KR101907250B1 - Thin film transistor and manufacturing method thereof - Google Patents
Thin film transistor and manufacturing method thereof Download PDFInfo
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- KR101907250B1 KR101907250B1 KR1020160009090A KR20160009090A KR101907250B1 KR 101907250 B1 KR101907250 B1 KR 101907250B1 KR 1020160009090 A KR1020160009090 A KR 1020160009090A KR 20160009090 A KR20160009090 A KR 20160009090A KR 101907250 B1 KR101907250 B1 KR 101907250B1
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- thin film
- oxide semiconductor
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- 239000010409 thin film Substances 0.000 title claims abstract description 125
- 238000004519 manufacturing process Methods 0.000 title abstract description 9
- 239000004065 semiconductor Substances 0.000 claims abstract description 72
- 239000000463 material Substances 0.000 claims abstract description 18
- BPUBBGLMJRNUCC-UHFFFAOYSA-N oxygen(2-);tantalum(5+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Ta+5].[Ta+5] BPUBBGLMJRNUCC-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229910001936 tantalum oxide Inorganic materials 0.000 claims abstract description 17
- 239000000758 substrate Substances 0.000 claims abstract description 13
- 239000010408 film Substances 0.000 claims abstract description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 42
- 229910052757 nitrogen Inorganic materials 0.000 claims description 20
- 229910052738 indium Inorganic materials 0.000 claims description 8
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 8
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims description 6
- 229910052733 gallium Inorganic materials 0.000 claims description 6
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 4
- 229910052718 tin Inorganic materials 0.000 claims description 4
- 229910052725 zinc Inorganic materials 0.000 claims description 4
- 239000011701 zinc Substances 0.000 claims description 4
- 239000012535 impurity Substances 0.000 abstract description 21
- 229910000449 hafnium oxide Inorganic materials 0.000 abstract description 15
- WIHZLLGSGQNAGK-UHFFFAOYSA-N hafnium(4+);oxygen(2-) Chemical compound [O-2].[O-2].[Hf+4] WIHZLLGSGQNAGK-UHFFFAOYSA-N 0.000 abstract description 14
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 abstract description 14
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract description 13
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 20
- 229910052786 argon Inorganic materials 0.000 description 10
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 6
- 239000007789 gas Substances 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 229910052735 hafnium Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- 239000008186 active pharmaceutical agent Substances 0.000 description 3
- 229910021478 group 5 element Inorganic materials 0.000 description 3
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 229910052715 tantalum Inorganic materials 0.000 description 3
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 3
- 239000013077 target material Substances 0.000 description 3
- 229910052719 titanium Inorganic materials 0.000 description 3
- 239000010936 titanium Substances 0.000 description 3
- 238000002834 transmittance Methods 0.000 description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 229910052785 arsenic Inorganic materials 0.000 description 2
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 2
- 238000000231 atomic layer deposition Methods 0.000 description 2
- 238000005229 chemical vapour deposition Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- AJNVQOSZGJRYEI-UHFFFAOYSA-N digallium;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Ga+3].[Ga+3] AJNVQOSZGJRYEI-UHFFFAOYSA-N 0.000 description 2
- 229910001873 dinitrogen Inorganic materials 0.000 description 2
- 229910001195 gallium oxide Inorganic materials 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 238000004544 sputter deposition Methods 0.000 description 2
- 238000000427 thin-film deposition Methods 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- 229910004143 HfON Inorganic materials 0.000 description 1
- 229910010282 TiON Inorganic materials 0.000 description 1
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- -1 hafnium nitride Chemical class 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- JMOHEPRYPIIZQU-UHFFFAOYSA-N oxygen(2-);tantalum(2+) Chemical compound [O-2].[Ta+2] JMOHEPRYPIIZQU-UHFFFAOYSA-N 0.000 description 1
- MZLGASXMSKOWSE-UHFFFAOYSA-N tantalum nitride Chemical compound [Ta]#N MZLGASXMSKOWSE-UHFFFAOYSA-N 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
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- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/68—Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
- H01L29/76—Unipolar devices, e.g. field effect transistors
- H01L29/772—Field effect transistors
- H01L29/78—Field effect transistors with field effect produced by an insulated gate
- H01L29/786—Thin film transistors, i.e. transistors with a channel being at least partly a thin film
- H01L29/7869—Thin film transistors, i.e. transistors with a channel being at least partly a thin film having a semiconductor body comprising an oxide semiconductor material, e.g. zinc oxide, copper aluminium oxide, cadmium stannate
