KR102032124B1 - Leather yarn and its manufacturing method - Google Patents

Leather yarn and its manufacturing method Download PDF

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KR102032124B1
KR102032124B1 KR1020180052351A KR20180052351A KR102032124B1 KR 102032124 B1 KR102032124 B1 KR 102032124B1 KR 1020180052351 A KR1020180052351 A KR 1020180052351A KR 20180052351 A KR20180052351 A KR 20180052351A KR 102032124 B1 KR102032124 B1 KR 102032124B1
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South Korea
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natural leather
yarn
leather powder
powder
adhesive
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KR1020180052351A
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Korean (ko)
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김종원
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김종원
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    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/06Threads formed from strip material other than paper
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/22Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
    • D02G3/40Yarns in which fibres are united by adhesives; Impregnated yarns or threads
    • D02G3/408Flocked yarns

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Textile Engineering (AREA)
  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)

Abstract

Provided is a method for manufacturing a leather yarn, which prepares natural leather powder of a predetermined size, manufactured by degreasing, refining, dyeing, grinding, and electroplating waste leather, and a fiber selected from synthetic fibers including a water-soluble polyurethane adhesive and a nylon filament yarn as a core yarn, applies an adhesive to a surface of the core yarn, and supplies the natural leather powder to a flocking chamber while passing through the flocking chamber. Also, the natural leather powder is planted on the surface of the core yarn passing through the flocking chamber by generating high pressure static electricity to be dried. In addition, a brush roller is in contact with a dried chamber not to be planted on the surface of the core yarn. The stained natural leather powder is dropped by the brush roller, and the surface of the natural leather powder is polished by sand paper. Therefore, a leather yarn having a circular outer diameter while having the texture and appearance of natural leather is manufactured to be conveniently used for various purposes.

Description

폐가죽을 활용하는 가죽사 제조방법{Leather yarn and its manufacturing method}Leather yarn manufacturing method using waste leather {Leather yarn and its manufacturing method}

본 발명은 폐가죽을 활용하여 얻어지는 가죽사 제조방법 및 그 가죽사에 관한 것으로 보다 구체적인 것은, 폐가죽을 탈지, 정련, 염색하여 분쇄하고, 전착처리하여 제조한 일정규격의 천연가죽분말과, 수용성폴리우레탄접착제와, 나일론필라멘트사를 포함하는 합성섬유 중에서 선택한 섬유를 중심사로 준비하여 중심사 표면에 접착제를 도포하고, 플로킹룸을 통과시키면서 플로킹룸에 천연가죽분말을 공급하고, 고압정전기를 발생시켜 플로킹룸을 통과하는 중심사 표면에 천연가죽분말을 식모한 다음 건조시키며, 건조된 중심사의 표면에 브러시롤러를 접촉시켜서 중심사 표면에 식모가 되지 않고, 묻어 있는 천연가죽분말을 브러시롤러로 떨어낸 다음, 샌드페이퍼로 천연가죽분말의 표면을 연마하여 천연가죽의 질감과 외관을 가지면서 외경이 원형으로 되는 가죽사를 제조하여 편리하게 사용할 수 있는 가죽사 제조방법이 제공하여 천연가죽의 질감과 외모를 가지는 가죽사를 제공하고, 더불어 가죽사의 단면이 일반실과 같은 원형을 유지하게 제조하여 단면이 4각형으로 된 실에서 일어날 수 있는 실의 꼬임이나 튀틀림 결합이 없는 천연질감의 가죽사를 제공한다.
또한, 본 발명은 중심사 표면에서 떨어낸 천연가죽분말을 집진기로 회수하여 다시 사용하게 된다.
The present invention relates to a method for manufacturing leather yarn obtained by utilizing waste leather and to the leather yarn, and more specifically, to a specific standard of natural leather powder prepared by degreasing, refining, dyeing, grinding and electrodeposition of waste leather, and water-soluble polyurethane. Prepare the selected fiber among the adhesive and synthetic fiber including nylon filament yarn as a center yarn, apply adhesive on the surface of the center yarn, supply natural leather powder to the flocking room while passing through the flocking room, and generate high pressure static electricity. The natural leather powder is planted on the surface of the core yarn passing through and dried, and the brush roller is brought into contact with the surface of the dried core yarn so that it does not grow on the surface of the core yarn. The surface of natural leather powder is polished with sand paper to give the texture and appearance of natural leather The leather yarn manufacturing method which can be used conveniently by manufacturing the leather yarn is provided to provide the leather yarn having the texture and appearance of natural leather, and the cross section of the leather yarn is manufactured to maintain the same circular shape as the general thread. Provides natural leather thread without twisting or torsional bonding of threads that can occur in square yarns.
In addition, the present invention is used to recover the natural leather powder dropped from the surface of the core yarn with a dust collector.

