KR102036879B1 - A Eco-friendly Waterproofing Treatment Composition for Road and Waterproofing Methods using Thereof - Google Patents
A Eco-friendly Waterproofing Treatment Composition for Road and Waterproofing Methods using Thereof Download PDFInfo
- Publication number
- KR102036879B1 KR102036879B1 KR1020190089084A KR20190089084A KR102036879B1 KR 102036879 B1 KR102036879 B1 KR 102036879B1 KR 1020190089084 A KR1020190089084 A KR 1020190089084A KR 20190089084 A KR20190089084 A KR 20190089084A KR 102036879 B1 KR102036879 B1 KR 102036879B1
- Authority
- KR
- South Korea
- Prior art keywords
- parts
- weight
- asphalt
- waterproofing
- weight based
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 158
- 238000004078 waterproofing Methods 0.000 title claims abstract description 116
- 238000000034 method Methods 0.000 title claims abstract description 60
- 239000010426 asphalt Substances 0.000 claims abstract description 153
- 229920005989 resin Polymers 0.000 claims abstract description 39
- 239000011347 resin Substances 0.000 claims abstract description 39
- 239000003208 petroleum Substances 0.000 claims abstract description 32
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 23
- 239000002245 particle Substances 0.000 claims abstract description 23
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 22
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims abstract description 17
- FACXGONDLDSNOE-UHFFFAOYSA-N buta-1,3-diene;styrene Chemical compound C=CC=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 FACXGONDLDSNOE-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 12
- 239000000835 fiber Substances 0.000 claims abstract description 12
- JYCQQPHGFMYQCF-UHFFFAOYSA-N 4-tert-Octylphenol monoethoxylate Chemical compound CC(C)(C)CC(C)(C)C1=CC=C(OCCO)C=C1 JYCQQPHGFMYQCF-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 11
- 229920002113 octoxynol Polymers 0.000 claims abstract description 11
- 239000012874 anionic emulsifier Substances 0.000 claims abstract description 10
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 10
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 claims abstract description 10
- 239000011248 coating agent Substances 0.000 claims abstract description 8
- 238000004132 cross linking Methods 0.000 claims description 82
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 21
- 239000002987 primer (paints) Substances 0.000 claims description 18
- 238000004806 packaging method and process Methods 0.000 claims description 14
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 claims description 12
- 238000010276 construction Methods 0.000 claims description 12
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 11
- 238000002156 mixing Methods 0.000 claims description 11
- -1 Sulfoxy Chemical group 0.000 claims description 10
- 239000002318 adhesion promoter Substances 0.000 claims description 8
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 8
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 claims description 8
- 238000004381 surface treatment Methods 0.000 claims description 8
- 238000002844 melting Methods 0.000 claims description 7
- 230000008018 melting Effects 0.000 claims description 7
- 238000000576 coating method Methods 0.000 claims description 6
- 229910052622 kaolinite Inorganic materials 0.000 claims description 6
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 claims description 5
- FBPFZTCFMRRESA-FSIIMWSLSA-N L-glucitol Chemical compound OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 5
- 125000001931 aliphatic group Chemical group 0.000 claims description 5
- ONCZQWJXONKSMM-UHFFFAOYSA-N dialuminum;disodium;oxygen(2-);silicon(4+);hydrate Chemical compound O.[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Na+].[Na+].[Al+3].[Al+3].[Si+4].[Si+4].[Si+4].[Si+4] ONCZQWJXONKSMM-UHFFFAOYSA-N 0.000 claims description 5
- 239000000395 magnesium oxide Substances 0.000 claims description 5
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 5
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 5
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 claims description 5
- 239000003415 peat Substances 0.000 claims description 5
- 229940080314 sodium bentonite Drugs 0.000 claims description 5
- 229910000280 sodium bentonite Inorganic materials 0.000 claims description 5
- 239000010456 wollastonite Substances 0.000 claims description 5
- 229910052882 wollastonite Inorganic materials 0.000 claims description 5
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 4
- 239000005711 Benzoic acid Substances 0.000 claims description 4
- 239000002033 PVDF binder Substances 0.000 claims description 4
- 239000000908 ammonium hydroxide Substances 0.000 claims description 4
- 235000010233 benzoic acid Nutrition 0.000 claims description 4
- 229920006217 cellulose acetate butyrate Polymers 0.000 claims description 4
- DLNKOYKMWOXYQA-UHFFFAOYSA-N dl-pseudophenylpropanolamine Natural products CC(N)C(O)C1=CC=CC=C1 DLNKOYKMWOXYQA-UHFFFAOYSA-N 0.000 claims description 4
- 239000003112 inhibitor Substances 0.000 claims description 4
- RAFRTSDUWORDLA-UHFFFAOYSA-N phenyl 3-chloropropanoate Chemical compound ClCCC(=O)OC1=CC=CC=C1 RAFRTSDUWORDLA-UHFFFAOYSA-N 0.000 claims description 4
- DLNKOYKMWOXYQA-APPZFPTMSA-N phenylpropanolamine Chemical compound C[C@@H](N)[C@H](O)C1=CC=CC=C1 DLNKOYKMWOXYQA-APPZFPTMSA-N 0.000 claims description 4
- 229960000395 phenylpropanolamine Drugs 0.000 claims description 4
- 229920002981 polyvinylidene fluoride Polymers 0.000 claims description 4
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims description 4
- 235000019982 sodium hexametaphosphate Nutrition 0.000 claims description 4
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims description 4
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims description 4
- ATVJXMYDOSMEPO-UHFFFAOYSA-N 3-prop-2-enoxyprop-1-ene Chemical compound C=CCOCC=C ATVJXMYDOSMEPO-UHFFFAOYSA-N 0.000 claims description 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 3
- 229940044175 cobalt sulfate Drugs 0.000 claims description 3
- 229910000361 cobalt sulfate Inorganic materials 0.000 claims description 3
- KTVIXTQDYHMGHF-UHFFFAOYSA-L cobalt(2+) sulfate Chemical compound [Co+2].[O-]S([O-])(=O)=O KTVIXTQDYHMGHF-UHFFFAOYSA-L 0.000 claims description 3
- GCYHRYNSUGLLMA-UHFFFAOYSA-N 2-prop-2-enoxyethanol Chemical compound OCCOCC=C GCYHRYNSUGLLMA-UHFFFAOYSA-N 0.000 claims 1
- 239000002202 Polyethylene glycol Substances 0.000 claims 1
- 239000008199 coating composition Substances 0.000 claims 1
- 229910017052 cobalt Inorganic materials 0.000 claims 1
- 239000010941 cobalt Substances 0.000 claims 1
- 229920001223 polyethylene glycol Polymers 0.000 claims 1
- 239000004567 concrete Substances 0.000 abstract description 23
- 230000035515 penetration Effects 0.000 abstract description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 8
- 239000011148 porous material Substances 0.000 abstract description 6
- 239000003623 enhancer Substances 0.000 abstract description 2
- 230000001681 protective effect Effects 0.000 abstract description 2
- 230000035939 shock Effects 0.000 abstract 1
- 241000220259 Raphanus Species 0.000 description 43
- 235000006140 Raphanus sativus var sativus Nutrition 0.000 description 43
- 239000010410 layer Substances 0.000 description 38
- 239000000463 material Substances 0.000 description 11
- 229940102838 methylmethacrylate Drugs 0.000 description 10
- 230000000694 effects Effects 0.000 description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
- 239000000853 adhesive Substances 0.000 description 7
- 230000001070 adhesive effect Effects 0.000 description 7
- 239000000843 powder Substances 0.000 description 6
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 description 6
- 229920003002 synthetic resin Polymers 0.000 description 6
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 5
- 239000005995 Aluminium silicate Substances 0.000 description 5
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 5
- 235000012211 aluminium silicate Nutrition 0.000 description 5
- 239000003431 cross linking reagent Substances 0.000 description 5
- 238000001035 drying Methods 0.000 description 5
- 239000004745 nonwoven fabric Substances 0.000 description 5
- 239000002952 polymeric resin Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
- 239000003513 alkali Substances 0.000 description 4
- 150000001412 amines Chemical class 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 4
- 238000005260 corrosion Methods 0.000 description 4
- 230000001965 increasing effect Effects 0.000 description 4
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 4
- 229920005591 polysilicon Polymers 0.000 description 4
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 4
- 229910010271 silicon carbide Inorganic materials 0.000 description 4
- 239000000377 silicon dioxide Substances 0.000 description 4
- 239000010802 sludge Substances 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 229920005992 thermoplastic resin Polymers 0.000 description 4
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 4
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 4
- IKEHOXWJQXIQAG-UHFFFAOYSA-N 2-tert-butyl-4-methylphenol Chemical compound CC1=CC=C(O)C(C(C)(C)C)=C1 IKEHOXWJQXIQAG-UHFFFAOYSA-N 0.000 description 3
- 206010016807 Fluid retention Diseases 0.000 description 3
- 239000004840 adhesive resin Substances 0.000 description 3
- 229920006223 adhesive resin Polymers 0.000 description 3
- 239000011384 asphalt concrete Substances 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 238000005336 cracking Methods 0.000 description 3
- 239000003995 emulsifying agent Substances 0.000 description 3
- 230000005484 gravity Effects 0.000 description 3
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 3
- 239000000391 magnesium silicate Substances 0.000 description 3
- 229910052919 magnesium silicate Inorganic materials 0.000 description 3
- 235000019792 magnesium silicate Nutrition 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011775 sodium fluoride Substances 0.000 description 3
- 235000013024 sodium fluoride Nutrition 0.000 description 3
- 229920001909 styrene-acrylic polymer Polymers 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 2
- 229920003043 Cellulose fiber Polymers 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- BCKXLBQYZLBQEK-KVVVOXFISA-M Sodium oleate Chemical compound [Na+].CCCCCCCC\C=C/CCCCCCCC([O-])=O BCKXLBQYZLBQEK-KVVVOXFISA-M 0.000 description 2
- NWGKJDSIEKMTRX-AAZCQSIUSA-N Sorbitan monooleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NWGKJDSIEKMTRX-AAZCQSIUSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 229910010413 TiO 2 Inorganic materials 0.000 description 2
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
- JUNWLZAGQLJVLR-UHFFFAOYSA-J calcium diphosphate Chemical compound [Ca+2].[Ca+2].[O-]P([O-])(=O)OP([O-])([O-])=O JUNWLZAGQLJVLR-UHFFFAOYSA-J 0.000 description 2
- 229940043256 calcium pyrophosphate Drugs 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000011294 coal tar pitch Substances 0.000 description 2
- 230000002542 deteriorative effect Effects 0.000 description 2
- 235000019821 dicalcium diphosphate Nutrition 0.000 description 2
- IQDGSYLLQPDQDV-UHFFFAOYSA-N dimethylazanium;chloride Chemical compound Cl.CNC IQDGSYLLQPDQDV-UHFFFAOYSA-N 0.000 description 2
- 238000010828 elution Methods 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 238000006703 hydration reaction Methods 0.000 description 2
- TWQLWICCIMYMES-UHFFFAOYSA-N hydrazine 4-phenyltriazine Chemical compound C1(=CC=CC=C1)C1=NN=NC=C1.NN TWQLWICCIMYMES-UHFFFAOYSA-N 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000012948 isocyanate Substances 0.000 description 2
- 150000002513 isocyanates Chemical class 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- 239000005011 phenolic resin Substances 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 description 2
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 2
- 235000010234 sodium benzoate Nutrition 0.000 description 2
- 239000004299 sodium benzoate Substances 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- DMXPRXFEDTZXER-UHFFFAOYSA-N C(C=C/C(=O)OCC)(=O)OCC.C(C)(=O)OC=C Chemical compound C(C=C/C(=O)OCC)(=O)OCC.C(C)(=O)OC=C DMXPRXFEDTZXER-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 241001379910 Ephemera danica Species 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 229920000388 Polyphosphate Polymers 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 229920002310 Welan gum Polymers 0.000 description 1
- KJVBXWVJBJIKCU-UHFFFAOYSA-N [hydroxy(2-hydroxyethoxy)phosphoryl] prop-2-enoate Chemical compound OCCOP(O)(=O)OC(=O)C=C KJVBXWVJBJIKCU-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 125000005037 alkyl phenyl group Chemical group 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000008422 chlorobenzenes Chemical class 0.000 description 1
- 229920006026 co-polymeric resin Polymers 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- BCAARMUWIRURQS-UHFFFAOYSA-N dicalcium;oxocalcium;silicate Chemical compound [Ca+2].[Ca+2].[Ca]=O.[O-][Si]([O-])([O-])[O-] BCAARMUWIRURQS-UHFFFAOYSA-N 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000011372 high-strength concrete Substances 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical class C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000002530 phenolic antioxidant Substances 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920013716 polyethylene resin Polymers 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 229920000137 polyphosphoric acid Polymers 0.000 description 1
- 150000003097 polyterpenes Chemical class 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- 238000010257 thawing Methods 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- XLOMVQKBTHCTTD-UHFFFAOYSA-N zinc oxide Inorganic materials [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D195/00—Coating compositions based on bituminous materials, e.g. asphalt, tar, pitch
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/002—Priming paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/48—Stabilisers against degradation by oxygen, light or heat
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
-
- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01D—CONSTRUCTION OF BRIDGES, ELEVATED ROADWAYS OR VIADUCTS; ASSEMBLY OF BRIDGES
- E01D19/00—Structural or constructional details of bridges
- E01D19/08—Damp-proof or other insulating layers; Drainage arrangements or devices ; Bridge deck surfacings
- E01D19/083—Waterproofing of bridge decks; Other insulations for bridges, e.g. thermal ; Bridge deck surfacings
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Architecture (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
본 발명은 친환경 교면방수제 조성물 및 이를 이용한 방수공법에 관한 것으로서, 보다 상세하게는 콘크리트 구조물, 포장면 등의 교면에 방수포장면을 형성시켜 내구성, 방수성, 염화물 침투 저항성을 향상시킬 수 있는 친환경 교면방수제 조성물 및 이를 이용한 방수공법에 관한 것이다.The present invention relates to an environmentally friendly bristle waterproofing composition and a waterproofing method using the same, and more specifically, an environmentally friendly bristle waterproofing composition which can improve durability, waterproofness, and chloride penetration resistance by forming a waterproof packaging surface on a bridge such as a concrete structure or a pavement surface. And it relates to a waterproof method using the same.
일반적으로, 콘크리트 교량 또는 구조물의 교면은 공용 연수가 증가할수록 빗물이나 제설재의 침투량이 많아지고 교면에 가해지는 하중이 누적되므로 재료 간 결합력이 저하되고 온도변화에 따른 물의 체적변화 등으로 균열이 발생하기 쉽다.In general, the concrete bridges or bridges of bridges have increased rainwater or snow removal materials and accumulate loads on the bridges as the number of common years increases, so that the bonding strength between materials decreases and cracks occur due to changes in the volume of water due to temperature changes. easy.
콘크리트 구조물 등의 균열은 시간이 경과할수록 확대되어, 콘크리트 구조물의 강도 및 수명 저하를 초래하고, 우수 등이 아스팔트 공극 균열부분과 중앙분리대 및 조인트 부위의 틈새를 통해 침투 시, 콘크리트 내부의 철근이 부식되어 구조물의 수명단축 및 붕괴를 초래한다.The cracks in concrete structures expand over time, causing the strength and life of concrete structures to deteriorate, and when rainwater penetrates through the gaps between asphalt gap cracks, median and joints, the steel reinforces within the concrete. Resulting in shortening and collapse of the structure.
따라서 빗물이나 제설재 등이 침투되어 콘크리트 구조물의 강도 및 수명이 저하되는 것을 방지하기 위하여 콘크리트 교량 또는 구조물의 교면에 방수제를 도포하고 있다. 이러한 콘크리트 구조물의 교면에 방수제를 도포함으로써, 포장층으로부터 침투되는 물과 염화물에 의한 바닥판 콘크리트의 열화 및 철근 부식을 방지할 수 있다.Therefore, in order to prevent rainwater or snow removal materials from infiltrating and deteriorating the strength and life of the concrete structure, a waterproofing agent is applied to the concrete bridge or the bridge surface of the structure. By applying a waterproofing agent to the intersection of such a concrete structure, it is possible to prevent deterioration of the bottom plate concrete and reinforcement corrosion by water and chloride penetrating from the pavement layer.