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- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02107—Forming insulating materials on a substrate
- H01L21/02109—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates
- H01L21/02112—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer
- H01L21/02123—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer the material containing silicon
- H01L21/02142—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer the material containing silicon the material containing silicon and at least one metal element, e.g. metal silicate based insulators or metal silicon oxynitrides
- H01L21/02148—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer the material containing silicon the material containing silicon and at least one metal element, e.g. metal silicate based insulators or metal silicon oxynitrides the material containing hafnium, e.g. HfSiOx or HfSiON
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- H01L21/02107—Forming insulating materials on a substrate
- H01L21/02109—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates
- H01L21/02112—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer
- H01L21/02123—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer the material containing silicon
- H01L21/02142—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer the material containing silicon the material containing silicon and at least one metal element, e.g. metal silicate based insulators or metal silicon oxynitrides
- H01L21/0215—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer the material containing silicon the material containing silicon and at least one metal element, e.g. metal silicate based insulators or metal silicon oxynitrides the material containing tantalum, e.g. TaSiOx
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- H01L21/02107—Forming insulating materials on a substrate
- H01L21/02109—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates
- H01L21/02112—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer
- H01L21/02123—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer the material containing silicon
- H01L21/02142—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer the material containing silicon the material containing silicon and at least one metal element, e.g. metal silicate based insulators or metal silicon oxynitrides
- H01L21/02153—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer the material containing silicon the material containing silicon and at least one metal element, e.g. metal silicate based insulators or metal silicon oxynitrides the material containing titanium, e.g. TiSiOx
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- H01L29/68—Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
- H01L29/76—Unipolar devices, e.g. field effect transistors
- H01L29/772—Field effect transistors
- H01L29/778—Field effect transistors with two-dimensional charge carrier gas channel, e.g. HEMT ; with two-dimensional charge-carrier layer formed at a heterojunction interface
- H01L29/7786—Field effect transistors with two-dimensional charge carrier gas channel, e.g. HEMT ; with two-dimensional charge-carrier layer formed at a heterojunction interface with direct single heterostructure, i.e. with wide bandgap layer formed on top of active layer, e.g. direct single heterostructure MIS-like HEMT
- H01L29/7787—Field effect transistors with two-dimensional charge carrier gas channel, e.g. HEMT ; with two-dimensional charge-carrier layer formed at a heterojunction interface with direct single heterostructure, i.e. with wide bandgap layer formed on top of active layer, e.g. direct single heterostructure MIS-like HEMT with wide bandgap charge-carrier supplying layer, e.g. direct single heterostructure MODFET
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Abstract
A thin film transistor using a transparent P-type oxide semiconductor thin film as a channel layer and a manufacturing method thereof are disclosed. The disclosed thin film transistor includes a substrate; A gate insulating film; And a P-type oxide semiconductor thin film, wherein the P-type oxide semiconductor thin film is a thin film to which an impurity is added to a material selected from tantalum oxide, titanium oxide and hafnium oxide.
Description
The present invention relates to a thin film transistor and a method of manufacturing the same, and more particularly, to a thin film transistor using a thin P-type oxide semiconductor thin film as a channel layer and a method of manufacturing the same.
Recently, as a new application of thin film transistor (TFT), a technology for integrating thin film transistors on a transparent glass or plastic substrate into a logic circuit has been studied.
Conventional N-type transparent oxide thin film transistors are attracting great interest because they can have large charge mobility even in an amorphous state. For example, an oxide semiconductor having a band gap energy of about 3.0 eV or more exhibits a transparent characteristic. The N-type transparent oxide thin film transistor is formed of zinc oxide (ZnO), indium gallium oxide (IGO), indium gallium zinc oxide (IGZO) or the like is used as a channel layer.