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종래의 가죽사는 천연가죽을 세폭으로 절개하여 사용하거나 박판으로 만들어 기존의 실 외면에 감아서 피복하는 방법으로 제조하였기 때문에 실의 단면을 원형으로 제조할 수 없어 사용중에 뒤틀림과 비꼬임이 일어나는 문제가 있고, 굵기가 균등하지 않아 의류, 가방, 신발을 비롯하여 인테리어 분야에 적용할 때 사용이 제한되어 부족함이 많은 불편이 있었다.Conventional leather yarns are manufactured by cutting natural leather into thin sections, or by laminating and coating them on the outer surface of existing yarns, so that the cross section of the yarns cannot be manufactured in a circular shape, causing distortion and twisting during use. In addition, since the thickness is not even, there are many inconveniences in that the use is limited when applied to the interior field including clothing, bags and shoes.

선행기술 실용신안공개 20-1984-0006011호Utility Model Publication 20-1984-0006011

본 발명은 상기 불편을 해소하기 위하여 개발된 것이다.The present invention has been developed to solve the above inconvenience.

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본 발명은 폐가죽을 탈지, 정련, 염색, 분쇄하고 전착처리하여 제조한 평균 입경 3 ~ 10 미크론 규격을 가지는 천연가죽분말준비단계와,
수용성폴리우레탄에 수용성폴리우레탄 100중량부 대비 3중량부의 경화제, 0.3중량부 ~ 0.4중량부의 천연가죽분말색상과 같은 안료 및 적정량의 증점제를 혼합하여 점도 4000 ~ 9000 CPS를 유지하도록 제조한 수용성폴리우레탄접착제준비단계와,
420 ~ 840 데니어 규격을 가지는 나일론필라멘트사를 포함하는 합성섬유 중에서 선택한 섬유를 중심사로 선택하는 중심사준비단계와,
준비된 중심사 표면에 수용성폴리우레탄 접착제를 40∼60㎛ 두께로 도포하는 접착제 도포단계와,
접착제가 도포된 중심사를 플로킹룸으로 공급하고, 플로킹룸 상부에서 플로킹룸 내부로 천연가죽분말을 공급하면서 플로킹룸 내부에 20 ~ 30KV 고압정전기를 발생시켜 플로킹룸을 분당 15 ~ 20m 속도로 통과하는 중심사 표면에 도포된 접착제에 천연가죽분말을 충돌시켜 천연가죽분말이 접착제에 식모되게 한 천연가죽분말식모단계와,
천연가죽분말이 식모된 중심사를 120℃에서 15분간 열풍처리하여 건조시키는 단계와,
건조된 중심사에 브러시롤러를 접촉시켜 중심사에 식모되지 않고 표면에 묻어 있는 상태로 남아 있는 천연가죽분말을 브러시롤러로 떨어내는 천연가죽분말분리단계와,
천연가죽분말이 식모된 중심사를 회전하는 샌드페이퍼에 접촉시켜 천연가죽분말 표면을 연마하고, 실의 단면을 원형으로 가공하는 표면 가공 단계를 실시하여 가죽사를 제조하고 제조된 가죽사를 보빈에 권취하는 단계로 가죽사를 제조하는 것이다.
즉, 폐가죽을 탈지, 정련, 염색, 분쇄하고 전착처리하여 제조한 평균 입경 3~10미크론 되는 천연가죽분말과, 수용성폴리우레탄 100중량부 대비 3중량부의 경화제와 0.3중량부 ~ 0.4중량부의 천연가죽분말색상과 같은 안료와 약간의 증점제를 혼합하여 용도에 맞도록 점도를 조정한 수용성폴리우레탄접착제와, 420 ~ 840 데니어 규격을 가지는 나일론필라멘트사를 포함하는 합성섬유 중에서 선택한 섬유를 중심사로 준비하고, 중심사 표면에 수용성폴리우레탄접착제를 도포하여 도포된 접착제에 천연가죽분말을 플로킹룸 공법으로 식모하여 중심사와 일체가 되는 가죽사를 제공하기 위한 것이다.
The present invention is a natural leather powder preparation step having an average particle size of 3 ~ 10 microns prepared by degreasing, refining, dyeing, grinding and electrodeposition waste leather,
A water-soluble polyurethane prepared to maintain a viscosity of 4000 to 9000 CPS by mixing a water-soluble polyurethane with 3 parts by weight of a curing agent, 0.3 parts by weight to 0.4 parts by weight of a pigment such as natural leather powder, and an appropriate amount of a thickener. Adhesive preparation step,
