KR101873224B1 - Method for recycling waste lcd glass and application thereof - Google Patents

Method for recycling waste lcd glass and application thereof Download PDF

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KR101873224B1
KR101873224B1 KR1020170025588A KR20170025588A KR101873224B1 KR 101873224 B1 KR101873224 B1 KR 101873224B1 KR 1020170025588 A KR1020170025588 A KR 1020170025588A KR 20170025588 A KR20170025588 A KR 20170025588A KR 101873224 B1 KR101873224 B1 KR 101873224B1
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South Korea
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glass
waste lcd
separating
polarizing film
recycling
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KR1020170025588A
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Korean (ko)
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이찬기
김세열
윤진호
박재량
강이승
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고등기술연구원연구조합
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B02CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
    • B02CCRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
    • B02C7/00Crushing or disintegrating by disc mills
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B07SEPARATING SOLIDS FROM SOLIDS; SORTING
    • B07BSEPARATING SOLIDS FROM SOLIDS BY SIEVING, SCREENING, SIFTING OR BY USING GAS CURRENTS; SEPARATING BY OTHER DRY METHODS APPLICABLE TO BULK MATERIAL, e.g. LOOSE ARTICLES FIT TO BE HANDLED LIKE BULK MATERIAL
    • B07B1/00Sieving, screening, sifting, or sorting solid materials using networks, gratings, grids, or the like
    • B07B1/28Moving screens not otherwise provided for, e.g. swinging, reciprocating, rocking, tilting or wobbling screens
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B07SEPARATING SOLIDS FROM SOLIDS; SORTING
    • B07BSEPARATING SOLIDS FROM SOLIDS BY SIEVING, SCREENING, SIFTING OR BY USING GAS CURRENTS; SEPARATING BY OTHER DRY METHODS APPLICABLE TO BULK MATERIAL, e.g. LOOSE ARTICLES FIT TO BE HANDLED LIKE BULK MATERIAL
    • B07B13/00Grading or sorting solid materials by dry methods, not otherwise provided for; Sorting articles otherwise than by indirectly controlled devices
    • B07B13/04Grading or sorting solid materials by dry methods, not otherwise provided for; Sorting articles otherwise than by indirectly controlled devices according to size
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B3/00Destroying solid waste or transforming solid waste into something useful or harmless
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B37/00Manufacture or treatment of flakes, fibres, or filaments from softened glass, minerals, or slags
    • C03B37/01Manufacture of glass fibres or filaments
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F2203/00Function characteristic
    • G02F2203/68Green display, e.g. recycling, reduction of harmful substances
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/20Waste processing or separation
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/60Glass recycling

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Food Science & Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Glass Melting And Manufacturing (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

The present invention relates to a method for recycling waste LCD glass and an application thereof and, more specifically, to a method for recycling waste LCD glass which applies a wet separation method to waste LCD panels to separate polarizing films and glass and then collect the separated glass, and a method of using glass powder obtained by pulverizing glass collected by the same to manufacture long glass fiber. According to the present invention, a wet separation method using a polarizing film separation solution with an excellent polarizing film separation effect is applied to collect glass from waste LCD panels at a high collection rate. Also, glass collected in accordance with the present invention has a low foreign substance content and is pulverized to allow high value-added recycling.

Description

METHOD FOR RECYCLING WASTE LCD GLASS AND APPLICATION THEREOF FIELD OF THE INVENTION [0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a recycling method of waste LCD glass and its application, and more particularly, to a waste LCD The present invention relates to a method for recycling glass and a method for producing glass fiber using the glass powder obtained by micronizing glass recovered by the above method.

LCD glass is a high value added product manufactured through high-level quality control. LCD glass is divided into STN (Super-Twisted Nematic) and TFT, and the glass composition is different. Since STN glass substrates require flat surfaces due to the nature of the driving method, soda borosilicate glass with a strain point of 550 ° C or less suitable for LCD manufacturing processes is used. In addition, since the transparent conductive film is damaged by surface diffusion of alkali ions generated by alkali oxides such as Na 2 O and K 2 O, a silica protective film is first formed on the surface of the substrate glass. STN LCDs have been used in recent years because they are inexpensive to manufacture but are poor in color and appear only in the front. Currently, TFT LCDs are used in most LCDs. Alumino borosilicate glass, which has a high strain point and a low coefficient of thermal expansion, is used because soda-borosilicate glass can not satisfy TFT manufacturing process temperature.