콘크리트 교면 방수제는 건축 및 기타분야에 적용되는 방수재와 달리 주행차량에 의한 반복하중, 진동, 충격, 전단 등의 역학적 작용과 온도변화에 의한 수축ㅇ팽창 등이 복잡하게 작용하는 교면에 사용되므로 교면 방수제층은 손상되기 쉽고, 이로 인해 손상된 교면 방수제층을 보수하거나 보강하는 데는 많은 비용이 소요될 뿐만 아니라 공사 중 차로를 부분 통제함으로써 교통지체를 유발하는 문제점이 있다.Unlike concrete waterproofing materials used in construction and other fields, concrete cross-linking waterproofing is used for the cross-linking where complex mechanical action such as cyclic load, vibration, impact, shear, and shrinkage and expansion due to temperature change are complicated. The floor is easy to be damaged, and as a result, it is not only expensive to repair or reinforce the damaged bridge waterproofing layer, but also causes a traffic delay by partially controlling the lanes during construction.
한편, 콘크리트 교면에 적용되는 방수공법으로는, 침투식 방수공법, 시트식 방수공법 및 도막식 방수공법이 있다. 침투식 방수공법은 적용하기에 매우 간편하고 경제적인 이유로 폭넓게 사용되어 왔으나 고강도 콘크리트 교면에는 방수제가 충분히 침투되지 않아 방수성능을 기대할 수 없는 단점이 있으며, 시트식 방수공법은 저온특성이 떨어져 우리나라와 같이 사계절이 있는 나라의 경우 콘크리트 교면의 방수성능 향상에 큰 효과를 나타내지 못하는 문제점이 있다. On the other hand, as a waterproof method applied to the concrete bridge, there are a penetration type waterproof method, a sheet type waterproof method and a coating film waterproof method. The penetration type waterproof method has been widely used for economic reasons because it is very easy to apply and economical, but the waterproofing agent is not penetrated sufficiently in high strength concrete bridges, so the waterproof performance cannot be expected. In the case of four seasons, there is a problem in that it does not show a great effect on the waterproof performance of concrete bridges.
따라서 최근에는 합성수지재료를 도포해서 방수도막을 형성시켜 시공하는 도막식방수공법이 선호되고 있다.Therefore, in recent years, the coating-type waterproofing method of applying a synthetic resin material to form a waterproof coating has been preferred.
도막식 방수공법을 적용한 예를 살펴보면, 대한민국 공개특허 제 1999-37809호에는, 교량 등의 표면에 에폭시 프라이머 층을 도포하고 그 위에 속건성 고분자 수지층과 지건성 고분자 수지층 및 세석골재층을 형성하는 교면 방수공법이 개시되어 있다.Looking at the example of applying the coating-type waterproofing method, Korean Patent Laid-Open Publication No. 1999-37809, an epoxy primer layer is applied to the surface of the bridge and the like to form a quick-drying polymer resin layer, a dry-dry polymer resin layer and fine stone aggregate layer thereon Bridge waterproofing method is disclosed.
하지만, 상기 공개특허에 개시된 교면 방수공법에 적용된 고분자 수지층은 5초 이내에 경화되는 속건성 이어서 아스팔트 콘크리트와 아스팔트 및 에폭시 프라이머 층이 상호 융합되기도 전에 각 층이 분리되거나 크랙이 발생하는 바, 충분한 방수효과를 기대할 수 없다. 또한, 프라이머층 위에 속건성 및 지건성 고분자 수지 층과 세석골재층 등 다양한 처리층을 형성해야하는데, 이와 같이 다중층을 적층하지 않으면 각 층의 접착력이 약해져서 밀리게 되어 층분리 현상이 발생하게 되는바, 실제로 시공을 할 수 없거나 시공을 하더라도 방수효과가 떨어지는 문제점이 있다.However, the polymer resin layer applied to the cross-sectional waterproofing method disclosed in the above patent is fast-drying, which is cured within 5 seconds, so that each layer is separated or cracks before the asphalt concrete and the asphalt and epoxy primer layers are fused together. Can't expect it. In addition, various treatment layers such as fast-drying and slow-drying polymer resin layer and fine stone aggregate layer should be formed on the primer layer. If the multilayers are not laminated in this way, the adhesive strength of each layer is weakened, and the layer separation phenomenon occurs. , In fact, even if you can not do the construction or there is a problem that the waterproof effect falls.
이러한 다중층의 문제점을 보완하기 위하여 대한민국 공개특허 제 2002-76214호에서는 교량 등의 표면에 폴리우레탄수지 프라이머층을 도포한 후 그 위에 속건성 고분자 수지층을 형성하고, 그위에 과량의 이소시아네이트를 첨가한 폴리우레탄 제조 혼합물을 도포한 후 아스팔트 접착제층과 아스팔트 콘크리트층을 차례로 적층하는 처리방법을 개시하고 있다. In order to solve the problem of the multilayer, Korean Patent Laid-Open Publication No. 2002-76214, after applying a polyurethane resin primer layer on the surface of the bridge and the like to form a quick-drying polymer resin layer thereon, and added an excess of isocyanate thereon Disclosed is a treatment method of laminating an asphalt adhesive layer and an asphalt concrete layer after applying a polyurethane production mixture.
그러나 이 방법은 폴리우레탄 제조 혼합물층에 존재하는 과량의 이소시아네이트가 주위의 습기와 반응하여 오히려 결합력이 약해지는 단점이 있으며, 이러한 문제점을 방지하기 위해 현장에서 작업시 매우 주의를 요하는 까다로운 작업공정을 필요로 하게 되는 또 다른 문제점이 발생한다.However, this method has a disadvantage in that an excessive amount of isocyanate present in the polyurethane production mixture layer reacts with the surrounding moisture, thereby weakening the bonding strength, and it is a difficult work process that requires very careful work in the field to prevent this problem. Another problem arises that is needed.
본 발명은 상기와 같은 문제점을 해결하기 위해 창출한 것으로, 콘크리트 구조물의 미세균열 및 모세관 공극 등의 침투성능이 우수하여 내투수 저항성이 탁월하고, 외부하중이나 충격 등으로 손상받기 쉬운 콘크리트 교면과 방수제 계면의 결합을 공고히 함으로써 콘크리트 교면의 내구성을 대폭 향상시킬 수 있도록 하는 친환경 교면방수제 조성물을 제공하고자 한다.The present invention has been made to solve the above problems, excellent in permeation resistance, such as fine cracks and capillary pores of concrete structures, excellent water resistance resistance, concrete bridges and waterproofing agents susceptible to damage due to external load or impact, etc. It is an object of the present invention to provide an environmentally friendly bristle waterproofing composition that can significantly improve the durability of concrete bridges by solidifying the bonding of the interface.
본 발명은The present invention
아스팔트 100중량부 기준으로,Based on 100 parts by weight of asphalt,
스티렌부타디엔스티렌 10 내지 40중량부;10 to 40 parts by weight of styrene butadiene styrene;
석유수지 1 내지 15중량부;1 to 15 parts by weight of petroleum resin;
탄산칼슘 10 내지 30중량부;10 to 30 parts by weight of calcium carbonate;
메틸메타크릴레이트 5 내지 30중량부;5 to 30 parts by weight of methyl methacrylate;
음이온 유화제 3 내지 20중량부;3 to 20 parts by weight of anionic emulsifier;
옥틸페놀에톡실레이트 1 내지 10중량부;1 to 10 parts by weight of octylphenolethoxylate;
섬유 3 내지 15중량부;3 to 15 parts by weight of fibers;
나노세라믹입자 3 내지 20중량부;3 to 20 parts by weight of nanoceramic particles;
박리방지제 5 내지 30중량부; 5 to 30 parts by weight of a peeling inhibitor;
산화방지제 3 내지 10중량부; 및3 to 10 parts by weight of antioxidant; And
부착증진제 1 내지 20중량부를 포함하는 교면방수제 조성물을 제공한다.It provides a crosslinking waterproofing composition comprising 1 to 20 parts by weight of adhesion promoter.
또한, 본 발명은 In addition, the present invention
교면방수제 조성물을 시공하기 위한 시공표면을 처리하는 표면처리단계;A surface treatment step of treating the construction surface for constructing the crosslinking waterproofing composition;
상기 표면처리단계가 종료된 후 톨루엔 40 내지 60중량부와 아스팔트 40 내지 60중량부를 혼합하고 용융시켜 제조한 프라이머를 도포하는 프라이머 도포단계;A primer coating step of applying a primer prepared by mixing and melting 40 to 60 parts by weight of toluene and 40 to 60 parts by weight of asphalt after the surface treatment step is completed;
상기 프라이머 도포단계가 종료된 후 아스팔트 100중량부 기준으로, 스티렌부타디엔스티렌 10 내지 40중량부, 석유수지 1 내지 15중량부, 탄산칼슘 10 내지 30중량부, 메틸메타크릴레이트 5 내지 30중량부, 음이온 유화제 3 내지 20중량부, 옥틸페놀에톡실레이트 1 내지 10중량부, 섬유 3 내지 15중량부, 나노세라믹입자 3 내지 20중량부, 박리방지제 5 내지 30중량부, 산화방지제 3 내지 10중량부, 및 부착증진제 1 내지 20중량부를 포함하는 교면방수제 조성물을 도포하는 교면방수제 조성물 도포단계;After completion of the primer coating step, based on 100 parts by weight of asphalt, 10 to 40 parts by weight of styrene butadiene styrene, 1 to 15 parts by weight of petroleum resin, 10 to 30 parts by weight of calcium carbonate, 5 to 30 parts by weight of methyl methacrylate, 3 to 20 parts by weight of anionic emulsifier, 1 to 10 parts by weight of octyl phenol ethoxylate, 3 to 15 parts by weight of fiber, 3 to 20 parts by weight of nanoceramic particles, 5 to 30 parts by weight of anti-release agent, 3 to 10 parts by weight of antioxidant And a crosslinking waterproofing composition applying step of applying a crosslinking waterproofing composition comprising 1 to 20 parts by weight of an adhesion promoter;
상기 교면방수제 조성물 도포단계가 종료된 후 방수시트를 부착하여 방수시트층을 형성하는 방수시트층 형성단계; 및A waterproof sheet layer forming step of attaching the waterproof sheet to form the waterproof sheet layer after the application of the crosslinking waterproofing composition is completed; And
상기 방수시트층 형성단계가 종료된 후 아스콘 포장을 하는 아스콘 포장단계를 포함하는 교면 방수공법을 제공한다.After the waterproof sheet layer forming step is completed provides an interstitial waterproof method comprising an ascon packaging step of packaging ascon.
본 발명에 따른 교면방수제 조성물은 친환경적이면서도 콘크리트의 미세균열 및 모세관 공극 등의 침투성능이 우수한 도포제를 방수공법에 적용함으로써, 추가적 보호막을 형성할 수 있고, 외부하중이나 충격 등으로 손상받기 쉬운 콘크리트 교면과 방수제 계면의 결합을 공고히 할 수 있을 뿐만 아니라 내투수 저항성을 향상시킬 수 있어 콘크리트 교면의 내구성을 대폭 향상시킬 수 있다.The crosslinking waterproofing composition according to the present invention is an environmentally friendly concrete coating that can form an additional protective film by applying a coating agent having excellent penetration performance such as microcracks and capillary pores of concrete to the waterproofing method, and is easily damaged by external loads or impacts. Not only can the bond between the interface and the waterproofing agent be firmly strengthened, but also the permeability resistance can be improved, thereby significantly improving the durability of the concrete bridge.
이하, 본 발명을 구체적으로 설명한다.Hereinafter, the present invention will be described in detail.
한 가지 관점에서, 본 발명은 아스팔트 100중량부 기준으로, 스티렌부타디엔스티렌 10 내지 40중량부; 석유수지 1 내지 15중량부; 탄산칼슘 10 내지 30중량부; 메틸메타크릴레이트 5 내지 30중량부; 음이온 유화제 3 내지 20중량부; 옥틸페놀에톡실레이트 1 내지 10중량부; 섬유 3 내지 15중량부; 나노세라믹입자 3 내지 20중량부; 박리방지제 5 내지 30중량부; 산화방지제 3 내지 10중량부; 및 부착증진제 1 내지 20중량부를 포함하는 교면방수제 조성물을 제공한다.In one aspect, the present invention is based on 100 parts by weight of asphalt, 10 to 40 parts by weight of styrene butadiene styrene; 1 to 15 parts by weight of petroleum resin; 10 to 30 parts by weight of calcium carbonate; 5 to 30 parts by weight of methyl methacrylate; 3 to 20 parts by weight of anionic emulsifier; 1 to 10 parts by weight of octylphenolethoxylate; 3 to 15 parts by weight of fibers; 3 to 20 parts by weight of nanoceramic particles; 5 to 30 parts by weight of a peeling inhibitor; 3 to 10 parts by weight of antioxidant; And it provides a cross-linking waterproofing composition comprising 1 to 20 parts by weight of adhesion promoter.
다른 관점에서, 본 발명은 교면방수제 조성물을 시공하기 위한 시공표면을 처리하는 표면처리단계; 상기 표면처리단계가 종료된 후 톨루엔 40 내지 60중량부와 아스팔트 40 내지 60중량부를 혼합하고 용융시켜 제조한 프라이머를 도포하는 프라이머 도포단계; 상기 프라이머 도포단계가 종료된 후 아스팔트 100중량부 기준으로, 스티렌부타디엔스티렌 10 내지 40중량부, 석유수지 1 내지 15중량부, 탄산칼슘 10 내지 30중량부, 메틸메타크릴레이트 5 내지 30중량부, 음이온 유화제 3 내지 20중량부, 옥틸페놀에톡실레이트 1 내지 10중량부, 섬유 3 내지 15중량부, 나노세라믹입자 3 내지 20중량부, 박리방지제 5 내지 30중량부, 산화방지제 3 내지 10중량부, 및 부착증진제 1 내지 20중량부를 포함하는 교면방수제 조성물을 도포하는 교면방수제 조성물 도포단계; 상기 교면방수제 조성물 도포단계가 종료된 후 방수시트를 부착하여 방수시트층을 형성하는 방수시트층 형성단계; 및In another aspect, the present invention comprises a surface treatment step of treating the construction surface for the construction of the cross-linking agent composition; A primer coating step of applying a primer prepared by mixing and melting 40 to 60 parts by weight of toluene and 40 to 60 parts by weight of asphalt after the surface treatment step is completed; After completion of the primer coating step, based on 100 parts by weight of asphalt, 10 to 40 parts by weight of styrene butadiene styrene, 1 to 15 parts by weight of petroleum resin, 10 to 30 parts by weight of calcium carbonate, 5 to 30 parts by weight of methyl methacrylate, 3 to 20 parts by weight of anionic emulsifier, 1 to 10 parts by weight of octyl phenol ethoxylate, 3 to 15 parts by weight of fiber, 3 to 20 parts by weight of nanoceramic particles, 5 to 30 parts by weight of anti-release agent, 3 to 10 parts by weight of antioxidant And a crosslinking waterproofing composition applying step of applying a crosslinking waterproofing composition comprising 1 to 20 parts by weight of an adhesion promoter; A waterproof sheet layer forming step of attaching the waterproof sheet to form the waterproof sheet layer after the application of the crosslinking waterproofing composition is completed; And
상기 방수시트층 형성단계가 종료된 후 아스콘 포장을 하는 아스콘 포장단계를 포함하는 교면 방수공법을 제공을 제공한다.Provides a cross-section waterproofing method comprising an ascon packaging step of packaging the ascon after the waterproof sheet layer forming step is completed.
본 발명에 따른 교면방수제 조성물은 교면, 포장면, 건축물의 내/외부 등에 발생한 균열로 인한 누수 및 결로현상을 방지하기 위해 사용되는 것으로서, 이러한 목적을 위해 당업계에서 통상적으로 사용되는 교면방수제 조성물이라면 어떠한 것을 사용하여도 무방하다.The crosslinking waterproofing composition according to the present invention is used to prevent leakage and condensation due to cracks occurring in bridges, pavement surfaces, inside / outside of buildings, and the like. Anything may be used.