A core yarn preparation step of selecting a fiber selected from synthetic fibers including nylon filament yarn having 420 to 840 denier as a core yarn;
An adhesive coating step of applying a water-soluble polyurethane adhesive to the prepared core yarn surface to a thickness of 40 to 60㎛,
The adhesive coated central yarn is supplied to the flocking room, and the natural leather powder is supplied from the top of the flocking room to the flocking room while generating high pressure static electricity in the flocking room to pass the flocking room at a speed of 15 to 20m per minute. Natural leather powder seedling step in which the natural leather powder is planted in the adhesive by colliding the natural leather powder with the adhesive applied on the surface of the core yarn;
A step of drying the core yarn in which the natural leather powder is planted by hot air treatment at 120 ° C. for 15 minutes, and
A natural leather powder separation step of contacting the dried roller with a brush roller and dropping the natural leather powder remaining on the surface without being planted in the central yarn with a brush roller;
The core of the natural leather powder is brought into contact with the rotating sandpaper to polish the surface of the natural leather powder, and the surface processing step of processing the cross section of the yarn is carried out to manufacture the leather yarn. The steps taken are to manufacture leather yarn.
That is, natural leather powder having an average particle diameter of 3 to 10 microns prepared by degreasing, refining, dyeing, pulverizing and electrodepositing waste leather, 3 parts by weight of a curing agent and 0.3 parts by weight to 0.4 parts by weight of natural leather, relative to 100 parts by weight of water-soluble polyurethane. Prepare a fiber selected from a synthetic fiber including a water-soluble polyurethane adhesive with a viscosity such as powder color and a slight thickener to adjust the viscosity to suit the application, and nylon filament yarn having a 420 ~ 840 denier standard, It is to provide a leather yarn integral with the core yarn by planting the natural leather powder in the flocking room method to the adhesive applied by applying a water-soluble polyurethane adhesive on the surface of the core yarn.