In Korea, waste LCD glass is processed waste glass and used waste glass. The possibility of the waste LCD glass is extremely limited, and the initial composition is maintained, so that the difference in the chemical composition of the waste LCD itself is not large. In order to recycle waste LCD glass, it is necessary to develop uniformization of recycled glass and development of technologies for removing impurities (metal, organic materials, etc.). However, development of technologies related to waste display and LCD panel glass recycling in Korea is very insufficient, In fact, it is necessary to conduct research on the landfill.

Korean Patent No. 10-0886684

The present invention provides a method of recycling a waste LCD glass performed by a method of applying a wet separation method to a waste LCD panel to separate a polarizing film and a glass and then recovering the separated glass. The present invention also provides a method for producing glass fiber using the glass powder obtained by micronizing the glass recovered by the above method.

The present invention provides a method of recycling a waste LCD glass comprising grinding a waste LCD panel and then wet-separating the polarizing film by mixing with a separating liquid, and then screening the glass.

Wherein the separating liquid comprises a composition for separating a polarizing film, wherein the composition for separating polarizing film comprises 5 to 15% by weight of ethylenediaminetetracetic acid based on 100% by weight of the total of the separating composition; 0.5 to 5% by weight of potassium hydroxide; 5 to 15% by weight of sodium metasilicate pentahydrate; 5 to 15% by weight of octoxinol; And a remaining amount of water. ≪ IMAGE >

The composition for separating polarizing film may further contain an inhibitor and the content thereof may be 2 to 12% by weight.

Wherein the inhibitor is at least one selected from the group consisting of polyvinyl oxazolidone, polyvinyl pyrrolidone, polyvinylimidazole polyamine N-oxide, and copolymers of N-vinylpyrrolidone and N-vinylimidazole But is not limited thereto.

Crushing of waste LCD panel

The waste LCD panel may be pulverized into a chip shape having a size of 10 to 50 mm, and more preferably a chip shape having a size of 20 to 30 mm. In consideration of the recycling treatment capacity and process efficiency, it is preferable to crush to the above-mentioned range.

When the waste LCD panel is recycled without being pulverized, it is difficult to remove the encapsulant, the efficiency of removing impurities may decrease, and the throughput of the recycling process may decrease.

Wet separation

The step of pulverizing the waste LCD panel and mixing the waste LCD panel may be performed by mixing the pulverized LCD panel with 100 g of the pulverized LCD panel per 500 to 2000 ml of the separated liquid.

The separation liquid may contain 5 to 50 v / v%, and more preferably 10 to 30 v / v%, of the composition for separating a polarizing film.

The separating liquid may be a form in which the separating composition is diluted with distilled water.

The wet separation may be carried out by pulverizing the waste LCD panel, charging it into the separation liquid, and then stirring at a temperature of 30 to 60 DEG C for 1 to 5 hours. More preferably at a temperature of 50 DEG C for 3 hours. In the case of a closed LCD panel, it is difficult to physically separate the glass because the glass and the film are adhered to each other. When performing the wet separation in the temperature and time range, the glass and the polarizing film of the waste LCD panel can be easily separated.

Glass selection

The step of screening the glass may be carried out by using a difference in size of the mixture. At this time, the recyclable glass is recovered and the separated polarizing film is discarded.

Separation is essential for separating the mixture, and it is necessary to select it by using specific gravity, physicochemical properties of the surface, magnetism, color and gloss, electrical conductivity, shape, hardness and ductility, thermal differentiation, friction coefficient, conductivity, thermal conductivity, flame resistance, Can be selected. The step of screening the glass can be performed by applying specific gravity screening, middle liquid screening, magnetic force screening, electrification screening, floating screening, color screening, spectroscopy or thermal adhesion. However, It is preferable to apply a selection method using

ITO leaching

The recycling method may further include an ITO leaching step. The ITO leaching step can be carried out using 3-5 moles of hydrochloric acid, sulfuric acid, nitric acid, or a mixed acid thereof or an oxidizing agent (H 2 O 2 ) (3 to 5 moles), preferably an oxidizing agent (H 2 O 2 ).