본 발명에 따른 아스팔트는 당업계에서 통상적으로 사용되는 아스팔트라면 특별히 한정되지 않지만, 추천하기로는 석유계 아스팔트 또는 아스팔트 혼합물을 사용할 수 있다.Asphalt according to the present invention is not particularly limited as long as it is conventionally used in the art, it is recommended to use petroleum-based asphalt or asphalt mixture.
여기서, 상기 아스팔트 혼합물은 천연 아스팔트 혼합물을 사용하는 것을 추천한다.Here, it is recommended to use a natural asphalt mixture for the asphalt mixture.
상기 아스팔트 혼합물, 특정적으로 천연 아스팔트 혼합물은 당업계에서 통상적으로 사용되는 천연 아스팔트 혼합물이라면 특별히 한정되지 않지만, 바람직하게는 스트레이트(straight) 아스팔트, 트리니다드레이크(Trinidad lake) 아스팔트, 트리니다드에퓨레(Trinidad epure) 아스팔트 또는 이들로부터 선택된 적어도 하나 이상의 혼합물을 사용하는 것이 좋고, 보다 바람직하게는 침입도 20 내지 40의 스트레이트 아스팔트와 천연 아스팔트, 예를 들면 트리니다드레이크 아스팔트 및/또는 트리니다드에퓨레 아스팔트 혼합물을 사용하는 것이 좋고, 더욱 바람직하게는 침입도 20 내지 40의 스트레이트 아스팔트 70 내지 80중량% 및 트리니다드레이크 아스팔트 또는 트리니다드에퓨레 아스팔트로 이루어진 천연 아스팔트 20 내지 30중량%를 혼합한 것을 사용하는 것을 추천한다.The asphalt mixture, in particular the natural asphalt mixture, is not particularly limited as long as it is a natural asphalt mixture commonly used in the art, but preferably straight asphalt, Trinidad lake asphalt, Trinidad epure It is preferable to use asphalt or at least one or more mixtures selected from them, and more preferably to use straight asphalt and natural asphalt, such as Trinidad Lake Asphalt and / or Trinidad Epure Asphalt mixture, having a penetration of 20 to 40. It is preferable to use a mixture of 70 to 80% by weight of straight asphalt having a penetration degree of 20 to 40 and 20 to 30% by weight of natural asphalt composed of Trinidad and Asphalt or Trinidad Epure asphalt. It's mean.
여기서, 상기 스트레이트 아스팔트(straight asphalt)는 석유 아스팔트로 원료를 건류 또는 증류한 잔류물을 정제한 통상의 아스팔트로, 특히 침입도가 20 내지 40인 것이 도로에 시공 시 용이성이 있어 더욱 좋다.Here, the straight asphalt is a conventional asphalt obtained by refining the residue obtained by distilling or distilling the raw material from petroleum asphalt, and particularly, having an infiltration degree of 20 to 40 may be easily installed on the road.
상기 스트레이트 아스팔트는 아스팔트 혼합물에 70 내지 80중량%로 포함되는 것이 바람직하다. 그 함량이 70중량% 미만일 경우에는 아스팔트 포장 후 굳는데 오랜 시간이 소요될 수 있고, 연화점이 낮아질 수 있으며, 80중량%를 초과할 경우에는 유동성이 저하될 수 있다.The straight asphalt is preferably contained in 70 to 80% by weight in the asphalt mixture. If the content is less than 70% by weight, it may take a long time to harden after asphalt paving, the softening point may be lowered, and when it exceeds 80% by weight, fluidity may be reduced.
또한, 상기 천연 아스팔트는 트리니다드레이크(trinidad lake) 아스팔트 및/또는 트리니다드에퓨레(Trinidad epure) 아스팔트 등을 사용할 수 있다.In addition, the natural asphalt may be a trinidad lake (trinidad lake) asphalt and / or Trinidad epure asphalt (Trinidad epure) asphalt.
상기 천연 아스팔트는 아스팔트 혼합물에 20 내지 30중량%로 포함되는 것이 바람직하며, 그 함량이 20중량% 미만일 경우에는 유동성, 변형저항, 미끄럼저항 및 마찰저항의 개선효과가 미미하며, 30중량%를 초과할 경우에는 본 발명의 아스팔트가 연질화되고 연화점이 낮아질 수 있다.The natural asphalt is preferably contained in 20 to 30% by weight in the asphalt mixture, when the content is less than 20% by weight, the effect of improving the fluidity, deformation resistance, sliding resistance and frictional resistance is insignificant, exceeding 30% by weight In this case, the asphalt of the present invention may be softened and the softening point may be lowered.
본 발명에 따른 친환경 교면방수제 조성물을 구성하는 아스팔트 외 나머지 성분의 함량은 아스팔트 100중량부 기준으로 한다.The content of the remaining components other than asphalt constituting the environmentally friendly bridge waterproofing agent composition according to the present invention is based on 100 parts by weight of asphalt.
본 발명에 따른 스티렌부타디엔스티렌(stylene butadien stylene; SBS)은 교면방수제 조성물, 특정적으로 친환경 교면방수제 조성물의 균열 발생을 억제하고, 방수성능을 제공하는 동시에 강도를 향상시킨다.Styrene butadien styrene (SBS) according to the present invention suppresses the occurrence of cracks in the crosslinking waterproofing composition, in particular the environmentally friendly crosslinking waterproofing composition, while providing a waterproofing performance and improve the strength.
바람직한 스티렌부타디엔스티렌의 사용량은 사용자의 선택에 따라 변경 가능하지만, 추천하기로는 아스팔트 100중량부 기준으로 10 내지 40중량부인 것이 바람직하다.The amount of the preferred styrene butadiene styrene can be changed according to the user's choice, but it is preferably 10 to 40 parts by weight based on 100 parts by weight of asphalt.
본 발명에 따른 석유수지는 교면방수제 조성물, 특정적으로 친환경 교면방수제 조성물에 고점착성을 제공하기 위한 것으로서, 이러한 목적을 갖는 당업계의 통상적인 석유수지라면 어떠한 것을 사용하여도 무방하지만, 바람직하게는 방향족계 석유수지, 지방족계 석유수지 또는 이들의 혼합물을 사용할 수 있고, 특히 바람직하게는 용융온도가 100℃ 이상이고 침입도가 3dmm이하, 140℃에서 점도(이하 140℃ 점도)가 50내지 500cps인 석유 수지가 적합하지만, 추천하기로는 용융온도가 110℃ 내지 140℃이고 침입도가 0.5 내지 2dmm, 140℃ 점도가 50 내지 300cps인 석유수지가 좋지만, 더욱 추천하기로는 점도가 100 내지 150cps인 지방족 C-5석유수지를 사용하는 것이 좋다.The petroleum resin according to the present invention is to provide high adhesion to the crosslinking waterproofing composition, and particularly to the environment-friendly crosslinking waterproofing composition, and any petroleum resin conventional in the art having such a purpose may be used, but preferably Aromatic petroleum resins, aliphatic petroleum resins or mixtures thereof may be used, and particularly preferably, the melting temperature is 100 ° C. or higher, the penetration is 3 dmm or less, and the viscosity (140 ° C. or less) is 50 to 500 cps at 140 ° C. Although petroleum resins are suitable, petroleum resins having a melting temperature of 110 ° C. to 140 ° C. and a penetration of 0.5 to 2 dmm and a viscosity of 50 ° C. to 300 cps are preferable, but more preferably aliphatic C having a viscosity of 100 to 150 cps. -5 Petroleum resin is recommended.
한 가지 양태로서, 상기 석유수지는 온도변화와 관계없이 강력한 점착성능을 발휘하도록 하기 위하여, 연화점이 낮거나 높은 석유수지를 서로 배합하여 사용할 수도 있다.In one embodiment, the petroleum resin may be used in combination with each other, in order to exhibit a strong adhesive performance irrespective of temperature changes, low or high softening point.
이때, 바람직한 석유수지의 배합으로서, 연화점이 90 내지 100℃ 정도로 작은 것과 연화점이 105 내지 120℃ 정도로 큰 것을 1:9 내지 9:1, 바람직하게는 6.5:3.5의 중량 비율로 배합함으로써, 목적하는 물성을 조절하여 얻을 수 있다.At this time, as the blending of the preferred petroleum resin, a softening point of about 90 to 100 ° C. and a softening point of about 105 to 120 ° C. are compounded in a weight ratio of 1: 9 to 9: 1, preferably 6.5: 3.5, Can be obtained by adjusting the physical properties.
또한, 상기 연화점이 낮은 석유수지는 초기 점착력을 좋게 하여 점착력을 향상시키며, 연화점이 높은 석유수지는 내열성을 상승시켜 흘러내림을 방지하고, 내후성을 증가시킬 뿐만 아니라 점착력도 향상시킬 수 있다.In addition, the petroleum resin having a low softening point improves the adhesive strength by improving the initial adhesive force, and the petroleum resin having a high softening point may increase heat resistance to prevent flowing down, increase weather resistance as well as improve adhesive strength.
다른 한 가지 양태로서, 본 발명에 따른 석유수지는 점착 기능을 보완하기 위해, 송진 등을 부가하여 송진의 늘어나는 성질이 점착 성능을 보다 안정적으로 제공하도록 할 수 있다. In another aspect, the petroleum resin according to the present invention may be added to the rosin to supplement the adhesive function, so that the increasing properties of the rosin can provide a more stable adhesive performance.
이때, 상기 석유수지와 송진의 혼합비는 특별히 한정되지 않지만, 1:9 내지 9:1의 중량비로 혼합되는 것이 좋다.At this time, the mixing ratio of the petroleum resin and rosin is not particularly limited, but may be mixed in a weight ratio of 1: 9 to 9: 1.
여기서, 상기 석유수지의 용융온도가 100℃ 이하이면 온도가 높을 시 상호 달라붙거나 덩어리가 형성되어 불량 제품이 될 수 있어 좋지 않고, 침입도가 0.5dmm 이하이면 너무 물러 아스팔트의 고온 물성 개선을 하는데 문제가 된다. Here, if the melting temperature of the petroleum resin is less than 100 ℃ can not be a bad product by sticking together or forming a lump when the temperature is high, if the penetration is less than 0.5dmm too high to improve the high-temperature properties of asphalt It is a problem.
또한, 석유수지의 140℃ 점도가 500cps 이상이면 아스팔트 보다 점도가 높아 제조 시간이 너무 길어지게 된다.In addition, if the 140 ℃ viscosity of the petroleum resin is 500cps or more, the viscosity is higher than asphalt, the production time is too long.
특정적으로 본 발명에 따른 석유수지는 평균분자량 450 내지 4,00Da인 접착성 수지를 포함하는 것을 추천한다.Specifically, it is recommended that the petroleum resin according to the present invention include an adhesive resin having an average molecular weight of 450 to 4,00 Da.
여기서, 상기 접착성 수지는 접착 성능을 갖는 수지라면 특별히 한정되지 않지만, 바람직하게는 평균분자량 450 내지 4,000Da인 접착성 수지, 예를 들면 에폭시 수지, 우레탄 수지, 페놀 수지, 아크릴 수지, 에멀젼 수지, 에틸렌/비닐알코올 공중합 수지, 폴리아미드 수지, 방향족 탄화수소계 석유수지, 지방족 탄화수소계 석유수지, 폴리터펜 수지, 터펜 페놀 수지, 로진, 로진 에스터 등의 천연계 석유수지와 이들의 수소 첨가물 등을 사용할 수 있으며, 보다 바람직하게는 연화점이 70 내지 170℃인 방향족 탄화수소계 석유수지를 사용하는 것이 좋다. 또는 이들의 혼합물을 사용하는 것이 좋다.Here, the adhesive resin is not particularly limited as long as it is a resin having adhesion performance, but preferably an adhesive resin having an average molecular weight of 450 to 4,000 Da, for example, an epoxy resin, a urethane resin, a phenol resin, an acrylic resin, an emulsion resin, Natural petroleum resins such as ethylene / vinyl alcohol copolymer resin, polyamide resin, aromatic hydrocarbon petroleum resin, aliphatic hydrocarbon petroleum resin, polyterpene resin, terpene phenol resin, rosin, rosin ester, and hydrogenated additives thereof More preferably, aromatic hydrocarbon petroleum resin having a softening point of 70 to 170 ° C is preferably used. Or mixtures thereof.
본 발명에 따른 석유수지의 사용량은 특별히 한정되는 것은 아니지만, 아스팔트 100중량부 기준으로 1 내지 15중량부인 것이 좋다.The amount of the petroleum resin according to the present invention is not particularly limited, but is preferably 1 to 15 parts by weight based on 100 parts by weight of asphalt.
본 발명에 따른 탄산칼슘은 교면방수제 조성물 내에 발생하는 공극을 충전하고, 용적을 증대시키며 일정 두께를 형성할 수 있어 증량제로서의 역할을 수행하기 위한 것이다.Calcium carbonate according to the present invention is to fill the pores generated in the cross-linking waterproofing composition, increase the volume and form a certain thickness to serve as an extender.
바람직한 탄산칼슘의 사용량은 사용자의 선택에 따라 변경 가능하지만, 추천하기로는 아스팔트 100중량부 기준으로 10 내지 30중량부인 것이 좋다.The amount of the preferred calcium carbonate can be changed according to the user's choice, but it is preferably 10 to 30 parts by weight based on 100 parts by weight of asphalt.
본 발명에 따른 메틸메타아크릴레이트(MMA: Methyl MethAcrylate)는 우수한 접착력 및 기계적 물성을 유지하여 외부 충격에 의한 크랙 및 탈락현상을 방지하기 위한 것이다.Methyl methacrylate (MMA: Methyl Meth Acrylate) according to the present invention maintains excellent adhesion and mechanical properties to prevent cracking and dropping due to external impact.
바람직한 메틸메타아크릴레이트의 사용량은 아스팔트 100중량부 기준으로 5 내지 30중량부인 것을 추천한다.The preferred amount of methyl methacrylate is 5 to 30 parts by weight based on 100 parts by weight of asphalt.
여기서, 상기 메틸메타아크릴레이트는 점도가 10 내지 1,000cps인 저점도 메틸메타크릴레이트(MMA) 수지 49 내지 70중량%와, 점도가 2,000 내지 20,000cps인 고점도 메틸메타크릴레이트(MMA) 20 내지 50중량%를 혼합하여 얻어지는 메틸메타크릴레이트 혼합물에 SIS(stylene isoprene stylene), SBR(stylene butadiene rubber), SBS(stylene butadiene stylene) 중에서 선택된 하나 이상의 혼합물 1 내지 10중량%를 혼합한 변성 메틸메타아크릴레이트를 사용할 수도 있다.Here, the methyl methacrylate is 49 to 70% by weight of low viscosity methyl methacrylate (MMA) resin having a viscosity of 10 to 1,000 cps, and high viscosity methyl methacrylate (MMA) 20 to 50 having a viscosity of 2,000 to 20,000 cps. Modified methyl methacrylate obtained by mixing 1 to 10% by weight of one or more mixtures selected from styrene (stylene isoprene stylene), SBR (stylene butadiene rubber) and SBS (stylene butadiene stylene) to a methyl methacrylate mixture obtained by mixing the weight%. You can also use
본 발명에 따른 음이온 유화제(Anionic emulsifier)는 교면방수제 조성물을 구성하는 각 구성성분 및 반응물 등을 용이하게 분산시키기 위한 것으로서, 이러한 목적을 갖는 당업계의 통상적인 음이온 유화제라면 어떠한 것을 사용하여도 무방하다.Anionic emulsifier according to the present invention is for easily dispersing the components and reactants, etc. constituting the cross-linking agent composition, any of the conventional anionic emulsifiers in the art having this purpose may be used. .
