을 30 내지 35 : 3 내지 4 : 0.2 내지 0.7 : 1 내지 2 : 10 내지 20 : 20 내지 25 : 1 내지 3으로 형성됨으로써, 세제로서의 기능 뿐만 아니라 세탁물에 대한 살균 효과를 동시에 제공할 수 있다. The hybrid capsule detergent composition for washing may be composed of a surfactant, a stabilizer, an enzyme, an acidity adjusting agent, a water-soluble film agent, and purified water in a preset weight ratio. Here, surfactants, stabilizers, enzymes, acidity regulators, water-soluble film agents, purified water, and disinfectable capsules in a preset weight ratio of 30 to 35: 3 to 4: 0.2 to 0.7: 1 to 2: 10 to 20: 20 to 25 : Formed from 1 to 3, it is possible to provide not only a function as a detergent but also a sterilizing effect for laundry.
한편, 계면활성제는 제 1 비이온 계면활성제(비이온 알코올계), 음이온 계면활성제(음이온 알코올계), 제 2 비이온 계면활성제(비이온 지방산계)가 전체 계면활성제 내에서 2.5 내지 3 : 2.3 내지 2.7 : 1.2 내지 1.5 중량비로 형성될 수 있다.On the other hand, as the surfactant, the first nonionic surfactant (nonionic alcohol-based), anionic surfactant (anionic alcohol-based), and second nonionic surfactant (nonionic fatty acid-based) are 2.5 to 3:2.3 in the total surfactant. To 2.7: may be formed in a weight ratio of 1.2 to 1.5.
제 1 비이온 계면활성제(비이온 알코올계)는 옥시에틸렌 알코올, 세틸 알코올 및 스테아릴 알코올 및 이들의 혼합물로 이루어진 군으로부터 선택될 수 있다.The first nonionic surfactant (nonionic alcohol-based) may be selected from the group consisting of oxyethylene alcohol, cetyl alcohol and stearyl alcohol and mixtures thereof.
여기서 제 1 비이온 계면활성제(비이온 알코올계)의 함량이 3 중량비를 초과하는 경우, 세탁용 하이브리드 캡슐 세제 조성물로 형성된 세탁용 하이브리드 캡슐 세제의 수용성 필름제의 제형성(劑形性)이 현격히 떨어지므로 3중량비를 초과하지 않는 것이 바람직하다. Here, when the content of the first nonionic surfactant (nonionic alcohol-based) exceeds 3 weight ratio, the formulation property of the water-soluble film agent of the laundry hybrid capsule detergent formed of the laundry hybrid capsule detergent composition is markedly As it falls, it is preferable not to exceed 3 weight ratio.
본 발명에 따른 제 1 비이온 계면활성제(비이온 알코올계)의 예로는 LA5 (pentaoxyethylated lauryl alcohol), LA7 (heptaoxyethylated lauryl alcohol), LA9 (nonaoxyethylated lauryl alcohol) 등을 단독으로 또는 혼합하여 사용될 수 있으며, 본 발명에서는 헵타옥시에틸레이티드 라우릴 알코올(LA7), 노나옥시에틸레이티드 라우릴 알코올(LA9) 또는 이들의 혼합물이 더욱 바람직하다.Examples of the first nonionic surfactant (nonionic alcohol-based) according to the present invention may be used alone or in combination with LA5 (pentaoxyethylated lauryl alcohol), LA7 (heptaoxyethylated lauryl alcohol), LA9 (nonaoxyethylated lauryl alcohol), etc. In the present invention, heptoxyoxyethylated lauryl alcohol (LA7), nonaoxyethylated lauryl alcohol (LA9) or a mixture thereof is more preferable.
음이온 계면활성제(음이온 알코올계)는 물에 녹인 경우 친수기가 음이온에 해리하는 것으로 음이온 알코올계 계면활성제의 함량 비율이 2.7를 초과하는 경우에는, 세탁물의 표면을 변화시키는데 충분한 효과를 얻을 수 없을 뿐만 아니라, 음이온 알코올계 계면활성제가 세탁물 표면에 흡착될 가능성이 높아질 수 있다.The anionic surfactant (anionic alcohol-based) is a hydrophilic group that dissociates into an anion when dissolved in water. When the content ratio of the anionic alcohol-based surfactant exceeds 2.7, it is not only impossible to obtain a sufficient effect to change the surface of laundry. , Anionic alcohol-based surfactant may be more likely to be adsorbed on the laundry surface.
음이온 계면활성제(음이온 알코올계)로는 2차 알코올 황산염, 그 밖의 본 발명의 다른 실시예로, SLES 2 (sodium laureth sulfate), SLES 3, SLS (sodium lauryl sulfate), SAS(Sodium alkanesulfonate), ALS (Ammonium Lauryl Sulfate), AOS (Alpha Olefin sulfonate), ALES (Ammonium Laureth Sulfate), LAS(linear alkylbenze sulphonate)-MEA(mono ethanol amine), LAS-Na (Soduim linear alkylbenze sulphonate), Lauric acid-K (Potassium Laurate), Myristic acid-K (Potassium Myristrate), MES (methyl ester sulfonate)로 이루어진 군으로부터 선택된 하나 이상 또는 화합물을 일종 또는 이종 이상 선택 사용할 수 있다.As anionic surfactants (anionic alcohol-based), secondary alcohol sulfates, and other embodiments of the present invention, SLES 2 (sodium laureth sulfate), SLES 3, SLS (sodium lauryl sulfate), SAS (Sodium alkanesulfonate), ALS ( Ammonium Lauryl Sulfate), AOS (Alpha Olefin sulfonate), ALES (Ammonium Laureth Sulfate), LAS (linear alkylbenze sulphonate)-MEA (mono ethanol amine), LAS-Na (Soduim linear alkylbenze sulphonate), Lauric acid-K (Potassium Laurate) ), Myristic acid-K (Potassium Myristrate), MES (methyl ester sulfonate), one or more or more compounds selected from the group consisting of may be used.
알코올계 계면활성제는 세탁물의 세정과 찬물에서도 세정이 활발하도록 하는 역할을 수행할 뿐만 아니라, 세탁물에 부착된 유기물질을 제거하는 효과가 있다.Alcohol-based surfactants not only play a role in cleaning and washing water in the laundry, but also have an effect of removing organic substances attached to the laundry.
알코올계 계면활성제는 오염물질을 제거하고 또한 그것의 재부착을 방지함으로써 세정시킬 뿐만 아니라 세탁기 블레이드와 세탁물의 마찰시 마찰력을 감소시켜 소음을 방지하고 원활하게 움직일 수 있도록 하는 윤활제의 역할도 한다.The alcohol-based surfactant not only cleans by removing contaminants and preventing re-attachment, but also acts as a lubricant to reduce the frictional force during friction between the washing machine blade and the laundry to prevent noise and move smoothly.