In order to form a thin film transistor into a CMOS (Complementary Metal-Oxide Semiconductor) type, a P-type transparent oxide thin film transistor having a carrier as well as an N-type transparent oxide thin film transistor having a carrier is required. It is actively proceeding.
Related Korean Patent Publication Nos. 2010-0083322 and 2015-0017040.
The present invention provides a thin film transistor using a transparent P-type oxide semiconductor thin film as a channel layer and a method of manufacturing the same.
According to an aspect of the present invention, there is provided a plasma display panel comprising: a substrate; A gate insulating film; And a P-type oxide semiconductor thin film, wherein the P-type oxide semiconductor thin film is a thin film in which impurity is added to a material selected from tantalum oxide, titanium oxide and hafnium oxide.
According to another aspect of the present invention, there is provided a plasma display panel comprising: a substrate; A gate insulating film; A P-type oxide semiconductor thin film; And an N-type oxide semiconductor thin film, wherein the P-type oxide semiconductor thin film is a thin film in which an impurity is added to a material selected from tantalum oxide, titanium oxide and hafnium oxide.
According to another aspect of the present invention, there is provided a method of manufacturing a semiconductor device, comprising: forming an oxide semiconductor thin film on a substrate; And implanting a P-type impurity into the oxide semiconductor thin film, wherein the oxide semiconductor thin film is selected from tantalum oxide, titanium oxide, and hafnium oxide.
According to the present invention, a transparent P-type thin film transistor can be provided by implanting a P-type impurity into a material selected from tantalum oxide, titanium oxide and hafnium oxide.
Also, according to the present invention, the transparency of the thin film transistor can be controlled by adjusting the concentration of the P-type impurity or the bandgap control material.
Also, according to the present invention, a transparent CMOS thin film transistor can be implemented together with a transparent N-type thin film transistor.
1 and 2 are views for explaining a thin film transistor according to an embodiment of the present invention.
FIG. 3 shows transfer characteristics when TaON is used as a P-type oxide semiconductor thin film and ITO is used as a source / drain electrode.
4 shows characteristics of a transistor in which ZnSnTaON is used as a P-type oxide semiconductor thin film and ITO is used as a source / drain electrode.
5 shows the transfer characteristics when TaON is used as the P-type oxide semiconductor thin film and Ni is used as the source / drain electrode.
6 is a view for explaining a method of manufacturing a thin film transistor according to an embodiment of the present invention.
Fig. 7 shows the transfer characteristics when the ratio of nitrogen and argon is changed in Fig. 5. Fig.
8 is a graph showing the transparency of the P-type oxide semiconductor thin film according to the ratio of nitrogen and argon.
9 is a diagram illustrating an inverter using a thin film transistor according to an embodiment of the present invention.
While the invention is susceptible to various modifications and alternative forms, specific embodiments thereof are shown by way of example in the drawings and will herein be described in detail. It should be understood, however, that the invention is not intended to be limited to the particular embodiments, but includes all modifications, equivalents, and alternatives falling within the spirit and scope of the invention. Like reference numerals are used for like elements in describing each drawing.
The present invention provides a P-type transparent thin film transistor using a transparent P-type oxide semiconductor thin film. A transparent CMOS thin film transistor can be implemented together with an N-type transparent thin film transistor using the thin film transistor according to the present invention.
The P-type transparent oxide semiconductor thin film according to the present invention is a thin film to which an impurity is added to a material selected from tantalum oxide (TaO), titanium oxide (TiO), and hafnium oxide (HfO). Tantalum oxide, titanium oxide or hafnium oxide may exhibit P-type characteristics due to impurities, and Group 5 elements such as nitrogen, phosphorus, and arsenic may be used as impurities.
Hereinafter, embodiments according to the present invention will be described in detail with reference to the accompanying drawings.
FIG. 1 and FIG. 2 illustrate a thin film transistor according to an embodiment of the present invention. FIG. 1 shows a bottom gate type thin film transistor, and FIG. 2 shows a top gate type thin film transistor.