이와 같이 된 본 발명은 폐가죽을 활용하여 제조한 일정규격의 천연가죽분말을 수용성폴리우레탄접착제가 도포된 중심사 표면에 공급하고, 고압정전기를 발생시킴으로써, 플로킹 공법으로 천연가죽분말이 접착제에 충돌하는 힘으로 식모되어 접착되고, 실의 단면이 원형을 유지하도록 연마가공하여 실을 제조하였기 때문에 천연가죽분말이 견고하게 중심사 표면에 부착되어 내구성을 가지게 되며, 제조된 가죽사가 천연가죽과 같은 질감과 외관을 유지하면서 일반실과 같은 모양을 낼 수 있어 제직, 편직에 사용할 수 있을 뿐 아니라 신발, 가방, 인테리어분야에 다양하게 활용할 수 있는 이점이 있다.
또한, 본 발명은 천연가죽분말을 평균 입경 3 ~ 10미크론 되게 분말한 것을 준비하고, 중심사 표면에 수용성폴리우레탄접착제를 40 ~ 60㎛ 두께로 도포하여 플로킹룸에 공급하고, 플로킹룸 상부에서 플로킹룸 속으로 준비한 천연가죽분말을 공급하면서 20 ~ 30KV 고압정전기를 발생시킴으로써, 플로킹룸에 공급된 천연가죽분말이 정전기압을 받아 플로킹룸을 지나가는 중심사 표면에 도포한 접착제에 충돌하여 식모되게 부착되므로 식모공정이 종료된 다음 건조시키면, 천연가죽분말이 중심사 표면에 일체로 접착되어 내구성을 가지게 되고, 식모되지 않고 중심사 표면에 묻어 있는 상태로 남아 있는 천연가죽분말은 브러시롤러를 접촉시켜 떨어냄으로써, 중심사에서 분리시키고, 집진기로 회수하여 재사용을 할 수 있게 되며 천연가죽분말이 식모된 실의 표면을 샌드페이퍼에 접촉시켜서 천연가죽분말의 표면을 연마가공함으로써, 표면이 가지런하게 가공이 이루어지고, 실의 단면이 원형으로 되는 가죽사를 얻을 수 있게 된다.
따라서 본 발명의 제법으로 가죽사를 제조하면 내구성이 높고 천연가죽의 질감과 외모를 가지는 가죽사 제조가 용이하여 폐가죽의 활용률을 높일 수 있고, 대량생산으로 가죽사를 제조할 수 있으며, 가죽사의 단면이 원형으로 제조되므로 일반적인 실과 같이 제직에 사용할 수 있어 다양한 피혁지의 제조가 가능하게 되고, 신발, 가방, 인테리어에 패턴이 다양한 가죽사 제품을 공급할 수 있는 이점이 있다.
In the present invention as described above, by supplying a natural leather powder of a certain standard prepared by using the waste leather to the surface of the core yarn coated with a water-soluble polyurethane adhesive, by generating a high-pressure electrostatic, the natural leather powder collides with the adhesive by the flocking method Since the thread is manufactured by bonding with the force and grinding the cross section of the thread to maintain the circular shape, the natural leather powder is firmly attached to the surface of the core yarn and has durability. It can be used for weaving and knitting, while maintaining its appearance, and can be used for weaving and knitting.
In addition, the present invention is to prepare a powder of natural leather powder with an average particle diameter of 3 ~ 10 microns, and to apply a water-soluble polyurethane adhesive 40 to 60㎛ thickness on the surface of the core yarn to supply to the flocking room, flocking on the top of the flocking room By supplying 20 ~ 30KV high voltage static electricity while supplying the natural leather powder into the room, the natural leather powder supplied to the flocking room receives the electrostatic pressure and collides with the adhesive applied on the surface of the core yarn passing through the flocking room. When the hair-drying process is finished and dried, the natural leather powder is integrally adhered to the surface of the core yarn to have durability, and the natural leather powder which is not planted and remains on the surface of the core yarn is brought into contact with the brush roller. Can be separated from the main thread, collected with a dust collector, and reused. Is brought into contact with the surface to sandpaper the surface of the natural leather, by processing the abrasive powder, it is justified that the surface processing is done, the cross-sectional area of the chamber it is possible to obtain a leather which is used in a circular shape.
Therefore, if the leather yarn is manufactured by the manufacturing method of the present invention, leather yarn having high durability and texture and appearance of natural leather can be easily manufactured to increase utilization of waste leather, and leather yarn can be manufactured by mass production. Since the cross section is manufactured in a circular shape, it can be used for weaving like a general thread, and thus, it is possible to manufacture a variety of leather papers, and there is an advantage of supplying a variety of leather products in patterns to shoes, bags, and interiors.

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도 1은 본 발명의 제조공정 개략도
도 2는 플로킹룸 예시도
도 3은 가죽사 실물 사진
도 4는 가죽사 단면 예시도이다.
1 is a manufacturing process schematic diagram of the present invention
2 is an illustration of a flooring room
3 is a leather yarn physical picture
4 is a cross-sectional view of leather yarn.