제 2 비이온 계면활성제(비이온 지방산계)는 지방산 모노에스테르계 계면활성제(PEG-Fatty acid monoester surfactant), PEG-지방산 디에스테르계 계면활성제(PEG-Fatty acid diester surfactant), PEG 글리세롤 지방산 에스테르계 계면활성제(PEG-Glycerol Fatty acid ester surfactant), 폴리글리세르화 지방산계 계면활성제(Polyglycerized Fatty acids), 폴리프로필렌글리콜 지방산 에스테르계 계면활성제(Polypropylene Glycol Fatty acid esters), PEG-솔비탄 지방산 에스테르계 계면활성제(PEG-Sorbitan Fatty acid ester), 자당 지방산 에스테르계 계면활성제(Sugar ester surfactant)로 이루어진 군으로부터 선택된 하나 이상 또는 화합물을 일종 또는 이종 이상 선택 사용할 수 있다. 제 2 비이온 계면활성제(비이온 지방산계)는 알코올계 계면활성제와 병용하여 유화력, 세정력이 현저히 상승시키는데 사용할 수 있다. The second nonionic surfactant (nonionic fatty acid type) is a fatty acid monoester surfactant (PEG-Fatty acid monoester surfactant), PEG-Fatty acid diester surfactant, PEG glycerol fatty acid ester type Surfactant (PEG-Glycerol Fatty acid ester surfactant), Polyglycerized Fatty acids, Polypropylene Glycol Fatty acid esters, PEG-Solbitan fatty acid ester surfactants One or more or more compounds selected from the group consisting of PEG-Sorbitan Fatty acid ester and Sucrose fatty acid ester surfactant may be used. The second nonionic surfactant (nonionic fatty acid-based) can be used in combination with an alcohol-based surfactant to significantly increase the emulsifying and cleaning power.
안정화제는 포스파이트, 포스포나이트, 아민계 산화방지제, 히드록실아민, 벤조퓨란-2-온, 티오시너지스트, 가소제, 산 스캐빈저, 활택제, 분산 조제, 입체 장애 아민, UV 흡수제 및 입체장애 페놀로 이루어진 군에서 선택된 하나 이상을 첨가함으로써, 계면활성제, 효소, 산도조절제, 정제수, 소독형 캡슐에 대해서 수성 에멀젼이 아닌 저점도를 갖는 저장 안정성 액체 배합물로 수용성 필름제 내에서 유지될 수 있도록 한다. Stabilizers are phosphites, phosphonites, amine antioxidants, hydroxylamines, benzofuran-2-ones, thiosynergists, plasticizers, acid scavengers, lubricants, dispersion aids, steric hindrance amines, UV absorbers and By adding at least one selected from the group consisting of hindered phenols, surfactants, enzymes, acidity regulators, purified water, storage stability liquid formulations with low viscosity rather than aqueous emulsions for disinfectable capsules can be maintained in water-soluble film formulations. To make.
효소는 단백질분해효소를 사용하는 것이 바람직하다. 본 발명에서 단백질분해효소는 카텝신(cathepsin)류 효소, MMP(matrix metalloproteinase)류 효소, 카스파아제(caspase)류 효소, 세크레타아제(secretase)류 효소, 유로키나제(urokinase), HIV-1 단백분해효소(HIV-1 protease), HSV-1 단백분해효소(HSV-1 protease), TEV 단백질분해효소(TEV protease), PSA(Prostate Specific Antigen), 탄저 치사 인자 엔도펩티다아제(Anthrax lethal factor endopeptidase) 및 트롬빈(thrombin)으로 구성된 군에서 선택되는 어느 하나인 것을 사용하는 것이 바람직하다. It is preferable to use protease as the enzyme. Protease in the present invention is cathepsin (cathepsin) enzymes, MMP (matrix metalloproteinase) enzymes, caspase (caspase) enzymes, secretase (secretase) enzymes, eurokinase (urokinase), HIV-1 proteolysis Enzymes (HIV-1 protease), HSV-1 protease, TEV protease, PSA (Prostate Specific Antigen), Anthrax lethal factor endopeptidase and thrombin It is preferable to use any one selected from the group consisting of (thrombin).
산도조절제는 세탁물의 유지얼룩을 제거 효과가 우수하며, 중성 내지 약알칼리성을 제공하는 임의의 저분자량의 유기 또는 임의의 유기화합물이 가능하다. 본 발명에서, 산도조절제는, 모노에탄올아민, 디에탄올아민, 트리에탄올아민, 소듐하이드록사이드, 포타슘 하이드록사이드의 액상의 알칼리제 및 구연산, 사과산, 살리실산, 주석산, 젖산, 아세트산, 소르브산, 벤조인산에서 적어도 하나 이상에 해당하는 제 1 산도조절제와, 메틸에탄올아민, 에틸에탄올아민, N-아미노-N-프로판올, 메틸아민, 디메틸아민, 트리메틸아민, 에틸아민, 디에틸아민, 트리에틸아민, 에틸렌디아민, 모노에탄올아민, N-(β-아미노에틸)에탄올아민, 헥사메틸렌디아민, 디에틸렌트리아민, 트리에틸렌테트라민, 테트라에틸렌펜타민, 무수 피페라진, 피페라진 육수화물, 1-(2-아미노에틸)피페라진 및 N-메틸피페라진, 암모니아, 수산화테트라메틸암모늄, 수산화테트라에틸암모늄, 탄산수소암모늄, 탄산암모늄, 탄산수소칼륨, 탄산칼륨, 탄산수소나트륨, 탄산나트륨, 암모니아, 수산화칼륨, 수산화나트륨, 수산화테트라메틸암모늄, 수산화테트라에틸암모늄, 탄산수소암모늄, 탄산암모늄, 탄산수소칼륨, 탄산칼륨, 탄산수소나트륨 및 탄산나트륨으로 이루어진 군에서 선택되는 적어도 하나 이상에 해당하는 제 2 산도 조절제를 중량비 1 : 1.2 내지 1.5로 혼합하여 사용하는 것이 바람직하다. The acidity adjusting agent has an excellent effect of removing maintenance stains from laundry, and any low molecular weight organic or any organic compound providing neutral to weak alkalinity is possible. In the present invention, the acidity adjusting agent, monoethanolamine, diethanolamine, triethanolamine, sodium hydroxide, potassium hydroxide liquid alkali and citric acid, malic acid, salicylic acid, tartaric acid, lactic acid, acetic acid, sorbic acid, benzoic acid A first acidity regulator corresponding to at least one or more, methylethanolamine, ethylethanolamine, N-amino-N-propanol, methylamine, dimethylamine, trimethylamine, ethylamine, diethylamine, triethylamine, ethylene Diamine, monoethanolamine, N-(β-aminoethyl)ethanolamine, hexamethylenediamine, diethylenetriamine, triethylenetetramine, tetraethylenepentamine, piperazine anhydride, piperazine hexahydrate, 1-(2- Aminoethyl)piperazine and N-methylpiperazine, ammonia, tetramethylammonium hydroxide, tetraethylammonium hydroxide, ammonium hydrogencarbonate, ammonium carbonate, potassium hydrogencarbonate, potassium carbonate, sodium hydrogencarbonate, sodium carbonate, ammonia, potassium hydroxide, hydroxide Sodium, tetramethylammonium hydroxide, tetraethylammonium hydroxide, ammonium hydrogen carbonate, ammonium carbonate, potassium hydrogen carbonate, potassium carbonate, sodium hydrogen carbonate and a second acidity control agent corresponding to at least one selected from the group consisting of sodium carbonate weight ratio 1 : It is preferred to use it in a mixture of 1.2 to 1.5.