Undifferentiation

The recycling method may further include a glass sorting step or an undifferentation step after the ITO leaching step. The undifferentiation step can be performed using a disk mill, but is not limited thereto. The average particle size of the glass powder after the refining step may be about 400 탆. The undifferentiated glass powder can be used for the production of glass fibers, especially glass fiber.

In addition, the present invention can provide a method for producing glass fiber filaments using the undifferentiated glass powder recovered by the above method. The production of glass fiber can be carried out by melting glass powder as a raw material and then making it into a fiber. The preparation in the form of fibers can be carried out through a nozzle, but not limited thereto, and all known methods used for producing glass fiber can be applied.

Further, the present invention can provide glass filaments prepared in the form of fibers after melting the undifferentiated glass powder recovered by the above method.

According to the present invention, glass can be recovered from a waste LCD panel at a high recovery rate by applying a wet separation method using a polarizing film separating liquid having an excellent polarizing film separating effect. In addition, the glass recovered according to the present invention has a low foreign matter content and is advantageous in that it can be pulverized and recycled at a high added value.

1 schematically illustrates a recycling process of a waste LCD glass according to an embodiment of the present invention.
2A is a photograph showing a vibrating body (vibrating screen) applied to an embodiment of the present invention. 2B is a schematic view of the vibrating body (vibrating screen). 2C is a photograph showing a polarizing film (upper side) and a cullet (lower side) separated by the vibrating body (vibrating screen).
FIG. 3A is a photograph showing a disc mill applied to the refining step of glass recovered according to an embodiment of the present invention. FIG. FIG. 3B is a photograph showing glass fractions recovered after grinding with the disc mill.
FIG. 4 is a result of particle size analysis (average particle size of 400 μm) after pulverizing the recovered glass according to the recycling process of waste LCD glass according to an embodiment of the present invention.

Hereinafter, the present invention will be described in more detail with reference to Examples. The objects, features and advantages of the present invention will be readily understood through the following examples. The present invention is not limited to the embodiments described herein, but may be embodied in other forms. The embodiments described herein are provided to enable those skilled in the art to fully understand the spirit of the present invention. Therefore, the present invention should not be limited by the following examples.

The method of recycling the waste LCD glass according to an embodiment of the present invention may include the step of crushing the waste LCD panel, the step of separating the polarizing film using the separating liquid for separating the polarizing film, and the step of screening the glass . Further, it may further include an ITO leaching step and a glass refining step (see FIG. 1).

Example

100 g of the waste LCD panel separated in the waste display dismantling process was pulverized into chips having a size of about 25 to 30 mm and then 1000 ml of a polarizing film separator prepared by mixing the composition for separation made of the composition shown in Table 1 in distilled water 20 v / v%). Thereafter, the mixture was stirred at 50 DEG C for 3 hours to effect wet separation. The wet-separated solid phase mixture is composed of a polarizing film, a cullet and a glass fine powder. At this time, the separated polarizing film showed a size of about 10 mm to 30 mm, and the cullet showed a size of 10 mm or less. Using the size difference of the mixture, the vibrator was sorted to separate the cullet, the polarizing film and the glass fine powder, and the glass was recovered using a vibration screen (see FIG. 2).

ingredient Content (% by weight) Ethylenediaminetetraacetic acid 11 Potassium hydroxide 2 Sodium metasilicate · pentahydrate 11 Oxycinol 11 water 65 Sum 100

Experimental Example 1: Analysis of glass recovery

The recovery rate of glass was calculated by measuring the weight of recovered glass compared to the input glass (waste glass). At this time, since the polarizing film is attached to the panel, the weight of the polarizing film recovered from the input amount is excluded. As a result, the recovery rates were 87.6%, 87.7%, 85.9%, 89.0% and 82.1%, respectively. The mean glass recovery rate of the glass recovery experiment conducted five times was 86.5%.