건조된 중심사 표면에 브러시롤러를 접촉시켜서 중심사에 식모되지 않고 중심사 표면에 남아 있는 천연가죽분말을 브러시롤러로 떨어내는 천연가죽분말 분리단계와,
천연가죽분말이 식모된 중심사를 회전하는 샌드페이퍼에 접촉시켜 천연가죽분말 표면을 연마하고, 실의 단면을 원형으로 가공하는 표면 가공 단계를 실시하여 가죽사를 제조하고 제조된 가죽사를 보빈에 권취하는 단계로 이루어진다.
한편, 본 발명의 플로킹룸(4)에는 상부측에 천연가죽분말공급실(4a)을 형성하여 그 배출구(4b) 내측에 회전브러시(4c)를 장치하여 이루어지고, 플로킹품 내부에는 고압정전기발생장치(4d)를 배치하여 이루어진다.

위 방법에 의해 제조된 가죽사는, 폐가죽을 탈지, 정련, 염색, 분쇄하고 전착처리하여 제조한 평균 입경 3~10 미크론 되는 천연가죽분말(3)과,
수용성폴리우레탄에 수용성폴리우레탄 100중량부 대비 3중량부의 경화제, 0.3중량부 ~ 0.4중량부의 천연가죽분말색상과 같은 안료 및 약간의 증점제를 혼합하여 용도에 맞게 점도를 형성한 수용성폴리우레탄접착제(2)와,
420 ~ 840 데니어 규격을 가지는 나일론필라멘트사를 포함하는 합성섬유 중에서 선택한 섬유를 중심사로 준비하고, 선택한 중심사(1) 표면에 수용성우레탄접착제를 도포하여 접착제에 천연가죽분말을 식모하여 천연가죽분말이 중심사와 일체가 되는 구성으로 된다.

A step of separating the natural leather powder by contacting the dried roller surface with the brush roller and dropping the natural leather powder remaining on the surface of the core yarn with the brush roller without being planted in the core yarn;
The core of the natural leather powder is brought into contact with the rotating sandpaper to polish the surface of the natural leather powder, and the surface processing step of processing the cross section of the yarn is carried out to manufacture the leather yarn. Taking steps.
Meanwhile, in the flocking room 4 of the present invention, a natural leather powder supply chamber 4a is formed on the upper side, and a rotating brush 4c is provided inside the discharge port 4b. 4d is arranged.

Leather yarn prepared by the above method, the natural leather powder (3) having an average particle diameter of 3 to 10 microns prepared by degreasing, refining, dyeing, pulverizing and electrodeposition waste leather,
A water-soluble polyurethane adhesive having a viscosity suited to a purpose by mixing a water-soluble polyurethane with 3 parts by weight of a curing agent, 0.3 parts by weight to 0.4 parts by weight of a pigment such as natural leather powder, and a slight thickener (2 )Wow,
Prepare the selected fiber among the synthetic fibers including nylon filament yarn having 420 ~ 840 denier as a core yarn, apply a water-soluble urethane adhesive on the surface of the selected core yarn (1) to plant the natural leather powder on the adhesive It becomes the structure united with the central thread.

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1 : 중심사 2 : 수용성폴리우레탄접착제
3 : 천연가죽분말 4 : 플로킹룸
4a : 천연가죽분말공급실 4b : 배출구
4c : 회전브러시 4d : 고압정전기발생장치
1: center yarn 2: water-soluble polyurethane adhesive
3: natural leather powder 4: flooring room
4a: natural leather powder supply room 4b: outlet
4c: Rotary brush 4d: High pressure electrostatic generator

Claims (2)