바람직한 음이온 유화제로는 수지산나트륨염, 리그닌술폰산알카리금속염, 나프탈렌 설포닉 산(Naphthalene Sulfonic acid) 유도체, 클로로벤젠(Chlorobenzene) 유도체, 고급지방산알카리금속염, 알킬벤젠슬폰산염, 알파-올레핀슬폰산염, 폴리옥시에칠렌알킬페닐에텔류, 알킬아릴슬폰산나트륨류 또는 이들의 혼합물을 사용할 수 있다.Preferred anionic emulsifiers include sodium resinate, lignin sulfonic acid alkali metal salts, naphthalene sulfonic acid derivatives, chlorobenzene derivatives, higher fatty acid alkali metal salts, alkylbenzene sulfonates, alpha-olefin sulfonates, poly Oxy ethylene alkyl phenyl ethers, alkyl aryl sulfonate, or a mixture thereof can be used.
바람직한 음이온 유화제의 사용량은 아스팔트 100중량부 기준으로 3 내지 20중량부인 것이 좋다.The amount of the preferred anionic emulsifier is preferably 3 to 20 parts by weight based on 100 parts by weight of asphalt.
본 발명에 따른 옥틸페놀에톡실레이트는 에톡실화된 옥틸페놀 유도체로서, 교면방수제 조성물에 포함되어 방수 대상면에 방수막이 용이하게 형성될 수 있도록 한다.The octylphenol ethoxylate according to the present invention is an ethoxylated octylphenol derivative, which is included in the crosslinking waterproofing composition so that the waterproof membrane can be easily formed on the surface to be waterproofed.
바람직한 옥틸페놀에톡실레이트의 사용량은 아스팔트 100중량부 기준으로 1 내지 10중량부인 것이 좋다.The amount of the preferred octyl phenol ethoxylate is preferably 1 to 10 parts by weight based on 100 parts by weight of asphalt.
본 발명에 따른 섬유는 교면방수제 조성물로 형성된 방수제 교면의 종-횡 방향으로 가해지는 응력에 의한 인장력 및/또는 경량성 등을 제공하기 위한 것으로서, 이러한 목적을 갖는 섬유라면 어떠한 것을 사용하여도 무방하지만, 바람직하게는 친환경적 재료인 천연 셀룰로오즈 섬유를 사용하는 것이 좋고, 그 사용량은 아스팔트 100중량부 기준으로 3 내지 15중량부인 것이 좋다.Fiber according to the present invention is to provide a tensile force and / or light weight due to the stress applied in the longitudinal-lateral direction of the cross-linking waterproofing agent formed of the cross-linking waterproofing composition, and any fiber having this purpose may be used. It is preferable to use natural cellulose fiber, which is preferably an environmentally friendly material, and the amount thereof is preferably 3 to 15 parts by weight based on 100 parts by weight of asphalt.
본 발명에 따른 나노세라믹 입자는 친환경 교면방수제 조성물의 양생 중에 표면으로 부상하여 치밀하고 경도가 높은 표면을 형성하기 때문에, 수증기와 기타 기체, 액체의 투과를 방지함은 물론, 내습성, 내구성, 내후성, 내충격성, 내약품성이 향상된다.Since the nanoceramic particles according to the present invention rise to the surface during curing of the environmentally friendly crosslinking agent composition to form a dense and high hardness surface, as well as preventing the permeation of water vapor, other gases and liquids, as well as moisture resistance, durability, weather resistance , Impact resistance and chemical resistance are improved.
상기 나노세라믹 입자의 사용량은 아스팔트 100중량부 기준으로 3 내지 20중량부인 것이 좋다.The amount of the nanoceramic particles used may be 3 to 20 parts by weight based on 100 parts by weight of asphalt.
바람직한 나노세라믹 입자는 실리콘카바이드, 알루미나, 실리카, 지르코니아-실리카, ZnO, TiO2 및/또는 CaCO3가 포함된다. Preferred nanoceramic particles include silicon carbide, alumina, silica, zirconia-silica, ZnO, TiO 2 and / or CaCO 3 .
이들 세라믹입자는 평균 입경이 나노미터 범위인 것이 바람직한데, 구체적으로 상기 실리콘카바이드의 평균 입경은 300 내지 500nm, 상기 알루미나의 평균 입경은 500 내지 1000nm, 상기 실리카의 평균 입경은 700 내지 1500nm, 상기 지르코니아-실리카의 평균 입경은 500 내지 1000nm, 상기 ZnO의 평균 입경은 500 내지 1000nm, 상기 TiO2의 평균 입경은 100 내지 300nm, 그리고 CaCO3의 평균 입경은 500 내지 1000nm인 것이 바람직하다.It is preferable that these ceramic particles have an average particle diameter in the range of nanometer. Specifically, the average particle diameter of the silicon carbide is 300 to 500 nm, the average particle diameter of the alumina is 500 to 1000 nm, the average particle diameter of the silica is 700 to 1500 nm, and the zirconia The average particle diameter of silica is 500 to 1000 nm, the average particle diameter of ZnO is 500 to 1000 nm, the average particle diameter of TiO 2 is 100 to 300 nm, and the average particle diameter of CaCO 3 is preferably 500 to 1000 nm.
이 중에서도 실리콘카바이드는 천연광물로 존재하지 않으므로 인공적으로 합성하며, 고온에서의 화학적 안정성 및 내식성이 뛰어나고 높은 경도를 갖으며 친환경적인 재료이다.Among them, silicon carbide is artificially present because it does not exist as a natural mineral, and has excellent chemical stability and corrosion resistance at high temperature, high hardness, and is an environmentally friendly material.
본 발명에 따른 박리방지제는 친환경 교면방수제 조성물이 교면으로부터 쉽게 박리되는 것을 방지하기 위한 것으로서, 이러한 목적을 갖는 당업계의 통상적인 박리방지제라면 어떠한 것을 사용하여도 무방하지만, 바람직하게는 폴리인산계, 아민계, 또는 인산 에스테르계 박리방지제를 사용하는 것이 좋다.The anti-peeling agent according to the present invention is intended to prevent the environmentally friendly cross-linking agent composition from being easily peeled off from the cross-linking. Any anti-peeling agent in the art having such a purpose may be used, but preferably, polyphosphate, It is preferable to use an amine-based or phosphate ester anti-release agent.
특정적으로, 상기 박리방지제는 액상형으로 비중이 1.0 이상이고 60℃ 점도가 110 cPs인 폴리인산계 박리방지제; 산가가 10 ㎎KOH/g 이하이고, 총 아민가가 140 내지 400㎎HCl/g인 아민계 박리방지제일 수 있다.Specifically, the anti-peeling agent is a liquid-type polyphosphoric anti-peeling agent having a specific gravity of 1.0 or more and a viscosity of 110 cPs of 60 ° C .; It may be an amine-based anti-peeling agent having an acid value of 10 mgKOH / g or less and a total amine value of 140 to 400 mgHCl / g.
바람직한 박리방지제의 사용량은 아스팔트 100중량부 기준으로 5 내지 30중량부인 것을 추천한다.It is recommended that the preferred amount of the anti-peeling agent is 5 to 30 parts by weight based on 100 parts by weight of asphalt.
본 발명에 따른 산화방지제는 친환경 교면방수제 조성물의 산화를 방지하기 위한 것이다.Antioxidant according to the present invention is to prevent the oxidation of the environment-friendly cross-linking agent composition.
바람직한 산화방지제는 아민계, 비스페놀계, 모노페놀계 및 유황계 산화방지제가 사용될 수 있고, 그 사용량은 아스팔트 100중량부 기준으로 3 내지 10중량부인 것이 좋다.Preferred antioxidants may be used amine-based, bisphenol-based, monophenol-based and sulfur-based antioxidants, the amount is preferably 3 to 10 parts by weight based on 100 parts by weight of asphalt.
특정적으로, 본 발명에 따른 산화방지제는 고온에서 가공이 이루어질 경우 저분자형 고분자형 페놀계 산화방지제, 예를 들면 2.2-메틸렌비스(4-메틸-6-t-부틸페놀)[2 . 2 - M e t h y l e n e b i s ( 4 - m e t h y l - 6 - t - b u t y l p h e n o l )], 2.6-디-t-부틸-4-메틸페놀(2.6-di -t-Butyl-4-methylphenol) 또는 이들의 혼합물을 사용하는 것을 추천한다.Specifically, the antioxidant according to the present invention is a low molecular type polymeric phenolic antioxidant such as 2.2-methylenebis (4-methyl-6-t-butylphenol) [2. 2-M ethylenebis (4-methyl-6-t-butylphenol)], 2.6-di-t-butyl-4-methylphenol (2.6-di-t-Butyl-4-methylphenol) or mixtures thereof I recommend you.
본 발명에 따른 부착증진제는 교면방수제 조성물이 적용되는 교면에 보다 용이하게 접착할 수 있도록 하기 위한 것으로서, 이러한 목적을 갖는 당업계의 통상적인 부착증진제라면 어떠한 것을 사용하여도 무방하지만, 추천하기로는 하이드록시 에틸 아크릴로일 포스페이트, 하이드록시 에틸 메타 아크릴레이트 포스페이트 또는 이들의 혼합물을 사용하는 것이 좋고, 그 사용량은 아스팔트 100중량부 기준으로 1 내지 20중량부인 것이 좋다.The adhesion enhancer according to the present invention is intended to be more easily adhered to the bridge to which the cross-linking waterproofing composition is applied, and may be used as long as it is a conventional adhesion promoter in the art having such a purpose, but it is recommended to use a hyde. It is preferable to use oxy ethyl acryloyl phosphate, hydroxy ethyl methacrylate phosphate or a mixture thereof, and the amount thereof is preferably 1 to 20 parts by weight based on 100 parts by weight of asphalt.
본 발명에 따른 교면방수제 조성물, 특정적으로 친환경 교면방수제 조성물은 하기의 특정 양태로 실시되는 부가물을 1종 또는 1종 이상 더 포함할 수 있다.The crosslinking waterproofing composition according to the present invention, specifically, the environmentally friendly crosslinking waterproofing composition may further include one kind or more than one kind of adducts carried out in the following specific embodiments.
특정 양태로서, 본 발명에 따른 교면방수제 조성물은 조성물의 초기 접착력을 유지하기 위하여 톨루엔 및 검로진이 1:1의 중량비로 혼합된 톨루엔-검로진 혼합물을 아스팔트 100중량부 기준으로 1 내지 5중량부 더 포함할 수 있다.In a particular embodiment, the crosslinking waterproofing composition according to the present invention comprises 1 to 5 parts by weight of a toluene-grosene mixture, based on 100 parts by weight of asphalt, in which toluene and gumrogin are mixed in a weight ratio of 1: 1 to maintain the initial adhesion of the composition. It may include.
다른 특정 양태로서, 본 발명에 따른 교면방수제 조성물은 조성물의 수명 연장을 위하여 마그네슘 실리케이트를 아스팔트 100중량부 기준으로 0.1 내지 3중량부로 더 포함할 수 있다.In another specific embodiment, the crosslinking waterproofing composition according to the present invention may further include magnesium silicate in an amount of 0.1 to 3 parts by weight based on 100 parts by weight of asphalt to extend the life of the composition.
상기, 마그네슘 실리케이트는 내화학성 및 내약품성과 풍화 저항성이 우수한 물성을 갖고 있으므로 채움재 조성물의 수명이 연장된다.Since the magnesium silicate has excellent chemical resistance, chemical resistance and weathering resistance, the life of the filler composition is extended.
또 다른 특정 양태로서, 본 발명에 따른 교면방수제 조성물은 공극을 치밀하게 하고 누수를 방지하며 강도를 향상시키기 위하여 나트륨벤토나이트를 아스팔트 100중량부 기준으로 1 내지 10중량부로 더 포함할 수 있다.In another specific embodiment, the cross-linking waterproofing composition according to the present invention may further include sodium bentonite in an amount of 1 to 10 parts by weight based on 100 parts by weight of asphalt to densify voids, prevent leakage, and improve strength.
상기 나트륨벤토나이트는 많은 양의 물을 흡수해 원래 부피의 여러 배로 팽창되며 겔과 같은 상태가 되어 조성물의 공극을 치밀하게 메우게 되어 누수를 방지하고 강도를 향상시켜 균열방지에 기여하게 된다.The sodium bentonite absorbs a large amount of water and expands to several times its original volume and becomes a gel-like state to densely fill the pores of the composition, thereby preventing leakage and improving strength, thereby contributing to crack prevention.
또 다른 특정 양태로서, 본 발명에 따른 교면방수제 조성물은 조성물의 혼합시 급격한 반응을 억제하고 분산성 향상을 위하여 수산화암모늄을 아스팔트 100중량부 기준으로 1 내지 5중량부 더 포함할 수 있다.In another specific embodiment, the cross-linking waterproofing composition according to the present invention may further include 1 to 5 parts by weight of ammonium hydroxide, based on 100 parts by weight of asphalt, in order to suppress rapid reaction and improve dispersibility when mixing the composition.
또 다른 특정 양태로서, 본 발명에 따른 교면방수제 조성물은 조성물의 응집력과 재료의 분리를 방지하기 위하여 폴리비닐리덴 플루오라이드 수지를 아스팔트 100중량부 기준으로 1 내지 5중량부 더 포함할 수 있다.In another specific embodiment, the cross-linking waterproofing composition according to the present invention may further include 1 to 5 parts by weight of polyvinylidene fluoride resin based on 100 parts by weight of asphalt to prevent cohesion of the composition and separation of materials.
또 다른 특정 양태로서, 본 발명에 따른 교면방수제 조성물은 조성물의 성분들 간의 비중차에 따른 재료의 분리 현상을 방지하기 위하여 웰란 검(welan gum)을 아스팔트 100중량부 기준으로 0.1 내지 3중량부 더 포함할 수 있다.In another specific embodiment, the crosslinking waterproofing composition according to the present invention may further include 0.1 to 3 parts by weight of welan gum, based on 100 parts by weight of asphalt, to prevent separation of materials due to specific gravity differences between the components of the composition. It may include.
또 다른 특정 양태로서, 본 발명에 따른 교면방수제 조성물은 작업성과 품질 안정성을 높일 뿐만 아니라, 피접착면과의 계면 접착력을 증대하기 위하여 올레인산나트륨을 아스팔트 100중량부 기준으로 1 내지 5중량부 더 포함할 수 있다.In another specific embodiment, the crosslinking waterproofing composition according to the present invention further comprises 1 to 5 parts by weight of sodium oleate based on 100 parts by weight of asphalt to not only improve workability and quality stability, but also increase interfacial adhesion with the surface to be bonded. can do.
또 다른 양태로서, 본 발명에 따른 교면방수제 조성물은 조성물중 음이온 유화제 , 섬유 등이 세균, 곰팡이, 박테리아에 의해 부패되는 것을 방지하고, 상온에서 공기중의 산소에 의해 산화되는 것을 방지하기 위하여의 벤조산(benzolc acid) 아스팔트 100중량부 기준으로 0.1 내지 2중량부로 더 포함할 수 있다.In another aspect, the cross-linking waterproofing composition according to the present invention is a benzoic acid to prevent the anion emulsifier, fibers, etc. in the composition from being rotted by bacteria, mold, bacteria, and oxidized by oxygen in the air at room temperature (benzolc acid) may further include 0.1 to 2 parts by weight based on 100 parts by weight of asphalt.
또 다른 특정 양태로서, 본 발명에 따른 교면방수제 조성물은 조성물의 강도 증가, 표면평활성 개선, 내후성, 내부식성 등을 향상시키기 위하여 규회석을 아스팔트 100중량부 기준으로 0.1 내지 2중량부로 더 포함할 수 있는데, 상기 규회석은 흰색 또는 회백색의 유리광택이 있는 삼사정계에 속하는 광물질로서 철, 망간 등을 함유하고 있으며, 이러한 규회석이 상기 교면방수제 조성물에 포함되면 상기와 같은 물리적 특성 뿐만 아니라, 아스팔트의 고유한 악취 및 흄의 발생을 억제할 수 있다.In another specific embodiment, the crosslinking waterproofing composition according to the present invention may further include wollastonite in an amount of 0.1 to 2 parts by weight, based on 100 parts by weight of asphalt, in order to increase the strength of the composition, improve surface smoothness, weather resistance, and corrosion resistance. , The wollastonite is a mineral belonging to the triclinic system having a white or off-white glass gloss and contains iron, manganese, and the like. And generation of fumes can be suppressed.