수용성 필름제는 수용성 수지와 탄소 섬유를 중량비 10 내지 12 : 1의 함량으로 형성한 투명형의 필름을 제조하여 계면활성제, 안정화제, 효소, 산도조절제, 정제수, 그리고 소독형 캡슐이 상술한 미리 설정된 중량비로 교반되어 도 1과 같은 형태로 점도를 갖는 겔(gel) 형으로 제조된 뒤, 겔 형태의 세제 조성물을 포장하는데 활용할 수 있다. 수용성 수지는 폴리비닐 알코올; 변형된 폴리비닐 알코올; 구아 검, 잔탄 검, 카라기난, 및 전분을 포함하는 수용해성 천연 고분자; 에톡실화 전분 및 하이드록실프로필화 전분을 포함하는 수용해성 고분자 유도체; 이들의 공중합체; 및 이들의 임의의 조합으로 이루어진 군으로부터 선택된 것인일 수 있다.The water-soluble film is prepared by forming a transparent film formed of a water-soluble resin and carbon fiber in a weight ratio of 10 to 12:1, and surfactants, stabilizers, enzymes, acidity regulators, purified water, and sterilized capsules are set in advance as described above. After being stirred in a weight ratio and prepared in the form of a gel having a viscosity in the form shown in FIG. 1, it can be utilized to package a detergent composition in a gel form. Water-soluble resins include polyvinyl alcohol; Modified polyvinyl alcohol; Water-soluble natural polymers including guar gum, xanthan gum, carrageenan, and starch; Water-soluble polymer derivatives including ethoxylated starch and hydroxylpropylated starch; Copolymers thereof; And it may be selected from the group consisting of any combination thereof.
수용성 필름은 약 232 J/g 또는 그 미만의 용융열을 가지며, 0.2mm 두께일 때, 23 ℃에서 물에 30초 미만으로 용해되는 것을 특징으로 한다. The water-soluble film has a heat of fusion of about 232 J/g or less, and when it is 0.2 mm thick, it is characterized by being dissolved in water at 23° C. for less than 30 seconds.
소독형 캡슐은 제 1 코팅형 미산성 차아염소산수 캡슐, 제 2 코팅형 에탄올 캡슐로 이루어질 수 있으며, 소독형 캡슐 전체 함량에 대해서 1 : 2.5 내지 3.7 중량비로 이루어질 수 있다. The disinfecting capsule may be composed of a first coating type acidic hypochlorous acid capsule and a second coating type ethanol capsule, and may be formed in a weight ratio of 1: 2.5 to 3.7 based on the total content of the disinfection type capsule.
제 1 코팅형 미산성 차아염소산수 캡슐에서 사용되는 미산성 차아염소산수는 pH가 6.0 내지 6.7이면서 유효염소농도가 5 내지 7ppm인 것으로, 식품원료 및 식품의 살균용으로 사용이 가능할 정도로 인체에 전혀 무해하게 된다. 이러한 미산성 차아염소산수는 3 내지 7%의 식품첨가용 희석염산과 천일염 그리고 수돗물을 무격막 전해조에서 전기분해하여 획득할 수 있다. 미산성 차아염소산수는 에탄올의 함량을 낮추는 부작용으로 살균력이 떨어지는 단점을 보충하기 위해 추가됨으로써, 식중독균 곰팡이, 효모, 바이러스, 아포균, 각종 병원성 미생물 등을 살균 및 소독할 수 있는 살균 및 소독영역을 갖게 된다. The acidic hypochlorous acid used in the first coating type acidic hypochlorous acid capsule has a pH of 6.0 to 6.7 and an effective chlorine concentration of 5 to 7ppm, which is not at all sufficient for the human body to be used for sterilization of food ingredients and food. It becomes harmless. Such acidic hypochlorous acid water can be obtained by electrolyzing 3 to 7% of dilute hydrochloric acid for food additives, sun salt and tap water in a diaphragm electrolyzer. Micro-acidic hypochlorous acid water is added to compensate for the disadvantages of low sterilization power as a side effect of lowering the content of ethanol, thereby sterilizing and disinfecting areas that can sterilize and disinfect food poisoning fungi, yeast, viruses, apobacteria, and various pathogenic microorganisms. You have.
여기서, 본 발명에서 사용되는 미산성 차아염소산수는 pH가 6.0 내지 6.3인 약산성이지만, pH가 6.3 미만의 강산성인 경우 분자상 유효염소성분인 차아염소산이 염소로 휘발되면서 미산성 차아염소산수의 유효염소농도를 저하시켜 보관 안전성을 떨어뜨리고, 자극적인 염소향과 금속부식을 유발하게 되는 등의 문제가 있으며, pH가 6.3을 초과한 경우, 차아염소산이온의 생성이 많아질 뿐만 아니라, 세탁용 하이브리드 캡슐 세제 조성물이 중성 내지 약알칼리성(pH7 내지 9)로 제조됨에 있어서 산도조절제가 과량 투입됨으로써, 세탁물의 품질을 떨어지는 문제점이 발생할 수 있다. Here, the acidic hypochlorous acid used in the present invention is weakly acidic with a pH of 6.0 to 6.3, but when the pH is strongly acidic of less than 6.3, the hypochlorous acid, which is a molecularly effective chlorine component, volatilizes as chlorine, and is effective of the acidic hypochlorous acid water. There are problems such as lowering chlorine concentration, deteriorating storage safety, and causing irritating chlorine and metal corrosion. When the pH exceeds 6.3, hypochlorous acid ions are not only produced, but also hybrid for washing. In the case where the capsule detergent composition is manufactured to be neutral to weakly alkaline (pH7 to 9), an excessive amount of the acidity adjusting agent may be introduced, thereby causing a problem of deteriorating the quality of laundry.
또한, 본 발명에 따른 미산성 차아염소산수는 유효염소농도가 5 내지 7ppm이어야 하는데, 유효염소농도가 7ppm 미만인 경우 제 2 코팅형 에탄올 캡슐의 에탄올 함량에도 불구하고 세탁물에 유효한 살균 및 소독효과를 기대할 수 없게 되고, 유효염소농도가 7ppm을 초과하는 경우 제 2 코팅형 에탄올 캡슐의 에탄올 함량에 더하여 불필요하게 살균력이 크고 경제성이 현저히 떨어지는 등의 문제가 있다.In addition, the acidic hypochlorous acid water according to the present invention should have an effective chlorine concentration of 5 to 7 ppm, and if the effective chlorine concentration is less than 7 ppm, it is expected to have an effective sterilizing and disinfecting effect on laundry despite the ethanol content of the second coated ethanol capsule. When the effective chlorine concentration exceeds 7 ppm, there is a problem in that, in addition to the ethanol content of the second coated ethanol capsule, the sterilization power is unnecessarily large and the economic efficiency is significantly reduced.