Referring to FIG. 1, a
The P-type oxide semiconductor
Tantalum oxide, titanium oxide, and hafnium oxide exhibit P-type characteristics by the addition of impurities, and a Group 5 element such as nitrogen, phosphorus, and arsenic can be used as an impurity. In particular, nitrogen has an ionic radius similar to that of oxygen and has the lowest p-orbital energy among Group 5 elements, so that it is suitable as an impurity for exhibiting P-type characteristics. (TaON), titanium nitride oxide (TiON), and hafnium nitride oxide (HfON) are implanted into the p-type oxide semiconductor
On the other hand, the transparency of the P-type oxide semiconductor
(1.31), Ca (1.00), Sr (0.95) and La (0.95) which are less electronegative than tantalum (1.5), titanium (1.54) and hafnium 1.1), Sc (1.36), Y (1.22), Ba (0.89), and the like can be used. In this case, the transparency of the P-type oxide semiconductor
2, the
3 to 5 are views showing transfer characteristics of a thin film transistor according to an embodiment of the present invention. 3 shows transfer characteristics when TaON is used as a P-type oxide semiconductor thin film and ITO is used as a source / drain electrode. 4 shows characteristics of a transistor in which ZnSnTaON is used as a P-type oxide semiconductor thin film and ITO is used as a source / drain electrode. 5 shows the transfer characteristics when TaON is used as the P-type oxide semiconductor thin film and Ni is used as the source / drain electrode.
As shown in FIGS. 3 to 5, when V GS is increased to a negative voltage, the TFT turns on and the I DS increases. As a result, it can be confirmed that the TFT operates as a P-type semiconductor.
6 is a view for explaining a method of manufacturing a thin film transistor according to an embodiment of the present invention. FIG. 7 shows the transfer characteristics when the ratio of nitrogen and argon is changed in FIG. 5, and FIG. 8 is a graph showing the transparency of the P-type oxide semiconductor thin film according to the ratio of nitrogen and argon.
As shown in Fig. 6, in step S610, an oxide semiconductor thin film is formed on the substrate, and in step S620, a p-type impurity is implanted into the oxide semiconductor thin film. The oxide semiconductor thin film is selected from tantalum oxide, titanium oxide, and hafnium oxide, and the oxide semiconductor thin film can exhibit P-type characteristics by implanting P-type impurities.
The P-type oxide semiconductor thin film may be formed by a thin film deposition process such as chemical vapor deposition (CVD), atomic layer deposition (ALD), or sputtering. A process of forming a P-type oxide semiconductor thin film of a bottom gate type thin film transistor structure by sputtering will be described in more detail. A substrate on which a gate electrode and a gate insulating film are formed and a target material are prepared. The target material may be selected from tantalum oxide, titanium oxide, and hafnium oxide, and a target material containing a bandgap control material in tantalum oxide, titanium oxide, or hafnium oxide may be used.
A nitrogen-doped P-type oxide semiconductor thin film can be formed by injecting and accelerating argon gas and nitrogen gas into a chamber in which a substrate having a patterned shadow mask adhered thereto is prepared. At this time, the ratio of argon gas and nitrogen gas may be 3: 7, and the concentration of nitrogen may be variously adjusted according to the embodiment. The bandgap of the P-type oxide semiconductor thin film is controlled according to the concentration of nitrogen, the transparency of the P-type oxide semiconductor thin film can be controlled, and the transfer characteristics of the P-type oxide semiconductor thin film can be changed.
FIG. 7 (a) shows the ratio of nitrogen to argon gas of 6: 4, FIG. 7 (b) shows the ratio of nitrogen to argon gas of 7: 3, The transfer characteristics are shown. It can be confirmed that the transfer characteristics of the thin film transistor are the most excellent when the ratio of nitrogen to argon gas is 7: 3. Note in Figure 7 (b) is a view corresponding to Figure 5, Figure 7 is a black line in the case of V DS is -0.1V red line represents the transfer characteristic in the case where V DS is -5.1V.
8 is a graph showing the transmittance of the thin film transistor for each wavelength when tantalum nitride oxide (TaON) is used as the P-type oxide semiconductor thin film and the ratio of nitrogen to argon gas is 6: 4, 7: 3 and 8: transmittance. In all three cases, the transmittance is more than 65% at the wavelength of 400 ~ 700nm which is the visible ray region. The higher the ratio of nitrogen in the chamber, the lower the transparency. That is, the higher the concentration of the P-type impurity implanted into the P-type oxide semiconductor thin film, the lower the band gap energy and the lower the transparency of the P-type oxide semiconductor thin film.