또 다른 특정 양태로서, 본 발명에 따른 교면방수제 조성물은 조성물 접착력 향상 및 건기에 교면방수제 조성물의 낮은 함수율로 인해 물성이 저하되는 것을 방지하기 위하여 아스팔트 100중량부 기준으로 1 내지 5중량부의 메셀로스를 더 포함할 수 있는데, 상기 메셀로스(mecellose, methyl cellulose)는 목재, 면화 등에 의해 얻어진 셀룰로스를 그 원료로 하는 것으로 친환경적인 재료라 할 수 있다.In another specific embodiment, the crosslinking waterproofing composition according to the present invention may contain 1 to 5 parts by weight of mecellose based on 100 parts by weight of asphalt in order to improve the composition adhesion and prevent physical properties from deteriorating due to the low moisture content of the crosslinking waterproofing composition in the dry season. It may further include, the mecellose (mecellose, methyl cellulose) is made of cellulose obtained by wood, cotton, etc. as the raw material can be said to be an environmentally friendly material.
또 다른 특정 양태로서, 본 발명에 따른 교면방수제 조성물은 조성물의 점탄성을 높이기 위하여 소듐 벤조 에이트(sodium benzoate)를 아스팔트 100중량부 기준으로 0.1 내지 1중량부를 더 포함할 수 있는데, 그 함량이 아스팔트 100중량부 기준으로 0.1중량부 보다 적을 경우 효과가 미미하며, 1중량부를 초과할 경우 과량이 되어 물성을 저하시킬 수 있어 좋지 않다.In another specific embodiment, the cross-linking waterproofing composition according to the present invention may further include 0.1 to 1 parts by weight of sodium benzoate based on 100 parts by weight of asphalt to increase the viscoelasticity of the composition, the content of which is asphalt 100 When the amount is less than 0.1 part by weight, the effect is insignificant, and when it exceeds 1 part by weight, the amount becomes excessive, which is not good because it can lower the physical properties.
또 다른 특정 양태로서, 본 발명에 따른 교면방수제 조성물은 조성물의 내구성 및 내알칼리성을 개선하기 위하여 아스팔트 100중량부 기준으로 1 내지 10중량부의 아크릴니트릴을 더 포함할 수 있는데, 그 사용량이 아스팔트 100중량부 기준으로 1중량부 보다 적을 경우에는 내구성 및 내알칼리성 개선 효과가 미미하며, 10중량부를 초과할 경우 점도가 높아져 작업성을 저하시킬 수 있다.In another specific embodiment, the crosslinking waterproofing composition according to the present invention may further include 1 to 10 parts by weight of acrylonitrile based on 100 parts by weight of asphalt in order to improve durability and alkali resistance of the composition, the amount of which is 100 parts by weight of asphalt. When the amount is less than 1 part by weight, the effect of improving durability and alkali resistance is insignificant, and when the amount exceeds 10 parts by weight, the viscosity may be increased, thereby reducing workability.
또 다른 특정 양태로서, 본 발명에 따른 교면방수제 조성물은 조성물의 초기작업 성능을 유지하고 강도를 향상시키기 위하여 피로인산칼슘을 더 포함할 수 있는데, 그 사용량은 아스팔트 100중량부 기준으로 0.1 내지 2중량부가 좋다.In another specific embodiment, the crosslinking waterproofing composition according to the present invention may further include calcium pyrophosphate in order to maintain the initial working performance of the composition and improve the strength thereof, and the amount of the crosslinking waterproofing agent may be 0.1 to 2 parts by weight based on 100 parts by weight of asphalt. Wealth is good.
또 다른 특정 양태로서, 본 발명에 따른 교면방수제 조성물은 조성물의 부식을 억제하고 분산성을 향상시키기 위하여 아스팔트 100중량부 기준으로 1 내지 10중량부의 칼슘아질산염을 더 포함할 수 있다.In another specific embodiment, the crosslinking waterproofing composition according to the present invention may further include 1 to 10 parts by weight of calcium nitrite based on 100 parts by weight of asphalt to suppress corrosion and improve dispersibility of the composition.
또 다른 특정 양태로서, 본 발명에 따른 교면방수제 조성물은 아스팔트 콘크리트 조성물과 유기물과의 경화를 방지함으로써 경화 반응성을 향상시키기 위하여 아스팔트 100중량부 기준으로 1 내지 5중량부의 수산화리튬을 더 포함할 수 있다.In another specific embodiment, the cross-linking waterproofing composition according to the present invention may further include 1 to 5 parts by weight of lithium hydroxide based on 100 parts by weight of asphalt in order to improve curing reactivity by preventing curing of the asphalt concrete composition and the organic material. .
또 다른 특정 양태로서, 본 발명에 따른 교면방수제 조성물은 조성물의 신율과 강도를 개선하기 위하여 테트라 플루오로 에틸렌을 아스팔트 100중량부 기준으로 1 내지 10중량부로 더 포함할 수 있는데, 그 함량이 열경화성 수지 100중량부를 기준으로 1중량부 미만이면 신율 및 강도 개선의 효과가 미미하며, 10중량부를 초과하면 경제적이지 못하여 좋지 않다.In another specific embodiment, the crosslinking waterproofing composition according to the present invention may further comprise tetrafluoro ethylene in an amount of 1 to 10 parts by weight based on 100 parts by weight of asphalt in order to improve the elongation and strength of the composition, the content of which is thermosetting resin If it is less than 1 part by weight based on 100 parts by weight, the effect of improving elongation and strength is insignificant, and if it exceeds 10 parts by weight, it is not economical.
또 다른 특정 양태로서, 본 발명에 따른 교면방수제 조성물은 조성물의 초기강도를 증가시키기 위하여 아스팔트 100중량부 기준으로 1 내지 10중량부의 앨라이트(Alite, C3S)를 더 포함할 수 있다.In another specific embodiment, the crosslinking waterproofing composition according to the present invention may further include 1 to 10 parts by weight of allite (Alite, C3S) based on 100 parts by weight of asphalt to increase the initial strength of the composition.
여기서, 상기 앨라이트는 3CaOㅇSiO2 등 혼합물을 의미하는 것으로서, 이는 수화반응을 촉진시켜 용액 중의 수산화칼슘(Ca(OH)2)의 과포화도가 최고에 도달하게 되고, 수화생성물의 석출이 매우 활발해져 초기 강도가 커지게 된다.Here, the allite means a mixture such as 3CaOSiO 2 , which promotes a hydration reaction to reach the highest degree of supersaturation of calcium hydroxide (Ca (OH) 2 ) in the solution, and the precipitation of the hydration product becomes very active. The strength is increased.
또 다른 특정 양태로서, 본 발명에 따른 교면방수제 조성물은 조성물의 결합강도를 증가시키기 위하여 아스팔트 100중량부 기준으로 카올리나이트 2 내지 8중량부를 더 포함할 수 있다.In another specific embodiment, the crosslinking waterproofing composition according to the present invention may further include 2 to 8 parts by weight of kaolinite based on 100 parts by weight of asphalt to increase the bonding strength of the composition.
여기서, 상기 카올리나이트는 카올린을 주성분으로 함에 따라 흡수성 및 점성이 우수하여 도자기의 재료로 많이 사용된다. Here, the kaolinite is mainly used as a material of porcelain due to its excellent absorption and viscosity as the main component of kaolin.
또한, 상기 카올리나이트는 비교적 미립이고, 경도가 2 내지 2.5이므로 조성물이 교면에 시공될 경우 조성물의 구성성분들의 사이로 침투하여 고화됨에 따라 교면의 내력을 더욱 강화시킨다.In addition, the kaolinite is relatively fine, the hardness is 2 to 2.5 so that when the composition is applied to the bridge, the strength of the bridge is further strengthened as it penetrates and solidifies between the components of the composition.
또 다른 특정 양태로서, 본 발명에 따른 교면방수제 조성물은 조성물의 공극을 메워주어 시공시 공극이 발생하는 것을 방지하기 위하여 아스팔트 100중량부 기준으로 0.1 내지 3중량부의 차아염소산염을 더 포함할 수 있다.In another specific embodiment, the cross-linking waterproofing composition according to the present invention may further include 0.1 to 3 parts by weight of hypochlorite based on 100 parts by weight of asphalt in order to fill the pores of the composition to prevent voids during construction.
또 다른 특정 양태로서, 본 발명에 따른 교면방수제 조성물은 조성물을 구성하는 성분들간의 배합을 용이하게 하고 조성물의 안정성을 향상하기 위하여 술폭시폴리에틸렌글리콜알릴에테르를 아스팔트 100중량부 기준으로 1 내지 10로 더 포함할 수 있는데, 그 함량이 아스팔트 100중량부 기준으로 1중량부 미만이면 조성물의 배합이 용이하지 못하며, 10중량부를 초과하면 과량으로 안정성이 저하되어 좋지 않다.In another specific embodiment, the cross-linking waterproofing composition according to the present invention may contain sulfoxypolyethylene glycol allyl ether in an amount of 1 to 10 based on 100 parts by weight of asphalt in order to facilitate blending between the components constituting the composition and to improve stability of the composition. It may further include, if the content is less than 1 part by weight based on 100 parts by weight of asphalt is not easy to mix the composition, if it exceeds 10 parts by weight is not good because the stability is excessively reduced.
또 다른 특정 양태로서, 본 발명에 따른 교면방수제 조성물은 조성물의 이온화를 방지하기 위하여 아스팔트 100중량부 기준으로 1 내지 10중량부의 소듐헥사메타포스페이트를 더 포함할 수 있다.In another specific embodiment, the crosslinking waterproofing composition according to the present invention may further include 1 to 10 parts by weight of sodium hexametaphosphate based on 100 parts by weight of asphalt to prevent ionization of the composition.
또 다른 특정 양태로서, 본 발명에 따른 교면방수제 조성물은 조성물의 강도향상 및 방수성 향상을 위하여 소르비탄모노올레산에스테르를 아스팔트 100중량부 기준으로 1 내지 5중량부 더 포함할 수 있다.In another specific embodiment, the cross-linking waterproofing composition according to the present invention may further include 1 to 5 parts by weight of sorbitan monooleic acid ester based on 100 parts by weight of asphalt in order to improve the strength of the composition and improve waterproofing.
또 다른 특정 양태로서, 본 발명에 따른 교면방수제 조성물은 알칼리이온 촉진을 향상시키기 위하여 페닐프로파놀아민을 아스팔트 100중량부 기준으로 1 내지 3중량부 더 포함할 수 있다.In another specific embodiment, the cross-linking waterproofing composition according to the present invention may further include 1 to 3 parts by weight of phenylpropanolamine based on 100 parts by weight of asphalt to improve alkali ion promotion.
또 다른 특정 양태로서, 본 발명에 따른 교면방수제 조성물은 압축강도를 향상시키기 위하여 폴리실리콘 슬러지를 아스팔트 100중량부 기준으로 1 내지 5중량부 더 포함할 수 있다.In another specific embodiment, the cross-linking waterproofing composition according to the present invention may further include 1 to 5 parts by weight of polysilicon sludge based on 100 parts by weight of asphalt to improve compressive strength.
여기서, 상기 폴리실리콘 슬러지는 그 성상이 밝은 회색빛을 띄고 있고, 함수율 62%로 높은 함수율로 배출되며, 밀도가 낮고 가벼우며, 분말도가 7,122㎤/g로 미세한 분말 형태로서, 화학조성은 대부분 SiO2와 CaO로 조성되어 있고 알칼리성분인 K2O와 Na2O가 미량 포함되어 있다. Here, the polysilicon sludge has a light gray color, is discharged at a high moisture content of 62%, low density and light, and has a fine powder form of 7,122 cm 3 / g. It is composed of SiO 2 and CaO and contains trace amounts of alkali components K 2 O and Na 2 O.
또한, 폴리실리콘 슬러지 분말을 60℃에서 24시간 이상 건조시킨 후, 얻은 결정상은 CaCO3로 이루어져 있으며, Na2O와 Cl의 화합물인 NaCl이 소량포함되어 있다.In addition, after the polysilicon sludge powder is dried at 60 ° C. for at least 24 hours, the obtained crystal phase is composed of CaCO 3 and contains a small amount of NaCl, a compound of Na 2 O and Cl.
또 다른 특정 양태로서, 본 발명에 따른 교면방수제 조성물은 조성물의 분산성 및 유동성을 일정시간 유지할 수 있도록 하기 위한 이타코닉 산(IA, Itaconic acid)을 아스팔트 100중량부 기준으로 1 내지 10중량부 더 포함할 수 있다.In another specific embodiment, the crosslinking waterproofing composition according to the present invention is 1 to 10 parts by weight of itaconic acid (IA) based on 100 parts by weight of asphalt to maintain the dispersibility and fluidity of the composition for a certain time. It may include.
또 다른 특정 양태로서, 본 발명에 따른 교면방수제 조성물은 조성물의 강도를 증진시키고 방수성, 내염해성, 동결융해성 등을 향상시키기 위하여 트리지마이트를 아스팔트 100중량부 기준으로 1 내지 10중량부 더 포함할 수 있다.In another specific embodiment, the crosslinking waterproofing composition according to the present invention may further include 1 to 10 parts by weight of trizimite based on 100 parts by weight of asphalt in order to enhance the strength of the composition and to improve water resistance, salt resistance, and freeze thawing. Can be.
또 다른 특정 양태로서, 본 발명에 따른 교면방수제 조성물은 아스팔트 100중량부 기준으로 0.1 내지 10중량부의 토탄을 더 포함할 수 있다.In another specific embodiment, the crosslinking waterproofing composition according to the present invention may further include 0.1 to 10 parts by weight of peat based on 100 parts by weight of asphalt.
여기서, 상기 토탄은 독특한 섬유구조로 인해 통상 10배 정도의 우수한 보수성을 가져 교면방수제 조성물의 장기 강도 발현 및 내구성을 향상시키게 된다. Here, the peat has an excellent water retention of about 10 times due to the unique fiber structure, thereby improving long-term strength expression and durability of the crosslinking waterproofing composition.
또 다른 특정 양태로서, 본 발명에 따른 교면방수제 조성물은 조성물의 점도 및 보수성을 개선하기 위하여 아스팔트 100중량부 기준으로 1 내지 10중량부의 셀룰로오스 아세테이트 부틸레이트를 더 포함할 수 있다.In another specific embodiment, the crosslinking waterproofing composition according to the present invention may further include 1 to 10 parts by weight of cellulose acetate butyrate based on 100 parts by weight of asphalt to improve the viscosity and water retention of the composition.
또 다른 특정 양태로서, 본 발명에 따른 교면방수제 조성물은 조성물이 수축하는 것을 방지하기 위하여 아스팔트 100중량부 기준으로 1 내지 10중량부의 산화마그네슘을 더 포함할 수 있다.In another specific embodiment, the crosslinking waterproofing composition according to the present invention may further include 1 to 10 parts by weight of magnesium oxide based on 100 parts by weight of asphalt to prevent the composition from shrinking.
여기서, 상기 산화마그네슘은 시공시 시공대상면에 수분이 유입이 되었을 때 보수 대상면을 단단하게 개량하는 효과를 제공할 수 있다.Here, the magnesium oxide may provide an effect of hardly improving the surface to be repaired when water is introduced into the surface to be constructed during construction.
또 다른 특정 양태로서, 본 발명에 따른 교면방수제 조성물은 조성물의 가소성 및 보수성을 향상시키고 균열방지와 강도증진을 위하여 코코베타인을 아스팔트 100중량부 기준으로 2 내지 8중량부 더 포함할 수 있다.In another specific embodiment, the cross-linking waterproofing composition according to the present invention may further include 2 to 8 parts by weight of cocobetaine, based on 100 parts by weight of asphalt, to improve plasticity and water retention of the composition, and to prevent cracking and increase strength.