본 발명에서 사용되는 액상조성액으로 사용되는 미산성 차아염소산수는 매우 불안정한 상태로, 직사광선 또는 공기에 노출되거나 바이러스 등에 감염될 경우 역반응이 일어나면서 안정화 상태인 물로 환원되는 문제가 있다.The acidic hypochlorous acid used as a liquid composition used in the present invention is in a very unstable state, and when exposed to direct sunlight or air or infected with a virus, there is a problem that it is reduced to water that is stabilized while a reverse reaction occurs.
따라서, 본 발명에서는 미산성 차아염소산수를 추가하는 세탁용 하이브리드 캡슐 세제 조성물의 제조과정에서 미산성 차아염소산수가 직사광선 또는 공기에 노출되거나 바이러스 등에 감염되지 않도록 제 1 코팅형 미산성 차아염소산수 캡슐로 세탁용 하이브리드 캡슐 세제 조성물을 제조하는 것이 바람직하다.Therefore, in the present invention, in the process of preparing a hybrid capsule detergent composition for washing with adding acidic hypochlorous acid, the first coating type acidic hypochlorous acid capsule is used to prevent the acidic hypochlorous acid from being exposed to direct sunlight, air, or viruses. It is preferred to prepare a hybrid capsule detergent composition for washing.
본 발명에서 사용되는 제 1 코팅형 미산성 차아염소산수 캡슐의 코팅제는 PLA(PolyLactic Acid) 옥수수 전분을 주원료로 한 PVAc(Polyvinyl Acetate), PVA(Polyvinyl Alcohol)를 첨가한 천연 식물계 원료로, 합성수지(PC, ABS 등)를 포함하지 않고 자연 조건 하에서 100% 분해될 수 있다. 또한, 다이옥신 등의 유해물질 발생 및 기타 환경오염을 방지할 수 있다. PLA(PolyLactic Acid)는 사출 및 압출플라스틱에 대한 대체가 가능하며, 범용적인 물적 특성을 가진 획기적 친환경 수지로 제품화가 가능하다. 한편, PLA는 결정성, 자연순환형, 생체적합, CO2 저감 등에 대한 특성을 갖으며, PLA는 식물계 원료로 제품의 자연적 분해가 가능한 친환경 소재이다.The coating agent of the first coating type acidic hypochlorous acid capsule used in the present invention is a natural plant-based raw material containing polyvinyl acetate (PVAc), polyvinyl alcohol (PVA) based on PLA (PolyLactic Acid) corn starch, and synthetic resin ( PC, ABS, etc.), and can be decomposed 100% under natural conditions. In addition, it is possible to prevent the generation of harmful substances such as dioxins and other environmental pollution. PLA (PolyLactic Acid) can be substituted for injection and extruded plastics, and it can be commercialized as an innovative eco-friendly resin with general-purpose physical properties. On the other hand, PLA has properties for crystallinity, natural circulation, biocompatibility, CO 2 reduction, etc. PLA is a plant-based raw material and is an eco-friendly material capable of natural decomposition of products.
본 발명에서 제 1 코팅형 미산성 차아염소산수 캡슐의 미산성 차아염소산수에 사용되는 코팅제를 생성하기 위한 PLA(PolyLactic Acid) 옥수수 전분을 주원료로 한 PVAc(Polyvinyl Acetate), PVA(Polyvinyl Alcohol)를 첨가한 천연 식물계 원료에는 나노 셀룰로오스 섬유가 추가될 수 있으며, 천연 식물계 원료와 나노 셀룰로오스 섬유의 중량비를 3.2 내지 3.5 : 1로 이루어지도록 혼합하여 캡슐 타입으로 제작하고, PLA(PolyLactic Acid), PVAc(Polyvinyl Acetate), PVA(Polyvinyl Alcohol) 간의 중량비는 1 : 0.1 내지 0.3 : 0.05 내지 0.07로 이루어지도록 형성된 뒤, 내부에 미산성 치아염소산수를 주입한 형태로 제 1 코팅형 미산성 차아염소산수 캡슐이 생성됨으로써, 세탁용 하이브리드 캡슐 세제 조성물이 세탁기 내에서 세탁물과의 마찰시 세탁용 하이브리드 캡슐 세제 조성물 내부의 제 1 코팅형 미산성 차아염소산수 캡슐의 코팅제가 찢어지면서 코팅제의 외부로 미산성 차아염소산수가 흘러서 세탁물에 대해서 에탄올과 함께 살균 효과를 제공할 수 있다.In the present invention, PVAc (Polyvinyl Acetate), PVA (Polyvinyl Alcohol) based on PLA (PolyLactic Acid) corn starch for producing a coating agent used for the acidic hypochlorous acid water of the first coating type acidic hypochlorous acid capsule Nano-cellulose fibers may be added to the added natural plant-based raw materials, and the weight ratio of the natural plant-based raw materials and nano-cellulose fibers is mixed in a ratio of 3.2 to 3.5:1 to produce a capsule type, and PLA (PolyLactic Acid), PVAc (Polyvinyl) Acetate), PVA (Polyvinyl Alcohol) weight ratio between 1: 0.1 to 0.3: 0.05 to 0.07 is formed, and then a first coating type of acidic hypochlorous acid capsule is produced by injecting acidic hypochlorous acid water inside. As a result, when the hybrid capsule detergent composition for laundry is rubbed with laundry in the washing machine, the coating agent of the first coating type acidic hypochlorous acid capsule inside the hybrid capsule detergent composition for washing is torn, and the acidic hypochlorous acid water flows out of the coating agent. It can provide a sterilizing effect with ethanol for laundry.
이러한 나노 셀룰로오스 섬유가 추가된 코팅제는 단순히 천연 식물계 원료만을 사용하여 제조된 코팅제에 비해 살균효과를 세탁물에 대해서 세탁기 내에서 오랫동안 유지함으로써, 살균효과를 증대시키는 역할을 수행할 수 있다. The coating agent to which the nano-cellulose fiber is added can serve to increase the sterilizing effect by maintaining the sterilizing effect in the washing machine for laundry for a long time compared to the coating agent prepared using only natural plant-based raw materials.
뿐만 아니라, 나노 셀룰로오스 섬유가 첨가된 코팅제는 나노 셀룰로오스 섬유가 높은 비표면적과 비강도 및 낮은 밀도를 가지고 있어 천연 식물계 원료에 보강 기능에 해당하는 우수한 물성을 나타낼 뿐만 아니라, 극소량만으로도 열적 및 기계적 특성이 우수한 복합체를 얻을 수 있고, 친환경성 및 경량특성을 제공할 수 있다. In addition, the coating material containing nano-cellulose fibers has high specific surface area, specific strength, and low density, so it exhibits excellent physical properties corresponding to reinforcing functions in natural plant-based raw materials, and has only a small amount of thermal and mechanical properties. It is possible to obtain an excellent composite, and can provide eco-friendly and lightweight properties.