Consequently, the transfer characteristics and the transparency of the thin film transistor are controlled in accordance with the concentration of the P-type impurity, and the concentration of the P-type impurity can be determined in accordance with the embodiment.
On the other hand, after the p-type oxide semiconductor thin film is formed, the substrate is subjected to heat treatment in a glove box of nitrogen atmosphere at 600 ° C or 400 ° C for 2 hours. Finally, a thin film transistor can be manufactured by forming a source / drain electrode of ITO or Ni by using a patterned shadow mask and performing a heat treatment at 200 degrees.
A P-type semiconductor oxide thin film may be formed by first forming a semiconductor oxide thin film by a thin film deposition process and doping the P-type impurity. As described above, the bandgap of the P-type oxide semiconductor thin film can be adjusted according to the doping concentration of the P-type impurity.
9 is a diagram illustrating an inverter using a thin film transistor according to an embodiment of the present invention.
9, the transparent P-type
In other words, the thin film transistor according to another embodiment of the present invention is a CMOS thin film transistor including a substrate, a gate insulating film, a P-type oxide semiconductor thin film, and an N-type oxide semiconductor thin film, wherein the P-type oxide semiconductor thin film includes tantalum oxide, An oxide, and a hafnium oxide. The transparent N-type oxide semiconductor thin film may be selected from zinc oxide (ZnO), indium gallium oxide (IGO), indium gallium zinc oxide (IGZO).
As described above, the present invention has been described with reference to particular embodiments, such as specific elements, and specific embodiments and drawings. However, it should be understood that the present invention is not limited to the above- And various modifications and changes may be made thereto by those skilled in the art to which the present invention pertains. Accordingly, the spirit of the present invention should not be construed as being limited to the embodiments described, and all of the equivalents or equivalents of the claims, as well as the following claims, belong to the scope of the present invention .
Claims (10)
A gate insulating film; And
A p-type oxide semiconductor thin film,
The P-type oxide semiconductor thin film
Thin film with nitrogen added to tantalum oxide
Thin film transistor.
The P-type oxide semiconductor thin film
Further comprising a band gap adjusting material for adjusting a band gap energy of the P-type oxide semiconductor thin film
Thin film transistor.
The band gap adjusting material
Tin, zinc, indium and gallium
Thin film transistor.
A gate insulating film;
A P-type oxide semiconductor thin film; And
An N-type oxide semiconductor thin film,
The P-type oxide semiconductor thin film
Thin film with nitrogen added to tantalum oxide
Thin film transistor.
And injecting nitrogen into the oxide semiconductor thin film to form a P-type oxide semiconductor thin film,
The P-type oxide semiconductor thin film
Thin film with nitrogen added to tantalum oxide
Lt; / RTI >
The P-type oxide semiconductor thin film
Further comprising a band gap adjusting material for adjusting a band gap energy of the P-type oxide semiconductor thin film
Lt; / RTI >
The band gap adjusting material
Tin, zinc, indium and gallium
Lt; / RTI >
The band gap energy of the P-type oxide semiconductor thin film is
The concentration of nitrogen
Lt; / RTI >
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Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2001322814A (en) | 2000-05-12 | 2001-11-20 | Kenkichiro Kobayashi | P-type oxide semiconductor and its manufacturing method |
US20120097922A1 (en) | 2009-06-26 | 2012-04-26 | Showa Denko K.K. | Light emitting element, method of producing same, lamp, electronic equipment, and mechinical apparatus |
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2016
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Patent Citations (2)
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JP2001322814A (en) | 2000-05-12 | 2001-11-20 | Kenkichiro Kobayashi | P-type oxide semiconductor and its manufacturing method |
US20120097922A1 (en) | 2009-06-26 | 2012-04-26 | Showa Denko K.K. | Light emitting element, method of producing same, lamp, electronic equipment, and mechinical apparatus |
Non-Patent Citations (1)
Title |
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김상철 외, P-type 투명산화물 반도체 개발 및 응용기술 연구, 한국전기연구원 |
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