또 다른 특정 양태로서, 본 발명에 따른 교면방수제 조성물은 조성물의 수분이 급격히 증발하는 것을 방지하여 화학적 안정성을 부여함으로써 장시간의 저장성을 높이고, 시공시 급격한 경화를 방지하여 우수한 품질을 제공할 수 있도록 아스팔트 100중량부 기준으로 1 내지 5중량부의 스티렌-아크릴 에스터 공중합체(Styrene-Acrylic ester copolymer)를 더 포함할 수 있다.As another specific aspect, the cross-linking waterproofing composition according to the present invention prevents the evaporation of moisture of the composition to give a chemical stability to increase the shelf life for a long time, prevent the rapid curing during construction to provide excellent quality asphalt Based on 100 parts by weight of 1 to 5 parts by weight of the styrene-acrylic ester copolymer (Styrene-Acrylic ester copolymer) may further include.
또 다른 특정 양태로서, 본 발명에 따른 교면방수제 조성물은 조성물의 강성, 안정성, 결합력 및 보전성 등을 향상시키기 위하여 아스팔트 100중량부 기준으로 1 내지 5중량부의 사이클로헥산을 더 포함할 수 있다.In another specific embodiment, the crosslinking waterproofing composition according to the present invention may further include 1 to 5 parts by weight of cyclohexane based on 100 parts by weight of asphalt in order to improve the stiffness, stability, binding strength and integrity of the composition.
또 다른 특정 양태로서, 본 발명에 따른 교면방수제 조성물은 조성물간의 결합력을 등을 향상시키기 위하여 아스팔트 100중량부 기준으로 1 내지 5중량부의 불포화지방산을 더 포함할 수 있다.In another specific embodiment, the crosslinking waterproofing composition according to the present invention may further include 1 to 5 parts by weight of unsaturated fatty acid based on 100 parts by weight of asphalt to improve the bonding strength between the compositions and the like.
여기서, 상기 불포화지방산은 탄소수 14 내지 18인 직쇄 불포화지방산을 사용하는 것이 좋다.Here, the unsaturated fatty acid is preferably used a straight chain unsaturated fatty acid having 14 to 18 carbon atoms.
또 다른 특정 양태로서, 본 발명에 따른 교면방수제 조성물은 조성물의 접착력 및 내구성을 향상시키기 위하여 아스팔트 100중량부 기준으로 5 내지 15중량부의 초산비닐-말레인산디에틸을 더 포함할 수 있다.In another specific embodiment, the crosslinking waterproofing composition according to the present invention may further include 5 to 15 parts by weight of diethyl acetate-maleic acid diethyl acetate based on 100 parts by weight of asphalt to improve adhesion and durability of the composition.
또 다른 특정 양태로서, 본 발명에 따른 교면방수제 조성물은 조성물의 내구성 및 교면 방수제 조성물의 도막의 들뜸 현상을 방지하기 위하여 카올린 분말을 아스팔트 100중량부 기준으로 3 내지 10중량부로 더 포함할 수 있는데, 카올린 분말은 1~3㎛의 입자크기가 바람직하며, 카올린 분말이 아스팔트 100중량부 기준으로 3중량부 미만이면 들뜸 방지에 효과가 없고 10중량부를 초과하면 점도가 크게 상승하여 작업성이 감소하게 되어 좋지 않다.In another specific embodiment, the crosslinking waterproofing composition according to the present invention may further include 3 to 10 parts by weight of kaolin powder based on 100 parts by weight of asphalt in order to prevent the durability of the composition and lifting of the coating film of the crosslinking waterproofing composition. Kaolin powder is preferably a particle size of 1 ~ 3㎛, kaolin powder is less than 3 parts by weight based on 100 parts by weight of asphalt is not effective to prevent lifting and when the content exceeds 10 parts by weight greatly increases the workability is reduced Not good.
또 다른 특정 양태로서, 본 발명에 따른 교면방수제 조성물은 자외선을 흡수하고 크랙의 발생을 방지하기 위하여 아스팔트 100중량부 기준으로 1 내지 5중량부의 하이드라진 페닐 트리아진을 더 포함할 수 있다.In another specific embodiment, the crosslinking waterproofing composition according to the present invention may further include 1 to 5 parts by weight of hydrazine phenyl triazine based on 100 parts by weight of asphalt to absorb ultraviolet rays and prevent cracking.
또 다른 특정 양태로서, 본 발명에 따른 교면방수제 조성물은 조성물의 용해성 및 분산성 향상을 위하여 아스팔트 100중량부 기준으로 1 내지 5중량부의 황산 코발트를 더 포함할 수 있다.In another specific embodiment, the crosslinking waterproofing composition according to the present invention may further include 1 to 5 parts by weight of cobalt sulfate based on 100 parts by weight of asphalt for improving solubility and dispersibility of the composition.
또 다른 특정 양태로서, 본 발명에 따른 교면방수제 조성물은 조성물의 충진성 및 내구성을 향상시키기 위하여 아스팔트 100중량부 기준으로 1 내지 5중량부의 플루오린화나트륨을 더 포함할 수 있는데, 플루오린화나트륨은 1차적으로 충진제로서의 역할도 하지만, 2차적으로는 내구성을 향상시키는 역할을 하는 것으로, 상기와 같은 함량 범위에서 그 효과를 얻을 수 있다.In another specific embodiment, the crosslinking waterproofing composition according to the present invention may further include 1 to 5 parts by weight of sodium fluoride based on 100 parts by weight of asphalt in order to improve the filling and durability of the composition, sodium fluoride is 1 Secondly, but also serves as a filler, secondary to improve the durability, the effect can be obtained in the above content range.
또 다른 특정 양태로서, 본 발명에 따른 교면방수제 조성물은 조성물이 접착되는 피접착면에 존재하는 유해 성분들이 외부로 용출되는 것을 방지함으로써 환경오염을 유발되는 것을 방지하기 위하여 아스팔트 100중량부 기준으로 5 내지 15중량부의 디메틸 암모늄 클로라이드를 더 포함할 수 있다.In another specific embodiment, the crosslinking waterproofing composition according to the present invention is based on 100 parts by weight of asphalt in order to prevent environmental pollution by preventing the harmful components present on the adhered surface to which the composition is adhered to the outside. It may further comprise from 15 parts by weight of dimethyl ammonium chloride.
또 다른 특정 양태로서, 본 발명에 따른 교면방수제 조성물은 조성물의 경도를 향상시키고 표면오염을 감소시키기 위하여 아스팔트 100중량부 기준으로 1 내지 5중량부의 트리메틸올프로판 트리아크릴레이트를 더 포함할 수 있다.In another specific embodiment, the crosslinking waterproofing composition according to the present invention may further include 1 to 5 parts by weight of trimethylolpropane triacrylate based on 100 parts by weight of asphalt to improve the hardness of the composition and reduce surface contamination.
또 다른 특정 양태로서, 본 발명에 따른 교면방수제 조성물은 방수성을 보다 향상시키기 위하여 아스팔트 100중량부 기준으로 10 내지 30중량부의 콜타르 피치를 더 포함할 수 있다.In another specific embodiment, the cross-linking waterproofing composition according to the present invention may further include 10 to 30 parts by weight of coal tar pitch based on 100 parts by weight of asphalt in order to further improve waterproofness.
이와 같은 구성을 갖는 본 발명에 따른 친환경 교면방수제 조성물을 이용한 교면 방수공법을 설명하면 다음과 같다.When explaining the bridge waterproofing method using an environment-friendly bridge waterproofing composition according to the present invention having such a configuration as follows.
본 발명에 따른 친환경 교면방수제 조성물을 이용한 방수공법은 교면방수제 조성물을 시공하기 위한 시공표면을 처리하는 표면처리단계;Waterproofing method using an environmentally friendly bristle waterproofing composition according to the present invention comprises a surface treatment step of treating the construction surface for the construction of a bristle waterproofing composition;
상기 표면처리단계가 종료된 후 톨루엔 40 내지 60중량부와 아스팔트 40 내지 60중량부를 혼합하고 용융시켜 제조한 프라이머를 도포하는 프라이머 도포단계;A primer coating step of applying a primer prepared by mixing and melting 40 to 60 parts by weight of toluene and 40 to 60 parts by weight of asphalt after the surface treatment step is completed;
상기 프라이머 도포단계가 종료된 후 아스팔트 100중량부 기준으로, 스티렌부타디엔스티렌 10 내지 40중량부, 석유수지 1 내지 15중량부, 탄산칼슘 10 내지 30중량부, 메틸메타크릴레이트 5 내지 30중량부, 음이온 유화제 3 내지 20중량부, 옥틸페놀에톡실레이트 1 내지 10중량부, 섬유 3 내지 15중량부, 나노세라믹입자 3 내지 20중량부, 박리방지제 5 내지 30중량부, 산화방지제 3 내지 10중량부, 및 부착증진제 1 내지 20중량부를 포함하는 교면방수제 조성물을 도포하는 교면방수제 조성물 도포단계;After completion of the primer coating step, based on 100 parts by weight of asphalt, 10 to 40 parts by weight of styrene butadiene styrene, 1 to 15 parts by weight of petroleum resin, 10 to 30 parts by weight of calcium carbonate, 5 to 30 parts by weight of methyl methacrylate, 3 to 20 parts by weight of anionic emulsifier, 1 to 10 parts by weight of octyl phenol ethoxylate, 3 to 15 parts by weight of fiber, 3 to 20 parts by weight of nanoceramic particles, 5 to 30 parts by weight of anti-release agent, 3 to 10 parts by weight of antioxidant And a crosslinking waterproofing composition applying step of applying a crosslinking waterproofing composition comprising 1 to 20 parts by weight of an adhesion promoter;
상기 교면방수제 조성물 도포단계가 종료된 후 방수시트를 부착하여 방수시트층을 형성하는 방수시트층 형성단계; 및A waterproof sheet layer forming step of attaching the waterproof sheet to form the waterproof sheet layer after the application of the crosslinking waterproofing composition is completed; And
상기 방수시트층 형성단계가 종료된 후 아스콘 포장을 하는 아스콘 포장단계를 포함하는 교면 방수공법을 제공한다.After the waterproof sheet layer forming step is completed provides an interstitial waterproof method comprising an ascon packaging step of packaging ascon.
여기서, 상기 방수시트층 형성단계의 방수시트는 열가소성수지필름과 부직포가 결합되어 이루어지되, 상기 열가소성수지필름 및 부직포는 교면을 방수도포하는 방수공법에 통상적으로 사용되는 열가소성수지필름 및 부직포를 사용한다.Here, the waterproof sheet of the waterproof sheet layer forming step is made of a thermoplastic resin film and a non-woven fabric, the thermoplastic resin film and the non-woven fabric uses a thermoplastic resin film and a non-woven fabric commonly used in the waterproofing method to waterproof the cross-section. .
상기 부직포는 교면방수제 조성물이 도포된 도막방수층과 접하며, 상기 열가소성수지필름은 상기 포장층과 접하도록 배치되어 상기 포장층 시공시 상기 아스콘 포장단계의 아스콘의 온도 의해 가열되면서 녹거나 변형되어 상기 포장층과 결합되는 것을 포함한다.The nonwoven fabric is in contact with the coating waterproof layer coated with a cross-linking waterproofing composition, the thermoplastic resin film is disposed in contact with the packaging layer is melted or deformed while being heated or heated by the temperature of the ascon packaging step when the packaging layer is constructed, the packaging layer It is combined with.
이하에서 실시예를 통하여 본 발명을 구체적으로 설명하기로 한다. 그러나 하기의 실시예는 오로지 본 발명을 구체적으로 설명하기 위한 것으로 이들 실시예에 의해 본 발명의 범위를 한정하는 것은 아니다.Hereinafter, the present invention will be described in detail through examples. However, the following examples are only for illustrating the present invention in detail and are not intended to limit the scope of the present invention by these examples.
[실시예 1]Example 1
침입도 30의 스트레이트 아스팔트 75g 및 트리니다드레이크 아스팔트로 이루어진 천연 아스팔트 25g의 혼합물로 이루어진 아스팔트 혼합물 100g, 스티렌부타디엔스티렌 30g, 140℃ 점도가 130cps인 지방족 C-5석유수지 7g, 탄산칼슘 20g, 메틸메타아크릴레이트 15g, 수지산나트륨염 12g, 옥틸페놀에톡실레이트 5g, 천연 셀룰로오즈 섬유 10g, 평균입경이 400nm인 실리콘카바이드 12g, 액상형으로 비중이 1.0 이상이고 60℃ 점도가 110 cPs인 폴리인산계 박리방지제 16g, 2.2-메틸렌비스(4-메틸-6-t-부틸페놀) 6g, 및 하이드록시 에틸 아크릴로일 포스페이트 10g를 혼합하여 교면방수제 조성물을 제조하였다.100 g of asphalt mixture consisting of a mixture of 75 g of straight asphalt with a penetration of 30 g and 25 g of natural asphalt consisting of Trinidad and Drake asphalt, 30 g of styrene-butadiene styrene, 7 g of an aliphatic C-5 petroleum resin having a viscosity of 130 cps at 140 ° C, 20 g of calcium carbonate, methyl methacryl 15g rate, 12g sodium resinate, 5g octylphenolethoxylate, 10g natural cellulose fiber, 12g silicon carbide with an average particle size of 400nm, 16g polyphosphoric acid peeling inhibitor with specific gravity of 1.0 or more and a viscosity of 110 cPs at 60 ℃ , 6 g of 2.2-methylenebis (4-methyl-6-t-butylphenol), and 10 g of hydroxyethyl acryloyl phosphate were mixed to prepare a crosslinking waterproofing composition.
[실시예 2]Example 2
실시예 1과 동일한 방법으로 실시하되, 톨루엔 및 검로진이 1:1의 중량비로 혼합된 톨루엔-검로진 혼합물 3g을 더 부가하여 실시하였다.The same procedure as in Example 1 was performed except that 3 g of the toluene-grosene mixture in which toluene and gumrogin were mixed in a weight ratio of 1: 1 was added.
[실시예 3]Example 3
실시예 1과 동일한 방법으로 실시하되, 마그네슘 실리케이트 2g을 사용하여 실시하였다.The same procedure as in Example 1 was conducted except that 2 g of magnesium silicate was used.
[실시예 4]Example 4
실시예 1과 동일한 방법으로 실시하되, 나트륨벤토나이트 6g을 더 부가하여 실시하였다.The same procedure as in Example 1 was conducted except that 6 g of sodium bentonite was further added.
[실시예 5]Example 5
실시예 1과 동일한 방법으로 실시하되, 수산화암모늄 2g을 더 부가하여 실시하였다.The same procedure as in Example 1 was conducted except that 2 g of ammonium hydroxide was added.
[실시예 6]Example 6
실시예 1과 동일한 방법으로 실시하되, 폴리비닐리덴 플루오라이드 수지 3g을 더 부가하여 실시하였다.The same procedure as in Example 1 was conducted except that 3 g of polyvinylidene fluoride resin was further added.
[실시예 7]Example 7
실시예 1과 동일한 방법으로 실시하되, 웰란 검 2g을 더 부가하여 실시하였다.The same procedure as in Example 1 was conducted except that 2 g of wellan gum was added.
[실시예 8]Example 8
실시예 1과 동일한 방법으로 실시하되, 올레인산나트륨 3g을 더 부가하여 실시하였다.The same procedure as in Example 1 was carried out except that 3 g of sodium oleate was further added.
[실시예 9]Example 9
실시예 1과 동일한 방법으로 실시하되, 벤조산 0.5g을 더 부가하여 실시하였다.The same procedure as in Example 1 was carried out except that 0.5 g of benzoic acid was further added.
[실시예 10]Example 10
실시예 1과 동일한 방법으로 실시하되, 규회석 1g을 더 부가하여 실시하였다.The same procedure as in Example 1 was conducted except that 1 g of wollastonite was added.
[실시예 11]Example 11
실시예 1과 동일한 방법으로 실시하되, 메셀로스 5g을 더 부가하여 실시하였다.The same procedure as in Example 1 was carried out except that 5 g of mecellose was further added.
[실시예 12]Example 12
실시예 1과 동일한 방법으로 실시하되, 소듐 벤조 에이트 0.5g을 더 부가하여 실시하였다.The same procedure as in Example 1 was conducted except that 0.5 g of sodium benzoate was further added.