즉, 제 1 코팅형 미산성 차아염소산수 캡슐의 코팅제는 마이크로캡슐 형태로 제조되어 내부에 미산성 차아염소산수를 내부에 포집하여 함유할 수 있으며, 제 1 코팅형 미산성 차아염소산수 캡슐에 사용되는 코팅제는 미산성 차아염소산수 100 중량부를 기준으로 12 내지 15 중량부를 이룰 수 있으며, 여기서 12 중량부 미만인 경우 내부의 미산성 차아염소산수가 상온(25℃)에서 임계시간(30초 내지 45초) 사이에서 자동적으로 새어 나오는 문제점이 발생하며, 15 중량부를 초과하는 경우 입자(캡슐) 과량에 따른 점도 상승, 탁도 또는 침전물이 나타나는 현상을 발생시킬 수 있다. That is, the coating agent of the first coating-type micro-acidic hypochlorous acid capsule is manufactured in the form of a microcapsule, and may contain and contain micro-acidic hypochlorous acid therein, and is used for the first coating-type micro-acidic hypochlorous acid capsule. The coating agent to be formed can achieve 12 to 15 parts by weight based on 100 parts by weight of the acidic hypochlorous acid, wherein when it is less than 12 parts by weight, the internal acidic hypochlorous acid water has a critical time at room temperature (25°C) (30 seconds to 45 seconds) There is a problem that leaks out automatically, and when it exceeds 15 parts by weight, a viscosity increase, turbidity, or sediment may occur due to particle (capsule) excess.
제 2 코팅형 에탄올 캡슐은 에탄올의 농도는 75 내지 90%(v/v), 보다 바람직하게는 82.5%(v/v)일 수 있다. 에탄올은 식용의 곡물발효주정일 수 있다. 에탄올은 단백질 응고 작용 및 세포의 지질층 제거효과 있을 뿐만 아니라, 술의 성분으로서 식용으로 섭취가 가능하며, 섭취하더라도 체내에서 아세트알데히드를 거쳐 최종적으로 이산화탄소로 산화되므로 인체에 무해하며, 세탁용 하이브리드 캡슐 세제 조성물은 인체에 무해한 에탄올을 함유함으로써 세균에 대한 살균 효과를 제공할 수 있다. The second coated ethanol capsule may have an ethanol concentration of 75 to 90% (v/v), more preferably 82.5% (v/v). Ethanol may be an edible grain fermentation spirit. Ethanol not only has the effect of protein coagulation and removal of lipid layers from cells, but can be consumed for food as a component of alcohol, and even if consumed, it is harmless to the human body since it is finally oxidized to carbon dioxide through acetaldehyde in the body. The composition can provide a bactericidal effect against bacteria by containing ethanol, which is harmless to the human body.
에탄올은 우수한 살균 효과에도 불구하고 조성물 내에 과량 포함될 때 세탁물에 대한 과도한 자극성을 유발할 수 있는 반면, 미리 설정된 함량 이하로 함유될 때 살균 효과가 충분히 구현되지 않을 수 있으므로, 본 발명에서의 세탁용 하이브리드 캡슐 세제 조성물은 살균효과를 높이기 위해 보조 살균제로 제 1 코팅형 미산성 차아염소산수 캡슐 내의 미산성 차아염소산수를 추가로 활용하되, 제 1 코팅형 미산성 차아염소산수 캡슐 1 중량부에 대해서 제 2 코팅형 에탄올 캡슐을 2.5 내지 3.7 중량부를 첨가함으로써, 에탄올의 함량을 저감하면서도 미산성 차아염소산수에 의하 보조 살균효과를 얻을 수 있다.Ethanol may cause excessive irritation to laundry when excessively contained in the composition despite excellent sterilizing effect, whereas when it is contained below a predetermined content, the sterilizing effect may not be sufficiently implemented, so the hybrid capsule for washing in the present invention The detergent composition additionally utilizes the acidic hypochlorous acid water in the first coating-type acidic hypochlorous acid capsule as an auxiliary disinfecting agent to increase the sterilizing effect, but is second to 1 part by weight of the first coating-type acidic hypochlorous acid capsule By adding 2.5 to 3.7 parts by weight of the coated ethanol capsule, it is possible to obtain an auxiliary sterilization effect by the acidic hypochlorous acid water while reducing the content of ethanol.
제 2 코팅형 에탄올 캡슐의 코팅제는 PLA(PolyLactic Acid) 옥수수 전분을 주원료로 한 PVAc(Polyvinyl Acetate), PVA(Polyvinyl Alcohol)를 첨가한 천연 식물계 원료와 나노 셀룰로오스 섬유의 중량비를 2.8 내지 2.9 : 1로 이루어지도록 혼합하여 캡슐 타입으로 제작하고, PLA(PolyLactic Acid), PVAc(Polyvinyl Acetate), PVA(Polyvinyl Alcohol) 간의 중량비는 1 : 0.4 내지 0.5 : 0.07 내지 0.09로 이루어지도록 형성된 뒤, 내부에 에탄올을 주입한 형태로 제 2 코팅형 에탄올 캡슐이 생성됨으로써, 세탁용 하이브리드 캡슐 세제 조성물이 세탁기 내에서 세탁물과의 마찰시 세탁용 하이브리드 캡슐 세제 조성물 내부의 제 2 코팅형 에탄올 캡슐의 코팅제가 찢어지면서 코팅제의 외부로 에탄올이 소량 흘러서 세탁물에 대해서 미산성 차아염소산수과 함께 살균 효과를 제공할 수 있다.The coating agent of the second coated ethanol capsule has a weight ratio of 2.8 to 2.9:1 of the natural plant-based raw material added with PVAC (Polyvinyl Acetate) and PVA (Polyvinyl Alcohol) based on PLA (PolyLactic Acid) corn starch as the main raw material. The mixture is made to be made into a capsule type, and the weight ratio between PLA (PolyLactic Acid), PVAc (Polyvinyl Acetate), and PVA (Polyvinyl Alcohol) is formed to be 1: 0.4 to 0.5: 0.07 to 0.09, and ethanol is injected into the inside. The second coating-type ethanol capsule is produced in one form, and when the laundry hybrid capsule detergent composition is rubbed with laundry in the washing machine, the coating agent of the second coating-type ethanol capsule inside the laundry hybrid capsule detergent composition is torn and the outside of the coating agent As a small amount of ethanol flows into the laundry, it can provide a sterilizing effect together with the acidic hypochlorous acid water.
상술한 세탁용 하이브리드 캡슐 세제 조성물은 도 2와 같이 700ml 총 50개입으로 제조되며, 중성 내지 약알칼리성(pH7 내지 9)으로 제공되는 것이 바람직하며, 강력하고 깨긋한 세척 효과외에 살균효과, 그리고 무형광, 무색소에 피부자극이 기준치 이하일 수 있다. The above-described hybrid capsule detergent composition for washing is prepared with a total of 50 pieces of 700 ml as shown in FIG. 2, and is preferably provided with neutral to weak alkali (pH7 to 9), sterilizing effect in addition to strong and clean washing effect, and non-fluorescent, The skin irritation may be colorless or below the standard value.