삭제delete 폐가죽을 탈지, 정련, 염색, 분쇄하고 전착처리하여 제조한 평균 입경 3 ~ 10 미크론 규격을 가지도록 가공하는 천연가죽분말(3) 준비단계와;
수용성폴리우레탄에 수용성폴리우레탄 100중량부 대비 3중량부의 경화제, 0.3중량부 ~ 0.4중량부의 천연가죽분말색상과 같은 안료 및 증점제를 혼합하여 접착제를 조성하되 접착제의 점도를 4000 ~ 9000 CPS로 조정하는 수용성폴리우레탄접착제(2) 준비단계와;
420 ~ 840 데니어 규격을 가지는 나일론필라멘트사를 포함하는 합성섬유 중에서 선택한 섬유를 중심사로 하는 중심사(1) 준비단계와;
준비된 중심사의 표면에 수용성폴리우레탄 접착제를 40 ~ 60㎛ 두께로 도포하는 접착제 도포단계와,
접착제가 도포된 중심사를 분당 15 ~ 20m 속도로 플로킹룸으로 공급하고, 플로킹룸 상부에서 플로킹룸 내부로 천연가죽분말(3)을 공급하면서 플로킹룸 내부에 20 ~ 30KV 되는 고압정전기를 발생시켜 중심사 표면에 도포된 접착제에 천연가죽분말을 충돌시켜 식모하는 천연가죽분말식모단계와;
천연가죽분말이 식모된 중심사를 120℃에서 15분간 열풍처리하여 건조시키는 단계와;
건조된 중심사 표면에 브러시롤러를 접촉시켜 중심사 표면에서 식모되지 않고 묻어 있는 천연가죽분말을 브러시롤러로 떨어내는 천연가죽분말 분리단계와;
천연가죽분말이 식모된 중심사를 회전하는 샌드페이퍼에 접촉시켜 천연가죽분말 표면을 연마하고, 실의 단면이 원형으로 되게 가공하는 표면 가공 단계를 실시하여 이루어지는 폐가죽을 활용하는 가죽사 제조방법.
A step of preparing natural leather powder (3) for processing waste leather to have an average particle size of 3 to 10 microns prepared by degreasing, refining, dyeing, grinding and electrodeposition;
The adhesive is formed by mixing a water-soluble polyurethane with 3 parts by weight of a curing agent compared to 100 parts by weight of a water-soluble polyurethane, and 0.3 parts by weight to 0.4 parts by weight of a pigment, such as a natural leather powder color, to adjust the viscosity of the adhesive to 4000 to 9000 CPS. Preparing a water-soluble polyurethane adhesive (2);
A core yarn (1) preparing step comprising a fiber selected from synthetic fibers including nylon filament yarn having a denier size of 420 to 840;
Adhesive coating step of applying a water-soluble polyurethane adhesive 40 ~ 60㎛ thickness on the surface of the prepared core yarn,
The center is coated with the adhesive-coated core yarn at a speed of 15-20m per minute to the flocking room, and a high-voltage static electricity of 20-30KV is generated inside the flocking room while supplying the natural leather powder (3) from the top of the flocking room to the flocking room. A natural leather powder flocking step of impregnating natural leather powder with the adhesive applied to the yarn surface;
A step of drying the core yarn in which the natural leather powder is planted by hot air treatment at 120 ° C. for 15 minutes;
A natural leather powder separation step of contacting the dried roller surface with a brush roller to drop the natural leather powder which is not planted on the surface of the central yarn with a brush roller;
A method for producing leather yarn utilizing waste leather, which is performed by contacting a central paper in which a natural leather powder is planted with a rotating sandpaper, polishing the surface of the natural leather powder, and performing a surface processing step of processing a circular cross section of the yarn.
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CN112831882A (en) * 2021-02-03 2021-05-25 武汉红金叶新材料科技有限公司 Production process and product of cooling type granular viscose fiber
CN113622190A (en) * 2021-08-06 2021-11-09 武汉纺织大学 Leather-imitated color functional yarn for clothing and preparation method thereof

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KR20060040626A (en) * 2006-04-12 2006-05-10 (주)동원플록 The he manufacturing method of flocked fabrics with elasticity using scrapped leather
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KR101514996B1 (en) * 2014-05-19 2015-04-24 김종원 A method for manufacturing a synthethic yarn andsynthethic yarn thereby

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KR840006011U (en) 1982-03-10 1984-11-10 오익야 Manufacturing equipment for leather shoes for mens shoes
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KR20060040626A (en) * 2006-04-12 2006-05-10 (주)동원플록 The he manufacturing method of flocked fabrics with elasticity using scrapped leather
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112831882A (en) * 2021-02-03 2021-05-25 武汉红金叶新材料科技有限公司 Production process and product of cooling type granular viscose fiber
CN112831882B (en) * 2021-02-03 2024-02-27 武汉红金叶新材料科技有限公司 Manufacturing process of cooling type granule viscose fiber and product
CN113622190A (en) * 2021-08-06 2021-11-09 武汉纺织大学 Leather-imitated color functional yarn for clothing and preparation method thereof

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