[실시예 13]Example 13
실시예 1과 동일한 방법으로 실시하되, 아크릴니트릴 5g을 더 부가하여 실시하였다.The same procedure as in Example 1 was conducted except that 5 g of acrylonitrile was added.
[실시예 14]Example 14
실시예 1과 동일한 방법으로 실시하되, 피로인산칼슘 1g을 더 부가하여 실시하였다.The same procedure as in Example 1 was conducted except that 1 g of calcium pyrophosphate was further added.
[실시예 15]Example 15
실시예 1과 동일한 방법으로 실시하되, 칼슘아질산염 5g을 더 부가하여 실시하였다.The same procedure as in Example 1 was conducted except that 5 g of calcium nitrite was further added.
[실시예 16]Example 16
실시예 1과 동일한 방법으로 실시하되, 수산화리튬 3g을 더 부가하여 실시하였다.The same procedure as in Example 1 was conducted except that 3 g of lithium hydroxide was further added.
[실시예 17]Example 17
실시예 1과 동일한 방법으로 실시하되, 테트라 플루오로 에틸렌 5g을 더 부가하여 실시하였다.The same procedure as in Example 1 was conducted except that 5 g of tetrafluoroethylene was further added.
[실시예 18]Example 18
실시예 1과 동일한 방법으로 실시하되, 앨라이트 5g을 더 부가하여 실시하였다.The same procedure as in Example 1 was conducted except that 5 g of allite was further added.
[실시예 19]Example 19
실시예 1과 동일한 방법으로 실시하되, 카올리나이트 4g을 더 부가하여 실시하였다.The same procedure as in Example 1 was carried out except that 4 g of kaolinite was added.
[실시예 20]Example 20
실시예 1과 동일한 방법으로 실시하되, 차아염소산염 2g을 더 부가하여 실시하였다.The same procedure as in Example 1 was carried out except that 2 g of hypochlorite was further added.
[실시예 21]Example 21
실시예 1과 동일한 방법으로 실시하되, 술폭시폴리에틸렌글리콜알릴에테르 5g을 더 부가하여 실시하였다.The same procedure as in Example 1 was conducted except that 5 g of sulfoxypolyethylene glycol allyl ether was further added.
[실시예 22]Example 22
실시예 1과 동일한 방법으로 실시하되, 소듐헥사메타포스페이트 5g을 더 부가하여 실시하였다.The same procedure as in Example 1 was conducted except that 5 g of sodium hexametaphosphate was further added.
[실시예 23]Example 23
실시예 1과 동일한 방법으로 실시하되, 소르비탄모노올레산에스테르 3g을 더 부가하여 실시하였다.The same procedure as in Example 1 was carried out except that 3 g of sorbitan monooleic acid ester was further added.
[실시예 24]Example 24
실시예 1과 동일한 방법으로 실시하되, 페닐프로파놀아민 2g을 더 부가하여 실시하였다.The same procedure as in Example 1 was conducted except that 2 g of phenylpropanolamine was further added.
[실시예 25]Example 25
실시예 1과 동일한 방법으로 실시하되, 폴리실리콘 슬러지 3g을 더 부가하여 실시하였다.The same procedure as in Example 1 was conducted except that 3 g of polysilicon sludge was added.
[실시예 26]Example 26
실시예 1과 동일한 방법으로 실시하되, 이타코닉 산 5g을 더 부가하여 실시하였다.The same procedure as in Example 1 was conducted except that 5 g of itaconic acid was further added.
[실시예 27]Example 27
실시예 1과 동일한 방법으로 실시하되, 트리지마이트 5g을 더 부가하여 실시하였다.The same procedure as in Example 1 was carried out except that 5 g of trizimite was added.
[실시예 28]Example 28
실시예 1과 동일한 방법으로 실시하되, 토탄 5g을 더 부가하여 실시하였다.The same procedure as in Example 1 was conducted except that 5 g of peat was added.
[실시예 29]Example 29
실시예 1과 동일한 방법으로 실시하되, 셀룰로오스 아세테이트 부틸레이트 5g을 더 포함시켜 실시하였다.It carried out in the same manner as in Example 1, but was further carried out with 5g of cellulose acetate butyrate.
[실시예 30]Example 30
실시예 1과 동일한 방법으로 실시하되, 산화마그네슘 5g을 더 포함시켜 실시하였다.It carried out in the same manner as in Example 1, but was further carried out with 5g of magnesium oxide.
[실시예 31]Example 31
실시예 1과 동일한 방법으로 실시하되, 코코베타인 5g을 더 포함시켜 실시하였다.It carried out in the same manner as in Example 1, it was carried out by further containing 5g cocobetaine.
[실시예 32]Example 32
실시예 1과 동일한 방법으로 실시하되, 스티렌-아크릴 에스터 공중합체 3g을 더 포함시켜 실시하였다.It carried out in the same manner as in Example 1, it was carried out by further comprising 3g of styrene-acrylic ester copolymer.
[실시예 33]Example 33
실시예 1과 동일한 방법으로 실시하되, 사이클로헥산 3g을 더 포함시켜 실시하였다.It carried out in the same manner as in Example 1, it was carried out by further comprising 3g of cyclohexane.
[실시예 34]Example 34
실시예 1과 동일한 방법으로 실시하되, 탄소수 14 내지 18인 직쇄 불포화지방산 3g을 더 포함시켜 실시하였다.It carried out in the same manner as in Example 1, it was carried out by further comprising 3g of linear unsaturated fatty acids having 14 to 18 carbon atoms.
[실시예 35]Example 35
실시예 1과 동일한 방법으로 실시하되, 초산비닐-말레인산디에틸 10g을 더 부가하여 실시하였다.The same procedure as in Example 1 was conducted except that 10 g of vinyl acetate-diethyl maleate was further added.
[실시예 36]Example 36
실시예 1과 동일한 방법으로 실시하되, 평균입경이 2㎛인 카올린 분말 4g을 더 부가하여 실시하였다.The same procedure as in Example 1 was carried out except that 4 g of kaolin powder having an average particle diameter of 2 μm was added thereto.
[실시예 37]Example 37
실시예 1과 동일한 방법으로 실시하되, 하이드라진 페닐 트리아진 3g을 더 부가하여 실시하였다.The same procedure as in Example 1 was conducted except that 3 g of hydrazine phenyl triazine was further added.
[실시예 38]Example 38
실시예 1과 동일한 방법으로 실시하되, 황산 코발트 3g을 더 부가하여 실시하였다.The same procedure as in Example 1 was conducted except that 3 g of cobalt sulfate was further added.
[실시예 39]Example 39
실시예 1과 동일한 방법으로 실시하되, 플루오린화나트륨 3g을 더 부가하여 실시하였다.The same procedure as in Example 1 was conducted except that 3 g of sodium fluoride was further added.
[실시예 40]Example 40
실시예 1과 동일한 방법으로 실시하되, 디메틸 암모늄 클로라이드 10g을 더 부가하여 실시하였다.The same procedure as in Example 1 was conducted except that 10 g of dimethyl ammonium chloride was further added.
[실시예 41]Example 41
실시예 1과 동일한 방법으로 실시하되, 트리메틸올프로판 트리아크릴레이트 3g을 더 부가하여 실시하였다.The same procedure as in Example 1 was carried out except that 3 g of trimethylolpropane triacrylate was further added.
[실시예 42]Example 42
실시예 1과 동일한 방법으로 실시하되, 콜타르 피치 20g을 더 부가하여 실시하였다.It carried out in the same manner as in Example 1, it was carried out by adding a further 20g coal tar pitch.
[실시예 43]Example 43
실시예 1과 동일한 방법으로 실시하되, 실시예 2 내지 실시예 42에 부가된 부가물을 모두 부가하여 실시하였다.The same procedure as in Example 1 was carried out except that all the additives added in Examples 2 to 42 were added.
[실험][Experiment]
가로/세로 50cm의 넓이의 콘크리트 표면에 톨루엔 50g과 아스팔트 50g을 혼합하여 용융시켜 제조한 프라이머를 도포하여 프라이머층을 제조하였다.A primer layer was prepared by applying a primer prepared by mixing 50 g of toluene and 50 g of asphalt on a concrete surface having a width of 50 cm.
그 다음, 실시예들에 따라 제조된 교면방수제 조성물을 약 1mm 두께로 도포하였다.Next, the crosslinking waterproofing composition prepared according to the examples was applied to a thickness of about 1 mm.
그 다음, 방수층의 위에 폴리에틸렌 수지와 부직포로 구성된 방수시트를 부착하여 방수시트층을 형성시켰다.Then, a waterproof sheet made of polyethylene resin and nonwoven fabric was attached on the waterproof layer to form a waterproof sheet layer.
그 다음, 상기 방수시트층의 위에 아스콘을 타설하여 포장층을 형성한 뒤 부착성, 방수성, 건조수축률, 유해성분 용출여부 등을 측정하여 표 1로 나타냈다.Next, ascon was poured on the waterproof sheet layer to form a packaging layer, and the adhesion, waterproofness, dry shrinkage rate, and toxic component elution were measured and shown in Table 1 below.
표 1에 나타난 바와 같이, 실시예 1 내지 실시예 43에 따라 제조된 교면방수제 조성물의 방수성, 부착성 및 건조수축률이 좋고, 유해성분이 용출되지 않는 것으로 나타났다.As shown in Table 1, the waterproofing, adhesiveness and dry shrinkage rate of the crosslinking waterproofing composition prepared according to Examples 1 to 43 was good, and no harmful components were eluted.
이상에서 설명한 바와 같이, 본 발명이 속하는 기술 분야의 당업자는 본 발명이 그 기술적 사상이나 필수적 특징을 변경하지 않고서 다른 구체적인 형태로 실시될 수 있다는 것을 이해할 수 있을 것이다. 그러므로 이상에서 기술한 실시예는 모두 예시적인 것이며 한정적인 것이 아닌 것으로서 이해해야만 한다. 본 발명의 범위는 상기 상세한 설명보다는 후술하는 특허청구범위의 의미 및 범위 그리고 그 등가개념으로부터 도출되는 모두 변경 또는 변형된 형태가 본 발명의 범위에 포함되는 것으로 해석되어야 한다.As described above, those skilled in the art will understand that the present invention can be implemented in other specific forms without changing the technical spirit or essential features. Therefore, it should be understood that the embodiments described above are all illustrative and not restrictive. The scope of the present invention should be construed as being included in the scope of the present invention all changes or modifications derived from the meaning and scope of the appended claims rather than the detailed description and equivalent concepts thereof.
Claims (3)
스티렌부타디엔스티렌 10 내지 40중량부;
140℃ 점도가 130cps인 지방족 C-5석유수지 1 내지 15중량부;
탄산칼슘 10 내지 30중량부;
메틸메타크릴레이트 5 내지 30중량부;
음이온 유화제 3 내지 20중량부;
옥틸페놀에톡실레이트 1 내지 10중량부;
섬유 3 내지 15중량부;
나노세라믹입자 3 내지 20중량부;
박리방지제 5 내지 30중량부;
산화방지제 3 내지 10중량부; 및
부착증진제 1 내지 20중량부를 포함하는 교면방수제 조성물에,
나트륨벤토나이트를 아스팔트 100중량부 기준으로 1 내지 10중량부로 더 포함하고,
수산화암모늄을 아스팔트 100중량부 기준으로 1 내지 5중량부로 더 포함하며,
폴리비닐리덴 플루오라이드 수지를 아스팔트 100중량부 기준으로 1 내지 5중량부로 더 포함하고,
벤조산을 아스팔트 100중량부 기준으로 0.1 내지 2중량부로 더 포함하며,
규회석을 아스팔트 100중량부 기준으로 0.1 내지 2중량부로 더 포함하고,
메셀로스를 아스팔트 100중량부 기준으로 1 내지 5중량부로 더 포함하며,
아크릴니트릴을 아스팔트 100중량부 기준으로 1 내지 10중량부로 더 포함하고,
칼슘아질산염을 아스팔트 100중량부 기준으로 1 내지 10중량부로 더 포함하며,
수산화리튬을 아스팔트 100중량부 기준으로 1 내지 5중량부로 더 포함하고,
테트라 플루오로 에틸렌을 아스팔트 100중량부 기준으로 1 내지 10중량부로 더 포함하며,
앨라이트를 아스팔트 100중량부 기준으로 1 내지 10중량부로 더 포함하고,
카올리나이트를 아스팔트 100중량부 기준으로 2 내지 8중량부로 더 포함하며,
차아염소산염을 아스팔트 100중량부 기준으로 0.1 내지 3중량부로 더 포함하고,
술폭시폴리에틸렌글리콜알릴에테르를 아스팔트 100중량부 기준으로 1 내지 10중량부로 더 포함하며,
소듐헥사메타포스페이트를 아스팔트 100중량부 기준으로 1 내지 10중량부로 더 포함하고,
페닐프로파놀아민을 아스팔트 100중량부 기준으로 1 내지 3중량부로 더 포함하며,
이타코닉 산을 아스팔트 100중량부 기준으로 1 내지 10중량부로 더 포함하고,
트리지마이트를 아스팔트 100중량부 기준으로 1 내지 10중량부로 더 포함하며,
토탄을 아스팔트 100중량부 기준으로 0.1 내지 10중량부로 더 포함하고,
셀룰로오스 아세테이트 부틸레이트를 아스팔트 100중량부 기준으로 1 내지 10중량부로 더 포함하며,
산화마그네슘을 아스팔트 100중량부 기준으로 1 내지 10중량부로 더 포함하고,
황산 코발트를 아스팔트 100중량부 기준으로 1 내지 5중량부로 더 포함하는 교면방수제 조성물.
Based on 100 parts by weight of asphalt,
10 to 40 parts by weight of styrene butadiene styrene;
1 to 15 parts by weight of an aliphatic C-5 petroleum resin having a viscosity of 130 cps at 140 ° C;
10 to 30 parts by weight of calcium carbonate;
5 to 30 parts by weight of methyl methacrylate;
3 to 20 parts by weight of anionic emulsifier;
1 to 10 parts by weight of octylphenolethoxylate;
3 to 15 parts by weight of fibers;
3 to 20 parts by weight of nanoceramic particles;
5 to 30 parts by weight of a peeling inhibitor;
3 to 10 parts by weight of antioxidant; And
In a crosslinking waterproofing composition comprising 1 to 20 parts by weight of adhesion promoter,
Sodium bentonite further comprises 1 to 10 parts by weight based on 100 parts by weight of asphalt,
Ammonium hydroxide further comprises 1 to 5 parts by weight based on 100 parts by weight of asphalt,
Further comprising 1 to 5 parts by weight of polyvinylidene fluoride resin based on 100 parts by weight of asphalt,
Benzoic acid further comprises 0.1 to 2 parts by weight based on 100 parts by weight of asphalt,
Wollastonite further comprises 0.1 to 2 parts by weight based on 100 parts by weight of asphalt,
Mescelose is further included 1 to 5 parts by weight based on 100 parts by weight of asphalt,
Acryl nitrile further comprises 1 to 10 parts by weight based on 100 parts by weight of asphalt,
Calcium nitrite further comprises 1 to 10 parts by weight based on 100 parts by weight of asphalt,
Lithium hydroxide further comprises 1 to 5 parts by weight based on 100 parts by weight of asphalt,
Tetrafluoroethylene further comprises 1 to 10 parts by weight based on 100 parts by weight of asphalt,
It further comprises an allite in an amount of 1 to 10 parts by weight based on 100 parts by weight of asphalt,
Kaolinite further comprises 2 to 8 parts by weight based on 100 parts by weight of asphalt,
Hypochlorite further comprises 0.1 to 3 parts by weight based on 100 parts by weight of asphalt,
Sulfoxy polyethylene glycol allyl ether further comprises 1 to 10 parts by weight based on 100 parts by weight of asphalt,
Sodium hexametaphosphate further comprises 1 to 10 parts by weight based on 100 parts by weight of asphalt,
Further comprising 1 to 3 parts by weight of phenylpropanolamine based on 100 parts by weight of asphalt,
Itaconic acid further comprises 1 to 10 parts by weight based on 100 parts by weight of asphalt,
Further comprises 1 to 10 parts by weight of trizimite based on 100 parts by weight of asphalt,
Peat is further included 0.1 to 10 parts by weight based on 100 parts by weight of asphalt,
Cellulose acetate butyrate further comprises 1 to 10 parts by weight based on 100 parts by weight of asphalt,
Magnesium oxide further comprises 1 to 10 parts by weight based on 100 parts by weight of asphalt,
Cross-coating waterproofing composition further comprises 1 to 5 parts by weight of cobalt sulfate based on 100 parts by weight of asphalt.