한편, 계면활성제, 안정화제, 효소, 산도조절제, 수용성 필름제, 정제수, 그리고 소독형 캡슐을 31 : 3 : 0.3 : 1 : 10 : 22 : 2의 중량비로 형성하는 제 1 실시예, 그리고, 계면활성제, 안정화제, 효소, 산도조절제, 수용성 필름제, 정제수, 그리고 소독형 캡슐 중 제 1 코팅형 미산성 차아염소산수 캡슐만을 31 : 3 : 0.3 : 1 : 10 : 22 : 1의 중량비로 형성하는 제 2 실시예, 계면활성제, 안정화제, 효소, 산도조절제, 수용성 필름제, 정제수, 그리고 소독형 캡슐 중 제 2 코팅형 에탄올 캡슐만을 31 : 3 : 0.3 : 1 : 10 : 22 : 1의 중량비로 형성하는 제 3 실시예에 대해서 하기와 같은 방법으로 세정력 시험을 실시하였다.On the other hand, the first embodiment to form a surfactant, stabilizer, enzyme, acidity regulator, water-soluble film agent, purified water, and disinfectable capsules in a weight ratio of 31: 3: 0.3: 1: 10: 22: 2, and the interface Activators, stabilizers, enzymes, acidity regulators, water-soluble film agents, purified water, and only the first coated type of non-acidic hypochlorous acid capsules formed in a weight ratio of 31: 3: 0.3: 1: 10: 22: 1 In the second embodiment, surfactant, stabilizer, enzyme, acidity regulator, water-soluble film, purified water, and only the second coated ethanol capsule among the sterilized capsules in a weight ratio of 31:3:0.3:1:1:10:22:1 For the third example to be formed, a cleaning power test was conducted in the following manner.
세정력 평가는 오염포로 인공오염포(JIS,), AS-10, WFK-10D, WFK-20D의 4종에 대해, 세제 농도가 1g/L인 세탁수를 넣은 세척기기를 이용하여, 상온(15±2℃)에서 교반속도 200±5 rpm로 세척함으로써 수행되었다. 8분 동안 세척하고, 3분간 2회 헹구었다. 세척력 평가를 위해, 색차계를 이용하여 세탁 전·후, 오염포의 반사율을 측정하여 값을 구했으며, 하기의 표 1에 나타내었다. 반사율이 높을수록 우수한 세정력을 의미한다.For the evaluation of the cleaning power, using 4 kinds of artificial pollutants (JIS,), AS-10, WFK-10D, and WFK-20D as contaminated fabrics, using a washing machine with washing water with a detergent concentration of 1 g/L, room temperature (15± 2°C) at a stirring rate of 200±5 rpm. Wash for 8 minutes and rinse twice for 3 minutes. For evaluating the cleaning power, values were obtained by measuring the reflectance of contaminated fabric before and after washing using a colorimeter, and are shown in Table 1 below. The higher the reflectance, the better the cleaning power.
한편, 상술한 제 1 내지 제 3 실시예에 해당하는 세탁용 하이브리드 캡슐 세제 조성물의 살균 효과에 대한 실험을 위해서 채취된 세균을 450g의 면 세탁물에 대해서 5g씩 도말 후 세제 농도가 1g/L인 세탁수를 넣은 세척기기를 이용하여, 상온(15±2℃)에서 교반속도 200±5 rpm로 세척함으로써 수행되었다. 8분 동안 세척하고, 3분간 2회 헹군 뒤, 세탁물에 대해서 각각의 세균 군집 수를 측정하였다. 살균소독제의 살균 효과 비교평가 결과는 하기의 표 2 내지 표 5와 나타났으며, 평가기준으로 "-"는 없음, "+"는 적음, "++"는 보통임, "+++"는 많음으로 표시하였다.On the other hand, for the experiment on the sterilizing effect of the hybrid capsule detergent composition for washing corresponding to the above-described first to third embodiments, wash the bacteria collected after 5 g for 450 g of cotton laundry, and the detergent concentration is 1 g/L. It was carried out by washing at room temperature (15±2° C.) with a stirring speed of 200±5 rpm using a washing machine with water. After washing for 8 minutes, rinsing twice for 3 minutes, the number of each bacterial community was measured for the laundry. The results of the comparative evaluation of the disinfecting effect of the disinfectant disinfectant are shown in Tables 2 to 5 below. It was marked as plentiful.
여기서 A 세균은 Vibrio Comma Inaba를 사용하며, B 세균은 Typhoid bacillus을 사용하였으며, 표 2 내지 표 4와 같이 제 1 실시예에 따른 세탁용 하이브리드 캡슐 세제 조성물이 세균에 대한 살균 효과가 좋고 오래 지속됨을 알 수 있었다. Here, the bacteria A used Vibrio Comma Inaba, and the bacteria B used Typhoid bacillus, as shown in Tables 2 to 4, the hybrid capsule detergent composition for washing according to the first embodiment has good sterilization effect on bacteria and has a long lasting effect. Could know.
이상과 같이, 본 명세서와 도면에는 본 발명의 바람직한 실시예에 대하여 개시하였으며, 비록 특정 용어들이 사용되었으나, 이는 단지 본 발명의 기술 내용을 쉽게 설명하고 발명의 이해를 돕기 위한 일반적인 의미에서 사용된 것이지, 본 발명의 범위를 한정하고자 하는 것은 아니다. 여기에 개시된 실시예 외에도 본 발명의 기술적 사상에 바탕을 둔 다른 변형 예들이 실시 가능하다는 것은 본 발명이 속하는 기술 분야에서 통상의 지식을 가진 자에게 자명한 것이다.As described above, in the present specification and drawings, preferred embodiments of the present invention have been disclosed, and although specific terms are used, they are merely used in a general sense to easily describe the technical contents of the present invention and to help understand the invention. , It is not intended to limit the scope of the present invention. It is apparent to those skilled in the art to which the present invention pertains that other modified examples based on the technical idea of the present invention can be implemented in addition to the embodiments disclosed herein.