Figure 112017019923905-pat00001

Results of glass recovery 1 time Episode 2 3rd time 4 times 5 times Average Waste LCD panel input (g) 100 100 100 100 100 100 Waste glass input (g) 93.8 92.7 94.4 91.9 93.1 93.1 Recovery glass (g) 82.2 81.3 81.1 81.8 76.4 80.6 The recovered polarizing film (g) 6.2 7.3 5.6 8.1 6.9 6.8 Recovery rate (%) 87.6 87.7 85.9 89.0 82.1 86.5

Experimental Example 2: Undifferentiation and particle size analysis of recovered glass

In order to understand the pulverization characteristics of the recovered glass cullet, glass pulverization was carried out using a disc mill. Disc mills are used for milling a variety of products in the commercialization process. The glass fine powder is supplied to the inside of the disk mill through the inlet of the disk mill. Inside the disk mill, the effect of pressure and frictional force is generated by the rotation of the grinding disk, and the pulverized material is recovered through the lower screen (see FIG. 3). The particle size distribution of the pulverized glass fine powder was analyzed using a disk mill, and the results are shown in FIG. As shown in Fig. 4, it was confirmed that the average particle size of the undifferentiated glass powder was 400 mu m.

Claims (12)

CLAIMS What is claimed is: 1. A method of recycling a waste LCD glass comprising grinding a waste LCD panel and then wet-separating the polarizing film by mixing with a separating liquid, and then screening the glass,
Wherein the separating liquid comprises a composition for separating a polarizing film,
The composition for separating polarizing film may further comprise:
On the basis of 100% by weight of the entire separating composition,
5 to 15% by weight of ethylene diamine tetraacetic acid;
0.5 to 5% by weight of potassium hydroxide;
5 to 15% by weight of sodium metasilicate · pentahydrate;
5 to 15% by weight of octocinol; And
A method of recycling a waste LCD glass, characterized in that it comprises residual water.
The method according to claim 1,
Wherein the waste LCD panel is pulverized into a chip shape having a size of 10 to 50 mm.
The method according to claim 1,
The method of recycling waste LCD glass according to claim 1, wherein the pulverized waste LCD panel is mixed with the separated liquid at a ratio of 100 g of pulverized waste LCD panel per 500 to 2000 ml of the separated liquid.
The method according to claim 1,
Wherein the separating liquid is a form in which the separating composition is diluted in distilled water.
The method according to claim 1,
Wherein the separation liquid comprises 5 to 50 v / v% of a composition for separating polarizing film.
The method according to claim 1,
Wherein the wet separation is carried out by stirring at a temperature of 30 to 60 DEG C for 1 to 5 hours.
The method according to claim 1,
The method of recycling waste LCD glass according to claim 1, wherein the step of screening the glass is carried out by using a size difference of the mixture.
The method according to claim 1,
Characterized in that the method further comprises the step of micronizing the recovered glass.
The method of claim 8,
Characterized in that the pulverizing step comprises pulverizing the recovered glass into a glass powder having an average particle size of 400 mu m.
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KR1020170025588A 2017-02-27 2017-02-27 Method for recycling waste lcd glass and application thereof KR101873224B1 (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20220028631A (en) * 2020-08-31 2022-03-08 고등기술연구원연구조합 Method of Removing Impurities for Recycling Waste Touch Panel Glass
CN114798688A (en) * 2022-04-22 2022-07-29 安徽汇容再生资源有限公司 Resource recycling system and process for waste liquid crystal panels

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009280425A (en) * 2008-05-21 2009-12-03 Sharp Corp Recycling method for non-alkali glass, and glass material obtained thereby

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009280425A (en) * 2008-05-21 2009-12-03 Sharp Corp Recycling method for non-alkali glass, and glass material obtained thereby

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20220028631A (en) * 2020-08-31 2022-03-08 고등기술연구원연구조합 Method of Removing Impurities for Recycling Waste Touch Panel Glass
KR102528871B1 (en) * 2020-08-31 2023-05-03 고등기술연구원연구조합 Method of Removing Impurities for Recycling Waste Touch Panel Glass
CN114798688A (en) * 2022-04-22 2022-07-29 安徽汇容再生资源有限公司 Resource recycling system and process for waste liquid crystal panels

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