상기 표면처리단계가 종료된 후 톨루엔 40 내지 60중량부와 아스팔트 40 내지 60중량부를 혼합하고 용융시켜 제조한 프라이머를 도포하는 프라이머 도포단계;
상기 프라이머 도포단계가 종료된 후 아스팔트 100중량부 기준으로, 스티렌부타디엔스티렌 10 내지 40중량부, 140℃ 점도가 130cps인 지방족 C-5석유수지 1 내지 15중량부, 탄산칼슘 10 내지 30중량부, 메틸메타크릴레이트 5 내지 30중량부, 음이온 유화제 3 내지 20중량부, 옥틸페놀에톡실레이트 1 내지 10중량부, 섬유 3 내지 15중량부, 나노세라믹입자 3 내지 20중량부, 박리방지제 5 내지 30중량부, 산화방지제 3 내지 10중량부, 및 부착증진제 1 내지 20중량부를 포함하는 교면방수제 조성물에, 나트륨벤토나이트를 아스팔트 100중량부 기준으로 1 내지 10중량부로 더 포함하고, 수산화암모늄을 아스팔트 100중량부 기준으로 1 내지 5중량부로 더 포함하며, 폴리비닐리덴 플루오라이드 수지를 아스팔트 100중량부 기준으로 1 내지 5중량부로 더 포함하고, 벤조산을 아스팔트 100중량부 기준으로 0.1 내지 2중량부로 더 포함하며, 규회석을 아스팔트 100중량부 기준으로 0.1 내지 2중량부로 더 포함하고, 메셀로스를 아스팔트 100중량부 기준으로 1 내지 5중량부로 더 포함하며, 아크릴니트릴을 아스팔트 100중량부 기준으로 1 내지 10중량부로 더 포함하고, 칼슘아질산염을 아스팔트 100중량부 기준으로 1 내지 10중량부로 더 포함하며, 수산화리튬을 아스팔트 100중량부 기준으로 1 내지 5중량부로 더 포함하고, 테트라 플루오로 에틸렌을 아스팔트 100중량부 기준으로 1 내지 10중량부로 더 포함하며, 앨라이트를 아스팔트 100중량부 기준으로 1 내지 10중량부로 더 포함하고, 카올리나이트를 아스팔트 100중량부 기준으로 2 내지 8중량부로 더 포함하며, 차아염소산염을 아스팔트 100중량부 기준으로 0.1 내지 3중량부로 더 포함하고, 술폭시폴리에틸렌글리콜알릴에테르를 아스팔트 100중량부 기준으로 1 내지 10중량부로 더 포함하며, 소듐헥사메타포스페이트를 아스팔트 100중량부 기준으로 1 내지 10중량부로 더 포함하고, 페닐프로파놀아민을 아스팔트 100중량부 기준으로 1 내지 3중량부로 더 포함하며, 이타코닉 산을 아스팔트 100중량부 기준으로 1 내지 10중량부로 더 포함하고, 트리지마이트를 아스팔트 100중량부 기준으로 1 내지 10중량부로 더 포함하며, 토탄을 아스팔트 100중량부 기준으로 0.1 내지 10중량부로 더 포함하고, 셀룰로오스 아세테이트 부틸레이트를 아스팔트 100중량부 기준으로 1 내지 10중량부로 더 포함하며, 산화마그네슘을 아스팔트 100중량부 기준으로 1 내지 10중량부로 더 포함하고, 황산 코발트를 아스팔트 100중량부 기준으로 1 내지 5중량부로 더 포함하는 교면방수제 조성물을 도포하는 교면방수제 조성물 도포단계;
상기 교면방수제 조성물 도포단계가 종료된 후 방수시트를 부착하여 방수시트층을 형성하는 방수시트층 형성단계; 및
상기 방수시트층 형성단계가 종료된 후 아스콘 포장을 하는 아스콘 포장단계를 포함하는 교면 방수공법.A surface treatment step of treating the construction surface for constructing the crosslinking waterproofing composition;
A primer coating step of applying a primer prepared by mixing and melting 40 to 60 parts by weight of toluene and 40 to 60 parts by weight of asphalt after the surface treatment step is completed;
After completion of the primer coating step, based on 100 parts by weight of asphalt, 10 to 40 parts by weight of styrene butadiene styrene, 1 to 15 parts by weight of aliphatic C-5 petroleum resin having a viscosity of 130 cps at 140 ° C, 10 to 30 parts by weight of calcium carbonate, 5 to 30 parts by weight of methyl methacrylate, 3 to 20 parts by weight of anionic emulsifier, 1 to 10 parts by weight of octylphenol ethoxylate, 3 to 15 parts by weight of fiber, 3 to 20 parts by weight of nanoceramic particles, 5 to 30 anti-peeling agent In the crosslinking waterproofing composition comprising parts by weight, 3 to 10 parts by weight of antioxidant, and 1 to 20 parts by weight of adhesion promoter, sodium bentonite is further included in an amount of 1 to 10 parts by weight based on 100 parts by weight of asphalt, and 100 parts by weight of ammonium hydroxide. It further comprises 1 to 5 parts by weight based on parts, further comprises 1 to 5 parts by weight of polyvinylidene fluoride resin based on 100 parts by weight of asphalt, benzoic acid asphalt It further comprises 0.1 to 2 parts by weight based on 100 parts by weight, further comprises wollastonite as 0.1 to 2 parts by weight based on 100 parts by weight of asphalt, and 1 to 5 parts by weight of mecellose based on 100 parts by weight of asphalt, and acrylic Nitrile is further included from 1 to 10 parts by weight based on 100 parts by weight of asphalt, calcium nitrite is further included from 1 to 10 parts by weight based on 100 parts by weight of asphalt, and lithium hydroxide is added to 1 to 5 parts by weight based on 100 parts by weight of asphalt. It further comprises tetrafluoro ethylene in an amount of 1 to 10 parts by weight based on 100 parts by weight of asphalt, further includes 1 to 10 parts by weight of allite based on 100 parts by weight of asphalt, and kaolinite based on 100 parts by weight of asphalt 2 To 8 parts by weight further, hypochlorite 0.1 to 3 parts by weight based on 100 parts by weight of asphalt, sulfoxypol Ethylene glycol allyl ether further comprises 1 to 10 parts by weight based on 100 parts by weight of asphalt, further comprises 1 to 10 parts by weight of sodium hexametaphosphate based on 100 parts by weight of asphalt, 100 parts by weight of phenylpropanolamine It further comprises 1 to 3 parts by weight based on 100 parts by weight of itaconic acid based on 1 to 10 parts by weight, further comprises trizimite to 1 to 10 parts by weight based on 100 parts by weight of asphalt, peat 0.1 to 10 parts by weight based on 100 parts by weight of asphalt, cellulose acetate butyrate further comprises 1 to 10 parts by weight based on 100 parts by weight of asphalt, and magnesium oxide by 1 to 10 parts by weight based on 100 parts by weight of asphalt. Cross-linking waterproofing composition comprising more, 1 to 5 parts by weight based on 100 parts by weight of asphalt cobalt Bridge Deck repellant coating composition comprising: applying a;
A waterproof sheet layer forming step of attaching the waterproof sheet to form the waterproof sheet layer after the application of the crosslinking waterproofing composition is completed; And
Cross-section waterproofing method comprising the ascon packaging step of ascon packaging after the step of forming the waterproof sheet layer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020190089084A KR102036879B1 (en) | 2019-07-23 | 2019-07-23 | A Eco-friendly Waterproofing Treatment Composition for Road and Waterproofing Methods using Thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020190089084A KR102036879B1 (en) | 2019-07-23 | 2019-07-23 | A Eco-friendly Waterproofing Treatment Composition for Road and Waterproofing Methods using Thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR102036879B1 true KR102036879B1 (en) | 2019-10-25 |
Family
ID=68420415
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020190089084A KR102036879B1 (en) | 2019-07-23 | 2019-07-23 | A Eco-friendly Waterproofing Treatment Composition for Road and Waterproofing Methods using Thereof |
Country Status (1)
| Country | Link |
|---|---|
| KR (1) | KR102036879B1 (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102203028B1 (en) * | 2020-11-04 | 2021-01-14 | 김지태 | Environment Friendly Permeative Waterproof Agent Composition of Cream Type and Waterproofing Methods Using Thereof |
| CN112280473A (en) * | 2020-10-14 | 2021-01-29 | 上海东方雨虹防水技术有限责任公司 | Modified asphalt coating material and modified asphalt waterproof coiled material |
| KR102231335B1 (en) * | 2020-10-29 | 2021-03-24 | 주식회사 지케이기술연구소 | Coating Composition for Prime Coating Comprising Stylene Isoprene Stylene and Petroleum Resin Added Hydrogen and Constructing Methods Using Thereof |
| CN115074030A (en) * | 2022-08-03 | 2022-09-20 | 苏州市月星建筑防水材料有限公司 | High-viscosity anti-slip water-based polymer asphalt waterproof coating and preparation method and construction method thereof |
| CN116622290A (en) * | 2023-06-13 | 2023-08-22 | 北京建海中建国际防水材料有限公司 | Black gold steel fluorocarbon modified high-performance waterproof paint and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101776893B1 (en) * | 2017-02-20 | 2017-09-08 | 주식회사 라온건설기술 | A Eco-friendly Waterproofing Treatment Composition for Road and Waterproofing Methods using Thereof |
| KR101900004B1 (en) * | 2018-05-10 | 2018-09-18 | 김상운 | A Eco-friendly Waterproofing Treatment Composition for Road and Waterproofing Methods using Thereof |
| KR101954235B1 (en) * | 2018-10-08 | 2019-03-06 | 주식회사 지케이기술연구소 | Asphalt Waterproofing Agent Composition Comprising SIS and SBS and Constructing Methods Using Thereof |
-
2019
- 2019-07-23 KR KR1020190089084A patent/KR102036879B1/en active IP Right Grant
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101776893B1 (en) * | 2017-02-20 | 2017-09-08 | 주식회사 라온건설기술 | A Eco-friendly Waterproofing Treatment Composition for Road and Waterproofing Methods using Thereof |
| KR101900004B1 (en) * | 2018-05-10 | 2018-09-18 | 김상운 | A Eco-friendly Waterproofing Treatment Composition for Road and Waterproofing Methods using Thereof |
| KR101954235B1 (en) * | 2018-10-08 | 2019-03-06 | 주식회사 지케이기술연구소 | Asphalt Waterproofing Agent Composition Comprising SIS and SBS and Constructing Methods Using Thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112280473A (en) * | 2020-10-14 | 2021-01-29 | 上海东方雨虹防水技术有限责任公司 | Modified asphalt coating material and modified asphalt waterproof coiled material |
| KR102231335B1 (en) * | 2020-10-29 | 2021-03-24 | 주식회사 지케이기술연구소 | Coating Composition for Prime Coating Comprising Stylene Isoprene Stylene and Petroleum Resin Added Hydrogen and Constructing Methods Using Thereof |
| KR102203028B1 (en) * | 2020-11-04 | 2021-01-14 | 김지태 | Environment Friendly Permeative Waterproof Agent Composition of Cream Type and Waterproofing Methods Using Thereof |
| CN115074030A (en) * | 2022-08-03 | 2022-09-20 | 苏州市月星建筑防水材料有限公司 | High-viscosity anti-slip water-based polymer asphalt waterproof coating and preparation method and construction method thereof |
| CN116622290A (en) * | 2023-06-13 | 2023-08-22 | 北京建海中建国际防水材料有限公司 | Black gold steel fluorocarbon modified high-performance waterproof paint and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR102036879B1 (en) | A Eco-friendly Waterproofing Treatment Composition for Road and Waterproofing Methods using Thereof | |
| KR101954235B1 (en) | Asphalt Waterproofing Agent Composition Comprising SIS and SBS and Constructing Methods Using Thereof | |
| CN107033611B (en) | High-grade asphalt composition with waterproof function and construction method using same | |
| KR101776893B1 (en) | A Eco-friendly Waterproofing Treatment Composition for Road and Waterproofing Methods using Thereof | |
| KR101900004B1 (en) | A Eco-friendly Waterproofing Treatment Composition for Road and Waterproofing Methods using Thereof | |
| KR101954238B1 (en) | Waterproofing Treatment Composition Comprising SIS and Waterproofing Methods using Thereof | |
| KR102318294B1 (en) | A Eco-friendly Waterproofing Treatment Composition for Road and Waterproofing Methods using Thereof | |
| KR101835081B1 (en) | High Grade Waterproofing Asphalt Concrete Composition of Low-Temperature Cure Type Having Crack Reducing Effects and Constructing Methods for Using Thereof | |
| KR102040532B1 (en) | Modified-Asphalt Concrete Composition for Paving Road Using Petroleum Resin Added Hydrogen and Stylene Isoprene Stylene and Constructing Methods Using Thereof | |
| KR101961270B1 (en) | Color Guss Mastic Asphalt Concrete Composition Using Stylene Isoprene Stylene and Constructing Methods Using Thereof | |
| KR102058021B1 (en) | A Waterproofing Treatment Composition for Road and Complex Waterproofing Methods using Waterproofing Sheet | |
| KR102054820B1 (en) | Waterproof Asphalt Concrete Composition for Overlay Pavement Using Petroleum Resin Added Hydrogen, Stylene Isoprene Stylene and Stylene Butadien Stylene and Constructing Methods of Entire Type Waterproof for Cracks of Surface Using Thereof | |
| KR100791587B1 (en) | Asphalt waterproof composition for building and manufacturing method thereof | |
| KR102119756B1 (en) | Asphalt Waterproofing Agent Composition Comprising Styrene Isoprene Styrene, Styrene Ethylene Butylene Styrene and Aggregate-powder of Improved Grain Size and Constructing Methods Using Thereof | |
| KR102052402B1 (en) | Binder Compositions for Asphalt Concrete Using Petroleum Resin Added Hydrogen and Stylene Isoprene Stylene and Constructing Methods Using Thereof | |
| KR102117062B1 (en) | Crack reduction type quick-hardening cement concrete composition comprising phase change material and functional binder, or repairing method for road pavement therewith | |
| KR102178147B1 (en) | A Waterproofing Treatment Composition for Road and Waterproofing Methods using Thereof | |
| KR102058674B1 (en) | Modified-Asphalt Concrete Composition and Constructing Methods Using Thereof | |
| KR20180126269A (en) | Method for preparing concrete crack penetrating sealing material, the concrete crack penetrating sealing material and the application method thereof | |
| KR102059840B1 (en) | Waterproof Asphalt Concrete Composition for Thin Overlay Pavement Using Petroleum Resin Added Hydrogen and Stylene Isoprene Stylene and Constructing Repairing Method of Entire Type Waterproof for Cracks of Surface Using Thereof | |
| KR101806135B1 (en) | Waterproof composition of Self-healing type composition and waterproof method using fiber reinforcing agent | |
| KR100605003B1 (en) | A road repairing composit and tape using it and manufacturing method thereof | |
| KR102059837B1 (en) | Half-Elastic Modified Asphalt Concrete Composition Using Petroleum Resin Added Hydrogen and Stylene Isoprene Stylene and Constructing Repairing Method of Entire Type Waterproof for Cracks of Surface Using Thereof | |
| KR102574077B1 (en) | A Eco-friendly Waterproofing Treatment Composition for Road and Waterproofing Methods using Thereof | |
| KR102460723B1 (en) | Aspalt seal-waterproofing material and water-proofing method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| E701 | Decision to grant or registration of patent right | ||
| GRNT | Written decision to grant |