Claims (2)
상기 계면활성제는,
제 1 비이온 계면활성제(비이온 알코올계), 음이온 계면활성제(음이온 알코올계), 제 2 비이온 계면활성제(비이온 지방산계)가 전체 계면활성제 내에서 2.5 내지 3 : 2.3 내지 2.7 : 1.2 내지 1.5 중량비로 형성되며,
상기 안정화제는,
포스파이트, 포스포나이트, 아민계 산화방지제, 히드록실아민, 벤조퓨란-2-온, 티오시너지스트, 가소제, 산 스캐빈저, 활택제, 분산 조제, 입체 장애 아민, UV 흡수제 및 입체장애 페놀로 이루어진 군에서 선택된 하나 이상을 첨가하고,
상기 효소는, 단백질분해효소로, 카텝신(cathepsin)류 효소, MMP(matrix metalloproteinase)류 효소, 카스파아제(caspase)류 효소, 세크레타아제(secretase)류 효소, 유로키나제(urokinase), HIV-1 단백분해효소(HIV-1 protease), HSV-1 단백분해효소(HSV-1 protease), TEV 단백질분해효소(TEV protease), PSA(Prostate Specific Antigen), 탄저 치사 인자 엔도펩티다아제(Anthrax lethal factor endopeptidase) 및 트롬빈(thrombin)으로 구성된 군에서 선택되는 어느 하나인 것을 사용하며,
상기 산도조절제는,
세탁물의 유지얼룩을 제거와, 중성 내지 약알칼리성을 제공하는 유기화합물로,
모노에탄올아민, 디에탄올아민, 트리에탄올아민, 소듐하이드록사이드, 포타슘 하이드록사이드의 액상의 알칼리제 및 구연산, 사과산, 살리실산, 주석산, 젖산, 아세트산, 소르브산, 벤조인산에서 적어도 하나 이상에 해당하는 제 1 산도조절제와, 메틸에탄올아민, 에틸에탄올아민, N-아미노-N-프로판올, 메틸아민, 디메틸아민, 트리메틸아민, 에틸아민, 디에틸아민, 트리에틸아민, 에틸렌디아민, 모노에탄올아민, N-(β-아미노에틸)에탄올아민, 헥사메틸렌디아민, 디에틸렌트리아민, 트리에틸렌테트라민, 테트라에틸렌펜타민, 무수 피페라진, 피페라진 육수화물, 1-(2-아미노에틸)피페라진 및 N-메틸피페라진, 암모니아, 수산화테트라메틸암모늄, 수산화테트라에틸암모늄, 탄산수소암모늄, 탄산암모늄, 탄산수소칼륨, 탄산칼륨, 탄산수소나트륨, 탄산나트륨, 암모니아, 수산화칼륨, 수산화나트륨, 수산화테트라메틸암모늄, 수산화테트라에틸암모늄, 탄산수소암모늄, 탄산암모늄, 탄산수소칼륨, 탄산칼륨, 탄산수소나트륨 및 탄산나트륨으로 이루어진 군에서 선택되는 적어도 하나 이상에 해당하는 제 2 산도 조절제를 중량비 1 : 1.2 내지 1.5로 혼합하여 사용하며
상기 수용성 필름제는,
수용성 수지와 탄소 섬유를 중량비 10 내지 12 : 1의 함량으로 형성한 투명형의 필름을 제조하여 계면활성제, 안정화제, 효소, 산도조절제, 정제수, 그리고 소독형 캡슐이 미리 설정된 중량비로 교반되어 점도를 갖는 겔(gel) 형으로 제조된 뒤, 겔 형태의 세제 조성물을 포장하는데 활용하며, 수용성 수지로 폴리비닐 알코올; 변형된 폴리비닐 알코올; 구아 검, 잔탄 검, 카라기난, 및 전분을 포함하는 수용해성 천연 고분자; 에톡실화 전분 및 하이드록실프로필화 전분을 포함하는 수용해성 고분자 유도체; 이들의 공중합체; 및 이들의 조합으로 이루어진 군으로부터 선택된 것이며, 수용성 필름은 232 J/g의 용융열을 가지며, 0.2mm 두께일 때, 23 ℃에서 물에 30초 미만으로 용해되며,
소독형 캡슐은, 제 1 코팅형 미산성 차아염소산수 캡슐, 제 2 코팅형 에탄올 캡슐로 이루어지며, 소독형 캡슐 전체 함량에 대해서 1 : 2.5 내지 3.7 중량비로 이루어지며,
제 1 코팅형 미산성 차아염소산수 캡슐에서 사용되는 미산성 차아염소산수는 pH가 6.0 내지 6.7이면서 유효염소농도가 5 내지 7ppm인 것으로 3 내지 7%의 식품첨가용 희석염산과 천일염 그리고 수돗물을 무격막 전해조에서 전기분해하여 획득한 것을 사용하며, 제 1 코팅형 미산성 차아염소산수 캡슐의 코팅제는 PLA(PolyLactic Acid) 옥수수 전분을 주원료로 한 PVAc(Polyvinyl Acetate), PVA(Polyvinyl Alcohol)을 첨가한 천연 식물계 원료로, PLA(PolyLactic Acid) 옥수수 전분을 주원료로 한 PVAc(Polyvinyl Acetate), PVA(Polyvinyl Alcohol)을 첨가한 천연 식물계 원료에는 나노 셀룰로오스 섬유가 추가되며, 천연 식물계 원료와 나노 셀룰로오스 섬유의 중량비를 3.2 내지 3.5 : 1로 이루어지도록 혼합하여 캡슐 타입으로 제작하고, PLA(PolyLactic Acid), PVAc(Polyvinyl Acetate), PVA(Polyvinyl Alcohol) 간의 중량비는 1 : 0.1 내지 0.3 : 0.05 내지 0.07로 이루어지도록 형성된 뒤, 내부에 미산성 치아염소산수를 주입한 형태로 제 1 코팅형 미산성 차아염소산수 캡슐이 생성됨으로써, 세탁용 하이브리드 캡슐 세제 조성물이 세탁기 내에서 세탁물과의 마찰시 세탁용 하이브리드 캡슐 세제 조성물 내부의 제 1 코팅형 미산성 차아염소산수 캡슐의 코팅제가 찢어지면서 코팅제의 외부로 미산성 차아염소산수가 흘러서 세탁물에 대해서 에탄올과 함께 살균 효과를 제공하며, 제 1 코팅형 미산성 차아염소산수 캡슐에 사용되는 코팅제는 미산성 차아염소산수 100 중량부를 기준으로 12 내지 15 중량부로 이루어지며,
제 2 코팅형 에탄올 캡슐은, 에탄올의 농도는 75 내지 90%(v/v)로 에탄올은 식용의 곡물발효주정으로, 제 1 코팅형 미산성 차아염소산수 캡슐 1 중량부 기준으로 제 2 코팅형 에탄올 캡슐을 2.5 내지 3.7 중량부를 첨가함으로써, 에탄올의 함량을 저감하면서도 미산성 차아염소산수에 의하 보조 살균효과를 얻으며, 제 2 코팅형 에탄올 캡슐의 코팅제는 PLA(PolyLactic Acid) 옥수수 전분을 주원료로 한 PVAc(Polyvinyl Acetate), PVA(Polyvinyl Alcohol)을 첨가한 천연 식물계 원료와 나노 셀룰로오스 섬유의 중량비를 2.8 내지 2.9 : 1로 이루어지도록 혼합하여 캡슐 타입으로 제작하고, PLA(PolyLactic Acid), PVAc(Polyvinyl Acetate), PVA(Polyvinyl Alcohol) 간의 중량비는 1 : 0.4 내지 0.5 : 0.07 내지 0.09로 이루어지도록 형성된 뒤, 내부에 에탄올을 주입한 형태로 제 2 코팅형 에탄올 캡슐이 생성됨으로써, 세탁용 하이브리드 캡슐 세제 조성물이 세탁기 내에서 세탁물과의 마찰시 세탁용 하이브리드 캡슐 세제 조성물 내부의 제 2 코팅형 에탄올 캡슐의 코팅제가 찢어지면서 코팅제의 외부로 에탄올이 흘러서 세탁물에 대해서 미산성 차아염소산수과 함께 살균 효과를 제공하며,
세탁용 하이브리드 캡슐 세제 조성물은 중성 내지 약알칼리성(pH7 내지 9)으로 제공되는 것을 특징으로 하는 세탁용 하이브리드 캡슐 세제 조성물.
Surfactants, stabilizers, enzymes, acidity regulators, water-soluble film agents, purified water, disinfectable capsules 30 to 35: 3 to 4: 0.2 to 0.7: 1 to 2: 10 to 20: 20 to 25: 1 to 3 in advance In the hybrid capsule detergent composition for washing, which is formed at a set weight ratio, thereby simultaneously providing a function as a detergent as well as a sterilizing effect on laundry,
The surfactant,
The first nonionic surfactant (nonionic alcohol-based), anionic surfactant (anionic alcohol-based), and second nonionic surfactant (nonionic fatty acid-based) are 2.5 to 3: 2.3 to 2.7: 1.2 to 1.2 in total surfactant. It is formed in a 1.5 weight ratio,
The stabilizer,
Phosphite, phosphonite, amine antioxidant, hydroxylamine, benzofuran-2-one, thiosynergist, plasticizer, acid scavenger, lubricant, dispersion aid, steric hindered amine, UV absorber and hindered phenol Add one or more selected from the group consisting of,
The enzyme is a protease, cathepsin-like enzyme, matrix metalloproteinase (MMP)-like enzyme, caspase-like enzyme, secretase-like enzyme, eurokinase, HIV-1 Protease (HIV-1 protease), HSV-1 protease, TEV protease, PSA (Prostate Specific Antigen), Anthrax lethal factor endopeptidase And thrombin (thrombin) is selected from the group consisting of one used,
The acidity regulator,
It is an organic compound that removes maintenance stains from laundry and provides neutral to weak alkalinity.
Liquid alkali agents of monoethanolamine, diethanolamine, triethanolamine, sodium hydroxide, and potassium hydroxide and at least one of citric acid, malic acid, salicylic acid, tartaric acid, lactic acid, acetic acid, sorbic acid, and benzoic acid 1 Acidity regulator, methylethanolamine, ethylethanolamine, N-amino-N-propanol, methylamine, dimethylamine, trimethylamine, ethylamine, diethylamine, triethylamine, ethylenediamine, monoethanolamine, N- (β-aminoethyl)ethanolamine, hexamethylenediamine, diethylenetriamine, triethylenetetramine, tetraethylenepentamine, piperazine anhydride, piperazine hexahydrate, 1-(2-aminoethyl)piperazine and N- Methylpiperazine, ammonia, tetramethylammonium hydroxide, tetraethylammonium hydroxide, ammonium hydrogen carbonate, ammonium carbonate, potassium hydrogen carbonate, potassium carbonate, sodium hydrogen carbonate, sodium carbonate, ammonia, potassium hydroxide, sodium hydroxide, tetramethylammonium hydroxide, hydroxide Tetraethylammonium, ammonium hydrogen carbonate, ammonium carbonate, potassium hydrogen carbonate, potassium carbonate, sodium hydrogen carbonate and a second acidity adjusting agent corresponding to at least one selected from the group consisting of sodium carbonate is used by mixing in a weight ratio of 1: 1.2 to 1.5 And
The water-soluble film agent,
To prepare a transparent film formed of water-soluble resin and carbon fiber in a weight ratio of 10 to 12:1, surfactant, stabilizer, enzyme, acidity regulator, purified water, and sterilized capsules are stirred at a preset weight ratio to increase viscosity. After having a gel (gel) type having, it is used to package the detergent composition in the form of a gel, polyvinyl alcohol as a water-soluble resin; Modified polyvinyl alcohol; Water-soluble natural polymers including guar gum, xanthan gum, carrageenan, and starch; Water-soluble polymer derivatives including ethoxylated starch and hydroxylpropylated starch; Copolymers thereof; And combinations thereof, and the water-soluble film has a heat of fusion of 232 J/g and, when 0.2 mm thick, dissolves in water at 23° C. for less than 30 seconds,
The disinfecting capsule is composed of a first coating type of acidic hypochlorous acid capsule and a second coating type of ethanol capsule, and is made in a weight ratio of 1: 2.5 to 3.7 with respect to the total content of the disinfection type capsule,
The acidic hypochlorous acid used in the first coating-type acidic hypochlorous acid capsule has a pH of 6.0 to 6.7 and an effective chlorine concentration of 5 to 7 ppm, and 3 to 7% of dilute hydrochloric acid for food addition, sun salt and tap water are not used. It is obtained by electrolysis in a diaphragm electrolyzer, and the coating agent of the first coating-type micro-acidic hypochlorous acid capsule is added with PVAc (Polyvinyl Acetate) and PVA (Polyvinyl Alcohol) based on PLA (PolyLactic Acid) corn starch. As a natural plant-based raw material, PLA (PolyLactic Acid) corn starch as a main raw material, PVAc (Polyvinyl Acetate), PVA (Polyvinyl Alcohol) is added to the natural plant-based raw material, and nanocellulose fiber is added, and the weight ratio of the natural plant-based raw material and nanocellulose fiber The mixture was made to form a capsule type of 3.2 to 3.5:1, and the weight ratio between PLA (PolyLactic Acid), PVAc (Polyvinyl Acetate), and PVA (Polyvinyl Alcohol) was formed to be 1: 0.1 to 0.3: 0.05 to 0.07. Afterwards, the first coated type of acidic hypochlorous acid capsule is produced in the form of injecting the acidic hypochlorous acid inside, whereby the hybrid capsule detergent composition for washing is inside the hybrid capsule detergent composition for washing when rubbing with laundry in the washing machine As the coating agent of the first coating type of acidic hypochlorous acid capsule is torn, the acidic hypochlorous acid water flows to the outside of the coating agent to provide sterilization effect with ethanol for laundry, and is used for the first coating type of acidic hypochlorous acid capsule The coating agent is made of 12 to 15 parts by weight based on 100 parts by weight of the acidic hypochlorous acid,
The second coating-type ethanol capsule has an ethanol concentration of 75 to 90% (v/v), and ethanol is an edible grain fermentation alcohol. By adding 2.5 to 3.7 parts by weight of the ethanol capsule, while reducing the content of ethanol, while obtaining a secondary sterilization effect by the acidic hypochlorous acid, the coating agent of the second coating type ethanol capsule is PLA (PolyLactic Acid) corn starch as the main raw material The weight ratio of natural plant-based raw materials added with PVAc (Polyvinyl Acetate) and PVA (Polyvinyl Alcohol) and nano-cellulose fibers is mixed in a ratio of 2.8 to 2.9:1 to produce a capsule type, PLA (PolyLactic Acid), PVAc (Polyvinyl Acetate) ), the weight ratio between PVA (Polyvinyl Alcohol) is 1: 0.4 to 0.5: 0.07 to 0.09 is formed, and then a second coated ethanol capsule is produced in the form of injecting ethanol into the laundry detergent capsule composition. When rubbing with laundry in the washing machine, the coating agent of the second coating type ethanol capsule inside the laundry hybrid capsule detergent composition is torn, and ethanol flows out of the coating agent to provide laundry with antimicrobial hypochlorous acid water and provides a sterilizing effect.
The hybrid capsule detergent composition for washing is a hybrid capsule detergent composition for washing, characterized in that it is provided with a neutral to weak alkalinity (pH7 to 9).
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Cited By (2)
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| KR20240003665A (en) | 2022-07-01 | 2024-01-09 | 이기호 | Silicone insole using the action of non-polar rubber and non-polar material |
| CN117660125A (en) * | 2023-10-20 | 2024-03-08 | 广东星帮尼科技股份有限公司 | Quaternary ammonium salt clothes cleaning disinfectant and preparation method thereof |
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